data_1001237
_chemical_name_systematic
;
Rubidium phosphorus tungsten oxide (.8/4/16/56)
;
_chemical_formula_structural       'Rb.8 P4 W16 O56'
_chemical_formula_sum              'O56 P4 Rb.8 W16'
_publ_section_title
;
Rb~x~ P~8~ W~32~ O~112~: A Tunnel Structure Built up from Re O~3~-Type
Blocks and P~2~ O~7~ Groups
;
loop_
_publ_author_name
  'Giroult, J P'
  'Goreaud, M'
  'Labbe, P'
  'Raveau, B'
_journal_name_full                 'Acta Crystallographica B (24,1968-38,1982)'
_journal_coden_ASTM                ACBCAR
_journal_volume                    36
_journal_year                      1980
_journal_page_first                2570
_journal_page_last                 2575
_cell_length_a                     16.194(3)
_cell_length_b                     3.7719(4)
_cell_length_c                     17.095(4)
_cell_angle_alpha                  90
_cell_angle_beta                   93.89(2)
_cell_angle_gamma                  90
_cell_volume                       1041.8
_cell_formula_units_Z              1
_symmetry_space_group_name_H-M     'P 1 2/c 1'
_symmetry_Int_Tables_number        13
_symmetry_cell_setting             monoclinic
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '-x,y,1/2-z'
  '-x,-y,-z'
  'x,-y,1/2+z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  Rb1+   1.000
  P5+    5.000
  W6+    5.700
  O2-   -2.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  Rb1   Rb1+   2 d 0.5 0. 0.5 0.4  0 d
  P1    P5+    4 g 0.4316(4) 0.4062(15) 0.1456(3) 0.5  0 d
  P2    P5+    4 g 0.4317(4) 0.5936(16) 0.1450(4) 0.5  0 d
  W1    W6+    4 g 0.15094(3) 0.48884(15) 0.21246(3) 1.  0 d
  W2    W6+    4 g 0.35917(3) 0.53926(15) 0.32722(2) 1.  0 d
  W3    W6+    4 g 0.25863(3) 0.47253(18) 0.52189(2) 1.  0 d
  W4    W6+    4 g 0.05192(3) 0.50512(11) 0.40526(3) 1.  0 d
  O1    O2-    2 c 0. 0.5 0. 1.  0 d
  O2    O2-    4 g 0.2141(17) 0.4784(85) 0.1143(16) 0.5  0 d
  O3    O2-    4 g 0.2134(22) 0.5144(97) 0.1152(20) 0.5  0 d
  O4    O2-    4 g 0.1635(6) 0.4991(34) 0.4613(6) 1.  0 d
  O5    O2-    4 g 0.0532(7) 0.4885(39) 0.1522(7) 1.  0 d
  O6    O2-    4 g 0.1033(6) 0.4959(29) 0.3060(6) 1.  0 d
  O7    O2-    4 g 0.3273(11) 0.4602(63) 0.4248(9) 0.5  0 d
  O8    O2-    4 g 0.3215(14) 0.5537(79) 0.4221(12) 0.5  0 d
  O9    O2-    4 g 0.3769(14) 0.4535(79) 0.0766(13) 0.5  0 d
  O10   O2-    4 g 0.3766(88) 0.05472(88) 0.0778(15) 0.5  0 d
  O11   O2-    4 g 0.2613(16) 0.4521(86) 0.2741(14) 0.5  0 d
  O12   O2-    4 g 0.2636(13) 0.5442(76) 0.2714(12) 0.5  0 d
  O13   O2-    4 g 0.4117(15) 0.4418(77) 0.2228(14) 0.5  0 d
  O14   O2-    4 g 0.4156(13) 0.5724(61) 0.2235(11) 0.5  0 d
  O15   O2-    4 g 0.4787(15) 0.4379(84) 0.3743(14) 0.5  0 d
  O16   O2-    4 g 0.4806(12) 0.5449(69) 0.3730(11) 0.5  0 d
  O17   O2-    4 g 0.2625(1) 0.0037(53) 0.0217(9) 0.5  0 d
  O18   O2-    4 g 0.2839(14) 0.0065(60) 0.0123(11) 0.5  0 d
  O19   O2-    4 g 0.1706(13) -0.0041(57) 0.2065(11) 0.5  0 d
  O20   O2-    4 g 0.1483(13) -0.0004(52) 0.2114(10) 0.5  0 d
  O21   O2-    4 g 0.3845(13) 0.0139(62) 0.3179(11) 0.5  0 d
  O22   O2-    4 g 0.3571(15) 0.0102(76) 0.3311(14) 0.5  0 d
  O23   O2-    4 g 0.0557(7) 0.0008(31) 0.4044(7) 1.  0 d
  O24   O2-    4 g 0.4112(13) 0.0042(66) 0.1537(13) 0.5  0 d
_refine_ls_R_factor_all            0.038