data_1010481
_chemical_name_systematic          'Tricaesium cobalt chloride'
_chemical_formula_structural       'Cs3 Co Cl5'
_chemical_formula_sum              'Cl5 Co Cs3'
_publ_section_title
;
The Structure of Caesium Cobalt Chloride ( Cs~3~ Co Cl~5~ )
;
loop_
_publ_author_name
  'Powell, H M'
  'Wells, A F'
_journal_name_full                 'Journal of the Chemical Society'
_journal_coden_ASTM                JCSOA9
_journal_volume                    1935
_journal_year                      1935
_journal_page_first                359
_journal_page_last                 362
_cell_length_a                     9.18
_cell_length_b                     9.18
_cell_length_c                     14.47
_cell_angle_alpha                  90
_cell_angle_beta                   90
_cell_angle_gamma                  90
_cell_volume                       1219.4
_cell_formula_units_Z              4
_symmetry_space_group_name_H-M     'I 4/m c m S'
_symmetry_Int_Tables_number        140
_symmetry_cell_setting             tetragonal
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  'x,y,1/2-z'
  '-y,1/2+x,z'
  '-y,1/2+x,1/2-z'
  '1/2-x,1/2-y,z'
  '1/2-x,1/2-y,1/2-z'
  '1/2+y,-x,z'
  '1/2+y,-x,1/2-z'
  'x,1/2-y,1/2+z'
  'x,1/2-y,-z'
  '1/2+y,1/2+x,1/2+z'
  '1/2+y,1/2+x,-z'
  '1/2-x,y,1/2+z'
  '1/2-x,y,-z'
  '-y,-x,1/2+z'
  '-y,-x,-z'
  '1/2+x,1/2+y,1/2+z'
  '1/2+x,1/2+y,-z'
  '1/2-y,x,1/2+z'
  '1/2-y,x,-z'
  '-x,-y,1/2+z'
  '-x,-y,-z'
  'y,1/2-x,1/2+z'
  'y,1/2-x,-z'
  '1/2+x,-y,z'
  '1/2+x,-y,1/2-z'
  'y,x,z'
  'y,x,1/2-z'
  '-x,1/2+y,z'
  '-x,1/2+y,1/2-z'
  '1/2-y,1/2-x,z'
  '1/2-y,1/2-x,1/2-z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  Cs1+   1.000
  Cl1-  -1.000
  Co2+   2.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  Cs1   Cs1+   4 c 0. 0. 0. 1.  0 d
  Cs2   Cs1+   8 h 0.1667 0.6667 0.25 1.  0 d
  Cl1   Cl1-   4 a 0. 0. 0.25 1.  0 d
  Cl2   Cl1-  16 l 0.155 0.655 0.9167 1.  0 d
  Co1   Co2+   4 d 0. 0.5 0. 1.  0 d