data_1008001
_chemical_name_systematic
;
Zinc silver hydrogen triphosphate hydrate (2/.6/.4/1/9)
;
_chemical_formula_structural       'ZN2 AG0.62 H0.38 P3 O10 (H2 O)9'
_chemical_formula_sum              'H18.38 Ag.62 O19 P3 Zn2'
_publ_section_title
;
Structure cristalline d'un tripolyphosphate acide mixte zinc-argent
nonahydrate: Zn~2~ Ag~0.62~ H~0.38~ P~3~ O~10~ (H~2~ O)~9~
;
loop_
_publ_author_name
  'Averbuch-Pouchot, M T'
  'Guitel, J C'
_journal_name_full                 'Acta Crystallographica B (24,1968-38,1982)'
_journal_coden_ASTM                ACBCAR
_journal_volume                    32
_journal_year                      1976
_journal_page_first                2270
_journal_page_last                 2274
_cell_length_a                     10.473(4)
_cell_length_b                     10.683(5)
_cell_length_c                     8.629(3)
_cell_angle_alpha                  101.08(1)
_cell_angle_beta                   109.81(1)
_cell_angle_gamma                  98.87(1)
_cell_volume                       865.9
_cell_formula_units_Z              2
_symmetry_space_group_name_H-M     'P -1'
_symmetry_Int_Tables_number        2
_symmetry_cell_setting             triclinic
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  Zn2+   2.000
  Ag1+   1.000
  P5+    5.000
  O2-   -2.000
  H1+    1.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  Zn1   Zn2+   1 a 0. 0. 0. 1.  0 d
  Zn2   Zn2+   1 h 0.5 0.5 0.5 1.  0 d
  Zn3   Zn2+   2 i 0.49618(3) 0.04802(3) 0.76801(4) 1.  0 d
  Ag1   Ag1+   2 i 0.02347(6) 0.14238(5) 0.41954(7) 0.62  0 d
  P1    P5+    2 i 0.28901(7) 0.06500(6) 0.96031(9) 1.  0 d
  P2    P5+    2 i 0.28297(7) 0.22409(6) 0.27121(9) 1.  0 d
  P3    P5+    2 i 0.54975(7) 0.20593(6) 0.50696(8) 1.  0 d
  O1    O2-    2 i 0.1318(2) 0.0281(2) 0.8766(3) 1.  0 d
  O2    O2-    2 i 0.3581(2) 0.1101(2) 0.8459(3) 1.  0 d
  O3    O2-    2 i 0.6536(2) 0.0404(2) 0.9625(3) 1.  0 d
  O4    O2-    2 i 0.3341(2) 0.1964(2) 0.1159(3) 1.  0 d
  O5    O2-    2 i 0.1374(2) 0.1459(2) 0.2189(3) 1.  0 d
  O6    O2-    2 i 0.3115(2) 0.3688(2) 0.3377(3) 1.  0 d
  O7    O2-    2 i 0.3803(2) 0.1636(2) 0.4084(3) 1.  0 d
  O8    O2-    2 i 0.6042(2) 0.1185(2) 0.3961(3) 1.  0 d
  O9    O2-    2 i 0.5762(2) 0.1765(2) 0.6774(3) 1.  0 d
  O10   O2-    2 i 0.5999(2) 0.3489(2) 0.5243(3) 1.  0 d
  O11   O2-    2 i 0.9045(2) 0.1471(2) 0.8992(3) 1.  2 d
  O12   O2-    2 i 0.4445(2) 0.4848(2) 0.7154(3) 1.  2 d
  O13   O2-    2 i 0.2179(3) 0.2796(3) 0.6786(4) 1.  2 d
  O14   O2-    2 i 0.9180(5) 0.3233(5) 0.3853(6) 1.  2 d
  O15   O2-    2 i 0.8724(3) 0.0610(3) 0.5479(3) 1.  2 d
  O16   O2-    2 i 0.6914(4) 0.4345(3) 0.9201(4) 1.  2 d
  O17   O2-    2 i 0.6609(4) 0.3106(3) 0.1590(5) 1.  2 d
  O18   O2-    2 i 0.0716(3) 0.3656(3) 0.8927(4) 1.  2 d
  O19   O2-    2 i 0.9066(4) 0.4842(5) 0.6707(6) 1.  2 d
  H1    H1+    2 i -1. -1. -1. 18.38  0 dum
_refine_ls_R_factor_all            0.041