#------------------------------------------------------------------------------
#$Date: 2019-11-28 14:09:37 +0200 (Thu, 28 Nov 2019) $
#$Revision: 243921 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/26/7702604.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7702604
loop_
_publ_author_name
'Seisenbaeva, Gulaim A.'
'Shevelkov, Andrei V.'
'Tegenfeldt, Jörgen'
'Kloo, Lars'
'Drobot, Dmitrii V.'
'Kessler, Vadim G.'
_publ_section_title
;
 Homo- and hetero-metallic rhenium oxomethoxide complexes with a
 M4(µ-O)2(µ-OMe)4 planar core---a new family of metal
 alkoxides displaying a peculiar structural disorder. Preparation and
 X-ray single crystal study
;
_journal_issue                   19
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2762
_journal_paper_doi               10.1039/b103287a
_journal_year                    2001
_chemical_formula_sum            'C12 H36 Mo2.4 O18 Re1.6'
_chemical_formula_weight         996.57
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.41(2)
_cell_angle_beta                 92.92(2)
_cell_angle_gamma                92.71(3)
_cell_formula_units_Z            3
_cell_length_a                   7.905(2)
_cell_length_b                   15.997(4)
_cell_length_c                   17.519(6)
_cell_measurement_reflns_used    6485
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.00
_cell_measurement_theta_min      1.39
_cell_volume                     2024.9(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINTPLUS'
_computing_molecular_graphics    'Bruker SHELXTL-NT'
_computing_publication_material  'Bruker SHELXTL-NT'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.858
_diffrn_measured_fraction_theta_max 0.858
_diffrn_measurement_device_type  'Bruker SMART CCD 1K'
_diffrn_measurement_method       'SMART CCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0394
_diffrn_reflns_av_sigmaI/netI    0.1169
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            11977
_diffrn_reflns_theta_full        28.40
_diffrn_reflns_theta_max         28.40
_diffrn_reflns_theta_min         1.39
_exptl_absorpt_coefficient_mu    2.771
_exptl_absorpt_correction_T_max  0.4903
_exptl_absorpt_correction_T_min  0.3110
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Bruker SADABS'
_exptl_crystal_colour            'reddish black'
_exptl_crystal_density_diffrn    2.451
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             473
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.30
_refine_diff_density_max         2.331
_refine_diff_density_min         -2.467
_refine_diff_density_rms         0.313
_refine_ls_extinction_coef       0.00060(6)
_refine_ls_extinction_expression Fc^*^==kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.816
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     485
_refine_ls_number_reflns         8733
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.846
_refine_ls_R_factor_all          0.0745
_refine_ls_R_factor_gt           0.0534
_refine_ls_shift/su_max          0.191
_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w==1/[σ²(Fo²)+(0.0565P)²+0.0000P] where P==(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1214
_refine_ls_wR_factor_ref         0.1242
_reflns_number_gt                5036
_reflns_number_total             8733
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b103287a.txt
_cod_data_source_block           moreme11
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Empirical' was
changed to 'empirical' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        2024.9(10)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7702604
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Re1 Re -0.42000(9) 0.83909(5) 0.95060(5) 0.0351(3) Uani 0.521(4) 1 d P
Mo1 Mo -0.42000(9) 0.83909(5) 0.95060(5) 0.0351(3) Uani 0.48 1 d P
Re2 Re -0.36352(8) 1.04507(5) 1.14761(5) 0.0354(3) Uani 0.543(4) 1 d P
Mo2 Mo -0.36352(8) 1.04507(5) 1.14761(5) 0.0354(3) Uani 0.46 1 d P
Re3 Re -0.19840(8) 0.68765(4) 1.20487(5) 0.0317(3) Uani 0.494(4) 1 d P
Mo3 Mo -0.19840(8) 0.68765(4) 1.20487(5) 0.0317(3) Uani 0.51 1 d P
Re4 Re 0.00989(8) 0.53776(4) 1.26640(4) 0.0315(2) Uani 0.497(4) 1 d P
Mo4 Mo 0.00989(8) 0.53776(4) 1.26640(4) 0.0315(2) Uani 0.50 1 d P
Re5 Re -0.10130(9) 0.66924(5) 1.48279(5) 0.0326(3) Uani 0.473(4) 1 d P
Mo5 Mo -0.10130(9) 0.66924(5) 1.48279(5) 0.0326(3) Uani 0.53 1 d P
Re6 Re -0.30321(8) 0.82040(4) 1.42017(5) 0.0347(3) Uani 0.512(4) 1 d P
Mo6 Mo -0.30321(8) 0.82040(4) 1.42017(5) 0.0347(3) Uani 0.49 1 d P
O1 O -0.0796(13) 0.6015(6) 1.3689(8) 0.072(3) Uani 1 1 d .
O2 O -0.4283(13) 0.9439(9) 1.0471(8) 0.083(4) Uani 1 1 d .
O3 O -0.0639(12) 0.7912(7) 1.4712(7) 0.059(3) Uani 1 1 d .
O4 O -0.2103(13) 0.7557(7) 1.3195(8) 0.069(3) Uani 1 1 d .
O5 O -0.2131(14) 0.5634(7) 1.4870(7) 0.071(3) Uani 1 1 d .
O6 O -0.1408(14) 0.6191(8) 1.0949(8) 0.077(3) Uani 1 1 d .
O7 O -0.6644(13) 0.8733(7) 0.9161(8) 0.074(4) Uani 1 1 d .
O8 O -0.2082(15) 0.9333(8) 1.4326(8) 0.081(4) Uani 1 1 d .
O9 O -0.4614(15) 0.9938(9) 1.2158(8) 0.087(4) Uani 1 1 d .
O10 O -0.4980(14) 0.8123(8) 1.3723(9) 0.049(4) Uani 0.70 1 d P
O11 O -0.0838(15) 0.4242(8) 1.2574(7) 0.072(3) Uani 1 1 d .
O12 O 0.2082(14) 0.5468(9) 1.3113(9) 0.092(4) Uani 1 1 d .
O13 O -0.2318(13) 0.5652(7) 1.2166(7) 0.063(3) Uani 1 1 d .
O14 O -0.3512(14) 0.8797(7) 1.5326(7) 0.075(3) Uani 1 1 d .
O15 O -0.5256(15) 0.7726(8) 1.0055(8) 0.081(4) Uani 1 1 d .
O16 O -0.3890(13) 0.9142(8) 0.8799(8) 0.076(4) Uani 1 1 d .
O17 O -0.1723(16) 0.7331(8) 1.5908(8) 0.087(4) Uani 1 1 d .
O18 O -0.2095(15) 0.8311(9) 0.9618(10) 0.102(5) Uani 1 1 d .
O19 O -0.1605(14) 1.0189(8) 1.1445(10) 0.099(5) Uani 1 1 d .
O20 O -0.3472(15) 1.1536(8) 1.2417(8) 0.078(4) Uani 1 1 d .
O21 O 0.0413(12) 0.6526(7) 1.2444(7) 0.060(3) Uani 1 1 d .
O22 O -0.0878(15) 0.7901(8) 1.1959(7) 0.072(3) Uani 1 1 d .
O23 O 0.1035(14) 0.6689(9) 1.5125(9) 0.097(5) Uani 1 1 d .
O24 O -0.4562(16) 0.7319(8) 0.8538(9) 0.088(4) Uani 1 1 d .
O25 O 0.0518(15) 0.4757(7) 1.1513(7) 0.073(3) Uani 1 1 d .
O26 O -0.3397(12) 0.7021(7) 1.4366(7) 0.062(3) Uani 1 1 d .
O27 O -0.4066(14) 0.6875(9) 1.1795(9) 0.094(4) Uani 1 1 d .
C1 C -0.3884(18) 0.5380(12) 1.2427(11) 0.073(5) Uani 1 1 d .
H1A H -0.4048 0.5800 1.2984 0.109 Uiso 1 1 calc R
H1B H -0.3824 0.4777 1.2413 0.109 Uiso 1 1 calc R
H1C H -0.4818 0.5384 1.2056 0.109 Uiso 1 1 calc R
C2 C -0.518(3) 0.8956(12) 1.1900(14) 0.102(7) Uani 1 1 d .
H2A H -0.5276 0.8657 1.1303 0.153 Uiso 1 1 calc R
H2B H -0.6264 0.8908 1.2109 0.153 Uiso 1 1 calc R
H2C H -0.4364 0.8670 1.2124 0.153 Uiso 1 1 calc R
C3 C 0.0936(18) 0.8162(12) 1.4448(11) 0.069(5) Uani 1 1 d .
H3A H 0.1869 0.8113 1.4797 0.104 Uiso 1 1 calc R
H3B H 0.0933 0.8779 1.4492 0.104 Uiso 1 1 calc R
H3C H 0.1055 0.7759 1.3879 0.104 Uiso 1 1 calc R
C4 C -0.498(2) 0.6847(13) 1.4707(13) 0.084(6) Uani 1 1 d .
H4A H -0.4964 0.7250 1.5286 0.126 Uiso 1 1 calc R
H4B H -0.5071 0.6225 1.4653 0.126 Uiso 1 1 calc R
H4C H -0.5935 0.6953 1.4405 0.126 Uiso 1 1 calc R
C5 C -0.215(2) 0.5300(11) 1.0408(12) 0.088(6) Uani 1 1 d .
H5A H -0.2335 0.4939 1.0726 0.132 Uiso 1 1 calc R
H5B H -0.1401 0.5007 0.9982 0.132 Uiso 1 1 calc R
H5C H -0.3219 0.5359 1.0153 0.132 Uiso 1 1 calc R
C6 C -0.108(3) 0.8240(13) 1.6554(13) 0.096(7) Uani 1 1 d .
H6A H -0.0398 0.8157 1.6985 0.144 Uiso 1 1 calc R
H6B H -0.2019 0.8587 1.6790 0.144 Uiso 1 1 calc R
H6C H -0.0399 0.8561 1.6303 0.144 Uiso 1 1 calc R
C7 C -0.168(3) 0.3951(15) 1.3142(13) 0.110(8) Uani 1 1 d .
H7A H -0.0909 0.3655 1.3375 0.165 Uiso 1 1 calc R
H7B H -0.2639 0.3532 1.2849 0.165 Uiso 1 1 calc R
H7C H -0.2073 0.4473 1.3582 0.165 Uiso 1 1 calc R
C8 C -0.131(2) 0.9566(12) 1.3685(12) 0.087(6) Uani 1 1 d .
H8A H -0.0782 0.9047 1.3310 0.130 Uiso 1 1 calc R
H8B H -0.0471 1.0068 1.3946 0.130 Uiso 1 1 calc R
H8C H -0.2173 0.9735 1.3379 0.130 Uiso 1 1 calc R
C9 C 0.1961(19) 0.6688(12) 1.2090(11) 0.072(5) Uani 1 1 d .
H9A H 0.2924 0.6564 1.2375 0.108 Uiso 1 1 calc R
H9B H 0.2070 0.7313 1.2155 0.108 Uiso 1 1 calc R
H9C H 0.1908 0.6293 1.1508 0.108 Uiso 1 1 calc R
C10 C -0.2398(19) 0.9746(12) 0.8883(13) 0.081(6) Uani 1 1 d .
H10A H -0.2647 1.0368 0.9192 0.122 Uiso 1 1 calc R
H10B H -0.2084 0.9674 0.8339 0.122 Uiso 1 1 calc R
H10C H -0.1477 0.9596 0.9173 0.122 Uiso 1 1 calc R
C11 C -0.369(2) 0.7104(14) 0.7767(12) 0.094(7) Uani 1 1 d .
H11A H -0.3748 0.7601 0.7593 0.140 Uiso 1 1 calc R
H11B H -0.4227 0.6558 0.7337 0.140 Uiso 1 1 calc R
H11C H -0.2521 0.7013 0.7869 0.140 Uiso 1 1 calc R
C12 C -0.269(3) 0.5510(14) 1.5575(12) 0.098(7) Uani 1 1 d .
H12A H -0.1769 0.5334 1.5843 0.147 Uiso 1 1 calc R
H12B H -0.3605 0.5041 1.5401 0.147 Uiso 1 1 calc R
H12C H -0.3082 0.6071 1.5959 0.147 Uiso 1 1 calc R
C13 C -0.376(3) 0.9725(12) 1.5787(14) 0.104(8) Uani 1 1 d .
H13A H -0.3015 1.0098 1.5614 0.157 Uiso 1 1 calc R
H13B H -0.3513 0.9873 1.6370 0.157 Uiso 1 1 calc R
H13C H -0.4916 0.9836 1.5690 0.157 Uiso 1 1 calc R
C14 C -0.811(2) 0.8055(13) 0.8925(15) 0.108(8) Uani 1 1 d .
H14A H -0.9124 0.8339 0.8871 0.161 Uiso 1 1 calc R
H14B H -0.8209 0.7819 0.9347 0.161 Uiso 1 1 calc R
H14C H -0.7945 0.7564 0.8402 0.161 Uiso 1 1 calc R
C15 C -0.381(2) 1.1736(14) 1.3273(11) 0.091(6) Uani 1 1 d .
H15A H -0.5014 1.1763 1.3327 0.137 Uiso 1 1 calc R
H15B H -0.3241 1.2313 1.3630 0.137 Uiso 1 1 calc R
H15C H -0.3411 1.1265 1.3429 0.137 Uiso 1 1 calc R
C16 C 0.085(3) 0.3829(12) 1.1114(13) 0.109(8) Uani 1 1 d .
H16A H 0.2012 0.3756 1.1253 0.163 Uiso 1 1 calc R
H16B H 0.0665 0.3634 1.0521 0.163 Uiso 1 1 calc R
H16C H 0.0110 0.3465 1.1298 0.163 Uiso 1 1 calc R
C17 C -0.055(3) 0.8000(13) 1.1227(12) 0.097(7) Uani 1 1 d .
H17A H 0.0272 0.7587 1.0944 0.145 Uiso 1 1 calc R
H17B H -0.0123 0.8616 1.1357 0.145 Uiso 1 1 calc R
H17C H -0.1586 0.7865 1.0873 0.145 Uiso 1 1 calc R
C18 C -0.555(3) 0.6756(12) 0.9767(14) 0.113(9) Uani 1 1 d .
H18A H -0.4597 0.6465 0.9484 0.169 Uiso 1 1 calc R
H18B H -0.6556 0.6554 0.9390 0.169 Uiso 1 1 calc R
H18C H -0.5708 0.6597 1.0234 0.169 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O18 Re1 O2 95.7(6) . .
O18 Re1 O24 94.8(6) . .
O2 Re1 O24 169.2(5) . .
O18 Re1 O15 107.0(6) . .
O2 Re1 O15 88.2(5) . .
O24 Re1 O15 86.3(5) . .
O18 Re1 O16 92.2(6) . .
O2 Re1 O16 91.8(5) . .
O24 Re1 O16 90.4(5) . .
O15 Re1 O16 160.7(5) . .
O18 Re1 O7 162.7(6) . .
O2 Re1 O7 84.6(5) . .
O24 Re1 O7 86.1(5) . .
O15 Re1 O7 90.3(5) . .
O16 Re1 O7 70.5(4) . .
O19 Re2 O20 100.4(6) . .
O19 Re2 O9 105.4(6) . .
O20 Re2 O9 85.3(5) . .
O19 Re2 O2 92.2(6) . .
O20 Re2 O2 166.9(5) . .
O9 Re2 O2 94.9(5) . .
O19 Re2 O7 94.9(6) . 2_477
O20 Re2 O7 84.9(5) . 2_477
O9 Re2 O7 158.7(5) . 2_477
O2 Re2 O7 90.4(4) . 2_477
O19 Re2 O16 163.6(6) . 2_477
O20 Re2 O16 85.5(5) . 2_477
O9 Re2 O16 90.2(5) . 2_477
O2 Re2 O16 81.3(5) . 2_477
O7 Re2 O16 70.2(4) 2_477 2_477
O27 Re3 O4 95.4(6) . .
O27 Re3 O22 107.4(5) . .
O4 Re3 O22 89.7(5) . .
O27 Re3 O6 95.8(6) . .
O4 Re3 O6 168.8(5) . .
O22 Re3 O6 87.0(5) . .
O27 Re3 O13 92.3(5) . .
O4 Re3 O13 92.8(4) . .
O22 Re3 O13 159.8(4) . .
O6 Re3 O13 86.7(5) . .
O27 Re3 O21 162.6(5) . .
O4 Re3 O21 83.5(4) . .
O22 Re3 O21 89.9(4) . .
O6 Re3 O21 85.8(5) . .
O13 Re3 O21 70.5(4) . .
O12 Re4 O1 92.9(6) . .
O12 Re4 O11 104.5(5) . .
O1 Re4 O11 93.5(5) . .
O12 Re4 O25 100.0(6) . .
O1 Re4 O25 166.9(5) . .
O11 Re4 O25 85.5(5) . .
O12 Re4 O21 95.3(5) . .
O1 Re4 O21 92.0(4) . .
O11 Re4 O21 159.2(5) . .
O25 Re4 O21 84.5(4) . .
O12 Re4 O13 164.6(5) . .
O1 Re4 O13 82.7(4) . .
O11 Re4 O13 90.6(4) . .
O25 Re4 O13 84.3(5) . .
O21 Re4 O13 70.2(4) . .
O23 Re5 O1 95.3(6) . .
O23 Re5 O17 96.5(7) . .
O1 Re5 O17 168.0(5) . .
O23 Re5 O5 106.1(5) . .
O1 Re5 O5 88.4(5) . .
O17 Re5 O5 86.3(5) . .
O23 Re5 O3 93.0(5) . .
O1 Re5 O3 92.5(4) . .
O17 Re5 O3 89.1(5) . .
O5 Re5 O3 160.7(4) . .
O23 Re5 O26 163.7(5) . .
O1 Re5 O26 82.9(4) . .
O17 Re5 O26 86.3(5) . .
O5 Re5 O26 90.0(4) . .
O3 Re5 O26 71.0(4) . .
O10 Re6 O8 104.4(6) . .
O10 Re6 O4 92.4(6) . .
O8 Re6 O4 95.2(5) . .
O10 Re6 O14 100.2(6) . .
O8 Re6 O14 85.2(5) . .
O4 Re6 O14 166.8(5) . .
O10 Re6 O26 94.9(5) . .
O8 Re6 O26 159.9(5) . .
O4 Re6 O26 89.3(4) . .
O14 Re6 O26 86.0(5) . .
O10 Re6 O3 164.6(5) . .
O8 Re6 O3 90.4(5) . .
O4 Re6 O3 81.8(4) . .
O14 Re6 O3 85.0(5) . .
O26 Re6 O3 70.8(4) . .
Re4 O1 Re5 163.0(6) . .
Re1 O2 Re2 162.0(6) . .
C3 O3 Re5 121.2(9) . .
C3 O3 Re6 118.3(9) . .
Re5 O3 Re6 108.4(4) . .
Re6 O4 Re3 159.5(7) . .
C12 O5 Re5 128.3(12) . .
C5 O6 Re3 125.6(11) . .
C14 O7 Mo2 119.1(11) . 2_477
C14 O7 Re2 119.1(11) . 2_477
Mo2 O7 Re2 0.00(3) 2_477 2_477
C14 O7 Re1 119.8(9) . .
Mo2 O7 Re1 110.4(5) 2_477 .
Re2 O7 Re1 110.4(5) 2_477 .
C8 O8 Re6 127.0(11) . .
C2 O9 Re2 125.6(12) . .
C7 O11 Re4 132.9(12) . .
C1 O13 Re3 121.7(9) . .
C1 O13 Re4 118.6(9) . .
Re3 O13 Re4 108.2(4) . .
C13 O14 Re6 129.2(12) . .
C18 O15 Re1 127.8(12) . .
C10 O16 Re1 124.0(10) . .
C10 O16 Mo2 118.4(9) . 2_477
Re1 O16 Mo2 108.7(5) . 2_477
C10 O16 Re2 118.4(9) . 2_477
Re1 O16 Re2 108.7(5) . 2_477
Mo2 O16 Re2 0.000(15) 2_477 2_477
C6 O17 Re5 129.4(11) . .
C15 O20 Re2 131.7(11) . .
C9 O21 Re4 119.0(9) . .
C9 O21 Re3 119.8(9) . .
Re4 O21 Re3 110.7(4) . .
C17 O22 Re3 126.6(12) . .
C11 O24 Re1 126.1(11) . .
C16 O25 Re4 125.7(12) . .
C4 O26 Re6 118.9(9) . .
C4 O26 Re5 118.4(9) . .
Re6 O26 Re5 109.7(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Re1 O18 1.683(11) .
Re1 O2 1.855(15) .
Re1 O24 1.869(14) .
Re1 O15 1.888(12) .
Re1 O16 2.055(10) .
Re1 O7 2.155(10) .
Re2 O19 1.676(11) .
Re2 O20 1.853(13) .
Re2 O9 1.874(13) .
Re2 O2 1.884(14) .
Re2 O7 2.038(11) 2_477
Re2 O16 2.182(10) 2_477
Re3 O27 1.682(11) .
Re3 O4 1.876(12) .
Re3 O22 1.887(12) .
Re3 O6 1.892(12) .
Re3 O13 2.056(9) .
Re3 O21 2.159(10) .
Re4 O12 1.691(11) .
Re4 O1 1.872(13) .
Re4 O11 1.872(11) .
Re4 O25 1.915(11) .
Re4 O21 2.029(10) .
Re4 O13 2.195(10) .
Re5 O23 1.676(11) .
Re5 O1 1.877(13) .
Re5 O17 1.888(12) .
Re5 O5 1.903(11) .
Re5 O3 2.050(10) .
Re5 O26 2.181(10) .
Re6 O10 1.689(11) .
Re6 O8 1.848(11) .
Re6 O4 1.864(12) .
Re6 O14 1.884(11) .
Re6 O26 2.035(10) .
Re6 O3 2.200(10) .
O3 C3 1.443(16) .
O5 C12 1.414(18) .
O6 C5 1.437(18) .
O7 C14 1.470(17) .
O7 Mo2 2.038(11) 2_477
O7 Re2 2.038(11) 2_477
O8 C8 1.467(19) .
O9 C2 1.49(2) .
O11 C7 1.436(19) .
O13 C1 1.447(16) .
O14 C13 1.408(19) .
O15 C18 1.432(18) .
O16 C10 1.452(17) .
O16 Mo2 2.182(10) 2_477
O16 Re2 2.182(10) 2_477
O17 C6 1.49(2) .
O20 C15 1.45(2) .
O21 C9 1.457(15) .
O22 C17 1.388(18) .
O24 C11 1.471(18) .
O25 C16 1.413(19) .
O26 C4 1.474(16) .
