data_1001409
_chemical_name_systematic
;
Bismuth lead distrontium yttrium dicopper oxide
;
_chemical_formula_structural       'Bi Pb Sr2 Y Cu2 O8'
_chemical_formula_sum              'Bi Cu2 O8 Pb Sr2 Y'
_publ_section_title
;
Superconducting properties and Structural Study of Bi~2-x~ Pb~x~ Sr~2~
Ca~1-x~ Y~x~ Cu~2~ O~8~ (0< x< 1)
;
loop_
_publ_author_name
  'Retoux, R'
  'Caignaert, V'
  'Provost, J'
  'Michel, C'
  'Hervieu, M'
  'Raveau, B'
_journal_name_full                 'Journal of Solid State Chemistry'
_journal_coden_ASTM                JSSCBI
_journal_volume                    79
_journal_year                      1989
_journal_page_first                157
_journal_page_last                 168
_cell_length_a                     5.385
_cell_length_b                     5.424
_cell_length_c                     30.316
_cell_angle_alpha                  90
_cell_angle_beta                   90
_cell_angle_gamma                  90
_cell_volume                       885.5
_cell_formula_units_Z              4
_symmetry_space_group_name_H-M     'F m m m'
_symmetry_Int_Tables_number        69
_symmetry_cell_setting             orthorhombic
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  'x,-y,-z'
  '-x,y,-z'
  '-x,-y,z'
  '-x,-y,-z'
  '-x,y,z'
  'x,-y,z'
  'x,y,-z'
  'x,1/2+y,1/2+z'
  '1/2+x,y,1/2+z'
  '1/2+x,1/2+y,z'
  'x,1/2-y,1/2-z'
  '1/2+x,-y,1/2-z'
  '1/2+x,1/2-y,-z'
  '-x,1/2+y,1/2-z'
  '1/2-x,y,1/2-z'
  '1/2-x,1/2+y,-z'
  '-x,1/2-y,1/2+z'
  '1/2-x,-y,1/2+z'
  '1/2-x,1/2-y,z'
  '-x,1/2-y,1/2-z'
  '1/2-x,-y,1/2-z'
  '1/2-x,1/2-y,-z'
  '-x,1/2+y,1/2+z'
  '1/2-x,y,1/2+z'
  '1/2-x,1/2+y,z'
  'x,1/2-y,1/2+z'
  '1/2+x,-y,1/2+z'
  '1/2+x,1/2-y,z'
  'x,1/2+y,1/2-z'
  '1/2+x,y,1/2-z'
  '1/2+x,1/2+y,-z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  Bi3+   3.000
  Pb2+   2.000
  Sr2+   2.000
  Y3+    3.000
  Cu2+   2.000
  O2-   -2.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  Bi1   Bi3+   8 i 0. 0. 0.2018(6) 0.5  0 d
  Pb1   Pb2+   8 i 0. 0. 0.2018(6) 0.5  0 d
  Sr1   Sr2+   8 i 0. 0. 0.6147(9) 1.  0 d
  Y1    Y3+    4 b 0. 0. 0.5 1.  0 d
  Cu1   Cu2+   8 i 0. 0. 0.0554(13) 1.  0 d
  O1    O2-   16 j 0.25 0.25 0.049(2) 1.  0 d
  O2    O2-    8 i 0. 0. 0.686(4) 1.  0 d
  O3    O2-    8 i 0. 0. 0.133(5) 1.  0 d
_refine_ls_R_factor_all            0.069