data_1011121
_chemical_name_systematic          'Copper arsenate(V) hydroxide'
_chemical_name_mineral             'Olivenite'
_chemical_compound_source          'from Cornwall, England'
_chemical_formula_structural       'Cu2 (As O4) (O H)'
_chemical_formula_sum              'H As Cu2 O5'
_publ_section_title                'Die Struktur des Olivenites Cu2 O H As O4'
_publ_author_name                  'Heritsch, H'
_journal_name_full
;
Zeitschrift fuer Kristallographie, Kristallgeometrie, Kristallphysik,
Kristallchemie (-144,1977)
;
_journal_coden_ASTM                ZEKGAX
_journal_volume                    99
_journal_year                      1938
_journal_page_first                466
_journal_page_last                 479
_cell_length_a                     8.62
_cell_length_b                     8.2
_cell_length_c                     5.94
_cell_angle_alpha                  90
_cell_angle_beta                   90
_cell_angle_gamma                  90
_cell_volume                       419.9
_cell_formula_units_Z              4
_exptl_crystal_density_meas        4.4
_symmetry_space_group_name_H-M     'P n n m'
_symmetry_Int_Tables_number        58
_symmetry_cell_setting             orthorhombic
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '-x,-y,z'
  '1/2+x,1/2-y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  'x,y,-z'
  '1/2-x,1/2+y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  O2-   -2.000
  As5+   5.000
  Cu2+   2.000
  H1+    1.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  O1    O2-    4 g 0.097 -0.119 0. 1.  1 d
  O2    O2-    4 g 0.105 -0.147 0.5 1.  0 d
  O3    O2-    4 g 0.114 0.375 0. 1.  0 d
  O4    O2-    8 h 0.236 0.139 0.25 1.  0 d
  As1   As5+   4 g 0.244 0.264 0. 1.  0 d
  Cu1   Cu2+   4 e 0. 0. 0.25 1.  0 d
  Cu2   Cu2+   4 g -0.122 0.361 0. 1.  0 d
  H1    H1+    8 h -1. -1. -1. 0.5  0 dum