#------------------------------------------------------------------------------
#$Date: 2019-11-28 21:55:27 +0200 (Thu, 28 Nov 2019) $
#$Revision: 244734 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/94/7239499.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7239499
loop_
_publ_author_name
'Efthymiou, Constantinos G.'
'Kyprianidou, Eleni J.'
'Milios, Constantinos J.'
'Manos, Manolis J.'
'Tasiopoulos, Anastasios J.'
_publ_section_title
;
 Flexible lanthanide MOFs as highly selective and reusable liquid MeOH
 sorbents
;
_journal_issue                   16
_journal_name_full               'Journal of Materials Chemistry A'
_journal_page_first              5061
_journal_paper_doi               10.1039/c3ta00115f
_journal_volume                  1
_journal_year                    2013
_chemical_formula_moiety         'C82 H68 Gd4 N10 O31, 4(O0.25)'
_chemical_formula_sum            'C82 H68 Gd4 N10 O32'
_chemical_formula_weight         2334.46
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.760(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   28.747(2)
_cell_length_b                   14.4478(10)
_cell_length_c                   13.3233(8)
_cell_measurement_reflns_used    4416
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      70.8664
_cell_measurement_theta_min      3.1170
_cell_volume                     5453.5(6)
_computing_cell_refinement       'CrysAlis RED'
_computing_data_collection       'CrysAlis CCD'
_computing_data_reduction        'CrysAlis RED'
_computing_molecular_graphics
;
DIAMOND (Brandenburg, 2006)
MERCURY (Bruno et al. 2002)
;
_computing_publication_material  'WINGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.4223
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Cu) X-ray Source'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0554
_diffrn_reflns_av_sigmaI/netI    0.0683
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            9376
_diffrn_reflns_theta_full        67.00
_diffrn_reflns_theta_max         67.00
_diffrn_reflns_theta_min         3.12
_exptl_absorpt_coefficient_mu    16.095
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.33348
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Empirical absorption correction (CrysAlis RED, Oxford Diffraction)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.422
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2284
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.02
_refine_diff_density_max         2.004
_refine_diff_density_min         -1.671
_refine_diff_density_rms         0.181
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     329
_refine_ls_number_reflns         4854
_refine_ls_number_restraints     106
_refine_ls_restrained_S_all      1.065
_refine_ls_R_factor_all          0.0877
_refine_ls_R_factor_gt           0.0750
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1443P)²+15.0849P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2065
_refine_ls_wR_factor_ref         0.2199
_reflns_number_gt                3806
_reflns_number_total             4854
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ta00115f.txt
_cod_data_source_block           UCY-9
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7239499
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Gd1 Gd 0.182860(15) 0.71325(3) 0.45891(4) 0.0314(2) Uani 1 1 d .
O1 O 0.1091(3) 0.6832(6) 0.5150(8) 0.063(2) Uani 1 1 d .
O2 O 0.1225(3) 0.8316(5) 0.4971(7) 0.060(2) Uani 1 1 d .
O3 O 0.2061(2) 0.5716(4) 0.5532(5) 0.0433(15) Uani 1 1 d .
O4 O 0.2312(2) 0.8459(4) 0.4589(5) 0.0406(15) Uani 1 1 d .
O5 O 0.2014(2) 0.7601(5) 0.6298(5) 0.0389(14) Uani 1 1 d .
O6 O 0.2279(2) 0.6698(5) 0.3310(5) 0.0462(17) Uani 1 1 d .
O7 O 0.1430(4) 0.5894(8) 0.3601(8) 0.057(2) Uani 0.75 1 d PDU
O7A O 0.1494(14) 0.537(3) 0.359(3) 0.071(4) Uani 0.25 1 d PU
O8 O 0.1400(5) 0.7797(12) 0.3066(14) 0.066(3) Uani 0.75 1 d PDU
O8A O 0.153(2) 0.788(4) 0.302(5) 0.074(5) Uani 0.25 1 d PU
N1 N -0.0983(3) 0.9190(6) 0.6476(7) 0.050(2) Uani 1 1 d .
N2 N 0.1187(5) 0.5138(10) 0.1938(11) 0.071(3) Uani 0.75 1 d PDU
N3 N 0.1205(7) 0.8789(13) 0.1748(14) 0.095(4) Uani 0.75 1 d PDU
C1 C 0.0972(3) 0.7667(8) 0.5217(8) 0.045(2) Uani 1 1 d .
C2 C 0.0521(4) 0.7880(7) 0.5563(9) 0.047(2) Uani 1 1 d .
C3 C 0.0226(5) 0.7146(9) 0.5771(14) 0.077(5) Uani 1 1 d .
H3 H 0.0317 0.6535 0.5701 0.092 Uiso 1 1 calc R
C4 C -0.0203(5) 0.7345(11) 0.6082(16) 0.097(6) Uani 1 1 d .
H4 H -0.0397 0.6862 0.6221 0.116 Uiso 1 1 calc R
C5 C -0.0342(4) 0.8221(9) 0.6183(10) 0.059(3) Uani 1 1 d .
C6 C -0.0053(4) 0.8952(9) 0.5977(9) 0.060(3) Uani 1 1 d .
H6 H -0.0145 0.9561 0.6058 0.072 Uiso 1 1 calc R
C7 C 0.0368(4) 0.8766(8) 0.5652(10) 0.057(3) Uani 1 1 d .
H7 H 0.0552 0.9255 0.5491 0.069 Uiso 1 1 calc R
C8 C -0.0812(4) 0.8387(10) 0.6470(9) 0.060(3) Uani 1 1 d D
H16 H -0.098(4) 0.788(6) 0.670(11) 0.072 Uiso 1 1 d D
C9 C 0.2503(3) 0.5819(6) 0.5731(7) 0.0335(18) Uani 1 1 d .
C10 C 0.2803(3) 0.5081(6) 0.6276(7) 0.0368(19) Uani 1 1 d .
C11 C 0.3273(3) 0.4983(6) 0.6153(8) 0.040(2) Uani 1 1 d .
H11 H 0.3404 0.5394 0.5743 0.048 Uiso 1 1 calc R
C12 C 0.3546(3) 0.4257(7) 0.6655(8) 0.042(2) Uani 1 1 d .
C13 C 0.3364(3) 0.3698(6) 0.7341(7) 0.038(2) Uani 1 1 d .
H13 H 0.3555 0.3253 0.7712 0.046 Uiso 1 1 calc R
C14 C 0.2894(3) 0.3800(6) 0.7476(7) 0.0353(19) Uani 1 1 d .
C15 C 0.2610(3) 0.4473(6) 0.6923(7) 0.037(2) Uani 1 1 d .
H15 H 0.2293 0.4520 0.6983 0.044 Uiso 1 1 calc R
C16 C 0.2297(4) 0.8194(7) 0.6804(8) 0.043(2) Uani 1 1 d .
C17 C 0.1338(7) 0.5865(13) 0.2606(14) 0.075(3) Uani 0.75 1 d PDU
C18 C 0.1210(9) 0.4262(15) 0.2502(18) 0.100(5) Uani 0.75 1 d PDU
H18A H 0.1106 0.3765 0.2039 0.150 Uiso 0.75 1 calc PR
H18B H 0.1010 0.4297 0.3009 0.150 Uiso 0.75 1 calc PR
H18C H 0.1530 0.4150 0.2826 0.150 Uiso 0.75 1 calc PR
C19 C 0.1017(8) 0.5248(15) 0.0886(14) 0.084(4) Uani 0.75 1 d PDU
H19A H 0.0928 0.4655 0.0587 0.126 Uiso 0.75 1 calc PR
H19B H 0.1259 0.5515 0.0564 0.126 Uiso 0.75 1 calc PR
H19C H 0.0746 0.5649 0.0792 0.126 Uiso 0.75 1 calc PR
C20 C 0.1525(8) 0.8206(17) 0.2427(18) 0.088(4) Uani 0.75 1 d PDU
C21 C 0.0745(8) 0.8904(17) 0.1961(18) 0.100(5) Uani 0.75 1 d PDU
H21A H 0.0696 0.8483 0.2490 0.150 Uiso 0.75 1 calc PR
H21B H 0.0520 0.8779 0.1358 0.150 Uiso 0.75 1 calc PR
H21C H 0.0707 0.9528 0.2179 0.150 Uiso 0.75 1 calc PR
C22 C 0.1413(9) 0.9243(17) 0.1064(18) 0.102(5) Uani 0.75 1 d PDU
H22A H 0.1729 0.9015 0.1092 0.153 Uiso 0.75 1 calc PR
H22B H 0.1423 0.9892 0.1218 0.153 Uiso 0.75 1 calc PR
H22C H 0.1236 0.9145 0.0394 0.153 Uiso 0.75 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -8.8380 11.9157 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Gd1 O4 74.3(2) . .
O5 Gd1 O8A 135.3(16) . .
O4 Gd1 O8A 75.8(14) . .
O5 Gd1 O8 135.0(5) . .
O4 Gd1 O8 83.8(4) . .
O8A Gd1 O8 10.0(15) . .
O5 Gd1 O6 134.8(2) . .
O4 Gd1 O6 79.9(2) . .
O8A Gd1 O6 69.4(16) . .
O8 Gd1 O6 76.4(4) . .
O5 Gd1 O7 139.2(3) . .
O4 Gd1 O7 146.2(3) . .
O8A Gd1 O7 77.8(15) . .
O8 Gd1 O7 72.8(5) . .
O6 Gd1 O7 71.3(3) . .
O5 Gd1 O1 79.5(3) . .
O4 Gd1 O1 134.0(2) . .
O8A Gd1 O1 98.8(14) . .
O8 Gd1 O1 88.9(4) . .
O6 Gd1 O1 141.9(3) . .
O7 Gd1 O1 70.8(3) . .
O5 Gd1 O3 75.2(2) . .
O4 Gd1 O3 124.8(2) . .
O8A Gd1 O3 149.3(15) . .
O8 Gd1 O3 146.4(4) . .
O6 Gd1 O3 90.7(2) . .
O7 Gd1 O3 73.7(3) . .
O1 Gd1 O3 82.4(2) . .
O5 Gd1 O2 70.3(3) . .
O4 Gd1 O2 82.9(2) . .
O8A Gd1 O2 73.6(16) . .
O8 Gd1 O2 68.2(5) . .
O6 Gd1 O2 142.0(3) . .
O7 Gd1 O2 109.4(3) . .
O1 Gd1 O2 52.6(3) . .
O3 Gd1 O2 126.7(2) . .
O5 Gd1 O4 69.7(2) . 7_566
O4 Gd1 O4 75.9(2) . 7_566
O8A Gd1 O4 132.3(15) . 7_566
O8 Gd1 O4 141.8(4) . 7_566
O6 Gd1 O4 68.4(2) . 7_566
O7 Gd1 O4 108.0(3) . 7_566
O1 Gd1 O4 128.3(3) . 7_566
O3 Gd1 O4 50.60(19) . 7_566
O2 Gd1 O4 138.4(3) . 7_566
O5 Gd1 C1 72.6(3) . .
O4 Gd1 C1 108.5(3) . .
O8A Gd1 C1 86.4(15) . .
O8 Gd1 C1 78.0(4) . .
O6 Gd1 C1 152.0(3) . .
O7 Gd1 C1 90.4(3) . .
O1 Gd1 C1 26.2(3) . .
O3 Gd1 C1 104.6(3) . .
O2 Gd1 C1 26.4(3) . .
O4 Gd1 C1 139.1(3) 7_566 .
O5 Gd1 C9 70.3(2) . .
O4 Gd1 C9 100.8(2) . .
O8A Gd1 C9 148.4(16) . .
O8 Gd1 C9 153.8(4) . .
O6 Gd1 C9 79.1(2) . .
O7 Gd1 C9 90.8(3) . .
O1 Gd1 C9 105.1(3) . .
O3 Gd1 C9 24.9(2) . .
O2 Gd1 C9 137.7(3) . .
O4 Gd1 C9 25.7(2) 7_566 .
C1 Gd1 C9 123.4(3) . .
C1 O1 Gd1 96.5(6) . .
C1 O2 Gd1 89.7(6) . .
C9 O3 Gd1 100.8(5) . .
C9 O4 Gd1 159.9(6) 7_566 .
C9 O4 Gd1 89.3(5) 7_566 7_566
Gd1 O4 Gd1 104.1(2) . 7_566
C16 O5 Gd1 135.8(6) . .
C16 O6 Gd1 134.7(6) 7_566 .
O7A O7 C17 87(3) . .
O7A O7 Gd1 130(3) . .
C17 O7 Gd1 125.2(11) . .
O7 O7A C17 61(3) . .
C20 O8 Gd1 131.1(16) . .
C20 O8A Gd1 161(5) . .
C8 N1 C12 116.8(10) . 3_455
C17 N2 C19 124.4(16) . .
C17 N2 C18 109.9(16) . .
C19 N2 C18 125.7(17) . .
C22 N3 C21 128(2) . .
C22 N3 C20 114(2) . .
C21 N3 C20 117.5(19) . .
O1 C1 O2 121.2(9) . .
O1 C1 C2 118.8(9) . .
O2 C1 C2 120.0(10) . .
O1 C1 Gd1 57.3(5) . .
O2 C1 Gd1 63.9(5) . .
C2 C1 Gd1 176.1(8) . .
C7 C2 C3 118.2(10) . .
C7 C2 C1 122.3(10) . .
C3 C2 C1 119.4(10) . .
C4 C3 C2 119.6(12) . .
C4 C3 H3 120.2 . .
C2 C3 H3 120.2 . .
C5 C4 C3 121.1(13) . .
C5 C4 H4 119.5 . .
C3 C4 H4 119.5 . .
C4 C5 C6 119.9(11) . .
C4 C5 C8 118.5(12) . .
C6 C5 C8 121.6(12) . .
C7 C6 C5 119.7(12) . .
C7 C6 H6 120.2 . .
C5 C6 H6 120.2 . .
C2 C7 C6 121.6(11) . .
C2 C7 H7 119.2 . .
C6 C7 H7 119.2 . .
N1 C8 C5 121.6(11) . .
N1 C8 H16 119(8) . .
C5 C8 H16 119(8) . .
O3 C9 O4 119.3(8) . 7_566
O3 C9 C10 119.9(8) . .
O4 C9 C10 120.7(7) 7_566 .
O3 C9 Gd1 54.3(5) . .
O4 C9 Gd1 65.0(5) 7_566 .
C10 C9 Gd1 173.8(6) . .
C11 C10 C15 119.8(8) . .
C11 C10 C9 120.6(8) . .
C15 C10 C9 119.5(8) . .
C10 C11 C12 119.6(8) . .
C10 C11 H11 120.2 . .
C12 C11 H11 120.2 . .
C13 C12 C11 120.2(8) . .
C13 C12 N1 123.3(9) . 3_545
C11 C12 N1 116.3(8) . 3_545
C12 C13 C14 120.1(8) . .
C12 C13 H13 119.9 . .
C14 C13 H13 119.9 . .
C15 C14 C13 119.8(8) . .
C15 C14 C16 120.6(8) . 4_546
C13 C14 C16 119.6(8) . 4_546
C14 C15 C10 120.1(8) . .
C14 C15 H15 119.9 . .
C10 C15 H15 119.9 . .
O6 C16 O5 123.7(9) 7_566 .
O6 C16 C14 118.6(9) 7_566 4_556
O5 C16 C14 117.7(8) . 4_556
O7 C17 N2 131.0(18) . .
O7 C17 O7A 31.6(15) . .
N2 C17 O7A 102(2) . .
N2 C18 H18A 109.5 . .
N2 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N2 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N2 C19 H19A 109.5 . .
N2 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
N2 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
O8A C20 O8 20(4) . .
O8A C20 N3 140(5) . .
O8 C20 N3 121(2) . .
N3 C21 H21A 109.5 . .
N3 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
N3 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
N3 C22 H22A 109.5 . .
N3 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
N3 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 O5 2.348(6) .
Gd1 O4 2.367(6) .
Gd1 O8A 2.38(7) .
Gd1 O8 2.389(17) .
Gd1 O6 2.392(6) .
Gd1 O7 2.395(11) .
Gd1 O1 2.404(7) .
Gd1 O3 2.435(7) .
Gd1 O2 2.548(7) .
Gd1 O4 2.669(6) 7_566
Gd1 C1 2.838(9) .
Gd1 C9 2.945(9) .
O1 C1 1.261(14) .
O2 C1 1.263(13) .
O3 C9 1.263(10) .
O4 C9 1.277(10) 7_566
O4 Gd1 2.669(6) 7_566
O5 C16 1.290(12) .
O6 C16 1.263(11) 7_566
O7 O7A 0.78(4) .
O7 C17 1.308(19) .
O7A C17 1.49(4) .
O8 C20 1.14(3) .
O8A C20 0.92(6) .
N1 C8 1.262(15) .
N1 C12 1.415(11) 3_455
N2 C17 1.40(2) .
N2 C19 1.41(2) .
N2 C18 1.47(2) .
N3 C22 1.34(2) .
N3 C21 1.41(3) .
N3 C20 1.45(3) .
C1 C2 1.481(14) .
C2 C7 1.365(15) .
C2 C3 1.415(16) .
C3 C4 1.397(19) .
C3 H3 0.9300 .
C4 C5 1.34(2) .
C4 H4 0.9300 .
C5 C6 1.399(17) .
C5 C8 1.485(15) .
C6 C7 1.380(15) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 H16 0.95(2) .
C9 O4 1.277(10) 7_566
C9 C10 1.481(12) .
C10 C11 1.395(12) .
C10 C15 1.409(13) .
C11 C12 1.410(13) .
C11 H11 0.9300 .
C12 C13 1.387(12) .
C12 N1 1.415(11) 3_545
C13 C14 1.402(12) .
C13 H13 0.9300 .
C14 C15 1.396(13) .
C14 C16 1.472(12) 4_546
C15 H15 0.9300 .
C16 O6 1.264(11) 7_566
C16 C14 1.472(12) 4_556
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.500 -0.001 301 80 ' '
2 0.251 0.750 -0.001 192 52 ' '
3 0.500 0.001 -0.001 300 80 ' '
4 0.750 0.250 0.000 190 51 ' '
5 0.250 0.250 0.500 190 51 ' '
6 0.750 0.750 0.500 190 51 ' '
