#------------------------------------------------------------------------------
#$Date: 2020-08-06 16:54:10 +0300 (Thu, 06 Aug 2020) $
#$Revision: 254958 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/46/7704673.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7704673
loop_
_publ_author_name
'Yu, Wei-Bin'
'Qiu, Feng-Yi'
'Sun, Po'
'Shi, Hua-Tian'
'Xin, Zhi-Feng'
_publ_section_title
;
 A new supramolecular catalytic system: the self-assembly of Rh8 cage host
 anthracene molecules for [4 + 4] cycloaddition induced by UV irradiation.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9688
_journal_page_last               9693
_journal_paper_doi               10.1039/d0dt01978j
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C188 H183 F24 N8 O40 Rh8 S8'
_chemical_formula_sum            'C188 H183 F24 N8 O40 Rh8 S8'
_chemical_formula_weight         4730.17
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2019-12-31 deposited with the CCDC.	2020-06-12 downloaded from the CCDC.
;
_cell_angle_alpha                103.235(3)
_cell_angle_beta                 91.953(3)
_cell_angle_gamma                109.093(3)
_cell_formula_units_Z            2
_cell_length_a                   16.3634(13)
_cell_length_b                   22.2895(17)
_cell_length_c                   38.292(3)
_cell_measurement_reflns_used    9127
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      57.38
_cell_measurement_theta_min      3.44
_cell_volume                     12757.0(18)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34138
_diffrn_reflns_av_R_equivalents  0.0606
_diffrn_reflns_av_unetI/netI     0.0628
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.976
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_limit_l_min       -47
_diffrn_reflns_number            158306
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.976
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         57.798
_diffrn_reflns_theta_min         2.835
_exptl_absorpt_coefficient_mu    3.591
_exptl_absorpt_correction_T_max  0.519
_exptl_absorpt_correction_T_min  0.267
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.231
_exptl_crystal_description       block
_exptl_crystal_F_000             4782
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.210
_exptl_crystal_size_min          0.210
_refine_diff_density_max         2.490
_refine_diff_density_min         -1.332
_refine_diff_density_rms         0.115
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     2524
_refine_ls_number_reflns         52335
_refine_ls_number_restraints     6191
_refine_ls_restrained_S_all      1.096
_refine_ls_R_factor_all          0.0805
_refine_ls_R_factor_gt           0.0732
_refine_ls_shift/su_max          0.087
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1278P)²+16.1106P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2176
_refine_ls_wR_factor_ref         0.2261
_reflns_Friedel_coverage         0.000
_reflns_number_gt                43967
_reflns_number_total             52335
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt01978j2.cif
_cod_data_source_block           cage1
_cod_depositor_comments          'Adding full bibliography for 7704673.cif.'
_cod_original_cell_volume        12757.0(17)
_cod_database_code               7704673
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.267
_shelx_estimated_absorpt_t_max   0.519
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.43014(2) 0.59840(2) 0.46078(2) 0.04714(9) Uani 1 1 d . U . . .
Rh2 Rh 0.72359(3) 0.77807(2) 0.54807(2) 0.06208(12) Uani 1 1 d . U . . .
Rh3 Rh 0.22858(3) 1.26940(2) 0.84160(2) 0.05110(10) Uani 1 1 d . U . . .
Rh4 Rh -0.07736(3) 1.11085(2) 0.75299(2) 0.05364(10) Uani 1 1 d . U . . .
Rh5 Rh 0.04916(3) 0.88281(2) 1.03364(2) 0.05308(10) Uani 1 1 d . U . . .
Rh6 Rh -0.25421(3) 0.73062(2) 0.94193(2) 0.05559(10) Uani 1 1 d . U . . .
Rh7 Rh 0.63512(2) 0.40196(2) 0.75018(2) 0.05187(10) Uani 1 1 d . U . . .
Rh8 Rh 0.32052(2) 0.23982(2) 0.66847(2) 0.04698(9) Uani 1 1 d . U . . .
S1S S 0.26081(11) 0.41325(7) 0.57041(4) 0.0684(3) Uani 1 1 d . U . . .
S2S S 0.83630(11) 0.91188(8) 0.83970(4) 0.0748(4) Uani 1 1 d . U . . .
S3S S 0.25463(16) 0.07523(11) 0.93627(5) 0.0994(6) Uani 1 1 d . U . . .
S4S S 0.97367(14) 0.40028(12) 0.78916(7) 0.1021(6) Uani 1 1 d . U . . .
S5S S 0.06342(19) 0.97264(12) 0.60485(6) 0.1182(8) Uani 1 1 d . U . . .
S6S S 0.69471(11) 0.61777(10) 0.66368(4) 0.0799(4) Uani 1 1 d . U . . .
S7S S 0.5958(2) 0.0726(2) 0.68374(17) 0.1943(18) Uani 1 1 d . U . . .
S8S S 0.3991(2) 0.6263(2) 0.90547(11) 0.1585(13) Uani 1 1 d . U . . .
F1S F 0.1252(4) 0.4452(3) 0.5900(2) 0.153(2) Uani 1 1 d . U . . .
F2S F 0.0934(3) 0.3438(3) 0.56337(15) 0.1194(16) Uani 1 1 d . U . . .
F3S F 0.1525(4) 0.3801(3) 0.61736(14) 0.1304(19) Uani 1 1 d . U . . .
F4S F 0.7605(5) 0.7929(3) 0.79943(17) 0.159(3) Uani 1 1 d . U . . .
F5S F 0.6981(4) 0.8603(4) 0.79206(19) 0.164(3) Uani 1 1 d . U . . .
F6S F 0.8152(4) 0.8660(3) 0.76987(13) 0.152(3) Uani 1 1 d . U . . .
F7S F 0.3121(7) -0.0077(5) 0.9605(3) 0.208(4) Uani 1 1 d . U . . .
F8S F 0.3769(6) 0.0283(6) 0.91970(19) 0.209(4) Uani 1 1 d . U . . .
F9S F 0.4056(6) 0.0953(5) 0.9703(2) 0.214(4) Uani 1 1 d . U . . .
F10S F 0.9653(7) 0.5110(4) 0.8216(3) 0.200(4) Uani 1 1 d . U . . .
F11S F 1.0520(5) 0.4770(3) 0.85149(17) 0.146(2) Uani 1 1 d . U . . .
F12S F 1.0938(5) 0.5136(3) 0.80624(19) 0.158(2) Uani 1 1 d . U . . .
F13S F 0.0066(8) 0.9767(6) 0.5426(2) 0.285(6) Uani 1 1 d . U . . .
F14S F 0.1309(11) 0.9646(8) 0.5462(4) 0.339(7) Uani 1 1 d . U . . .
F15S F 0.1222(8) 1.0577(5) 0.5683(2) 0.251(6) Uani 1 1 d . U . . .
F16S F 0.7318(5) 0.7433(3) 0.69299(18) 0.149(2) Uani 1 1 d . U . . .
F17S F 0.8377(3) 0.7095(4) 0.69734(18) 0.149(2) Uani 1 1 d . U . . .
F18S F 0.7397(4) 0.6845(4) 0.73066(13) 0.157(3) Uani 1 1 d . U . . .
F19S F 0.5929(10) 0.0931(11) 0.7500(5) 0.371(9) Uani 1 1 d . U . . .
F20S F 0.5072(8) 0.1247(7) 0.7249(3) 0.255(5) Uani 1 1 d . U . . .
F21S F 0.4690(10) 0.0291(9) 0.7161(5) 0.363(9) Uani 1 1 d . U . . .
F22S F 0.2490(8) 0.5379(5) 0.8970(3) 0.264(6) Uani 1 1 d . U . . .
F23S F 0.2620(9) 0.6410(6) 0.9169(4) 0.261(5) Uani 1 1 d . U . . .
F24S F 0.2751(7) 0.6018(7) 0.8623(3) 0.267(6) Uani 1 1 d . U . . .
O1 O 0.5108(2) 0.33341(15) 0.75563(8) 0.0524(7) Uani 1 1 d . U . . .
O2 O 0.5712(2) 0.37013(17) 0.69609(9) 0.0551(7) Uani 1 1 d . U . . .
O1S O 0.2789(4) 0.3545(2) 0.56845(16) 0.0962(15) Uani 1 1 d . U . . .
O3 O 0.4464(2) 0.30360(16) 0.66327(8) 0.0516(7) Uani 1 1 d . U . . .
O2S O 0.2471(4) 0.4276(3) 0.53701(14) 0.1091(18) Uani 1 1 d . U . . .
O4 O 0.3875(2) 0.26388(15) 0.72228(8) 0.0504(7) Uani 1 1 d . U . . .
O3S O 0.3130(3) 0.4698(2) 0.59844(13) 0.0842(12) Uani 1 1 d . U . . .
O5 O 0.6291(3) 0.77172(18) 0.50614(9) 0.0650(9) Uani 1 1 d . U . . .
O4S O 0.7858(4) 0.8905(3) 0.86689(15) 0.1067(17) Uani 1 1 d . U . . .
O6 O 0.6598(2) 0.67410(17) 0.52855(9) 0.0572(8) Uani 1 1 d . U . . .
O5S O 0.9171(4) 0.9004(3) 0.83977(17) 0.1068(16) Uani 1 1 d . U . . .
O7 O 0.5134(2) 0.69953(18) 0.46979(9) 0.0592(8) Uani 1 1 d . U . . .
O6S O 0.8418(4) 0.9739(3) 0.83404(16) 0.1031(16) Uani 1 1 d . U . . .
O8 O 0.5426(2) 0.60150(16) 0.49284(8) 0.0493(7) Uani 1 1 d . U . . .
O7S O 0.2227(7) 0.0838(6) 0.9691(2) 0.196(4) Uani 1 1 d . U . . .
O9 O 0.1714(2) 1.24613(16) 0.78654(8) 0.0538(7) Uani 1 1 d . U . . .
O8S O 0.2950(8) 0.1306(4) 0.9261(2) 0.205(5) Uani 1 1 d . U . . .
O10 O 0.1003(2) 1.20582(16) 0.84379(8) 0.0551(7) Uani 1 1 d . U . . .
O9S O 0.2003(5) 0.0219(3) 0.90795(16) 0.121(2) Uani 1 1 d . U . . .
O11 O 0.0499(2) 1.17977(17) 0.75093(9) 0.0567(7) Uani 1 1 d . U . . .
O10S O 0.9009(5) 0.3728(4) 0.8075(2) 0.136(2) Uani 1 1 d . U . . .
O12 O -0.0206(2) 1.14024(16) 0.80815(9) 0.0566(8) Uani 1 1 d . U . . .
O11S O 0.9475(4) 0.4134(4) 0.75651(18) 0.124(2) Uani 1 1 d . U . . .
O13 O -0.0498(2) 0.89138(17) 0.99941(8) 0.0563(8) Uani 1 1 d . U . . .
O12S O 1.0434(5) 0.3746(4) 0.7871(2) 0.143(3) Uani 1 1 d . U . . .
O14 O -0.0470(3) 0.78496(17) 1.02048(9) 0.0607(8) Uani 1 1 d . U . . .
O13S O 0.0091(9) 1.0068(5) 0.6217(3) 0.204(4) Uani 1 1 d . U . . .
O15 O -0.1714(2) 0.83043(17) 0.96256(9) 0.0581(8) Uani 1 1 d . U . . .
O14S O 0.0257(6) 0.9023(4) 0.5957(2) 0.162(3) Uani 1 1 d . U . . .
O16 O -0.1664(3) 0.72349(17) 0.98260(9) 0.0609(8) Uani 1 1 d . U . . .
O15S O 0.1486(7) 0.9977(4) 0.6235(3) 0.193(4) Uani 1 1 d . U . . .
O16S O 0.7227(4) 0.6324(3) 0.63109(13) 0.1039(17) Uani 1 1 d . U . . .
O17S O 0.6068(3) 0.6112(3) 0.66775(13) 0.1012(17) Uani 1 1 d . U . . .
O18S O 0.7210(5) 0.5700(4) 0.6748(2) 0.127(2) Uani 1 1 d . U . . .
O19S O 0.6188(7) 0.0177(5) 0.6845(5) 0.262(6) Uani 1 1 d . U . . .
O20S O 0.5305(10) 0.0594(10) 0.6534(4) 0.310(8) Uani 1 1 d . U . . .
O21S O 0.6674(7) 0.1336(6) 0.6916(5) 0.266(7) Uani 1 1 d . U . . .
O22S O 0.4158(7) 0.6145(6) 0.9406(3) 0.225(5) Uani 1 1 d . U . . .
O23S O 0.4285(6) 0.6861(5) 0.8999(3) 0.196(5) Uani 1 1 d . U . . .
O24S O 0.4031(7) 0.5656(5) 0.8970(4) 0.242(6) Uani 1 1 d . U . . .
N1 N 0.5754(3) 0.47459(19) 0.75849(11) 0.0566(9) Uani 1 1 d . U . . .
N2 N 0.0980(3) 0.8501(2) 0.98474(11) 0.0618(10) Uani 1 1 d . U . . .
N3 N 0.6253(3) 0.7731(2) 0.58323(11) 0.0631(10) Uani 1 1 d . U . . .
N4 N 0.2577(4) 1.1827(2) 0.82469(12) 0.0664(11) Uani 1 1 d . U . . .
N5 N -0.1592(3) 0.7252(2) 0.90632(11) 0.0617(10) Uani 1 1 d . U . . .
N6 N -0.0188(3) 1.03765(19) 0.74499(11) 0.0516(8) Uani 1 1 d . U . . .
N7 N 0.3871(3) 0.6287(2) 0.51124(10) 0.0513(8) Uani 1 1 d . U . . .
N8 N 0.2894(3) 0.32603(19) 0.68793(10) 0.0509(8) Uani 1 1 d . U . . .
C1 C 0.2359(3) 0.3309(2) 0.71288(13) 0.0544(10) Uani 1 1 d . U . . .
H1 H 0.216821 0.297015 0.725090 0.065 Uiso 1 1 calc R U . . .
C2 C 0.2068(3) 0.3840(2) 0.72171(13) 0.0551(9) Uani 1 1 d . U . . .
H2 H 0.167653 0.385548 0.739365 0.066 Uiso 1 1 calc R U . . .
C1S C 0.1535(5) 0.3942(3) 0.58559(19) 0.0815(16) Uani 1 1 d . U . . .
C3 C 0.2353(3) 0.4350(2) 0.70458(12) 0.0516(9) Uani 1 1 d . U . . .
C2S C 0.7771(6) 0.8551(5) 0.7981(2) 0.111(3) Uani 1 1 d . U . . .
C4 C 0.2941(4) 0.4293(2) 0.67966(14) 0.0580(10) Uani 1 1 d . U . . .
H4 H 0.318253 0.463776 0.668311 0.070 Uiso 1 1 calc R U . . .
C3S C 0.3425(8) 0.0467(7) 0.9462(3) 0.134(3) Uani 1 1 d . U . . .
C5 C 0.3171(4) 0.3750(2) 0.67145(13) 0.0562(9) Uani 1 1 d . U . . .
H5 H 0.354505 0.371472 0.653242 0.067 Uiso 1 1 calc R U . . .
C4S C 1.0247(9) 0.4777(5) 0.8173(3) 0.122(3) Uani 1 1 d . U . . .
C6 C 0.2031(3) 0.4904(2) 0.71066(12) 0.0509(8) Uani 1 1 d . U . . .
C5S C 0.0802(10) 0.9953(7) 0.5646(3) 0.163(4) Uani 1 1 d . U . . .
C7 C 0.1194(4) 0.4835(2) 0.71890(14) 0.0582(10) Uani 1 1 d . U . . .
H7 H 0.083200 0.443068 0.722812 0.070 Uiso 1 1 calc R U . . .
C6S C 0.7526(5) 0.6943(5) 0.69806(19) 0.0959(19) Uani 1 1 d . U . . .
C8 C 0.0876(3) 0.5345(2) 0.72153(13) 0.0555(9) Uani 1 1 d . U . . .
H8 H 0.029462 0.528347 0.726631 0.067 Uiso 1 1 calc R U . . .
C7S C 0.5390(9) 0.0780(11) 0.7204(6) 0.225(5) Uani 1 1 d . U . . .
C9 C 0.2560(3) 0.5512(2) 0.70644(13) 0.0544(9) Uani 1 1 d . U . . .
H9 H 0.314154 0.557339 0.701268 0.065 Uiso 1 1 calc R U . . .
C8S C 0.2871(9) 0.5990(7) 0.8917(4) 0.148(3) Uani 1 1 d . U . . .
C10 C 0.2246(3) 0.6023(2) 0.70971(13) 0.0542(9) Uani 1 1 d . U . . .
H10 H 0.261910 0.643354 0.707063 0.065 Uiso 1 1 calc R U . . .
C11 C -0.0190(3) 0.6750(2) 0.75096(13) 0.0532(9) Uani 1 1 d . U . . .
H11 H -0.044931 0.675018 0.728387 0.064 Uiso 1 1 calc R U . . .
C12 C -0.0575(3) 0.6890(2) 0.78184(13) 0.0555(9) Uani 1 1 d . U . . .
H12 H -0.108069 0.700802 0.780437 0.067 Uiso 1 1 calc R U . . .
C13 C -0.0238(4) 0.6863(2) 0.81480(13) 0.0556(9) Uani 1 1 d . U . . .
C14 C 0.0505(4) 0.6697(2) 0.81677(13) 0.0567(9) Uani 1 1 d . U . . .
H14 H 0.073894 0.666945 0.839169 0.068 Uiso 1 1 calc R U . . .
C15 C 0.0905(4) 0.6571(2) 0.78611(13) 0.0557(9) Uani 1 1 d . U . . .
H15 H 0.141342 0.645767 0.787821 0.067 Uiso 1 1 calc R U . . .
C16 C -0.0657(4) 0.7025(2) 0.84774(13) 0.0566(10) Uani 1 1 d . U . . .
C17 C -0.0968(4) 0.7547(3) 0.85445(14) 0.0617(11) Uani 1 1 d . U . . .
H17 H -0.086831 0.783426 0.838929 0.074 Uiso 1 1 calc R U . . .
C18 C -0.1420(4) 0.7646(3) 0.88372(14) 0.0631(11) Uani 1 1 d . U . . .
H18 H -0.161949 0.800861 0.888073 0.076 Uiso 1 1 calc R U . . .
C19 C -0.0780(4) 0.6650(3) 0.87320(14) 0.0625(11) Uani 1 1 d . U . . .
H19 H -0.053847 0.631125 0.871130 0.075 Uiso 1 1 calc R U . . .
C20 C -0.1255(4) 0.6777(3) 0.90124(14) 0.0631(11) Uani 1 1 d . U . . .
H20 H -0.134571 0.650984 0.917829 0.076 Uiso 1 1 calc R U . . .
C21 C 0.1069(3) 0.6513(2) 0.72067(12) 0.0498(8) Uani 1 1 d . U . . .
C22 C 0.1221(3) 0.6923(2) 0.69854(12) 0.0495(8) Uani 1 1 d . U . . .
C23 C 0.1398(3) 0.5951(2) 0.71679(12) 0.0506(8) Uani 1 1 d . U . . .
C24 C 0.0583(3) 0.6606(2) 0.75269(12) 0.0497(8) Uani 1 1 d . U . . .
C25 C 0.1657(3) 0.6813(2) 0.66529(12) 0.0490(8) Uani 1 1 d . U . . .
C26 C 0.2304(3) 0.7345(2) 0.65749(13) 0.0531(9) Uani 1 1 d . U . . .
H26 H 0.244178 0.777145 0.673116 0.064 Uiso 1 1 calc R U . . .
C27 C 0.2741(3) 0.7261(2) 0.62776(13) 0.0538(9) Uani 1 1 d . U . . .
H27 H 0.317450 0.762945 0.623149 0.065 Uiso 1 1 calc R U . . .
C28 C 0.2556(3) 0.6647(2) 0.60447(13) 0.0539(9) Uani 1 1 d . U . . .
C29 C 0.1898(4) 0.6116(3) 0.61103(13) 0.0590(10) Uani 1 1 d . U . . .
H29 H 0.175821 0.569291 0.595022 0.071 Uiso 1 1 calc R U . . .
C30 C 0.1444(4) 0.6200(2) 0.64083(13) 0.0577(10) Uani 1 1 d . U . . .
H30 H 0.098428 0.583714 0.644508 0.069 Uiso 1 1 calc R U . . .
C31 C 0.3048(3) 0.6540(3) 0.57305(13) 0.0552(9) Uani 1 1 d . U . . .
C32 C 0.3300(4) 0.6992(3) 0.55220(14) 0.0601(10) Uani 1 1 d . U . . .
H32 H 0.319859 0.739614 0.558937 0.072 Uiso 1 1 calc R U . . .
C33 C 0.3702(4) 0.6849(3) 0.52150(14) 0.0607(10) Uani 1 1 d . U . . .
H33 H 0.386232 0.715816 0.507312 0.073 Uiso 1 1 calc R U . . .
C34 C 0.3654(4) 0.5861(3) 0.53248(13) 0.0563(10) Uani 1 1 d . U . . .
H34 H 0.378872 0.546977 0.526073 0.068 Uiso 1 1 calc R U . . .
C35 C 0.3247(4) 0.5971(2) 0.56278(13) 0.0562(10) Uani 1 1 d . U . . .
H35 H 0.310201 0.565781 0.576753 0.067 Uiso 1 1 calc R U . . .
C36 C 0.1016(3) 0.7536(2) 0.70662(11) 0.0476(8) Uani 1 1 d . U . . .
C37 C 0.0603(3) 0.7706(2) 0.67986(12) 0.0539(9) Uani 1 1 d . U . . .
H37 H 0.045807 0.742415 0.656131 0.065 Uiso 1 1 calc R U . . .
C38 C 0.0401(3) 0.8275(2) 0.68711(12) 0.0535(9) Uani 1 1 d . U . . .
H38 H 0.012345 0.838140 0.668394 0.064 Uiso 1 1 calc R U . . .
C39 C 0.0605(3) 0.8696(2) 0.72228(12) 0.0481(8) Uani 1 1 d . U . . .
C40 C 0.1025(3) 0.8532(2) 0.74876(13) 0.0547(9) Uani 1 1 d . U . . .
H40 H 0.117192 0.881204 0.772537 0.066 Uiso 1 1 calc R U . . .
C41 C 0.1232(3) 0.7972(2) 0.74106(13) 0.0537(9) Uani 1 1 d . U . . .
H41 H 0.152962 0.787535 0.759602 0.064 Uiso 1 1 calc R U . . .
C42 C 0.0357(3) 0.9285(2) 0.73021(12) 0.0498(8) Uani 1 1 d . U . . .
C43 C 0.0340(3) 0.9645(2) 0.70492(13) 0.0544(9) Uani 1 1 d . U . . .
H43 H 0.051471 0.951999 0.681754 0.065 Uiso 1 1 calc R U . . .
C44 C 0.0073(4) 1.0179(2) 0.71330(14) 0.0565(9) Uani 1 1 d . U . . .
H44 H 0.007530 1.041803 0.695663 0.068 Uiso 1 1 calc R U . . .
C45 C -0.0159(4) 1.0054(2) 0.77008(13) 0.0566(10) Uani 1 1 d . U . . .
H45 H -0.033308 1.019938 0.792986 0.068 Uiso 1 1 calc R U . . .
C46 C 0.0114(4) 0.9516(2) 0.76411(13) 0.0555(9) Uani 1 1 d . U . . .
H46 H 0.013691 0.930490 0.782861 0.067 Uiso 1 1 calc R U . . .
C47 C 0.5872(4) 0.5165(3) 0.73708(14) 0.0627(11) Uani 1 1 d . U . . .
H47 H 0.618508 0.510637 0.716881 0.075 Uiso 1 1 calc R U . . .
C48 C 0.5301(4) 0.4823(2) 0.78622(14) 0.0592(10) Uani 1 1 d . U . . .
H48 H 0.521158 0.452615 0.801171 0.071 Uiso 1 1 calc R U . . .
C49 C 0.4951(4) 0.5326(2) 0.79419(13) 0.0572(10) Uani 1 1 d . U . . .
H49 H 0.462141 0.536111 0.814011 0.069 Uiso 1 1 calc R U . . .
C50 C 0.5554(4) 0.5674(3) 0.74360(13) 0.0588(10) Uani 1 1 d . U . . .
H50 H 0.565136 0.596018 0.728022 0.071 Uiso 1 1 calc R U . . .
C51 C 0.5084(3) 0.5774(2) 0.77325(12) 0.0524(9) Uani 1 1 d . U . . .
C52 C 0.4768(3) 0.6334(2) 0.78208(12) 0.0521(9) Uani 1 1 d . U . . .
C53 C 0.3937(3) 0.6256(2) 0.79168(13) 0.0551(9) Uani 1 1 d . U . . .
H53 H 0.356408 0.583635 0.793079 0.066 Uiso 1 1 calc R U . . .
C54 C 0.3650(3) 0.6781(2) 0.79918(13) 0.0535(9) Uani 1 1 d . U . . .
H54 H 0.307817 0.671777 0.805640 0.064 Uiso 1 1 calc R U . . .
C55 C 0.4178(3) 0.7399(2) 0.79752(12) 0.0514(8) Uani 1 1 d . U . . .
C56 C 0.5033(3) 0.7490(2) 0.78978(13) 0.0531(9) Uani 1 1 d . U . . .
H56 H 0.541925 0.791714 0.790388 0.064 Uiso 1 1 calc R U . . .
C57 C 0.5320(3) 0.6964(2) 0.78131(13) 0.0530(9) Uani 1 1 d . U . . .
H57 H 0.589298 0.702594 0.774928 0.064 Uiso 1 1 calc R U . . .
C58 C 0.3832(3) 0.7957(2) 0.80273(12) 0.0513(8) Uani 1 1 d . U . . .
C59 C 0.3983(3) 0.8366(2) 0.78051(12) 0.0523(8) Uani 1 1 d . U . . .
C60 C 0.3306(3) 0.8012(2) 0.83382(12) 0.0535(9) Uani 1 1 d . U . . .
C61 C 0.3528(4) 0.7884(3) 0.86599(13) 0.0604(10) Uani 1 1 d . U . . .
H61 H 0.402098 0.775347 0.868168 0.072 Uiso 1 1 calc R U . . .
C62 C 0.3052(4) 0.7941(3) 0.89490(14) 0.0627(10) Uani 1 1 d . U . . .
H62 H 0.322527 0.785279 0.916574 0.075 Uiso 1 1 calc R U . . .
C63 C 0.2327(4) 0.8125(3) 0.89263(13) 0.0590(10) Uani 1 1 d . U . . .
C64 C 0.2068(4) 0.8233(3) 0.85983(13) 0.0582(10) Uani 1 1 d . U . . .
H64 H 0.156062 0.834485 0.857377 0.070 Uiso 1 1 calc R U . . .
C65 C 0.2555(3) 0.8175(3) 0.83113(13) 0.0564(9) Uani 1 1 d . U . . .
H65 H 0.237373 0.824819 0.809111 0.068 Uiso 1 1 calc R U . . .
C66 C 0.1825(4) 0.8226(3) 0.92378(13) 0.0593(10) Uani 1 1 d . U . . .
C67 C 0.1724(4) 0.7861(3) 0.94941(14) 0.0675(11) Uani 1 1 d . U . . .
H67 H 0.193759 0.750573 0.946416 0.081 Uiso 1 1 calc R U . . .
C68 C 0.1313(4) 0.8019(3) 0.97907(14) 0.0675(11) Uani 1 1 d . U . . .
H68 H 0.126300 0.777149 0.996533 0.081 Uiso 1 1 calc R U . . .
C69 C 0.1475(4) 0.8728(3) 0.92960(14) 0.0656(11) Uani 1 1 d . U . . .
H69 H 0.152681 0.898854 0.912783 0.079 Uiso 1 1 calc R U . . .
C70 C 0.1056(4) 0.8848(3) 0.95952(14) 0.0644(11) Uani 1 1 d . U . . .
H70 H 0.081064 0.918557 0.962624 0.077 Uiso 1 1 calc R U . . .
C71 C 0.4350(3) 0.8232(2) 0.74581(12) 0.0504(8) Uani 1 1 d . U . . .
C72 C 0.4127(3) 0.7606(2) 0.72301(13) 0.0559(9) Uani 1 1 d . U . . .
H72 H 0.373021 0.724851 0.730068 0.067 Uiso 1 1 calc R U . . .
C73 C 0.4459(4) 0.7483(3) 0.69055(13) 0.0570(10) Uani 1 1 d . U . . .
H73 H 0.431114 0.704541 0.676151 0.068 Uiso 1 1 calc R U . . .
C74 C 0.5019(4) 0.8010(3) 0.67896(13) 0.0578(10) Uani 1 1 d . U . . .
C75 C 0.5238(4) 0.8636(3) 0.70065(14) 0.0588(10) Uani 1 1 d . U . . .
H75 H 0.560681 0.899552 0.692787 0.071 Uiso 1 1 calc R U . . .
C76 C 0.4922(3) 0.8753(2) 0.73437(13) 0.0561(9) Uani 1 1 d . U . . .
H76 H 0.509713 0.918635 0.749467 0.067 Uiso 1 1 calc R U . . .
C77 C 0.5399(4) 0.7888(3) 0.64461(13) 0.0584(10) Uani 1 1 d . U . . .
C78 C 0.5664(4) 0.7353(3) 0.63365(13) 0.0590(10) Uani 1 1 d . U . . .
H78 H 0.554238 0.702340 0.646601 0.071 Uiso 1 1 calc R U . . .
C79 C 0.6107(4) 0.7301(3) 0.60360(14) 0.0625(11) Uani 1 1 d . U . . .
H79 H 0.631731 0.694566 0.597176 0.075 Uiso 1 1 calc R U . . .
C80 C 0.5932(4) 0.8216(3) 0.59197(16) 0.0711(12) Uani 1 1 d . U . . .
H80 H 0.600296 0.850859 0.576831 0.085 Uiso 1 1 calc R U . . .
C81 C 0.5507(4) 0.8313(3) 0.62165(15) 0.0677(11) Uani 1 1 d . U . . .
H81 H 0.528494 0.866395 0.626781 0.081 Uiso 1 1 calc R U . . .
C82 C 0.3757(3) 0.8978(2) 0.78795(12) 0.0525(8) Uani 1 1 d . U . . .
C83 C 0.3353(3) 0.9132(3) 0.76007(13) 0.0564(9) Uani 1 1 d . U . . .
H83 H 0.322286 0.884452 0.736524 0.068 Uiso 1 1 calc R U . . .
C84 C 0.3142(4) 0.9695(3) 0.76628(14) 0.0593(9) Uani 1 1 d . U . . .
H84 H 0.287803 0.979382 0.746881 0.071 Uiso 1 1 calc R U . . .
C85 C 0.3312(4) 1.0122(3) 0.80084(14) 0.0628(10) Uani 1 1 d . U . . .
C86 C 0.3722(4) 0.9972(3) 0.82825(15) 0.0650(10) Uani 1 1 d . U . . .
H86 H 0.384283 1.025665 0.851880 0.078 Uiso 1 1 calc R U . . .
C87 C 0.3960(4) 0.9416(3) 0.82196(14) 0.0597(10) Uani 1 1 d . U . . .
H87 H 0.426255 0.933511 0.840965 0.072 Uiso 1 1 calc R U . . .
C88 C 0.3052(4) 1.0701(3) 0.80770(15) 0.0656(10) Uani 1 1 d . U . . .
C89 C 0.2647(4) 1.0844(3) 0.83823(16) 0.0722(12) Uani 1 1 d . U . . .
H89 H 0.253024 1.056250 0.854074 0.087 Uiso 1 1 calc R U . . .
C90 C 0.2415(4) 1.1397(3) 0.84538(15) 0.0702(11) Uani 1 1 d . U . . .
H90 H 0.212401 1.147947 0.866041 0.084 Uiso 1 1 calc R U . . .
C91 C 0.3205(4) 1.1140(3) 0.78611(15) 0.0669(11) Uani 1 1 d . U . . .
H91 H 0.347698 1.106181 0.764846 0.080 Uiso 1 1 calc R U . . .
C92 C 0.2963(4) 1.1688(3) 0.79537(14) 0.0656(11) Uani 1 1 d . U . . .
H92 H 0.307716 1.197980 0.780104 0.079 Uiso 1 1 calc R U . . .
C93 C 0.0553(3) 1.1824(2) 0.81394(12) 0.0521(10) Uani 1 1 d . U . . .
C94 C 0.0950(3) 1.2044(2) 0.78090(12) 0.0504(9) Uani 1 1 d . U . . .
C95 C -0.1084(3) 0.7777(2) 0.99732(11) 0.0544(10) Uani 1 1 d . U . . .
C96 C -0.1100(3) 0.8383(2) 0.98551(11) 0.0520(10) Uani 1 1 d . U . . .
C97 C 0.4619(3) 0.3067(2) 0.72625(11) 0.0467(9) Uani 1 1 d . U . . .
C98 C 0.4960(3) 0.3282(2) 0.69257(12) 0.0476(9) Uani 1 1 d . U . . .
C99 C 0.5951(3) 0.6584(2) 0.50555(11) 0.0500(9) Uani 1 1 d . U . . .
C100 C 0.5775(3) 0.7142(2) 0.49265(12) 0.0541(10) Uani 1 1 d . U . . .
C121 C -0.1614(4) 1.0958(4) 0.70568(19) 0.0793(13) Uani 1 1 d . U . . .
C122 C -0.1503(4) 1.1588(3) 0.72926(19) 0.0757(12) Uani 1 1 d . U . . .
C123 C -0.1807(4) 1.1491(3) 0.76257(19) 0.0773(12) Uani 1 1 d . U . . .
C124 C -0.2129(4) 1.0781(4) 0.7581(2) 0.0801(13) Uani 1 1 d . U . . .
C125 C -0.2006(4) 1.0474(4) 0.7241(2) 0.0824(13) Uani 1 1 d . U . . .
C126 C -0.2548(5) 1.0434(5) 0.7865(3) 0.104(2) Uani 1 1 d . U . . .
H12A H -0.317740 1.022569 0.779326 0.156 Uiso 1 1 calc R U . . .
H12B H -0.243956 1.075489 0.809927 0.156 Uiso 1 1 calc R U . . .
H12C H -0.229635 1.009803 0.788451 0.156 Uiso 1 1 calc R U . . .
C127 C -0.2273(6) 0.9743(4) 0.7101(3) 0.111(2) Uani 1 1 d . U . . .
H12D H -0.200373 0.963915 0.688109 0.166 Uiso 1 1 calc R U . . .
H12E H -0.290808 0.955269 0.704644 0.166 Uiso 1 1 calc R U . . .
H12F H -0.208087 0.955963 0.728479 0.166 Uiso 1 1 calc R U . . .
C128 C -0.1422(6) 1.0825(5) 0.6672(2) 0.101(2) Uani 1 1 d . U . . .
H12G H -0.195880 1.070507 0.651033 0.151 Uiso 1 1 calc R U . . .
H12H H -0.119340 1.046246 0.662320 0.151 Uiso 1 1 calc R U . . .
H12I H -0.098963 1.121897 0.663199 0.151 Uiso 1 1 calc R U . . .
C129 C -0.1092(6) 1.2231(4) 0.7201(2) 0.0972(19) Uani 1 1 d . U . . .
H12J H -0.059554 1.221558 0.706763 0.146 Uiso 1 1 calc R U . . .
H12K H -0.089190 1.258410 0.742362 0.146 Uiso 1 1 calc R U . . .
H12L H -0.152121 1.231315 0.705083 0.146 Uiso 1 1 calc R U . . .
C130 C -0.1794(6) 1.1999(4) 0.7959(2) 0.100(2) Uani 1 1 d . U . . .
H13A H -0.151174 1.243702 0.792185 0.150 Uiso 1 1 calc R U . . .
H13B H -0.146923 1.194601 0.816273 0.150 Uiso 1 1 calc R U . . .
H13C H -0.239228 1.194622 0.801067 0.150 Uiso 1 1 calc R U . . .
C131 C 0.2544(5) 1.3234(3) 0.89680(15) 0.0748(13) Uani 1 1 d . U . . .
C132 C 0.2231(5) 1.3583(3) 0.87479(17) 0.0759(13) Uani 1 1 d . U . . .
C133 C 0.2844(5) 1.3739(3) 0.84955(17) 0.0780(13) Uani 1 1 d . U . . .
C134 C 0.3510(5) 1.3455(3) 0.85492(16) 0.0792(14) Uani 1 1 d . U . . .
C135 C 0.3311(5) 1.3161(3) 0.88463(16) 0.0781(13) Uani 1 1 d . U . . .
C136 C 0.4292(6) 1.3484(5) 0.8348(2) 0.107(2) Uani 1 1 d . U . . .
H13D H 0.445998 1.310166 0.835130 0.161 Uiso 1 1 calc R U . . .
H13E H 0.477676 1.388651 0.846326 0.161 Uiso 1 1 calc R U . . .
H13F H 0.414577 1.348184 0.809681 0.161 Uiso 1 1 calc R U . . .
C137 C 0.3851(6) 1.2833(4) 0.8999(2) 0.102(2) Uani 1 1 d . U . . .
H13G H 0.417457 1.266859 0.881202 0.153 Uiso 1 1 calc R U . . .
H13H H 0.347069 1.246591 0.908277 0.153 Uiso 1 1 calc R U . . .
H13I H 0.426193 1.315034 0.920271 0.153 Uiso 1 1 calc R U . . .
C138 C 0.2084(5) 1.2970(4) 0.92622(17) 0.0905(19) Uani 1 1 d . U . . .
H13J H 0.145290 1.283078 0.919860 0.136 Uiso 1 1 calc R U . . .
H13K H 0.225886 1.331307 0.948970 0.136 Uiso 1 1 calc R U . . .
H13L H 0.223970 1.259344 0.929046 0.136 Uiso 1 1 calc R U . . .
C139 C 0.1401(6) 1.3756(4) 0.8778(2) 0.104(2) Uani 1 1 d . U . . .
H13M H 0.108806 1.364771 0.853658 0.157 Uiso 1 1 calc R U . . .
H13N H 0.155480 1.422652 0.888954 0.157 Uiso 1 1 calc R U . . .
H13O H 0.102816 1.350474 0.892760 0.157 Uiso 1 1 calc R U . . .
C140 C 0.2775(6) 1.4074(3) 0.8205(2) 0.098(2) Uani 1 1 d . U . . .
H14A H 0.307787 1.392733 0.800383 0.148 Uiso 1 1 calc R U . . .
H14B H 0.304188 1.455001 0.830124 0.148 Uiso 1 1 calc R U . . .
H14C H 0.216004 1.396311 0.811820 0.148 Uiso 1 1 calc R U . . .
C141 C 0.8477(5) 0.7877(4) 0.5723(2) 0.0946(16) Uani 1 1 d . U . . .
C142 C 0.8265(5) 0.8407(4) 0.5899(2) 0.0939(16) Uani 1 1 d . U . . .
C143 C 0.8148(6) 0.8745(4) 0.5662(3) 0.1076(18) Uani 1 1 d . U . . .
C144 C 0.8311(5) 0.8503(5) 0.5343(2) 0.1091(18) Uani 1 1 d . U . . .
C145 C 0.8525(5) 0.7938(5) 0.5337(2) 0.1079(18) Uani 1 1 d . U . . .
C146 C 0.8644(7) 0.7407(6) 0.5864(4) 0.137(3) Uani 1 1 d . U . . .
H14D H 0.861943 0.742721 0.611409 0.164 Uiso 1 1 calc R U . . .
H14E H 0.878444 0.706243 0.571160 0.164 Uiso 1 1 calc R U . . .
C147 C 0.8154(7) 0.8568(6) 0.6290(2) 0.133(3) Uani 1 1 d . U . . .
H14F H 0.765178 0.871451 0.632231 0.200 Uiso 1 1 calc R U . . .
H14G H 0.867958 0.891869 0.642415 0.200 Uiso 1 1 calc R U . . .
H14H H 0.805707 0.817697 0.638161 0.200 Uiso 1 1 calc R U . . .
C148 C 0.7897(8) 0.9384(5) 0.5757(3) 0.143(3) Uani 1 1 d . U . . .
H14I H 0.748698 0.937145 0.556048 0.215 Uiso 1 1 calc R U . . .
H14J H 0.842286 0.977170 0.578832 0.215 Uiso 1 1 calc R U . . .
H14K H 0.762457 0.940682 0.598146 0.215 Uiso 1 1 calc R U . . .
C149 C 0.8245(7) 0.8754(6) 0.5009(3) 0.151(3) Uani 1 1 d . U . . .
H14L H 0.817245 0.839992 0.479206 0.226 Uiso 1 1 calc R U . . .
H14M H 0.877780 0.912194 0.501229 0.226 Uiso 1 1 calc R U . . .
H14N H 0.774281 0.890113 0.500900 0.226 Uiso 1 1 calc R U . . .
C150 C 0.8741(7) 0.7472(6) 0.5047(3) 0.155(3) Uani 1 1 d . U . . .
H15A H 0.880976 0.763767 0.483042 0.233 Uiso 1 1 calc R U . . .
H15B H 0.827140 0.704432 0.499247 0.233 Uiso 1 1 calc R U . . .
H15C H 0.928623 0.742279 0.512711 0.233 Uiso 1 1 calc R U . . .
C151 C 0.3334(3) 0.5045(3) 0.43944(12) 0.0595(10) Uani 1 1 d . U . . .
C152 C 0.3043(3) 0.5545(3) 0.43102(13) 0.0616(11) Uani 1 1 d . U . . .
C153 C 0.3645(4) 0.5864(3) 0.40887(12) 0.0588(10) Uani 1 1 d . U . . .
C154 C 0.4311(3) 0.5574(3) 0.40434(11) 0.0535(9) Uani 1 1 d . U . . .
C155 C 0.4109(3) 0.5062(2) 0.42299(11) 0.0519(9) Uani 1 1 d . U . . .
C156 C 0.2863(4) 0.4550(3) 0.45890(15) 0.0729(15) Uani 1 1 d . U . . .
H15D H 0.247110 0.415699 0.441411 0.109 Uiso 1 1 calc R U . . .
H15E H 0.252227 0.473568 0.475955 0.109 Uiso 1 1 calc R U . . .
H15F H 0.328490 0.443107 0.472115 0.109 Uiso 1 1 calc R U . . .
C157 C 0.2247(4) 0.5697(4) 0.44175(18) 0.0834(16) Uani 1 1 d . U . . .
H15G H 0.174898 0.542173 0.423645 0.125 Uiso 1 1 calc R U . . .
H15H H 0.234400 0.616071 0.443311 0.125 Uiso 1 1 calc R U . . .
H15I H 0.212650 0.560833 0.465312 0.125 Uiso 1 1 calc R U . . .
C158 C 0.3614(5) 0.6422(3) 0.39445(17) 0.0758(14) Uani 1 1 d . U . . .
H15J H 0.357485 0.629684 0.368023 0.114 Uiso 1 1 calc R U . . .
H15K H 0.414419 0.680262 0.404120 0.114 Uiso 1 1 calc R U . . .
H15L H 0.310401 0.653587 0.401688 0.114 Uiso 1 1 calc R U . . .
C159 C 0.5054(4) 0.5754(3) 0.38260(13) 0.0626(12) Uani 1 1 d . U . . .
H15M H 0.489530 0.546079 0.358193 0.094 Uiso 1 1 calc R U . . .
H15N H 0.556713 0.570987 0.394161 0.094 Uiso 1 1 calc R U . . .
H15O H 0.518500 0.620869 0.381177 0.094 Uiso 1 1 calc R U . . .
C160 C 0.4654(4) 0.4658(3) 0.42684(13) 0.0617(11) Uani 1 1 d . U . . .
H16A H 0.445747 0.425271 0.407340 0.093 Uiso 1 1 calc R U . . .
H16B H 0.460015 0.454774 0.450212 0.093 Uiso 1 1 calc R U . . .
H16C H 0.526431 0.490548 0.425500 0.093 Uiso 1 1 calc R U . . .
C161 C 0.1940(4) 0.1668(3) 0.65336(14) 0.0681(12) Uani 1 1 d . U . . .
C162 C 0.2541(5) 0.1372(3) 0.66186(17) 0.0793(13) Uani 1 1 d . U . . .
C163 C 0.3191(5) 0.1471(3) 0.63773(19) 0.0809(13) Uani 1 1 d . U . . .
C164 C 0.2962(4) 0.1820(3) 0.61444(14) 0.0684(12) Uani 1 1 d . U . . .
C165 C 0.2218(4) 0.1940(3) 0.62445(13) 0.0589(10) Uani 1 1 d . U . . .
C166 C 0.1116(5) 0.1650(4) 0.6705(2) 0.102(2) Uani 1 1 d . U . . .
H16D H 0.094508 0.201722 0.667074 0.153 Uiso 1 1 calc R U . . .
H16E H 0.122038 0.168732 0.696360 0.153 Uiso 1 1 calc R U . . .
H16F H 0.064965 0.123505 0.659074 0.153 Uiso 1 1 calc R U . . .
C167 C 0.2504(7) 0.1051(4) 0.6925(2) 0.119(3) Uani 1 1 d . U . . .
H16G H 0.211252 0.059381 0.684527 0.178 Uiso 1 1 calc R U . . .
H16H H 0.228553 0.128610 0.712788 0.178 Uiso 1 1 calc R U . . .
H16I H 0.308846 0.106516 0.700132 0.178 Uiso 1 1 calc R U . . .
C168 C 0.3947(7) 0.1238(5) 0.6345(3) 0.122(2) Uani 1 1 d . U . . .
H16J H 0.375298 0.078344 0.619848 0.183 Uiso 1 1 calc R U . . .
H16K H 0.419646 0.126167 0.658600 0.183 Uiso 1 1 calc R U . . .
H16L H 0.438870 0.151703 0.622892 0.183 Uiso 1 1 calc R U . . .
C169 C 0.3476(5) 0.2062(4) 0.58572(18) 0.106(2) Uani 1 1 d . U . . .
H16M H 0.309277 0.192297 0.562972 0.158 Uiso 1 1 calc R U . . .
H16N H 0.394645 0.188027 0.582375 0.158 Uiso 1 1 calc R U . . .
H16O H 0.372561 0.254279 0.593039 0.158 Uiso 1 1 calc R U . . .
C170 C 0.1722(5) 0.2265(4) 0.6062(2) 0.0845(16) Uani 1 1 d . U . . .
H17A H 0.211323 0.255119 0.593302 0.127 Uiso 1 1 calc R U . . .
H17B H 0.148201 0.252651 0.624363 0.127 Uiso 1 1 calc R U . . .
H17C H 0.124493 0.192857 0.588987 0.127 Uiso 1 1 calc R U . . .
C171 C 0.7279(6) 0.4249(5) 0.7950(3) 0.1160(18) Uani 1 1 d D U . . .
C172 C 0.7113(6) 0.3604(5) 0.7749(3) 0.1152(17) Uani 1 1 d D U . . .
C174 C 0.7432(5) 0.3712(5) 0.7395(3) 0.1160(18) Uani 1 1 d D U . . .
C175 C 0.7687(6) 0.4381(5) 0.7454(3) 0.1153(18) Uani 1 1 d D U . . .
C176 C 0.8043(8) 0.4860(6) 0.7207(4) 0.163(3) Uani 1 1 d D U . . .
H17D H 0.761621 0.506673 0.716533 0.245 Uiso 1 1 calc R U . . .
H17E H 0.814118 0.461342 0.697557 0.245 Uiso 1 1 calc R U . . .
H17F H 0.859258 0.520033 0.732690 0.245 Uiso 1 1 calc R U . . .
C177 C 0.7407(8) 0.3216(6) 0.7047(3) 0.172(3) Uani 1 1 d D U . . .
H17G H 0.798543 0.332645 0.696442 0.258 Uiso 1 1 calc R U . . .
H17H H 0.698396 0.322423 0.686253 0.258 Uiso 1 1 calc R U . . .
H17I H 0.723568 0.277642 0.708926 0.258 Uiso 1 1 calc R U . . .
C179 C 0.6719(8) 0.3049(7) 0.7901(4) 0.162(3) Uani 1 1 d D U . . .
H17J H 0.650411 0.319847 0.812834 0.244 Uiso 1 1 calc R U . . .
H17K H 0.715515 0.285230 0.794565 0.244 Uiso 1 1 calc R U . . .
H17L H 0.623291 0.272061 0.772976 0.244 Uiso 1 1 calc R U . . .
C180 C 0.7153(9) 0.4560(8) 0.8341(3) 0.166(3) Uani 1 1 d . U . . .
H18G H 0.720503 0.501849 0.836392 0.249 Uiso 1 1 calc R U . . .
H18H H 0.760013 0.454194 0.851087 0.249 Uiso 1 1 calc R U . . .
H18I H 0.657491 0.431641 0.839418 0.249 Uiso 1 1 calc R U . . .
C181 C 0.7570(6) 0.4677(5) 0.7759(3) 0.1211(19) Uani 1 1 d D U . . .
C182 C 0.7786(8) 0.5434(6) 0.7906(4) 0.158(3) Uani 1 1 d . U . . .
H18J H 0.805620 0.565710 0.772437 0.237 Uiso 1 1 calc R U . . .
H18K H 0.818876 0.559410 0.812875 0.237 Uiso 1 1 calc R U . . .
H18L H 0.724786 0.552339 0.795507 0.237 Uiso 1 1 calc R U . . .
C183 C -0.3626(6) 0.5987(4) 0.9651(3) 0.113(2) Uani 1 1 d . U . . .
H18V H -0.421745 0.573833 0.968933 0.169 Uiso 1 1 calc R U . . .
H18W H -0.326317 0.619146 0.988478 0.169 Uiso 1 1 calc R U . . .
H18X H -0.337842 0.569039 0.949812 0.169 Uiso 1 1 calc R U . . .
C184 C 0.0907(5) 0.8310(3) 1.10178(17) 0.0823(16) Uani 1 1 d . U . . .
H18S H 0.029267 0.803082 1.098611 0.123 Uiso 1 1 calc R U . . .
H18T H 0.112734 0.845715 1.127536 0.123 Uiso 1 1 calc R U . . .
H18U H 0.124477 0.806011 1.088686 0.123 Uiso 1 1 calc R U . . .
C185 C -0.0418(4) 0.9089(3) 1.10775(15) 0.0736(15) Uani 1 1 d . U . . .
H18M H -0.086481 0.918351 1.094521 0.110 Uiso 1 1 calc R U . . .
H18N H -0.028368 0.936954 1.132482 0.110 Uiso 1 1 calc R U . . .
H18O H -0.063243 0.862725 1.108405 0.110 Uiso 1 1 calc R U . . .
C186 C 0.2496(5) 0.9026(4) 1.0615(2) 0.0912(17) Uani 1 1 d . U . . .
H18D H 0.262274 0.904475 1.036831 0.137 Uiso 1 1 calc R U . . .
H18E H 0.240783 0.858322 1.064187 0.137 Uiso 1 1 calc R U . . .
H18F H 0.298649 0.934353 1.078756 0.137 Uiso 1 1 calc R U . . .
C187 C 0.2061(5) 1.0206(4) 1.03967(19) 0.0903(19) Uani 1 1 d . U . . .
H18P H 0.249382 1.003384 1.028273 0.135 Uiso 1 1 calc R U . . .
H18Q H 0.235934 1.062323 1.057525 0.135 Uiso 1 1 calc R U . . .
H18R H 0.169828 1.027581 1.021197 0.135 Uiso 1 1 calc R U . . .
C188 C 0.0267(5) 1.0207(3) 1.06667(15) 0.0737(14) Uani 1 1 d . U . . .
H18A H 0.046916 1.038246 1.046057 0.110 Uiso 1 1 calc R U . . .
H18B H 0.039965 1.056846 1.088499 0.110 Uiso 1 1 calc R U . . .
H18C H -0.036364 0.997349 1.062022 0.110 Uiso 1 1 calc R U . . .
C189 C 0.0708(4) 0.9752(3) 1.07179(12) 0.0636(11) Uani 1 1 d . U . . .
C190 C 0.0392(4) 0.9224(3) 1.08912(12) 0.0639(11) Uani 1 1 d . U . . .
C191 C 0.0992(4) 0.8891(3) 1.08740(13) 0.0676(12) Uani 1 1 d . U . . .
C192 C 0.1693(4) 0.9188(3) 1.06852(15) 0.0742(12) Uani 1 1 d . U . . .
C193 C 0.1499(4) 0.9723(3) 1.05806(14) 0.0695(12) Uani 1 1 d . U . . .
C194 C -0.3656(4) 0.7104(4) 0.90492(17) 0.0820(14) Uani 1 1 d . U . . .
C195 C -0.3763(4) 0.7469(3) 0.93863(17) 0.0763(13) Uani 1 1 d . U . . .
C196 C -0.3749(4) 0.7099(4) 0.96463(16) 0.0781(14) Uani 1 1 d . U . . .
C197 C -0.3657(4) 0.6512(3) 0.94694(18) 0.0809(14) Uani 1 1 d . U . . .
C198 C -0.3581(5) 0.6507(4) 0.91009(18) 0.0838(14) Uani 1 1 d . U . . .
C199 C -0.3679(6) 0.7268(5) 0.8692(2) 0.116(2) Uani 1 1 d . U . . .
H19A H -0.331931 0.707164 0.853782 0.174 Uiso 1 1 calc R U . . .
H19B H -0.345167 0.774570 0.872927 0.174 Uiso 1 1 calc R U . . .
H19C H -0.428055 0.709408 0.857551 0.174 Uiso 1 1 calc R U . . .
C200 C -0.3849(6) 0.8133(4) 0.9457(3) 0.111(2) Uani 1 1 d . U . . .
H20G H -0.360316 0.834709 0.926892 0.166 Uiso 1 1 calc R U . . .
H20H H -0.353337 0.840045 0.969356 0.166 Uiso 1 1 calc R U . . .
H20I H -0.446540 0.808711 0.945561 0.166 Uiso 1 1 calc R U . . .
C201 C -0.3869(6) 0.7324(5) 1.0032(2) 0.110(2) Uani 1 1 d . U . . .
H20A H -0.345235 0.776760 1.013532 0.165 Uiso 1 1 calc R U . . .
H20B H -0.377131 0.702427 1.016655 0.165 Uiso 1 1 calc R U . . .
H20C H -0.446378 0.732886 1.004782 0.165 Uiso 1 1 calc R U . . .
C202 C -0.3503(6) 0.5962(5) 0.8810(3) 0.123(3) Uani 1 1 d . U . . .
H20D H -0.405796 0.559487 0.875413 0.185 Uiso 1 1 calc R U . . .
H20E H -0.304376 0.581515 0.889148 0.185 Uiso 1 1 calc R U . . .
H20F H -0.335579 0.611744 0.859278 0.185 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0583 0.0400 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -0.0161 2.8414 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.2925 0.4295 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N7 Rh1 C152 95.93(18) . . ?
N7 Rh1 C151 101.15(17) . . ?
C152 Rh1 C151 39.6(2) . . ?
N7 Rh1 C153 125.54(19) . . ?
C152 Rh1 C153 39.43(19) . . ?
C151 Rh1 C153 65.8(2) . . ?
N7 Rh1 C155 135.56(16) . . ?
C152 Rh1 C155 66.0(2) . . ?
C151 Rh1 C155 39.09(19) . . ?
C153 Rh1 C155 65.4(2) . . ?
N7 Rh1 C154 162.14(18) . . ?
C152 Rh1 C154 66.21(19) . . ?
C151 Rh1 C154 65.86(18) . . ?
C153 Rh1 C154 39.0(2) . . ?
C155 Rh1 C154 39.12(18) . . ?
N7 Rh1 O8 84.70(14) . . ?
C152 Rh1 O8 155.99(19) . . ?
C151 Rh1 O8 116.61(18) . . ?
C153 Rh1 O8 149.52(16) . . ?
C155 Rh1 O8 96.84(16) . . ?
C154 Rh1 O8 111.75(16) . . ?
N7 Rh1 O7 86.06(14) . . ?
C152 Rh1 O7 126.20(19) . . ?
C151 Rh1 O7 164.19(17) . . ?
C153 Rh1 O7 98.54(18) . . ?
C155 Rh1 O7 137.87(15) . . ?
C154 Rh1 O7 103.73(16) . . ?
O8 Rh1 O7 77.80(13) . . ?
C143 Rh2 N3 105.4(3) . . ?
C143 Rh2 C141 63.4(4) . . ?
N3 Rh2 C141 115.4(3) . . ?
C143 Rh2 C145 62.9(4) . . ?
N3 Rh2 C145 156.6(3) . . ?
C141 Rh2 C145 41.8(3) . . ?
C143 Rh2 C144 35.4(3) . . ?
N3 Rh2 C144 139.1(3) . . ?
C141 Rh2 C144 65.3(4) . . ?
C145 Rh2 C144 38.5(4) . . ?
C143 Rh2 O5 111.2(3) . . ?
N3 Rh2 O5 87.52(17) . . ?
C141 Rh2 O5 157.1(2) . . ?
C145 Rh2 O5 115.4(3) . . ?
C144 Rh2 O5 97.1(3) . . ?
C143 Rh2 O6 165.8(3) . . ?
N3 Rh2 O6 85.26(15) . . ?
C141 Rh2 O6 103.8(3) . . ?
C145 Rh2 O6 103.7(3) . . ?
C144 Rh2 O6 135.6(3) . . ?
O5 Rh2 O6 78.04(14) . . ?
C143 Rh2 C142 37.0(3) . . ?
N3 Rh2 C142 93.6(2) . . ?
C141 Rh2 C142 37.5(3) . . ?
C145 Rh2 C142 64.6(3) . . ?
C144 Rh2 C142 61.6(3) . . ?
O5 Rh2 C142 147.0(3) . . ?
O6 Rh2 C142 135.0(3) . . ?
N4 Rh3 C134 104.8(3) . . ?
N4 Rh3 C135 96.2(3) . . ?
C134 Rh3 C135 39.6(2) . . ?
N4 Rh3 C132 160.8(2) . . ?
C134 Rh3 C132 66.8(3) . . ?
C135 Rh3 C132 66.1(3) . . ?
N4 Rh3 C131 121.2(2) . . ?
C134 Rh3 C131 66.0(2) . . ?
C135 Rh3 C131 38.5(3) . . ?
C132 Rh3 C131 39.9(3) . . ?
N4 Rh3 O10 85.45(17) . . ?
C134 Rh3 O10 163.2(2) . . ?
C135 Rh3 O10 127.30(18) . . ?
C132 Rh3 O10 99.2(2) . . ?
C131 Rh3 O10 97.34(19) . . ?
N4 Rh3 C133 141.8(3) . . ?
C134 Rh3 C133 40.1(3) . . ?
C135 Rh3 C133 66.1(3) . . ?
C132 Rh3 C133 39.2(3) . . ?
C131 Rh3 C133 65.9(2) . . ?
O10 Rh3 C133 132.5(2) . . ?
N4 Rh3 O9 84.76(16) . . ?
C134 Rh3 O9 115.14(18) . . ?
C135 Rh3 O9 154.16(18) . . ?
C132 Rh3 O9 114.4(2) . . ?
C131 Rh3 O9 153.5(2) . . ?
O10 Rh3 O9 78.54(12) . . ?
C133 Rh3 O9 97.45(19) . . ?
N6 Rh4 C124 115.7(2) . . ?
N6 Rh4 C121 109.4(2) . . ?
C124 Rh4 C121 64.5(3) . . ?
N6 Rh4 C125 95.3(2) . . ?
C124 Rh4 C125 37.8(3) . . ?
C121 Rh4 C125 38.7(3) . . ?
N6 Rh4 C123 155.8(2) . . ?
C124 Rh4 C123 40.1(3) . . ?
C121 Rh4 C123 65.8(3) . . ?
C125 Rh4 C123 65.7(3) . . ?
N6 Rh4 O12 86.97(15) . . ?
C124 Rh4 O12 102.0(2) . . ?
C121 Rh4 O12 161.9(2) . . ?
C125 Rh4 O12 135.2(2) . . ?
C123 Rh4 O12 96.1(2) . . ?
N6 Rh4 C122 147.4(2) . . ?
C124 Rh4 C122 65.1(3) . . ?
C121 Rh4 C122 39.2(3) . . ?
C125 Rh4 C122 65.1(3) . . ?
C123 Rh4 C122 38.8(3) . . ?
O12 Rh4 C122 125.4(2) . . ?
N6 Rh4 O11 86.91(15) . . ?
C124 Rh4 O11 157.4(2) . . ?
C121 Rh4 O11 109.8(2) . . ?
C125 Rh4 O11 147.0(2) . . ?
C123 Rh4 O11 117.3(2) . . ?
O12 Rh4 O11 77.77(13) . . ?
C122 Rh4 O11 96.2(2) . . ?
C193 Rh5 N2 101.9(2) . . ?
C193 Rh5 O13 114.6(2) . . ?
N2 Rh5 O13 85.21(16) . . ?
C193 Rh5 C190 66.0(2) . . ?
N2 Rh5 C190 162.9(2) . . ?
O13 Rh5 C190 110.5(2) . . ?
C193 Rh5 C192 40.2(3) . . ?
N2 Rh5 C192 97.5(2) . . ?
O13 Rh5 C192 154.8(2) . . ?
C190 Rh5 C192 65.4(2) . . ?
C193 Rh5 C191 66.2(2) . . ?
N2 Rh5 C191 126.9(2) . . ?
O13 Rh5 C191 147.8(2) . . ?
C190 Rh5 C191 38.3(2) . . ?
C192 Rh5 C191 39.1(2) . . ?
C193 Rh5 C189 39.2(2) . . ?
N2 Rh5 C189 136.17(19) . . ?
O13 Rh5 C189 94.72(19) . . ?
C190 Rh5 C189 39.30(19) . . ?
C192 Rh5 C189 66.0(3) . . ?
C191 Rh5 C189 65.2(2) . . ?
C193 Rh5 O14 166.10(18) . . ?
N2 Rh5 O14 85.44(16) . . ?
O13 Rh5 O14 77.45(14) . . ?
C190 Rh5 O14 104.08(17) . . ?
C192 Rh5 O14 127.7(2) . . ?
C191 Rh5 O14 99.97(18) . . ?
C189 Rh5 O14 137.42(18) . . ?
C198 Rh6 N5 96.8(2) . . ?
C198 Rh6 C194 39.6(3) . . ?
N5 Rh6 C194 101.2(2) . . ?
C198 Rh6 O15 157.7(3) . . ?
N5 Rh6 O15 84.68(16) . . ?
C194 Rh6 O15 118.2(2) . . ?
C198 Rh6 C197 39.1(3) . . ?
N5 Rh6 C197 126.6(2) . . ?
C194 Rh6 C197 65.4(3) . . ?
O15 Rh6 C197 148.4(2) . . ?
C198 Rh6 C196 65.0(3) . . ?
N5 Rh6 C196 161.8(2) . . ?
C194 Rh6 C196 65.2(2) . . ?
O15 Rh6 C196 112.1(2) . . ?
C197 Rh6 C196 37.9(3) . . ?
C198 Rh6 C195 65.2(3) . . ?
N5 Rh6 C195 135.0(2) . . ?
C194 Rh6 C195 38.5(3) . . ?
O15 Rh6 C195 98.1(2) . . ?
C197 Rh6 C195 64.5(3) . . ?
C196 Rh6 C195 39.1(3) . . ?
C198 Rh6 O16 124.5(3) . . ?
N5 Rh6 O16 86.91(17) . . ?
C194 Rh6 O16 162.4(2) . . ?
O15 Rh6 O16 77.77(14) . . ?
C197 Rh6 O16 97.2(2) . . ?
C196 Rh6 O16 103.0(2) . . ?
C195 Rh6 O16 137.8(2) . . ?
C172 Rh7 C181 65.0(4) . . ?
C172 Rh7 C175 64.9(4) . . ?
C181 Rh7 C175 34.9(3) . . ?
C172 Rh7 C171 38.9(3) . . ?
C181 Rh7 C171 36.3(3) . . ?
C175 Rh7 C171 59.5(4) . . ?
C172 Rh7 C174 42.1(3) . . ?
C181 Rh7 C174 63.5(4) . . ?
C175 Rh7 C174 38.0(3) . . ?
C171 Rh7 C174 64.6(4) . . ?
C172 Rh7 N1 145.0(3) . . ?
C181 Rh7 N1 94.0(3) . . ?
C175 Rh7 N1 114.0(3) . . ?
C171 Rh7 N1 108.1(3) . . ?
C174 Rh7 N1 151.8(3) . . ?
C172 Rh7 O2 128.6(3) . . ?
C181 Rh7 O2 135.0(3) . . ?
C175 Rh7 O2 105.4(3) . . ?
C171 Rh7 O2 162.3(3) . . ?
C174 Rh7 O2 97.9(3) . . ?
N1 Rh7 O2 86.17(15) . . ?
C172 Rh7 O1 96.1(3) . . ?
C181 Rh7 O1 146.9(3) . . ?
C175 Rh7 O1 158.6(3) . . ?
C171 Rh7 O1 112.4(3) . . ?
C174 Rh7 O1 121.1(3) . . ?
N1 Rh7 O1 87.09(15) . . ?
O2 Rh7 O1 78.04(12) . . ?
C165 Rh8 C164 38.1(2) . . ?
C165 Rh8 C163 65.0(2) . . ?
C164 Rh8 C163 39.2(3) . . ?
C165 Rh8 N8 97.99(19) . . ?
C164 Rh8 N8 126.5(2) . . ?
C163 Rh8 N8 163.0(2) . . ?
C165 Rh8 O3 122.21(17) . . ?
C164 Rh8 O3 95.45(19) . . ?
C163 Rh8 O3 102.5(2) . . ?
N8 Rh8 O3 86.61(14) . . ?
C165 Rh8 C161 38.6(2) . . ?
C164 Rh8 C161 64.6(2) . . ?
C163 Rh8 C161 65.4(3) . . ?
N8 Rh8 C161 101.5(2) . . ?
O3 Rh8 C161 159.57(17) . . ?
C165 Rh8 C162 64.7(2) . . ?
C164 Rh8 C162 65.0(2) . . ?
C163 Rh8 C162 39.2(3) . . ?
N8 Rh8 C162 134.9(3) . . ?
O3 Rh8 C162 138.4(2) . . ?
C161 Rh8 C162 38.8(3) . . ?
C165 Rh8 O4 159.58(16) . . ?
C164 Rh8 O4 148.0(2) . . ?
C163 Rh8 O4 111.0(2) . . ?
N8 Rh8 O4 84.78(14) . . ?
O3 Rh8 O4 78.06(12) . . ?
C161 Rh8 O4 121.03(17) . . ?
C162 Rh8 O4 99.11(18) . . ?
O2S S1S O1S 116.0(4) . . ?
O2S S1S O3S 113.7(3) . . ?
O1S S1S O3S 116.0(3) . . ?
O2S S1S C1S 102.8(4) . . ?
O1S S1S C1S 102.6(3) . . ?
O3S S1S C1S 102.9(3) . . ?
O4S S2S O6S 117.5(4) . . ?
O4S S2S O5S 113.7(4) . . ?
O6S S2S O5S 114.2(4) . . ?
O4S S2S C2S 104.3(4) . . ?
O6S S2S C2S 103.0(4) . . ?
O5S S2S C2S 101.6(5) . . ?
O8S S3S O7S 115.7(8) . . ?
O8S S3S O9S 114.7(5) . . ?
O7S S3S O9S 116.2(6) . . ?
O8S S3S C3S 103.7(7) . . ?
O7S S3S C3S 101.1(6) . . ?
O9S S3S C3S 102.3(5) . . ?
O11S S4S O12S 114.8(5) . . ?
O11S S4S O10S 112.4(4) . . ?
O12S S4S O10S 119.4(5) . . ?
O11S S4S C4S 103.1(5) . . ?
O12S S4S C4S 101.1(5) . . ?
O10S S4S C4S 103.0(5) . . ?
O15S S5S O13S 111.9(7) . . ?
O15S S5S O14S 114.0(6) . . ?
O13S S5S O14S 115.3(7) . . ?
O15S S5S C5S 102.5(7) . . ?
O13S S5S C5S 104.8(8) . . ?
O14S S5S C5S 106.9(6) . . ?
O18S S6S O16S 116.4(4) . . ?
O18S S6S O17S 113.8(4) . . ?
O16S S6S O17S 114.9(3) . . ?
O18S S6S C6S 104.2(5) . . ?
O16S S6S C6S 103.4(4) . . ?
O17S S6S C6S 101.5(4) . . ?
O19S S7S O21S 114.8(6) . . ?
O19S S7S O20S 112.4(10) . . ?
O21S S7S O20S 117.7(11) . . ?
O19S S7S C7S 101.2(10) . . ?
O21S S7S C7S 104.8(11) . . ?
O20S S7S C7S 103.4(9) . . ?
O23S S8S O24S 146.0(10) . . ?
O23S S8S O22S 121.9(8) . . ?
O24S S8S O22S 76.3(8) . . ?
O23S S8S C8S 103.9(7) . . ?
O24S S8S C8S 93.7(7) . . ?
O22S S8S C8S 110.7(6) . . ?
C97 O1 Rh7 113.2(3) . . ?
C98 O2 Rh7 113.3(3) . . ?
C98 O3 Rh8 113.5(3) . . ?
C97 O4 Rh8 112.6(3) . . ?
C100 O5 Rh2 113.4(4) . . ?
C99 O6 Rh2 113.4(3) . . ?
C100 O7 Rh1 112.3(3) . . ?
C99 O8 Rh1 113.1(3) . . ?
C94 O9 Rh3 112.4(3) . . ?
C93 O10 Rh3 113.4(3) . . ?
C94 O11 Rh4 113.5(3) . . ?
C93 O12 Rh4 114.0(3) . . ?
C96 O13 Rh5 114.3(3) . . ?
C95 O14 Rh5 112.7(3) . . ?
C96 O15 Rh6 114.1(3) . . ?
C95 O16 Rh6 112.7(3) . . ?
S8S O22S O24S 48.7(5) . . ?
S8S O24S O22S 55.0(6) . . ?
C48 N1 C47 118.7(4) . . ?
C48 N1 Rh7 120.4(3) . . ?
C47 N1 Rh7 120.8(3) . . ?
C68 N2 C70 117.3(4) . . ?
C68 N2 Rh5 123.8(3) . . ?
C70 N2 Rh5 118.5(4) . . ?
C80 N3 C79 117.8(4) . . ?
C80 N3 Rh2 120.6(4) . . ?
C79 N3 Rh2 119.5(4) . . ?
C92 N4 C90 116.8(5) . . ?
C92 N4 Rh3 123.9(4) . . ?
C90 N4 Rh3 119.2(3) . . ?
C20 N5 C18 117.4(4) . . ?
C20 N5 Rh6 122.6(3) . . ?
C18 N5 Rh6 119.1(4) . . ?
C44 N6 C45 118.3(4) . . ?
C44 N6 Rh4 120.4(3) . . ?
C45 N6 Rh4 120.9(3) . . ?
C33 N7 C34 117.6(4) . . ?
C33 N7 Rh1 123.2(3) . . ?
C34 N7 Rh1 118.7(3) . . ?
C1 N8 C5 118.1(4) . . ?
C1 N8 Rh8 122.9(3) . . ?
C5 N8 Rh8 118.5(3) . . ?
N8 C1 C2 122.1(4) . . ?
N8 C1 H1 119.0 . . ?
C2 C1 H1 119.0 . . ?
C1 C2 C3 120.0(4) . . ?
C1 C2 H2 120.0 . . ?
C3 C2 H2 120.0 . . ?
F2S C1S F3S 106.0(6) . . ?
F2S C1S F1S 107.0(7) . . ?
F3S C1S F1S 105.4(7) . . ?
F2S C1S S1S 113.7(5) . . ?
F3S C1S S1S 112.4(6) . . ?
F1S C1S S1S 111.8(5) . . ?
C4 C3 C2 116.1(4) . . ?
C4 C3 C6 120.7(4) . . ?
C2 C3 C6 123.1(4) . . ?
F6S C2S F4S 110.7(9) . . ?
F6S C2S F5S 105.0(8) . . ?
F4S C2S F5S 105.1(7) . . ?
F6S C2S S2S 113.2(5) . . ?
F4S C2S S2S 111.4(7) . . ?
F5S C2S S2S 110.9(8) . . ?
C5 C4 C3 120.6(4) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
F8S C3S F9S 107.5(11) . . ?
F8S C3S F7S 104.8(13) . . ?
F9S C3S F7S 109.1(11) . . ?
F8S C3S S3S 114.4(9) . . ?
F9S C3S S3S 110.0(10) . . ?
F7S C3S S3S 110.7(9) . . ?
N8 C5 C4 122.9(4) . . ?
N8 C5 H5 118.5 . . ?
C4 C5 H5 118.5 . . ?
F12S C4S F11S 104.8(10) . . ?
F12S C4S F10S 108.6(9) . . ?
F11S C4S F10S 105.8(9) . . ?
F12S C4S S4S 115.1(8) . . ?
F11S C4S S4S 113.3(6) . . ?
F10S C4S S4S 108.8(9) . . ?
C7 C6 C9 118.3(4) . . ?
C7 C6 C3 121.6(4) . . ?
C9 C6 C3 120.0(4) . . ?
F15S C5S F13S 109.4(15) . . ?
F15S C5S F14S 104.7(13) . . ?
F13S C5S F14S 105.5(12) . . ?
F15S C5S S5S 114.5(8) . . ?
F13S C5S S5S 112.7(10) . . ?
F14S C5S S5S 109.4(14) . . ?
C6 C7 C8 120.9(4) . . ?
C6 C7 H7 119.6 . . ?
C8 C7 H7 119.6 . . ?
F16S C6S F17S 107.9(8) . . ?
F16S C6S F18S 112.8(9) . . ?
F17S C6S F18S 104.4(6) . . ?
F16S C6S S6S 112.3(5) . . ?
F17S C6S S6S 109.9(7) . . ?
F18S C6S S6S 109.2(7) . . ?
C7 C8 C23 121.0(5) . . ?
C7 C8 H8 119.5 . . ?
C23 C8 H8 119.5 . . ?
F21S C7S F20S 99.7(14) . . ?
F21S C7S F19S 117.6(17) . . ?
F20S C7S F19S 104(2) . . ?
F21S C7S S7S 112(2) . . ?
F20S C7S S7S 113.5(12) . . ?
F19S C7S S7S 108.9(12) . . ?
C10 C9 C6 120.5(5) . . ?
C10 C9 H9 119.7 . . ?
C6 C9 H9 119.7 . . ?
F24S C8S F23S 115.0(16) . . ?
F24S C8S F22S 113.9(16) . . ?
F23S C8S F22S 106.9(11) . . ?
F24S C8S S8S 109.8(10) . . ?
F23S C8S S8S 101.0(12) . . ?
F22S C8S S8S 109.3(11) . . ?
C9 C10 C23 121.5(5) . . ?
C9 C10 H10 119.2 . . ?
C23 C10 H10 119.2 . . ?
C12 C11 C24 120.4(5) . . ?
C12 C11 H11 119.8 . . ?
C24 C11 H11 119.8 . . ?
C11 C12 C13 121.2(5) . . ?
C11 C12 H12 119.4 . . ?
C13 C12 H12 119.4 . . ?
C12 C13 C14 119.2(4) . . ?
C12 C13 C16 120.1(5) . . ?
C14 C13 C16 120.7(5) . . ?
C15 C14 C13 119.9(5) . . ?
C15 C14 H14 120.1 . . ?
C13 C14 H14 120.1 . . ?
C14 C15 C24 121.9(5) . . ?
C14 C15 H15 119.0 . . ?
C24 C15 H15 119.0 . . ?
C17 C16 C19 116.6(4) . . ?
C17 C16 C13 121.7(4) . . ?
C19 C16 C13 121.7(5) . . ?
C18 C17 C16 119.8(5) . . ?
C18 C17 H17 120.1 . . ?
C16 C17 H17 120.1 . . ?
N5 C18 C17 122.9(5) . . ?
N5 C18 H18 118.6 . . ?
C17 C18 H18 118.6 . . ?
C20 C19 C16 119.4(5) . . ?
C20 C19 H19 120.3 . . ?
C16 C19 H19 120.3 . . ?
N5 C20 C19 123.6(5) . . ?
N5 C20 H20 118.2 . . ?
C19 C20 H20 118.2 . . ?
C22 C21 C24 122.1(4) . . ?
C22 C21 C23 124.2(4) . . ?
C24 C21 C23 113.7(4) . . ?
C21 C22 C36 122.6(4) . . ?
C21 C22 C25 122.5(4) . . ?
C36 C22 C25 114.7(4) . . ?
C10 C23 C8 117.6(4) . . ?
C10 C23 C21 120.9(4) . . ?
C8 C23 C21 121.4(4) . . ?
C15 C24 C11 117.3(4) . . ?
C15 C24 C21 120.3(4) . . ?
C11 C24 C21 122.3(4) . . ?
C30 C25 C26 117.6(4) . . ?
C30 C25 C22 122.8(4) . . ?
C26 C25 C22 119.5(4) . . ?
C27 C26 C25 121.4(4) . . ?
C27 C26 H26 119.3 . . ?
C25 C26 H26 119.3 . . ?
C26 C27 C28 120.8(5) . . ?
C26 C27 H27 119.6 . . ?
C28 C27 H27 119.6 . . ?
C27 C28 C29 118.8(4) . . ?
C27 C28 C31 121.7(4) . . ?
C29 C28 C31 119.5(4) . . ?
C30 C29 C28 120.6(5) . . ?
C30 C29 H29 119.7 . . ?
C28 C29 H29 119.7 . . ?
C29 C30 C25 120.6(5) . . ?
C29 C30 H30 119.7 . . ?
C25 C30 H30 119.7 . . ?
C35 C31 C32 117.5(4) . . ?
C35 C31 C28 120.6(4) . . ?
C32 C31 C28 121.8(4) . . ?
C33 C32 C31 119.9(5) . . ?
C33 C32 H32 120.1 . . ?
C31 C32 H32 120.1 . . ?
N7 C33 C32 122.1(4) . . ?
N7 C33 H33 118.9 . . ?
C32 C33 H33 118.9 . . ?
N7 C34 C35 122.9(5) . . ?
N7 C34 H34 118.6 . . ?
C35 C34 H34 118.6 . . ?
C34 C35 C31 120.0(4) . . ?
C34 C35 H35 120.0 . . ?
C31 C35 H35 120.0 . . ?
C37 C36 C41 117.3(4) . . ?
C37 C36 C22 120.9(4) . . ?
C41 C36 C22 121.9(4) . . ?
C38 C37 C36 121.5(4) . . ?
C38 C37 H37 119.3 . . ?
C36 C37 H37 119.3 . . ?
C37 C38 C39 120.1(4) . . ?
C37 C38 H38 120.0 . . ?
C39 C38 H38 120.0 . . ?
C40 C39 C38 118.5(4) . . ?
C40 C39 C42 121.6(4) . . ?
C38 C39 C42 119.9(4) . . ?
C41 C40 C39 120.8(4) . . ?
C41 C40 H40 119.6 . . ?
C39 C40 H40 119.6 . . ?
C40 C41 C36 121.9(5) . . ?
C40 C41 H41 119.0 . . ?
C36 C41 H41 119.0 . . ?
C43 C42 C46 116.0(4) . . ?
C43 C42 C39 122.8(4) . . ?
C46 C42 C39 121.2(4) . . ?
C44 C43 C42 120.5(4) . . ?
C44 C43 H43 119.8 . . ?
C42 C43 H43 119.8 . . ?
N6 C44 C43 122.8(4) . . ?
N6 C44 H44 118.6 . . ?
C43 C44 H44 118.6 . . ?
N6 C45 C46 122.7(4) . . ?
N6 C45 H45 118.7 . . ?
C46 C45 H45 118.7 . . ?
C45 C46 C42 119.6(4) . . ?
C45 C46 H46 120.2 . . ?
C42 C46 H46 120.2 . . ?
N1 C47 C50 122.1(4) . . ?
N1 C47 H47 119.0 . . ?
C50 C47 H47 119.0 . . ?
N1 C48 C49 122.2(4) . . ?
N1 C48 H48 118.9 . . ?
C49 C48 H48 118.9 . . ?
C51 C49 C48 120.3(4) . . ?
C51 C49 H49 119.9 . . ?
C48 C49 H49 119.9 . . ?
C47 C50 C51 120.4(4) . . ?
C47 C50 H50 119.8 . . ?
C51 C50 H50 119.8 . . ?
C49 C51 C50 116.3(4) . . ?
C49 C51 C52 121.8(4) . . ?
C50 C51 C52 121.9(4) . . ?
C53 C52 C57 118.9(4) . . ?
C53 C52 C51 121.4(4) . . ?
C57 C52 C51 119.7(4) . . ?
C54 C53 C52 120.5(5) . . ?
C54 C53 H53 119.7 . . ?
C52 C53 H53 119.7 . . ?
C53 C54 C55 121.3(5) . . ?
C53 C54 H54 119.4 . . ?
C55 C54 H54 119.4 . . ?
C54 C55 C56 118.5(4) . . ?
C54 C55 C58 120.7(4) . . ?
C56 C55 C58 120.7(4) . . ?
C57 C56 C55 120.5(5) . . ?
C57 C56 H56 119.7 . . ?
C55 C56 H56 119.7 . . ?
C56 C57 C52 120.1(5) . . ?
C56 C57 H57 119.9 . . ?
C52 C57 H57 119.9 . . ?
C59 C58 C60 123.6(4) . . ?
C59 C58 C55 121.9(4) . . ?
C60 C58 C55 114.5(4) . . ?
C58 C59 C71 123.0(4) . . ?
C58 C59 C82 123.0(4) . . ?
C71 C59 C82 113.9(4) . . ?
C61 C60 C65 117.3(4) . . ?
C61 C60 C58 121.6(5) . . ?
C65 C60 C58 121.1(4) . . ?
C62 C61 C60 121.9(5) . . ?
C62 C61 H61 119.0 . . ?
C60 C61 H61 119.0 . . ?
C61 C62 C63 120.7(5) . . ?
C61 C62 H62 119.7 . . ?
C63 C62 H62 119.7 . . ?
C62 C63 C64 118.5(4) . . ?
C62 C63 C66 122.4(5) . . ?
C64 C63 C66 119.1(5) . . ?
C65 C64 C63 120.0(5) . . ?
C65 C64 H64 120.0 . . ?
C63 C64 H64 120.0 . . ?
C64 C65 C60 121.5(5) . . ?
C64 C65 H65 119.2 . . ?
C60 C65 H65 119.2 . . ?
C69 C66 C67 116.9(5) . . ?
C69 C66 C63 120.3(4) . . ?
C67 C66 C63 122.7(5) . . ?
C68 C67 C66 119.3(5) . . ?
C68 C67 H67 120.4 . . ?
C66 C67 H67 120.4 . . ?
N2 C68 C67 123.8(5) . . ?
N2 C68 H68 118.1 . . ?
C67 C68 H68 118.1 . . ?
C70 C69 C66 120.4(5) . . ?
C70 C69 H69 119.8 . . ?
C66 C69 H69 119.8 . . ?
N2 C70 C69 122.3(5) . . ?
N2 C70 H70 118.9 . . ?
C69 C70 H70 118.9 . . ?
C72 C71 C76 117.5(4) . . ?
C72 C71 C59 122.6(4) . . ?
C76 C71 C59 119.9(4) . . ?
C73 C72 C71 122.7(5) . . ?
C73 C72 H72 118.7 . . ?
C71 C72 H72 118.7 . . ?
C72 C73 C74 119.4(5) . . ?
C72 C73 H73 120.3 . . ?
C74 C73 H73 120.3 . . ?
C75 C74 C73 119.2(4) . . ?
C75 C74 C77 120.4(5) . . ?
C73 C74 C77 120.3(5) . . ?
C74 C75 C76 120.8(5) . . ?
C74 C75 H75 119.6 . . ?
C76 C75 H75 119.6 . . ?
C71 C76 C75 120.4(5) . . ?
C71 C76 H76 119.8 . . ?
C75 C76 H76 119.8 . . ?
C78 C77 C81 117.0(5) . . ?
C78 C77 C74 121.5(5) . . ?
C81 C77 C74 121.5(5) . . ?
C77 C78 C79 119.3(5) . . ?
C77 C78 H78 120.3 . . ?
C79 C78 H78 120.3 . . ?
N3 C79 C78 122.9(5) . . ?
N3 C79 H79 118.6 . . ?
C78 C79 H79 118.6 . . ?
N3 C80 C81 123.1(5) . . ?
N3 C80 H80 118.5 . . ?
C81 C80 H80 118.5 . . ?
C80 C81 C77 119.5(6) . . ?
C80 C81 H81 120.3 . . ?
C77 C81 H81 120.3 . . ?
C87 C82 C83 118.3(5) . . ?
C87 C82 C59 121.7(4) . . ?
C83 C82 C59 120.0(4) . . ?
C84 C83 C82 121.0(5) . . ?
C84 C83 H83 119.5 . . ?
C82 C83 H83 119.5 . . ?
C83 C84 C85 120.8(5) . . ?
C83 C84 H84 119.6 . . ?
C85 C84 H84 119.6 . . ?
C86 C85 C84 118.1(5) . . ?
C86 C85 C88 121.3(5) . . ?
C84 C85 C88 120.7(5) . . ?
C85 C86 C87 121.5(5) . . ?
C85 C86 H86 119.3 . . ?
C87 C86 H86 119.3 . . ?
C86 C87 C82 120.3(5) . . ?
C86 C87 H87 119.8 . . ?
C82 C87 H87 119.8 . . ?
C91 C88 C89 116.7(5) . . ?
C91 C88 C85 124.3(5) . . ?
C89 C88 C85 119.0(5) . . ?
C90 C89 C88 119.5(5) . . ?
C90 C89 H89 120.2 . . ?
C88 C89 H89 120.2 . . ?
N4 C90 C89 123.6(5) . . ?
N4 C90 H90 118.2 . . ?
C89 C90 H90 118.2 . . ?
C92 C91 C88 120.3(5) . . ?
C92 C91 H91 119.8 . . ?
C88 C91 H91 119.8 . . ?
N4 C92 C91 123.1(5) . . ?
N4 C92 H92 118.5 . . ?
C91 C92 H92 118.5 . . ?
O10 C93 O12 124.8(4) . . ?
O10 C93 C94 118.3(4) . . ?
O12 C93 C94 116.9(4) . . ?
O11 C94 O9 125.1(4) . . ?
O11 C94 C93 117.8(5) . . ?
O9 C94 C93 117.1(4) . . ?
O16 C95 O14 124.1(5) . . ?
O16 C95 C96 118.3(5) . . ?
O14 C95 C96 117.6(4) . . ?
O15 C96 O13 125.6(5) . . ?
O15 C96 C95 116.9(4) . . ?
O13 C96 C95 117.4(5) . . ?
O4 C97 O1 125.2(4) . . ?
O4 C97 C98 117.5(4) . . ?
O1 C97 C98 117.4(4) . . ?
O3 C98 O2 124.0(4) . . ?
O3 C98 C97 117.9(4) . . ?
O2 C98 C97 118.0(4) . . ?
O8 C99 O6 125.4(5) . . ?
O8 C99 C100 117.3(4) . . ?
O6 C99 C100 117.3(4) . . ?
O7 C100 O5 124.5(5) . . ?
O7 C100 C99 118.2(4) . . ?
O5 C100 C99 117.3(5) . . ?
C125 C121 C122 107.9(6) . . ?
C125 C121 C128 125.4(7) . . ?
C122 C121 C128 126.6(7) . . ?
C125 C121 Rh4 70.8(4) . . ?
C122 C121 Rh4 70.9(4) . . ?
C128 C121 Rh4 127.7(5) . . ?
C123 C122 C121 108.4(6) . . ?
C123 C122 C129 127.0(7) . . ?
C121 C122 C129 124.5(7) . . ?
C123 C122 Rh4 70.4(3) . . ?
C121 C122 Rh4 69.8(4) . . ?
C129 C122 Rh4 123.3(5) . . ?
C122 C123 C124 105.8(6) . . ?
C122 C123 C130 128.2(7) . . ?
C124 C123 C130 126.0(7) . . ?
C122 C123 Rh4 70.9(3) . . ?
C124 C123 Rh4 69.6(3) . . ?
C130 C123 Rh4 123.2(5) . . ?
C125 C124 C123 109.1(6) . . ?
C125 C124 C126 125.6(7) . . ?
C123 C124 C126 125.3(7) . . ?
C125 C124 Rh4 71.3(4) . . ?
C123 C124 Rh4 70.3(4) . . ?
C126 C124 Rh4 125.2(5) . . ?
C124 C125 C121 108.8(7) . . ?
C124 C125 C127 123.6(8) . . ?
C121 C125 C127 127.6(7) . . ?
C124 C125 Rh4 70.9(4) . . ?
C121 C125 Rh4 70.5(4) . . ?
C127 C125 Rh4 125.5(5) . . ?
C124 C126 H12A 109.5 . . ?
C124 C126 H12B 109.5 . . ?
H12A C126 H12B 109.5 . . ?
C124 C126 H12C 109.5 . . ?
H12A C126 H12C 109.5 . . ?
H12B C126 H12C 109.5 . . ?
C125 C127 H12D 109.5 . . ?
C125 C127 H12E 109.5 . . ?
H12D C127 H12E 109.5 . . ?
C125 C127 H12F 109.5 . . ?
H12D C127 H12F 109.5 . . ?
H12E C127 H12F 109.5 . . ?
C121 C128 H12G 109.5 . . ?
C121 C128 H12H 109.5 . . ?
H12G C128 H12H 109.5 . . ?
C121 C128 H12I 109.5 . . ?
H12G C128 H12I 109.5 . . ?
H12H C128 H12I 109.5 . . ?
C122 C129 H12J 109.5 . . ?
C122 C129 H12K 109.5 . . ?
H12J C129 H12K 109.5 . . ?
C122 C129 H12L 109.5 . . ?
H12J C129 H12L 109.5 . . ?
H12K C129 H12L 109.5 . . ?
C123 C130 H13A 109.5 . . ?
C123 C130 H13B 109.5 . . ?
H13A C130 H13B 109.5 . . ?
C123 C130 H13C 109.5 . . ?
H13A C130 H13C 109.5 . . ?
H13B C130 H13C 109.5 . . ?
C135 C131 C132 108.5(5) . . ?
C135 C131 C138 126.6(7) . . ?
C132 C131 C138 124.8(7) . . ?
C135 C131 Rh3 70.4(4) . . ?
C132 C131 Rh3 69.9(3) . . ?
C138 C131 Rh3 123.1(4) . . ?
C133 C132 C131 107.5(6) . . ?
C133 C132 C139 125.8(7) . . ?
C131 C132 C139 126.6(6) . . ?
C133 C132 Rh3 71.3(4) . . ?
C131 C132 Rh3 70.2(4) . . ?
C139 C132 Rh3 124.0(5) . . ?
C132 C133 C134 107.5(5) . . ?
C132 C133 C140 126.7(8) . . ?
C134 C133 C140 125.5(7) . . ?
C132 C133 Rh3 69.5(3) . . ?
C134 C133 Rh3 68.6(3) . . ?
C140 C133 Rh3 122.7(5) . . ?
C135 C134 C133 107.1(6) . . ?
C135 C134 C136 125.2(8) . . ?
C133 C134 C136 127.6(6) . . ?
C135 C134 Rh3 70.5(4) . . ?
C133 C134 Rh3 71.3(4) . . ?
C136 C134 Rh3 125.5(5) . . ?
C131 C135 C134 109.2(7) . . ?
C131 C135 C137 126.2(6) . . ?
C134 C135 C137 124.6(7) . . ?
C131 C135 Rh3 71.1(4) . . ?
C134 C135 Rh3 69.9(4) . . ?
C137 C135 Rh3 125.5(5) . . ?
C134 C136 H13D 109.5 . . ?
C134 C136 H13E 109.5 . . ?
H13D C136 H13E 109.5 . . ?
C134 C136 H13F 109.5 . . ?
H13D C136 H13F 109.5 . . ?
H13E C136 H13F 109.5 . . ?
C135 C137 H13G 109.5 . . ?
C135 C137 H13H 109.5 . . ?
H13G C137 H13H 109.5 . . ?
C135 C137 H13I 109.5 . . ?
H13G C137 H13I 109.5 . . ?
H13H C137 H13I 109.5 . . ?
C131 C138 H13J 109.5 . . ?
C131 C138 H13K 109.5 . . ?
H13J C138 H13K 109.5 . . ?
C131 C138 H13L 109.5 . . ?
H13J C138 H13L 109.5 . . ?
H13K C138 H13L 109.5 . . ?
C132 C139 H13M 109.5 . . ?
C132 C139 H13N 109.5 . . ?
H13M C139 H13N 109.5 . . ?
C132 C139 H13O 109.5 . . ?
H13M C139 H13O 109.5 . . ?
H13N C139 H13O 109.5 . . ?
C133 C140 H14A 109.5 . . ?
C133 C140 H14B 109.5 . . ?
H14A C140 H14B 109.5 . . ?
C133 C140 H14C 109.5 . . ?
H14A C140 H14C 109.5 . . ?
H14B C140 H14C 109.5 . . ?
C142 C141 C146 128.4(10) . . ?
C142 C141 C145 104.4(8) . . ?
C146 C141 C145 127.1(10) . . ?
C142 C141 Rh2 72.0(5) . . ?
C146 C141 Rh2 124.5(6) . . ?
C145 C141 Rh2 69.4(4) . . ?
C143 C142 C141 109.7(8) . . ?
C143 C142 C147 125.4(10) . . ?
C141 C142 C147 124.8(10) . . ?
C143 C142 Rh2 70.3(5) . . ?
C141 C142 Rh2 70.5(4) . . ?
C147 C142 Rh2 124.1(6) . . ?
C144 C143 C142 111.9(10) . . ?
C144 C143 C148 122.6(11) . . ?
C142 C143 C148 125.4(9) . . ?
C144 C143 Rh2 73.2(5) . . ?
C142 C143 Rh2 72.7(5) . . ?
C148 C143 Rh2 124.3(7) . . ?
C143 C144 C145 110.3(9) . . ?
C143 C144 C149 126.5(12) . . ?
C145 C144 C149 123.2(10) . . ?
C143 C144 Rh2 71.4(5) . . ?
C145 C144 Rh2 70.6(4) . . ?
C149 C144 Rh2 122.2(6) . . ?
C144 C145 C150 132.8(11) . . ?
C144 C145 C141 103.6(7) . . ?
C150 C145 C141 123.6(11) . . ?
C144 C145 Rh2 70.8(5) . . ?
C150 C145 Rh2 123.0(6) . . ?
C141 C145 Rh2 68.9(4) . . ?
C141 C146 H14D 120.0 . . ?
C141 C146 H14E 120.0 . . ?
H14D C146 H14E 120.0 . . ?
C142 C147 H14F 109.5 . . ?
C142 C147 H14G 109.5 . . ?
H14F C147 H14G 109.5 . . ?
C142 C147 H14H 109.5 . . ?
H14F C147 H14H 109.5 . . ?
H14G C147 H14H 109.5 . . ?
C143 C148 H14I 109.5 . . ?
C143 C148 H14J 109.5 . . ?
H14I C148 H14J 109.5 . . ?
C143 C148 H14K 109.5 . . ?
H14I C148 H14K 109.5 . . ?
H14J C148 H14K 109.5 . . ?
C144 C149 H14L 109.5 . . ?
C144 C149 H14M 109.5 . . ?
H14L C149 H14M 109.5 . . ?
C144 C149 H14N 109.5 . . ?
H14L C149 H14N 109.5 . . ?
H14M C149 H14N 109.5 . . ?
C145 C150 H15A 109.5 . . ?
C145 C150 H15B 109.5 . . ?
H15A C150 H15B 109.5 . . ?
C145 C150 H15C 109.5 . . ?
H15A C150 H15C 109.5 . . ?
H15B C150 H15C 109.5 . . ?
C155 C151 C152 108.3(4) . . ?
C155 C151 C156 125.5(6) . . ?
C152 C151 C156 126.0(5) . . ?
C155 C151 Rh1 71.2(3) . . ?
C152 C151 Rh1 70.1(3) . . ?
C156 C151 Rh1 128.9(4) . . ?
C153 C152 C151 107.2(5) . . ?
C153 C152 C157 125.5(6) . . ?
C151 C152 C157 127.3(5) . . ?
C153 C152 Rh1 71.1(3) . . ?
C151 C152 Rh1 70.3(3) . . ?
C157 C152 Rh1 125.6(4) . . ?
C154 C153 C152 108.5(5) . . ?
C154 C153 C158 125.2(5) . . ?
C152 C153 C158 126.2(5) . . ?
C154 C153 Rh1 70.6(3) . . ?
C152 C153 Rh1 69.5(3) . . ?
C158 C153 Rh1 123.6(4) . . ?
C153 C154 C155 107.6(4) . . ?
C153 C154 C159 125.8(5) . . ?
C155 C154 C159 126.5(5) . . ?
C153 C154 Rh1 70.3(3) . . ?
C155 C154 Rh1 70.3(2) . . ?
C159 C154 Rh1 126.9(4) . . ?
C151 C155 C154 108.3(5) . . ?
C151 C155 C160 126.0(4) . . ?
C154 C155 C160 125.5(4) . . ?
C151 C155 Rh1 69.7(3) . . ?
C154 C155 Rh1 70.5(3) . . ?
C160 C155 Rh1 121.8(3) . . ?
C151 C156 H15D 109.5 . . ?
C151 C156 H15E 109.5 . . ?
H15D C156 H15E 109.5 . . ?
C151 C156 H15F 109.5 . . ?
H15D C156 H15F 109.5 . . ?
H15E C156 H15F 109.5 . . ?
C152 C157 H15G 109.5 . . ?
C152 C157 H15H 109.5 . . ?
H15G C157 H15H 109.5 . . ?
C152 C157 H15I 109.5 . . ?
H15G C157 H15I 109.5 . . ?
H15H C157 H15I 109.5 . . ?
C153 C158 H15J 109.5 . . ?
C153 C158 H15K 109.5 . . ?
H15J C158 H15K 109.5 . . ?
C153 C158 H15L 109.5 . . ?
H15J C158 H15L 109.5 . . ?
H15K C158 H15L 109.5 . . ?
C154 C159 H15M 109.5 . . ?
C154 C159 H15N 109.5 . . ?
H15M C159 H15N 109.5 . . ?
C154 C159 H15O 109.5 . . ?
H15M C159 H15O 109.5 . . ?
H15N C159 H15O 109.5 . . ?
C155 C160 H16A 109.5 . . ?
C155 C160 H16B 109.5 . . ?
H16A C160 H16B 109.5 . . ?
C155 C160 H16C 109.5 . . ?
H16A C160 H16C 109.5 . . ?
H16B C160 H16C 109.5 . . ?
C165 C161 C162 107.3(6) . . ?
C165 C161 C166 126.2(7) . . ?
C162 C161 C166 126.3(6) . . ?
C165 C161 Rh8 69.7(3) . . ?
C162 C161 Rh8 70.8(4) . . ?
C166 C161 Rh8 128.1(4) . . ?
C161 C162 C163 107.9(5) . . ?
C161 C162 C167 124.4(8) . . ?
C163 C162 C167 127.6(8) . . ?
C161 C162 Rh8 70.5(3) . . ?
C163 C162 Rh8 69.9(3) . . ?
C167 C162 Rh8 122.5(5) . . ?
C164 C163 C162 106.7(6) . . ?
C164 C163 C168 123.9(8) . . ?
C162 C163 C168 129.3(8) . . ?
C164 C163 Rh8 70.2(3) . . ?
C162 C163 Rh8 70.9(3) . . ?
C168 C163 Rh8 126.3(5) . . ?
C165 C164 C163 108.4(6) . . ?
C165 C164 C169 125.3(7) . . ?
C163 C164 C169 126.1(7) . . ?
C165 C164 Rh8 70.5(3) . . ?
C163 C164 Rh8 70.6(3) . . ?
C169 C164 Rh8 121.2(4) . . ?
C164 C165 C161 109.7(5) . . ?
C164 C165 C170 126.7(6) . . ?
C161 C165 C170 123.5(6) . . ?
C164 C165 Rh8 71.4(3) . . ?
C161 C165 Rh8 71.7(3) . . ?
C170 C165 Rh8 126.8(4) . . ?
C161 C166 H16D 109.5 . . ?
C161 C166 H16E 109.5 . . ?
H16D C166 H16E 109.5 . . ?
C161 C166 H16F 109.5 . . ?
H16D C166 H16F 109.5 . . ?
H16E C166 H16F 109.5 . . ?
C162 C167 H16G 109.5 . . ?
C162 C167 H16H 109.5 . . ?
H16G C167 H16H 109.5 . . ?
C162 C167 H16I 109.5 . . ?
H16G C167 H16I 109.5 . . ?
H16H C167 H16I 109.5 . . ?
C163 C168 H16J 109.5 . . ?
C163 C168 H16K 109.5 . . ?
H16J C168 H16K 109.5 . . ?
C163 C168 H16L 109.5 . . ?
H16J C168 H16L 109.5 . . ?
H16K C168 H16L 109.5 . . ?
C164 C169 H16M 109.5 . . ?
C164 C169 H16N 109.5 . . ?
H16M C169 H16N 109.5 . . ?
C164 C169 H16O 109.5 . . ?
H16M C169 H16O 109.5 . . ?
H16N C169 H16O 109.5 . . ?
C165 C170 H17A 109.5 . . ?
C165 C170 H17B 109.5 . . ?
H17A C170 H17B 109.5 . . ?
C165 C170 H17C 109.5 . . ?
H17A C170 H17C 109.5 . . ?
H17B C170 H17C 109.5 . . ?
C181 C171 C172 112.4(10) . . ?
C181 C171 C180 113.6(11) . . ?
C172 C171 C180 133.9(11) . . ?
C181 C171 Rh7 71.5(6) . . ?
C172 C171 Rh7 70.2(5) . . ?
C180 C171 Rh7 123.3(7) . . ?
C171 C172 C179 121.4(11) . . ?
C171 C172 C174 101.4(8) . . ?
C179 C172 C174 137.2(11) . . ?
C171 C172 Rh7 70.9(5) . . ?
C179 C172 Rh7 121.5(7) . . ?
C174 C172 Rh7 69.7(4) . . ?
C175 C174 C177 127.5(11) . . ?
C175 C174 C172 102.5(8) . . ?
C177 C174 C172 129.8(10) . . ?
C175 C174 Rh7 70.3(5) . . ?
C177 C174 Rh7 120.5(7) . . ?
C172 C174 Rh7 68.2(4) . . ?
C181 C175 C174 114.8(10) . . ?
C181 C175 C176 112.1(11) . . ?
C174 C175 C176 133.0(11) . . ?
C181 C175 Rh7 72.4(6) . . ?
C174 C175 Rh7 71.7(5) . . ?
C176 C175 Rh7 120.6(7) . . ?
C175 C176 H17D 109.5 . . ?
C175 C176 H17E 109.5 . . ?
H17D C176 H17E 109.5 . . ?
C175 C176 H17F 109.5 . . ?
H17D C176 H17F 109.5 . . ?
H17E C176 H17F 109.5 . . ?
C174 C177 H17G 109.5 . . ?
C174 C177 H17H 109.5 . . ?
H17G C177 H17H 109.5 . . ?
C174 C177 H17I 109.5 . . ?
H17G C177 H17I 109.5 . . ?
H17H C177 H17I 109.5 . . ?
C172 C179 H17J 109.5 . . ?
C172 C179 H17K 109.5 . . ?
H17J C179 H17K 109.5 . . ?
C172 C179 H17L 109.5 . . ?
H17J C179 H17L 109.5 . . ?
H17K C179 H17L 109.5 . . ?
C171 C180 H18G 109.5 . . ?
C171 C180 H18H 109.5 . . ?
H18G C180 H18H 109.5 . . ?
C171 C180 H18I 109.4 . . ?
H18G C180 H18I 109.5 . . ?
H18H C180 H18I 109.5 . . ?
C175 C181 C171 108.7(11) . . ?
C175 C181 C182 126.9(12) . . ?
C171 C181 C182 124.3(12) . . ?
C175 C181 Rh7 72.7(6) . . ?
C171 C181 Rh7 72.2(6) . . ?
C182 C181 Rh7 124.1(8) . . ?
C181 C182 H18J 109.5 . . ?
C181 C182 H18K 109.5 . . ?
H18J C182 H18K 109.5 . . ?
C181 C182 H18L 109.5 . . ?
H18J C182 H18L 109.5 . . ?
H18K C182 H18L 109.5 . . ?
C197 C183 H18V 109.5 . . ?
C197 C183 H18W 109.5 . . ?
H18V C183 H18W 109.5 . . ?
C197 C183 H18X 109.5 . . ?
H18V C183 H18X 109.5 . . ?
H18W C183 H18X 109.5 . . ?
C191 C184 H18S 109.5 . . ?
C191 C184 H18T 109.5 . . ?
H18S C184 H18T 109.5 . . ?
C191 C184 H18U 109.5 . . ?
H18S C184 H18U 109.5 . . ?
H18T C184 H18U 109.5 . . ?
C190 C185 H18M 109.5 . . ?
C190 C185 H18N 109.5 . . ?
H18M C185 H18N 109.5 . . ?
C190 C185 H18O 109.5 . . ?
H18M C185 H18O 109.5 . . ?
H18N C185 H18O 109.5 . . ?
C192 C186 H18D 109.5 . . ?
C192 C186 H18E 109.5 . . ?
H18D C186 H18E 109.5 . . ?
C192 C186 H18F 109.5 . . ?
H18D C186 H18F 109.5 . . ?
H18E C186 H18F 109.5 . . ?
C193 C187 H18P 109.5 . . ?
C193 C187 H18Q 109.5 . . ?
H18P C187 H18Q 109.5 . . ?
C193 C187 H18R 109.5 . . ?
H18P C187 H18R 109.5 . . ?
H18Q C187 H18R 109.5 . . ?
C189 C188 H18A 109.5 . . ?
C189 C188 H18B 109.5 . . ?
H18A C188 H18B 109.5 . . ?
C189 C188 H18C 109.5 . . ?
H18A C188 H18C 109.5 . . ?
H18B C188 H18C 109.5 . . ?
C193 C189 C190 107.7(5) . . ?
C193 C189 C188 125.9(5) . . ?
C190 C189 C188 126.3(5) . . ?
C193 C189 Rh5 69.1(3) . . ?
C190 C189 Rh5 70.1(3) . . ?
C188 C189 Rh5 122.8(4) . . ?
C191 C190 C189 108.6(5) . . ?
C191 C190 C185 126.7(5) . . ?
C189 C190 C185 124.6(6) . . ?
C191 C190 Rh5 71.1(3) . . ?
C189 C190 Rh5 70.6(3) . . ?
C185 C190 Rh5 127.0(4) . . ?
C190 C191 C192 109.1(5) . . ?
C190 C191 C184 125.9(6) . . ?
C192 C191 C184 125.0(6) . . ?
C190 C191 Rh5 70.6(3) . . ?
C192 C191 Rh5 70.3(3) . . ?
C184 C191 Rh5 123.9(4) . . ?
C191 C192 C193 106.7(6) . . ?
C191 C192 C186 128.8(7) . . ?
C193 C192 C186 124.5(6) . . ?
C191 C192 Rh5 70.6(4) . . ?
C193 C192 Rh5 68.8(4) . . ?
C186 C192 Rh5 127.4(5) . . ?
C189 C193 C192 107.8(5) . . ?
C189 C193 C187 124.8(6) . . ?
C192 C193 C187 127.1(7) . . ?
C189 C193 Rh5 71.7(3) . . ?
C192 C193 Rh5 71.0(3) . . ?
C187 C193 Rh5 127.5(4) . . ?
C195 C194 C198 107.5(6) . . ?
C195 C194 C199 127.7(8) . . ?
C198 C194 C199 124.7(7) . . ?
C195 C194 Rh6 71.6(4) . . ?
C198 C194 Rh6 69.4(4) . . ?
C199 C194 Rh6 127.7(5) . . ?
C194 C195 C196 107.8(6) . . ?
C194 C195 C200 125.4(7) . . ?
C196 C195 C200 126.8(7) . . ?
C194 C195 Rh6 69.9(4) . . ?
C196 C195 Rh6 70.0(4) . . ?
C200 C195 Rh6 124.1(5) . . ?
C197 C196 C195 108.3(5) . . ?
C197 C196 C201 128.6(7) . . ?
C195 C196 C201 123.0(8) . . ?
C197 C196 Rh6 71.0(4) . . ?
C195 C196 Rh6 70.9(3) . . ?
C201 C196 Rh6 126.6(5) . . ?
C196 C197 C198 108.7(6) . . ?
C196 C197 C183 124.1(7) . . ?
C198 C197 C183 127.2(8) . . ?
C196 C197 Rh6 71.1(4) . . ?
C198 C197 Rh6 69.3(4) . . ?
C183 C197 Rh6 124.5(6) . . ?
C197 C198 C194 107.7(6) . . ?
C197 C198 C202 126.8(8) . . ?
C194 C198 C202 125.3(8) . . ?
C197 C198 Rh6 71.7(4) . . ?
C194 C198 Rh6 71.0(4) . . ?
C202 C198 Rh6 126.2(6) . . ?
C194 C199 H19A 109.5 . . ?
C194 C199 H19B 109.5 . . ?
H19A C199 H19B 109.5 . . ?
C194 C199 H19C 109.5 . . ?
H19A C199 H19C 109.5 . . ?
H19B C199 H19C 109.5 . . ?
C195 C200 H20G 109.5 . . ?
C195 C200 H20H 109.5 . . ?
H20G C200 H20H 109.5 . . ?
C195 C200 H20I 109.5 . . ?
H20G C200 H20I 109.5 . . ?
H20H C200 H20I 109.5 . . ?
C196 C201 H20A 109.5 . . ?
C196 C201 H20B 109.5 . . ?
H20A C201 H20B 109.5 . . ?
C196 C201 H20C 109.5 . . ?
H20A C201 H20C 109.5 . . ?
H20B C201 H20C 109.5 . . ?
C198 C202 H20D 109.5 . . ?
C198 C202 H20E 109.5 . . ?
H20D C202 H20E 109.5 . . ?
C198 C202 H20F 109.5 . . ?
H20D C202 H20F 109.5 . . ?
H20E C202 H20F 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N7 2.119(4) . ?
Rh1 C152 2.124(5) . ?
Rh1 C151 2.126(5) . ?
Rh1 C153 2.144(5) . ?
Rh1 C155 2.145(5) . ?
Rh1 C154 2.148(4) . ?
Rh1 O8 2.150(3) . ?
Rh1 O7 2.158(4) . ?
Rh2 C143 2.116(8) . ?
Rh2 N3 2.124(4) . ?
Rh2 C141 2.127(8) . ?
Rh2 C145 2.135(7) . ?
Rh2 C144 2.137(7) . ?
Rh2 O5 2.139(4) . ?
Rh2 O6 2.143(4) . ?
Rh2 C142 2.146(7) . ?
Rh3 N4 2.106(4) . ?
Rh3 C134 2.112(6) . ?
Rh3 C135 2.121(7) . ?
Rh3 C132 2.126(6) . ?
Rh3 C131 2.130(6) . ?
Rh3 O10 2.131(3) . ?
Rh3 C133 2.149(6) . ?
Rh3 O9 2.154(3) . ?
Rh4 N6 2.119(4) . ?
Rh4 C124 2.128(7) . ?
Rh4 C121 2.130(7) . ?
Rh4 C125 2.134(7) . ?
Rh4 C123 2.137(6) . ?
Rh4 O12 2.142(4) . ?
Rh4 C122 2.144(6) . ?
Rh4 O11 2.163(4) . ?
Rh5 C193 2.112(6) . ?
Rh5 N2 2.130(4) . ?
Rh5 O13 2.133(4) . ?
Rh5 C190 2.139(5) . ?
Rh5 C192 2.142(7) . ?
Rh5 C191 2.146(5) . ?
Rh5 C189 2.147(5) . ?
Rh5 O14 2.164(4) . ?
Rh6 C198 2.106(7) . ?
Rh6 N5 2.118(4) . ?
Rh6 C194 2.127(7) . ?
Rh6 O15 2.135(4) . ?
Rh6 C197 2.137(6) . ?
Rh6 C196 2.138(6) . ?
Rh6 C195 2.149(7) . ?
Rh6 O16 2.150(4) . ?
Rh7 C172 2.095(7) . ?
Rh7 C181 2.095(10) . ?
Rh7 C175 2.098(9) . ?
Rh7 C171 2.103(9) . ?
Rh7 C174 2.117(7) . ?
Rh7 N1 2.121(4) . ?
Rh7 O2 2.140(3) . ?
Rh7 O1 2.158(3) . ?
Rh8 C165 2.107(5) . ?
Rh8 C164 2.119(5) . ?
Rh8 C163 2.124(6) . ?
Rh8 N8 2.125(4) . ?
Rh8 O3 2.132(3) . ?
Rh8 C161 2.134(6) . ?
Rh8 C162 2.137(6) . ?
Rh8 O4 2.165(3) . ?
S1S O2S 1.416(5) . ?
S1S O1S 1.420(5) . ?
S1S O3S 1.444(5) . ?
S1S C1S 1.816(7) . ?
S2S O4S 1.422(5) . ?
S2S O6S 1.423(6) . ?
S2S O5S 1.427(6) . ?
S2S C2S 1.803(8) . ?
S3S O8S 1.348(8) . ?
S3S O7S 1.376(7) . ?
S3S O9S 1.425(7) . ?
S3S C3S 1.813(14) . ?
S4S O11S 1.431(7) . ?
S4S O12S 1.431(7) . ?
S4S O10S 1.438(6) . ?
S4S C4S 1.727(12) . ?
S5S O15S 1.416(9) . ?
S5S O13S 1.430(10) . ?
S5S O14S 1.436(8) . ?
S5S C5S 1.734(11) . ?
S6S O18S 1.411(7) . ?
S6S O16S 1.415(5) . ?
S6S O17S 1.416(5) . ?
S6S C6S 1.836(9) . ?
S7S O19S 1.398(10) . ?
S7S O21S 1.435(11) . ?
S7S O20S 1.459(13) . ?
S7S C7S 1.71(2) . ?
S8S O23S 1.330(8) . ?
S8S O24S 1.342(10) . ?
S8S O22S 1.463(10) . ?
S8S C8S 1.751(15) . ?
F1S C1S 1.338(9) . ?
F2S C1S 1.318(8) . ?
F3S C1S 1.324(8) . ?
F4S C2S 1.337(12) . ?
F5S C2S 1.352(13) . ?
F6S C2S 1.296(9) . ?
F7S C3S 1.397(14) . ?
F8S C3S 1.232(12) . ?
F9S C3S 1.354(14) . ?
F10S C4S 1.395(13) . ?
F11S C4S 1.376(12) . ?
F12S C4S 1.301(12) . ?
F13S C5S 1.333(18) . ?
F14S C5S 1.36(2) . ?
F15S C5S 1.304(14) . ?
F16S C6S 1.297(11) . ?
F17S C6S 1.323(10) . ?
F18S C6S 1.328(9) . ?
F19S C7S 1.32(2) . ?
F20S C7S 1.29(2) . ?
F21S C7S 1.27(2) . ?
F22S C8S 1.365(15) . ?
F23S C8S 1.355(17) . ?
F24S C8S 1.156(15) . ?
O1 C97 1.257(6) . ?
O2 C98 1.260(6) . ?
O3 C98 1.258(6) . ?
O4 C97 1.256(6) . ?
O5 C100 1.257(6) . ?
O6 C99 1.253(6) . ?
O7 C100 1.248(7) . ?
O8 C99 1.249(6) . ?
O9 C94 1.265(6) . ?
O10 C93 1.241(6) . ?
O11 C94 1.246(6) . ?
O12 C93 1.263(6) . ?
O13 C96 1.252(6) . ?
O14 C95 1.262(6) . ?
O15 C96 1.252(6) . ?
O16 C95 1.257(6) . ?
O22S O24S 1.736(17) . ?
N1 C48 1.326(6) . ?
N1 C47 1.352(6) . ?
N2 C68 1.333(8) . ?
N2 C70 1.354(6) . ?
N3 C80 1.333(8) . ?
N3 C79 1.336(7) . ?
N4 C92 1.331(6) . ?
N4 C90 1.346(7) . ?
N5 C20 1.325(8) . ?
N5 C18 1.342(7) . ?
N6 C44 1.327(6) . ?
N6 C45 1.332(6) . ?
N7 C33 1.345(7) . ?
N7 C34 1.356(6) . ?
N8 C1 1.328(6) . ?
N8 C5 1.345(6) . ?
C1 C2 1.392(7) . ?
C1 H1 0.9500 . ?
C2 C3 1.398(6) . ?
C2 H2 0.9500 . ?
C3 C4 1.392(6) . ?
C3 C6 1.471(7) . ?
C4 C5 1.355(7) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.383(7) . ?
C6 C9 1.398(7) . ?
C7 C8 1.384(7) . ?
C7 H7 0.9500 . ?
C8 C23 1.397(7) . ?
C8 H8 0.9500 . ?
C9 C10 1.377(7) . ?
C9 H9 0.9500 . ?
C10 C23 1.388(7) . ?
C10 H10 0.9500 . ?
C11 C12 1.379(6) . ?
C11 C24 1.407(7) . ?
C11 H11 0.9500 . ?
C12 C13 1.383(7) . ?
C12 H12 0.9500 . ?
C13 C14 1.386(8) . ?
C13 C16 1.485(6) . ?
C14 C15 1.380(7) . ?
C14 H14 0.9500 . ?
C15 C24 1.396(7) . ?
C15 H15 0.9500 . ?
C16 C17 1.392(8) . ?
C16 C19 1.402(7) . ?
C17 C18 1.380(7) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C20 1.378(7) . ?
C19 H19 0.9500 . ?
C20 H20 0.9500 . ?
C21 C22 1.356(7) . ?
C21 C24 1.495(6) . ?
C21 C23 1.497(6) . ?
C22 C36 1.479(6) . ?
C22 C25 1.492(6) . ?
C25 C30 1.393(7) . ?
C25 C26 1.407(7) . ?
C26 C27 1.373(6) . ?
C26 H26 0.9500 . ?
C27 C28 1.383(7) . ?
C27 H27 0.9500 . ?
C28 C29 1.395(7) . ?
C28 C31 1.487(6) . ?
C29 C30 1.393(6) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C35 1.385(7) . ?
C31 C32 1.392(7) . ?
C32 C33 1.391(7) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
C34 C35 1.370(6) . ?
C34 H34 0.9500 . ?
C35 H35 0.9500 . ?
C36 C37 1.395(7) . ?
C36 C41 1.402(6) . ?
C37 C38 1.384(7) . ?
C37 H37 0.9500 . ?
C38 C39 1.412(6) . ?
C38 H38 0.9500 . ?
C39 C40 1.386(7) . ?
C39 C42 1.468(6) . ?
C40 C41 1.370(7) . ?
C40 H40 0.9500 . ?
C41 H41 0.9500 . ?
C42 C43 1.397(6) . ?
C42 C46 1.404(6) . ?
C43 C44 1.373(7) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 C46 1.387(7) . ?
C45 H45 0.9500 . ?
C46 H46 0.9500 . ?
C47 C50 1.372(8) . ?
C47 H47 0.9500 . ?
C48 C49 1.397(7) . ?
C48 H48 0.9500 . ?
C49 C51 1.387(7) . ?
C49 H49 0.9500 . ?
C50 C51 1.409(6) . ?
C50 H50 0.9500 . ?
C51 C52 1.477(7) . ?
C52 C53 1.385(7) . ?
C52 C57 1.406(7) . ?
C53 C54 1.373(7) . ?
C53 H53 0.9500 . ?
C54 C55 1.385(7) . ?
C54 H54 0.9500 . ?
C55 C56 1.399(7) . ?
C55 C58 1.502(7) . ?
C56 C57 1.378(7) . ?
C56 H56 0.9500 . ?
C57 H57 0.9500 . ?
C58 C59 1.357(7) . ?
C58 C60 1.498(6) . ?
C59 C71 1.485(6) . ?
C59 C82 1.496(7) . ?
C60 C61 1.388(7) . ?
C60 C65 1.399(7) . ?
C61 C62 1.381(7) . ?
C61 H61 0.9500 . ?
C62 C63 1.383(8) . ?
C62 H62 0.9500 . ?
C63 C64 1.408(7) . ?
C63 C66 1.487(6) . ?
C64 C65 1.386(6) . ?
C64 H64 0.9500 . ?
C65 H65 0.9500 . ?
C66 C69 1.393(8) . ?
C66 C67 1.394(7) . ?
C67 C68 1.375(7) . ?
C67 H67 0.9500 . ?
C68 H68 0.9500 . ?
C69 C70 1.374(7) . ?
C69 H69 0.9500 . ?
C70 H70 0.9500 . ?
C71 C72 1.389(7) . ?
C71 C76 1.401(7) . ?
C72 C73 1.380(7) . ?
C72 H72 0.9500 . ?
C73 C74 1.407(7) . ?
C73 H73 0.9500 . ?
C74 C75 1.375(7) . ?
C74 C77 1.481(6) . ?
C75 C76 1.408(6) . ?
C75 H75 0.9500 . ?
C76 H76 0.9500 . ?
C77 C78 1.381(8) . ?
C77 C81 1.408(7) . ?
C78 C79 1.384(7) . ?
C78 H78 0.9500 . ?
C79 H79 0.9500 . ?
C80 C81 1.365(8) . ?
C80 H80 0.9500 . ?
C81 H81 0.9500 . ?
C82 C87 1.391(7) . ?
C82 C83 1.400(7) . ?
C83 C84 1.379(7) . ?
C83 H83 0.9500 . ?
C84 C85 1.400(8) . ?
C84 H84 0.9500 . ?
C85 C86 1.386(8) . ?
C85 C88 1.459(8) . ?
C86 C87 1.390(8) . ?
C86 H86 0.9500 . ?
C87 H87 0.9500 . ?
C88 C91 1.387(7) . ?
C88 C89 1.389(7) . ?
C89 C90 1.377(8) . ?
C89 H89 0.9500 . ?
C90 H90 0.9500 . ?
C91 C92 1.379(8) . ?
C91 H91 0.9500 . ?
C92 H92 0.9500 . ?
C93 C94 1.548(6) . ?
C95 C96 1.527(7) . ?
C97 C98 1.536(6) . ?
C99 C100 1.544(7) . ?
C121 C125 1.413(11) . ?
C121 C122 1.435(10) . ?
C121 C128 1.499(10) . ?
C122 C123 1.421(9) . ?
C122 C129 1.499(10) . ?
C123 C124 1.463(10) . ?
C123 C130 1.493(10) . ?
C124 C125 1.381(10) . ?
C124 C126 1.529(11) . ?
C125 C127 1.501(11) . ?
C126 H12A 0.9800 . ?
C126 H12B 0.9800 . ?
C126 H12C 0.9800 . ?
C127 H12D 0.9800 . ?
C127 H12E 0.9800 . ?
C127 H12F 0.9800 . ?
C128 H12G 0.9800 . ?
C128 H12H 0.9800 . ?
C128 H12I 0.9800 . ?
C129 H12J 0.9800 . ?
C129 H12K 0.9800 . ?
C129 H12L 0.9800 . ?
C130 H13A 0.9800 . ?
C130 H13B 0.9800 . ?
C130 H13C 0.9800 . ?
C131 C135 1.400(10) . ?
C131 C132 1.452(10) . ?
C131 C138 1.501(8) . ?
C132 C133 1.433(9) . ?
C132 C139 1.530(11) . ?
C133 C134 1.460(11) . ?
C133 C140 1.495(9) . ?
C134 C135 1.435(8) . ?
C134 C136 1.507(10) . ?
C135 C137 1.496(11) . ?
C136 H13D 0.9800 . ?
C136 H13E 0.9800 . ?
C136 H13F 0.9800 . ?
C137 H13G 0.9800 . ?
C137 H13H 0.9800 . ?
C137 H13I 0.9800 . ?
C138 H13J 0.9800 . ?
C138 H13K 0.9800 . ?
C138 H13L 0.9800 . ?
C139 H13M 0.9800 . ?
C139 H13N 0.9800 . ?
C139 H13O 0.9800 . ?
C140 H14A 0.9800 . ?
C140 H14B 0.9800 . ?
C140 H14C 0.9800 . ?
C141 C142 1.375(12) . ?
C141 C146 1.379(14) . ?
C141 C145 1.519(12) . ?
C142 C143 1.352(13) . ?
C142 C147 1.489(11) . ?
C143 C144 1.293(12) . ?
C143 C148 1.576(15) . ?
C144 C145 1.409(14) . ?
C144 C149 1.519(14) . ?
C145 C150 1.475(12) . ?
C146 H14D 0.9500 . ?
C146 H14E 0.9500 . ?
C147 H14F 0.9800 . ?
C147 H14G 0.9800 . ?
C147 H14H 0.9800 . ?
C148 H14I 0.9800 . ?
C148 H14J 0.9800 . ?
C148 H14K 0.9800 . ?
C149 H14L 0.9800 . ?
C149 H14M 0.9800 . ?
C149 H14N 0.9800 . ?
C150 H15A 0.9800 . ?
C150 H15B 0.9800 . ?
C150 H15C 0.9800 . ?
C151 C155 1.429(7) . ?
C151 C152 1.441(8) . ?
C151 C156 1.492(7) . ?
C152 C153 1.440(7) . ?
C152 C157 1.497(8) . ?
C153 C154 1.434(8) . ?
C153 C158 1.486(8) . ?
C154 C155 1.437(7) . ?
C154 C159 1.494(6) . ?
C155 C160 1.486(8) . ?
C156 H15D 0.9800 . ?
C156 H15E 0.9800 . ?
C156 H15F 0.9800 . ?
C157 H15G 0.9800 . ?
C157 H15H 0.9800 . ?
C157 H15I 0.9800 . ?
C158 H15J 0.9800 . ?
C158 H15K 0.9800 . ?
C158 H15L 0.9800 . ?
C159 H15M 0.9800 . ?
C159 H15N 0.9800 . ?
C159 H15O 0.9800 . ?
C160 H16A 0.9800 . ?
C160 H16B 0.9800 . ?
C160 H16C 0.9800 . ?
C161 C165 1.400(7) . ?
C161 C162 1.417(10) . ?
C161 C166 1.512(10) . ?
C162 C163 1.428(11) . ?
C162 C167 1.499(9) . ?
C163 C164 1.423(9) . ?
C163 C168 1.488(11) . ?
C164 C165 1.379(8) . ?
C164 C169 1.499(9) . ?
C165 C170 1.500(9) . ?
C166 H16D 0.9800 . ?
C166 H16E 0.9800 . ?
C166 H16F 0.9800 . ?
C167 H16G 0.9800 . ?
C167 H16H 0.9800 . ?
C167 H16I 0.9800 . ?
C168 H16J 0.9800 . ?
C168 H16K 0.9800 . ?
C168 H16L 0.9800 . ?
C169 H16M 0.9800 . ?
C169 H16N 0.9800 . ?
C169 H16O 0.9800 . ?
C170 H17A 0.9800 . ?
C170 H17B 0.9800 . ?
C170 H17C 0.9800 . ?
C171 C181 1.309(12) . ?
C171 C172 1.399(12) . ?
C171 C180 1.549(16) . ?
C172 C179 1.454(14) . ?
C172 C174 1.512(12) . ?
C174 C175 1.372(12) . ?
C174 C177 1.513(14) . ?
C175 C181 1.258(12) . ?
C175 C176 1.571(15) . ?
C176 H17D 0.9800 . ?
C176 H17E 0.9800 . ?
C176 H17F 0.9800 . ?
C177 H17G 0.9800 . ?
C177 H17H 0.9800 . ?
C177 H17I 0.9800 . ?
C179 H17J 0.9800 . ?
C179 H17K 0.9800 . ?
C179 H17L 0.9800 . ?
C180 H18G 0.9800 . ?
C180 H18H 0.9800 . ?
C180 H18I 0.9800 . ?
C181 C182 1.564(16) . ?
C182 H18J 0.9800 . ?
C182 H18K 0.9800 . ?
C182 H18L 0.9800 . ?
C183 C197 1.504(11) . ?
C183 H18V 0.9800 . ?
C183 H18W 0.9800 . ?
C183 H18X 0.9800 . ?
C184 C191 1.487(9) . ?
C184 H18S 0.9800 . ?
C184 H18T 0.9800 . ?
C184 H18U 0.9800 . ?
C185 C190 1.503(8) . ?
C185 H18M 0.9800 . ?
C185 H18N 0.9800 . ?
C185 H18O 0.9800 . ?
C186 C192 1.491(10) . ?
C186 H18D 0.9800 . ?
C186 H18E 0.9800 . ?
C186 H18F 0.9800 . ?
C187 C193 1.498(8) . ?
C187 H18P 0.9800 . ?
C187 H18Q 0.9800 . ?
C187 H18R 0.9800 . ?
C188 C189 1.466(9) . ?
C188 H18A 0.9800 . ?
C188 H18B 0.9800 . ?
C188 H18C 0.9800 . ?
C189 C193 1.428(9) . ?
C189 C190 1.441(7) . ?
C190 C191 1.406(9) . ?
C191 C192 1.434(8) . ?
C192 C193 1.463(10) . ?
C194 C195 1.410(9) . ?
C194 C198 1.432(11) . ?
C194 C199 1.496(10) . ?
C195 C196 1.435(10) . ?
C195 C200 1.497(12) . ?
C196 C197 1.387(11) . ?
C196 C201 1.489(9) . ?
C197 C198 1.418(9) . ?
C198 C202 1.491(11) . ?
C199 H19A 0.9800 . ?
C199 H19B 0.9800 . ?
C199 H19C 0.9800 . ?
C200 H20G 0.9800 . ?
C200 H20H 0.9800 . ?
C200 H20I 0.9800 . ?
C201 H20A 0.9800 . ?
C201 H20B 0.9800 . ?
C201 H20C 0.9800 . ?
C202 H20D 0.9800 . ?
C202 H20E 0.9800 . ?
C202 H20F 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O23S S8S O22S O24S -148.6(10) . . . . ?
C8S S8S O22S O24S 88.8(9) . . . . ?
O23S S8S O24S O22S 127.8(13) . . . . ?
C8S S8S O24S O22S -110.5(7) . . . . ?
C5 N8 C1 C2 1.3(8) . . . . ?
Rh8 N8 C1 C2 -170.9(4) . . . . ?
N8 C1 C2 C3 -1.2(8) . . . . ?
O2S S1S C1S F2S 60.5(7) . . . . ?
O1S S1S C1S F2S -60.3(6) . . . . ?
O3S S1S C1S F2S 178.9(6) . . . . ?
O2S S1S C1S F3S -179.0(6) . . . . ?
O1S S1S C1S F3S 60.2(6) . . . . ?
O3S S1S C1S F3S -60.7(6) . . . . ?
O2S S1S C1S F1S -60.7(7) . . . . ?
O1S S1S C1S F1S 178.5(6) . . . . ?
O3S S1S C1S F1S 57.6(7) . . . . ?
C1 C2 C3 C4 -1.4(8) . . . . ?
C1 C2 C3 C6 175.8(5) . . . . ?
O4S S2S C2S F6S -178.2(8) . . . . ?
O6S S2S C2S F6S 58.7(10) . . . . ?
O5S S2S C2S F6S -59.8(9) . . . . ?
O4S S2S C2S F4S -52.6(9) . . . . ?
O6S S2S C2S F4S -175.8(7) . . . . ?
O5S S2S C2S F4S 65.8(8) . . . . ?
O4S S2S C2S F5S 64.1(7) . . . . ?
O6S S2S C2S F5S -59.1(7) . . . . ?
O5S S2S C2S F5S -177.5(6) . . . . ?
C2 C3 C4 C5 3.8(8) . . . . ?
C6 C3 C4 C5 -173.5(5) . . . . ?
O8S S3S C3S F8S -67.3(12) . . . . ?
O7S S3S C3S F8S 172.5(12) . . . . ?
O9S S3S C3S F8S 52.3(12) . . . . ?
O8S S3S C3S F9S 53.8(10) . . . . ?
O7S S3S C3S F9S -66.4(10) . . . . ?
O9S S3S C3S F9S 173.4(8) . . . . ?
O8S S3S C3S F7S 174.5(9) . . . . ?
O7S S3S C3S F7S 54.3(10) . . . . ?
O9S S3S C3S F7S -65.9(9) . . . . ?
C1 N8 C5 C4 1.2(8) . . . . ?
Rh8 N8 C5 C4 173.8(5) . . . . ?
C3 C4 C5 N8 -3.9(9) . . . . ?
O11S S4S C4S F12S -62.5(9) . . . . ?
O12S S4S C4S F12S 56.5(9) . . . . ?
O10S S4S C4S F12S -179.6(8) . . . . ?
O11S S4S C4S F11S 177.0(8) . . . . ?
O12S S4S C4S F11S -64.1(10) . . . . ?
O10S S4S C4S F11S 59.9(9) . . . . ?
O11S S4S C4S F10S 59.6(8) . . . . ?
O12S S4S C4S F10S 178.5(8) . . . . ?
O10S S4S C4S F10S -57.5(8) . . . . ?
C4 C3 C6 C7 146.2(5) . . . . ?
C2 C3 C6 C7 -30.9(8) . . . . ?
C4 C3 C6 C9 -30.7(8) . . . . ?
C2 C3 C6 C9 152.2(5) . . . . ?
O15S S5S C5S F15S -53.5(16) . . . . ?
O13S S5S C5S F15S 63.5(16) . . . . ?
O14S S5S C5S F15S -173.7(14) . . . . ?
O15S S5S C5S F13S -179.4(13) . . . . ?
O13S S5S C5S F13S -62.4(15) . . . . ?
O14S S5S C5S F13S 60.5(16) . . . . ?
O15S S5S C5S F14S 63.6(12) . . . . ?
O13S S5S C5S F14S -179.4(11) . . . . ?
O14S S5S C5S F14S -56.5(12) . . . . ?
C9 C6 C7 C8 2.5(8) . . . . ?
C3 C6 C7 C8 -174.5(5) . . . . ?
O18S S6S C6S F16S -176.4(7) . . . . ?
O16S S6S C6S F16S 61.4(7) . . . . ?
O17S S6S C6S F16S -58.0(7) . . . . ?
O18S S6S C6S F17S 63.4(7) . . . . ?
O16S S6S C6S F17S -58.7(7) . . . . ?
O17S S6S C6S F17S -178.1(6) . . . . ?
O18S S6S C6S F18S -50.6(7) . . . . ?
O16S S6S C6S F18S -172.7(7) . . . . ?
O17S S6S C6S F18S 67.9(7) . . . . ?
C6 C7 C8 C23 -1.5(8) . . . . ?
O19S S7S C7S F21S -65.5(14) . . . . ?
O21S S7S C7S F21S 174.8(13) . . . . ?
O20S S7S C7S F21S 50.9(16) . . . . ?
O19S S7S C7S F20S -177.7(15) . . . . ?
O21S S7S C7S F20S 62.6(16) . . . . ?
O20S S7S C7S F20S -61.2(18) . . . . ?
O19S S7S C7S F19S 66.5(18) . . . . ?
O21S S7S C7S F19S -53.2(18) . . . . ?
O20S S7S C7S F19S -177.0(17) . . . . ?
C7 C6 C9 C10 -1.3(8) . . . . ?
C3 C6 C9 C10 175.7(5) . . . . ?
O23S S8S C8S F24S 55.6(16) . . . . ?
O24S S8S C8S F24S -95.0(16) . . . . ?
O22S S8S C8S F24S -171.8(14) . . . . ?
O23S S8S C8S F23S -66.3(11) . . . . ?
O24S S8S C8S F23S 143.0(11) . . . . ?
O22S S8S C8S F23S 66.3(12) . . . . ?
O23S S8S C8S F22S -178.8(11) . . . . ?
O24S S8S C8S F22S 30.6(13) . . . . ?
O22S S8S C8S F22S -46.2(14) . . . . ?
C6 C9 C10 C23 -0.8(8) . . . . ?
C24 C11 C12 C13 -3.2(8) . . . . ?
C11 C12 C13 C14 0.6(8) . . . . ?
C11 C12 C13 C16 179.1(5) . . . . ?
C12 C13 C14 C15 0.9(8) . . . . ?
C16 C13 C14 C15 -177.6(5) . . . . ?
C13 C14 C15 C24 0.0(8) . . . . ?
C12 C13 C16 C17 -40.8(8) . . . . ?
C14 C13 C16 C17 137.7(6) . . . . ?
C12 C13 C16 C19 137.5(6) . . . . ?
C14 C13 C16 C19 -44.0(8) . . . . ?
C19 C16 C17 C18 -4.1(9) . . . . ?
C13 C16 C17 C18 174.3(5) . . . . ?
C20 N5 C18 C17 4.7(9) . . . . ?
Rh6 N5 C18 C17 -165.0(5) . . . . ?
C16 C17 C18 N5 -0.9(9) . . . . ?
C17 C16 C19 C20 5.4(8) . . . . ?
C13 C16 C19 C20 -173.1(5) . . . . ?
C18 N5 C20 C19 -3.3(9) . . . . ?
Rh6 N5 C20 C19 166.0(5) . . . . ?
C16 C19 C20 N5 -1.8(9) . . . . ?
C24 C21 C22 C36 7.6(8) . . . . ?
C23 C21 C22 C36 -169.4(5) . . . . ?
C24 C21 C22 C25 -176.3(5) . . . . ?
C23 C21 C22 C25 6.8(8) . . . . ?
C9 C10 C23 C8 1.8(8) . . . . ?
C9 C10 C23 C21 179.3(5) . . . . ?
C7 C8 C23 C10 -0.6(8) . . . . ?
C7 C8 C23 C21 -178.2(5) . . . . ?
C22 C21 C23 C10 43.6(8) . . . . ?
C24 C21 C23 C10 -133.6(5) . . . . ?
C22 C21 C23 C8 -138.9(5) . . . . ?
C24 C21 C23 C8 43.9(7) . . . . ?
C14 C15 C24 C11 -2.5(7) . . . . ?
C14 C15 C24 C21 175.7(5) . . . . ?
C12 C11 C24 C15 4.0(7) . . . . ?
C12 C11 C24 C21 -174.1(5) . . . . ?
C22 C21 C24 C15 -133.2(5) . . . . ?
C23 C21 C24 C15 44.0(6) . . . . ?
C22 C21 C24 C11 44.8(7) . . . . ?
C23 C21 C24 C11 -137.9(5) . . . . ?
C21 C22 C25 C30 44.9(8) . . . . ?
C36 C22 C25 C30 -138.6(5) . . . . ?
C21 C22 C25 C26 -136.2(5) . . . . ?
C36 C22 C25 C26 40.3(6) . . . . ?
C30 C25 C26 C27 -3.0(8) . . . . ?
C22 C25 C26 C27 178.0(5) . . . . ?
C25 C26 C27 C28 0.0(8) . . . . ?
C26 C27 C28 C29 2.0(8) . . . . ?
C26 C27 C28 C31 -177.2(5) . . . . ?
C27 C28 C29 C30 -1.0(8) . . . . ?
C31 C28 C29 C30 178.3(5) . . . . ?
C28 C29 C30 C25 -2.1(9) . . . . ?
C26 C25 C30 C29 4.0(8) . . . . ?
C22 C25 C30 C29 -177.0(5) . . . . ?
C27 C28 C31 C35 142.9(6) . . . . ?
C29 C28 C31 C35 -36.3(8) . . . . ?
C27 C28 C31 C32 -39.2(8) . . . . ?
C29 C28 C31 C32 141.6(6) . . . . ?
C35 C31 C32 C33 2.7(9) . . . . ?
C28 C31 C32 C33 -175.2(5) . . . . ?
C34 N7 C33 C32 -1.5(8) . . . . ?
Rh1 N7 C33 C32 170.3(4) . . . . ?
C31 C32 C33 N7 -1.0(9) . . . . ?
C33 N7 C34 C35 2.3(8) . . . . ?
Rh1 N7 C34 C35 -169.9(4) . . . . ?
N7 C34 C35 C31 -0.6(9) . . . . ?
C32 C31 C35 C34 -2.0(8) . . . . ?
C28 C31 C35 C34 176.0(5) . . . . ?
C21 C22 C36 C37 -135.3(5) . . . . ?
C25 C22 C36 C37 48.3(6) . . . . ?
C21 C22 C36 C41 45.3(7) . . . . ?
C25 C22 C36 C41 -131.2(5) . . . . ?
C41 C36 C37 C38 -1.1(7) . . . . ?
C22 C36 C37 C38 179.4(5) . . . . ?
C36 C37 C38 C39 -0.5(8) . . . . ?
C37 C38 C39 C40 1.3(7) . . . . ?
C37 C38 C39 C42 -177.5(5) . . . . ?
C38 C39 C40 C41 -0.4(7) . . . . ?
C42 C39 C40 C41 178.3(5) . . . . ?
C39 C40 C41 C36 -1.2(8) . . . . ?
C37 C36 C41 C40 2.0(7) . . . . ?
C22 C36 C41 C40 -178.6(5) . . . . ?
C40 C39 C42 C43 147.7(5) . . . . ?
C38 C39 C42 C43 -33.6(7) . . . . ?
C40 C39 C42 C46 -32.7(7) . . . . ?
C38 C39 C42 C46 146.0(5) . . . . ?
C46 C42 C43 C44 -1.9(8) . . . . ?
C39 C42 C43 C44 177.7(5) . . . . ?
C45 N6 C44 C43 2.4(8) . . . . ?
Rh4 N6 C44 C43 -170.4(4) . . . . ?
C42 C43 C44 N6 -0.7(9) . . . . ?
C44 N6 C45 C46 -1.3(8) . . . . ?
Rh4 N6 C45 C46 171.4(4) . . . . ?
N6 C45 C46 C42 -1.3(9) . . . . ?
C43 C42 C46 C45 2.9(8) . . . . ?
C39 C42 C46 C45 -176.8(5) . . . . ?
C48 N1 C47 C50 1.3(9) . . . . ?
Rh7 N1 C47 C50 -174.5(5) . . . . ?
C47 N1 C48 C49 -0.6(9) . . . . ?
Rh7 N1 C48 C49 175.2(4) . . . . ?
N1 C48 C49 C51 -1.2(9) . . . . ?
N1 C47 C50 C51 -0.2(9) . . . . ?
C48 C49 C51 C50 2.2(8) . . . . ?
C48 C49 C51 C52 -176.5(5) . . . . ?
C47 C50 C51 C49 -1.5(8) . . . . ?
C47 C50 C51 C52 177.1(5) . . . . ?
C49 C51 C52 C53 -44.7(8) . . . . ?
C50 C51 C52 C53 136.7(5) . . . . ?
C49 C51 C52 C57 134.3(5) . . . . ?
C50 C51 C52 C57 -44.3(7) . . . . ?
C57 C52 C53 C54 2.1(7) . . . . ?
C51 C52 C53 C54 -178.9(5) . . . . ?
C52 C53 C54 C55 -0.2(8) . . . . ?
C53 C54 C55 C56 -3.3(7) . . . . ?
C53 C54 C55 C58 174.8(5) . . . . ?
C54 C55 C56 C57 4.9(7) . . . . ?
C58 C55 C56 C57 -173.2(4) . . . . ?
C55 C56 C57 C52 -3.1(7) . . . . ?
C53 C52 C57 C56 -0.4(7) . . . . ?
C51 C52 C57 C56 -179.5(5) . . . . ?
C54 C55 C58 C59 -134.3(5) . . . . ?
C56 C55 C58 C59 43.8(7) . . . . ?
C54 C55 C58 C60 45.0(6) . . . . ?
C56 C55 C58 C60 -137.0(5) . . . . ?
C60 C58 C59 C71 -167.5(5) . . . . ?
C55 C58 C59 C71 11.7(8) . . . . ?
C60 C58 C59 C82 9.7(8) . . . . ?
C55 C58 C59 C82 -171.1(5) . . . . ?
C59 C58 C60 C61 -143.2(6) . . . . ?
C55 C58 C60 C61 37.5(7) . . . . ?
C59 C58 C60 C65 38.7(8) . . . . ?
C55 C58 C60 C65 -140.5(5) . . . . ?
C65 C60 C61 C62 -2.7(8) . . . . ?
C58 C60 C61 C62 179.2(5) . . . . ?
C60 C61 C62 C63 0.5(9) . . . . ?
C61 C62 C63 C64 1.9(9) . . . . ?
C61 C62 C63 C66 -176.7(5) . . . . ?
C62 C63 C64 C65 -2.1(8) . . . . ?
C66 C63 C64 C65 176.5(5) . . . . ?
C63 C64 C65 C60 -0.1(8) . . . . ?
C61 C60 C65 C64 2.5(8) . . . . ?
C58 C60 C65 C64 -179.4(5) . . . . ?
C62 C63 C66 C69 142.7(6) . . . . ?
C64 C63 C66 C69 -35.9(8) . . . . ?
C62 C63 C66 C67 -33.4(9) . . . . ?
C64 C63 C66 C67 148.0(6) . . . . ?
C69 C66 C67 C68 -1.6(9) . . . . ?
C63 C66 C67 C68 174.6(6) . . . . ?
C70 N2 C68 C67 0.1(10) . . . . ?
Rh5 N2 C68 C67 -171.8(5) . . . . ?
C66 C67 C68 N2 1.5(10) . . . . ?
C67 C66 C69 C70 0.2(9) . . . . ?
C63 C66 C69 C70 -176.1(6) . . . . ?
C68 N2 C70 C69 -1.6(9) . . . . ?
Rh5 N2 C70 C69 170.7(5) . . . . ?
C66 C69 C70 N2 1.5(10) . . . . ?
C58 C59 C71 C72 38.1(8) . . . . ?
C82 C59 C71 C72 -139.3(5) . . . . ?
C58 C59 C71 C76 -144.2(5) . . . . ?
C82 C59 C71 C76 38.3(7) . . . . ?
C76 C71 C72 C73 1.4(8) . . . . ?
C59 C71 C72 C73 179.1(5) . . . . ?
C71 C72 C73 C74 -2.7(9) . . . . ?
C72 C73 C74 C75 1.4(8) . . . . ?
C72 C73 C74 C77 178.6(5) . . . . ?
C73 C74 C75 C76 1.2(9) . . . . ?
C77 C74 C75 C76 -176.1(5) . . . . ?
C72 C71 C76 C75 1.2(8) . . . . ?
C59 C71 C76 C75 -176.6(5) . . . . ?
C74 C75 C76 C71 -2.5(9) . . . . ?
C75 C74 C77 C78 139.5(6) . . . . ?
C73 C74 C77 C78 -37.8(8) . . . . ?
C75 C74 C77 C81 -40.5(8) . . . . ?
C73 C74 C77 C81 142.3(6) . . . . ?
C81 C77 C78 C79 7.5(8) . . . . ?
C74 C77 C78 C79 -172.4(5) . . . . ?
C80 N3 C79 C78 -1.9(9) . . . . ?
Rh2 N3 C79 C78 161.9(5) . . . . ?
C77 C78 C79 N3 -3.8(9) . . . . ?
C79 N3 C80 C81 3.6(9) . . . . ?
Rh2 N3 C80 C81 -160.1(5) . . . . ?
N3 C80 C81 C77 0.4(10) . . . . ?
C78 C77 C81 C80 -6.0(9) . . . . ?
C74 C77 C81 C80 174.0(6) . . . . ?
C58 C59 C82 C87 46.0(8) . . . . ?
C71 C59 C82 C87 -136.6(5) . . . . ?
C58 C59 C82 C83 -135.9(5) . . . . ?
C71 C59 C82 C83 41.6(7) . . . . ?
C87 C82 C83 C84 -1.6(8) . . . . ?
C59 C82 C83 C84 -179.8(5) . . . . ?
C82 C83 C84 C85 -1.2(8) . . . . ?
C83 C84 C85 C86 2.0(8) . . . . ?
C83 C84 C85 C88 -177.2(5) . . . . ?
C84 C85 C86 C87 -0.1(9) . . . . ?
C88 C85 C86 C87 179.1(6) . . . . ?
C85 C86 C87 C82 -2.7(9) . . . . ?
C83 C82 C87 C86 3.5(8) . . . . ?
C59 C82 C87 C86 -178.4(5) . . . . ?
C86 C85 C88 C91 133.7(7) . . . . ?
C84 C85 C88 C91 -47.2(9) . . . . ?
C86 C85 C88 C89 -44.3(9) . . . . ?
C84 C85 C88 C89 134.8(6) . . . . ?
C91 C88 C89 C90 0.5(10) . . . . ?
C85 C88 C89 C90 178.7(6) . . . . ?
C92 N4 C90 C89 1.9(10) . . . . ?
Rh3 N4 C90 C89 -174.5(6) . . . . ?
C88 C89 C90 N4 -1.7(11) . . . . ?
C89 C88 C91 C92 0.4(10) . . . . ?
C85 C88 C91 C92 -177.7(6) . . . . ?
C90 N4 C92 C91 -0.9(10) . . . . ?
Rh3 N4 C92 C91 175.3(5) . . . . ?
C88 C91 C92 N4 -0.1(11) . . . . ?
Rh3 O10 C93 O12 175.1(4) . . . . ?
Rh3 O10 C93 C94 -3.1(5) . . . . ?
Rh4 O12 C93 O10 -179.5(4) . . . . ?
Rh4 O12 C93 C94 -1.2(5) . . . . ?
Rh4 O11 C94 O9 -179.6(4) . . . . ?
Rh4 O11 C94 C93 0.6(5) . . . . ?
Rh3 O9 C94 O11 -175.4(4) . . . . ?
Rh3 O9 C94 C93 4.4(5) . . . . ?
O10 C93 C94 O11 178.8(4) . . . . ?
O12 C93 C94 O11 0.4(6) . . . . ?
O10 C93 C94 O9 -1.0(6) . . . . ?
O12 C93 C94 O9 -179.3(4) . . . . ?
Rh6 O16 C95 O14 -175.9(4) . . . . ?
Rh6 O16 C95 C96 1.5(5) . . . . ?
Rh5 O14 C95 O16 171.8(4) . . . . ?
Rh5 O14 C95 C96 -5.7(5) . . . . ?
Rh6 O15 C96 O13 174.6(3) . . . . ?
Rh6 O15 C96 C95 -5.1(5) . . . . ?
Rh5 O13 C96 O15 -174.4(4) . . . . ?
Rh5 O13 C96 C95 5.2(5) . . . . ?
O16 C95 C96 O15 2.5(6) . . . . ?
O14 C95 C96 O15 -179.9(4) . . . . ?
O16 C95 C96 O13 -177.2(4) . . . . ?
O14 C95 C96 O13 0.4(6) . . . . ?
Rh8 O4 C97 O1 173.3(4) . . . . ?
Rh8 O4 C97 C98 -6.6(5) . . . . ?
Rh7 O1 C97 O4 178.0(4) . . . . ?
Rh7 O1 C97 C98 -2.1(5) . . . . ?
Rh8 O3 C98 O2 -175.6(3) . . . . ?
Rh8 O3 C98 C97 3.2(5) . . . . ?
Rh7 O2 C98 O3 178.9(3) . . . . ?
Rh7 O2 C98 C97 0.0(5) . . . . ?
O4 C97 C98 O3 2.5(6) . . . . ?
O1 C97 C98 O3 -177.5(4) . . . . ?
O4 C97 C98 O2 -178.6(4) . . . . ?
O1 C97 C98 O2 1.5(6) . . . . ?
Rh1 O8 C99 O6 170.7(3) . . . . ?
Rh1 O8 C99 C100 -7.5(4) . . . . ?
Rh2 O6 C99 O8 -172.7(3) . . . . ?
Rh2 O6 C99 C100 5.6(5) . . . . ?
Rh1 O7 C100 O5 -170.1(4) . . . . ?
Rh1 O7 C100 C99 9.6(5) . . . . ?
Rh2 O5 C100 O7 174.4(4) . . . . ?
Rh2 O5 C100 C99 -5.3(5) . . . . ?
O8 C99 C100 O7 -1.6(6) . . . . ?
O6 C99 C100 O7 -179.9(4) . . . . ?
O8 C99 C100 O5 178.2(4) . . . . ?
O6 C99 C100 O5 -0.2(6) . . . . ?
C125 C121 C122 C123 1.5(7) . . . . ?
C128 C121 C122 C123 176.7(7) . . . . ?
Rh4 C121 C122 C123 -60.0(4) . . . . ?
C125 C121 C122 C129 178.7(6) . . . . ?
C128 C121 C122 C129 -6.1(11) . . . . ?
Rh4 C121 C122 C129 117.2(7) . . . . ?
C125 C121 C122 Rh4 61.5(5) . . . . ?
C128 C121 C122 Rh4 -123.3(7) . . . . ?
C121 C122 C123 C124 -1.5(7) . . . . ?
C129 C122 C123 C124 -178.7(7) . . . . ?
Rh4 C122 C123 C124 -61.2(4) . . . . ?
C121 C122 C123 C130 177.3(7) . . . . ?
C129 C122 C123 C130 0.2(11) . . . . ?
Rh4 C122 C123 C130 117.6(7) . . . . ?
C121 C122 C123 Rh4 59.7(4) . . . . ?
C129 C122 C123 Rh4 -117.4(7) . . . . ?
C122 C123 C124 C125 1.1(7) . . . . ?
C130 C123 C124 C125 -177.8(7) . . . . ?
Rh4 C123 C124 C125 -61.0(5) . . . . ?
C122 C123 C124 C126 -178.1(7) . . . . ?
C130 C123 C124 C126 3.0(11) . . . . ?
Rh4 C123 C124 C126 119.8(7) . . . . ?
C122 C123 C124 Rh4 62.1(4) . . . . ?
C130 C123 C124 Rh4 -116.8(7) . . . . ?
C123 C124 C125 C121 -0.2(8) . . . . ?
C126 C124 C125 C121 179.0(7) . . . . ?
Rh4 C124 C125 C121 -60.5(5) . . . . ?
C123 C124 C125 C127 -179.1(7) . . . . ?
C126 C124 C125 C127 0.0(12) . . . . ?
Rh4 C124 C125 C127 120.5(7) . . . . ?
C123 C124 C125 Rh4 60.4(5) . . . . ?
C126 C124 C125 Rh4 -120.5(7) . . . . ?
C122 C121 C125 C124 -0.8(8) . . . . ?
C128 C121 C125 C124 -176.1(7) . . . . ?
Rh4 C121 C125 C124 60.8(5) . . . . ?
C122 C121 C125 C127 178.1(7) . . . . ?
C128 C121 C125 C127 2.8(12) . . . . ?
Rh4 C121 C125 C127 -120.3(8) . . . . ?
C122 C121 C125 Rh4 -61.6(5) . . . . ?
C128 C121 C125 Rh4 123.1(7) . . . . ?
C135 C131 C132 C133 -1.8(7) . . . . ?
C138 C131 C132 C133 -178.9(6) . . . . ?
Rh3 C131 C132 C133 -61.9(4) . . . . ?
C135 C131 C132 C139 178.3(6) . . . . ?
C138 C131 C132 C139 1.3(10) . . . . ?
Rh3 C131 C132 C139 118.3(7) . . . . ?
C135 C131 C132 Rh3 60.1(5) . . . . ?
C138 C131 C132 Rh3 -117.0(6) . . . . ?
C131 C132 C133 C134 2.9(7) . . . . ?
C139 C132 C133 C134 -177.2(6) . . . . ?
Rh3 C132 C133 C134 -58.3(4) . . . . ?
C131 C132 C133 C140 177.4(6) . . . . ?
C139 C132 C133 C140 -2.8(11) . . . . ?
Rh3 C132 C133 C140 116.2(7) . . . . ?
C131 C132 C133 Rh3 61.2(4) . . . . ?
C139 C132 C133 Rh3 -119.0(7) . . . . ?
C132 C133 C134 C135 -2.9(7) . . . . ?
C140 C133 C134 C135 -177.5(6) . . . . ?
Rh3 C133 C134 C135 -61.8(4) . . . . ?
C132 C133 C134 C136 179.7(7) . . . . ?
C140 C133 C134 C136 5.2(11) . . . . ?
Rh3 C133 C134 C136 120.9(8) . . . . ?
C132 C133 C134 Rh3 58.8(4) . . . . ?
C140 C133 C134 Rh3 -115.7(6) . . . . ?
C132 C131 C135 C134 0.0(7) . . . . ?
C138 C131 C135 C134 176.9(6) . . . . ?
Rh3 C131 C135 C134 59.7(5) . . . . ?
C132 C131 C135 C137 179.6(7) . . . . ?
C138 C131 C135 C137 -3.4(11) . . . . ?
Rh3 C131 C135 C137 -120.6(8) . . . . ?
C132 C131 C135 Rh3 -59.8(4) . . . . ?
C138 C131 C135 Rh3 117.2(6) . . . . ?
C133 C134 C135 C131 1.8(8) . . . . ?
C136 C134 C135 C131 179.2(7) . . . . ?
Rh3 C134 C135 C131 -60.5(5) . . . . ?
C133 C134 C135 C137 -177.8(7) . . . . ?
C136 C134 C135 C137 -0.4(12) . . . . ?
Rh3 C134 C135 C137 119.9(7) . . . . ?
C133 C134 C135 Rh3 62.3(4) . . . . ?
C136 C134 C135 Rh3 -120.3(7) . . . . ?
C146 C141 C142 C143 -179.7(8) . . . . ?
C145 C141 C142 C143 2.7(8) . . . . ?
Rh2 C141 C142 C143 -59.5(6) . . . . ?
C146 C141 C142 C147 -1.5(13) . . . . ?
C145 C141 C142 C147 -179.1(7) . . . . ?
Rh2 C141 C142 C147 118.6(8) . . . . ?
C146 C141 C142 Rh2 -120.1(9) . . . . ?
C145 C141 C142 Rh2 62.2(4) . . . . ?
C141 C142 C143 C144 -3.5(10) . . . . ?
C147 C142 C143 C144 178.4(8) . . . . ?
Rh2 C142 C143 C144 -63.2(6) . . . . ?
C141 C142 C143 C148 179.9(8) . . . . ?
C147 C142 C143 C148 1.7(14) . . . . ?
Rh2 C142 C143 C148 120.2(9) . . . . ?
C141 C142 C143 Rh2 59.7(6) . . . . ?
C147 C142 C143 Rh2 -118.5(8) . . . . ?
C142 C143 C144 C145 2.7(10) . . . . ?
C148 C143 C144 C145 179.4(8) . . . . ?
Rh2 C143 C144 C145 -60.2(6) . . . . ?
C142 C143 C144 C149 179.7(8) . . . . ?
C148 C143 C144 C149 -3.6(14) . . . . ?
Rh2 C143 C144 C149 116.8(9) . . . . ?
C142 C143 C144 Rh2 62.9(6) . . . . ?
C148 C143 C144 Rh2 -120.4(9) . . . . ?
C143 C144 C145 C150 178.3(9) . . . . ?
C149 C144 C145 C150 1.1(14) . . . . ?
Rh2 C144 C145 C150 117.6(9) . . . . ?
C143 C144 C145 C141 -0.9(9) . . . . ?
C149 C144 C145 C141 -178.0(7) . . . . ?
Rh2 C144 C145 C141 -61.5(4) . . . . ?
C143 C144 C145 Rh2 60.7(6) . . . . ?
C149 C144 C145 Rh2 -116.5(8) . . . . ?
C142 C141 C145 C144 -1.1(8) . . . . ?
C146 C141 C145 C144 -178.8(8) . . . . ?
Rh2 C141 C145 C144 62.9(5) . . . . ?
C142 C141 C145 C150 179.6(7) . . . . ?
C146 C141 C145 C150 1.9(12) . . . . ?
Rh2 C141 C145 C150 -116.3(8) . . . . ?
C142 C141 C145 Rh2 -64.0(5) . . . . ?
C146 C141 C145 Rh2 118.3(8) . . . . ?
C155 C151 C152 C153 0.6(6) . . . . ?
C156 C151 C152 C153 -173.9(5) . . . . ?
Rh1 C151 C152 C153 61.8(4) . . . . ?
C155 C151 C152 C157 178.4(5) . . . . ?
C156 C151 C152 C157 3.9(9) . . . . ?
Rh1 C151 C152 C157 -120.3(6) . . . . ?
C155 C151 C152 Rh1 -61.2(4) . . . . ?
C156 C151 C152 Rh1 124.2(5) . . . . ?
C151 C152 C153 C154 -1.2(6) . . . . ?
C157 C152 C153 C154 -179.1(5) . . . . ?
Rh1 C152 C153 C154 60.1(4) . . . . ?
C151 C152 C153 C158 -178.5(5) . . . . ?
C157 C152 C153 C158 3.6(9) . . . . ?
Rh1 C152 C153 C158 -117.2(6) . . . . ?
C151 C152 C153 Rh1 -61.3(4) . . . . ?
C157 C152 C153 Rh1 120.8(6) . . . . ?
C152 C153 C154 C155 1.4(6) . . . . ?
C158 C153 C154 C155 178.7(5) . . . . ?
Rh1 C153 C154 C155 60.8(3) . . . . ?
C152 C153 C154 C159 178.7(5) . . . . ?
C158 C153 C154 C159 -4.0(8) . . . . ?
Rh1 C153 C154 C159 -121.9(5) . . . . ?
C152 C153 C154 Rh1 -59.4(4) . . . . ?
C158 C153 C154 Rh1 118.0(6) . . . . ?
C152 C151 C155 C154 0.3(6) . . . . ?
C156 C151 C155 C154 174.8(5) . . . . ?
Rh1 C151 C155 C154 -60.3(3) . . . . ?
C152 C151 C155 C160 175.8(5) . . . . ?
C156 C151 C155 C160 -9.6(8) . . . . ?
Rh1 C151 C155 C160 115.3(5) . . . . ?
C152 C151 C155 Rh1 60.6(4) . . . . ?
C156 C151 C155 Rh1 -124.9(5) . . . . ?
C153 C154 C155 C151 -1.1(5) . . . . ?
C159 C154 C155 C151 -178.3(5) . . . . ?
Rh1 C154 C155 C151 59.7(3) . . . . ?
C153 C154 C155 C160 -176.6(5) . . . . ?
C159 C154 C155 C160 6.2(8) . . . . ?
Rh1 C154 C155 C160 -115.8(5) . . . . ?
C153 C154 C155 Rh1 -60.8(3) . . . . ?
C159 C154 C155 Rh1 122.0(5) . . . . ?
C165 C161 C162 C163 0.2(6) . . . . ?
C166 C161 C162 C163 176.1(6) . . . . ?
Rh8 C161 C162 C163 -60.2(4) . . . . ?
C165 C161 C162 C167 177.0(6) . . . . ?
C166 C161 C162 C167 -7.1(10) . . . . ?
Rh8 C161 C162 C167 116.6(6) . . . . ?
C165 C161 C162 Rh8 60.4(4) . . . . ?
C166 C161 C162 Rh8 -123.7(6) . . . . ?
C161 C162 C163 C164 -0.9(7) . . . . ?
C167 C162 C163 C164 -177.5(6) . . . . ?
Rh8 C162 C163 C164 -61.4(4) . . . . ?
C161 C162 C163 C168 -177.7(7) . . . . ?
C167 C162 C163 C168 5.7(11) . . . . ?
Rh8 C162 C163 C168 121.8(7) . . . . ?
C161 C162 C163 Rh8 60.6(4) . . . . ?
C167 C162 C163 Rh8 -116.1(7) . . . . ?
C162 C163 C164 C165 1.2(7) . . . . ?
C168 C163 C164 C165 178.3(6) . . . . ?
Rh8 C163 C164 C165 -60.7(4) . . . . ?
C162 C163 C164 C169 176.9(6) . . . . ?
C168 C163 C164 C169 -6.1(10) . . . . ?
Rh8 C163 C164 C169 115.0(6) . . . . ?
C162 C163 C164 Rh8 61.9(4) . . . . ?
C168 C163 C164 Rh8 -121.1(7) . . . . ?
C163 C164 C165 C161 -1.1(6) . . . . ?
C169 C164 C165 C161 -176.8(6) . . . . ?
Rh8 C164 C165 C161 -61.9(4) . . . . ?
C163 C164 C165 C170 -176.7(6) . . . . ?
C169 C164 C165 C170 7.5(10) . . . . ?
Rh8 C164 C165 C170 122.5(6) . . . . ?
C163 C164 C165 Rh8 60.7(4) . . . . ?
C169 C164 C165 Rh8 -115.0(6) . . . . ?
C162 C161 C165 C164 0.6(6) . . . . ?
C166 C161 C165 C164 -175.4(6) . . . . ?
Rh8 C161 C165 C164 61.7(4) . . . . ?
C162 C161 C165 C170 176.3(5) . . . . ?
C166 C161 C165 C170 0.4(9) . . . . ?
Rh8 C161 C165 C170 -122.6(6) . . . . ?
C162 C161 C165 Rh8 -61.1(4) . . . . ?
C166 C161 C165 Rh8 123.0(6) . . . . ?
C181 C171 C172 C179 -174.9(9) . . . . ?
C180 C171 C172 C179 1.7(16) . . . . ?
Rh7 C171 C172 C179 -115.8(9) . . . . ?
C181 C171 C172 C174 4.5(10) . . . . ?
C180 C171 C172 C174 -178.8(10) . . . . ?
Rh7 C171 C172 C174 63.6(5) . . . . ?
C181 C171 C172 Rh7 -59.1(7) . . . . ?
C180 C171 C172 Rh7 117.6(11) . . . . ?
C171 C172 C174 C175 -1.9(8) . . . . ?
C179 C172 C174 C175 177.4(11) . . . . ?
Rh7 C172 C174 C175 62.6(5) . . . . ?
C171 C172 C174 C177 -176.7(9) . . . . ?
C179 C172 C174 C177 2.6(17) . . . . ?
Rh7 C172 C174 C177 -112.3(10) . . . . ?
C171 C172 C174 Rh7 -64.5(5) . . . . ?
C179 C172 C174 Rh7 114.9(11) . . . . ?
C177 C174 C175 C181 173.7(10) . . . . ?
C172 C174 C175 C181 -1.3(11) . . . . ?
Rh7 C174 C175 C181 59.8(8) . . . . ?
C177 C174 C175 C176 -1.3(17) . . . . ?
C172 C174 C175 C176 -176.3(10) . . . . ?
Rh7 C174 C175 C176 -115.2(11) . . . . ?
C177 C174 C175 Rh7 113.9(9) . . . . ?
C172 C174 C175 Rh7 -61.1(5) . . . . ?
C174 C175 C181 C171 4.2(13) . . . . ?
C176 C175 C181 C171 -179.7(9) . . . . ?
Rh7 C175 C181 C171 63.7(7) . . . . ?
C174 C175 C181 C182 -179.5(9) . . . . ?
C176 C175 C181 C182 -3.4(16) . . . . ?
Rh7 C175 C181 C182 -120.1(11) . . . . ?
C174 C175 C181 Rh7 -59.4(7) . . . . ?
C176 C175 C181 Rh7 116.6(8) . . . . ?
C172 C171 C181 C175 -5.6(12) . . . . ?
C180 C171 C181 C175 177.0(9) . . . . ?
Rh7 C171 C181 C175 -64.0(8) . . . . ?
C172 C171 C181 C182 178.0(9) . . . . ?
C180 C171 C181 C182 0.6(15) . . . . ?
Rh7 C171 C181 C182 119.6(11) . . . . ?
C172 C171 C181 Rh7 58.4(7) . . . . ?
C180 C171 C181 Rh7 -119.0(8) . . . . ?
C193 C189 C190 C191 2.2(6) . . . . ?
C188 C189 C190 C191 178.0(5) . . . . ?
Rh5 C189 C190 C191 61.3(4) . . . . ?
C193 C189 C190 C185 178.8(5) . . . . ?
C188 C189 C190 C185 -5.5(9) . . . . ?
Rh5 C189 C190 C185 -122.2(6) . . . . ?
C193 C189 C190 Rh5 -59.1(4) . . . . ?
C188 C189 C190 Rh5 116.7(6) . . . . ?
C189 C190 C191 C192 -1.0(6) . . . . ?
C185 C190 C191 C192 -177.4(5) . . . . ?
Rh5 C190 C191 C192 60.0(4) . . . . ?
C189 C190 C191 C184 -179.3(5) . . . . ?
C185 C190 C191 C184 4.2(9) . . . . ?
Rh5 C190 C191 C184 -118.3(6) . . . . ?
C189 C190 C191 Rh5 -61.0(4) . . . . ?
C185 C190 C191 Rh5 122.6(6) . . . . ?
C190 C191 C192 C193 -0.6(7) . . . . ?
C184 C191 C192 C193 177.8(6) . . . . ?
Rh5 C191 C192 C193 59.6(4) . . . . ?
C190 C191 C192 C186 177.0(6) . . . . ?
C184 C191 C192 C186 -4.7(10) . . . . ?
Rh5 C191 C192 C186 -122.9(7) . . . . ?
C190 C191 C192 Rh5 -60.2(4) . . . . ?
C184 C191 C192 Rh5 118.2(6) . . . . ?
C190 C189 C193 C192 -2.6(6) . . . . ?
C188 C189 C193 C192 -178.3(5) . . . . ?
Rh5 C189 C193 C192 -62.3(4) . . . . ?
C190 C189 C193 C187 -176.9(6) . . . . ?
C188 C189 C193 C187 7.4(9) . . . . ?
Rh5 C189 C193 C187 123.5(6) . . . . ?
C190 C189 C193 Rh5 59.7(4) . . . . ?
C188 C189 C193 Rh5 -116.1(6) . . . . ?
C191 C192 C193 C189 2.0(6) . . . . ?
C186 C192 C193 C189 -175.7(6) . . . . ?
Rh5 C192 C193 C189 62.7(4) . . . . ?
C191 C192 C193 C187 176.1(6) . . . . ?
C186 C192 C193 C187 -1.6(10) . . . . ?
Rh5 C192 C193 C187 -123.2(6) . . . . ?
C191 C192 C193 Rh5 -60.8(4) . . . . ?
C186 C192 C193 Rh5 121.6(6) . . . . ?
C198 C194 C195 C196 0.4(8) . . . . ?
C199 C194 C195 C196 176.2(7) . . . . ?
Rh6 C194 C195 C196 -60.0(5) . . . . ?
C198 C194 C195 C200 178.6(7) . . . . ?
C199 C194 C195 C200 -5.6(12) . . . . ?
Rh6 C194 C195 C200 118.2(7) . . . . ?
C198 C194 C195 Rh6 60.4(5) . . . . ?
C199 C194 C195 Rh6 -123.8(8) . . . . ?
C194 C195 C196 C197 -1.5(8) . . . . ?
C200 C195 C196 C197 -179.7(7) . . . . ?
Rh6 C195 C196 C197 -61.5(5) . . . . ?
C194 C195 C196 C201 -178.2(7) . . . . ?
C200 C195 C196 C201 3.6(11) . . . . ?
Rh6 C195 C196 C201 121.8(7) . . . . ?
C194 C195 C196 Rh6 60.0(5) . . . . ?
C200 C195 C196 Rh6 -118.2(7) . . . . ?
C195 C196 C197 C198 2.1(8) . . . . ?
C201 C196 C197 C198 178.5(7) . . . . ?
Rh6 C196 C197 C198 -59.3(5) . . . . ?
C195 C196 C197 C183 -179.2(7) . . . . ?
C201 C196 C197 C183 -2.7(12) . . . . ?
Rh6 C196 C197 C183 119.4(7) . . . . ?
C195 C196 C197 Rh6 61.4(4) . . . . ?
C201 C196 C197 Rh6 -122.1(8) . . . . ?
C196 C197 C198 C194 -1.8(8) . . . . ?
C183 C197 C198 C194 179.5(7) . . . . ?
Rh6 C197 C198 C194 -62.3(5) . . . . ?
C196 C197 C198 C202 -177.6(7) . . . . ?
C183 C197 C198 C202 3.7(13) . . . . ?
Rh6 C197 C198 C202 121.9(8) . . . . ?
C196 C197 C198 Rh6 60.5(5) . . . . ?
C183 C197 C198 Rh6 -118.2(8) . . . . ?
C195 C194 C198 C197 0.8(8) . . . . ?
C199 C194 C198 C197 -175.1(7) . . . . ?
Rh6 C194 C198 C197 62.7(5) . . . . ?
C195 C194 C198 C202 176.7(7) . . . . ?
C199 C194 C198 C202 0.8(12) . . . . ?
Rh6 C194 C198 C202 -121.4(8) . . . . ?
C195 C194 C198 Rh6 -61.8(5) . . . . ?
C199 C194 C198 Rh6 122.3(7) . . . . ?
