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#$Date: 2020-05-05 16:25:52 +0300 (Tue, 05 May 2020) $
#$Revision: 251647 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/34/7703426.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7703426
loop_
_publ_author_name
'Smith Pellizzeri, Tiffany M.'
'Sanjeewa, Liurukara D.'
'Pellizzeri, Steven'
'McMillen, Colin D.'
'Garlea, V. Ovidiu'
'Ye, Feng'
'Sefat, Athena S.'
'Kolis, Joseph W.'
_publ_section_title
;
 Single crystal neutron and magnetic measurements of
 Rb₂Mn₃(VO₄)₂CO₃
 and K₂Co₃(VO₄)₂CO₃
 with mixed honeycomb and triangular magnetic lattices.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4323
_journal_page_last               4335
_journal_paper_doi               10.1039/c9dt03389k
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C Mn3 O11 V2, 2 (Rb)'
_chemical_formula_sum            'C Mn3 O11 Rb2 V2'
_chemical_formula_weight         625.65
_space_group_crystal_system      trigonal
_space_group_IT_number           163
_space_group_name_Hall           '-P 3 2c'
_space_group_name_H-M_alt        'P -3 1 c'
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-07-25 deposited with the CCDC.	2019-12-06 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            2
_cell_length_a                   5.2488(3)
_cell_length_b                   5.2488(3)
_cell_length_c                   22.7020(14)
_cell_measurement_reflns_used    2443
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      28.26
_cell_measurement_theta_min      3.59
_cell_volume                     541.65(6)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0652
_diffrn_reflns_av_unetI/netI     0.0375
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            3863
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.260
_diffrn_reflns_theta_min         3.590
_diffrn_source                   'Incoatec I\mS'
_exptl_absorpt_coefficient_mu    14.042
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.298
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    3.836
_exptl_crystal_description       'hexagonal block'
_exptl_crystal_F_000             578
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.686
_refine_diff_density_min         -0.752
_refine_diff_density_rms         0.152
_refine_ls_extinction_coef       0.040(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.180
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     36
_refine_ls_number_reflns         453
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.180
_refine_ls_R_factor_all          0.0400
_refine_ls_R_factor_gt           0.0299
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0089P)²+3.8547P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0667
_refine_ls_wR_factor_ref         0.0701
_reflns_Friedel_coverage         0.000
_reflns_number_gt                383
_reflns_number_total             453
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt03389k2.cif
_cod_data_source_block           I
_cod_depositor_comments
'Adding full bibliography for 7703426--7703427.cif.'
_cod_original_cell_volume        541.64(7)
_cod_database_code               7703426
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-y, -x, -z+1/2'
'-x+y, y, -z+1/2'
'x, x-y, -z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'y, x, z-1/2'
'x-y, -y, z-1/2'
'-x, -x+y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Rb1 Rb 0.6667 0.3333 0.15685(3) 0.0092(3) Uani 1 3 d S T P
Mn1 Mn 0.6667 0.3333 -0.00442(5) 0.0046(3) Uani 1 3 d S T P
Mn2 Mn 0.0000 0.0000 0.2500 0.0056(4) Uani 1 6 d S T P
V1 V 0.0000 0.0000 0.07840(5) 0.0025(3) Uani 1 3 d S T P
C1 C 0.3333 -0.3333 0.2500 0.006(2) Uani 1 6 d S T P
O1 O 0.3170(7) 0.3077(7) 0.05374(12) 0.0058(6) Uani 1 1 d . . .
O2 O 0.0000 0.0000 0.1534(2) 0.0078(12) Uani 1 3 d S T P
O3 O 0.0810(15) -0.3526(17) 0.2501(3) 0.0108(13) Uani 0.5 1 d . . P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Rb1 O3 72.3(2) 4 6_655
O3 Rb1 O3 72.3(2) 4 5_665
O3 Rb1 O3 72.3(2) 6_655 5_665
O3 Rb1 O3 82.9(2) 4 1_665
O3 Rb1 O3 22.4(3) 6_655 1_665
O3 Rb1 O3 55.8(2) 5_665 1_665
O3 Rb1 O3 22.4(3) 4 3_655
O3 Rb1 O3 55.8(2) 6_655 3_655
O3 Rb1 O3 82.9(2) 5_665 3_655
O3 Rb1 O3 72.2(2) 1_665 3_655
O3 Rb1 O3 55.8(2) 4 2
O3 Rb1 O3 82.9(2) 6_655 2
O3 Rb1 O3 22.4(3) 5_665 2
O3 Rb1 O3 72.2(2) 1_665 2
O3 Rb1 O3 72.2(2) 3_655 2
O3 Rb1 O1 116.14(16) 4 .
O3 Rb1 O1 171.51(14) 6_655 .
O3 Rb1 O1 108.75(14) 5_665 .
O3 Rb1 O1 152.33(16) 1_665 .
O3 Rb1 O1 132.50(15) 3_655 .
O3 Rb1 O1 101.09(15) 2 .
O3 Rb1 O1 108.75(14) 4 2_655
O3 Rb1 O1 116.14(16) 6_655 2_655
O3 Rb1 O1 171.51(14) 5_665 2_655
O3 Rb1 O1 132.50(15) 1_665 2_655
O3 Rb1 O1 101.09(15) 3_655 2_655
O3 Rb1 O1 152.33(16) 2 2_655
O1 Rb1 O1 63.02(9) . 2_655
O3 Rb1 O1 171.51(14) 4 3_665
O3 Rb1 O1 108.75(14) 6_655 3_665
O3 Rb1 O1 116.14(16) 5_665 3_665
O3 Rb1 O1 101.09(15) 1_665 3_665
O3 Rb1 O1 152.33(16) 3_655 3_665
O3 Rb1 O1 132.50(14) 2 3_665
O1 Rb1 O1 63.02(9) . 3_665
O1 Rb1 O1 63.02(9) 2_655 3_665
O3 Rb1 O2 81.99(15) 4 1_655
O3 Rb1 O2 61.57(16) 6_655 1_655
O3 Rb1 O2 132.17(16) 5_665 1_655
O3 Rb1 O2 82.01(15) 1_665 1_655
O3 Rb1 O2 61.62(16) 3_655 1_655
O3 Rb1 O2 132.09(16) 2 1_655
O1 Rb1 O2 118.76(11) . 1_655
O1 Rb1 O2 55.84(11) 2_655 1_655
O1 Rb1 O2 91.11(10) 3_665 1_655
O3 Rb1 O2 61.57(16) 4 .
O3 Rb1 O2 132.17(16) 6_655 .
O3 Rb1 O2 82.00(16) 5_665 .
O3 Rb1 O2 132.09(16) 1_665 .
O3 Rb1 O2 82.01(16) 3_655 .
O3 Rb1 O2 61.62(16) 2 .
O1 Rb1 O2 55.84(11) . .
O1 Rb1 O2 91.11(10) 2_655 .
O1 Rb1 O2 118.76(11) 3_665 .
O2 Rb1 O2 119.936(9) 1_655 .
O3 Rb1 O2 132.17(16) 4 1_665
O3 Rb1 O2 82.00(15) 6_655 1_665
O3 Rb1 O2 61.57(16) 5_665 1_665
O3 Rb1 O2 61.62(16) 1_665 1_665
O3 Rb1 O2 132.09(16) 3_655 1_665
O3 Rb1 O2 82.01(16) 2 1_665
O1 Rb1 O2 91.11(10) . 1_665
O1 Rb1 O2 118.76(11) 2_655 1_665
O1 Rb1 O2 55.84(11) 3_665 1_665
O2 Rb1 O2 119.936(9) 1_655 1_665
O2 Rb1 O2 119.936(9) . 1_665
O1 Mn1 O1 95.49(10) 8 9_655
O1 Mn1 O1 95.49(10) 8 7_665
O1 Mn1 O1 95.49(10) 9_655 7_665
O1 Mn1 O1 172.60(11) 8 3_665
O1 Mn1 O1 91.86(10) 9_655 3_665
O1 Mn1 O1 84.64(16) 7_665 3_665
O1 Mn1 O1 91.86(10) 8 2_655
O1 Mn1 O1 84.64(16) 9_655 2_655
O1 Mn1 O1 172.60(11) 7_665 2_655
O1 Mn1 O1 87.97(11) 3_665 2_655
O1 Mn1 O1 84.64(16) 8 .
O1 Mn1 O1 172.60(11) 9_655 .
O1 Mn1 O1 91.86(10) 7_665 .
O1 Mn1 O1 87.97(11) 3_665 .
O1 Mn1 O1 87.97(11) 2_655 .
O1 Mn1 Mn1 90.00(8) 8 7_665
O1 Mn1 Mn1 142.13(9) 9_655 7_665
O1 Mn1 Mn1 46.65(8) 7_665 7_665
O1 Mn1 Mn1 84.71(8) 3_665 7_665
O1 Mn1 Mn1 132.71(9) 2_655 7_665
O1 Mn1 Mn1 45.21(8) . 7_665
O1 Mn1 Mn1 142.13(9) 8 7_765
O1 Mn1 Mn1 46.65(8) 9_655 7_765
O1 Mn1 Mn1 90.00(8) 7_665 7_765
O1 Mn1 Mn1 45.21(8) 3_665 7_765
O1 Mn1 Mn1 84.71(9) 2_655 7_765
O1 Mn1 Mn1 132.71(9) . 7_765
Mn1 Mn1 Mn1 119.568(9) 7_665 7_765
O1 Mn1 Mn1 46.65(8) 8 7_655
O1 Mn1 Mn1 90.00(8) 9_655 7_655
O1 Mn1 Mn1 142.13(9) 7_665 7_655
O1 Mn1 Mn1 132.71(9) 3_665 7_655
O1 Mn1 Mn1 45.21(8) 2_655 7_655
O1 Mn1 Mn1 84.71(8) . 7_655
Mn1 Mn1 Mn1 119.568(9) 7_665 7_655
Mn1 Mn1 Mn1 119.567(9) 7_765 7_655
O1 Mn1 Rb1 121.28(8) 8 .
O1 Mn1 Rb1 121.28(8) 9_655 .
O1 Mn1 Rb1 121.28(8) 7_665 .
O1 Mn1 Rb1 53.31(8) 3_665 .
O1 Mn1 Rb1 53.31(8) 2_655 .
O1 Mn1 Rb1 53.31(8) . .
Mn1 Mn1 Rb1 86.21(4) 7_665 .
Mn1 Mn1 Rb1 86.21(4) 7_765 .
Mn1 Mn1 Rb1 86.21(4) 7_655 .
O3 Mn2 O3 120.000(1) 2 3
O3 Mn2 O3 120.000(4) 2 .
O3 Mn2 O3 120.000(4) 3 .
O3 Mn2 O2 89.91(17) 2 4
O3 Mn2 O2 89.91(17) 3 4
O3 Mn2 O2 89.91(17) . 4
O3 Mn2 O2 90.09(17) 2 .
O3 Mn2 O2 90.09(17) 3 .
O3 Mn2 O2 90.09(17) . .
O2 Mn2 O2 180.0 4 .
O3 Mn2 Rb1 51.10(18) 2 4_665
O3 Mn2 Rb1 140.38(18) 3 4_665
O3 Mn2 Rb1 81.67(19) . 4_665
O2 Mn2 Rb1 55.093(9) 4 4_665
O2 Mn2 Rb1 124.907(9) . 4_665
O3 Mn2 Rb1 140.54(18) 2 1_445
O3 Mn2 Rb1 81.77(18) 3 1_445
O3 Mn2 Rb1 51.22(18) . 1_445
O2 Mn2 Rb1 124.907(9) 4 1_445
O2 Mn2 Rb1 55.093(9) . 1_445
Rb1 Mn2 Rb1 131.586(6) 4_665 1_445
O3 Mn2 Rb1 140.38(18) 2 4
O3 Mn2 Rb1 81.67(18) 3 4
O3 Mn2 Rb1 51.10(18) . 4
O2 Mn2 Rb1 55.093(9) 4 4
O2 Mn2 Rb1 124.907(9) . 4
Rb1 Mn2 Rb1 90.504(13) 4_665 4
Rb1 Mn2 Rb1 69.815(18) 1_445 4
O3 Mn2 Rb1 51.22(18) 2 .
O3 Mn2 Rb1 140.54(18) 3 .
O3 Mn2 Rb1 81.77(18) . .
O2 Mn2 Rb1 124.908(9) 4 .
O2 Mn2 Rb1 55.092(9) . .
Rb1 Mn2 Rb1 69.815(18) 4_665 .
Rb1 Mn2 Rb1 90.504(13) 1_445 .
Rb1 Mn2 Rb1 131.586(6) 4 .
O3 Mn2 Rb1 81.77(18) 2 1_455
O3 Mn2 Rb1 51.22(18) 3 1_455
O3 Mn2 Rb1 140.54(18) . 1_455
O2 Mn2 Rb1 124.907(9) 4 1_455
O2 Mn2 Rb1 55.093(9) . 1_455
Rb1 Mn2 Rb1 131.585(6) 4_665 1_455
Rb1 Mn2 Rb1 90.504(13) 1_445 1_455
Rb1 Mn2 Rb1 131.585(6) 4 1_455
Rb1 Mn2 Rb1 90.504(13) . 1_455
O3 Mn2 Rb1 81.67(18) 2 4_565
O3 Mn2 Rb1 51.10(18) 3 4_565
O3 Mn2 Rb1 140.38(18) . 4_565
O2 Mn2 Rb1 55.093(9) 4 4_565
O2 Mn2 Rb1 124.907(9) . 4_565
Rb1 Mn2 Rb1 90.504(13) 4_665 4_565
Rb1 Mn2 Rb1 131.585(6) 1_445 4_565
Rb1 Mn2 Rb1 90.504(13) 4 4_565
Rb1 Mn2 Rb1 131.585(6) . 4_565
Rb1 Mn2 Rb1 69.814(18) 1_455 4_565
O2 V1 O1 108.85(10) . .
O2 V1 O1 108.85(10) . 3
O1 V1 O1 110.08(9) . 3
O2 V1 O1 108.85(10) . 2
O1 V1 O1 110.08(9) . 2
O1 V1 O1 110.08(9) 3 2
O2 V1 Rb1 59.557(18) . .
O1 V1 Rb1 56.42(9) . .
O1 V1 Rb1 100.65(10) 3 .
O1 V1 Rb1 149.26(10) 2 .
O2 V1 Rb1 59.557(18) . 1_445
O1 V1 Rb1 149.26(10) . 1_445
O1 V1 Rb1 56.42(9) 3 1_445
O1 V1 Rb1 100.65(10) 2 1_445
Rb1 V1 Rb1 96.60(2) . 1_445
O2 V1 Rb1 59.557(18) . 1_455
O1 V1 Rb1 100.65(10) . 1_455
O1 V1 Rb1 149.26(10) 3 1_455
O1 V1 Rb1 56.42(9) 2 1_455
Rb1 V1 Rb1 96.60(2) . 1_455
Rb1 V1 Rb1 96.60(2) 1_445 1_455
O3 C1 O3 120.000(5) . 3_655
O3 C1 O3 119.999(6) . 2_545
O3 C1 O3 119.999(5) 3_655 2_545
O3 C1 Rb1 132.8(3) . 4_655
O3 C1 Rb1 93.1(3) 3_655 4_655
O3 C1 Rb1 42.4(3) 2_545 4_655
O3 C1 Rb1 133.0(3) . 1_545
O3 C1 Rb1 93.3(3) 3_655 1_545
O3 C1 Rb1 42.7(3) 2_545 1_545
Rb1 C1 Rb1 69.815(18) 4_655 1_545
O3 C1 Rb1 42.7(3) . 1_445
O3 C1 Rb1 133.0(3) 3_655 1_445
O3 C1 Rb1 93.3(3) 2_545 1_445
Rb1 C1 Rb1 131.586(6) 4_655 1_445
Rb1 C1 Rb1 90.504(13) 1_545 1_445
O3 C1 Rb1 93.1(3) . 4_665
O3 C1 Rb1 42.4(3) 3_655 4_665
O3 C1 Rb1 132.8(3) 2_545 4_665
Rb1 C1 Rb1 90.504(13) 4_655 4_665
Rb1 C1 Rb1 131.586(6) 1_545 4_665
Rb1 C1 Rb1 131.585(6) 1_445 4_665
O3 C1 Rb1 42.4(3) . 4
O3 C1 Rb1 132.8(3) 3_655 4
O3 C1 Rb1 93.1(3) 2_545 4
Rb1 C1 Rb1 90.504(13) 4_655 4
Rb1 C1 Rb1 131.586(6) 1_545 4
Rb1 C1 Rb1 69.815(18) 1_445 4
Rb1 C1 Rb1 90.503(13) 4_665 4
O3 C1 Rb1 93.3(3) . .
O3 C1 Rb1 42.7(3) 3_655 .
O3 C1 Rb1 133.0(3) 2_545 .
Rb1 C1 Rb1 131.586(6) 4_655 .
Rb1 C1 Rb1 90.503(13) 1_545 .
Rb1 C1 Rb1 90.503(13) 1_445 .
Rb1 C1 Rb1 69.815(18) 4_665 .
Rb1 C1 Rb1 131.585(6) 4 .
V1 O1 Mn1 125.61(16) . 7_665
V1 O1 Mn1 129.14(16) . .
Mn1 O1 Mn1 88.14(10) 7_665 .
V1 O1 Rb1 94.13(11) . .
Mn1 O1 Rb1 128.54(13) 7_665 .
Mn1 O1 Rb1 89.57(10) . .
V1 O2 Mn2 180.0 . .
V1 O2 Rb1 91.46(10) . 1_445
Mn2 O2 Rb1 88.54(10) . 1_445
V1 O2 Rb1 91.46(10) . .
Mn2 O2 Rb1 88.54(10) . .
Rb1 O2 Rb1 119.936(9) 1_445 .
V1 O2 Rb1 91.46(10) . 1_455
Mn2 O2 Rb1 88.54(10) . 1_455
Rb1 O2 Rb1 119.935(9) 1_445 1_455
Rb1 O2 Rb1 119.936(9) . 1_455
C1 O3 Mn2 126.2(5) . .
C1 O3 Rb1 120.2(4) . 4
Mn2 O3 Rb1 94.5(2) . 4
C1 O3 Rb1 119.9(4) . 1_445
Mn2 O3 Rb1 94.3(2) . 1_445
Rb1 O3 Rb1 94.2(2) 4 1_445
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rb1 O3 2.884(7) 4
Rb1 O3 2.884(7) 6_655
Rb1 O3 2.884(7) 5_665
Rb1 O3 2.889(7) 1_665
Rb1 O3 2.889(7) 3_655
Rb1 O3 2.889(7) 2
Rb1 O1 2.936(3) .
Rb1 O1 2.936(3) 2_655
Rb1 O1 2.936(3) 3_665
Rb1 O2 3.0314(2) 1_655
Rb1 O2 3.0314(2) .
Rb1 O2 3.0314(2) 1_665
Mn1 O1 2.156(3) 8
Mn1 O1 2.156(3) 9_655
Mn1 O1 2.156(3) 7_665
Mn1 O1 2.210(3) 3_665
Mn1 O1 2.210(3) 2_655
Mn1 O1 2.210(3) .
Mn1 Mn1 3.0370(2) 7_665
Mn1 Mn1 3.0370(2) 7_765
Mn1 Mn1 3.0370(2) 7_655
Mn2 O3 2.096(7) 2
Mn2 O3 2.096(7) 3
Mn2 O3 2.096(7) .
Mn2 O2 2.192(5) 4
Mn2 O2 2.192(5) .
Mn2 Rb1 3.6952(4) 4_665
Mn2 Rb1 3.6952(4) 1_445
Mn2 Rb1 3.6952(4) 4
Mn2 Rb1 3.6953(4) 1_455
Mn2 Rb1 3.6953(4) 4_565
V1 O2 1.704(5) .
V1 O1 1.733(3) .
V1 O1 1.733(3) 3
V1 O1 1.733(3) 2
V1 Rb1 3.5150(7) 1_445
V1 Rb1 3.5150(7) 1_455
C1 O3 1.277(6) .
C1 O3 1.277(7) 3_655
C1 O3 1.277(6) 2_545
C1 Rb1 3.6952(4) 4_655
C1 Rb1 3.6952(4) 1_545
C1 Rb1 3.6953(4) 1_445
C1 Rb1 3.6953(4) 4_665
C1 Rb1 3.6953(4) 4
O1 Mn1 2.156(3) 7_665
O2 Rb1 3.0314(2) 1_445
O2 Rb1 3.0314(2) 1_455
O3 Rb1 2.884(7) 4
O3 Rb1 2.889(7) 1_445
