#------------------------------------------------------------------------------
#$Date: 2019-11-07 23:17:45 +0200 (Thu, 07 Nov 2019) $
#$Revision: 223981 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/06/7700600.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7700600
loop_
_publ_author_name
'Kandel, Ramjee'
'Schatte, Gabriele'
'Jessop, Philip G.'
_publ_section_title
;
 Rh(i) and Ru(ii) phosphaamidine and phosphaguanidine (1,3-P,N) complexes
 and their activity for CO₂ hydrogenation.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12512
_journal_page_last               12521
_journal_paper_doi               10.1039/c9dt00602h
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C51 H40 Cl2 N2 O P2 Rh2'
_chemical_formula_sum            'C51 H40 Cl2 N2 O P2 Rh2'
_chemical_formula_weight         1035.51
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'manual editing of SHELXL-2014 template'
_audit_update_record
;
2018-07-23 deposited with the CCDC.    2019-07-22 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 102.5930(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   19.2924(4)
_cell_length_b                   18.3550(4)
_cell_length_c                   16.0363(4)
_cell_measurement_reflns_used    7543
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      23.29
_cell_measurement_theta_min      2.16
_cell_volume                     5542.0(2)
_computing_cell_refinement
;Saint V8.38A and SADABS V2016/2 (Apex3 v2017.3-0; Bruker AXS).
 Ref. for SADABS: Krause, L.; Herbst-Irmer, R.; Sheldrick G.M.; 
 Stalke D., J. Appl. Cryst., 48 (2015), 3-10.
;
_computing_data_collection
'APEX2 software package v2013.3-0 (Bruker AXS)'
_computing_data_reduction
;Saint V8.38A and SADABS V2016/2 (Apex3 v2017.3-0; Bruker AXS).
 Ref. for SADABS: Krause, L.; Herbst-Irmer, R.; Sheldrick G.M.; 
 Stalke D., J. Appl. Cryst., 48 (2015), 3-10. 
;
_computing_molecular_graphics    'XP (SHELXTL-NT v6.14, Bruker AXS)'
_computing_structure_refinement
; SHELXL-2014/7 (Sheldrick, 2014).G. M. Sheldrick, Acta Cryst. 2008,
  A64, 112--122.
;
_computing_structure_solution
; SHELXT-2014 (Sheldrick, 2014). G. M. Sheldrick, Acta Cryst. 2015, A71,
  3-8.
;
_diffrn_ambient_temperature      180(2)
_diffrn_detector                 'Bruker Smart Apex2 CCD detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker Smart Apex2 CCD (Bruker AXS)'
_diffrn_measurement_method       'CCD rotation images,φ and ω scans'
_diffrn_radiation_monochromator  'horizontal mounted graphite crystal'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0556
_diffrn_reflns_av_unetI/netI     0.0408
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            35084
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.730
_diffrn_reflns_theta_min         1.549
_diffrn_source                   'Bruker AXS K780, fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.782
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6472
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2016/2 (Apex3, Bruker AXS)'
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.241
_exptl_crystal_description       needle-like
_exptl_crystal_F_000             2088
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.040
_refine_diff_density_max         1.021
_refine_diff_density_min         -1.014
_refine_diff_density_rms         0.077
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     321
_refine_ls_number_reflns         5884
_refine_ls_number_restraints     72
_refine_ls_restrained_S_all      1.054
_refine_ls_R_factor_all          0.0550
_refine_ls_R_factor_gt           0.0366
_refine_ls_shift/su_max          0.017
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0461P)²+1.8389P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0852
_refine_ls_wR_factor_ref         0.0926
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4384
_reflns_number_total             5884
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt00602h2.cif
_cod_data_source_block           pj52-sq
_cod_depositor_comments
'Adding full bibliography for 7700596--7700600.cif.'
_cod_database_code               7700600
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.828
_shelx_estimated_absorpt_t_max   0.969
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.46528(2) 0.37206(2) 0.17045(2) 0.02771(9) Uani 1 1 d . . . . .
Cl1 Cl 0.40296(5) 0.41840(6) 0.03878(6) 0.0626(3) Uani 1 1 d . . . . .
P1 P 0.37194(4) 0.39934(5) 0.22399(5) 0.02912(18) Uani 1 1 d . . . . .
O1 O 0.5000 0.2292(2) 0.2500 0.0599(10) Uani 1 2 d S T P . .
N1 N 0.55770(13) 0.35583(13) 0.12060(15) 0.0300(6) Uani 1 1 d . . . . .
C1 C 0.5484(16) 0.3354(11) 0.0344(16) 0.032(2) Uani 0.56(3) 1 d . U P A 1
C2 C 0.5342(12) 0.2623(11) 0.0148(11) 0.039(3) Uani 0.56(3) 1 d . U P A 1
H2 H 0.5288 0.2292 0.0584 0.047 Uiso 0.56(3) 1 calc R U P A 1
C3 C 0.5277(7) 0.2371(9) -0.0701(11) 0.049(3) Uani 0.56(3) 1 d . U P A 1
H3 H 0.5167 0.1878 -0.0853 0.059 Uiso 0.56(3) 1 calc R U P A 1
C4 C 0.5382(6) 0.2873(13) -0.1284(9) 0.052(3) Uani 0.56(3) 1 d . U P A 1
H4 H 0.5368 0.2710 -0.1850 0.063 Uiso 0.56(3) 1 calc R U P A 1
C5 C 0.5504(8) 0.3588(12) -0.1111(8) 0.054(3) Uani 0.56(3) 1 d . U P A 1
H5 H 0.5553 0.3912 -0.1557 0.064 Uiso 0.56(3) 1 calc R U P A 1
C6 C 0.5558(11) 0.3850(9) -0.0307(11) 0.041(3) Uani 0.56(3) 1 d . U P A 1
H6 H 0.5643 0.4353 -0.0184 0.049 Uiso 0.56(3) 1 calc R U P A 1
C1A C 0.549(2) 0.3203(15) 0.035(2) 0.032(2) Uani 0.44(3) 1 d . U P A 2
C2A C 0.5314(15) 0.2475(14) 0.0310(15) 0.039(3) Uani 0.44(3) 1 d . U P A 2
H2A H 0.5253 0.2214 0.0800 0.046 Uiso 0.44(3) 1 calc R U P A 2
C3A C 0.5234(9) 0.2146(13) -0.0468(12) 0.047(4) Uani 0.44(3) 1 d . U P A 2
H3A H 0.5136 0.1638 -0.0520 0.057 Uiso 0.44(3) 1 calc R U P A 2
C4A C 0.5297(8) 0.2559(14) -0.1213(10) 0.042(4) Uani 0.44(3) 1 d . U P A 2
H4A H 0.5233 0.2322 -0.1751 0.050 Uiso 0.44(3) 1 calc R U P A 2
C5A C 0.5450(9) 0.3294(13) -0.1151(10) 0.046(4) Uani 0.44(3) 1 d . U P A 2
H5A H 0.5486 0.3573 -0.1639 0.055 Uiso 0.44(3) 1 calc R U P A 2
C6A C 0.5550(12) 0.3612(12) -0.0335(15) 0.039(3) Uani 0.44(3) 1 d . U P A 2
H6A H 0.5662 0.4115 -0.0264 0.047 Uiso 0.44(3) 1 calc R U P A 2
C7 C 0.38009(16) 0.37398(15) 0.33794(18) 0.0301(6) Uani 1 1 d . . . . .
C8 C 0.31524(15) 0.37073(17) 0.37409(18) 0.0314(7) Uani 1 1 d . . . . .
C9 C 0.28059(17) 0.30433(19) 0.3774(2) 0.0425(8) Uani 1 1 d . . . . .
H9 H 0.2994 0.2609 0.3589 0.051 Uiso 1 1 calc R U . . .
C10 C 0.21884(19) 0.3022(2) 0.4076(2) 0.0511(9) Uani 1 1 d . . . . .
H10 H 0.1952 0.2571 0.4100 0.061 Uiso 1 1 calc R U . . .
C11 C 0.19116(18) 0.3652(2) 0.4345(2) 0.0522(10) Uani 1 1 d . . . . .
H11 H 0.1485 0.3635 0.4548 0.063 Uiso 1 1 calc R U . . .
C12 C 0.22517(18) 0.4297(2) 0.4317(2) 0.0491(9) Uani 1 1 d . . . . .
H12 H 0.2060 0.4729 0.4505 0.059 Uiso 1 1 calc R U . . .
C13 C 0.28730(17) 0.43372(18) 0.4020(2) 0.0396(8) Uani 1 1 d . . . . .
H13 H 0.3107 0.4791 0.4008 0.048 Uiso 1 1 calc R U . . .
C14 C 0.28932(16) 0.35405(18) 0.17479(19) 0.0357(7) Uani 1 1 d . . . . .
C15 C 0.29386(18) 0.28820(19) 0.1341(2) 0.0429(8) Uani 1 1 d . . . . .
H15 H 0.3392 0.2695 0.1311 0.051 Uiso 1 1 calc R U . . .
C16 C 0.2332(2) 0.2490(2) 0.0974(2) 0.0526(10) Uani 1 1 d . . . . .
H16 H 0.2368 0.2033 0.0707 0.063 Uiso 1 1 calc R U . . .
C17 C 0.1678(2) 0.2776(3) 0.1006(2) 0.0596(11) Uani 1 1 d . . . . .
H17 H 0.1259 0.2523 0.0738 0.072 Uiso 1 1 calc R U . . .
C18 C 0.16233(19) 0.3416(3) 0.1415(3) 0.0625(11) Uani 1 1 d . . . . .
H18 H 0.1167 0.3595 0.1443 0.075 Uiso 1 1 calc R U . . .
C19 C 0.22224(17) 0.3810(2) 0.1791(2) 0.0518(10) Uani 1 1 d . . . . .
H19 H 0.2179 0.4257 0.2074 0.062 Uiso 1 1 calc R U . . .
C20 C 0.35318(16) 0.49585(17) 0.22755(19) 0.0344(7) Uani 1 1 d . . . . .
C21 C 0.30634(19) 0.53042(19) 0.1600(2) 0.0445(8) Uani 1 1 d . . . . .
H21 H 0.2844 0.5034 0.1108 0.053 Uiso 1 1 calc R U . . .
C22 C 0.2923(2) 0.6037(2) 0.1653(2) 0.0540(10) Uani 1 1 d . . . . .
H22 H 0.2606 0.6270 0.1194 0.065 Uiso 1 1 calc R U . . .
C23 C 0.3237(2) 0.64365(19) 0.2364(2) 0.0495(9) Uani 1 1 d . . . . .
H23 H 0.3125 0.6938 0.2401 0.059 Uiso 1 1 calc R U . . .
C24 C 0.37105(18) 0.61101(18) 0.3018(2) 0.0424(8) Uani 1 1 d . . . . .
H24 H 0.3934 0.6388 0.3502 0.051 Uiso 1 1 calc R U . . .
C25 C 0.38664(16) 0.53703(17) 0.2975(2) 0.0365(7) Uani 1 1 d . . . . .
H25 H 0.4202 0.5148 0.3425 0.044 Uiso 1 1 calc R U . . .
C26 C 0.5000 0.2919(3) 0.2500 0.0440(12) Uani 1 2 d S T P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C26 Rh1 N1 86.80(7) . .
C26 Rh1 P1 96.22(3) . .
N1 Rh1 P1 174.86(7) . .
C26 Rh1 Cl1 152.72(11) . .
N1 Rh1 Cl1 91.12(7) . .
P1 Rh1 Cl1 88.09(3) . .
C26 Rh1 Rh1 48.44(11) . 2_655
N1 Rh1 Rh1 94.23(6) . 2_655
P1 Rh1 Rh1 84.75(2) . 2_655
Cl1 Rh1 Rh1 158.66(3) . 2_655
C20 P1 C14 107.36(15) . .
C20 P1 C7 100.87(13) . .
C14 P1 C7 100.97(14) . .
C20 P1 Rh1 114.72(10) . .
C14 P1 Rh1 116.00(11) . .
C7 P1 Rh1 115.02(10) . .
C7 N1 C1 118.9(12) 2_655 .
C7 N1 C1A 119.9(15) 2_655 .
C7 N1 Rh1 122.3(2) 2_655 .
C1 N1 Rh1 118.0(12) . .
C1A N1 Rh1 117.8(15) . .
C2 C1 N1 117.1(17) . .
C2 C1 C6 120.0(16) . .
N1 C1 C6 122.8(14) . .
C1 C2 C3 120.3(12) . .
C1 C2 H2 119.9 . .
C3 C2 H2 119.9 . .
C4 C3 C2 116.4(10) . .
C4 C3 H3 121.8 . .
C2 C3 H3 121.8 . .
C5 C4 C3 124.2(11) . .
C5 C4 H4 117.9 . .
C3 C4 H4 117.9 . .
C4 C5 C6 120.8(11) . .
C4 C5 H5 119.6 . .
C6 C5 H5 119.6 . .
C5 C6 C1 118.3(12) . .
C5 C6 H6 120.9 . .
C1 C6 H6 120.9 . .
C6A C1A C2A 124(2) . .
C6A C1A N1 119.3(19) . .
C2A C1A N1 117(2) . .
C3A C2A C1A 117.0(17) . .
C3A C2A H2A 121.5 . .
C1A C2A H2A 121.5 . .
C2A C3A C4A 120.7(13) . .
C2A C3A H3A 119.6 . .
C4A C3A H3A 119.6 . .
C5A C4A C3A 120.7(12) . .
C5A C4A H4A 119.7 . .
C3A C4A H4A 119.7 . .
C4A C5A C6A 117.2(13) . .
C4A C5A H5A 121.4 . .
C6A C5A H5A 121.4 . .
C1A C6A C5A 120.4(15) . .
C1A C6A H6A 119.8 . .
C5A C6A H6A 119.8 . .
N1 C7 C8 123.9(3) 2_655 .
N1 C7 P1 116.3(2) 2_655 .
C8 C7 P1 119.6(2) . .
C13 C8 C9 119.4(3) . .
C13 C8 C7 120.6(3) . .
C9 C8 C7 119.9(3) . .
C10 C9 C8 119.6(3) . .
C10 C9 H9 120.2 . .
C8 C9 H9 120.2 . .
C9 C10 C11 120.5(3) . .
C9 C10 H10 119.7 . .
C11 C10 H10 119.7 . .
C12 C11 C10 119.8(3) . .
C12 C11 H11 120.1 . .
C10 C11 H11 120.1 . .
C11 C12 C13 121.1(3) . .
C11 C12 H12 119.4 . .
C13 C12 H12 119.4 . .
C12 C13 C8 119.5(3) . .
C12 C13 H13 120.2 . .
C8 C13 H13 120.2 . .
C15 C14 C19 119.0(3) . .
C15 C14 P1 117.6(2) . .
C19 C14 P1 123.3(3) . .
C14 C15 C16 121.1(3) . .
C14 C15 H15 119.4 . .
C16 C15 H15 119.4 . .
C17 C16 C15 118.7(4) . .
C17 C16 H16 120.7 . .
C15 C16 H16 120.7 . .
C18 C17 C16 121.0(4) . .
C18 C17 H17 119.5 . .
C16 C17 H17 119.5 . .
C17 C18 C19 121.1(4) . .
C17 C18 H18 119.5 . .
C19 C18 H18 119.5 . .
C18 C19 C14 119.1(4) . .
C18 C19 H19 120.5 . .
C14 C19 H19 120.5 . .
C25 C20 C21 119.0(3) . .
C25 C20 P1 119.8(2) . .
C21 C20 P1 121.2(3) . .
C22 C21 C20 119.8(3) . .
C22 C21 H21 120.1 . .
C20 C21 H21 120.1 . .
C21 C22 C23 120.8(3) . .
C21 C22 H22 119.6 . .
C23 C22 H22 119.6 . .
C24 C23 C22 120.0(3) . .
C24 C23 H23 120.0 . .
C22 C23 H23 120.0 . .
C23 C24 C25 120.2(3) . .
C23 C24 H24 119.9 . .
C25 C24 H24 119.9 . .
C20 C25 C24 120.1(3) . .
C20 C25 H25 119.9 . .
C24 C25 H25 119.9 . .
O1 C26 Rh1 138.43(11) . .
O1 C26 Rh1 138.44(11) . 2_655
Rh1 C26 Rh1 83.1(2) . 2_655
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 C26 1.967(4) .
Rh1 N1 2.128(2) .
Rh1 P1 2.2147(8) .
Rh1 Cl1 2.3495(9) .
Rh1 Rh1 2.6104(4) 2_655
P1 C20 1.811(3) .
P1 C14 1.818(3) .
P1 C7 1.859(3) .
O1 C26 1.150(6) .
N1 C7 1.283(4) 2_655
N1 C1 1.41(2) .
N1 C1A 1.49(3) .
C1 C2 1.392(18) .
C1 C6 1.41(2) .
C2 C3 1.416(17) .
C2 H2 0.9500 .
C3 C4 1.358(13) .
C3 H3 0.9500 .
C4 C5 1.353(13) .
C4 H4 0.9500 .
C5 C6 1.359(15) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C1A C6A 1.36(3) .
C1A C2A 1.37(2) .
C2A C3A 1.36(2) .
C2A H2A 0.9500 .
C3A C4A 1.442(17) .
C3A H3A 0.9500 .
C4A C5A 1.380(17) .
C4A H4A 0.9500 .
C5A C6A 1.41(2) .
C5A H5A 0.9500 .
C6A H6A 0.9500 .
C7 N1 1.283(4) 2_655
C7 C8 1.490(4) .
C8 C13 1.390(4) .
C8 C9 1.397(4) .
C9 C10 1.381(4) .
C9 H9 0.9500 .
C10 C11 1.381(5) .
C10 H10 0.9500 .
C11 C12 1.359(5) .
C11 H11 0.9500 .
C12 C13 1.385(4) .
C12 H12 0.9500 .
C13 H13 0.9500 .
C14 C15 1.386(5) .
C14 C19 1.401(4) .
C15 C16 1.390(4) .
C15 H15 0.9500 .
C16 C17 1.378(5) .
C16 H16 0.9500 .
C17 C18 1.360(6) .
C17 H17 0.9500 .
C18 C19 1.386(5) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C25 1.389(4) .
C20 C21 1.402(4) .
C21 C22 1.378(5) .
C21 H21 0.9500 .
C22 C23 1.380(5) .
C22 H22 0.9500 .
C23 C24 1.369(5) .
C23 H23 0.9500 .
C24 C25 1.396(4) .
C24 H24 0.9500 .
C25 H25 0.9500 .
C26 Rh1 1.967(4) 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C7 N1 C1 C2 109.8(17) 2_655 .
Rh1 N1 C1 C2 -80.2(19) . .
C7 N1 C1 C6 -68(2) 2_655 .
Rh1 N1 C1 C6 102(2) . .
N1 C1 C2 C3 -177(2) . .
C6 C1 C2 C3 1(3) . .
C1 C2 C3 C4 2(2) . .
C2 C3 C4 C5 -3.5(18) . .
C3 C4 C5 C6 2.6(19) . .
C4 C5 C6 C1 0(2) . .
C2 C1 C6 C5 -2(3) . .
N1 C1 C6 C5 176(2) . .
C7 N1 C1A C6A -74(3) 2_655 .
Rh1 N1 C1A C6A 107(2) . .
C7 N1 C1A C2A 108(2) 2_655 .
Rh1 N1 C1A C2A -70(2) . .
C6A C1A C2A C3A 3(4) . .
N1 C1A C2A C3A -180(3) . .
C1A C2A C3A C4A -3(3) . .
C2A C3A C4A C5A 1(2) . .
C3A C4A C5A C6A 1(2) . .
C2A C1A C6A C5A -1(4) . .
N1 C1A C6A C5A -178(2) . .
C4A C5A C6A C1A -1(3) . .
C20 P1 C7 N1 -111.7(2) . 2_655
C14 P1 C7 N1 138.1(2) . 2_655
Rh1 P1 C7 N1 12.4(3) . 2_655
C20 P1 C7 C8 72.5(2) . .
C14 P1 C7 C8 -37.8(3) . .
Rh1 P1 C7 C8 -163.48(19) . .
N1 C7 C8 C13 102.1(4) 2_655 .
P1 C7 C8 C13 -82.4(3) . .
N1 C7 C8 C9 -80.2(4) 2_655 .
P1 C7 C8 C9 95.4(3) . .
C13 C8 C9 C10 0.5(5) . .
C7 C8 C9 C10 -177.3(3) . .
C8 C9 C10 C11 0.1(5) . .
C9 C10 C11 C12 -0.5(6) . .
C10 C11 C12 C13 0.3(6) . .
C11 C12 C13 C8 0.3(5) . .
C9 C8 C13 C12 -0.7(5) . .
C7 C8 C13 C12 177.1(3) . .
C20 P1 C14 C15 154.5(2) . .
C7 P1 C14 C15 -100.3(3) . .
Rh1 P1 C14 C15 24.7(3) . .
C20 P1 C14 C19 -28.1(3) . .
C7 P1 C14 C19 77.1(3) . .
Rh1 P1 C14 C19 -157.9(2) . .
C19 C14 C15 C16 0.3(5) . .
P1 C14 C15 C16 177.8(3) . .
C14 C15 C16 C17 1.4(5) . .
C15 C16 C17 C18 -2.5(6) . .
C16 C17 C18 C19 1.9(6) . .
C17 C18 C19 C14 -0.2(6) . .
C15 C14 C19 C18 -0.9(5) . .
P1 C14 C19 C18 -178.3(3) . .
C14 P1 C20 C25 142.8(2) . .
C7 P1 C20 C25 37.5(3) . .
Rh1 P1 C20 C25 -86.7(2) . .
C14 P1 C20 C21 -38.5(3) . .
C7 P1 C20 C21 -143.7(3) . .
Rh1 P1 C20 C21 92.1(3) . .
C25 C20 C21 C22 -2.3(5) . .
P1 C20 C21 C22 178.9(3) . .
C20 C21 C22 C23 -0.1(6) . .
C21 C22 C23 C24 1.9(6) . .
C22 C23 C24 C25 -1.3(5) . .
C21 C20 C25 C24 2.9(5) . .
P1 C20 C25 C24 -178.3(2) . .
C23 C24 C25 C20 -1.2(5) . .
