#------------------------------------------------------------------------------
#$Date: 2019-11-28 14:52:31 +0200 (Thu, 28 Nov 2019) $
#$Revision: 243988 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/27/7702722.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7702722
loop_
_publ_author_name
'Clarke, Matthew L.'
'Holliday, Gemma L.'
'Slawin, Alexandra M. Z.'
'Woollins, J. Derek'
_publ_section_title
;
 Highly electron rich alkyl- and dialkyl-N-pyrrolidinyl phosphines: an
 evaluation of their electronic and structural properties
;
_journal_issue                   6
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1093
_journal_paper_doi               10.1039/b108467d
_journal_year                    2002
_chemical_formula_moiety         'C25 H52 Cl N2 O P2 Rh'
_chemical_formula_sum            'C25 H52 Cl N2 O P2 Rh'
_chemical_formula_weight         596.99
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 116.033(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            12
_cell_length_a                   26.7010(8)
_cell_length_b                   15.1617(5)
_cell_length_c                   24.5230(3)
_cell_measurement_reflns_used    108
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      168
_cell_measurement_theta_min      12
_cell_volume                     8920.5(4)
_computing_cell_refinement       SMART/SAINT
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 0.9
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0610
_diffrn_reflns_av_sigmaI/netI    0.0557
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            22067
_diffrn_reflns_theta_full        23.29
_diffrn_reflns_theta_max         23.29
_diffrn_reflns_theta_min         1.64
_exptl_absorpt_coefficient_mu    0.791
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.767656
_exptl_absorpt_correction_type   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.334
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             3792
_exptl_crystal_size_max          .18
_exptl_crystal_size_mid          .1
_exptl_crystal_size_min          .04
_refine_diff_density_max         0.340
_refine_diff_density_min         -0.332
_refine_diff_density_rms         0.073
_refine_ls_extinction_coef       0.00000(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.940
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     436
_refine_ls_number_reflns         6403
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.940
_refine_ls_R_factor_all          0.0678
_refine_ls_R_factor_gt           0.0366
_refine_ls_shift/su_max          0.732
_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0454P)²+3.7903P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0752
_refine_ls_wR_factor_ref         0.0851
_reflns_number_gt                4491
_reflns_number_total             6403
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b108467d.txt
_cod_data_source_block           13
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7702722
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rh1 Rh -0.160820(14) 0.03573(2) 0.501938(14) 0.03747(12) Uani 1 1 d .
Cl1 Cl -0.08446(6) 0.12227(11) 0.50743(7) 0.0816(5) Uani 1 1 d .
P1 P -0.17568(5) -0.02638(8) 0.40734(5) 0.0377(3) Uani 1 1 d .
N1 N -0.21091(15) -0.1220(2) 0.39453(16) 0.0475(10) Uani 1 1 d .
C2 C -0.1939(2) -0.1922(3) 0.4402(2) 0.0741(16) Uani 1 1 d .
H2A H -0.1574 -0.2145 0.4477 0.089 Uiso 1 1 calc R
H2B H -0.1922 -0.1699 0.4781 0.089 Uiso 1 1 calc R
C3 C -0.2343(3) -0.2600(5) 0.4169(3) 0.137(3) Uani 1 1 d .
H3A H -0.2629 -0.2523 0.4308 0.165 Uiso 1 1 calc R
H3B H -0.2171 -0.3173 0.4301 0.165 Uiso 1 1 calc R
C4 C -0.2587(4) -0.2527(5) 0.3500(3) 0.133(3) Uani 1 1 d .
H4A H -0.2418 -0.2955 0.3338 0.159 Uiso 1 1 calc R
H4B H -0.2985 -0.2637 0.3323 0.159 Uiso 1 1 calc R
C5 C -0.2478(2) -0.1630(3) 0.3358(2) 0.0694(16) Uani 1 1 d .
H5A H -0.2823 -0.1301 0.3161 0.083 Uiso 1 1 calc R
H5B H -0.2297 -0.1644 0.3091 0.083 Uiso 1 1 calc R
C6 C -0.2235(2) 0.0509(3) 0.34623(19) 0.0495(12) Uani 1 1 d .
C7 C -0.2003(2) 0.1440(3) 0.3621(2) 0.0723(16) Uani 1 1 d .
H7A H -0.1939 0.1577 0.4029 0.108 Uiso 1 1 calc R
H7B H -0.2267 0.1851 0.3346 0.108 Uiso 1 1 calc R
H7C H -0.1659 0.1480 0.3588 0.108 Uiso 1 1 calc R
C8 C -0.2799(2) 0.0499(4) 0.3485(2) 0.0696(16) Uani 1 1 d .
H8A H -0.2960 -0.0079 0.3382 0.104 Uiso 1 1 calc R
H8B H -0.3044 0.0921 0.3201 0.104 Uiso 1 1 calc R
H8C H -0.2747 0.0649 0.3887 0.104 Uiso 1 1 calc R
C9 C -0.2328(2) 0.0305(4) 0.2809(2) 0.0768(17) Uani 1 1 d .
H9A H -0.2478 -0.0279 0.2699 0.115 Uiso 1 1 calc R
H9B H -0.1979 0.0343 0.2785 0.115 Uiso 1 1 calc R
H9C H -0.2585 0.0725 0.2535 0.115 Uiso 1 1 calc R
C10 C -0.1105(2) -0.0544(3) 0.3971(2) 0.0538(13) Uani 1 1 d .
C11 C -0.0846(2) 0.0260(4) 0.3814(3) 0.0792(18) Uani 1 1 d .
H11A H -0.0765 0.0704 0.4120 0.119 Uiso 1 1 calc R
H11B H -0.1102 0.0492 0.3428 0.119 Uiso 1 1 calc R
H11C H -0.0507 0.0088 0.3797 0.119 Uiso 1 1 calc R
C12 C -0.0688(2) -0.0919(4) 0.4582(2) 0.0763(17) Uani 1 1 d .
H12A H -0.0608 -0.0483 0.4893 0.115 Uiso 1 1 calc R
H12B H -0.0350 -0.1079 0.4559 0.115 Uiso 1 1 calc R
H12C H -0.0845 -0.1432 0.4678 0.115 Uiso 1 1 calc R
C13 C -0.1219(2) -0.1244(3) 0.3483(2) 0.0741(17) Uani 1 1 d .
H13A H -0.1381 -0.1755 0.3575 0.111 Uiso 1 1 calc R
H13B H -0.0876 -0.1406 0.3473 0.111 Uiso 1 1 calc R
H13C H -0.1473 -0.1013 0.3095 0.111 Uiso 1 1 calc R
P2 P -0.14812(4) 0.08163(7) 0.59976(5) 0.0362(3) Uani 1 1 d .
N21 N -0.20982(14) 0.0862(3) 0.60292(14) 0.0471(10) Uani 1 1 d .
C22 C -0.2232(2) 0.0689(4) 0.6539(2) 0.0707(17) Uani 1 1 d .
H22A H -0.2078 0.1145 0.6846 0.085 Uiso 1 1 calc R
H22B H -0.2086 0.0122 0.6723 0.085 Uiso 1 1 calc R
C23 C -0.2847(2) 0.0695(6) 0.6269(3) 0.114(3) Uani 1 1 d .
H23A H -0.2983 0.0103 0.6272 0.137 Uiso 1 1 calc R
H23B H -0.2971 0.1074 0.6503 0.137 Uiso 1 1 calc R
C24 C -0.3064(2) 0.1015(4) 0.5648(2) 0.0800(18) Uani 1 1 d .
H24A H -0.3330 0.1487 0.5580 0.096 Uiso 1 1 calc R
H24B H -0.3247 0.0543 0.5362 0.096 Uiso 1 1 calc R
C25 C -0.25720(19) 0.1344(4) 0.5574(2) 0.0660(15) Uani 1 1 d .
H25A H -0.2612 0.1222 0.5169 0.079 Uiso 1 1 calc R
H25B H -0.2526 0.1975 0.5646 0.079 Uiso 1 1 calc R
C26 C -0.10688(17) -0.0092(3) 0.65329(19) 0.0427(11) Uani 1 1 d .
C27 C -0.1428(2) -0.0932(3) 0.6362(2) 0.0676(15) Uani 1 1 d .
H27A H -0.1561 -0.1046 0.5936 0.101 Uiso 1 1 calc R
H27B H -0.1740 -0.0852 0.6453 0.101 Uiso 1 1 calc R
H27C H -0.1208 -0.1422 0.6590 0.101 Uiso 1 1 calc R
C28 C -0.05642(19) -0.0277(4) 0.6407(2) 0.0647(14) Uani 1 1 d .
H28A H -0.0689 -0.0395 0.5983 0.097 Uiso 1 1 calc R
H28B H -0.0365 -0.0780 0.6639 0.097 Uiso 1 1 calc R
H28C H -0.0322 0.0227 0.6521 0.097 Uiso 1 1 calc R
C29 C -0.0859(2) 0.0086(4) 0.7208(2) 0.0635(14) Uani 1 1 d .
H29A H -0.1170 0.0202 0.7296 0.095 Uiso 1 1 calc R
H29B H -0.0615 0.0589 0.7321 0.095 Uiso 1 1 calc R
H29C H -0.0659 -0.0420 0.7435 0.095 Uiso 1 1 calc R
C30 C -0.1147(2) 0.1922(3) 0.6299(2) 0.0547(13) Uani 1 1 d .
C31 C -0.0510(2) 0.1945(4) 0.6523(2) 0.0759(17) Uani 1 1 d .
H31A H -0.0338 0.1535 0.6851 0.114 Uiso 1 1 calc R
H31B H -0.0375 0.2529 0.6660 0.114 Uiso 1 1 calc R
H31C H -0.0422 0.1785 0.6196 0.114 Uiso 1 1 calc R
C32 C -0.1273(3) 0.2243(4) 0.6823(2) 0.0858(19) Uani 1 1 d .
H32A H -0.1105 0.1848 0.7161 0.129 Uiso 1 1 calc R
H32B H -0.1668 0.2256 0.6690 0.129 Uiso 1 1 calc R
H32C H -0.1123 0.2825 0.6944 0.129 Uiso 1 1 calc R
C33 C -0.1417(2) 0.2587(3) 0.5774(3) 0.0793(17) Uani 1 1 d .
H33A H -0.1814 0.2581 0.5632 0.119 Uiso 1 1 calc R
H33B H -0.1329 0.2426 0.5448 0.119 Uiso 1 1 calc R
H33C H -0.1277 0.3168 0.5915 0.119 Uiso 1 1 calc R
C34 C -0.2214(2) -0.0228(3) 0.49581(19) 0.0489(12) Uani 1 1 d .
O34 O -0.25931(14) -0.0577(2) 0.49222(14) 0.0667(10) Uani 1 1 d .
Rh2 Rh 0.0000 0.59711(3) 0.7500 0.03621(15) Uani 1 2 d S
Cl2 Cl 0.0000 0.75380(11) 0.7500 0.0703(6) Uani 1 2 d S
P3 P 0.00212(5) 0.58996(7) 0.65424(5) 0.0368(3) Uani 1 1 d .
N41 N 0.03054(15) 0.4938(2) 0.64667(15) 0.0472(10) Uani 1 1 d .
C42 C 0.0847(2) 0.4644(4) 0.6927(2) 0.0677(15) Uani 1 1 d .
H42A H 0.0870 0.4704 0.7331 0.081 Uiso 1 1 calc R
H42B H 0.1146 0.4982 0.6905 0.081 Uiso 1 1 calc R
C43 C 0.0879(3) 0.3702(4) 0.6777(2) 0.095(2) Uani 1 1 d .
H43A H 0.1263 0.3514 0.6922 0.114 Uiso 1 1 calc R
H43B H 0.0696 0.3328 0.6956 0.114 Uiso 1 1 calc R
C44 C 0.0588(3) 0.3665(4) 0.6110(3) 0.109(3) Uani 1 1 d .
H44A H 0.0393 0.3108 0.5978 0.131 Uiso 1 1 calc R
H44B H 0.0852 0.3723 0.5939 0.131 Uiso 1 1 calc R
C45 C 0.0180(2) 0.4418(3) 0.5909(2) 0.0681(16) Uani 1 1 d .
H45A H 0.0230 0.4775 0.5608 0.082 Uiso 1 1 calc R
H45B H -0.0200 0.4201 0.5735 0.082 Uiso 1 1 calc R
C46 C -0.07291(18) 0.5857(3) 0.59570(19) 0.0461(12) Uani 1 1 d .
C47 C -0.0976(2) 0.4996(3) 0.6063(2) 0.0648(15) Uani 1 1 d .
H47A H -0.0907 0.4960 0.6481 0.097 Uiso 1 1 calc R
H47B H -0.0805 0.4503 0.5965 0.097 Uiso 1 1 calc R
H47C H -0.1371 0.4986 0.5809 0.097 Uiso 1 1 calc R
C48 C -0.0835(2) 0.5917(4) 0.52923(19) 0.0669(15) Uani 1 1 d .
H48A H -0.0641 0.5448 0.5203 0.100 Uiso 1 1 calc R
H48B H -0.0703 0.6475 0.5222 0.100 Uiso 1 1 calc R
H48C H -0.1228 0.5867 0.5035 0.100 Uiso 1 1 calc R
C49 C -0.1041(2) 0.6616(4) 0.6090(2) 0.0684(15) Uani 1 1 d .
H49A H -0.0977 0.6588 0.6506 0.103 Uiso 1 1 calc R
H49B H -0.1433 0.6565 0.5831 0.103 Uiso 1 1 calc R
H49C H -0.0907 0.7170 0.6016 0.103 Uiso 1 1 calc R
C50 C 0.0416(2) 0.6786(3) 0.6341(2) 0.0594(14) Uani 1 1 d .
C51 C 0.0579(2) 0.6478(4) 0.5843(3) 0.0841(18) Uani 1 1 d .
H51A H 0.0248 0.6379 0.5473 0.126 Uiso 1 1 calc R
H51B H 0.0788 0.5940 0.5968 0.126 Uiso 1 1 calc R
H51C H 0.0802 0.6923 0.5777 0.126 Uiso 1 1 calc R
C52 C 0.0950(2) 0.6965(4) 0.6925(3) 0.091(2) Uani 1 1 d .
H52A H 0.0853 0.7168 0.7237 0.136 Uiso 1 1 calc R
H52B H 0.1168 0.7407 0.6848 0.136 Uiso 1 1 calc R
H52C H 0.1163 0.6431 0.7056 0.136 Uiso 1 1 calc R
C53 C 0.0091(2) 0.7657(3) 0.6137(3) 0.0790(17) Uani 1 1 d .
H53A H -0.0010 0.7861 0.6446 0.119 Uiso 1 1 calc R
H53B H -0.0240 0.7562 0.5767 0.119 Uiso 1 1 calc R
H53C H 0.0320 0.8092 0.6070 0.119 Uiso 1 1 calc R
C54 C 0.0000 0.4791(5) 0.7500 0.0483(17) Uani 1 2 d S
O54 O 0.0000 0.4030(3) 0.7500 0.0739(15) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C34 Rh1 P1 87.94(14) . .
C34 Rh1 P2 87.32(13) . .
P1 Rh1 P2 173.43(4) . .
C34 Rh1 Cl1 175.98(16) . .
P1 Rh1 Cl1 92.62(4) . .
P2 Rh1 Cl1 92.43(4) . .
N1 P1 C6 105.0(2) . .
N1 P1 C10 104.5(2) . .
C6 P1 C10 111.7(2) . .
N1 P1 Rh1 111.41(13) . .
C6 P1 Rh1 107.14(14) . .
C10 P1 Rh1 116.48(15) . .
C2 N1 C5 106.8(4) . .
C2 N1 P1 121.6(3) . .
C5 N1 P1 128.6(3) . .
C3 C2 N1 107.0(5) . .
C2 C3 C4 106.2(6) . .
C5 C4 C3 107.2(5) . .
C4 C5 N1 106.0(4) . .
C7 C6 C8 107.2(4) . .
C7 C6 C9 108.3(4) . .
C8 C6 C9 108.9(4) . .
C7 C6 P1 108.4(3) . .
C8 C6 P1 107.3(3) . .
C9 C6 P1 116.4(3) . .
C12 C10 C13 108.5(4) . .
C12 C10 C11 109.1(4) . .
C13 C10 C11 108.3(4) . .
C12 C10 P1 105.4(3) . .
C13 C10 P1 112.2(3) . .
C11 C10 P1 113.2(3) . .
N21 P2 C26 106.38(19) . .
N21 P2 C30 104.4(2) . .
C26 P2 C30 110.1(2) . .
N21 P2 Rh1 110.46(12) . .
C26 P2 Rh1 105.65(14) . .
C30 P2 Rh1 119.21(15) . .
C25 N21 C22 106.7(3) . .
C25 N21 P2 121.4(3) . .
C22 N21 P2 129.9(3) . .
N21 C22 C23 104.8(4) . .
C24 C23 C22 109.1(4) . .
C23 C24 C25 105.7(4) . .
N21 C25 C24 104.7(4) . .
C29 C26 C27 109.4(4) . .
C29 C26 C28 108.3(4) . .
C27 C26 C28 106.9(4) . .
C29 C26 P2 116.8(3) . .
C27 C26 P2 108.1(3) . .
C28 C26 P2 106.8(3) . .
C33 C30 C31 108.8(4) . .
C33 C30 C32 107.3(4) . .
C31 C30 C32 107.8(4) . .
C33 C30 P2 106.6(3) . .
C31 C30 P2 114.6(3) . .
C32 C30 P2 111.5(4) . .
O34 C34 Rh1 178.8(5) . .
C54 Rh2 P3 87.39(3) . 2_556
C54 Rh2 P3 87.39(3) . .
P3 Rh2 P3 174.77(6) 2_556 .
C54 Rh2 Cl2 180.000(1) . .
P3 Rh2 Cl2 92.61(3) 2_556 .
P3 Rh2 Cl2 92.61(3) . .
N41 P3 C46 105.4(2) . .
N41 P3 C50 104.7(2) . .
C46 P3 C50 110.6(2) . .
N41 P3 Rh2 110.75(13) . .
C46 P3 Rh2 106.01(14) . .
C50 P3 Rh2 118.71(16) . .
C42 N41 C45 107.2(4) . .
C42 N41 P3 121.2(3) . .
C45 N41 P3 129.0(3) . .
N41 C42 C43 104.3(4) . .
C44 C43 C42 104.6(5) . .
C43 C44 C45 106.8(5) . .
N41 C45 C44 105.3(4) . .
C48 C46 C47 109.8(4) . .
C48 C46 C49 108.5(4) . .
C47 C46 C49 106.8(4) . .
C48 C46 P3 116.6(3) . .
C47 C46 P3 107.0(3) . .
C49 C46 P3 107.9(3) . .
C53 C50 C51 108.6(4) . .
C53 C50 C52 108.2(5) . .
C51 C50 C52 108.9(4) . .
C53 C50 P3 113.1(4) . .
C51 C50 P3 111.9(4) . .
C52 C50 P3 106.0(3) . .
O54 C54 Rh2 180.000(1) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 C34 1.793(5) .
Rh1 P1 2.3702(11) .
Rh1 P2 2.3749(11) .
Rh1 Cl1 2.3782(13) .
P1 N1 1.681(4) .
P1 C6 1.889(5) .
P1 C10 1.912(5) .
N1 C2 1.465(6) .
N1 C5 1.479(5) .
C2 C3 1.417(7) .
C3 C4 1.480(9) .
C4 C5 1.464(8) .
C6 C7 1.522(6) .
C6 C8 1.533(6) .
C6 C9 1.541(6) .
C10 C12 1.532(7) .
C10 C13 1.527(6) .
C10 C11 1.531(7) .
P2 N21 1.684(3) .
P2 C26 1.887(4) .
P2 C30 1.891(5) .
N21 C25 1.463(5) .
N21 C22 1.468(5) .
C22 C23 1.475(7) .
C23 C24 1.455(7) .
C24 C25 1.488(7) .
C26 C29 1.522(6) .
C26 C27 1.538(6) .
C26 C28 1.534(6) .
C30 C33 1.542(7) .
C30 C31 1.540(7) .
C30 C32 1.543(6) .
C34 O34 1.111(5) .
Rh2 C54 1.789(7) .
Rh2 P3 2.3761(10) 2_556
Rh2 P3 2.3762(10) .
Rh2 Cl2 2.3757(18) .
P3 N41 1.691(4) .
P3 C46 1.885(4) .
P3 C50 1.903(5) .
N41 C42 1.460(6) .
N41 C45 1.485(5) .
C42 C43 1.487(7) .
C43 C44 1.471(7) .
C44 C45 1.502(7) .
C46 C48 1.530(6) .
C46 C47 1.536(6) .
C46 C49 1.537(6) .
C50 C53 1.538(7) .
C50 C51 1.538(7) .
C50 C52 1.539(7) .
C54 O54 1.154(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C34 Rh1 P1 N1 -25.5(2) .
P2 Rh1 P1 N1 18.4(4) .
Cl1 Rh1 P1 N1 158.50(15) .
C34 Rh1 P1 C6 88.8(2) .
P2 Rh1 P1 C6 132.7(4) .
Cl1 Rh1 P1 C6 -87.18(17) .
C34 Rh1 P1 C10 -145.2(2) .
P2 Rh1 P1 C10 -101.4(4) .
Cl1 Rh1 P1 C10 38.73(18) .
C6 P1 N1 C2 -165.3(4) .
C10 P1 N1 C2 76.9(4) .
Rh1 P1 N1 C2 -49.7(4) .
C6 P1 N1 C5 37.0(5) .
C10 P1 N1 C5 -80.7(5) .
Rh1 P1 N1 C5 152.7(4) .
C5 N1 C2 C3 -22.3(7) .
P1 N1 C2 C3 175.8(5) .
N1 C2 C3 C4 26.5(9) .
C2 C3 C4 C5 -20.9(10) .
C3 C4 C5 N1 7.0(9) .
C2 N1 C5 C4 8.9(7) .
P1 N1 C5 C4 169.1(5) .
N1 P1 C6 C7 168.2(3) .
C10 P1 C6 C7 -79.0(4) .
Rh1 P1 C6 C7 49.7(3) .
N1 P1 C6 C8 52.8(4) .
C10 P1 C6 C8 165.6(3) .
Rh1 P1 C6 C8 -65.7(3) .
N1 P1 C6 C9 -69.4(4) .
C10 P1 C6 C9 43.3(4) .
Rh1 P1 C6 C9 172.0(3) .
N1 P1 C10 C12 -84.0(4) .
C6 P1 C10 C12 163.0(3) .
Rh1 P1 C10 C12 39.4(4) .
N1 P1 C10 C13 33.9(4) .
C6 P1 C10 C13 -79.1(4) .
Rh1 P1 C10 C13 157.3(3) .
N1 P1 C10 C11 156.9(3) .
C6 P1 C10 C11 43.8(4) .
Rh1 P1 C10 C11 -79.7(4) .
C34 Rh1 P2 N21 -28.3(2) .
P1 Rh1 P2 N21 -72.2(4) .
Cl1 Rh1 P2 N21 147.71(16) .
C34 Rh1 P2 C26 86.4(2) .
P1 Rh1 P2 C26 42.5(4) .
Cl1 Rh1 P2 C26 -97.63(15) .
C34 Rh1 P2 C30 -149.1(2) .
P1 Rh1 P2 C30 167.0(4) .
Cl1 Rh1 P2 C30 26.85(19) .
C26 P2 N21 C25 -165.6(4) .
C30 P2 N21 C25 77.9(4) .
Rh1 P2 N21 C25 -51.4(4) .
C26 P2 N21 C22 33.0(5) .
C30 P2 N21 C22 -83.5(5) .
Rh1 P2 N21 C22 147.2(4) .
C25 N21 C22 C23 25.3(6) .
P2 N21 C22 C23 -171.2(5) .
N21 C22 C23 C24 -9.9(8) .
C22 C23 C24 C25 -8.9(8) .
C22 N21 C25 C24 -31.0(6) .
P2 N21 C25 C24 163.8(4) .
C23 C24 C25 N21 24.3(7) .
N21 P2 C26 C29 -70.6(4) .
C30 P2 C26 C29 42.0(4) .
Rh1 P2 C26 C29 171.9(3) .
N21 P2 C26 C27 53.2(4) .
C30 P2 C26 C27 165.7(3) .
Rh1 P2 C26 C27 -64.3(3) .
N21 P2 C26 C28 167.9(3) .
C30 P2 C26 C28 -79.5(3) .
Rh1 P2 C26 C28 50.5(3) .
N21 P2 C30 C33 -79.5(4) .
C26 P2 C30 C33 166.6(3) .
Rh1 P2 C30 C33 44.3(4) .
N21 P2 C30 C31 160.1(3) .
C26 P2 C30 C31 46.2(4) .
Rh1 P2 C30 C31 -76.1(4) .
N21 P2 C30 C32 37.2(4) .
C26 P2 C30 C32 -76.6(4) .
Rh1 P2 C30 C32 161.1(3) .
P1 Rh1 C34 O34 -129(21) .
P2 Rh1 C34 O34 55(21) .
Cl1 Rh1 C34 O34 -31(23) .
C54 Rh2 P3 N41 -25.09(15) .
P3 Rh2 P3 N41 -25.10(15) 2_556
Cl2 Rh2 P3 N41 154.91(15) .
C54 Rh2 P3 C46 88.72(15) .
P3 Rh2 P3 C46 88.72(16) 2_556
Cl2 Rh2 P3 C46 -91.28(15) .
C54 Rh2 P3 C50 -146.27(19) .
P3 Rh2 P3 C50 -146.28(19) 2_556
Cl2 Rh2 P3 C50 33.73(19) .
C46 P3 N41 C42 -166.6(4) .
C50 P3 N41 C42 76.7(4) .
Rh2 P3 N41 C42 -52.4(4) .
C46 P3 N41 C45 34.1(5) .
C50 P3 N41 C45 -82.6(4) .
Rh2 P3 N41 C45 148.3(4) .
C45 N41 C42 C43 -30.6(5) .
P3 N41 C42 C43 166.1(4) .
N41 C42 C43 C44 34.8(6) .
C42 C43 C44 C45 -26.0(8) .
C42 N41 C45 C44 14.5(6) .
P3 N41 C45 C44 176.0(4) .
C43 C44 C45 N41 7.4(7) .
N41 P3 C46 C48 -69.5(4) .
C50 P3 C46 C48 43.2(4) .
Rh2 P3 C46 C48 173.1(3) .
N41 P3 C46 C47 53.7(3) .
C50 P3 C46 C47 166.4(3) .
Rh2 P3 C46 C47 -63.7(3) .
N41 P3 C46 C49 168.3(3) .
C50 P3 C46 C49 -79.1(4) .
Rh2 P3 C46 C49 50.8(3) .
N41 P3 C50 C53 157.3(4) .
C46 P3 C50 C53 44.3(4) .
Rh2 P3 C50 C53 -78.5(4) .
N41 P3 C50 C51 34.3(4) .
C46 P3 C50 C51 -78.7(4) .
Rh2 P3 C50 C51 158.5(3) .
N41 P3 C50 C52 -84.2(4) .
C46 P3 C50 C52 162.7(4) .
Rh2 P3 C50 C52 39.9(4) .
P3 Rh2 C54 O54 -117(100) 2_556
P3 Rh2 C54 O54 63(100) .
Cl2 Rh2 C54 O54 0(100) .
