#------------------------------------------------------------------------------
#$Date: 2022-08-24 01:50:38 +0300 (Wed, 24 Aug 2022) $
#$Revision: 277361 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/10/7711048.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7711048
loop_
_publ_author_name
'Zámbó, Greta Gundis'
'Mayr, Johannes'
'Sauer, Michael Johannes'
'Schlachta, Tim Pascal'
'Reich, Robert M.'
'Kühn, Fritz Elmar'
_publ_section_title
;
 The first macrocyclic abnormally coordinating
 tetra-1,2,3-triazole-5-ylidene iron complex: a promising candidate for
 olefin epoxidation
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT02561B
_journal_year                    2022
_chemical_compound_source        'see text'
_chemical_formula_moiety         'C20 H26 Fe N14, 2(F6 P), 2(C2 H3 N)'
_chemical_formula_sum            'C24 H32 F12 Fe N16 P2'
_chemical_formula_weight         890.45
_chemical_properties_physical
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2022-07-07 deposited with the CCDC.	2022-08-23 downloaded from the CCDC.
;
_cell_angle_alpha                112.440(3)
_cell_angle_beta                 109.710(3)
_cell_angle_gamma                94.233(4)
_cell_formula_units_Z            1
_cell_length_a                   9.1316(7)
_cell_length_b                   9.4899(9)
_cell_length_c                   11.6931(10)
_cell_measurement_reflns_used    7048
_cell_measurement_temperature    100
_cell_measurement_theta_max      25.6430
_cell_measurement_theta_min      2.3809
_cell_volume                     857.48(13)
_computing_cell_refinement       'SAINT (Bruker, 2019)'
_computing_data_collection       'APEX 4 Control Software (Bruker, 2021)'
_computing_data_reduction        'SAINT (Bruker, 2019)'
_computing_molecular_graphics    'PLATON (Spek, 2011)'
_computing_publication_material  'PLATON (Spek, 2011), enCIFer (Allen, 2004)'
_computing_structure_refinement
'SHELXL (Sheldrick, 2018), SHELXLE (Huebschle, 2011)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      100
_diffrn_detector                 ' Bruker Photon II CPAD '
_diffrn_detector_area_resol_mean 7.5
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device       ' κ-geometry diffractometer '
_diffrn_measurement_device_type  ' Bruker D8 Venture '
_diffrn_measurement_method       ' phi- and omega-rotation '
_diffrn_radiation_monochromator  'Helios optic'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'IMS microsource'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0677
_diffrn_reflns_av_unetI/netI     0.0303
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            31239
_diffrn_reflns_reduction_process
;
;
_diffrn_reflns_theta_full        25.24
_diffrn_reflns_theta_max         25.68
_diffrn_reflns_theta_min         2.05
_exptl_absorpt_coefficient_mu    0.646
_exptl_absorpt_correction_T_max  0.7449
_exptl_absorpt_correction_T_min  0.7098
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2016/2, Bruker, 2016'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.724
_exptl_crystal_density_method    'Not Measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             452
_exptl_crystal_recrystallization_method 'Vapor diffusion of Et2O into MeCN'
_exptl_crystal_size_max          0.116
_exptl_crystal_size_mid          0.076
_exptl_crystal_size_min          0.068
_refine_diff_density_max         0.303
_refine_diff_density_min         -0.316
_refine_diff_density_rms         0.057
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     254
_refine_ls_number_reflns         3267
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0389
_refine_ls_R_factor_gt           0.0316
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'W=1/[Σ²(FO²)+(0.0186P)²+0.9044P] WHERE P=(FO²+2FC²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0652
_refine_ls_wR_factor_ref         0.0686
_reflns_number_gt                2850
_reflns_number_total             3267
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            d2dt02561b2.cif
_cod_data_source_block           mo_zamgr4_0m
_cod_database_code               7711048
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_thermal_displace_type
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Fe1 Fe Uani 0.50000 1.00000 0.50000 1.000 0.0108(1) d SP . .
P1 P Uani 0.86356(7) 0.56659(6) 0.27320(5) 1.000 0.0159(2) d . . .
F1 F Uani 0.97150(16) 0.59411(16) 0.42275(13) 1.000 0.0289(4) d . . .
N1 N Uani 0.5946(2) 1.09453(19) 0.31245(17) 1.000 0.0125(5) d . . .
N2 N Uani 0.6094(2) 1.04167(19) 0.19392(17) 1.000 0.0140(5) d . . .
F2 F Uani 0.75414(16) 0.53831(17) 0.12260(13) 1.000 0.0294(4) d . . .
N3 N Uani 0.5537(2) 0.88826(19) 0.14340(17) 1.000 0.0133(5) d . . .
F3 F Uani 0.70553(16) 0.52249(16) 0.29487(14) 1.000 0.0289(4) d . . .
F4 F Uani 0.85296(18) 0.74486(15) 0.32646(14) 1.000 0.0339(5) d . . .
N4 N Uani 0.4031(2) 0.66313(19) 0.29769(17) 1.000 0.0129(5) d . . .
N5 N Uani 0.3455(2) 0.51486(19) 0.27206(17) 1.000 0.0147(5) d . . .
F5 F Uani 1.01998(16) 0.60857(19) 0.24976(15) 1.000 0.0366(5) d . . .
N6 N Uani 0.3264(2) 0.53394(19) 0.38438(17) 1.000 0.0134(5) d . . .
F6 F Uani 0.87077(18) 0.38617(16) 0.21882(15) 1.000 0.0358(5) d . . .
N7 N Uani 0.7148(2) 0.97683(19) 0.57340(17) 1.000 0.0135(5) d . . .
C1 C Uani 0.6407(2) 1.2658(2) 0.3906(2) 1.000 0.0149(6) d . . .
C2 C Uani 0.5317(2) 0.9826(2) 0.3410(2) 1.000 0.0126(6) d . . .
C3 C Uani 0.5054(2) 0.8473(2) 0.2266(2) 1.000 0.0128(6) d . . .
C4 C Uani 0.5496(3) 0.7876(2) 0.0113(2) 1.000 0.0195(7) d . . .
C5 C Uani 0.4330(3) 0.6811(2) 0.1875(2) 1.000 0.0156(6) d . . .
C6 C Uani 0.4217(2) 0.7755(2) 0.4201(2) 1.000 0.0124(6) d . . .
C7 C Uani 0.3695(2) 0.6859(2) 0.4751(2) 1.000 0.0126(6) d . . .
C8 C Uani 0.2573(3) 0.3954(2) 0.3926(2) 1.000 0.0177(6) d . . .
C9 C Uani 0.8427(3) 0.9616(2) 0.6139(2) 1.000 0.0157(6) d . . .
C10 C Uani 1.0051(3) 0.9406(3) 0.6655(2) 1.000 0.0214(7) d . . .
N8 N Uani 0.7878(3) -0.0093(3) 0.9122(2) 1.000 0.0369(8) d . . .
C11 C Uani 0.9870(3) 0.2425(3) 0.9714(3) 1.000 0.0329(8) d . . .
C12 C Uani 0.8744(3) 0.1019(3) 0.9390(2) 1.000 0.0279(8) d . . .
H1A H Uiso 0.56951 1.31382 0.33931 1.000 0.0180 c RU . .
H1B H Uiso 0.75159 1.30503 0.40410 1.000 0.0180 c RU . .
H4A H Uiso 0.59967 0.70126 0.01668 1.000 0.0290 c RU . .
H4B H Uiso 0.60794 0.84893 -0.01747 1.000 0.0290 c RU . .
H4C H Uiso 0.43823 0.74505 -0.05411 1.000 0.0290 c RU . .
H5A H Uiso 0.33085 0.64481 0.10766 1.000 0.0190 c RU . .
H5B H Uiso 0.50585 0.61455 0.16240 1.000 0.0190 c RU . .
H8A H Uiso 0.32458 0.39323 0.47700 1.000 0.0260 c RU . .
H8B H Uiso 0.25184 0.30050 0.31614 1.000 0.0260 c RU . .
H8C H Uiso 0.14945 0.39973 0.39002 1.000 0.0260 c RU . .
H10A H Uiso 1.08222 1.03815 0.69632 1.000 0.0320 c RU . .
H10B H Uiso 1.02156 0.85601 0.59373 1.000 0.0320 c RU . .
H10C H Uiso 1.02043 0.91364 0.74107 1.000 0.0320 c RU . .
H11A H Uiso 0.97102 0.33385 1.03815 1.000 0.0490 c RU . .
H11B H Uiso 0.96899 0.25693 0.88953 1.000 0.0490 c RU . .
H11C H Uiso 1.09665 0.23118 1.00848 1.000 0.0490 c RU . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 ' International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N7 Fe1 C2 88.74(8) . . . yes
N7 Fe1 C6 89.91(8) . . . yes
N7 Fe1 N7 180.00 . . 2_676 yes
N7 Fe1 C2 91.26(8) . . 2_676 yes
N7 Fe1 C6 90.09(8) . . 2_676 yes
C2 Fe1 C6 90.14(9) . . . yes
N7 Fe1 C2 91.26(8) 2_676 . . yes
C2 Fe1 C2 180.00 . . 2_676 yes
C2 Fe1 C6 89.86(9) . . 2_676 yes
N7 Fe1 C6 90.09(8) 2_676 . . yes
C2 Fe1 C6 89.86(9) 2_676 . . yes
C6 Fe1 C6 180.00 . . 2_676 yes
N7 Fe1 C2 88.74(8) 2_676 . 2_676 yes
N7 Fe1 C6 89.91(8) 2_676 . 2_676 yes
C2 Fe1 C6 90.14(9) 2_676 . 2_676 yes
F2 P1 F3 89.52(8) . . . yes
F2 P1 F4 89.50(8) . . . yes
F2 P1 F5 89.96(8) . . . yes
F2 P1 F6 90.06(9) . . . yes
F3 P1 F4 89.69(9) . . . yes
F3 P1 F5 179.25(8) . . . yes
F3 P1 F6 89.35(9) . . . yes
F4 P1 F5 90.84(10) . . . yes
F4 P1 F6 178.95(10) . . . yes
F5 P1 F6 90.12(10) . . . yes
F1 P1 F3 90.21(8) . . . yes
F1 P1 F4 90.61(8) . . . yes
F1 P1 F2 179.71(9) . . . yes
F1 P1 F6 89.82(8) . . . yes
F1 P1 F5 90.31(8) . . . yes
N2 N1 C2 115.80(18) . . . yes
N2 N1 C1 115.10(18) . . . yes
C1 N1 C2 129.01(17) . . . yes
N1 N2 N3 102.41(17) . . . yes
N2 N3 C3 112.37(17) . . . yes
C3 N3 C4 128.69(19) . . . yes
N2 N3 C4 118.93(18) . . . yes
N5 N4 C6 115.79(18) . . . yes
C5 N4 C6 129.18(19) . . . yes
N5 N4 C5 115.01(16) . . . yes
N4 N5 N6 102.07(16) . . . yes
N5 N6 C7 112.62(18) . . . yes
N5 N6 C8 118.42(17) . . . yes
C7 N6 C8 128.90(18) . . . yes
Fe1 N7 C9 178.27(17) . . . yes
N1 C1 C7 111.59(17) . . 2_676 yes
Fe1 C2 N1 130.73(15) . . . yes
Fe1 C2 C3 127.89(16) . . . yes
N1 C2 C3 101.26(17) . . . yes
N3 C3 C2 108.16(18) . . . yes
N3 C3 C5 121.42(18) . . . yes
C2 C3 C5 130.39(19) . . . no
N4 C5 C3 111.71(17) . . . yes
Fe1 C6 N4 130.36(16) . . . yes
Fe1 C6 C7 128.15(15) . . . yes
N4 C6 C7 101.49(18) . . . yes
N6 C7 C6 108.02(18) . . . yes
N6 C7 C1 121.66(19) . . 2_676 yes
C1 C7 C6 130.32(19) 2_676 . . no
N7 C9 C10 179.4(3) . . . yes
C7 C1 H1A 109.00 2_676 . . no
N1 C1 H1A 109.00 . . . no
N1 C1 H1B 109.00 . . . no
H1A C1 H1B 108.00 . . . no
C7 C1 H1B 109.00 2_676 . . no
H4B C4 H4C 109.00 . . . no
N3 C4 H4A 109.00 . . . no
N3 C4 H4B 109.00 . . . no
N3 C4 H4C 109.00 . . . no
H4A C4 H4B 110.00 . . . no
H4A C4 H4C 109.00 . . . no
N4 C5 H5B 109.00 . . . no
N4 C5 H5A 109.00 . . . no
C3 C5 H5A 109.00 . . . no
C3 C5 H5B 109.00 . . . no
H5A C5 H5B 108.00 . . . no
N6 C8 H8A 109.00 . . . no
N6 C8 H8B 109.00 . . . no
N6 C8 H8C 110.00 . . . no
H8A C8 H8B 109.00 . . . no
H8A C8 H8C 110.00 . . . no
H8B C8 H8C 109.00 . . . no
C9 C10 H10A 109.00 . . . no
C9 C10 H10B 109.00 . . . no
C9 C10 H10C 109.00 . . . no
H10A C10 H10B 109.00 . . . no
H10A C10 H10C 109.00 . . . no
H10B C10 H10C 109.00 . . . no
N8 C12 C11 178.8(3) . . . yes
C12 C11 H11A 109.00 . . . no
C12 C11 H11B 110.00 . . . no
C12 C11 H11C 109.00 . . . no
H11A C11 H11B 109.00 . . . no
H11A C11 H11C 109.00 . . . no
H11B C11 H11C 109.00 . . . no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Fe1 N7 1.9247(19) . . yes
Fe1 C2 1.924(2) . . yes
Fe1 C6 1.931(2) . . yes
Fe1 N7 1.9247(19) . 2_676 yes
Fe1 C2 1.924(2) . 2_676 yes
Fe1 C6 1.931(2) . 2_676 yes
P1 F1 1.5964(14) . . yes
P1 F2 1.6076(14) . . yes
P1 F3 1.6001(17) . . yes
P1 F4 1.5874(17) . . yes
P1 F5 1.5930(18) . . yes
P1 F6 1.5981(18) . . yes
N1 N2 1.340(2) . . yes
N1 C1 1.470(3) . . yes
N1 C2 1.371(3) . . yes
N2 N3 1.326(3) . . yes
N3 C3 1.358(3) . . yes
N3 C4 1.459(3) . . yes
N4 C6 1.363(3) . . yes
N4 C5 1.470(3) . . yes
N4 N5 1.345(3) . . yes
N5 N6 1.329(3) . . yes
N6 C8 1.467(3) . . yes
N6 C7 1.352(3) . . yes
N7 C9 1.146(3) . . yes
C1 C7 1.497(3) . 2_676 no
C2 C3 1.386(3) . . no
C3 C5 1.492(3) . . no
C6 C7 1.389(3) . . no
C9 C10 1.461(4) . . no
C1 H1A 0.9900 . . no
C1 H1B 0.9900 . . no
C4 H4C 0.9800 . . no
C4 H4B 0.9800 . . no
C4 H4A 0.9800 . . no
C5 H5A 0.9900 . . no
C5 H5B 0.9900 . . no
C8 H8B 0.9800 . . no
C8 H8A 0.9800 . . no
C8 H8C 0.9800 . . no
C10 H10C 0.9800 . . no
C10 H10A 0.9800 . . no
C10 H10B 0.9800 . . no
N8 C12 1.138(4) . . yes
C11 C12 1.459(4) . . no
C11 H11A 0.9800 . . no
C11 H11B 0.9800 . . no
C11 H11C 0.9800 . . no
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C1 H1B F1 0.9900 2.4700 3.309(3) 142.00 2_776 yes
C4 H4B N8 0.9800 2.5700 3.546(4) 173.00 1_564 yes
C5 H5A F2 0.9900 2.3900 3.152(2) 134.00 2_665 yes
C5 H5B F3 0.9900 2.4200 3.150(3) 130.00 . yes
C10 H10A F4 0.9800 2.2400 3.120(3) 149.00 2_776 yes
C10 H10B F1 0.9800 2.4100 3.332(3) 157.00 . yes
C11 H11A F6 0.9800 2.4700 3.260(3) 137.00 1_556 yes
C11 H11B F5 0.9800 2.4400 3.374(4) 158.00 2_766 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 Fe1 C2 N1 3.0(2) 2_676 . . . no
N7 Fe1 C2 C3 88.04(19) . . . . no
C6 Fe1 C2 C3 -1.87(19) . . . . no
N7 Fe1 C2 C3 -91.96(19) 2_676 . . . no
C6 Fe1 C2 C3 178.13(19) 2_676 . . . no
N7 Fe1 C6 N4 -88.7(2) . . . . no
C2 Fe1 C6 N4 0.10(19) . . . . no
N7 Fe1 C6 N4 91.4(2) 2_676 . . . no
C2 Fe1 C6 N4 -179.90(19) 2_676 . . . no
N7 Fe1 C6 C7 91.04(19) . . . . no
C2 Fe1 C6 C7 179.8(2) . . . . no
N7 Fe1 C6 C7 -88.96(19) 2_676 . . . no
N7 Fe1 C2 N1 -87.1(2) . . . . no
C6 Fe1 C2 N1 -177.0(2) . . . . no
N7 Fe1 C2 N1 93.0(2) 2_676 . . . no
C2 Fe1 C6 C7 -0.2(2) 2_676 . . . no
C2 N1 N2 N3 -0.1(2) . . . . no
N2 N1 C1 C7 -176.38(17) . . . 2_676 no
C1 N1 N2 N3 -177.10(17) . . . . no
N2 N1 C2 C3 -0.2(2) . . . . no
N2 N1 C2 Fe1 175.90(16) . . . . no
C2 N1 C1 C7 7.1(3) . . . 2_676 no
C1 N1 C2 Fe1 -7.6(3) . . . . no
C1 N1 C2 C3 176.4(2) . . . . no
N1 N2 N3 C3 0.3(2) . . . . no
N1 N2 N3 C4 179.72(19) . . . . no
C4 N3 C3 C2 -179.8(2) . . . . no
N2 N3 C3 C5 177.7(2) . . . . no
C4 N3 C3 C5 -1.6(3) . . . . no
N2 N3 C3 C2 -0.4(2) . . . . no
C5 N4 C6 C7 178.1(2) . . . . no
C5 N4 N5 N6 -178.42(19) . . . . no
C6 N4 C5 C3 5.1(3) . . . . no
N5 N4 C5 C3 -176.70(19) . . . . no
N5 N4 C6 Fe1 179.67(16) . . . . no
C5 N4 C6 Fe1 -2.2(3) . . . . no
N5 N4 C6 C7 -0.1(2) . . . . no
C6 N4 N5 N6 0.0(2) . . . . no
N4 N5 N6 C7 0.1(2) . . . . no
N4 N5 N6 C8 177.37(19) . . . . no
C8 N6 C7 C1 3.7(3) . . . 2_676 no
N5 N6 C7 C1 -179.39(18) . . . 2_676 no
N5 N6 C7 C6 -0.2(2) . . . . no
C8 N6 C7 C6 -177.1(2) . . . . no
N1 C1 C7 N6 177.34(18) . . 2_676 2_676 no
N1 C1 C7 C6 -3.6(3) . . 2_676 2_676 no
N1 C2 C3 C5 -177.6(2) . . . . no
N1 C2 C3 N3 0.3(2) . . . . no
Fe1 C2 C3 N3 -175.87(15) . . . . no
Fe1 C2 C3 C5 6.2(3) . . . . no
C2 C3 C5 N4 -7.3(3) . . . . no
N3 C3 C5 N4 175.03(19) . . . . no
Fe1 C6 C7 C1 -0.5(3) . . . 2_676 no
N4 C6 C7 N6 0.1(2) . . . . no
N4 C6 C7 C1 179.3(2) . . . 2_676 no
Fe1 C6 C7 N6 -179.62(15) . . . . no
