#------------------------------------------------------------------------------
#$Date: 2021-09-18 02:11:20 +0300 (Sat, 18 Sep 2021) $
#$Revision: 269200 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/83/7708339.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7708339
loop_
_publ_author_name
'Wallach, Chistoph'
'Selic, Yasmin'
'Witzel, Benedikt'
'Klein, Wilhelm'
'Fässler, Thomas F'
_publ_section_title
;
 Filled Trivacant Icosahedra as Building Fragments in 17-atomic Endohedral
 Germanides [TM2@Ge17]n- (TM = Co, Ni)
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D1DT03078G
_journal_year                    2021
_chemical_formula_moiety
'2(C18 H36 K N2 O6), 4(K), 15(H3 N), Co2 Ge17'
_chemical_formula_sum            'C36 H117 Co2 Ge17 K6 N19 O12'
_chemical_formula_weight         2594.97
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-04-30 deposited with the CCDC.	2021-09-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 110.634(2)
_cell_angle_gamma                90.000(2)
_cell_formula_units_Z            4
_cell_length_a                   19.6865(6)
_cell_length_b                   32.1696(10)
_cell_length_c                   15.3982(4)
_cell_measurement_reflns_used    28227
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.28
_cell_measurement_theta_min      1.30
_cell_volume                     9126.2(5)
_computing_cell_refinement       'STOE X-AREA 1.76'
_computing_data_collection       'STOE X-AREA 1.76'
_computing_data_reduction        'STOE X-AREA 1.76'
_computing_molecular_graphics    'DIAMOND 3.2k'
_computing_structure_refinement  SHELXL-2014/7
_computing_structure_solution    SHELXS-97
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 5.81
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'STOE StadiVari'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1763
_diffrn_reflns_av_unetI/netI     0.0555
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -39
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            277912
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_min         2.722
_diffrn_source                   'Genix 3D HF Mo'
_exptl_absorpt_coefficient_mu    6.181
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.481
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'STOE X-AREA 1.76'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.889
_exptl_crystal_description       block
_exptl_crystal_F_000             5096
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.553
_refine_diff_density_min         -1.455
_refine_diff_density_rms         0.154
_refine_ls_extinction_coef       0.00029(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     834
_refine_ls_number_reflns         17914
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0683
_refine_ls_R_factor_gt           0.0472
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0484P)²+34.3816P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1053
_refine_ls_wR_factor_ref         0.1142
_reflns_number_gt                13812
_reflns_number_total             17914
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt03078g2.cif
_cod_data_source_block           BW514
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7708339
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.23319(3) 0.35508(2) 0.21080(4) 0.02394(14) Uani 1 1 d . . . . .
Ge2 Ge 0.26085(3) 0.43397(2) 0.25608(4) 0.02232(14) Uani 1 1 d . . . . .
Ge3 Ge 0.23084(3) 0.41524(2) 0.07762(4) 0.02504(15) Uani 1 1 d . . . . .
Ge4 Ge 0.28727(4) 0.33861(2) 0.08129(4) 0.02565(15) Uani 1 1 d . . . . .
Ge5 Ge 0.37930(3) 0.32129(2) 0.25630(4) 0.02260(14) Uani 1 1 d . . . . .
Ge6 Ge 0.36089(3) 0.37947(2) 0.36407(4) 0.02227(14) Uani 1 1 d . . . . .
Ge7 Ge 0.34839(4) 0.46344(2) 0.17119(5) 0.02501(15) Uani 1 1 d . . . . .
Ge8 Ge 0.36633(4) 0.40367(2) 0.06508(5) 0.02885(16) Uani 1 1 d . . . . .
Ge9 Ge 0.45771(3) 0.39959(2) 0.26542(4) 0.02383(15) Uani 1 1 d . . . . .
Ge10 Ge 0.55172(4) 0.46880(2) 0.35928(5) 0.02638(15) Uani 1 1 d . . . . .
Ge11 Ge 0.52577(4) 0.41127(2) 0.46688(4) 0.02376(14) Uani 1 1 d . . . . .
Ge12 Ge 0.54621(4) 0.32393(2) 0.30933(4) 0.02396(15) Uani 1 1 d . . . . .
Ge13 Ge 0.57227(4) 0.37669(2) 0.19648(4) 0.02628(15) Uani 1 1 d . . . . .
Ge14 Ge 0.65539(3) 0.44034(2) 0.29697(5) 0.02587(15) Uani 1 1 d . . . . .
Ge15 Ge 0.67483(3) 0.42715(2) 0.47445(5) 0.02589(15) Uani 1 1 d . . . . .
Ge16 Ge 0.69002(3) 0.36369(2) 0.36260(5) 0.02533(15) Uani 1 1 d . . . . .
Ge17 Ge 0.62025(4) 0.35010(2) 0.48085(4) 0.02522(15) Uani 1 1 d . . . . .
Co1 Co 0.34006(4) 0.39042(2) 0.20293(5) 0.01513(16) Uani 1 1 d . . . . .
Co2 Co 0.57443(4) 0.39634(2) 0.34733(5) 0.01604(16) Uani 1 1 d . . . . .
K1 K 0.39431(8) 0.49235(5) 0.41076(11) 0.0356(3) Uani 1 1 d . . . . .
K2 K 0.44599(10) 0.30594(6) 0.04695(14) 0.0524(5) Uani 1 1 d . . . . .
K3 K 0.50295(10) 0.47932(8) 0.10686(15) 0.0633(6) Uani 1 1 d . . . . .
K4 K 0.46005(10) 0.29907(6) 0.49350(12) 0.0509(5) Uani 1 1 d . . . . .
K5 K 0.09015(7) 0.12700(4) 0.10873(8) 0.0214(3) Uani 1 1 d . . . . .
N1 N 0.0652(3) 0.11138(17) 0.2869(3) 0.0280(12) Uani 1 1 d . . . . .
N2 N 0.1143(3) 0.14451(19) -0.0687(4) 0.0330(13) Uani 1 1 d . . . . .
O1 O 0.1502(2) 0.05320(14) 0.2184(3) 0.0278(10) Uani 1 1 d . . . . .
O2 O 0.1931(3) 0.07680(15) 0.0670(3) 0.0330(11) Uani 1 1 d . . . . .
O3 O 0.1386(3) 0.20832(15) 0.0755(3) 0.0348(11) Uani 1 1 d . . . . .
O4 O 0.1354(3) 0.18849(14) 0.2525(3) 0.0344(11) Uani 1 1 d . . . . .
O5 O -0.0553(2) 0.11390(15) 0.1020(3) 0.0302(10) Uani 1 1 d . . . . .
O6 O -0.0271(2) 0.11599(15) -0.0659(3) 0.0299(10) Uani 1 1 d . . . . .
C1 C 0.0906(4) 0.0692(2) 0.3241(5) 0.0337(16) Uani 1 1 d . . . . .
H1A H 0.0533 0.0486 0.2905 0.040 Uiso 1 1 calc R U . . .
H1B H 0.0958 0.0682 0.3904 0.040 Uiso 1 1 calc R U . . .
C2 C 0.1619(4) 0.0573(2) 0.3150(4) 0.0282(14) Uani 1 1 d . . . . .
H2A H 0.1988 0.0790 0.3431 0.034 Uiso 1 1 calc R U . . .
H2B H 0.1795 0.0307 0.3475 0.034 Uiso 1 1 calc R U . . .
C3 C 0.2134(4) 0.0373(2) 0.2048(5) 0.0333(15) Uani 1 1 d . . . . .
H3A H 0.2248 0.0092 0.2324 0.040 Uiso 1 1 calc R U . . .
H3B H 0.2554 0.0557 0.2356 0.040 Uiso 1 1 calc R U . . .
C4 C 0.1997(4) 0.0353(2) 0.1028(5) 0.0371(16) Uani 1 1 d . . . . .
H4A H 0.2403 0.0208 0.0918 0.045 Uiso 1 1 calc R U . . .
H4B H 0.1545 0.0196 0.0709 0.045 Uiso 1 1 calc R U . . .
C5 C 0.1816(5) 0.0769(3) -0.0298(5) 0.048(2) Uani 1 1 d . . . . .
H5A H 0.1348 0.0632 -0.0645 0.058 Uiso 1 1 calc R U . . .
H5B H 0.2208 0.0611 -0.0412 0.058 Uiso 1 1 calc R U . . .
C6 C 0.1807(5) 0.1208(3) -0.0636(6) 0.051(2) Uani 1 1 d . . . . .
H6A H 0.2238 0.1356 -0.0215 0.062 Uiso 1 1 calc R U . . .
H6B H 0.1845 0.1202 -0.1260 0.062 Uiso 1 1 calc R U . . .
C7 C 0.1269(4) 0.1891(3) -0.0784(5) 0.0428(19) Uani 1 1 d . . . . .
H7A H 0.0793 0.2034 -0.1015 0.051 Uiso 1 1 calc R U . . .
H7B H 0.1498 0.1925 -0.1258 0.051 Uiso 1 1 calc R U . . .
C8 C 0.1736(4) 0.2099(3) 0.0090(6) 0.0444(19) Uani 1 1 d . . . . .
H8A H 0.2211 0.1956 0.0338 0.053 Uiso 1 1 calc R U . . .
H8B H 0.1821 0.2392 -0.0039 0.053 Uiso 1 1 calc R U . . .
C9 C 0.1791(5) 0.2313(2) 0.1579(6) 0.046(2) Uani 1 1 d . . . . .
H9A H 0.1858 0.2603 0.1416 0.055 Uiso 1 1 calc R U . . .
H9B H 0.2275 0.2186 0.1879 0.055 Uiso 1 1 calc R U . . .
C10 C 0.1382(5) 0.2303(2) 0.2221(6) 0.048(2) Uani 1 1 d . . . . .
H10A H 0.1624 0.2484 0.2762 0.058 Uiso 1 1 calc R U . . .
H10B H 0.0884 0.2409 0.1902 0.058 Uiso 1 1 calc R U . . .
C11 C 0.1006(5) 0.1862(2) 0.3195(5) 0.0444(19) Uani 1 1 d . . . . .
H11A H 0.0489 0.1940 0.2903 0.053 Uiso 1 1 calc R U . . .
H11B H 0.1240 0.2058 0.3708 0.053 Uiso 1 1 calc R U . . .
C12 C 0.1064(4) 0.1429(2) 0.3566(4) 0.0389(18) Uani 1 1 d . . . . .
H12A H 0.1582 0.1348 0.3813 0.047 Uiso 1 1 calc R U . . .
H12B H 0.0883 0.1426 0.4090 0.047 Uiso 1 1 calc R U . . .
C13 C -0.0128(4) 0.1152(3) 0.2687(5) 0.0409(19) Uani 1 1 d . . . . .
H13A H -0.0260 0.1450 0.2630 0.049 Uiso 1 1 calc R U . . .
H13B H -0.0234 0.1039 0.3223 0.049 Uiso 1 1 calc R U . . .
C14 C -0.0592(4) 0.0931(3) 0.1822(5) 0.0397(17) Uani 1 1 d . . . . .
H14A H -0.0423 0.0640 0.1833 0.048 Uiso 1 1 calc R U . . .
H14B H -0.1102 0.0924 0.1796 0.048 Uiso 1 1 calc R U . . .
C15 C -0.1010(4) 0.0939(2) 0.0188(5) 0.0366(16) Uani 1 1 d . . . . .
H15A H -0.1514 0.0923 0.0181 0.044 Uiso 1 1 calc R U . . .
H15B H -0.0836 0.0652 0.0156 0.044 Uiso 1 1 calc R U . . .
C16 C -0.0988(4) 0.1186(2) -0.0622(5) 0.0353(16) Uani 1 1 d . . . . .
H16A H -0.1347 0.1076 -0.1202 0.042 Uiso 1 1 calc R U . . .
H16B H -0.1111 0.1480 -0.0554 0.042 Uiso 1 1 calc R U . . .
C17 C -0.0196(4) 0.1403(2) -0.1392(4) 0.0349(16) Uani 1 1 d . . . . .
H17A H -0.0218 0.1702 -0.1256 0.042 Uiso 1 1 calc R U . . .
H17B H -0.0597 0.1339 -0.1980 0.042 Uiso 1 1 calc R U . . .
C18 C 0.0517(4) 0.1304(3) -0.1487(4) 0.0388(17) Uani 1 1 d . . . . .
H18A H 0.0552 0.1000 -0.1557 0.047 Uiso 1 1 calc R U . . .
H18B H 0.0536 0.1437 -0.2057 0.047 Uiso 1 1 calc R U . . .
K6 K 0.84437(7) 0.14359(4) 0.48074(9) 0.0209(3) Uani 1 1 d . . . . .
N3 N 0.9131(3) 0.06109(16) 0.5532(4) 0.0254(11) Uani 1 1 d . . . . .
N4 N 0.7761(3) 0.22582(16) 0.4085(3) 0.0233(11) Uani 1 1 d . . . . .
O7 O 0.7991(3) 0.07161(14) 0.3724(3) 0.0305(10) Uani 1 1 d . . . . .
O8 O 0.7567(2) 0.15108(14) 0.2915(3) 0.0305(10) Uani 1 1 d . . . . .
O9 O 0.7461(2) 0.17947(13) 0.5543(3) 0.0262(9) Uani 1 1 d . . . . .
O10 O 0.8328(2) 0.11030(14) 0.6463(3) 0.0264(9) Uani 1 1 d . . . . .
O11 O 0.9953(2) 0.13415(14) 0.5291(3) 0.0264(9) Uani 1 1 d . . . . .
O12 O 0.9343(2) 0.21558(13) 0.4972(3) 0.0251(9) Uani 1 1 d . . . . .
C19 C 0.8693(4) 0.0272(2) 0.4943(5) 0.0321(15) Uani 1 1 d . . . . .
H19A H 0.8259 0.0224 0.5113 0.039 Uiso 1 1 calc R U . . .
H19B H 0.8983 0.0013 0.5076 0.039 Uiso 1 1 calc R U . . .
C20 C 0.8452(4) 0.0361(2) 0.3922(5) 0.0346(16) Uani 1 1 d . . . . .
H20A H 0.8879 0.0414 0.3741 0.041 Uiso 1 1 calc R U . . .
H20B H 0.8187 0.0119 0.3565 0.041 Uiso 1 1 calc R U . . .
C21 C 0.7647(4) 0.0776(2) 0.2751(4) 0.0357(16) Uani 1 1 d . . . . .
H21A H 0.7367 0.0524 0.2468 0.043 Uiso 1 1 calc R U . . .
H21B H 0.8019 0.0822 0.2465 0.043 Uiso 1 1 calc R U . . .
C22 C 0.7153(4) 0.1141(2) 0.2572(5) 0.0368(16) Uani 1 1 d . . . . .
H22A H 0.6884 0.1168 0.1897 0.044 Uiso 1 1 calc R U . . .
H22B H 0.6796 0.1101 0.2883 0.044 Uiso 1 1 calc R U . . .
C23 C 0.7107(4) 0.1869(2) 0.2630(5) 0.0397(17) Uani 1 1 d . . . . .
H23A H 0.6680 0.1838 0.2824 0.048 Uiso 1 1 calc R U . . .
H23B H 0.6930 0.1894 0.1946 0.048 Uiso 1 1 calc R U . . .
C24 C 0.7524(4) 0.2256(2) 0.3065(4) 0.0338(15) Uani 1 1 d . . . . .
H24A H 0.7957 0.2280 0.2881 0.041 Uiso 1 1 calc R U . . .
H24B H 0.7215 0.2503 0.2820 0.041 Uiso 1 1 calc R U . . .
C25 C 0.7133(4) 0.2328(2) 0.4385(5) 0.0311(15) Uani 1 1 d . . . . .
H25A H 0.6721 0.2156 0.3996 0.037 Uiso 1 1 calc R U . . .
H25B H 0.6985 0.2623 0.4276 0.037 Uiso 1 1 calc R U . . .
C26 C 0.7280(4) 0.2228(2) 0.5385(5) 0.0327(15) Uani 1 1 d . . . . .
H26A H 0.7687 0.2400 0.5785 0.039 Uiso 1 1 calc R U . . .
H26B H 0.6845 0.2290 0.5543 0.039 Uiso 1 1 calc R U . . .
C27 C 0.7547(4) 0.1674(2) 0.6465(5) 0.0312(15) Uani 1 1 d . . . . .
H27A H 0.7110 0.1755 0.6603 0.037 Uiso 1 1 calc R U . . .
H27B H 0.7970 0.1821 0.6909 0.037 Uiso 1 1 calc R U . . .
C28 C 0.7658(4) 0.1216(2) 0.6580(5) 0.0320(15) Uani 1 1 d . . . . .
H28A H 0.7673 0.1133 0.7205 0.038 Uiso 1 1 calc R U . . .
H28B H 0.7248 0.1070 0.6114 0.038 Uiso 1 1 calc R U . . .
C29 C 0.8460(4) 0.0673(2) 0.6630(5) 0.0310(14) Uani 1 1 d . . . . .
H29A H 0.8053 0.0511 0.6199 0.037 Uiso 1 1 calc R U . . .
H29B H 0.8499 0.0605 0.7273 0.037 Uiso 1 1 calc R U . . .
C30 C 0.9164(4) 0.0559(2) 0.6486(4) 0.0290(14) Uani 1 1 d . . . . .
H30A H 0.9561 0.0734 0.6897 0.035 Uiso 1 1 calc R U . . .
H30B H 0.9284 0.0266 0.6672 0.035 Uiso 1 1 calc R U . . .
C31 C 0.9869(4) 0.0604(2) 0.5493(5) 0.0303(14) Uani 1 1 d . . . . .
H31A H 0.9831 0.0558 0.4842 0.036 Uiso 1 1 calc R U . . .
H31B H 1.0137 0.0366 0.5864 0.036 Uiso 1 1 calc R U . . .
C32 C 1.0299(4) 0.0995(2) 0.5845(5) 0.0303(14) Uani 1 1 d . . . . .
H32A H 1.0343 0.1044 0.6498 0.036 Uiso 1 1 calc R U . . .
H32B H 1.0794 0.0962 0.5827 0.036 Uiso 1 1 calc R U . . .
C33 C 1.0371(3) 0.1716(2) 0.5592(4) 0.0257(13) Uani 1 1 d . . . . .
H33A H 1.0877 0.1668 0.5625 0.031 Uiso 1 1 calc R U . . .
H33B H 1.0382 0.1794 0.6219 0.031 Uiso 1 1 calc R U . . .
C34 C 1.0040(3) 0.2055(2) 0.4929(5) 0.0271(13) Uani 1 1 d . . . . .
H34A H 1.0358 0.2303 0.5087 0.033 Uiso 1 1 calc R U . . .
H34B H 0.9985 0.1967 0.4292 0.033 Uiso 1 1 calc R U . . .
C35 C 0.9030(4) 0.2506(2) 0.4413(5) 0.0352(16) Uani 1 1 d . . . . .
H35A H 0.8985 0.2450 0.3762 0.042 Uiso 1 1 calc R U . . .
H35B H 0.9350 0.2750 0.4633 0.042 Uiso 1 1 calc R U . . .
C36 C 0.8287(4) 0.2597(2) 0.4458(5) 0.0292(14) Uani 1 1 d . . . . .
H36A H 0.8339 0.2648 0.5112 0.035 Uiso 1 1 calc R U . . .
H36B H 0.8095 0.2855 0.4103 0.035 Uiso 1 1 calc R U . . .
N5 N 0.3277(4) 0.2446(3) 0.4172(7) 0.082(3) Uani 1 1 d . . . . .
H5C H 0.2955 0.2405 0.4467 0.123 Uiso 1 1 d R U . . .
H5D H 0.3247 0.2232 0.3774 0.123 Uiso 1 1 d R U . . .
H5E H 0.3173 0.2689 0.3850 0.123 Uiso 1 1 d R U . . .
N6 N 0.4936(5) 0.2194(3) 0.3939(6) 0.069(2) Uani 1 1 d . . . . .
H6C H 0.5239 0.1998 0.3854 0.104 Uiso 1 1 calc R U . . .
H6D H 0.5173 0.2442 0.4079 0.104 Uiso 1 1 calc R U . . .
H6E H 0.4542 0.2221 0.3409 0.104 Uiso 1 1 calc R U . . .
N7 N 0.5627(4) 0.2509(2) 0.6365(5) 0.058(2) Uani 1 1 d . . . . .
H7C H 0.5942 0.2585 0.6080 0.087 Uiso 1 1 d R U . . .
H7D H 0.5755 0.2254 0.6631 0.087 Uiso 1 1 d R U . . .
H7E H 0.5642 0.2698 0.6809 0.087 Uiso 1 1 d R U . . .
N8 N 0.3838(7) 0.2815(4) 0.6344(9) 0.127(5) Uani 1 1 d . . . . .
H8C H 0.3702 0.3059 0.6532 0.190 Uiso 1 1 calc R U . . .
H8D H 0.4149 0.2678 0.6845 0.190 Uiso 1 1 calc R U . . .
H8E H 0.3438 0.2655 0.6071 0.190 Uiso 1 1 calc R U . . .
N9 N 0.5130(5) 0.3472(3) 0.6752(7) 0.079(3) Uani 1 1 d . . . . .
H9C H 0.5324 0.3293 0.7232 0.118 Uiso 1 1 calc R U . . .
H9D H 0.4751 0.3610 0.6827 0.118 Uiso 1 1 calc R U . . .
H9E H 0.5475 0.3659 0.6740 0.118 Uiso 1 1 calc R U . . .
N10 N 0.6245(4) 0.4776(3) 0.0334(6) 0.057(2) Uani 1 1 d . . . . .
H10C H 0.6516 0.4995 0.0274 0.086 Uiso 1 1 d R U . . .
H10D H 0.6255 0.4572 -0.0072 0.086 Uiso 1 1 d R U . . .
H10E H 0.6429 0.4675 0.0923 0.086 Uiso 1 1 d R U . . .
N11 N 0.5626(5) 0.5598(4) 0.1276(7) 0.092(3) Uani 1 1 d . . . . .
H11C H 0.5274 0.5788 0.1238 0.138 Uiso 1 1 calc R U . . .
H11D H 0.5808 0.5647 0.0819 0.138 Uiso 1 1 calc R U . . .
H11E H 0.5988 0.5620 0.1839 0.138 Uiso 1 1 calc R U . . .
N12 N 0.3123(8) 0.1530(3) 0.3167(10) 0.118(5) Uani 1 1 d . . . . .
H12C H 0.3282 0.1329 0.3608 0.178 Uiso 1 1 d R U . . .
H12D H 0.3394 0.1526 0.2795 0.178 Uiso 1 1 d R U . . .
H12E H 0.2649 0.1482 0.2818 0.178 Uiso 1 1 d R U . . .
N13 N 0.3742(5) 0.0888(3) 0.1190(6) 0.073(2) Uani 1 1 d . . . . .
H13C H 0.3893 0.0634 0.1445 0.110 Uiso 1 1 d R U . . .
H13D H 0.3546 0.0864 0.0562 0.110 Uiso 1 1 d R U . . .
H13E H 0.3401 0.0989 0.1409 0.110 Uiso 1 1 d R U . . .
N14 N 0.5602(6) 0.0626(3) 0.2750(9) 0.095(3) Uani 1 1 d . . . . .
H14C H 0.5355 0.0485 0.3057 0.142 Uiso 1 1 d R U . . .
H14D H 0.6046 0.0508 0.2872 0.142 Uiso 1 1 d R U . . .
H14E H 0.5349 0.0617 0.2129 0.142 Uiso 1 1 d R U . . .
N15 N 0.5886(5) 0.1352(3) 0.4396(7) 0.080(3) Uani 1 1 d . . . . .
H15C H 0.5764 0.1199 0.4816 0.119 Uiso 1 1 d R U . . .
H15D H 0.6366 0.1418 0.4636 0.119 Uiso 1 1 d R U . . .
H15E H 0.5796 0.1202 0.3866 0.119 Uiso 1 1 d R U . . .
N16 N 0.8240(3) 0.17896(18) 0.1347(4) 0.0361(13) Uani 1 1 d . . . . .
H16C H 0.8432 0.2036 0.1613 0.054 Uiso 1 1 d R U . . .
H16D H 0.8587 0.1638 0.1228 0.054 Uiso 1 1 d R U . . .
H16E H 0.8074 0.1646 0.1741 0.054 Uiso 1 1 d R U . . .
N17 N 0.9349(4) 0.2611(3) 0.2102(5) 0.064(2) Uani 1 1 d . . . . .
H17C H 0.9276 0.2598 0.1485 0.095 Uiso 1 1 d R U . . .
H17D H 0.9819 0.2546 0.2435 0.095 Uiso 1 1 d R U . . .
H17E H 0.9251 0.2872 0.2250 0.095 Uiso 1 1 d R U . . .
N18 N 0.1017(7) 0.0076(4) 0.7818(9) 0.108(4) Uani 1 1 d . U . . .
H18C H 0.1446 -0.0022 0.8220 0.162 Uiso 1 1 d R U . . .
H18D H 0.1086 0.0331 0.7608 0.162 Uiso 1 1 d R U . . .
H18E H 0.0843 -0.0102 0.7330 0.162 Uiso 1 1 d R U . . .
N19 N 0.9874(4) 0.0141(2) 0.8942(5) 0.0441(15) Uani 1 1 d . . . . .
H19C H 1.0198 0.0109 0.8649 0.066 Uiso 1 1 d R U . . .
H19D H 0.9794 0.0417 0.8996 0.066 Uiso 1 1 d R U . . .
H19E H 0.9448 0.0015 0.8607 0.066 Uiso 1 1 d R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Co1 Ge1 Ge4 57.78(3) . . ?
Co1 Ge1 Ge2 57.43(3) . . ?
Ge4 Ge1 Ge2 107.09(3) . . ?
Co1 Ge1 Ge3 55.48(2) . . ?
Ge4 Ge1 Ge3 59.40(2) . . ?
Ge2 Ge1 Ge3 58.58(2) . . ?
Co1 Ge1 Ge6 52.69(2) . . ?
Ge4 Ge1 Ge6 101.93(3) . . ?
Ge2 Ge1 Ge6 58.86(2) . . ?
Ge3 Ge1 Ge6 101.26(3) . . ?
Co1 Ge1 Ge5 52.38(2) . . ?
Ge4 Ge1 Ge5 58.54(2) . . ?
Ge2 Ge1 Ge5 101.58(3) . . ?
Ge3 Ge1 Ge5 101.13(3) . . ?
Ge6 Ge1 Ge5 53.43(2) . . ?
Co1 Ge2 Ge1 57.05(3) . . ?
Co1 Ge2 Ge3 57.39(2) . . ?
Ge1 Ge2 Ge3 63.91(3) . . ?
Co1 Ge2 Ge7 56.12(3) . . ?
Ge1 Ge2 Ge7 108.67(3) . . ?
Ge3 Ge2 Ge7 61.58(2) . . ?
Co1 Ge2 Ge6 54.91(2) . . ?
Ge1 Ge2 Ge6 65.12(2) . . ?
Ge3 Ge2 Ge6 109.49(3) . . ?
Ge7 Ge2 Ge6 94.28(3) . . ?
Co1 Ge2 K1 97.11(4) . . ?
Ge1 Ge2 K1 138.51(4) . . ?
Ge3 Ge2 K1 132.71(4) . . ?
Ge7 Ge2 K1 71.14(4) . . ?
Ge6 Ge2 K1 73.46(3) . . ?
Co1 Ge3 Ge2 56.68(2) . . ?
Co1 Ge3 Ge4 56.46(3) . . ?
Ge2 Ge3 Ge4 104.17(3) . . ?
Co1 Ge3 Ge7 55.11(3) . . ?
Ge2 Ge3 Ge7 59.37(2) . . ?
Ge4 Ge3 Ge7 103.97(3) . . ?
Co1 Ge3 Ge8 54.11(3) . . ?
Ge2 Ge3 Ge8 103.49(3) . . ?
Ge4 Ge3 Ge8 58.55(2) . . ?
Ge7 Ge3 Ge8 57.02(2) . . ?
Co1 Ge3 Ge1 54.48(2) . . ?
Ge2 Ge3 Ge1 57.51(2) . . ?
Ge4 Ge3 Ge1 56.90(2) . . ?
Ge7 Ge3 Ge1 102.29(3) . . ?
Ge8 Ge3 Ge1 100.96(3) . . ?
Co1 Ge4 Ge1 57.16(3) . . ?
Co1 Ge4 Ge8 55.53(3) . . ?
Ge1 Ge4 Ge8 108.57(3) . . ?
Co1 Ge4 Ge3 56.93(3) . . ?
Ge1 Ge4 Ge3 63.70(3) . . ?
Ge8 Ge4 Ge3 62.04(3) . . ?
Co1 Ge4 Ge5 55.05(3) . . ?
Ge1 Ge4 Ge5 66.16(3) . . ?
Ge8 Ge4 Ge5 92.66(3) . . ?
Ge3 Ge4 Ge5 109.47(3) . . ?
Co1 Ge4 K2 99.13(4) . . ?
Ge1 Ge4 K2 142.77(4) . . ?
Ge8 Ge4 K2 69.00(4) . . ?
Ge3 Ge4 K2 130.76(4) . . ?
Ge5 Ge4 K2 76.73(4) . . ?
Co1 Ge5 Ge6 56.88(3) . . ?
Co1 Ge5 Ge4 56.66(3) . . ?
Ge6 Ge5 Ge4 106.83(3) . . ?
Co1 Ge5 Ge1 53.30(2) . . ?
Ge6 Ge5 Ge1 62.60(2) . . ?
Ge4 Ge5 Ge1 55.30(2) . . ?
Co1 Ge5 Ge9 47.26(2) . . ?
Ge6 Ge5 Ge9 62.75(2) . . ?
Ge4 Ge5 Ge9 91.55(3) . . ?
Ge1 Ge5 Ge9 98.58(3) . . ?
Co1 Ge5 K4 121.22(4) . . ?
Ge6 Ge5 K4 66.25(4) . . ?
Ge4 Ge5 K4 166.48(4) . . ?
Ge1 Ge5 K4 111.88(4) . . ?
Ge9 Ge5 K4 95.02(4) . . ?
Co1 Ge5 K2 89.76(4) . . ?
Ge6 Ge5 K2 140.86(4) . . ?
Ge4 Ge5 K2 60.68(3) . . ?
Ge1 Ge5 K2 115.91(3) . . ?
Ge9 Ge5 K2 79.88(3) . . ?
K4 Ge5 K2 132.18(5) . . ?
Co1 Ge6 Ge5 57.18(3) . . ?
Co1 Ge6 Ge2 56.59(3) . . ?
Ge5 Ge6 Ge2 107.83(3) . . ?
Co1 Ge6 Ge1 53.89(2) . . ?
Ge5 Ge6 Ge1 63.97(2) . . ?
Ge2 Ge6 Ge1 56.02(2) . . ?
Co1 Ge6 Ge9 47.78(2) . . ?
Ge5 Ge6 Ge9 64.06(2) . . ?
Ge2 Ge6 Ge9 90.22(3) . . ?
Ge1 Ge6 Ge9 100.16(3) . . ?
Co1 Ge6 K4 124.65(5) . . ?
Ge5 Ge6 K4 69.52(4) . . ?
Ge2 Ge6 K4 169.48(4) . . ?
Ge1 Ge6 K4 115.11(4) . . ?
Ge9 Ge6 K4 97.37(4) . . ?
Co1 Ge6 K1 90.61(4) . . ?
Ge5 Ge6 K1 140.28(4) . . ?
Ge2 Ge6 K1 61.92(3) . . ?
Ge1 Ge6 K1 117.90(3) . . ?
Ge9 Ge6 K1 77.22(3) . . ?
K4 Ge6 K1 126.85(4) . . ?
Co1 Ge7 Ge8 56.48(3) . . ?
Co1 Ge7 Ge2 57.03(3) . . ?
Ge8 Ge7 Ge2 107.18(3) . . ?
Co1 Ge7 Ge3 56.67(3) . . ?
Ge8 Ge7 Ge3 62.07(3) . . ?
Ge2 Ge7 Ge3 59.06(2) . . ?
Co1 Ge7 K3 108.78(5) . . ?
Ge8 Ge7 K3 67.40(5) . . ?
Ge2 Ge7 K3 161.63(4) . . ?
Ge3 Ge7 K3 125.67(5) . . ?
Co1 Ge7 K1 93.12(4) . . ?
Ge8 Ge7 K1 141.90(4) . . ?
Ge2 Ge7 K1 64.10(3) . . ?
Ge3 Ge7 K1 123.15(4) . . ?
K3 Ge7 K1 108.56(5) . . ?
Co1 Ge8 Ge7 57.33(3) . . ?
Co1 Ge8 Ge4 57.50(3) . . ?
Ge7 Ge8 Ge4 107.75(3) . . ?
Co1 Ge8 Ge3 56.44(3) . . ?
Ge7 Ge8 Ge3 60.91(2) . . ?
Ge4 Ge8 Ge3 59.42(3) . . ?
Co1 Ge8 K3 110.59(5) . . ?
Ge7 Ge8 K3 68.98(5) . . ?
Ge4 Ge8 K3 163.49(4) . . ?
Ge3 Ge8 K3 126.06(5) . . ?
Co1 Ge8 K2 98.67(5) . . ?
Ge7 Ge8 K2 148.53(4) . . ?
Ge4 Ge8 K2 66.65(4) . . ?
Ge3 Ge8 K2 125.82(4) . . ?
K3 Ge8 K2 107.18(5) . . ?
Co1 Ge9 Co2 166.85(4) . . ?
Co1 Ge9 Ge6 53.97(3) . . ?
Co2 Ge9 Ge6 115.84(3) . . ?
Co1 Ge9 Ge13 129.90(4) . . ?
Co2 Ge9 Ge13 53.78(3) . . ?
Ge6 Ge9 Ge13 150.85(3) . . ?
Co1 Ge9 Ge10 134.80(4) . . ?
Co2 Ge9 Ge10 53.33(3) . . ?
Ge6 Ge9 Ge10 109.20(3) . . ?
Ge13 Ge9 Ge10 86.35(3) . . ?
Co1 Ge9 Ge12 116.09(3) . . ?
Co2 Ge9 Ge12 54.01(3) . . ?
Ge6 Ge9 Ge12 98.10(3) . . ?
Ge13 Ge9 Ge12 53.05(2) . . ?
Ge10 Ge9 Ge12 107.25(3) . . ?
Co1 Ge9 Ge5 53.59(3) . . ?
Co2 Ge9 Ge5 114.37(3) . . ?
Ge6 Ge9 Ge5 53.19(2) . . ?
Ge13 Ge9 Ge5 103.18(3) . . ?
Ge10 Ge9 Ge5 155.08(3) . . ?
Ge12 Ge9 Ge5 63.74(2) . . ?
Co1 Ge9 Ge11 119.92(3) . . ?
Co2 Ge9 Ge11 53.49(3) . . ?
Ge6 Ge9 Ge11 67.33(2) . . ?
Ge13 Ge9 Ge11 107.12(3) . . ?
Ge10 Ge9 Ge11 53.72(2) . . ?
Ge12 Ge9 Ge11 81.36(2) . . ?
Ge5 Ge9 Ge11 101.36(3) . . ?
Co1 Ge9 K3 104.81(4) . . ?
Co2 Ge9 K3 88.11(4) . . ?
Ge6 Ge9 K3 145.26(4) . . ?
Ge13 Ge9 K3 63.58(4) . . ?
Ge10 Ge9 K3 63.91(4) . . ?
Ge12 Ge9 K3 116.58(4) . . ?
Ge5 Ge9 K3 140.94(5) . . ?
Ge11 Ge9 K3 117.55(4) . . ?
Co2 Ge10 Ge11 56.66(3) . . ?
Co2 Ge10 Ge14 57.16(3) . . ?
Ge11 Ge10 Ge14 108.74(3) . . ?
Co2 Ge10 Ge15 55.74(3) . . ?
Ge11 Ge10 Ge15 65.36(3) . . ?
Ge14 Ge10 Ge15 57.82(2) . . ?
Co2 Ge10 Ge9 47.51(2) . . ?
Ge11 Ge10 Ge9 63.29(2) . . ?
Ge14 Ge10 Ge9 89.55(3) . . ?
Ge15 Ge10 Ge9 101.81(3) . . ?
Co2 Ge10 K1 115.33(4) . . ?
Ge11 Ge10 K1 68.46(3) . . ?
Ge14 Ge10 K1 169.10(4) . . ?
Ge15 Ge10 K1 126.39(4) . . ?
Ge9 Ge10 K1 79.78(3) . . ?
Co2 Ge10 K1 114.94(4) . 3_666 ?
Ge11 Ge10 K1 71.21(4) . 3_666 ?
Ge14 Ge10 K1 118.41(4) . 3_666 ?
Ge15 Ge10 K1 69.34(3) . 3_666 ?
Ge9 Ge10 K1 132.46(4) . 3_666 ?
K1 Ge10 K1 71.27(4) . 3_666 ?
Co2 Ge10 K3 89.69(5) . . ?
Ge11 Ge10 K3 133.55(4) . . ?
Ge14 Ge10 K3 66.69(4) . . ?
Ge15 Ge10 K3 124.12(4) . . ?
Ge9 Ge10 K3 70.38(4) . . ?
K1 Ge10 K3 107.10(4) . . ?
K1 Ge10 K3 153.89(5) 3_666 . ?
Co2 Ge11 Ge10 56.25(3) . . ?
Co2 Ge11 Ge17 57.25(3) . . ?
Ge10 Ge11 Ge17 106.46(3) . . ?
Co2 Ge11 Ge9 47.35(2) . . ?
Ge10 Ge11 Ge9 63.00(2) . . ?
Ge17 Ge11 Ge9 92.09(3) . . ?
Co2 Ge11 K1 114.34(4) . . ?
Ge10 Ge11 K1 67.69(3) . . ?
Ge17 Ge11 K1 171.15(4) . . ?
Ge9 Ge11 K1 79.36(3) . . ?
Co2 Ge11 K1 110.27(4) . 3_666 ?
Ge10 Ge11 K1 65.80(3) . 3_666 ?
Ge17 Ge11 K1 114.87(3) . 3_666 ?
Ge9 Ge11 K1 127.00(4) . 3_666 ?
K1 Ge11 K1 69.51(4) . 3_666 ?
Co2 Ge11 K4 97.58(4) . . ?
Ge10 Ge11 K4 148.76(4) . . ?
Ge17 Ge11 K4 63.67(4) . . ?
Ge9 Ge11 K4 87.02(3) . . ?
K1 Ge11 K4 117.61(4) . . ?
K1 Ge11 K4 145.35(4) 3_666 . ?
Co2 Ge12 Ge13 56.74(3) . . ?
Co2 Ge12 Ge17 57.10(3) . . ?
Ge13 Ge12 Ge17 106.72(3) . . ?
Co2 Ge12 Ge9 47.38(2) . . ?
Ge13 Ge12 Ge9 62.99(2) . . ?
Ge17 Ge12 Ge9 92.25(3) . . ?
Co2 Ge12 K2 112.73(4) . . ?
Ge13 Ge12 K2 63.15(4) . . ?
Ge17 Ge12 K2 169.53(4) . . ?
Ge9 Ge12 K2 80.80(3) . . ?
Co2 Ge12 K4 98.31(4) . . ?
Ge13 Ge12 K4 149.77(4) . . ?
Ge17 Ge12 K4 64.30(3) . . ?
Ge9 Ge12 K4 87.83(4) . . ?
K2 Ge12 K4 122.79(4) . . ?
Co2 Ge13 Ge12 57.67(3) . . ?
Co2 Ge13 Ge14 56.68(3) . . ?
Ge12 Ge13 Ge14 109.24(3) . . ?
Co2 Ge13 Ge16 55.22(3) . . ?
Ge12 Ge13 Ge16 65.77(3) . . ?
Ge14 Ge13 Ge16 57.30(2) . . ?
Co2 Ge13 Ge9 47.86(2) . . ?
Ge12 Ge13 Ge9 63.96(2) . . ?
Ge14 Ge13 Ge9 89.44(3) . . ?
Ge16 Ge13 Ge9 101.68(3) . . ?
Co2 Ge13 K2 124.56(5) . . ?
Ge12 Ge13 K2 75.98(4) . . ?
Ge14 Ge13 K2 171.33(4) . . ?
Ge16 Ge13 K2 131.16(4) . . ?
Ge9 Ge13 K2 86.75(4) . . ?
Co2 Ge13 K3 90.25(5) . . ?
Ge12 Ge13 K3 134.88(4) . . ?
Ge14 Ge13 K3 66.82(4) . . ?
Ge16 Ge13 K3 123.81(5) . . ?
Ge9 Ge13 K3 70.98(4) . . ?
K2 Ge13 K3 104.55(5) . . ?
Co2 Ge14 Ge15 57.09(3) . . ?
Co2 Ge14 Ge16 56.85(3) . . ?
Ge15 Ge14 Ge16 62.39(3) . . ?
Co2 Ge14 Ge10 55.05(3) . . ?
Ge15 Ge14 Ge10 62.74(3) . . ?
Ge16 Ge14 Ge10 107.67(3) . . ?
Co2 Ge14 Ge13 54.61(3) . . ?
Ge15 Ge14 Ge13 107.63(3) . . ?
Ge16 Ge14 Ge13 62.82(3) . . ?
Ge10 Ge14 Ge13 94.49(3) . . ?
Co2 Ge14 K3 90.56(4) . . ?
Ge15 Ge14 K3 131.98(4) . . ?
Ge16 Ge14 K3 131.32(5) . . ?
Ge10 Ge14 K3 69.71(4) . . ?
Ge13 Ge14 K3 68.87(5) . . ?
Co2 Ge15 Ge14 57.26(3) . . ?
Co2 Ge15 Ge17 56.05(3) . . ?
Ge14 Ge15 Ge17 105.52(3) . . ?
Co2 Ge15 Ge16 55.60(3) . . ?
Ge14 Ge15 Ge16 58.88(2) . . ?
Ge17 Ge15 Ge16 58.54(2) . . ?
Co2 Ge15 Ge10 53.88(3) . . ?
Ge14 Ge15 Ge10 59.44(2) . . ?
Ge17 Ge15 Ge10 101.25(3) . . ?
Ge16 Ge15 Ge10 102.70(3) . . ?
Co2 Ge15 K1 109.87(4) . 3_666 ?
Ge14 Ge15 K1 116.15(4) . 3_666 ?
Ge17 Ge15 K1 114.14(4) . 3_666 ?
Ge16 Ge15 K1 165.42(3) . 3_666 ?
Ge10 Ge15 K1 65.12(3) . 3_666 ?
Co2 Ge16 Ge14 57.27(3) . . ?
Co2 Ge16 Ge17 56.71(3) . . ?
Ge14 Ge16 Ge17 106.60(3) . . ?
Co2 Ge16 Ge15 55.83(3) . . ?
Ge14 Ge16 Ge15 58.73(3) . . ?
Ge17 Ge16 Ge15 60.04(3) . . ?
Co2 Ge16 Ge13 53.63(2) . . ?
Ge14 Ge16 Ge13 59.88(2) . . ?
Ge17 Ge16 Ge13 100.78(3) . . ?
Ge15 Ge16 Ge13 102.84(3) . . ?
Co2 Ge17 Ge11 56.01(3) . . ?
Co2 Ge17 Ge12 56.38(3) . . ?
Ge11 Ge17 Ge12 91.77(3) . . ?
Co2 Ge17 Ge16 56.80(3) . . ?
Ge11 Ge17 Ge16 109.61(3) . . ?
Ge12 Ge17 Ge16 67.02(3) . . ?
Co2 Ge17 Ge15 56.39(3) . . ?
Ge11 Ge17 Ge15 66.24(3) . . ?
Ge12 Ge17 Ge15 109.73(3) . . ?
Ge16 Ge17 Ge15 61.43(3) . . ?
Co2 Ge17 K4 104.57(4) . . ?
Ge11 Ge17 K4 75.08(4) . . ?
Ge12 Ge17 K4 74.18(4) . . ?
Ge16 Ge17 K4 140.95(4) . . ?
Ge15 Ge17 K4 141.13(4) . . ?
Ge9 Co1 Ge8 80.81(3) . . ?
Ge9 Co1 Ge6 78.25(3) . . ?
Ge8 Co1 Ge6 159.03(4) . . ?
Ge9 Co1 Ge5 79.15(3) . . ?
Ge8 Co1 Ge5 108.93(4) . . ?
Ge6 Co1 Ge5 65.94(3) . . ?
Ge9 Co1 Ge7 79.72(3) . . ?
Ge8 Co1 Ge7 66.19(3) . . ?
Ge6 Co1 Ge7 110.71(4) . . ?
Ge5 Co1 Ge7 158.83(4) . . ?
Ge9 Co1 Ge1 147.12(4) . . ?
Ge8 Co1 Ge1 126.05(4) . . ?
Ge6 Co1 Ge1 73.43(3) . . ?
Ge5 Co1 Ge1 74.32(3) . . ?
Ge7 Co1 Ge1 125.88(4) . . ?
Ge9 Co1 Ge2 118.45(4) . . ?
Ge8 Co1 Ge2 123.92(4) . . ?
Ge6 Co1 Ge2 68.50(3) . . ?
Ge5 Co1 Ge2 125.65(4) . . ?
Ge7 Co1 Ge2 66.86(3) . . ?
Ge1 Co1 Ge2 65.52(3) . . ?
Ge9 Co1 Ge4 121.69(4) . . ?
Ge8 Co1 Ge4 66.98(3) . . ?
Ge6 Co1 Ge4 124.35(4) . . ?
Ge5 Co1 Ge4 68.29(3) . . ?
Ge7 Co1 Ge4 123.21(4) . . ?
Ge1 Co1 Ge4 65.06(3) . . ?
Ge2 Co1 Ge4 119.86(4) . . ?
Ge9 Co1 Ge3 142.77(4) . . ?
Ge8 Co1 Ge3 69.45(3) . . ?
Ge6 Co1 Ge3 130.04(4) . . ?
Ge5 Co1 Ge3 130.94(4) . . ?
Ge7 Co1 Ge3 68.22(3) . . ?
Ge1 Co1 Ge3 70.04(3) . . ?
Ge2 Co1 Ge3 65.92(3) . . ?
Ge4 Co1 Ge3 66.61(3) . . ?
Ge9 Co2 Ge10 79.17(3) . . ?
Ge9 Co2 Ge13 78.36(3) . . ?
Ge10 Co2 Ge13 113.09(4) . . ?
Ge9 Co2 Ge11 79.16(3) . . ?
Ge10 Co2 Ge11 67.10(3) . . ?
Ge13 Co2 Ge11 156.98(4) . . ?
Ge9 Co2 Ge12 78.61(3) . . ?
Ge10 Co2 Ge12 157.48(4) . . ?
Ge13 Co2 Ge12 65.59(3) . . ?
Ge11 Co2 Ge12 104.96(4) . . ?
Ge9 Co2 Ge17 120.91(4) . . ?
Ge10 Co2 Ge17 123.58(4) . . ?
Ge13 Co2 Ge17 122.14(4) . . ?
Ge11 Co2 Ge17 66.74(3) . . ?
Ge12 Co2 Ge17 66.52(3) . . ?
Ge9 Co2 Ge16 145.64(4) . . ?
Ge10 Co2 Ge16 127.22(4) . . ?
Ge13 Co2 Ge16 71.15(3) . . ?
Ge11 Co2 Ge16 128.43(4) . . ?
Ge12 Co2 Ge16 74.68(3) . . ?
Ge17 Co2 Ge16 66.49(3) . . ?
Ge9 Co2 Ge15 145.60(4) . . ?
Ge10 Co2 Ge15 70.38(3) . . ?
Ge13 Co2 Ge15 128.04(4) . . ?
Ge11 Co2 Ge15 74.59(3) . . ?
Ge12 Co2 Ge15 129.44(4) . . ?
Ge17 Co2 Ge15 67.56(3) . . ?
Ge16 Co2 Ge15 68.57(3) . . ?
Ge9 Co2 Ge14 117.08(4) . . ?
Ge10 Co2 Ge14 67.79(3) . . ?
Ge13 Co2 Ge14 68.71(3) . . ?
Ge11 Co2 Ge14 127.26(4) . . ?
Ge12 Co2 Ge14 126.79(4) . . ?
Ge17 Co2 Ge14 122.01(4) . . ?
Ge16 Co2 Ge14 65.87(3) . . ?
Ge15 Co2 Ge14 65.65(3) . . ?
Ge2 K1 Ge10 104.17(4) . . ?
Ge2 K1 Ge10 140.83(5) . 3_666 ?
Ge10 K1 Ge10 108.73(4) . 3_666 ?
Ge2 K1 Ge11 94.65(4) . . ?
Ge10 K1 Ge11 43.84(2) . . ?
Ge10 K1 Ge11 94.56(4) 3_666 . ?
Ge2 K1 Ge7 44.76(2) . . ?
Ge10 K1 Ge7 68.81(3) . . ?
Ge10 K1 Ge7 173.52(6) 3_666 . ?
Ge11 K1 Ge7 87.59(4) . . ?
Ge2 K1 Ge15 113.58(4) . 3_666 ?
Ge10 K1 Ge15 139.80(5) . 3_666 ?
Ge10 K1 Ge15 45.54(2) 3_666 3_666 ?
Ge11 K1 Ge15 139.82(5) . 3_666 ?
Ge7 K1 Ge15 132.59(5) . 3_666 ?
Ge2 K1 Ge11 154.70(5) . 3_666 ?
Ge10 K1 Ge11 92.58(4) . 3_666 ?
Ge10 K1 Ge11 42.99(2) 3_666 3_666 ?
Ge11 K1 Ge11 110.49(4) . 3_666 ?
Ge7 K1 Ge11 130.57(5) . 3_666 ?
Ge15 K1 Ge11 47.24(2) 3_666 3_666 ?
Ge2 K1 Ge6 44.62(2) . . ?
Ge10 K1 Ge6 81.77(3) . . ?
Ge10 K1 Ge6 120.53(5) 3_666 . ?
Ge11 K1 Ge6 52.76(3) . . ?
Ge7 K1 Ge6 65.51(3) . . ?
Ge15 K1 Ge6 135.63(5) 3_666 . ?
Ge11 K1 Ge6 159.55(5) 3_666 . ?
Ge2 K1 K1 151.14(7) . 3_666 ?
Ge10 K1 K1 54.43(4) . 3_666 ?
Ge10 K1 K1 54.30(3) 3_666 3_666 ?
Ge11 K1 K1 56.62(4) . 3_666 ?
Ge7 K1 K1 122.92(6) . 3_666 ?
Ge15 K1 K1 93.06(5) 3_666 3_666 ?
Ge11 K1 K1 53.86(4) 3_666 3_666 ?
Ge6 K1 K1 108.27(6) . 3_666 ?
N7 K2 N6 77.4(3) 4_565 4_565 ?
N7 K2 N5 106.2(2) 4_565 4_565 ?
N6 K2 N5 72.8(3) 4_565 4_565 ?
N7 K2 Ge4 136.13(19) 4_565 . ?
N6 K2 Ge4 139.08(19) 4_565 . ?
N5 K2 Ge4 74.69(16) 4_565 . ?
N7 K2 K4 52.11(15) 4_565 4_565 ?
N6 K2 K4 58.10(19) 4_565 4_565 ?
N5 K2 K4 54.71(17) 4_565 4_565 ?
Ge4 K2 K4 118.13(7) . 4_565 ?
N7 K2 Ge13 80.69(15) 4_565 . ?
N6 K2 Ge13 110.45(18) 4_565 . ?
N5 K2 Ge13 172.98(18) 4_565 . ?
Ge4 K2 Ge13 99.63(4) . . ?
K4 K2 Ge13 132.32(6) 4_565 . ?
N7 K2 Ge8 145.14(15) 4_565 . ?
N6 K2 Ge8 125.4(2) 4_565 . ?
N5 K2 Ge8 105.87(17) 4_565 . ?
Ge4 K2 Ge8 44.35(3) . . ?
K4 K2 Ge8 159.94(7) 4_565 . ?
Ge13 K2 Ge8 67.13(3) . . ?
N7 K2 Ge12 64.35(15) 4_565 . ?
N6 K2 Ge12 133.62(19) 4_565 . ?
N5 K2 Ge12 141.1(2) 4_565 . ?
Ge4 K2 Ge12 87.21(4) . . ?
K4 K2 Ge12 109.62(6) 4_565 . ?
Ge13 K2 Ge12 40.87(2) . . ?
Ge8 K2 Ge12 82.11(4) . . ?
N7 K2 Ge5 97.38(17) 4_565 . ?
N6 K2 Ge5 171.1(2) 4_565 . ?
N5 K2 Ge5 102.3(2) 4_565 . ?
Ge4 K2 Ge5 42.58(3) . . ?
K4 K2 Ge5 113.03(7) 4_565 . ?
Ge13 K2 Ge5 75.33(4) . . ?
Ge8 K2 Ge5 62.64(3) . . ?
Ge12 K2 Ge5 46.87(3) . . ?
N11 K3 N10 72.7(3) . . ?
N11 K3 N10 82.3(3) . 3_665 ?
N10 K3 N10 108.25(17) . 3_665 ?
N11 K3 K3 68.5(2) . 3_665 ?
N10 K3 K3 54.45(14) . 3_665 ?
N10 K3 K3 53.80(15) 3_665 3_665 ?
N11 K3 Ge8 156.9(2) . . ?
N10 K3 Ge8 125.54(19) . . ?
N10 K3 Ge8 78.30(16) 3_665 . ?
K3 K3 Ge8 108.68(10) 3_665 . ?
N11 K3 Ge7 117.7(2) . . ?
N10 K3 Ge7 169.17(19) . . ?
N10 K3 Ge7 71.77(15) 3_665 . ?
K3 K3 Ge7 124.52(8) 3_665 . ?
Ge8 K3 Ge7 43.62(3) . . ?
N11 K3 Ge14 91.9(2) . . ?
N10 K3 Ge14 75.64(14) . . ?
N10 K3 Ge14 171.5(2) 3_665 . ?
K3 K3 Ge14 129.54(8) 3_665 . ?
Ge8 K3 Ge14 105.82(5) . . ?
Ge7 K3 Ge14 105.88(5) . . ?
N11 K3 Ge13 134.7(2) . . ?
N10 K3 Ge13 83.32(15) . . ?
N10 K3 Ge13 142.51(18) 3_665 . ?
K3 K3 Ge13 125.52(12) 3_665 . ?
Ge8 K3 Ge13 66.62(4) . . ?
Ge7 K3 Ge13 90.42(4) . . ?
Ge14 K3 Ge13 44.31(3) . . ?
N11 K3 Ge10 91.2(2) . . ?
N10 K3 Ge10 116.97(15) . . ?
N10 K3 Ge10 129.94(18) 3_665 . ?
K3 K3 Ge10 159.28(12) 3_665 . ?
Ge8 K3 Ge10 91.58(4) . . ?
Ge7 K3 Ge10 67.80(4) . . ?
Ge14 K3 Ge10 43.60(3) . . ?
Ge13 K3 Ge10 66.03(3) . . ?
N11 K3 Ge9 136.1(2) . . ?
N10 K3 Ge9 128.48(15) . . ?
N10 K3 Ge9 116.15(15) 3_665 . ?
K3 K3 Ge9 155.00(12) 3_665 . ?
Ge8 K3 Ge9 47.36(3) . . ?
Ge7 K3 Ge9 46.86(3) . . ?
Ge14 K3 Ge9 64.26(3) . . ?
Ge13 K3 Ge9 45.44(3) . . ?
Ge10 K3 Ge9 45.71(3) . . ?
N11 K3 H10E 75.9 . . ?
N10 K3 H10E 17.7 . . ?
N10 K3 H10E 125.9 3_665 . ?
K3 K3 H10E 72.1 3_665 . ?
Ge8 K3 H10E 126.1 . . ?
Ge7 K3 H10E 160.7 . . ?
Ge14 K3 H10E 57.9 . . ?
Ge13 K3 H10E 70.7 . . ?
Ge10 K3 H10E 99.8 . . ?
Ge9 K3 H10E 113.8 . . ?
N7 K4 N5 105.3(2) . . ?
N7 K4 N9 69.4(2) . . ?
N5 K4 N9 128.6(3) . . ?
N7 K4 N8 75.3(3) . . ?
N5 K4 N8 66.5(3) . . ?
N9 K4 N8 62.8(3) . . ?
N7 K4 Ge6 163.64(18) . . ?
N5 K4 Ge6 88.60(16) . . ?
N9 K4 Ge6 95.22(18) . . ?
N8 K4 Ge6 103.2(3) . . ?
N7 K4 Ge5 148.2(2) . . ?
N5 K4 Ge5 72.56(17) . . ?
N9 K4 Ge5 137.46(18) . . ?
N8 K4 Ge5 127.9(2) . . ?
Ge6 K4 Ge5 44.23(2) . . ?
N7 K4 K2 52.49(16) . 4_566 ?
N5 K4 K2 53.33(15) . 4_566 ?
N9 K4 K2 107.71(18) . 4_566 ?
N8 K4 K2 64.0(3) . 4_566 ?
Ge6 K4 K2 141.92(6) . 4_566 ?
Ge5 K4 K2 113.34(7) . 4_566 ?
N7 K4 Ge17 83.97(16) . . ?
N5 K4 Ge17 153.2(2) . . ?
N9 K4 Ge17 78.21(17) . . ?
N8 K4 Ge17 140.1(2) . . ?
Ge6 K4 Ge17 87.42(4) . . ?
Ge5 K4 Ge17 86.29(4) . . ?
K2 K4 Ge17 126.22(7) 4_566 . ?
N7 K4 Ge12 107.63(18) . . ?
N5 K4 Ge12 112.1(2) . . ?
N9 K4 Ge12 118.18(18) . . ?
N8 K4 Ge12 177.0(2) . . ?
Ge6 K4 Ge12 74.01(3) . . ?
Ge5 K4 Ge12 49.36(3) . . ?
K2 K4 Ge12 117.52(7) 4_566 . ?
Ge17 K4 Ge12 41.52(3) . . ?
N7 K4 Ge11 114.29(16) . . ?
N5 K4 Ge11 140.35(16) . . ?
N9 K4 Ge11 66.85(17) . . ?
N8 K4 Ge11 120.2(3) . . ?
Ge6 K4 Ge11 51.89(3) . . ?
Ge5 K4 Ge11 75.37(3) . . ?
K2 K4 Ge11 166.06(6) 4_566 . ?
Ge17 K4 Ge11 41.25(2) . . ?
Ge12 K4 Ge11 58.97(3) . . ?
N7 K4 H5E 122.8 . . ?
N5 K4 H5E 17.6 . . ?
N9 K4 H5E 130.7 . . ?
N8 K4 H5E 74.4 . . ?
Ge6 K4 H5E 71.2 . . ?
Ge5 K4 H5E 58.2 . . ?
K2 K4 H5E 70.8 4_566 . ?
Ge17 K4 H5E 144.1 . . ?
Ge12 K4 H5E 103.5 . . ?
Ge11 K4 H5E 122.8 . . ?
N7 K4 H7C 18.1 . . ?
N5 K4 H7C 116.7 . . ?
N9 K4 H7C 74.2 . . ?
N8 K4 H7C 93.1 . . ?
Ge6 K4 H7C 154.0 . . ?
Ge5 K4 H7C 134.7 . . ?
K2 K4 H7C 63.7 4_566 . ?
Ge17 K4 H7C 67.4 . . ?
Ge12 K4 H7C 89.9 . . ?
Ge11 K4 H7C 102.4 . . ?
H5E K4 H7C 133.6 . . ?
N7 K4 H7E 17.4 . . ?
N5 K4 H7E 113.0 . . ?
N9 K4 H7E 52.2 . . ?
N8 K4 H7E 67.0 . . ?
Ge6 K4 H7E 147.3 . . ?
Ge5 K4 H7E 163.5 . . ?
K2 K4 H7E 64.0 4_566 . ?
Ge17 K4 H7E 83.3 . . ?
Ge12 K4 H7E 115.9 . . ?
Ge11 K4 H7E 104.4 . . ?
H5E K4 H7E 129.7 . . ?
H7C K4 H7E 28.8 . . ?
O2 K5 O5 133.94(15) . . ?
O2 K5 O4 121.03(15) . . ?
O5 K5 O4 99.47(15) . . ?
O2 K5 O6 96.88(14) . . ?
O5 K5 O6 59.05(13) . . ?
O4 K5 O6 137.23(14) . . ?
O2 K5 O3 99.69(15) . . ?
O5 K5 O3 121.04(14) . . ?
O4 K5 O3 58.69(14) . . ?
O6 K5 O3 98.73(14) . . ?
O2 K5 O1 59.38(13) . . ?
O5 K5 O1 95.61(13) . . ?
O4 K5 O1 99.34(13) . . ?
O6 K5 O1 117.97(14) . . ?
O3 K5 O1 138.44(14) . . ?
O2 K5 N2 62.85(15) . . ?
O5 K5 N2 118.32(15) . . ?
O4 K5 N2 118.04(16) . . ?
O6 K5 N2 60.19(15) . . ?
O3 K5 N2 59.91(16) . . ?
O1 K5 N2 121.42(15) . . ?
O2 K5 N1 118.20(14) . . ?
O5 K5 N1 61.54(14) . . ?
O4 K5 N1 60.98(15) . . ?
O6 K5 N1 119.89(15) . . ?
O3 K5 N1 119.00(16) . . ?
O1 K5 N1 59.73(13) . . ?
N2 K5 N1 178.77(17) . . ?
C13 N1 C1 109.7(6) . . ?
C13 N1 C12 110.3(6) . . ?
C1 N1 C12 108.6(5) . . ?
C13 N1 K5 108.0(4) . . ?
C1 N1 K5 111.4(4) . . ?
C12 N1 K5 108.8(4) . . ?
C7 N2 C18 109.6(6) . . ?
C7 N2 C6 109.2(6) . . ?
C18 N2 C6 110.2(6) . . ?
C7 N2 K5 111.3(4) . . ?
C18 N2 K5 110.5(4) . . ?
C6 N2 K5 105.9(4) . . ?
C3 O1 C2 111.0(5) . . ?
C3 O1 K5 113.8(4) . . ?
C2 O1 K5 114.3(3) . . ?
C5 O2 C4 111.3(6) . . ?
C5 O2 K5 111.9(4) . . ?
C4 O2 K5 114.8(4) . . ?
C8 O3 C9 111.1(6) . . ?
C8 O3 K5 115.7(4) . . ?
C9 O3 K5 114.9(4) . . ?
C11 O4 C10 111.7(6) . . ?
C11 O4 K5 115.1(4) . . ?
C10 O4 K5 115.6(4) . . ?
C14 O5 C15 110.7(5) . . ?
C14 O5 K5 113.3(4) . . ?
C15 O5 K5 113.8(4) . . ?
C17 O6 C16 112.2(5) . . ?
C17 O6 K5 113.6(4) . . ?
C16 O6 K5 115.5(4) . . ?
N1 C1 C2 113.1(5) . . ?
N1 C1 H1A 109.0 . . ?
C2 C1 H1A 109.0 . . ?
N1 C1 H1B 109.0 . . ?
C2 C1 H1B 109.0 . . ?
H1A C1 H1B 107.8 . . ?
O1 C2 C1 107.8(5) . . ?
O1 C2 H2A 110.1 . . ?
C1 C2 H2A 110.1 . . ?
O1 C2 H2B 110.1 . . ?
C1 C2 H2B 110.1 . . ?
H2A C2 H2B 108.5 . . ?
O1 C3 C4 109.0(5) . . ?
O1 C3 H3A 109.9 . . ?
C4 C3 H3A 109.9 . . ?
O1 C3 H3B 109.9 . . ?
C4 C3 H3B 109.9 . . ?
H3A C3 H3B 108.3 . . ?
O2 C4 C3 108.7(6) . . ?
O2 C4 H4A 110.0 . . ?
C3 C4 H4A 110.0 . . ?
O2 C4 H4B 110.0 . . ?
C3 C4 H4B 110.0 . . ?
H4A C4 H4B 108.3 . . ?
O2 C5 C6 109.9(7) . . ?
O2 C5 H5A 109.7 . . ?
C6 C5 H5A 109.7 . . ?
O2 C5 H5B 109.7 . . ?
C6 C5 H5B 109.7 . . ?
H5A C5 H5B 108.2 . . ?
N2 C6 C5 113.8(7) . . ?
N2 C6 H6A 108.8 . . ?
C5 C6 H6A 108.8 . . ?
N2 C6 H6B 108.8 . . ?
C5 C6 H6B 108.8 . . ?
H6A C6 H6B 107.7 . . ?
N2 C7 C8 114.6(6) . . ?
N2 C7 H7A 108.6 . . ?
C8 C7 H7A 108.6 . . ?
N2 C7 H7B 108.6 . . ?
C8 C7 H7B 108.6 . . ?
H7A C7 H7B 107.6 . . ?
O3 C8 C7 109.5(6) . . ?
O3 C8 H8A 109.8 . . ?
C7 C8 H8A 109.8 . . ?
O3 C8 H8B 109.8 . . ?
C7 C8 H8B 109.8 . . ?
H8A C8 H8B 108.2 . . ?
O3 C9 C10 108.5(6) . . ?
O3 C9 H9A 110.0 . . ?
C10 C9 H9A 110.0 . . ?
O3 C9 H9B 110.0 . . ?
C10 C9 H9B 110.0 . . ?
H9A C9 H9B 108.4 . . ?
O4 C10 C9 109.4(6) . . ?
O4 C10 H10A 109.8 . . ?
C9 C10 H10A 109.8 . . ?
O4 C10 H10B 109.8 . . ?
C9 C10 H10B 109.8 . . ?
H10A C10 H10B 108.2 . . ?
O4 C11 C12 109.6(6) . . ?
O4 C11 H11A 109.8 . . ?
C12 C11 H11A 109.8 . . ?
O4 C11 H11B 109.8 . . ?
C12 C11 H11B 109.8 . . ?
H11A C11 H11B 108.2 . . ?
N1 C12 C11 114.2(6) . . ?
N1 C12 H12A 108.7 . . ?
C11 C12 H12A 108.7 . . ?
N1 C12 H12B 108.7 . . ?
C11 C12 H12B 108.7 . . ?
H12A C12 H12B 107.6 . . ?
N1 C13 C14 113.5(6) . . ?
N1 C13 H13A 108.9 . . ?
C14 C13 H13A 108.9 . . ?
N1 C13 H13B 108.9 . . ?
C14 C13 H13B 108.9 . . ?
H13A C13 H13B 107.7 . . ?
O5 C14 C13 109.9(6) . . ?
O5 C14 H14A 109.7 . . ?
C13 C14 H14A 109.7 . . ?
O5 C14 H14B 109.7 . . ?
C13 C14 H14B 109.7 . . ?
H14A C14 H14B 108.2 . . ?
O5 C15 C16 108.2(6) . . ?
O5 C15 H15A 110.0 . . ?
C16 C15 H15A 110.0 . . ?
O5 C15 H15B 110.0 . . ?
C16 C15 H15B 110.0 . . ?
H15A C15 H15B 108.4 . . ?
O6 C16 C15 108.7(5) . . ?
O6 C16 H16A 110.0 . . ?
C15 C16 H16A 110.0 . . ?
O6 C16 H16B 110.0 . . ?
C15 C16 H16B 110.0 . . ?
H16A C16 H16B 108.3 . . ?
O6 C17 C18 108.9(5) . . ?
O6 C17 H17A 109.9 . . ?
C18 C17 H17A 109.9 . . ?
O6 C17 H17B 109.9 . . ?
C18 C17 H17B 109.9 . . ?
H17A C17 H17B 108.3 . . ?
N2 C18 C17 113.0(6) . . ?
N2 C18 H18A 109.0 . . ?
C17 C18 H18A 109.0 . . ?
N2 C18 H18B 109.0 . . ?
C17 C18 H18B 109.0 . . ?
H18A C18 H18B 107.8 . . ?
O7 K6 O9 117.28(14) . . ?
O7 K6 O11 98.79(14) . . ?
O9 K6 O11 138.60(14) . . ?
O7 K6 O8 60.47(14) . . ?
O9 K6 O8 97.11(14) . . ?
O11 K6 O8 119.11(14) . . ?
O7 K6 O10 96.49(13) . . ?
O9 K6 O10 60.65(13) . . ?
O11 K6 O10 97.62(13) . . ?
O8 K6 O10 137.99(14) . . ?
O7 K6 O12 140.73(14) . . ?
O9 K6 O12 97.09(13) . . ?
O11 K6 O12 60.21(13) . . ?
O8 K6 O12 98.97(14) . . ?
O10 K6 O12 117.74(13) . . ?
O7 K6 N4 120.01(14) . . ?
O9 K6 N4 60.33(13) . . ?
O11 K6 N4 119.15(14) . . ?
O8 K6 N4 60.74(14) . . ?
O10 K6 N4 119.80(14) . . ?
O12 K6 N4 60.19(13) . . ?
O7 K6 N3 60.03(14) . . ?
O9 K6 N3 119.74(14) . . ?
O11 K6 N3 60.76(14) . . ?
O8 K6 N3 119.28(14) . . ?
O10 K6 N3 60.26(13) . . ?
O12 K6 N3 119.72(14) . . ?
N4 K6 N3 179.90(16) . . ?
C30 N3 C31 110.2(5) . . ?
C30 N3 C19 109.9(5) . . ?
C31 N3 C19 109.5(5) . . ?
C30 N3 K6 109.2(4) . . ?
C31 N3 K6 108.6(4) . . ?
C19 N3 K6 109.4(4) . . ?
C24 N4 C36 109.5(5) . . ?
C24 N4 C25 110.4(5) . . ?
C36 N4 C25 108.4(5) . . ?
C24 N4 K6 108.9(4) . . ?
C36 N4 K6 110.3(4) . . ?
C25 N4 K6 109.5(4) . . ?
C21 O7 C20 111.4(5) . . ?
C21 O7 K6 116.6(4) . . ?
C20 O7 K6 119.3(4) . . ?
C22 O8 C23 109.8(5) . . ?
C22 O8 K6 111.8(4) . . ?
C23 O8 K6 118.3(4) . . ?
C27 O9 C26 111.6(5) . . ?
C27 O9 K6 115.7(4) . . ?
C26 O9 K6 119.6(4) . . ?
C29 O10 C28 110.1(5) . . ?
C29 O10 K6 117.5(4) . . ?
C28 O10 K6 112.5(3) . . ?
C32 O11 C33 111.3(5) . . ?
C32 O11 K6 118.8(4) . . ?
C33 O11 K6 115.2(3) . . ?
C35 O12 C34 111.5(5) . . ?
C35 O12 K6 117.7(4) . . ?
C34 O12 K6 112.6(3) . . ?
N3 C19 C20 113.7(5) . . ?
N3 C19 H19A 108.8 . . ?
C20 C19 H19A 108.8 . . ?
N3 C19 H19B 108.8 . . ?
C20 C19 H19B 108.8 . . ?
H19A C19 H19B 107.7 . . ?
O7 C20 C19 108.6(5) . . ?
O7 C20 H20A 110.0 . . ?
C19 C20 H20A 110.0 . . ?
O7 C20 H20B 110.0 . . ?
C19 C20 H20B 110.0 . . ?
H20A C20 H20B 108.3 . . ?
O7 C21 C22 109.9(5) . . ?
O7 C21 H21A 109.7 . . ?
C22 C21 H21A 109.7 . . ?
O7 C21 H21B 109.7 . . ?
C22 C21 H21B 109.7 . . ?
H21A C21 H21B 108.2 . . ?
O8 C22 C21 109.7(6) . . ?
O8 C22 H22A 109.7 . . ?
C21 C22 H22A 109.7 . . ?
O8 C22 H22B 109.7 . . ?
C21 C22 H22B 109.7 . . ?
H22A C22 H22B 108.2 . . ?
O8 C23 C24 109.8(6) . . ?
O8 C23 H23A 109.7 . . ?
C24 C23 H23A 109.7 . . ?
O8 C23 H23B 109.7 . . ?
C24 C23 H23B 109.7 . . ?
H23A C23 H23B 108.2 . . ?
N4 C24 C23 113.2(6) . . ?
N4 C24 H24A 108.9 . . ?
C23 C24 H24A 108.9 . . ?
N4 C24 H24B 108.9 . . ?
C23 C24 H24B 108.9 . . ?
H24A C24 H24B 107.7 . . ?
N4 C25 C26 114.0(5) . . ?
N4 C25 H25A 108.7 . . ?
C26 C25 H25A 108.7 . . ?
N4 C25 H25B 108.7 . . ?
C26 C25 H25B 108.7 . . ?
H25A C25 H25B 107.6 . . ?
O9 C26 C25 109.3(5) . . ?
O9 C26 H26A 109.8 . . ?
C25 C26 H26A 109.8 . . ?
O9 C26 H26B 109.8 . . ?
C25 C26 H26B 109.8 . . ?
H26A C26 H26B 108.3 . . ?
O9 C27 C28 110.4(5) . . ?
O9 C27 H27A 109.6 . . ?
C28 C27 H27A 109.6 . . ?
O9 C27 H27B 109.6 . . ?
C28 C27 H27B 109.6 . . ?
H27A C27 H27B 108.1 . . ?
O10 C28 C27 109.8(5) . . ?
O10 C28 H28A 109.7 . . ?
C27 C28 H28A 109.7 . . ?
O10 C28 H28B 109.7 . . ?
C27 C28 H28B 109.7 . . ?
H28A C28 H28B 108.2 . . ?
O10 C29 C30 109.2(5) . . ?
O10 C29 H29A 109.8 . . ?
C30 C29 H29A 109.8 . . ?
O10 C29 H29B 109.8 . . ?
C30 C29 H29B 109.8 . . ?
H29A C29 H29B 108.3 . . ?
N3 C30 C29 113.6(5) . . ?
N3 C30 H30A 108.9 . . ?
C29 C30 H30A 108.9 . . ?
N3 C30 H30B 108.9 . . ?
C29 C30 H30B 108.9 . . ?
H30A C30 H30B 107.7 . . ?
N3 C31 C32 114.2(5) . . ?
N3 C31 H31A 108.7 . . ?
C32 C31 H31A 108.7 . . ?
N3 C31 H31B 108.7 . . ?
C32 C31 H31B 108.7 . . ?
H31A C31 H31B 107.6 . . ?
O11 C32 C31 110.3(5) . . ?
O11 C32 H32A 109.6 . . ?
C31 C32 H32A 109.6 . . ?
O11 C32 H32B 109.6 . . ?
C31 C32 H32B 109.6 . . ?
H32A C32 H32B 108.1 . . ?
O11 C33 C34 109.4(5) . . ?
O11 C33 H33A 109.8 . . ?
C34 C33 H33A 109.8 . . ?
O11 C33 H33B 109.8 . . ?
C34 C33 H33B 109.8 . . ?
H33A C33 H33B 108.2 . . ?
O12 C34 C33 109.3(5) . . ?
O12 C34 H34A 109.8 . . ?
C33 C34 H34A 109.8 . . ?
O12 C34 H34B 109.8 . . ?
C33 C34 H34B 109.8 . . ?
H34A C34 H34B 108.3 . . ?
O12 C35 C36 110.2(5) . . ?
O12 C35 H35A 109.6 . . ?
C36 C35 H35A 109.6 . . ?
O12 C35 H35B 109.6 . . ?
C36 C35 H35B 109.6 . . ?
H35A C35 H35B 108.1 . . ?
N4 C36 C35 113.3(5) . . ?
N4 C36 H36A 108.9 . . ?
C35 C36 H36A 108.9 . . ?
N4 C36 H36B 108.9 . . ?
C35 C36 H36B 108.9 . . ?
H36A C36 H36B 107.7 . . ?
K2 N5 K4 71.97(19) 4_566 . ?
K2 N5 H5C 96.0 4_566 . ?
K4 N5 H5C 123.3 . . ?
K2 N5 H5D 83.6 4_566 . ?
K4 N5 H5D 123.1 . . ?
H5C N5 H5D 109.5 . . ?
K2 N5 H5E 144.3 4_566 . ?
K4 N5 H5E 73.2 . . ?
H5C N5 H5E 109.5 . . ?
H5D N5 H5E 109.5 . . ?
K2 N6 H6C 109.5 4_566 . ?
K2 N6 H6D 109.5 4_566 . ?
H6C N6 H6D 109.5 . . ?
K2 N6 H6E 109.5 4_566 . ?
H6C N6 H6E 109.5 . . ?
H6D N6 H6E 109.5 . . ?
K4 N7 K2 75.40(18) . 4_566 ?
K4 N7 H7C 84.2 . . ?
K2 N7 H7C 120.4 4_566 . ?
K4 N7 H7D 147.3 . . ?
K2 N7 H7D 72.1 4_566 . ?
H7C N7 H7D 109.5 . . ?
K4 N7 H7E 92.4 . . ?
K2 N7 H7E 126.5 4_566 . ?
H7C N7 H7E 109.5 . . ?
H7D N7 H7E 109.5 . . ?
K4 N8 H8C 109.5 . . ?
K4 N8 H8D 109.5 . . ?
H8C N8 H8D 109.5 . . ?
K4 N8 H8E 109.5 . . ?
H8C N8 H8E 109.5 . . ?
H8D N8 H8E 109.5 . . ?
K4 N9 H9C 109.5 . . ?
K4 N9 H9D 109.5 . . ?
H9C N9 H9D 109.5 . . ?
K4 N9 H9E 109.5 . . ?
H9C N9 H9E 109.5 . . ?
H9D N9 H9E 109.5 . . ?
K3 N10 K3 71.75(17) . 3_665 ?
K3 N10 H10C 127.0 . . ?
K3 N10 H10C 86.6 3_665 . ?
K3 N10 H10D 119.3 . . ?
K3 N10 H10D 93.1 3_665 . ?
H10C N10 H10D 109.5 . . ?
K3 N10 H10E 73.7 . . ?
K3 N10 H10E 144.8 3_665 . ?
H10C N10 H10E 109.5 . . ?
H10D N10 H10E 109.5 . . ?
K3 N11 H11C 109.5 . . ?
K3 N11 H11D 109.5 . . ?
H11C N11 H11D 109.5 . . ?
K3 N11 H11E 109.5 . . ?
H11C N11 H11E 109.5 . . ?
H11D N11 H11E 109.5 . . ?
H12C N12 H12D 109.5 . . ?
H12C N12 H12E 109.5 . . ?
H12D N12 H12E 109.5 . . ?
H13C N13 H13D 109.5 . . ?
H13C N13 H13E 109.5 . . ?
H13D N13 H13E 109.5 . . ?
H14C N14 H14D 109.5 . . ?
H14C N14 H14E 109.5 . . ?
H14D N14 H14E 109.5 . . ?
H15C N15 H15D 109.5 . . ?
H15C N15 H15E 109.5 . . ?
H15D N15 H15E 109.5 . . ?
H16C N16 H16D 109.5 . . ?
H16C N16 H16E 109.5 . . ?
H16D N16 H16E 109.5 . . ?
H17C N17 H17D 109.5 . . ?
H17C N17 H17E 109.5 . . ?
H17D N17 H17E 109.5 . . ?
H18C N18 H18D 109.5 . . ?
H18C N18 H18E 109.5 . . ?
H18D N18 H18E 109.5 . . ?
H19C N19 H19D 109.5 . . ?
H19C N19 H19E 109.5 . . ?
H19D N19 H19E 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 Co1 2.4317(9) . ?
Ge1 Ge4 2.6244(9) . ?
Ge1 Ge2 2.6374(9) . ?
Ge1 Ge3 2.8083(9) . ?
Ge1 Ge6 2.8851(9) . ?
Ge1 Ge5 2.9199(9) . ?
Ge2 Co1 2.4421(9) . ?
Ge2 Ge3 2.6682(9) . ?
Ge2 Ge7 2.6768(9) . ?
Ge2 Ge6 2.7221(9) . ?
Ge2 K1 3.4196(16) . ?
Ge3 Co1 2.4618(9) . ?
Ge3 Ge4 2.6963(10) . ?
Ge3 Ge7 2.7359(9) . ?
Ge3 Ge8 2.7664(10) . ?
Ge4 Co1 2.4484(9) . ?
Ge4 Ge8 2.6719(10) . ?
Ge4 Ge5 2.7229(9) . ?
Ge4 K2 3.5089(19) . ?
Ge5 Co1 2.4021(10) . ?
Ge5 Ge6 2.6099(9) . ?
Ge5 Ge9 2.9316(9) . ?
Ge5 K4 3.5051(18) . ?
Ge5 K2 3.917(2) . ?
Ge6 Co1 2.3940(9) . ?
Ge6 Ge9 2.8983(9) . ?
Ge6 K4 3.4248(18) . ?
Ge6 K1 3.7154(17) . ?
Ge7 Co1 2.4167(10) . ?
Ge7 Ge8 2.6264(9) . ?
Ge7 K3 3.5533(19) . ?
Ge7 K1 3.5972(16) . ?
Ge8 Co1 2.3934(9) . ?
Ge8 K3 3.514(2) . ?
Ge8 K2 3.5681(19) . ?
Ge9 Co1 2.1924(9) . ?
Ge9 Co2 2.1998(9) . ?
Ge9 Ge13 2.9056(9) . ?
Ge9 Ge10 2.9301(9) . ?
Ge9 Ge12 2.9303(9) . ?
Ge9 Ge11 2.9376(9) . ?
Ge9 K3 3.8557(18) . ?
Ge10 Co2 2.3927(10) . ?
Ge10 Ge11 2.6510(9) . ?
Ge10 Ge14 2.7027(9) . ?
Ge10 Ge15 2.7903(9) . ?
Ge10 K1 3.5406(17) . ?
Ge10 K1 3.5465(16) 3_666 ?
Ge10 K3 3.676(2) . ?
Ge11 Co2 2.4041(9) . ?
Ge11 Ge17 2.6637(9) . ?
Ge11 K1 3.5599(16) . ?
Ge11 K1 3.6809(16) 3_666 ?
Ge11 K4 3.9040(19) . ?
Ge12 Co2 2.4184(10) . ?
Ge12 Ge13 2.6061(9) . ?
Ge12 Ge17 2.6638(9) . ?
Ge12 K2 3.864(2) . ?
Ge12 K4 3.866(2) . ?
Ge13 Co2 2.3932(9) . ?
Ge13 Ge14 2.7351(10) . ?
Ge13 Ge16 2.8129(9) . ?
Ge13 K2 3.5535(19) . ?
Ge13 K3 3.652(2) . ?
Ge14 Co2 2.4528(10) . ?
Ge14 Ge15 2.6567(10) . ?
Ge14 Ge16 2.6609(10) . ?
Ge14 K3 3.5995(19) . ?
Ge15 Co2 2.4481(9) . ?
Ge15 Ge17 2.7170(10) . ?
Ge15 Ge16 2.7542(9) . ?
Ge15 K1 3.6578(16) 3_666 ?
Ge16 Co2 2.4412(9) . ?
Ge16 Ge17 2.6751(9) . ?
Ge17 Co2 2.4385(10) . ?
Ge17 K4 3.621(2) . ?
K1 Ge10 3.5464(16) 3_666 ?
K1 Ge15 3.6578(16) 3_666 ?
K1 Ge11 3.6810(16) 3_666 ?
K1 K1 4.129(3) 3_666 ?
K2 N7 2.878(8) 4_565 ?
K2 N6 2.942(8) 4_565 ?
K2 N5 2.961(8) 4_565 ?
K2 K4 3.511(3) 4_565 ?
K3 N11 2.815(10) . ?
K3 N10 2.986(8) . ?
K3 N10 3.010(7) 3_665 ?
K3 K3 3.513(4) 3_665 ?
K3 H10E 2.8660 . ?
K4 N7 2.863(7) . ?
K4 N5 3.014(9) . ?
K4 N9 3.043(11) . ?
K4 N8 3.095(14) . ?
K4 K2 3.511(3) 4_566 ?
K4 H5E 2.8855 . ?
K4 H7C 2.9158 . ?
K4 H7E 3.0403 . ?
K5 O2 2.836(5) . ?
K5 O5 2.859(5) . ?
K5 O4 2.867(5) . ?
K5 O6 2.882(4) . ?
K5 O3 2.892(5) . ?
K5 O1 2.912(5) . ?
K5 N2 2.987(5) . ?
K5 N1 2.994(5) . ?
N1 C13 1.467(9) . ?
N1 C1 1.488(8) . ?
N1 C12 1.492(9) . ?
N2 C7 1.472(10) . ?
N2 C18 1.473(10) . ?
N2 C6 1.492(9) . ?
O1 C3 1.428(8) . ?
O1 C2 1.428(8) . ?
O2 C5 1.428(8) . ?
O2 C4 1.433(8) . ?
O3 C8 1.420(9) . ?
O3 C9 1.441(9) . ?
O4 C11 1.426(9) . ?
O4 C10 1.433(9) . ?
O5 C14 1.432(8) . ?
O5 C15 1.433(8) . ?
O6 C17 1.423(8) . ?
O6 C16 1.436(8) . ?
C1 C2 1.509(10) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C4 1.498(10) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.503(13) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C7 C8 1.494(12) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.477(13) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 C12 1.494(11) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.503(12) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C16 1.492(11) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.495(10) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
K6 O7 2.809(4) . ?
K6 O9 2.812(4) . ?
K6 O11 2.813(4) . ?
K6 O8 2.825(4) . ?
K6 O10 2.848(4) . ?
K6 O12 2.871(4) . ?
K6 N4 2.998(5) . ?
K6 N3 3.009(6) . ?
N3 C30 1.457(8) . ?
N3 C31 1.474(8) . ?
N3 C19 1.485(8) . ?
N4 C24 1.473(8) . ?
N4 C36 1.475(8) . ?
N4 C25 1.481(8) . ?
O7 C21 1.423(8) . ?
O7 C20 1.424(9) . ?
O8 C22 1.434(8) . ?
O8 C23 1.437(9) . ?
O9 C27 1.423(8) . ?
O9 C26 1.437(8) . ?
O10 C29 1.415(8) . ?
O10 C28 1.440(8) . ?
O11 C32 1.424(8) . ?
O11 C33 1.440(7) . ?
O12 C35 1.419(8) . ?
O12 C34 1.435(7) . ?
C19 C20 1.501(10) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.487(11) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 C24 1.511(10) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C26 1.498(10) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C28 1.491(10) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.523(9) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.507(10) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 C34 1.481(9) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C36 1.518(10) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
N5 K2 2.961(8) 4_566 ?
N5 H5C 0.9100 . ?
N5 H5D 0.9100 . ?
N5 H5E 0.9100 . ?
N6 K2 2.942(8) 4_566 ?
N6 H6C 0.9100 . ?
N6 H6D 0.9100 . ?
N6 H6E 0.9100 . ?
N7 K2 2.878(8) 4_566 ?
N7 H7C 0.9100 . ?
N7 H7D 0.9100 . ?
N7 H7E 0.9100 . ?
N8 H8C 0.9100 . ?
N8 H8D 0.9100 . ?
N8 H8E 0.9100 . ?
N9 H9C 0.9100 . ?
N9 H9D 0.9100 . ?
N9 H9E 0.9100 . ?
N10 K3 3.010(7) 3_665 ?
N10 H10C 0.9100 . ?
N10 H10D 0.9100 . ?
N10 H10E 0.9100 . ?
N11 H11C 0.9100 . ?
N11 H11D 0.9100 . ?
N11 H11E 0.9100 . ?
N12 H12C 0.9100 . ?
N12 H12D 0.9100 . ?
N12 H12E 0.9100 . ?
N13 H13C 0.9100 . ?
N13 H13D 0.9100 . ?
N13 H13E 0.9100 . ?
N14 H14C 0.9100 . ?
N14 H14D 0.9100 . ?
N14 H14E 0.9100 . ?
N15 H15C 0.9100 . ?
N15 H15D 0.9100 . ?
N15 H15E 0.9100 . ?
N16 H16C 0.9100 . ?
N16 H16D 0.9101 . ?
N16 H16E 0.9100 . ?
N17 H17C 0.9100 . ?
N17 H17D 0.9100 . ?
N17 H17E 0.9100 . ?
N18 H18C 0.9100 . ?
N18 H18D 0.9100 . ?
N18 H18E 0.9100 . ?
N19 H19C 0.9100 . ?
N19 H19D 0.9100 . ?
N19 H19E 0.9100 . ?
