data_1000484
_chemical_name_systematic          'Lanthanum palladium oxide (4/1/7)'
_chemical_formula_structural       'La4 Pd O7'
_chemical_formula_sum              'La4 O7 Pd'
_publ_section_title
;
Structural correlations within the lanthanum palladium oxide family
;
loop_
_publ_author_name
  'Attfield, J P'
  'Ferey, G'
_journal_name_full                 'Journal of Solid State Chemistry'
_journal_coden_ASTM                JSSCBI
_journal_volume                    80
_journal_year                      1989
_journal_page_first                286
_journal_page_last                 298
_cell_length_a                     13.469(1)
_cell_length_b                     4.0262(1)
_cell_length_c                     9.448(1)
_cell_angle_alpha                  90
_cell_angle_beta                   133.42(1)
_cell_angle_gamma                  90
_cell_volume                       372.1
_cell_formula_units_Z              2
_symmetry_space_group_name_H-M     'C 1 2/m 1'
_symmetry_Int_Tables_number        12
_symmetry_cell_setting             monoclinic
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  'x,-y,z'
  '-x,-y,-z'
  '-x,y,-z'
  '1/2+x,1/2+y,z'
  '1/2+x,1/2-y,z'
  '1/2-x,1/2-y,-z'
  '1/2-x,1/2+y,-z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  La3+   3.000
  Pd2+   2.000
  O2-   -2.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  La1   La3+   4 i 0.2470(3) 0.5 0.1540(4) 1.  0 d
  La2   La3+   4 i 0.5839(3) 0. 0.3889(5) 1.  0 d
  Pd1   Pd2+   2 a 0. 0. 0. 1.  0 d
  O1    O2-    2 b 0. 0.5 0. 1.  0 d
  O2    O2-    4 i 0.3673(4) 0. 0.3101(6) 1.  0 d
  O3    O2-    4 i 0.0875(5) 0. -0.1126(8) 1.  0 d
  O4    O2-    4 i 0.2961(5) 0.5 0.4462(7) 1.  0 d