#------------------------------------------------------------------------------
#$Date: 2020-10-06 14:19:58 +0300 (Tue, 06 Oct 2020) $
#$Revision: 258000 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/24/05/7240555.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7240555
loop_
_publ_author_name
'Zhou, Shan-He'
'Wang, Jun'
'Liu, Yi-Wei'
'Zhong, Yuyu'
'Sun, Yan-Chun'
'Xie, Bin'
'Ma, Aiqing'
'Singh, Amita'
'Muddassir, Mohd.'
'Kumar, Abhinav'
_publ_section_title
;
 Structures and photocatalytic properties of two new Zn(ii) coordination
 polymers based on semi-rigid V-shaped multicarboxylate ligands
;
_journal_issue                   32
_journal_name_full               'RSC Advances'
_journal_page_first              18721
_journal_page_last               18727
_journal_paper_doi               10.1039/D0RA02222E
_journal_volume                  10
_journal_year                    2020
_chemical_formula_moiety         'C25 H18 N2 O8 Zn'
_chemical_formula_sum            'C25 H18 N2 O8 Zn'
_chemical_formula_weight         539.80
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-02-03 deposited with the CCDC.	2020-04-30 downloaded from the CCDC.
;
_cell_angle_alpha                111.943(2)
_cell_angle_beta                 102.760(2)
_cell_angle_gamma                106.552(2)
_cell_formula_units_Z            2
_cell_length_a                   9.9215(14)
_cell_length_b                   11.0863(16)
_cell_length_c                   12.2729(17)
_cell_measurement_reflns_used    3197
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.6448
_cell_measurement_theta_min      2.3032
_cell_volume                     1116.0(3)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.941
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0157
_diffrn_reflns_av_unetI/netI     0.0338
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.941
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            6839
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.941
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.736
_diffrn_reflns_theta_min         2.439
_exptl_absorpt_coefficient_mu    1.157
_exptl_crystal_density_diffrn    1.606
_exptl_crystal_description       block
_exptl_crystal_F_000             552
_exptl_crystal_size_max          0.280
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.160
_refine_diff_density_max         0.318
_refine_diff_density_min         -0.370
_refine_diff_density_rms         0.062
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     332
_refine_ls_number_reflns         5246
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0417
_refine_ls_R_factor_gt           0.0326
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0477P)²+0.2011P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0824
_refine_ls_wR_factor_ref         0.0866
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4233
_reflns_number_total             5246
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0ra02222e2.cif
_cod_data_source_block           yyy
_cod_depositor_comments
'Adding full bibliography for 7240555--7240556.cif.'
_cod_database_code               7240555
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.738
_shelx_estimated_absorpt_t_max   0.836
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O3 O -0.17420(16) 0.07387(17) 0.21479(14) 0.0363(4) Uani 1 1 d . . . . .
C8 C -0.1444(2) 0.1476(2) 0.15834(19) 0.0309(5) Uani 1 1 d . . . . .
Zn1 Zn 0.61163(2) 0.03970(2) 0.22156(2) 0.02484(9) Uani 1 1 d . . . . .
O8 O 0.50074(17) -0.13515(17) 0.04057(14) 0.0320(3) Uani 1 1 d D . . . .
O1 O 0.47311(16) 0.13044(17) 0.17389(14) 0.0325(3) Uani 1 1 d . . . . .
O2 O 0.30513(19) -0.00573(19) 0.21648(17) 0.0450(4) Uani 1 1 d . . . . .
O7 O 0.22690(18) 0.41822(15) 0.04436(14) 0.0346(3) Uani 1 1 d . . . . .
O6 O 0.1038(3) 0.3699(2) -0.50355(18) 0.0661(6) Uani 1 1 d . . . . .
O5 O -0.0018(2) 0.14370(17) -0.54887(15) 0.0429(4) Uani 1 1 d . . . . .
H5 H -0.0356 0.1330 -0.6207 0.064 Uiso 1 1 calc R U . . .
O4 O -0.23169(18) 0.1935(2) 0.11802(19) 0.0558(5) Uani 1 1 d . . . . .
N1 N 0.68817(19) 0.17919(19) 0.41678(16) 0.0286(4) Uani 1 1 d . . . . .
N2 N 0.59284(18) -0.10095(18) 0.30045(16) 0.0275(4) Uani 1 1 d . . . . .
C1 C 0.3458(2) 0.0874(2) 0.18589(18) 0.0276(4) Uani 1 1 d . . . . .
C3 C 0.1048(2) 0.1232(2) 0.17336(17) 0.0233(4) Uani 1 1 d . . . . .
H3 H 0.0786 0.0591 0.2048 0.028 Uiso 1 1 calc R U . . .
C21 C 0.6428(2) -0.0394(2) 0.42717(19) 0.0272(4) Uani 1 1 d . . . . .
C4 C 0.0059(2) 0.1823(2) 0.14286(17) 0.0240(4) Uani 1 1 d . . . . .
C6 C 0.1827(2) 0.3137(2) 0.08203(18) 0.0270(4) Uani 1 1 d . . . . .
C20 C 0.6917(2) 0.1175(2) 0.49246(19) 0.0267(4) Uani 1 1 d . . . . .
C11 C 0.0887(2) 0.2056(2) -0.3003(2) 0.0335(5) Uani 1 1 d . . . . .
H11 H 0.0459 0.1112 -0.3626 0.040 Uiso 1 1 calc R U . . .
C9 C 0.1870(2) 0.3769(2) -0.0828(2) 0.0288(4) Uani 1 1 d . . . . .
C2 C 0.2426(2) 0.1583(2) 0.15763(18) 0.0242(4) Uani 1 1 d . . . . .
C10 C 0.1263(3) 0.2365(2) -0.1747(2) 0.0338(5) Uani 1 1 d . . . . .
H10 H 0.1109 0.1637 -0.1522 0.041 Uiso 1 1 calc R U . . .
C5 C 0.0448(2) 0.2770(2) 0.09480(19) 0.0279(4) Uani 1 1 d . . . . .
H5A H -0.0220 0.3151 0.0715 0.034 Uiso 1 1 calc R U . . .
C12 C 0.1141(2) 0.3133(2) -0.3346(2) 0.0318(5) Uani 1 1 d . . . . .
C7 C 0.2821(2) 0.2566(2) 0.11341(19) 0.0267(4) Uani 1 1 d . . . . .
H7 H 0.3754 0.2836 0.1050 0.032 Uiso 1 1 calc R U . . .
C25 C 0.5437(2) -0.2428(2) 0.2359(2) 0.0349(5) Uani 1 1 d . . . . .
H25 H 0.5087 -0.2859 0.1482 0.042 Uiso 1 1 calc R U . . .
C19 C 0.7377(2) 0.1957(2) 0.6220(2) 0.0352(5) Uani 1 1 d . . . . .
H19 H 0.7372 0.1510 0.6728 0.042 Uiso 1 1 calc R U . . .
C13 C 0.1768(3) 0.4536(2) -0.2411(2) 0.0390(5) Uani 1 1 d . . . . .
H13 H 0.1951 0.5266 -0.2632 0.047 Uiso 1 1 calc R U . . .
C16 C 0.7338(3) 0.3200(2) 0.4692(2) 0.0385(5) Uani 1 1 d . . . . .
H16 H 0.7324 0.3629 0.4170 0.046 Uiso 1 1 calc R U . . .
C18 C 0.7840(3) 0.3407(3) 0.6742(2) 0.0431(6) Uani 1 1 d . . . . .
H18 H 0.8162 0.3955 0.7612 0.052 Uiso 1 1 calc R U . . .
C22 C 0.6477(3) -0.1180(3) 0.4918(2) 0.0384(5) Uani 1 1 d . . . . .
H22 H 0.6849 -0.0732 0.5797 0.046 Uiso 1 1 calc R U . . .
C17 C 0.7828(3) 0.4047(3) 0.5976(2) 0.0449(6) Uani 1 1 d . . . . .
H17 H 0.8143 0.5029 0.6316 0.054 Uiso 1 1 calc R U . . .
C14 C 0.2123(3) 0.4857(2) -0.1159(2) 0.0371(5) Uani 1 1 d . . . . .
H14 H 0.2530 0.5800 -0.0537 0.044 Uiso 1 1 calc R U . . .
C15 C 0.0729(3) 0.2806(3) -0.4692(2) 0.0368(5) Uani 1 1 d . . . . .
C24 C 0.5432(3) -0.3269(3) 0.2947(3) 0.0426(6) Uani 1 1 d . . . . .
H24 H 0.5071 -0.4251 0.2475 0.051 Uiso 1 1 calc R U . . .
C23 C 0.5969(3) -0.2632(3) 0.4243(3) 0.0435(6) Uani 1 1 d . . . . .
H23 H 0.5989 -0.3179 0.4660 0.052 Uiso 1 1 calc R U . . .
H8A H 0.528(3) -0.130(3) -0.013(2) 0.052 Uiso 1 1 d D U . . .
H8B H 0.4112(19) -0.154(3) 0.014(2) 0.052 Uiso 1 1 d D U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C8 O3 Zn1 110.47(13) . 1_455 ?
O4 C8 O3 122.88(19) . . ?
O4 C8 C4 118.8(2) . . ?
O3 C8 C4 118.28(18) . . ?
O1 Zn1 O3 127.92(6) . 1_655 ?
O1 Zn1 O8 89.83(6) . . ?
O3 Zn1 O8 94.20(6) 1_655 . ?
O1 Zn1 N2 132.16(6) . . ?
O3 Zn1 N2 99.82(6) 1_655 . ?
O8 Zn1 N2 89.53(6) . . ?
O1 Zn1 N1 93.20(6) . . ?
O3 Zn1 N1 95.49(6) 1_655 . ?
O8 Zn1 N1 165.01(6) . . ?
N2 Zn1 N1 77.57(7) . . ?
Zn1 O8 H8A 118(2) . . ?
Zn1 O8 H8B 111.8(19) . . ?
H8A O8 H8B 104(2) . . ?
C1 O1 Zn1 114.30(13) . . ?
C9 O7 C6 118.38(16) . . ?
C15 O5 H5 109.5 . . ?
C16 N1 C20 118.60(18) . . ?
C16 N1 Zn1 125.78(15) . . ?
C20 N1 Zn1 115.61(14) . . ?
C25 N2 C21 118.50(18) . . ?
C25 N2 Zn1 125.82(15) . . ?
C21 N2 Zn1 115.57(13) . . ?
O2 C1 O1 123.96(19) . . ?
O2 C1 C2 120.22(18) . . ?
O1 C1 C2 115.81(17) . . ?
C4 C3 C2 120.86(18) . . ?
C4 C3 H3 119.6 . . ?
C2 C3 H3 119.6 . . ?
N2 C21 C22 121.7(2) . . ?
N2 C21 C20 115.69(17) . . ?
C22 C21 C20 122.61(19) . . ?
C3 C4 C5 119.49(17) . . ?
C3 C4 C8 122.81(18) . . ?
C5 C4 C8 117.70(18) . . ?
C5 C6 C7 121.43(18) . . ?
C5 C6 O7 119.16(18) . . ?
C7 C6 O7 119.28(18) . . ?
N1 C20 C19 121.8(2) . . ?
N1 C20 C21 115.38(17) . . ?
C19 C20 C21 122.85(19) . . ?
C10 C11 C12 120.9(2) . . ?
C10 C11 H11 119.6 . . ?
C12 C11 H11 119.6 . . ?
O7 C9 C10 123.47(18) . . ?
O7 C9 C14 115.98(19) . . ?
C10 C9 C14 120.5(2) . . ?
C3 C2 C7 119.06(18) . . ?
C3 C2 C1 120.00(18) . . ?
C7 C2 C1 120.93(17) . . ?
C11 C10 C9 119.16(19) . . ?
C11 C10 H10 120.4 . . ?
C9 C10 H10 120.4 . . ?
C6 C5 C4 119.35(18) . . ?
C6 C5 H5A 120.3 . . ?
C4 C5 H5A 120.3 . . ?
C11 C12 C13 119.1(2) . . ?
C11 C12 C15 121.0(2) . . ?
C13 C12 C15 119.8(2) . . ?
C6 C7 C2 119.76(18) . . ?
C6 C7 H7 120.1 . . ?
C2 C7 H7 120.1 . . ?
N2 C25 C24 122.5(2) . . ?
N2 C25 H25 118.8 . . ?
C24 C25 H25 118.8 . . ?
C18 C19 C20 118.7(2) . . ?
C18 C19 H19 120.6 . . ?
C20 C19 H19 120.6 . . ?
C14 C13 C12 120.6(2) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
N1 C16 C17 122.7(2) . . ?
N1 C16 H16 118.6 . . ?
C17 C16 H16 118.6 . . ?
C17 C18 C19 119.8(2) . . ?
C17 C18 H18 120.1 . . ?
C19 C18 H18 120.1 . . ?
C23 C22 C21 119.0(2) . . ?
C23 C22 H22 120.5 . . ?
C21 C22 H22 120.5 . . ?
C18 C17 C16 118.4(2) . . ?
C18 C17 H17 120.8 . . ?
C16 C17 H17 120.8 . . ?
C13 C14 C9 119.7(2) . . ?
C13 C14 H14 120.2 . . ?
C9 C14 H14 120.2 . . ?
O6 C15 O5 122.7(2) . . ?
O6 C15 C12 123.6(2) . . ?
O5 C15 C12 113.7(2) . . ?
C23 C24 C25 118.8(2) . . ?
C23 C24 H24 120.6 . . ?
C25 C24 H24 120.6 . . ?
C24 C23 C22 119.5(2) . . ?
C24 C23 H23 120.3 . . ?
C22 C23 H23 120.3 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O3 C8 1.270(3) . ?
O3 Zn1 2.0757(15) 1_455 ?
C8 O4 1.226(3) . ?
C8 C4 1.504(3) . ?
Zn1 O1 2.0286(14) . ?
Zn1 O3 2.0757(15) 1_655 ?
Zn1 O8 2.0951(15) . ?
Zn1 N2 2.1085(17) . ?
Zn1 N1 2.1134(17) . ?
O8 H8A 0.780(16) . ?
O8 H8B 0.810(16) . ?
O1 C1 1.279(2) . ?
O2 C1 1.221(2) . ?
O7 C9 1.376(2) . ?
O7 C6 1.396(2) . ?
O6 C15 1.202(3) . ?
O5 C15 1.319(3) . ?
O5 H5 0.8200 . ?
N1 C16 1.332(3) . ?
N1 C20 1.344(3) . ?
N2 C25 1.342(3) . ?
N2 C21 1.343(3) . ?
C1 C2 1.514(3) . ?
C3 C4 1.386(3) . ?
C3 C2 1.388(3) . ?
C3 H3 0.9300 . ?
C21 C22 1.384(3) . ?
C21 C20 1.485(3) . ?
C4 C5 1.390(3) . ?
C6 C5 1.374(3) . ?
C6 C7 1.376(3) . ?
C20 C19 1.383(3) . ?
C11 C10 1.383(3) . ?
C11 C12 1.385(3) . ?
C11 H11 0.9300 . ?
C9 C10 1.382(3) . ?
C9 C14 1.386(3) . ?
C2 C7 1.388(3) . ?
C10 H10 0.9300 . ?
C5 H5A 0.9300 . ?
C12 C13 1.386(3) . ?
C12 C15 1.483(3) . ?
C7 H7 0.9300 . ?
C25 C24 1.375(3) . ?
C25 H25 0.9300 . ?
C19 C18 1.373(3) . ?
C19 H19 0.9300 . ?
C13 C14 1.376(3) . ?
C13 H13 0.9300 . ?
C16 C17 1.377(3) . ?
C16 H16 0.9300 . ?
C18 C17 1.373(4) . ?
C18 H18 0.9300 . ?
C22 C23 1.375(3) . ?
C22 H22 0.9300 . ?
C17 H17 0.9300 . ?
C14 H14 0.9300 . ?
C24 C23 1.372(4) . ?
C24 H24 0.9300 . ?
C23 H23 0.9300 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O8 H8B O4 0.810(16) 1.93(2) 2.667(2) 151(2) 2
O8 H8A O1 0.780(16) 1.968(19) 2.719(2) 161(3) 2_655
C17 H17 O6 0.93 2.59 3.158(3) 120.2 2_665
C22 H22 O2 0.93 2.29 3.185(3) 161.4 2_656
C16 H16 O6 0.93 2.59 3.171(3) 121.4 2_665
C19 H19 O2 0.93 2.47 3.396(3) 170.9 2_656
C25 H25 O8 0.93 2.49 3.055(3) 119.0 .
O5 H5 O3 0.82 1.91 2.704(2) 161.2 1_554
O5 H5 O3 0.82 1.91 2.704(2) 161.2 1_554
C25 H25 O8 0.93 2.49 3.055(3) 119.0 .
C19 H19 O2 0.93 2.47 3.396(3) 170.9 2_656
C16 H16 O6 0.93 2.59 3.171(3) 121.4 2_665
C22 H22 O2 0.93 2.29 3.185(3) 161.4 2_656
C17 H17 O6 0.93 2.59 3.158(3) 120.2 2_665
O8 H8A O1 0.780(16) 1.968(19) 2.719(2) 161(3) 2_655
O8 H8B O4 0.810(16) 1.93(2) 2.667(2) 151(2) 2
O5 H5 O3 0.82 1.91 2.704(2) 161.2 1_554
C25 H25 O8 0.93 2.49 3.055(3) 119.0 .
C19 H19 O2 0.93 2.47 3.396(3) 170.9 2_656
C16 H16 O6 0.93 2.59 3.171(3) 121.4 2_665
C22 H22 O2 0.93 2.29 3.185(3) 161.4 2_656
C17 H17 O6 0.93 2.59 3.158(3) 120.2 2_665
O8 H8A O1 0.780(16) 1.968(19) 2.719(2) 161(3) 2_655
O8 H8B O4 0.810(16) 1.93(2) 2.667(2) 151(2) 2
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Zn1 O3 C8 O4 1.9(3) 1_455 . . . ?
Zn1 O3 C8 C4 -179.38(13) 1_455 . . . ?
Zn1 O1 C1 O2 -3.9(3) . . . . ?
Zn1 O1 C1 C2 176.97(12) . . . . ?
C25 N2 C21 C22 1.5(3) . . . . ?
Zn1 N2 C21 C22 -175.11(16) . . . . ?
C25 N2 C21 C20 -178.48(17) . . . . ?
Zn1 N2 C21 C20 4.9(2) . . . . ?
C2 C3 C4 C5 0.6(3) . . . . ?
C2 C3 C4 C8 -179.95(17) . . . . ?
O4 C8 C4 C3 -173.1(2) . . . . ?
O3 C8 C4 C3 8.1(3) . . . . ?
O4 C8 C4 C5 6.4(3) . . . . ?
O3 C8 C4 C5 -172.41(18) . . . . ?
C9 O7 C6 C5 -88.9(2) . . . . ?
C9 O7 C6 C7 95.3(2) . . . . ?
C16 N1 C20 C19 1.6(3) . . . . ?
Zn1 N1 C20 C19 -179.22(15) . . . . ?
C16 N1 C20 C21 -178.54(18) . . . . ?
Zn1 N1 C20 C21 0.6(2) . . . . ?
N2 C21 C20 N1 -3.7(3) . . . . ?
C22 C21 C20 N1 176.35(19) . . . . ?
N2 C21 C20 C19 176.13(18) . . . . ?
C22 C21 C20 C19 -3.8(3) . . . . ?
C6 O7 C9 C10 -10.4(3) . . . . ?
C6 O7 C9 C14 170.17(19) . . . . ?
C4 C3 C2 C7 1.5(3) . . . . ?
C4 C3 C2 C1 -177.21(17) . . . . ?
O2 C1 C2 C3 3.6(3) . . . . ?
O1 C1 C2 C3 -177.18(17) . . . . ?
O2 C1 C2 C7 -175.0(2) . . . . ?
O1 C1 C2 C7 4.2(3) . . . . ?
C12 C11 C10 C9 1.3(3) . . . . ?
O7 C9 C10 C11 179.55(19) . . . . ?
C14 C9 C10 C11 -1.0(3) . . . . ?
C7 C6 C5 C4 1.3(3) . . . . ?
O7 C6 C5 C4 -174.38(17) . . . . ?
C3 C4 C5 C6 -2.0(3) . . . . ?
C8 C4 C5 C6 178.52(18) . . . . ?
C10 C11 C12 C13 -0.5(3) . . . . ?
C10 C11 C12 C15 -179.5(2) . . . . ?
C5 C6 C7 C2 0.8(3) . . . . ?
O7 C6 C7 C2 176.47(17) . . . . ?
C3 C2 C7 C6 -2.2(3) . . . . ?
C1 C2 C7 C6 176.52(18) . . . . ?
C21 N2 C25 C24 -0.2(3) . . . . ?
Zn1 N2 C25 C24 175.97(17) . . . . ?
N1 C20 C19 C18 -1.5(3) . . . . ?
C21 C20 C19 C18 178.7(2) . . . . ?
C11 C12 C13 C14 -0.6(3) . . . . ?
C15 C12 C13 C14 178.4(2) . . . . ?
C20 N1 C16 C17 -0.7(3) . . . . ?
Zn1 N1 C16 C17 -179.81(18) . . . . ?
C20 C19 C18 C17 0.5(4) . . . . ?
N2 C21 C22 C23 -1.5(3) . . . . ?
C20 C21 C22 C23 178.4(2) . . . . ?
C19 C18 C17 C16 0.3(4) . . . . ?
N1 C16 C17 C18 -0.2(4) . . . . ?
C12 C13 C14 C9 0.9(4) . . . . ?
O7 C9 C14 C13 179.4(2) . . . . ?
C10 C9 C14 C13 -0.1(3) . . . . ?
C11 C12 C15 O6 -173.6(2) . . . . ?
C13 C12 C15 O6 7.4(4) . . . . ?
C11 C12 C15 O5 6.6(3) . . . . ?
C13 C12 C15 O5 -172.4(2) . . . . ?
N2 C25 C24 C23 -1.0(3) . . . . ?
C25 C24 C23 C22 0.9(4) . . . . ?
C21 C22 C23 C24 0.3(3) . . . . ?
