#------------------------------------------------------------------------------ #$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $ #$Revision: 176729 $ #$URL: file:///home/coder/svn-repositories/cod/cif/1/51/72/1517231.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_1517231 loop_ _publ_author_name 'Clark, J. Stephen' 'Delion, Laetitia' 'Farrugia, Louis J.' _publ_section_title ; Total synthesis of the purported structure of sclerophytin f. ; _journal_issue 16 _journal_name_full 'Organic letters' _journal_page_first 4300 _journal_page_last 4303 _journal_paper_doi 10.1021/ol5020152 _journal_volume 16 _journal_year 2014 _chemical_absolute_configuration rm _chemical_compound_source 'as described' _chemical_formula_moiety 'C20 H32 O4' _chemical_formula_sum 'C20 H32 O4' _chemical_formula_weight 336.45 _chemical_name_systematic ; ? ; _space_group_IT_number 19 _symmetry_cell_setting orthorhombic _symmetry_Int_Tables_number 19 _symmetry_space_group_name_Hall 'P 2ac 2ab' _symmetry_space_group_name_H-M 'P 21 21 21' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _atom_sites_solution_secondary dual _audit_conform_dict_location ftp://ftp.iucr.org/pub/cif_core.dic _audit_conform_dict_name cif_core.dic _audit_conform_dict_version 2.4.3 _audit_creation_date 2014-03-13T10:47:03-00:00 _audit_creation_method 'WinGX routine CIF_UPDATE' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 5.624(3) _cell_length_b 16.550(10) _cell_length_c 19.160(12) _cell_measurement_reflns_used 6365 _cell_measurement_temperature 100(2) _cell_measurement_theta_max 22.43 _cell_measurement_theta_min 2.45 _cell_measurement_wavelength 0.71073 _cell_volume 1783.4(18) _computing_cell_refinement 'SAINT V8.34A integration software' _computing_data_collection 'Bruker APEX2 software' _computing_data_reduction 'SORTAV (Blessing, 1995)' _computing_molecular_graphics 'ORTEP-3 for Windows (Farrugia, 2012)' _computing_publication_material 'WinGX publication routines (Farrugia, 2012)' _computing_structure_refinement 'SHELXL-2014/3 (Sheldrick, 2008)' _computing_structure_solution 'SHELXT-2014/3 (Sheldrick, 2014)' _diffrn_ambient_temperature 100(2) _diffrn_detector 'APEX-II CCD' _diffrn_measured_fraction_theta_full 0.727 _diffrn_measured_fraction_theta_max 0.996 _diffrn_measurement_device '\k-geometry diffractometer' _diffrn_measurement_device_type 'Bruker APEX-II' _diffrn_measurement_method '\f or \w oscillation scans' _diffrn_orient_matrix_UB_11 -0.075183 _diffrn_orient_matrix_UB_12 -0.054442 _diffrn_orient_matrix_UB_13 0.005765 _diffrn_orient_matrix_UB_21 0.087264 _diffrn_orient_matrix_UB_22 -0.019957 _diffrn_orient_matrix_UB_23 -0.041955 _diffrn_orient_matrix_UB_31 0.135629 _diffrn_orient_matrix_UB_32 -0.017338 _diffrn_orient_matrix_UB_33 0.03019 _diffrn_radiation_monochromator graphite _diffrn_radiation_probe x-ray _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.097 _diffrn_reflns_Laue_measured_fraction_full 0.727 _diffrn_reflns_Laue_measured_fraction_max 0.996 _diffrn_reflns_limit_h_max 5 _diffrn_reflns_limit_h_min -6 _diffrn_reflns_limit_k_max 17 _diffrn_reflns_limit_k_min -17 _diffrn_reflns_limit_l_max 20 _diffrn_reflns_limit_l_min -20 _diffrn_reflns_number 13824 _diffrn_reflns_point_group_measured_fraction_full 0.713 _diffrn_reflns_point_group_measured_fraction_max 0.995 _diffrn_reflns_reduction_process ; Scaled and merged with Sortav R.H. Blessing, (1987) Cryst. Rev. 1, 3-58 R.H. Blessing, (1989) J. Appl. Cryst. 22, 396-397 ; _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 22.443 _diffrn_reflns_theta_min 1.626 _diffrn_source 'sealed x-ray tube' _exptl_absorpt_coefficient_mu 0.085 _exptl_absorpt_correction_T_max 0.655 _exptl_absorpt_correction_T_min 0.527 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; SADABS-2012/1 - Bruker AXS area detector scaling and absorption correction ; _exptl_crystal_colour colourless _exptl_crystal_density_diffrn 1.253 _exptl_crystal_density_method 'not measured' _exptl_crystal_description needle _exptl_crystal_F_000 736 _exptl_crystal_size_max 0.5 _exptl_crystal_size_mid 0.02 _exptl_crystal_size_min 0.02 _refine_diff_density_max 0.202 _refine_diff_density_min -0.224 _refine_diff_density_rms 0.052 _refine_ls_abs_structure_details ; Flack x determined using 648 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259). ; _refine_ls_abs_structure_Flack 1.2(10) _refine_ls_extinction_coef 0.010(3) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_extinction_method SHELXL _refine_ls_goodness_of_fit_ref 1.014 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_constraints 0 _refine_ls_number_parameters 223 _refine_ls_number_reflns 2295 _refine_ls_number_restraints 162 _refine_ls_restrained_S_all 0.977 _refine_ls_R_factor_all 0.0701 _refine_ls_R_factor_gt 0.044 _refine_ls_shift/su_max 0 _refine_ls_shift/su_mean 0 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0507P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0941 _refine_ls_wR_factor_ref 0.1027 _reflns_number_gt 1850 _reflns_number_total 2295 _reflns_threshold_expression 'I > 2\s(I)' _iucr_refine_instructions_details ; TITL shelx in P212121 CELL 0.71073 5.6238 16.5502 19.1603 90.000 90.000 90.000 ZERR 4.00 0.0031 0.0102 0.0122 0.000 0.000 0.000 LATT -1 SYMM 1/2 - X, - Y, 1/2 + Z SYMM 1/2 + X, 1/2 - Y, - Z SYMM - X, 1/2 + Y, 1/2 - Z SFAC O C H UNIT 16 80 128 MERG 2 SIMU FMAP 2 PLAN 5 SIZE 0.020 0.020 0.500 ACTA BOND $H CONF L.S. 10 TEMP -173.00 WGHT 0.050700 EXTI 0.009799 FVAR 0.63044 O1 1 1.214072 0.858460 0.813705 11.00000 0.01884 0.01907 = 0.02302 0.00251 -0.00293 0.00261 O2 1 1.075798 0.719082 0.886350 11.00000 0.02321 0.02337 = 0.02299 0.00659 0.00011 0.00335 AFIX 147 H2O 3 1.017385 0.688451 0.916813 11.00000 -1.50000 AFIX 0 O3 1 1.327020 0.900943 1.021096 11.00000 0.03777 0.03204 = 0.02130 -0.00298 -0.00901 0.00218 AFIX 147 H3O 3 1.295667 0.944953 1.040899 11.00000 -1.50000 AFIX 0 O4 1 1.170861 1.042003 0.978024 11.00000 0.04212 0.02945 = 0.02774 -0.00740 -0.00928 -0.00012 C1 2 0.851886 0.867015 0.750357 11.00000 0.02248 0.02121 = 0.01852 0.00436 0.00126 0.00031 AFIX 13 H1 3 0.680247 0.855680 0.759848 11.00000 -1.20000 AFIX 0 C2 2 1.008079 0.810852 0.794560 11.00000 0.01848 0.02472 = 0.01690 -0.00357 -0.00430 -0.00131 AFIX 13 H2 3 1.065308 0.766822 0.763011 11.00000 -1.20000 AFIX 0 C3 2 0.891462 0.769792 0.857860 11.00000 0.01706 0.02378 = 0.01816 0.00190 -0.00333 0.00693 C4 2 0.793498 0.826431 0.915234 11.00000 0.02472 0.02311 = 0.02030 0.00417 0.00160 0.00426 AFIX 23 H4A 3 0.745693 0.877747 0.892694 11.00000 -1.20000 H4B 3 0.647548 0.801455 0.934449 11.00000 -1.20000 AFIX 0 C5 2 0.956620 0.846975 0.976272 11.00000 0.03334 0.02475 = 0.01630 -0.00009 -0.00053 0.00582 AFIX 23 H5A 3 0.864120 0.879229 1.010278 11.00000 -1.20000 H5B 3 1.001245 0.795831 0.999651 11.00000 -1.20000 AFIX 0 C6 2 1.183381 0.892843 0.959781 11.00000 0.02246 0.02556 = 0.01513 0.00064 -0.00365 0.00239 AFIX 13 H6 3 1.275460 0.859930 0.925353 11.00000 -1.20000 AFIX 0 C7 2 1.143212 0.976824 0.927193 11.00000 0.02857 0.02147 = 0.01726 -0.00350 -0.00217 0.00239 C8 2 1.262688 0.994237 0.859336 11.00000 0.02458 0.02362 = 0.02356 0.00045 -0.00423 0.00041 AFIX 23 H8A 3 1.435934 0.986247 0.865366 11.00000 -1.20000 H8B 3 1.236724 1.051849 0.847709 11.00000 -1.20000 AFIX 0 C9 2 1.180306 0.943181 0.797876 11.00000 0.02328 0.02127 = 0.01830 0.00683 0.00131 0.00409 AFIX 13 H9 3 1.279133 0.957219 0.756217 11.00000 -1.20000 AFIX 0 C10 2 0.918065 0.952003 0.778421 11.00000 0.01815 0.02417 = 0.01872 0.00297 0.00335 -0.00204 AFIX 13 H10 3 0.826854 0.960832 0.822569 11.00000 -1.20000 AFIX 0 C11 2 0.865039 1.021833 0.730425 11.00000 0.02022 0.02381 = 0.02203 0.00661 -0.00129 -0.00074 C12 2 0.925547 1.007536 0.655532 11.00000 0.03496 0.02972 = 0.02411 0.00992 0.00262 0.00234 AFIX 23 H12A 3 1.100378 1.004444 0.650115 11.00000 -1.20000 H12B 3 0.867132 1.053229 0.626932 11.00000 -1.20000 AFIX 0 C13 2 0.813481 0.929533 0.630196 11.00000 0.03382 0.03278 = 0.02229 0.00433 -0.00045 0.00184 AFIX 23 H13A 3 0.852197 0.921514 0.580270 11.00000 -1.20000 H13B 3 0.638435 0.933332 0.634579 11.00000 -1.20000 AFIX 0 C14 2 0.903054 0.857018 0.672342 11.00000 0.01990 0.03088 = 0.01837 0.00297 -0.00051 -0.00012 AFIX 13 H14 3 1.080032 0.856564 0.667296 11.00000 -1.20000 AFIX 0 C15 2 0.813260 0.775332 0.642744 11.00000 0.02817 0.02599 = 0.02249 0.00202 -0.00466 -0.00137 AFIX 13 H15 3 0.871903 0.731953 0.674739 11.00000 -1.20000 AFIX 0 C16 2 0.543638 0.768756 0.640559 11.00000 0.03014 0.04122 = 0.02993 -0.00270 -0.00170 -0.00350 AFIX 137 H16A 3 0.498298 0.714300 0.625511 11.00000 -1.50000 H16B 3 0.480078 0.808540 0.607588 11.00000 -1.50000 H16C 3 0.478792 0.779189 0.687170 11.00000 -1.50000 AFIX 0 C17 2 0.914830 0.757716 0.570784 11.00000 0.03254 0.04669 = 0.02927 -0.01106 -0.00212 -0.00033 AFIX 137 H17A 3 0.853563 0.797335 0.537295 11.00000 -1.50000 H17B 3 0.867693 0.703270 0.556193 11.00000 -1.50000 H17C 3 1.088692 0.761191 0.572488 11.00000 -1.50000 AFIX 0 C18 2 0.690969 0.716564 0.830964 11.00000 0.02710 0.02268 = 0.02398 0.00348 -0.00089 -0.00288 AFIX 137 H18A 3 0.638799 0.679989 0.868159 11.00000 -1.50000 H18B 3 0.747613 0.684852 0.791098 11.00000 -1.50000 H18C 3 0.557302 0.750552 0.816304 11.00000 -1.50000 AFIX 0 C19 2 0.939606 1.027240 0.948886 11.00000 0.03669 0.03162 = 0.02656 -0.00129 -0.00107 0.00491 AFIX 23 H19A 3 0.876911 1.066907 0.914870 11.00000 -1.20000 H19B 3 0.818184 1.002273 0.979457 11.00000 -1.20000 AFIX 0 C20 2 0.764657 1.089158 0.752448 11.00000 0.03337 0.02913 = 0.02549 0.00957 -0.00114 0.00388 AFIX 93 H20A 3 0.727983 1.130942 0.720202 11.00000 -1.20000 H20B 3 0.729000 1.095884 0.800564 11.00000 -1.20000 AFIX 0 HKLF 4 REM shelx in P212121 REM R1 = 0.0440 for 1850 Fo > 4sig(Fo) and 0.0701 for all 2295 data REM 223 parameters refined using 162 restraints END ; _cod_data_source_file ol5020152_si_002.cif _cod_data_source_block shelx _cod_depositor_comments 'Adding full bibliography for 1517229--1517231.cif.' _cod_original_cell_volume 1783.3(19) _cod_database_code 1517231 #BEGIN Tags that were not found in dictionaries: _shelx_estimated_absorpt_t_min 0.959 _shelx_estimated_absorpt_t_max 0.998 _iucr_refine_reflections_details ; 0 0 2 534.724 35.3922 1 0 0 4 42.2257 4.68405 1 0 0 6 624.919 41.8823 1 0 0 8 215.012 9.86706 1 0 0 10 787.71 43.0683 1 0 0 12 7.21042 3.52022 1 0 0 14 12.6429 5.25288 1 0 0 16 0.8675 5.48527 1 0 0 18 468.00 36.0896 1 0 0 20 44.2141 12.577 1 0 1 1 1542.13 73.9097 1 0 1 2 633.708 30.0813 1 0 1 3 27.2603 2.48589 1 0 1 4 653.622 26.1462 1 0 1 5 960.555 42.8801 1 0 1 6 2922.98 105.742 1 0 1 7 298.702 10.7632 1 0 1 8 117.004 5.20116 1 0 1 9 608.923 21.995 1 0 1 10 4.26416 1.7619 1 0 1 11 133.728 8.74647 1 0 1 12 23.4105 2.78568 1 0 1 13 245.198 11.0082 1 0 1 14 110.959 6.6815 1 0 1 15 83.7622 6.24219 1 0 1 16 124.676 9.09595 1 0 1 17 18.1199 4.74578 1 0 1 18 24.2291 5.66693 1 0 1 19 5.60763 5.26766 1 0 1 20 29.1954 9.29385 1 0 2 0 29.8979 3.50494 1 0 2 1 4237.75 154.564 1 0 2 2 49.3406 3.99327 1 0 2 3 4.95329 1.88104 1 0 2 4 3865.90 133.266 1 0 2 5 133.508 7.22423 1 0 2 6 33.0686 2.41192 1 0 2 7 152.618 5.9997 1 0 2 8 54.3939 3.32731 1 0 2 9 434.418 15.6595 1 0 2 10 150.474 6.06752 1 0 2 11 35.254 2.45359 1 0 2 12 25.3512 2.78236 1 0 2 13 78.647 5.00511 1 0 2 14 8.87773 2.73994 1 0 2 15 18.3263 3.62014 1 0 2 16 38.4589 4.86044 1 0 2 17 22.4107 5.28638 1 0 2 18-0.32957 12.6898 1 0 2 19 108.221 13.4989 1 0 2 20-5.02818 14.3776 1 0 3 1 398.873 16.547 1 0 3 2 507.739 24.3051 1 0 3 3 336.788 14.3407 1 0 3 4 153.681 7.16611 1 0 3 5 726.75 29.0898 1 0 3 6 110.19 4.80503 1 0 3 7 511.248 18.0352 1 0 3 8 270.044 9.3659 1 0 3 9 18.4122 1.89183 1 0 3 10 25.0215 1.99358 1 0 3 11 51.0086 2.95307 1 0 3 12 10.426 2.33333 1 0 3 13 46.4418 3.33632 1 0 3 14 8.11999 3.29404 1 0 3 15 19.3652 3.89849 1 0 3 16 4.72483 5.01593 1 0 3 17 91.458 8.96008 1 0 3 18 12.8415 6.10373 1 0 3 19 28.3911 7.85755 1 0 3 20 118.077 13.538 1 0 4 0 2661.64 102.166 1 0 4 1 294.366 12.1425 1 0 4 2 4.90868 1.76889 1 0 4 3 17.5149 2.1411 1 0 4 4 4822.00 192.533 1 0 4 5 884.997 33.1976 1 0 4 6 3.21427 1.57186 1 0 4 7 621.942 22.2295 1 0 4 8 99.4594 4.4025 1 0 4 9 361.158 15.3411 1 0 4 10 429.464 15.8448 1 0 4 11 5.71496 1.84241 1 0 4 12 70.0809 3.77494 1 0 4 13 383.533 14.9791 1 0 4 14 1210.86 56.7377 1 0 4 15 151.658 8.45294 1 0 4 16 36.6626 6.4602 1 0 4 17 139.594 11.5133 1 0 4 18 76.5369 14.4758 1 0 4 19 107.283 16.1702 1 0 4 20 12.1652 8.25297 1 0 5 1 1823.54 66.3363 1 0 5 2 47.211 3.34501 1 0 5 3 1265.79 46.8937 1 0 5 4 702.872 24.6748 1 0 5 5 18.9385 1.91033 1 0 5 6 185.273 7.33159 1 0 5 7 73.35 3.85998 1 0 5 8 6.79312 1.84366 1 0 5 9 82.784 4.29635 1 0 5 10 16.3298 2.06455 1 0 5 11 3.71379 1.65657 1 0 5 12 14.6406 2.11945 1 0 5 13 63.1571 5.14357 1 0 5 14 2.57363 3.26971 1 0 5 15 119.548 8.99276 1 0 5 16 557.223 29.5355 1 0 5 17 131.567 10.4954 1 0 5 18 29.8147 8.2015 1 0 5 19 203.463 18.4486 1 0 6 0 8.18914 2.11464 1 0 6 1 60.8668 3.18099 1 0 6 2 77.8532 3.73645 1 0 6 3 45.9779 2.4139 1 0 6 4 10.0152 1.53479 1 0 6 5 115.978 5.12826 1 0 6 6 8.75127 1.73504 1 0 6 7 283.659 10.5664 1 0 6 8 447.687 20.0773 1 0 6 9 92.5206 6.30732 1 0 6 10 39.8824 3.06076 1 0 6 11 0.48338 2.3728 1 0 6 12 139.064 8.37032 1 0 6 13 895.671 48.9606 1 0 6 14 1.58768 3.5679 1 0 6 15 647.278 32.7749 1 0 6 16 29.9466 4.59715 1 0 6 17 82.2665 8.88837 1 0 6 18 17.8554 6.01691 1 0 6 19 59.5159 11.0133 1 0 7 1 28.1405 1.85728 1 0 7 2 1327.08 46.9543 1 0 7 3 1991.22 74.8896 1 0 7 4 445.226 18.9054 1 0 7 5 88.7982 4.40098 1 0 7 6 444.895 17.7513 1 0 7 7 1099.35 43.2858 1 0 7 8 161.397 6.90023 1 0 7 9 47.0726 3.41615 1 0 7 10 21.3335 2.98337 1 0 7 11 6.23642 2.69501 1 0 7 12 89.0142 6.22723 1 0 7 13 477.842 21.372 1 0 7 14 97.1613 6.77326 1 0 7 15 163.057 9.75082 1 0 7 16 23.0424 6.08656 1 0 7 17 18.5489 5.47555 1 0 7 18 180.866 15.5748 1 0 8 0 450.402 27.6213 1 0 8 1 525.047 20.7315 1 0 8 2 1.73507 1.55157 1 0 8 3 106.77 4.63586 1 0 8 4 100.878 4.93731 1 0 8 5 23.6163 2.16434 1 0 8 6 149.863 6.02478 1 0 8 7 6.55164 2.10897 1 0 8 8 1.76971 2.38441 1 0 8 9 408.075 18.1183 1 0 8 10 665.931 28.7882 1 0 8 11 26.8143 3.14606 1 0 8 12 244.023 11.5479 1 0 8 13 743.997 37.6922 1 0 8 14 13.3894 3.64264 1 0 8 15 35.1714 6.39958 1 0 8 16 15.8852 8.99809 1 0 8 17 32.8574 12.6744 1 0 8 18 5.49122 10.557 1 0 9 1 83.7237 3.83198 1 0 9 2 622.574 21.7415 1 0 9 3 397.888 17.1693 1 0 9 4 52.571 2.90122 1 0 9 5 10.5088 1.95999 1 0 9 6 239.876 9.31026 1 0 9 7 11.3281 2.23662 1 0 9 8 6.92384 2.4108 1 0 9 9 34.4186 3.45793 1 0 9 10 44.205 3.94451 1 0 9 11 19.20 3.59503 1 0 9 12 133.888 9.44849 1 0 9 13 22.6893 4.38829 1 0 9 14 204.588 13.1942 1 0 9 15 -7.9764 11.9421 1 0 9 16 43.1618 6.8902 1 0 9 17 13.3655 6.68363 1 0 10 0 105.18 6.23562 1 0 10 1 16.508 2.03707 1 0 10 2 102.301 4.91096 1 0 10 3 37.6154 2.64542 1 0 10 4 47.744 3.04845 1 0 10 5 17.4581 2.46245 1 0 10 6 3.73532 2.55281 1 0 10 7 2.82574 2.91824 1 0 10 8 145.277 7.99813 1 0 10 9 73.7686 4.67073 1 0 10 10 58.3896 5.24136 1 0 10 11 385.258 23.8759 1 0 10 12 5.98915 3.97628 1 0 10 13 5.74862 5.65388 1 0 10 14 1.88182 9.91959 1 0 10 15-5.89396 12.8023 1 0 10 16 4.18557 5.88529 1 0 10 17 183.491 17.7342 1 0 11 1 196.931 7.81484 1 0 11 2 65.2308 3.60692 1 0 11 3 142.598 6.80672 1 0 11 4 7.56141 2.3927 1 0 11 5 55.3065 4.14525 1 0 11 6 458.993 25.4397 1 0 11 7 15.3603 3.44581 1 0 11 8 43.2995 4.50359 1 0 11 9-5.45771 9.11921 1 0 11 10 83.1957 6.57006 1 0 11 11 18.3526 4.5549 1 0 11 12 73.8983 6.79684 1 0 11 13 52.8156 6.85594 1 0 11 14 40.1332 7.92487 1 0 11 15 1.97299 6.11364 1 0 11 16 21.5829 10.0447 1 0 12 0 101.085 8.47441 1 0 12 1 700.08 24.7902 1 0 12 2 25.2769 2.74326 1 0 12 3 138.145 6.41857 1 0 12 4 107.413 5.55874 1 0 12 5 4.22735 2.92403 1 0 12 6 5.63925 3.42134 1 0 12 7 106.659 8.69608 1 0 12 8 2.61115 4.30905 1 0 12 9 322.028 19.0471 1 0 12 10 28.078 7.93539 1 0 12 11 4.02729 7.93269 1 0 12 12 35.3706 9.51055 1 0 12 13-0.78709 20.7177 1 0 12 14 98.3271 15.6964 1 0 12 15 10.5555 8.33385 1 0 13 1 60.3939 4.25481 1 0 13 2 302.887 15.8277 1 0 13 3 72.1025 5.09354 1 0 13 4-2.39306 10.5436 1 0 13 5 8.37366 4.78555 1 0 13 6 11.2044 4.44722 1 0 13 7 64.1697 6.29497 1 0 13 8 -3.4811 12.2494 1 0 13 9-3.37419 13.4642 1 0 13 10 5.54868 5.20136 1 0 13 11 20.1655 9.67247 1 0 13 12 27.1981 10.9664 1 0 13 13 173.643 23.155 1 0 13 14 23.6583 10.261 1 0 14 0 90.9903 7.97107 1 0 14 1 132.38 7.27323 1 0 14 2 420.811 19.7323 1 0 14 3 594.616 29.4973 1 0 14 4 515.621 26.3614 1 0 14 5 164.893 11.98 1 0 14 6 216.935 14.0693 1 0 14 7 7.90237 7.29891 1 0 14 8 53.1764 7.62367 1 0 14 9 2.24687 7.50973 1 0 14 10 24.0545 6.67538 1 0 14 11 15.7846 10.8816 1 0 14 12-9.01113 17.4858 1 0 15 1 63.4361 6.66932 1 0 15 2 2.72906 6.10658 1 0 15 3 3.98531 5.43673 1 0 15 4 67.0906 9.28557 1 0 15 5-7.88984 14.3935 1 0 15 6-17.8883 12.9647 1 0 15 7 63.456 10.2994 1 0 15 8 16.5724 8.37618 1 0 15 9 0.30919 8.23705 1 0 15 10-7.40871 15.9222 1 0 15 11 35.8339 16.0941 1 0 16 0 162.312 16.402 1 0 16 1 17.513 5.75441 1 0 16 2 120.597 14.6405 1 0 16 3-9.75516 15.0695 1 0 16 4 1.03748 6.72856 1 0 16 5-6.40392 15.9858 1 0 16 6-5.07645 17.6466 1 0 16 7 18.9775 8.4614 1 0 16 8 13.7916 8.37181 1 0 17 1 27.997 8.17532 1 0 17 2 1.23303 8.64806 1 0 17 3 10.7222 7.47945 1 0 17 4 46.7207 9.68422 1 0 17 5 7.17811 8.89964 1 1 0 1 9292.20 424.875 1 1 0 2 3286.52 139.043 1 1 0 3 606.766 30.4979 1 1 0 4 404.901 17.1277 1 1 0 5 1471.33 63.9381 1 1 0 6 6.81325 1.78763 1 1 0 7 357.121 13.3441 1 1 0 8 99.2069 4.48027 1 1 0 9 128.149 5.49987 1 1 0 10 58.1765 4.3014 1 1 0 11 62.1859 3.60857 1 1 0 12 40.2113 2.58839 1 1 0 13 17.5632 3.23503 1 1 0 14 262.741 11.4129 1 1 0 15 53.0506 4.76755 1 1 0 16 33.6882 4.76694 1 1 0 17 7.87525 5.25781 1 1 0 18 15.1295 5.20815 1 1 0 19 41.2954 7.70466 1 1 0 20 39.955 8.0886 1 1 1 -20 7.28915 6.46597 1 1 1 -19 -6.5932 12.0923 1 1 1 -18 103.543 8.94571 1 1 1 -17 50.3347 5.79251 1 1 1 -16 81.0799 7.67529 1 1 1 -15 355.388 19.3683 1 1 1 -14 13.1777 2.93415 1 1 1 -13 60.4655 3.60956 1 1 1 -12 195.868 7.92754 1 1 1 -11 178.109 6.82799 1 1 1 -10 1167.40 46.8279 1 1 1 -9 423.066 15.1614 1 1 1 -8 615.517 23.5935 1 1 1 -7 788.629 28.0059 1 1 1 -6 1508.06 63.1814 1 1 1 -5 443.136 18.2951 1 1 1 -4 119.413 9.59075 1 1 1 -3 1590.94 68.7773 1 1 1 -2 2510.26 153.335 1 1 1 -1 1062.84 62.2189 1 1 1 0 53.8703 6.49725 1 1 1 1 1000.04 56.5242 1 1 1 2 2465.02 110.254 1 1 1 3 1562.24 72.4871 1 1 1 4 127.505 7.16391 1 1 1 5 408.993 19.0165 1 1 1 6 1500.43 62.1488 1 1 1 7 737.398 26.4743 1 1 1 8 617.395 25.2807 1 1 1 9 433.587 17.1471 1 1 1 10 1156.04 44.2466 1 1 1 11 180.997 7.26874 1 1 1 12 190.328 7.9256 1 1 1 13 57.5046 4.45753 1 1 1 14 14.7231 3.38063 1 1 1 15 315.985 18.9694 1 1 1 16 81.9644 6.47078 1 1 1 17 47.2453 5.18472 1 1 1 18 116.187 10.1384 1 1 1 19-0.91422 16.5701 1 1 1 20 13.1267 7.84569 1 1 2 -20 23.8764 10.3539 1 1 2 -19 15.8608 8.98807 1 1 2 -18 14.3967 5.92138 1 1 2 -17 29.6324 5.26151 1 1 2 -16 84.9292 9.98807 1 1 2 -15 51.2219 5.02253 1 1 2 -14 52.799 3.69605 1 1 2 -13 193.174 11.1662 1 1 2 -12 30.4874 2.76232 1 1 2 -11 50.7025 3.38374 1 1 2 -10 3.53378 1.85156 1 1 2 -9 385.511 13.9078 1 1 2 -8 190.523 8.17662 1 1 2 -7 273.341 12.8391 1 1 2 -6 80.1198 4.95911 1 1 2 -5 794.387 33.9025 1 1 2 -4 205.987 9.89398 1 1 2 -3 491.278 29.3965 1 1 2 -2 1291.08 95.4849 1 1 2 -1 968.006 47.884 1 1 2 0 1659.41 91.0052 1 1 2 1 997.256 42.0656 1 1 2 2 1376.56 59.197 1 1 2 3 538.492 24.5913 1 1 2 4 214.899 9.66306 1 1 2 5 777.052 34.7694 1 1 2 6 77.7703 4.53589 1 1 2 7 270.426 19.4976 1 1 2 8 172.454 10.401 1 1 2 9 379.191 21.6978 1 1 2 10 3.46164 1.65011 1 1 2 11 52.6289 3.43729 1 1 2 12 33.2383 2.56323 1 1 2 13 192.592 8.0589 1 1 2 14 54.6435 3.79182 1 1 2 15 49.9953 4.4782 1 1 2 16 88.3465 10.3155 1 1 2 17 27.3632 4.56513 1 1 2 18 22.1397 6.1593 1 1 2 19 28.6438 6.78268 1 1 2 20 22.0619 11.8255 1 1 3 -20 6.81846 7.03974 1 1 3 -19 155.386 14.0965 1 1 3 -18 185.378 13.7037 1 1 3 -17 153.729 11.3025 1 1 3 -16 3.5714 3.8725 1 1 3 -15 21.393 4.05575 1 1 3 -14 149.359 6.8365 1 1 3 -13 156.578 7.29472 1 1 3 -12 51.6956 3.44227 1 1 3 -11 571.163 21.9132 1 1 3 -10 108.573 5.56706 1 1 3 -9 238.257 8.24446 1 1 3 -8 384.155 15.526 1 1 3 -7 230.589 11.1597 1 1 3 -6 1220.28 45.9869 1 1 3 -5 261.133 11.7689 1 1 3 -4 184.209 8.18872 1 1 3 -3 394.23 16.3296 1 1 3 -2 505.831 21.2545 1 1 3 -1 1203.39 48.7216 1 1 3 0 534.684 25.6111 1 1 3 1 1227.06 52.4169 1 1 3 2 534.769 22.2097 1 1 3 3 395.053 19.0851 1 1 3 4 187.763 9.13429 1 1 3 5 256.369 13.8249 1 1 3 6 1367.99 51.0184 1 1 3 7 242.296 11.7096 1 1 3 8 377.208 14.663 1 1 3 9 230.117 9.5695 1 1 3 10 102.487 4.65653 1 1 3 11 538.575 23.284 1 1 3 12 48.5448 3.15581 1 1 3 13 144.614 6.61953 1 1 3 14 136.994 6.7289 1 1 3 15 21.4891 3.18758 1 1 3 16 7.01461 3.46656 1 1 3 17 160.308 12.5081 1 1 3 18 191.241 18.9538 1 1 3 19 177.447 15.3825 1 1 3 20 18.9008 12.2477 1 1 4 -19 12.8558 7.0652 1 1 4 -18 58.1002 8.02997 1 1 4 -17 58.9958 6.726 1 1 4 -16 266.376 15.2379 1 1 4 -15 121.572 8.59071 1 1 4 -14 193.016 9.63338 1 1 4 -13 281.949 11.0536 1 1 4 -12 124.484 5.62078 1 1 4 -11 50.3595 2.94232 1 1 4 -10 461.366 23.8032 1 1 4 -9 81.4623 3.71848 1 1 4 -8 19.7437 2.10329 1 1 4 -7 349.282 14.3278 1 1 4 -6 524.11 21.6666 1 1 4 -5 684.502 27.3116 1 1 4 -4 882.065 37.034 1 1 4 -3 509.849 20.4667 1 1 4 -2 332.068 13.9488 1 1 4 -1 517.567 25.1012 1 1 4 0 464.364 20.7864 1 1 4 1 586.547 24.8659 1 1 4 2 344.547 17.1938 1 1 4 3 477.862 18.6962 1 1 4 4 872.403 30.1001 1 1 4 5 715.831 26.6199 1 1 4 6 541.991 25.0346 1 1 4 7 335.088 16.2582 1 1 4 8 16.8799 2.29341 1 1 4 9 78.7141 4.12876 1 1 4 10 463.568 16.8527 1 1 4 11 48.1138 4.13875 1 1 4 12 124.376 5.54788 1 1 4 13 273.853 11.0291 1 1 4 14 179.163 9.03908 1 1 4 15 116.105 8.27966 1 1 4 16 254.368 15.6846 1 1 4 17 52.4268 8.30367 1 1 4 18 41.1019 7.43874 1 1 4 19 20.6905 6.92269 1 1 5 -19 23.3268 9.10031 1 1 5 -18 15.1044 6.37857 1 1 5 -17 41.6773 6.15486 1 1 5 -16 178.658 12.3936 1 1 5 -15 90.5186 7.20125 1 1 5 -14 5.26073 3.79625 1 1 5 -13 27.7326 2.95356 1 1 5 -12 250.137 10.3707 1 1 5 -11 88.5516 4.25506 1 1 5 -10 48.7814 3.10167 1 1 5 -9 98.2282 4.71399 1 1 5 -8 170.625 6.9389 1 1 5 -7 800.692 44.5639 1 1 5 -6 397.272 18.2337 1 1 5 -5 869.622 39.7843 1 1 5 -4 1066.41 43.574 1 1 5 -3 239.152 10.3132 1 1 5 -2 1006.65 36.6378 1 1 5 -1 110.368 4.76735 1 1 5 0 90.0589 4.63247 1 1 5 1 107.689 5.65086 1 1 5 2 1002.50 40.2535 1 1 5 3 235.524 9.73635 1 1 5 4 1145.02 44.3245 1 1 5 5 967.355 32.5849 1 1 5 6 398.865 17.5002 1 1 5 7 873.583 32.1887 1 1 5 8 163.77 11.0041 1 1 5 9 91.0074 6.90708 1 1 5 10 49.6294 4.12051 1 1 5 11 94.0448 5.07136 1 1 5 12 247.951 10.6017 1 1 5 13 23.6939 3.28323 1 1 5 14 3.34506 3.29817 1 1 5 15 86.0417 10.23 1 1 5 16 184.348 12.2794 1 1 5 17 39.2771 6.16843 1 1 5 18 12.5496 5.67909 1 1 5 19 8.51205 8.78864 1 1 6 -19 30.5183 10.7741 1 1 6 -18 44.0064 8.0874 1 1 6 -17 17.7299 5.96836 1 1 6 -16 11.9815 5.1989 1 1 6 -15 169.049 10.3938 1 1 6 -14 440.331 20.9622 1 1 6 -13 82.4704 5.34148 1 1 6 -12 7.64271 2.93193 1 1 6 -11 40.492 3.39806 1 1 6 -10 60.66 4.11117 1 1 6 -9 37.5583 2.87596 1 1 6 -8 160.333 7.65098 1 1 6 -7 234.81 11.5324 1 1 6 -6 63.3181 4.67075 1 1 6 -5 317.271 12.8581 1 1 6 -4 442.392 16.8368 1 1 6 -3 273.364 9.81454 1 1 6 -2 198.089 7.48015 1 1 6 -1 416.93 14.6958 1 1 6 0 402.709 14.8354 1 1 6 1 402.507 16.1343 1 1 6 2 193.61 8.37453 1 1 6 3 268.85 11.4111 1 1 6 4 427.457 19.5925 1 1 6 5 300.713 15.2643 1 1 6 6 63.884 3.14526 1 1 6 7 220.985 10.2126 1 1 6 8 175.139 7.26603 1 1 6 9 40.0023 3.94113 1 1 6 10 63.742 4.42312 1 1 6 11 41.6912 4.59699 1 1 6 12 3.26055 2.36661 1 1 6 13 79.4105 5.52527 1 1 6 14 447.36 19.9832 1 1 6 15 172.118 13.9458 1 1 6 16 23.5734 6.90697 1 1 6 17 23.2879 7.68468 1 1 6 18 38.7019 8.31984 1 1 6 19 45.2156 8.31195 1 1 7 -18 88.1177 10.4308 1 1 7 -17 50.18 7.46135 1 1 7 -16 149.993 10.635 1 1 7 -15 12.5564 4.98652 1 1 7 -14 107.026 7.52377 1 1 7 -13 229.787 11.8703 1 1 7 -12 126.342 7.2003 1 1 7 -11 49.4725 4.03335 1 1 7 -10 112.382 6.17557 1 1 7 -9 70.3698 4.32639 1 1 7 -8 726.151 32.8644 1 1 7 -7 7.93752 2.20531 1 1 7 -6 115.315 8.69466 1 1 7 -5 508.892 25.6695 1 1 7 -4 1415.90 83.82 1 1 7 -3 857.003 35.027 1 1 7 -2 34.9721 2.30588 1 1 7 -1 103.362 4.30729 1 1 7 0 192.292 9.35765 1 1 7 1 107.904 5.90332 1 1 7 2 35.2372 2.35022 1 1 7 3 850.772 30.5968 1 1 7 4 1469.52 59.0889 1 1 7 5 498.098 17.8368 1 1 7 6 119.925 7.43683 1 1 7 7 11.0316 1.51839 1 1 7 8 706.315 32.7053 1 1 7 9 70.64 3.77205 1 1 7 10 114.868 5.81985 1 1 7 11 51.005 4.44053 1 1 7 12 122.71 6.75283 1 1 7 13 227.515 11.8866 1 1 7 14 105.979 7.39611 1 1 7 15 8.27121 5.83998 1 1 7 16 145.618 13.6091 1 1 7 17 51.0454 12.9712 1 1 7 18 84.8524 21.978 1 1 8 -18 8.13658 11.7079 1 1 8 -17 55.209 8.79343 1 1 8 -16 9.79862 5.93601 1 1 8 -15 169.048 11.5412 1 1 8 -14 51.144 5.72129 1 1 8 -13 138.85 8.96792 1 1 8 -12 51.8246 4.93185 1 1 8 -11 380.431 21.9347 1 1 8 -10 341.917 16.1675 1 1 8 -9 76.6686 6.69592 1 1 8 -8 24.6153 3.07906 1 1 8 -7 113.197 5.84324 1 1 8 -6 7.62157 2.21113 1 1 8 -5 215.098 7.9517 1 1 8 -4 19.7749 2.17665 1 1 8 -3 339.401 11.5929 1 1 8 -2 253.566 11.9734 1 1 8 -1 360.385 14.7787 1 1 8 0 112.09 5.29428 1 1 8 1 363.385 12.6439 1 1 8 2 228.729 10.3676 1 1 8 3 302.969 14.8081 1 1 8 4 16.3086 1.95038 1 1 8 5 206.919 8.89267 1 1 8 6 9.31245 1.84739 1 1 8 7 115.997 5.64464 1 1 8 8 20.9784 1.87329 1 1 8 9 78.8467 5.38808 1 1 8 10 390.594 16.4282 1 1 8 11 375.005 16.0064 1 1 8 12 46.6453 7.10476 1 1 8 13 133.604 9.71266 1 1 8 14 47.1028 5.065 1 1 8 15 161.951 13.9203 1 1 8 16 11.3487 7.40727 1 1 8 17 55.5222 16.2814 1 1 8 18 11.6176 8.60682 1 1 9 -17 14.4205 7.0714 1 1 9 -16 20.6494 7.30522 1 1 9 -15 3.21754 5.43808 1 1 9 -14 27.5388 5.33947 1 1 9 -13 31.8858 5.36967 1 1 9 -12 66.9533 6.9627 1 1 9 -11 12.0686 3.71966 1 1 9 -10 20.2862 3.82618 1 1 9 -9 318.524 17.5405 1 1 9 -8 38.4724 3.58353 1 1 9 -7 106.382 5.74338 1 1 9 -6 64.2998 4.14436 1 1 9 -5 59.3383 5.02021 1 1 9 -4 24.77 2.28697 1 1 9 -3 135.776 5.52311 1 1 9 -2 174.546 6.64228 1 1 9 -1 239.869 10.2899 1 1 9 0 1.72575 2.36202 1 1 9 1 227.37 10.1737 1 1 9 2 180.108 6.83928 1 1 9 3 134.951 6.81435 1 1 9 4 21.1164 2.19888 1 1 9 5 59.2226 4.37716 1 1 9 6 60.834 4.00595 1 1 9 7 108.495 6.84871 1 1 9 8 41.5343 2.70265 1 1 9 9 343.706 13.6678 1 1 9 10 20.8184 3.29197 1 1 9 11 7.06323 3.97692 1 1 9 12 66.7096 6.90726 1 1 9 13 26.5713 6.9253 1 1 9 14 18.0858 6.24485 1 1 9 15 0.2765 5.87526 1 1 9 16 15.147 9.805 1 1 9 17 3.89941 7.43406 1 1 10 -16 19.2412 6.69217 1 1 10 -15-7.07492 17.6926 1 1 10 -14 6.80384 6.8629 1 1 10 -13 31.932 6.34602 1 1 10 -12 397.518 21.9724 1 1 10 -11 59.0735 5.94954 1 1 10 -10 50.5272 5.87277 1 1 10 -9 367.286 20.053 1 1 10 -8 31.8203 3.66559 1 1 10 -7 50.429 4.01085 1 1 10 -6 201.073 8.59214 1 1 10 -5 45.4255 3.20057 1 1 10 -4 77.5018 6.31126 1 1 10 -3 5.15811 2.18692 1 1 10 -2 45.8399 3.8792 1 1 10 -1 85.2176 4.70669 1 1 10 0 96.7098 5.26002 1 1 10 1 77.7329 5.6905 1 1 10 2 43.2163 2.83217 1 1 10 3 6.51389 2.10092 1 1 10 4 72.8024 5.03903 1 1 10 5 43.2451 3.15326 1 1 10 6 207.38 8.11128 1 1 10 7 54.2525 4.4162 1 1 10 8 28.1606 2.42046 1 1 10 9 391.092 17.9464 1 1 10 10 50.2413 4.83938 1 1 10 11 59.8085 6.08049 1 1 10 12 385.92 22.515 1 1 10 13 33.7275 6.21591 1 1 10 14 6.21066 10.0218 1 1 10 15-7.79638 12.1256 1 1 10 16 11.2631 6.88368 1 1 11 -15 2.58206 7.12922 1 1 11 -14 65.3456 9.04928 1 1 11 -13 116.734 12.1767 1 1 11 -12 85.5909 12.4485 1 1 11 -11 76.3096 8.09828 1 1 11 -10 120.501 9.04745 1 1 11 -9 15.9138 4.44659 1 1 11 -8 342.015 19.2612 1 1 11 -7 144.366 9.53504 1 1 11 -6 12.5598 2.76898 1 1 11 -5 166.025 8.44343 1 1 11 -4 78.9354 4.99394 1 1 11 -3 205.752 10.5318 1 1 11 -2 73.3647 4.32321 1 1 11 -1 100.132 5.3955 1 1 11 0 3.691 2.14606 1 1 11 1 101.303 5.11154 1 1 11 2 69.40 6.84802 1 1 11 3 201.779 10.4947 1 1 11 4 77.2309 5.58811 1 1 11 5 163.447 9.28091 1 1 11 6 10.6515 2.65973 1 1 11 7 136.422 8.38336 1 1 11 8 328.268 13.4355 1 1 11 9 23.5726 4.0837 1 1 11 10 138.726 11.7505 1 1 11 11 81.8632 11.93 1 1 11 12 61.2396 7.66879 1 1 11 13 104.651 10.3258 1 1 11 14 66.4277 16.6114 1 1 11 15-15.0556 14.7079 1 1 12 -14 17.9944 9.04829 1 1 12 -13 7.44885 9.88311 1 1 12 -12 143.458 12.4999 1 1 12 -11 75.4584 8.26087 1 1 12 -10 89.6294 8.38017 1 1 12 -9-1.02034 9.72313 1 1 12 -8-5.03708 10.515 1 1 12 -7 12.9575 4.76175 1 1 12 -6 170.376 9.7254 1 1 12 -5 40.1591 4.79334 1 1 12 -4 111.312 6.08225 1 1 12 -3 501.065 20.5293 1 1 12 -2 5.56038 2.87668 1 1 12 -1 48.8829 3.84863 1 1 12 0 236.156 12.5094 1 1 12 1 44.5433 3.79247 1 1 12 2 10.0749 3.0734 1 1 12 3 473.533 22.4041 1 1 12 4 111.854 7.78677 1 1 12 5 38.0453 4.10265 1 1 12 6 151.387 9.09216 1 1 12 7 17.3562 6.12695 1 1 12 8-0.83356 13.5113 1 1 12 9 8.30789 7.04102 1 1 12 10 98.4255 12.853 1 1 12 11 85.8904 13.1151 1 1 12 12 147.615 15.7783 1 1 12 13 10.0082 12.3357 1 1 12 14 15.0602 11.0534 1 1 13 -13 14.8744 7.53903 1 1 13 -12 9.7921 7.46084 1 1 13 -11 197.789 16.2555 1 1 13 -10 26.4892 8.14323 1 1 13 -9 270.046 18.9085 1 1 13 -8 101.927 8.76679 1 1 13 -7 63.9066 6.94329 1 1 13 -6 3.96777 4.30518 1 1 13 -5 15.8476 4.78066 1 1 13 -4 0.17227 4.30135 1 1 13 -3 47.6165 4.81854 1 1 13 -2 104.501 6.53731 1 1 13 -1 124.987 8.5931 1 1 13 0 247.305 11.9163 1 1 13 1 122.966 7.57289 1 1 13 2 85.8488 6.23725 1 1 13 3 42.0245 4.86038 1 1 13 4 2.5037 3.87399 1 1 13 5 6.41509 4.0758 1 1 13 6 6.86405 4.43921 1 1 13 7 70.7807 8.38535 1 1 13 8 83.497 11.4844 1 1 13 9 286.286 18.716 1 1 13 10 37.54 10.2142 1 1 13 11 196.76 25.6591 1 1 13 12 1.79615 6.62318 1 1 13 13 19.0792 14.3876 1 1 14 -12 12.6473 8.34483 1 1 14 -11-1.63537 16.5171 1 1 14 -10-4.31692 14.4073 1 1 14 -9 5.55552 9.11097 1 1 14 -8-3.93125 14.7363 1 1 14 -7 25.4512 6.36567 1 1 14 -6 40.333 6.54981 1 1 14 -5 160.751 12.5044 1 1 14 -4 100.889 10.4086 1 1 14 -3 23.5111 4.76592 1 1 14 -2 377.50 18.5027 1 1 14 -1 48.409 4.953 1 1 14 0 82.4391 6.27155 1 1 14 1 52.1277 5.61599 1 1 14 2 374.083 21.5255 1 1 14 3 33.2489 5.87039 1 1 14 4 98.2047 8.45829 1 1 14 5 171.616 12.5549 1 1 14 6 39.2297 10.4022 1 1 14 7 17.1839 9.6686 1 1 14 8-3.85958 13.2712 1 1 14 9 4.91286 8.33782 1 1 14 10-4.76974 22.006 1 1 14 11 2.86787 12.0652 1 1 14 12 5.8335 36.0947 1 1 15 -10-12.6771 16.8312 1 1 15 -9 31.9501 8.40809 1 1 15 -8 12.4776 7.36305 1 1 15 -7 86.3837 9.24088 1 1 15 -6 19.7571 10.5928 1 1 15 -5 76.071 9.35289 1 1 15 -4 168.362 12.2879 1 1 15 -3 2.73255 4.97463 1 1 15 -2 97.162 8.4156 1 1 15 -1 79.4219 7.29643 1 1 15 0-0.28685 15.4297 1 1 15 1 77.3164 7.26223 1 1 15 2 102.791 9.44829 1 1 15 3 8.17694 7.61341 1 1 15 4 173.083 13.7234 1 1 15 5 60.2905 9.21835 1 1 15 6 28.2813 11.4625 1 1 15 7 83.1717 20.5845 1 1 15 8 8.63924 12.8097 1 1 15 9 22.9432 9.25503 1 1 15 10-4.72001 19.7656 1 1 16 -8 10.4557 12.4468 1 1 16 -7-11.3907 15.1711 1 1 16 -6 0.88015 11.5344 1 1 16 -5 6.64316 15.6806 1 1 16 -4 13.0882 8.37991 1 1 16 -3 123.869 13.7861 1 1 16 -2 18.754 7.77533 1 1 16 -1 39.589 8.20718 1 1 16 0-13.6885 14.4841 1 1 16 1 41.0899 7.26346 1 1 16 2 21.6982 8.14633 1 1 16 3 139.582 16.606 1 1 16 4-8.54932 28.7229 1 1 16 5 12.5835 8.07985 1 1 16 6 17.7729 10.3786 1 1 16 7 17.057 13.4527 1 1 16 8 4.12817 15.4312 1 1 17 -4 60.289 16.2555 1 1 17 -3 56.7097 10.7593 1 1 17 -2 41.0011 8.75854 1 1 17 -1 29.0921 7.95738 1 1 17 0 3.04577 6.31757 1 1 17 1 29.5897 9.23113 1 1 17 2 25.7658 11.8195 1 1 17 3 37.5366 13.4719 1 1 17 4 68.9567 12.3854 1 2 0 0 1373.86 93.6329 1 2 0 1 957.57 40.4389 1 2 0 2 75.2531 6.5265 1 2 0 3 1017.91 45.6536 1 2 0 4 154.484 7.09668 1 2 0 5 4.67837 1.82566 1 2 0 6 20.4902 2.25377 1 2 0 7 124.134 6.9842 1 2 0 8 6.15586 1.93068 1 2 0 9 72.8993 5.095 1 2 0 10 40.0938 3.25994 1 2 0 11 49.5728 3.90181 1 2 0 12 88.4758 5.75822 1 2 0 13 24.6153 3.37009 1 2 0 14 81.7821 5.40444 1 2 0 15 4.97921 3.59442 1 2 0 16 28.0041 4.82375 1 2 0 17 114.711 10.467 1 2 0 18 335.202 23.1114 1 2 0 19-2.38415 23.7738 1 2 1 -19 30.3938 10.4148 1 2 1 -18 135.746 14.6814 1 2 1 -17 100.72 13.6264 1 2 1 -16 4.14986 5.25 1 2 1 -15 34.6488 5.00942 1 2 1 -14 82.5924 6.46812 1 2 1 -13 29.7443 3.69623 1 2 1 -12 108.737 8.13187 1 2 1 -11 437.131 18.6481 1 2 1 -10 255.782 10.5218 1 2 1 -9 456.712 24.3338 1 2 1 -8 64.3884 3.65992 1 2 1 -7 776.908 34.4372 1 2 1 -6 30.1963 2.41972 1 2 1 -5 134.142 6.10673 1 2 1 -4 223.832 10.8977 1 2 1 -3 350.076 30.9459 1 2 1 -2 536.495 25.8554 1 2 1 -1 994.848 55.4872 1 2 1 0 402.166 18.17 1 2 1 1 974.547 48.7666 1 2 1 2 552.546 24.1175 1 2 1 3 346.224 20.3638 1 2 1 4 209.891 9.59647 1 2 1 5 138.428 6.07551 1 2 1 6 34.3009 3.62859 1 2 1 7 796.909 34.2681 1 2 1 8 61.4019 5.83695 1 2 1 9 419.883 29.8183 1 2 1 10 261.413 11.5339 1 2 1 11 459.553 17.9979 1 2 1 12 114.105 5.78281 1 2 1 13 29.8908 3.44737 1 2 1 14 84.1435 5.69872 1 2 1 15 30.415 3.95186 1 2 1 16 7.53842 5.98351 1 2 1 17 114.276 11.4548 1 2 1 18 154.402 17.2009 1 2 1 19 50.9729 9.84643 1 2 2 -19 133.759 13.8031 1 2 2 -18 122.509 13.1852 1 2 2 -17 127.664 13.9525 1 2 2 -16 28.0164 6.83202 1 2 2 -15 114.799 12.014 1 2 2 -14 59.3058 5.20282 1 2 2 -13 126.534 9.58292 1 2 2 -12 148.531 7.77303 1 2 2 -11 43.2834 4.0147 1 2 2 -10 58.7137 5.81948 1 2 2 -9 293.56 12.0957 1 2 2 -8 411.433 17.3449 1 2 2 -7 77.3275 5.20876 1 2 2 -6 230.033 9.52003 1 2 2 -5 157.232 8.73033 1 2 2 -4 1.71686 2.0017 1 2 2 -3 341.785 17.1786 1 2 2 -2 92.9433 6.73549 1 2 2 -1 10.5793 2.00142 1 2 2 0 1482.32 60.6895 1 2 2 1 13.734 1.917 1 2 2 2 93.6823 7.46538 1 2 2 3 344.395 17.7619 1 2 2 4-0.08523 5.07106 1 2 2 5 138.034 8.94079 1 2 2 6 230.257 11.5171 1 2 2 7 87.5746 7.80796 1 2 2 8 409.909 16.7753 1 2 2 9 309.682 14.8373 1 2 2 10 56.7711 4.311 1 2 2 11 48.5751 3.61235 1 2 2 12 165.199 8.28302 1 2 2 13 134.424 7.32223 1 2 2 14 49.2792 4.25846 1 2 2 15 124.178 9.96746 1 2 2 16 24.7014 7.3099 1 2 2 17 111.192 10.6116 1 2 2 18 122.998 13.6436 1 2 2 19 104.646 12.2477 1 2 3 -19 36.0033 8.54593 1 2 3 -18 54.7837 10.7568 1 2 3 -17 121.159 12.3026 1 2 3 -16 201.706 13.4287 1 2 3 -15 6.64416 3.58438 1 2 3 -14 187.415 10.3665 1 2 3 -13 273.026 13.6751 1 2 3 -12 7.71773 2.79113 1 2 3 -11 6.4492 2.64475 1 2 3 -10 298.004 12.7885 1 2 3 -9 7.2596 2.38216 1 2 3 -8 771.202 41.9261 1 2 3 -7 55.2027 5.61076 1 2 3 -6 110.205 5.3025 1 2 3 -5 103.11 5.59642 1 2 3 -4 291.567 14.3982 1 2 3 -3 317.962 22.9093 1 2 3 -2 21.0661 2.38519 1 2 3 -1 78.3459 3.981 1 2 3 0 123.156 6.72051 1 2 3 1 76.0798 4.1245 1 2 3 2 22.977 2.02807 1 2 3 3 313.761 13.0868 1 2 3 4 282.599 15.2788 1 2 3 5 101.552 4.95458 1 2 3 6 103.394 6.69086 1 2 3 7 57.7088 4.67433 1 2 3 8 703.177 35.1488 1 2 3 9 5.57612 1.92196 1 2 3 10 328.833 14.84 1 2 3 11 8.75842 2.2644 1 2 3 12 12.0095 2.46041 1 2 3 13 282.575 12.2918 1 2 3 14 178.50 9.29103 1 2 3 15-2.05168 8.80968 1 2 3 16 210.042 15.609 1 2 3 17 127.947 12.8003 1 2 3 18 43.0262 7.43064 1 2 3 19 38.915 9.68145 1 2 4 -18 9.43498 7.3262 1 2 4 -17 12.3229 5.51106 1 2 4 -16 70.8589 7.4204 1 2 4 -15 14.4511 4.83383 1 2 4 -14 109.616 7.99986 1 2 4 -13 310.341 15.1973 1 2 4 -12 25.1659 3.73591 1 2 4 -11 38.0156 3.43168 1 2 4 -10 3.99256 2.24053 1 2 4 -9 130.296 6.86192 1 2 4 -8 27.3514 2.88087 1 2 4 -7 241.955 13.1166 1 2 4 -6 241.76 12.6272 1 2 4 -5 138.354 7.8717 1 2 4 -4 261.66 10.8077 1 2 4 -3 187.576 8.31104 1 2 4 -2 513.487 19.7808 1 2 4 -1 449.07 25.8244 1 2 4 0 1109.03 46.6158 1 2 4 1 463.631 19.054 1 2 4 2 484.978 19.9033 1 2 4 3 194.228 10.8891 1 2 4 4 279.262 14.6066 1 2 4 5 134.931 8.18051 1 2 4 6 242.615 14.8834 1 2 4 7 230.864 11.6946 1 2 4 8 27.348 2.05916 1 2 4 9 139.386 6.60007 1 2 4 10 4.45257 1.62456 1 2 4 11 40.4943 3.05076 1 2 4 12 21.9836 2.79795 1 2 4 13 297.849 13.2255 1 2 4 14 107.588 7.22651 1 2 4 15 4.93986 5.44076 1 2 4 16 71.6775 7.24008 1 2 4 17 -0.6319 15.1202 1 2 4 18-1.16788 15.9963 1 2 5 -18 43.6085 9.95454 1 2 5 -17 82.2178 9.94906 1 2 5 -16 54.1489 7.32327 1 2 5 -15 25.6809 5.06505 1 2 5 -14 123.658 10.133 1 2 5 -13 6.10438 3.8439 1 2 5 -12 77.4555 5.55019 1 2 5 -11 125.167 8.02828 1 2 5 -10 36.2306 3.1356 1 2 5 -9 210.00 9.5905 1 2 5 -8 23.5416 2.63224 1 2 5 -7 153.223 7.16802 1 2 5 -6 671.881 33.2409 1 2 5 -5 40.0882 3.98233 1 2 5 -4 211.612 9.2282 1 2 5 -3 379.183 15.4635 1 2 5 -2 156.252 8.98841 1 2 5 -1 512.852 25.8822 1 2 5 0 66.7664 4.43818 1 2 5 1 468.673 19.8791 1 2 5 2 150.937 9.63999 1 2 5 3 391.962 20.9023 1 2 5 4 238.943 11.0445 1 2 5 5 35.6285 2.44668 1 2 5 6 673.453 26.5781 1 2 5 7 139.227 7.76778 1 2 5 8 27.8853 2.14662 1 2 5 9 211.218 8.88229 1 2 5 10 32.5888 2.39398 1 2 5 11 114.138 5.31054 1 2 5 12 81.7508 4.25028 1 2 5 13-1.28723 7.79679 1 2 5 14 138.934 8.46529 1 2 5 15 24.9068 4.2656 1 2 5 16 58.9358 6.9078 1 2 5 17 78.9804 8.63183 1 2 5 18 41.7552 7.86193 1 2 6 -18 14.5615 8.91597 1 2 6 -17 4.84389 6.65092 1 2 6 -16 99.458 9.81695 1 2 6 -15 7.17353 5.76009 1 2 6 -14 215.016 12.7381 1 2 6 -13 90.7438 6.58516 1 2 6 -12 117.331 7.89014 1 2 6 -11 3.18484 3.43544 1 2 6 -10 256.421 12.5974 1 2 6 -9 27.9589 3.23511 1 2 6 -8 128.069 6.56109 1 2 6 -7 158.249 7.64377 1 2 6 -6 79.1448 5.2418 1 2 6 -5 146.052 10.885 1 2 6 -4 533.352 27.007 1 2 6 -3 250.803 9.63416 1 2 6 -2 408.762 17.3866 1 2 6 -1 75.1921 5.26181 1 2 6 0 86.705 7.49411 1 2 6 1 81.1855 4.33826 1 2 6 2 430.942 27.5201 1 2 6 3 247.74 11.41 1 2 6 4 539.102 33.3617 1 2 6 5 148.005 6.46677 1 2 6 6 73.8783 4.49571 1 2 6 7 161.397 6.4243 1 2 6 8 116.523 5.16519 1 2 6 9 31.9982 2.47562 1 2 6 10 268.93 10.8602 1 2 6 11-4.70579 5.7071 1 2 6 12 119.61 6.17773 1 2 6 13 96.9808 7.44386 1 2 6 14 224.396 12.3128 1 2 6 15 12.3659 4.51164 1 2 6 16 113.512 14.094 1 2 6 17 5.77877 8.55434 1 2 6 18 22.8712 10.4732 1 2 7 -17 20.4888 12.6877 1 2 7 -16 59.1528 8.2143 1 2 7 -15 12.1278 5.89566 1 2 7 -14 70.9037 6.66781 1 2 7 -13 81.6268 6.88095 1 2 7 -12 49.2117 5.04586 1 2 7 -11 20.3995 3.69264 1 2 7 -10 125.221 8.58439 1 2 7 -9 45.5008 4.18358 1 2 7 -8 100.183 6.23594 1 2 7 -7 159.787 7.93551 1 2 7 -6 34.1379 3.10316 1 2 7 -5 446.086 24.394 1 2 7 -4 432.78 17.9605 1 2 7 -3 298.034 11.4908 1 2 7 -2 369.558 14.7062 1 2 7 -1 105.324 7.61812 1 2 7 0 121.495 9.49917 1 2 7 1 114.116 6.42583 1 2 7 2 382.886 21.4407 1 2 7 3 312.675 16.7952 1 2 7 4 464.22 23.8635 1 2 7 5 453.181 44.6654 1 2 7 6 32.2313 2.36035 1 2 7 7 157.468 6.28767 1 2 7 8 86.9888 4.34691 1 2 7 9 35.381 2.77894 1 2 7 10 115.165 5.62531 1 2 7 11 12.6188 2.65975 1 2 7 12 43.0244 3.87369 1 2 7 13 84.721 6.20878 1 2 7 14 78.5968 8.78203 1 2 7 15 16.8349 9.14902 1 2 7 16 70.5277 9.07987 1 2 7 17 31.3494 8.13696 1 2 8 -17 55.3891 11.6299 1 2 8 -16 49.6411 9.76932 1 2 8 -15 71.6152 9.38478 1 2 8 -14 191.081 12.8633 1 2 8 -13 70.8789 9.06417 1 2 8 -12 34.7619 4.84635 1 2 8 -11 233.865 20.5683 1 2 8 -10 433.902 22.0563 1 2 8 -9 118.963 9.31824 1 2 8 -8 20.3268 3.50068 1 2 8 -7 235.495 11.6813 1 2 8 -6 253.006 11.8085 1 2 8 -5 6.25417 2.08493 1 2 8 -4 129.395 5.57925 1 2 8 -3 86.9493 3.98597 1 2 8 -2 151.83 6.96522 1 2 8 -1 198.979 9.8875 1 2 8 0-1.63416 6.03002 1 2 8 1 196.712 11.5799 1 2 8 2 153.173 6.87319 1 2 8 3 89.1492 6.39452 1 2 8 4 130.09 8.08606 1 2 8 5 4.63929 1.96754 1 2 8 6 261.67 12.323 1 2 8 7 219.052 11.8385 1 2 8 8 20.3383 2.2919 1 2 8 9 109.438 5.51153 1 2 8 10 433.602 19.7675 1 2 8 11 244.387 11.4343 1 2 8 12 32.5572 4.5861 1 2 8 13 62.6721 5.65928 1 2 8 14 188.622 13.5424 1 2 8 15 76.5819 9.50989 1 2 8 16 49.943 9.09662 1 2 8 17 52.671 34.3351 1 2 9 -16 11.5275 10.2902 1 2 9 -15 84.6317 13.7652 1 2 9 -14 38.793 7.38589 1 2 9 -13 8.84717 5.96321 1 2 9 -12 55.0054 6.0366 1 2 9 -11 2.0125 4.4323 1 2 9 -10 121.107 8.11313 1 2 9 -9 24.108 4.12905 1 2 9 -8 30.218 4.2471 1 2 9 -7 94.4446 5.69472 1 2 9 -6 62.5443 4.16408 1 2 9 -5 226.761 13.8413 1 2 9 -4 7.41211 2.32729 1 2 9 -3 338.478 13.719 1 2 9 -2 51.595 3.29741 1 2 9 -1 163.226 8.85887 1 2 9 0 1.52145 2.68961 1 2 9 1 169.452 8.92641 1 2 9 2 51.6229 3.23289 1 2 9 3 338.202 14.2043 1 2 9 4 8.75803 2.38795 1 2 9 5 225.404 9.24451 1 2 9 6 58.4595 3.74624 1 2 9 7 98.2158 5.48951 1 2 9 8 30.4706 2.72091 1 2 9 9 20.0632 3.01773 1 2 9 10 117.138 7.42278 1 2 9 11 2.2676 5.01544 1 2 9 12 53.0745 7.30268 1 2 9 13 18.0772 4.42553 1 2 9 14 32.8978 6.28139 1 2 9 15 102.866 12.8632 1 2 9 16 7.17213 9.79225 1 2 10 -15 75.2719 22.5002 1 2 10 -14-1.91143 15.8026 1 2 10 -13 8.47344 6.41247 1 2 10 -12-5.27099 13.1097 1 2 10 -11 116.79 10.4928 1 2 10 -10 392.958 25.1804 1 2 10 -9 4.31911 5.59546 1 2 10 -8 54.8957 5.80654 1 2 10 -7 1.6129 3.38054 1 2 10 -6 108.188 6.18754 1 2 10 -5 94.5367 5.80208 1 2 10 -4 220.956 9.44893 1 2 10 -3 36.7887 2.99903 1 2 10 -2 131.636 6.91866 1 2 10 -1 47.6275 3.23572 1 2 10 0 12.823 3.04323 1 2 10 1 49.8547 3.82871 1 2 10 2 137.156 7.14034 1 2 10 3 36.6289 3.42115 1 2 10 4 223.751 9.11635 1 2 10 5 90.7041 5.54768 1 2 10 6 102.614 6.10877 1 2 10 7 0.01619 3.69097 1 2 10 8 53.5163 4.25539 1 2 10 9-0.10868 12.7426 1 2 10 10 408.022 22.0403 1 2 10 11 124.254 9.72492 1 2 10 12 14.8449 7.31232 1 2 10 13-0.01785 16.937 1 2 10 14 7.05414 7.93801 1 2 10 15 68.4985 11.2444 1 2 11 -14 54.6885 9.73162 1 2 11 -13 7.13535 9.93641 1 2 11 -12 193.691 17.1266 1 2 11 -11 59.8959 8.36849 1 2 11 -10 52.5181 6.76745 1 2 11 -9 56.5556 6.62862 1 2 11 -8 23.0472 5.58186 1 2 11 -7 53.1648 6.22224 1 2 11 -6 125.536 9.99145 1 2 11 -5-1.98692 9.71987 1 2 11 -4 63.9402 4.99505 1 2 11 -3 69.4076 4.44134 1 2 11 -2 21.9234 3.30763 1 2 11 -1 121.796 7.40841 1 2 11 0 361.207 15.3024 1 2 11 1 117.615 6.48815 1 2 11 2 18.881 3.08564 1 2 11 3 71.6516 4.69915 1 2 11 4 69.0954 4.69272 1 2 11 5 2.22365 2.72122 1 2 11 6 144.823 9.19014 1 2 11 7 50.5386 5.48226 1 2 11 8 25.306 4.40669 1 2 11 9 56.9947 6.93668 1 2 11 10 56.6413 9.67292 1 2 11 11 54.6831 9.79627 1 2 11 12 194.824 20.83 1 2 11 13-2.08295 24.9127 1 2 11 14 38.756 32.6315 1 2 12 -13 17.1566 11.9377 1 2 12 -12 3.10775 7.45513 1 2 12 -11 115.179 11.413 1 2 12 -10 35.7553 6.93208 1 2 12 -9 31.8466 6.48689 1 2 12 -8 103.72 8.65158 1 2 12 -7 62.754 9.34993 1 2 12 -6 92.772 8.08811 1 2 12 -5 8.01806 4.0578 1 2 12 -4 289.235 15.0286 1 2 12 -3 158.494 10.1178 1 2 12 -2 12.1117 4.19153 1 2 12 -1 165.369 12.8594 1 2 12 0-0.13975 10.6572 1 2 12 1 132.645 13.5862 1 2 12 2 15.2549 4.50061 1 2 12 3 162.445 10.6564 1 2 12 4 275.295 15.5028 1 2 12 5 18.4651 4.56457 1 2 12 6 85.1006 7.51155 1 2 12 7 58.9541 6.32211 1 2 12 8 109.686 13.3704 1 2 12 9 29.9075 15.5353 1 2 12 10 33.6696 10.4918 1 2 12 11 104.876 14.666 1 2 12 12-3.71437 20.8594 1 2 12 13-6.79993 17.0514 1 2 13 -12 0.88912 9.64867 1 2 13 -11 48.1682 9.09142 1 2 13 -10 198.792 17.7159 1 2 13 -9 108.969 10.8242 1 2 13 -8 34.4606 7.35847 1 2 13 -7 28.951 8.83309 1 2 13 -6 39.8434 5.56526 1 2 13 -5 165.316 13.761 1 2 13 -4 137.301 12.0333 1 2 13 -3 326.33 17.3288 1 2 13 -2 60.1597 5.85242 1 2 13 -1 145.773 10.2171 1 2 13 0 20.292 5.41002 1 2 13 1 135.215 10.9309 1 2 13 2 59.6437 6.44575 1 2 13 3 338.351 19.4644 1 2 13 4 156.544 12.4826 1 2 13 5 153.358 21.4614 1 2 13 6 35.3834 10.6059 1 2 13 7 36.4247 6.70354 1 2 13 8 49.0409 8.91413 1 2 13 9 115.364 17.265 1 2 13 10 251.572 34.7463 1 2 13 11 55.4201 28.986 1 2 13 12 30.222 16.6309 1 2 14 -10 -4.9701 17.1402 1 2 14 -9 12.8427 7.74157 1 2 14 -8 19.7713 9.0313 1 2 14 -7 7.03263 7.77213 1 2 14 -6 33.4715 7.14678 1 2 14 -5 11.2014 5.641 1 2 14 -4 118.31 10.9481 1 2 14 -3 254.169 15.4416 1 2 14 -2 215.096 13.0743 1 2 14 -1 11.8068 11.415 1 2 14 0 4.95035 9.35548 1 2 14 1 14.4765 7.75682 1 2 14 2 199.416 15.1911 1 2 14 3 240.254 18.232 1 2 14 4 121.96 11.039 1 2 14 5 8.0046 9.23133 1 2 14 6 30.398 9.23696 1 2 14 7 7.2208 7.31843 1 2 14 8 12.1288 9.97133 1 2 14 9 12.9726 14.8161 1 2 14 10 16.2355 10.7329 1 2 15 -8 11.7507 10.5195 1 2 15 -7 12.8735 7.42176 1 2 15 -6 56.0472 9.11871 1 2 15 -5 77.1874 13.3889 1 2 15 -4 19.4525 11.0024 1 2 15 -3 26.7749 9.54699 1 2 15 -2 0.5245 14.4712 1 2 15 -1 9.26271 10.2285 1 2 15 0 120.731 19.6795 1 2 15 1 13.3667 9.04842 1 2 15 2 12.6895 4.93062 1 2 15 3 18.3977 7.12824 1 2 15 4 22.2974 7.32524 1 2 15 5 57.171 10.3658 1 2 15 6 44.9505 10.5471 1 2 15 7 11.8691 9.32837 1 2 15 8 16.186 18.7089 1 2 16 -5 7.97959 14.1249 1 2 16 -4 18.0168 14.0588 1 2 16 -3-9.14959 25.0378 1 2 16 -2 47.7096 11.6959 1 2 16 -1 35.398 14.4842 1 2 16 0 8.45469 21.6256 1 2 16 1 40.0233 16.7536 1 2 16 2 57.6897 12.4582 1 2 16 3 5.49387 10.6581 1 2 16 4 34.1668 10.2922 1 2 16 5 10.7288 12.8745 1 3 0 1 1252.09 48.9461 1 3 0 2 57.8831 3.66966 1 3 0 3 179.204 7.58332 1 3 0 4 82.8695 4.71971 1 3 0 5 133.214 7.0047 1 3 0 6 143.735 7.29588 1 3 0 7 20.594 2.82042 1 3 0 8 114.933 6.39003 1 3 0 9 326.821 18.4921 1 3 0 10 137.287 11.1583 1 3 0 11 4.15168 3.79955 1 3 0 12 9.30684 4.10531 1 3 0 13 30.5174 4.40651 1 3 0 14 87.0443 9.67978 1 3 0 15 15.2449 4.73201 1 3 0 16 68.7684 8.43863 1 3 0 17 318.73 24.1772 1 3 1 -17 108.224 11.116 1 3 1 -16 59.1756 7.64491 1 3 1 -15 0.31665 7.54462 1 3 1 -14 4.40603 4.05809 1 3 1 -13 17.3208 4.22054 1 3 1 -12 59.8122 5.10404 1 3 1 -11 211.234 11.2197 1 3 1 -10 65.1212 4.66675 1 3 1 -9 84.4889 6.88305 1 3 1 -8 44.0701 3.85129 1 3 1 -7 286.847 17.4684 1 3 1 -6 262.491 12.1847 1 3 1 -5 13.0369 2.08661 1 3 1 -4 105.949 5.0126 1 3 1 -3 109.489 5.32616 1 3 1 -2 233.463 11.2867 1 3 1 -1 194.132 7.87831 1 3 1 0 1256.92 55.2706 1 3 1 1 191.716 8.02993 1 3 1 2 234.66 9.07578 1 3 1 3 113.795 6.31544 1 3 1 4 98.9731 6.85043 1 3 1 5 14.3039 2.81036 1 3 1 6 259.80 16.1743 1 3 1 7 261.698 13.9992 1 3 1 8 41.0519 4.1703 1 3 1 9 93.6982 6.94279 1 3 1 10 79.8011 5.28497 1 3 1 11 234.246 17.408 1 3 1 12 60.6861 5.85121 1 3 1 13 13.6061 4.07738 1 3 1 14-7.38329 9.86471 1 3 1 15-3.70092 11.9782 1 3 1 16 39.6492 7.55642 1 3 1 17 88.0458 13.2434 1 3 2 -17 2.82558 7.22954 1 3 2 -16 93.1984 9.82542 1 3 2 -15 0.52114 6.70574 1 3 2 -14 54.6516 6.18495 1 3 2 -13 95.2347 7.11939 1 3 2 -12 5.36626 3.7813 1 3 2 -11 197.652 10.7674 1 3 2 -10 56.261 4.17132 1 3 2 -9 56.2529 4.2554 1 3 2 -8 152.90 16.4267 1 3 2 -7 79.2198 5.08584 1 3 2 -6 35.7707 3.16731 1 3 2 -5 475.81 23.2071 1 3 2 -4 405.91 20.7082 1 3 2 -3 53.9804 4.2784 1 3 2 -2 569.637 33.5199 1 3 2 -1 159.91 7.09292 1 3 2 0 240.547 10.4509 1 3 2 1 163.037 8.94063 1 3 2 2 653.26 29.4115 1 3 2 3 53.5935 3.70171 1 3 2 4 401.387 23.0342 1 3 2 5 521.481 26.0395 1 3 2 6 31.6456 2.98481 1 3 2 7 74.1764 6.14089 1 3 2 8 148.174 15.82 1 3 2 9 56.0038 6.07978 1 3 2 10 54.2366 4.30537 1 3 2 11 191.207 13.3072 1 3 2 12 0.73614 4.88254 1 3 2 13 94.6171 8.58055 1 3 2 14 60.7712 7.40803 1 3 2 15-4.10399 19.3633 1 3 2 16 100.186 20.1876 1 3 2 17 22.6368 7.31766 1 3 3 -17 120.521 14.0032 1 3 3 -16 107.593 14.1129 1 3 3 -15 114.193 10.1285 1 3 3 -14 144.393 10.6403 1 3 3 -13 129.948 11.4959 1 3 3 -12 6.62391 4.70573 1 3 3 -11 56.5468 5.26632 1 3 3 -10 66.0661 5.79835 1 3 3 -9 22.9885 3.30179 1 3 3 -8 35.0648 4.26263 1 3 3 -7 61.2207 4.52519 1 3 3 -6 319.957 13.9816 1 3 3 -5 129.186 7.69447 1 3 3 -4 56.684 3.90499 1 3 3 -3 451.67 24.4924 1 3 3 -2 344.851 28.1763 1 3 3 -1 303.385 13.6132 1 3 3 0 1.21793 1.88231 1 3 3 1 274.726 16.5467 1 3 3 2 339.225 27.1164 1 3 3 3 453.981 33.218 1 3 3 4 54.3898 3.45179 1 3 3 5 132.57 13.1948 1 3 3 6 278.46 12.6428 1 3 3 7 53.115 4.58128 1 3 3 8 37.5862 2.82728 1 3 3 9 25.0774 3.8568 1 3 3 10 70.5592 6.08038 1 3 3 11 58.1616 4.57108 1 3 3 12 8.06818 4.59485 1 3 3 13 131.48 11.6964 1 3 3 14 147.037 13.5786 1 3 3 15 103.525 11.9436 1 3 3 16 97.6909 16.2361 1 3 3 17 129.355 19.0709 1 3 4 -17 26.0314 7.92006 1 3 4 -16 26.5402 8.14791 1 3 4 -15 171.742 17.5444 1 3 4 -14 38.8834 9.77311 1 3 4 -13 170.305 10.7141 1 3 4 -12 233.583 12.3883 1 3 4 -11 8.6577 3.76732 1 3 4 -10 42.6581 3.83759 1 3 4 -9 31.142 3.82818 1 3 4 -8 172.511 14.1093 1 3 4 -7 107.807 9.63932 1 3 4 -6 44.9365 4.19239 1 3 4 -5 74.4879 4.67354 1 3 4 -4 7.82054 2.57091 1 3 4 -3 31.0085 5.02745 1 3 4 -2 107.241 7.23517 1 3 4 -1 49.80 3.82464 1 3 4 0 92.0894 7.12486 1 3 4 1 49.0954 3.06138 1 3 4 2 106.465 5.8473 1 3 4 3 29.9616 2.60264 1 3 4 4 6.73942 2.00843 1 3 4 5 73.4642 5.49988 1 3 4 6 44.9574 3.54107 1 3 4 7 108.738 8.12934 1 3 4 8 174.122 7.47095 1 3 4 9 27.2099 2.74812 1 3 4 10 40.7273 3.31693 1 3 4 11 12.2682 2.93989 1 3 4 12 235.836 11.3396 1 3 4 13 189.893 12.7684 1 3 4 14 42.9421 5.699 1 3 4 15 169.842 15.6728 1 3 4 16 27.6502 7.8826 1 3 4 17 28.5287 9.69445 1 3 5 -16-15.4422 17.4767 1 3 5 -15 159.866 13.9199 1 3 5 -14-5.11029 16.9065 1 3 5 -13 125.014 10.9738 1 3 5 -12 26.818 4.32602 1 3 5 -11 162.053 9.1096 1 3 5 -10 110.815 6.93791 1 3 5 -9 3.57007 3.49757 1 3 5 -8 338.634 15.5307 1 3 5 -7 201.272 9.47864 1 3 5 -6 91.4598 5.8888 1 3 5 -5 49.6605 4.05191 1 3 5 -4 106.339 6.97564 1 3 5 -3 72.9244 4.56058 1 3 5 -2 127.695 7.94782 1 3 5 -1 103.293 5.42289 1 3 5 0 513.617 20.4303 1 3 5 1 87.4528 4.4164 1 3 5 2 132.046 6.82082 1 3 5 3 75.5363 4.95794 1 3 5 4 102.902 5.50575 1 3 5 5 52.7511 4.95677 1 3 5 6 95.954 5.42854 1 3 5 7 210.86 9.72009 1 3 5 8 333.224 17.3693 1 3 5 9 2.17573 2.1667 1 3 5 10 126.022 6.72229 1 3 5 11 151.339 7.44838 1 3 5 12 23.0233 3.26388 1 3 5 13 136.085 10.4385 1 3 5 14 3.00224 8.56269 1 3 5 15 184.861 20.30 1 3 5 16 1.19175 5.97156 1 3 6 -16 1.50795 13.2378 1 3 6 -15 44.6542 13.5911 1 3 6 -14 131.939 11.2908 1 3 6 -13 62.0739 7.71749 1 3 6 -12 18.9228 4.24167 1 3 6 -11 171.555 10.7327 1 3 6 -10 18.8171 4.13198 1 3 6 -9 423.462 20.1752 1 3 6 -8 10.8763 3.44665 1 3 6 -7 123.92 7.00612 1 3 6 -6 19.4602 3.35461 1 3 6 -5 15.4067 2.80086 1 3 6 -4 513.052 29.99 1 3 6 -3 398.625 19.1742 1 3 6 -2 23.613 3.41368 1 3 6 -1 61.8211 3.88214 1 3 6 0 3.99511 1.87038 1 3 6 1 62.3686 3.83685 1 3 6 2 23.5981 2.86434 1 3 6 3 367.711 24.7282 1 3 6 4 525.298 22.0327 1 3 6 5 13.5124 2.39099 1 3 6 6 16.5963 3.14199 1 3 6 7 127.984 6.69956 1 3 6 8 6.84107 3.10207 1 3 6 9 415.02 17.9198 1 3 6 10 18.8338 2.54111 1 3 6 11 159.633 7.9298 1 3 6 12 18.8598 4.0513 1 3 6 13 69.8564 6.16739 1 3 6 14 134.111 11.522 1 3 6 15 47.6053 9.07545 1 3 6 16-2.38994 10.3015 1 3 7 -15 75.2265 11.1059 1 3 7 -14 19.6846 6.33666 1 3 7 -13 -6.4658 18.4772 1 3 7 -12 246.132 17.1815 1 3 7 -11 163.394 10.6954 1 3 7 -10 251.46 18.7495 1 3 7 -9 0.54824 4.00988 1 3 7 -8 245.06 13.8405 1 3 7 -7 8.67807 3.43605 1 3 7 -6 233.351 11.6518 1 3 7 -5 64.9308 5.31232 1 3 7 -4 118.766 10.4947 1 3 7 -3 84.3088 10.9847 1 3 7 -2 82.2639 7.73687 1 3 7 -1 135.074 7.63023 1 3 7 0 77.715 6.05404 1 3 7 1 137.051 7.93437 1 3 7 2 92.4695 6.16735 1 3 7 3 86.9208 6.82998 1 3 7 4 104.38 6.25444 1 3 7 5 59.5172 5.13608 1 3 7 6 238.856 16.361 1 3 7 7 7.12491 3.02963 1 3 7 8 240.507 12.9998 1 3 7 9 0.41621 3.05508 1 3 7 10 253.769 14.4192 1 3 7 11 139.555 10.2148 1 3 7 12 224.128 13.1738 1 3 7 13 -8.8724 10.7157 1 3 7 14 18.3023 7.69417 1 3 7 15 80.7271 15.079 1 3 8 -15 18.7055 8.33778 1 3 8 -14 15.6318 8.25048 1 3 8 -13 8.35261 10.3134 1 3 8 -12 68.1696 12.2166 1 3 8 -11 18.5479 5.16606 1 3 8 -10 69.8488 7.05905 1 3 8 -9 24.817 4.98764 1 3 8 -8 155.948 11.2573 1 3 8 -7 17.5893 4.66975 1 3 8 -6 95.0168 7.2244 1 3 8 -5 206.825 12.9892 1 3 8 -4 21.4026 4.85881 1 3 8 -3 73.5737 6.43766 1 3 8 -2-0.11793 8.47524 1 3 8 -1 169.99 7.65224 1 3 8 0 41.7467 3.77762 1 3 8 1 171.463 7.59325 1 3 8 2 1.33855 2.55092 1 3 8 3 65.3497 4.33195 1 3 8 4 25.2209 3.01555 1 3 8 5 185.377 10.0564 1 3 8 6 96.5478 5.86046 1 3 8 7 18.4266 3.25454 1 3 8 8 140.101 7.5942 1 3 8 9 23.253 3.81978 1 3 8 10 62.3393 8.6142 1 3 8 11 10.9047 6.99843 1 3 8 12 69.3206 11.3928 1 3 8 13-1.30198 11.6472 1 3 8 14 21.2291 6.7773 1 3 8 15 16.8762 6.3268 1 3 9 -14 67.5371 11.5395 1 3 9 -13 2.2085 6.27788 1 3 9 -12 38.6561 8.97422 1 3 9 -11 13.9571 6.68648 1 3 9 -10 82.7831 9.37432 1 3 9 -9 66.6718 6.86682 1 3 9 -8 166.946 11.3068 1 3 9 -7 43.6171 5.68405 1 3 9 -6 9.92585 5.10183 1 3 9 -5 140.809 9.15553 1 3 9 -4 493.413 34.8085 1 3 9 -3 10.2965 3.04162 1 3 9 -2 97.5517 7.68729 1 3 9 -1 111.674 6.14024 1 3 9 0 175.232 8.5445 1 3 9 1 108.293 6.42047 1 3 9 2 103.297 5.52899 1 3 9 3 4.8476 2.88709 1 3 9 4 530.904 26.3916 1 3 9 5 138.431 8.36968 1 3 9 6 11.2738 3.52658 1 3 9 7 41.0889 4.78455 1 3 9 8 171.427 10.9824 1 3 9 9 63.347 6.25494 1 3 9 10 88.8642 10.0834 1 3 9 11 9.95432 6.80606 1 3 9 12 32.8387 15.2751 1 3 9 13 3.97886 10.3406 1 3 9 14 52.7652 10.8082 1 3 10 -13-6.29286 17.5945 1 3 10 -12 6.19427 8.34418 1 3 10 -11 5.37994 9.92422 1 3 10 -10 143.851 11.7289 1 3 10 -9 134.461 14.7775 1 3 10 -8 26.3925 5.53507 1 3 10 -7 23.6712 6.46152 1 3 10 -6 84.3822 12.2678 1 3 10 -5 118.679 8.63062 1 3 10 -4 64.8237 7.07346 1 3 10 -3 202.064 14.3695 1 3 10 -2 36.1279 5.82204 1 3 10 -1 196.753 10.7498 1 3 10 0 145.497 8.39647 1 3 10 1 199.957 11.5906 1 3 10 2 41.7879 5.49048 1 3 10 3 195.324 11.5782 1 3 10 4 61.2895 5.65851 1 3 10 5 117.326 8.47674 1 3 10 6 94.8994 7.25531 1 3 10 7 15.5548 5.11798 1 3 10 8 14.2543 4.48838 1 3 10 9 118.714 9.44863 1 3 10 10 144.335 12.4476 1 3 10 11 0.1634 17.4368 1 3 10 12-3.86798 27.062 1 3 10 13-3.24572 15.5344 1 3 11 -12 2.45423 7.7489 1 3 11 -11 10.0161 10.6067 1 3 11 -10 62.77 14.4854 1 3 11 -9 -3.9112 25.4606 1 3 11 -8 8.7617 9.22078 1 3 11 -7 22.4341 6.0869 1 3 11 -6 21.5304 5.63519 1 3 11 -5 238.492 16.0559 1 3 11 -4 128.406 14.2613 1 3 11 -3 11.7334 6.20703 1 3 11 -2 71.3441 11.7148 1 3 11 -1 173.728 16.1145 1 3 11 0 661.791 38.798 1 3 11 1 170.83 12.8182 1 3 11 2 63.9417 6.42796 1 3 11 3 11.3252 5.21739 1 3 11 4 136.315 10.3874 1 3 11 5 264.112 15.50 1 3 11 6 24.9514 11.2868 1 3 11 7 8.50372 6.14797 1 3 11 8 7.24179 5.08968 1 3 11 9 -0.979 11.8491 1 3 11 10 47.8928 13.0672 1 3 11 11 8.73753 11.708 1 3 11 12 5.58104 13.8242 1 3 12 -11 19.149 9.50487 1 3 12 -10 8.0762 20.5142 1 3 12 -9 21.5815 12.5445 1 3 12 -8 48.9497 10.8965 1 3 12 -7-4.77481 17.2397 1 3 12 -6 157.571 14.3066 1 3 12 -5 14.4688 5.58299 1 3 12 -4-8.01026 14.2319 1 3 12 -3 15.6442 8.58997 1 3 12 -2 306.568 23.593 1 3 12 -1 41.0149 11.2489 1 3 12 0 299.325 20.6141 1 3 12 1 50.0016 7.20955 1 3 12 2 312.125 20.9356 1 3 12 3 22.039 8.28211 1 3 12 4 1.93676 7.17887 1 3 12 5 15.6023 8.76804 1 3 12 6 164.854 16.962 1 3 12 7-10.5637 15.4123 1 3 12 8 41.5406 11.0743 1 3 12 9 22.0334 10.8522 1 3 12 10 -9.2316 15.3792 1 3 12 11-17.0462 15.5051 1 3 13 -9 30.0255 11.6361 1 3 13 -8 41.3857 10.4709 1 3 13 -7 118.439 13.7021 1 3 13 -6 72.2825 10.3479 1 3 13 -5 12.0138 8.01588 1 3 13 -4 262.427 37.4225 1 3 13 -3 32.7677 11.1672 1 3 13 -2 61.72 12.4507 1 3 13 -1 74.8469 13.2394 1 3 13 0 85.085 13.7274 1 3 13 1 60.6657 11.7015 1 3 13 2 60.2011 9.69995 1 3 13 3 48.164 9.68208 1 3 13 4 275.154 25.3375 1 3 13 5 18.0128 7.15217 1 3 13 6 65.7192 14.0024 1 3 13 7 96.9467 17.8813 1 3 13 8 21.6296 13.7409 1 3 13 9 30.8048 20.6159 1 3 14 -7 115.968 15.5392 1 3 14 -6-2.62526 22.042 1 3 14 -5 22.42 9.89041 1 3 14 -4 75.6795 19.7268 1 3 14 -3 48.4664 16.3211 1 3 14 -2-2.85885 17.9171 1 3 14 -1-12.1728 16.2041 1 3 14 0-18.9904 17.569 1 3 14 1-8.69892 19.8761 1 3 14 2 8.57316 12.267 1 3 14 3 67.1242 16.1176 1 3 14 4 97.497 16.82 1 3 14 5 31.6014 18.6171 1 3 14 6 3.73013 15.0716 1 3 14 7 119.223 18.4165 1 3 15 -4 0.53564 17.9929 1 3 15 -3 5.00655 17.6619 1 3 15 -1-10.2329 15.3692 1 3 15 0 19.885 21.5576 1 3 15 1 2.40019 14.8216 1 3 15 2 119.315 31.5544 1 3 15 3 14.5137 25.8764 1 3 15 4 23.709 22.9728 1 4 0 0 110.736 6.59516 1 4 0 1 142.184 6.26743 1 4 0 2 27.3259 2.75809 1 4 0 3 60.8187 3.8013 1 4 0 4 7.18057 2.63955 1 4 0 5 279.656 13.9563 1 4 0 6 24.4142 3.524 1 4 0 7 3.91721 3.63105 1 4 0 8 29.3541 7.17569 1 4 0 9 30.3146 8.21807 1 4 0 10 43.6975 8.79102 1 4 0 11 245.135 29.2144 1 4 0 12 27.2953 19.8014 1 4 0 13 24.1779 11.5698 1 4 0 14 7.83398 8.67472 1 4 0 15 15.1355 9.55889 1 4 1 -15 9.15537 15.9575 1 4 1 -14 20.3124 10.5101 1 4 1 -13 23.3948 11.4718 1 4 1 -12 16.3957 14.2062 1 4 1 -11 275.541 24.2887 1 4 1 -10 20.7729 6.19783 1 4 1 -9 17.4342 5.53536 1 4 1 -8 392.158 23.9632 1 4 1 -7 684.672 39.4756 1 4 1 -6 58.58 6.68851 1 4 1 -5 204.51 15.4293 1 4 1 -4 207.694 13.2516 1 4 1 -3 34.3489 5.94286 1 4 1 -2 122.73 7.27696 1 4 1 -1 139.169 7.08043 1 4 1 0 10.4362 2.43588 1 4 1 1 132.607 6.51798 1 4 1 2 127.076 6.11441 1 4 1 3 34.8318 4.54628 1 4 1 4 219.85 11.9337 1 4 1 5 209.946 9.81606 1 4 1 6 45.9445 6.47089 1 4 1 7 691.051 43.7983 1 4 1 8 411.422 27.7748 1 4 1 9 19.8538 9.5954 1 4 1 10 17.8801 12.6108 1 4 1 11 271.848 36.0507 1 4 1 12 19.6833 10.9663 1 4 1 13 22.0024 9.22673 1 4 1 14 19.4987 10.2827 1 4 1 15 24.5563 9.15388 1 4 2 -15 56.0648 17.9079 1 4 2 -14 38.7649 19.2438 1 4 2 -13 72.1777 26.0801 1 4 2 -12 29.7062 12.3015 1 4 2 -11 166.018 14.1263 1 4 2 -10 316.585 38.3361 1 4 2 -9 185.158 15.9674 1 4 2 -8 68.0375 13.5107 1 4 2 -7 600.76 35.073 1 4 2 -6 50.2884 6.82856 1 4 2 -5 33.2169 4.55235 1 4 2 -4 136.899 9.24013 1 4 2 -3 140.814 7.50381 1 4 2 -2 120.418 6.68955 1 4 2 -1 98.6343 9.03033 1 4 2 0 55.0106 6.9185 1 4 2 1 97.7371 6.08402 1 4 2 2 115.826 6.27606 1 4 2 3 155.498 7.42197 1 4 2 4 156.97 8.52459 1 4 2 5 31.6411 3.52821 1 4 2 6 53.8084 10.9625 1 4 2 7 545.475 45.4349 1 4 2 8 76.1454 14.6055 1 4 2 9 180.658 16.3136 1 4 2 10 291.13 24.9207 1 4 2 11 176.909 15.0097 1 4 2 12 30.7262 6.56144 1 4 2 13 92.8063 12.1034 1 4 2 14 41.9241 13.9178 1 4 2 15 40.1739 26.7017 1 4 3 -15 64.3666 14.1103 1 4 3 -14 2.26691 15.2425 1 4 3 -13 28.7435 8.69738 1 4 3 -12 216.376 19.8631 1 4 3 -11 87.5888 10.4697 1 4 3 -10 64.121 10.8132 1 4 3 -9 12.5114 9.04566 1 4 3 -8 20.142 5.91462 1 4 3 -7 146.513 13.4515 1 4 3 -6 161.888 14.3186 1 4 3 -5 37.5123 4.91341 1 4 3 -4 31.2974 4.38768 1 4 3 -3 50.9138 5.18442 1 4 3 -2 218.134 13.9429 1 4 3 -1 18.6009 2.71602 1 4 3 0 29.9663 3.13442 1 4 3 1 16.8219 2.68427 1 4 3 2 221.54 10.7111 1 4 3 3 43.7431 3.6278 1 4 3 4 25.489 3.81812 1 4 3 5 37.4592 3.91138 1 4 3 6 152.175 9.19136 1 4 3 7 137.835 11.0276 1 4 3 8 17.911 4.48678 1 4 3 9 8.54701 4.08456 1 4 3 10 77.2663 9.34135 1 4 3 11 78.9963 12.1892 1 4 3 12 233.598 21.7249 1 4 3 13 22.354 12.7808 1 4 3 14-3.67039 25.5338 1 4 3 15 66.9922 19.3072 1 4 4 -14 7.34771 11.6702 1 4 4 -13 63.9203 13.7823 1 4 4 -12-0.45366 13.4248 1 4 4 -11 7.53108 6.9844 1 4 4 -10 21.5414 9.51763 1 4 4 -9 56.2063 10.6579 1 4 4 -8 77.5409 14.0002 1 4 4 -7 21.8481 8.6635 1 4 4 -6 107.054 10.6421 1 4 4 -5 29.0988 5.11933 1 4 4 -4 32.9506 6.05871 1 4 4 -3 6.3675 4.16994 1 4 4 -2 15.1322 4.21629 1 4 4 -1 56.99 6.01138 1 4 4 0 116.707 6.32238 1 4 4 1 63.5903 6.34024 1 4 4 2 10.2465 3.33717 1 4 4 3 3.89077 2.58372 1 4 4 4 26.8065 5.05359 1 4 4 5 19.3256 4.87358 1 4 4 6 98.8774 6.93876 1 4 4 7 12.6049 3.67614 1 4 4 8 92.3682 7.30225 1 4 4 9 49.5019 5.86676 1 4 4 10 25.3725 8.5744 1 4 4 11 31.0356 6.32444 1 4 4 12-1.38204 13.1379 1 4 4 13 101.741 14.7013 1 4 4 14 33.5994 7.9647 1 4 5 -14 71.3207 13.276 1 4 5 -13 11.4675 9.69668 1 4 5 -12 37.7245 9.11642 1 4 5 -11 6.13876 6.81423 1 4 5 -10 40.1627 8.07673 1 4 5 -9-10.2549 16.852 1 4 5 -8 62.7375 9.21135 1 4 5 -7 187.824 16.054 1 4 5 -6 349.059 43.4922 1 4 5 -5 35.817 6.83561 1 4 5 -4 56.9421 5.40451 1 4 5 -3 204.381 11.985 1 4 5 -2 111.404 18.2742 1 4 5 -1 64.9523 8.22396 1 4 5 0 133.258 8.08635 1 4 5 1 63.7114 5.43349 1 4 5 2 95.4821 6.80776 1 4 5 3 223.254 9.79906 1 4 5 4 57.4995 4.30617 1 4 5 5 35.1494 3.4594 1 4 5 6 330.173 17.3972 1 4 5 7 183.178 11.3018 1 4 5 8 64.0227 6.11505 1 4 5 9 7.31444 5.36051 1 4 5 10 42.847 7.76976 1 4 5 11 6.84385 10.5069 1 4 5 12 46.0957 9.19179 1 4 5 13 27.4145 7.23903 1 4 6 -13 43.4234 11.5815 1 4 6 -12 129.589 14.9108 1 4 6 -11 25.4028 8.6513 1 4 6 -10 55.5475 9.6907 1 4 6 -9 28.551 7.18118 1 4 6 -8 127.421 26.8414 1 4 6 -7 71.2271 15.2225 1 4 6 -6 346.532 26.7153 1 4 6 -5 12.1657 5.98983 1 4 6 -4 118.346 10.1302 1 4 6 -3 322.154 21.6814 1 4 6 -2 55.5342 6.87986 1 4 6 -1 29.7103 4.41102 1 4 6 0 37.836 4.17296 1 4 6 1 28.906 3.68811 1 4 6 2 55.6553 4.738 1 4 6 3 312.693 20.0793 1 4 6 4 123.092 7.19825 1 4 6 5 21.2592 3.50303 1 4 6 6 346.085 18.9581 1 4 6 7 75.9174 10.2255 1 4 6 8 135.485 16.1734 1 4 6 9 32.6365 15.7921 1 4 6 10 68.0109 11.9959 1 4 6 11 39.6533 8.57488 1 4 6 12 144.22 19.3782 1 4 6 13 48.5638 15.2209 1 4 7 -13 9.12849 7.93428 1 4 7 -12-5.07838 18.1108 1 4 7 -11 60.0378 13.4907 1 4 7 -10 22.3733 9.22692 1 4 7 -9 26.1102 13.0863 1 4 7 -8 93.3985 15.7764 1 4 7 -7 264.046 34.6703 1 4 7 -6-2.52666 20.2899 1 4 7 -5 196.63 24.8523 1 4 7 -4 110.795 12.0609 1 4 7 -3-6.46714 10.9478 1 4 7 -2 178.746 15.3384 1 4 7 -1 66.3249 6.4439 1 4 7 0-0.03062 8.62336 1 4 7 1 60.6595 5.48859 1 4 7 2 200.08 11.3522 1 4 7 3 2.26288 3.52321 1 4 7 4 119.272 7.57849 1 4 7 5 193.642 10.7801 1 4 7 6 16.4212 5.09984 1 4 7 7 228.77 13.8326 1 4 7 8 123.21 11.5241 1 4 7 9 14.3808 5.41509 1 4 7 10 27.9584 9.60236 1 4 7 11 62.1199 10.2873 1 4 7 12 13.3178 12.1652 1 4 7 13 3.8517 15.9051 1 4 8 -12 22.325 7.54914 1 4 8 -11 8.95993 8.83506 1 4 8 -10 154.057 26.6914 1 4 8 -9 37.244 10.951 1 4 8 -8 29.0209 14.4425 1 4 8 -7-13.8952 24.5378 1 4 8 -6 74.2081 19.0912 1 4 8 -5 24.4529 12.1626 1 4 8 -4 169.986 23.3561 1 4 8 -3 24.0145 11.3215 1 4 8 -2 125.395 29.0154 1 4 8 -1 21.5246 7.53182 1 4 8 0 58.031 7.93395 1 4 8 1 19.6872 5.24944 1 4 8 2 131.938 11.6453 1 4 8 3 24.778 6.60158 1 4 8 4 169.48 11.2786 1 4 8 5 28.1436 4.66347 1 4 8 6 81.4563 6.92844 1 4 8 7-0.54749 11.7257 1 4 8 8 52.2621 6.41989 1 4 8 9 25.8039 10.3944 1 4 8 10 174.486 20.1006 1 4 8 11-5.11265 17.4004 1 4 8 12 16.4093 23.5079 1 4 9 -11 45.872 12.317 1 4 9 -10 84.0973 16.527 1 4 9 -9 12.8805 11.1805 1 4 9 -8 8.95527 13.576 1 4 9 -7 74.1065 21.6446 1 4 9 -6-8.36915 22.1213 1 4 9 -5 4.96608 8.16904 1 4 9 -4-14.0039 25.1728 1 4 9 -3 232.415 25.7125 1 4 9 -2-6.70233 11.7732 1 4 9 -1 19.274 8.08232 1 4 9 0 37.3122 8.98909 1 4 9 1 17.9965 7.70022 1 4 9 2-3.44665 10.5465 1 4 9 3 203.272 14.5116 1 4 9 4 15.3321 5.10836 1 4 9 5 10.0043 4.91555 1 4 9 6 2.82959 10.2903 1 4 9 7 68.3104 8.3733 1 4 9 8 10.8538 5.5442 1 4 9 9 22.9648 8.14763 1 4 9 10 117.423 16.0745 1 4 9 11 43.4059 10.3659 1 4 10 -10 5.37967 10.8152 1 4 10 -9 78.2255 17.4764 1 4 10 -8 7.5489 22.5086 1 4 10 -7 14.651 14.0783 1 4 10 -6 69.5871 17.785 1 4 10 -5 79.3808 24.7882 1 4 10 -4-15.5539 16.6655 1 4 10 -3 20.4193 13.5881 1 4 10 -2 134.96 26.6176 1 4 10 -1 70.0298 15.0207 1 4 10 0 50.2071 26.8538 1 4 10 1 83.7029 25.1598 1 4 10 2 123.884 17.5176 1 4 10 3 32.1646 8.96284 1 4 10 4 7.22988 10.2175 1 4 10 5 112.171 11.9424 1 4 10 6 89.35 9.73731 1 4 10 7 17.9612 7.92471 1 4 10 8 27.2793 14.0351 1 4 10 9 115.489 14.5638 1 4 10 10-6.25579 14.6713 1 4 11 -8 9.83762 19.0428 1 4 11 -7 12.91 14.8765 1 4 11 -6 22.4451 19.0207 1 4 11 -5 13.2658 22.939 1 4 11 -4 25.9224 20.4043 1 4 11 -3-9.52217 27.3645 1 4 11 -2 15.7138 18.1958 1 4 11 -1 71.9709 13.1768 1 4 11 0 17.0201 14.9258 1 4 11 1 62.287 24.5882 1 4 11 2 24.8248 15.4503 1 4 11 3 9.11531 11.7008 1 4 11 4 31.9553 8.81327 1 4 11 5 36.0249 13.9913 1 4 11 6 15.2329 9.92981 1 4 11 7-1.37278 28.2173 1 4 11 8-8.13811 24.9623 1 4 12 -6 34.4045 26.8718 1 4 12 -5 46.1631 33.1648 1 4 12 -4 50.99 16.6739 1 4 12 -3-2.12062 23.2872 1 4 12 -2 75.8014 18.4296 1 4 12 -1 83.6264 22.0488 1 4 12 0 27.4729 17.1716 1 4 12 1 94.1118 20.6387 1 4 12 2 87.5765 15.8723 1 4 12 3 14.8763 50.1147 1 4 12 4 57.1432 17.4118 1 4 12 5 53.4268 19.632 1 4 12 6 34.6513 16.1937 1 4 13 -3-22.9511 24.1261 1 4 13 -2-1.80493 21.5595 1 4 13 -1-13.9826 19.5487 1 4 13 0 11.1271 15.8428 1 4 13 1 0.10775 25.447 1 4 13 2 3.22739 17.9004 1 5 0 1-6.07789 12.2284 1 5 0 2-0.18272 10.2028 1 5 0 3-5.41567 9.07001 1 5 0 4 138.878 30.6879 1 5 0 5 79.4842 15.8618 1 5 0 6 234.588 25.1666 1 5 0 7 55.241 9.61918 1 5 0 8 13.4146 23.2288 1 5 0 9 8.47943 10.2018 1 5 0 10 6.32479 9.07886 1 5 0 11 214.926 36.649 1 5 1 -11 62.6777 16.4468 1 5 1 -10 71.315 16.722 1 5 1 -9 16.9503 11.5563 1 5 1 -8 40.4211 11.0686 1 5 1 -7 35.0518 17.954 1 5 1 -6 260.562 20.3716 1 5 1 -5 60.2032 7.65933 1 5 1 -4 46.1567 7.13302 1 5 1 -3 28.2601 6.46921 1 5 1 -2 154.256 12.4187 1 5 1 -1 62.871 7.56226 1 5 1 0 93.3949 9.34165 1 5 1 1 52.8508 9.2488 1 5 1 2 133.315 13.3435 1 5 1 3 36.5383 7.19531 1 5 1 4 49.4249 7.32385 1 5 1 5 59.2385 9.14752 1 5 1 6 265.714 28.4455 1 5 1 7 33.7778 8.07043 1 5 1 8 41.9804 10.2059 1 5 1 9 19.7541 12.1734 1 5 1 10 64.591 17.7357 1 5 1 11 53.3334 44.1246 1 5 2 -11-4.20623 18.6487 1 5 2 -10 49.6897 18.9811 1 5 2 -9 6.05833 10.03 1 5 2 -8 91.2089 14.939 1 5 2 -7-2.24545 24.6821 1 5 2 -6 33.5791 9.46463 1 5 2 -5 17.3418 10.9003 1 5 2 -4 30.6463 6.2623 1 5 2 -3 68.4368 8.2506 1 5 2 -2 77.6011 17.3958 1 5 2 -1 43.5578 6.58767 1 5 2 0 61.7119 8.98799 1 5 2 1 31.6282 6.41783 1 5 2 2 63.1632 7.74268 1 5 2 3 82.1636 10.4026 1 5 2 4 31.4836 5.90872 1 5 2 5 2.09282 5.8254 1 5 2 6 43.3103 7.81844 1 5 2 7 10.695 11.6169 1 5 2 8 110.424 12.8278 1 5 2 9 34.4979 8.28843 1 5 2 10 52.5886 8.95701 1 5 2 11 7.63905 14.951 1 5 3 -10-15.0343 17.3243 1 5 3 -9 43.0634 12.8492 1 5 3 -8 152.708 19.647 1 5 3 -7 40.8004 10.619 1 5 3 -6 1.43664 8.17514 1 5 3 -5 11.6439 8.24774 1 5 3 -4 46.5643 9.72813 1 5 3 -3 55.0089 12.8957 1 5 3 -2 63.0309 8.25951 1 5 3 -1 48.6405 7.61627 1 5 3 0-3.50642 9.40673 1 5 3 1 53.4313 8.82533 1 5 3 2 52.256 9.12572 1 5 3 3 60.1423 7.75 1 5 3 4 40.8839 6.64201 1 5 3 5 17.4681 5.14042 1 5 3 6 11.717 6.18454 1 5 3 7 59.2587 8.4032 1 5 3 8 174.452 18.8562 1 5 3 9 57.3093 10.0936 1 5 3 10 10.5549 10.3941 1 5 4 -10 13.873 13.7018 1 5 4 -9 -5.3983 26.5524 1 5 4 -8 22.9753 10.4419 1 5 4 -7 19.2691 8.70805 1 5 4 -6 117.992 16.1048 1 5 4 -5 -2.543 21.0621 1 5 4 -4 -11.334 13.5025 1 5 4 -3 53.2872 9.95006 1 5 4 -2 14.2149 18.0399 1 5 4 -1 166.893 17.6297 1 5 4 0 79.522 10.5326 1 5 4 1 165.467 17.1129 1 5 4 2 13.5658 12.1644 1 5 4 3 56.9623 9.50914 1 5 4 4 10.9082 6.10206 1 5 4 5-0.39338 14.2584 1 5 4 6 141.27 12.307 1 5 4 7 23.7613 8.11351 1 5 4 8 43.6047 7.73185 1 5 4 9 17.0766 6.9923 1 5 4 10 35.3492 10.7203 1 5 5 -9 98.3393 24.634 1 5 5 -8 40.56 10.3062 1 5 5 -7 18.8427 10.104 1 5 5 -6-13.4848 18.8574 1 5 5 -5 3.43787 16.3538 1 5 5 -4 109.793 25.1227 1 5 5 -3 77.4045 36.2323 1 5 5 -2 254.958 64.1772 1 5 5 -1 40.7001 11.1486 1 5 5 0 9.01572 8.70336 1 5 5 1 39.301 13.4427 1 5 5 2 247.369 30.5449 1 5 5 3 93.2507 10.7965 1 5 5 4 141.441 20.0781 1 5 5 5 6.58465 6.83963 1 5 5 6 14.3315 6.16371 1 5 5 7 33.6725 6.65736 1 5 5 8 42.7783 8.31269 1 5 5 9 119.774 17.0487 1 5 6 -9 164.398 37.5797 1 5 6 -8 4.85105 36.9507 1 5 6 -7 34.4156 18.9343 1 5 6 -6 24.2915 19.1555 1 5 6 -5 9.51106 20.0643 1 5 6 -4 91.6218 16.4578 1 5 6 -3 121.924 28.1549 1 5 6 -2 18.7388 10.4572 1 5 6 -1 -0.9405 18.775 1 5 6 0 29.6631 8.65533 1 5 6 1 14.147 6.42967 1 5 6 2 22.1108 10.1093 1 5 6 3 116.139 12.2522 1 5 6 4 116.289 29.758 1 5 6 5 19.0394 10.1938 1 5 6 6 6.47586 15.2521 1 5 6 7 41.2154 8.93551 1 5 6 8 15.5681 6.57718 1 5 6 9 177.889 18.9284 1 5 7 -8 31.7978 25.0295 1 5 7 -7 42.4003 18.8275 1 5 7 -6 31.9159 19.674 1 5 7 -5 33.2085 10.3783 1 5 7 -4 21.4611 13.6236 1 5 7 -3 83.8817 17.3265 1 5 7 -2 94.5754 15.0994 1 5 7 -1 27.5816 16.1922 1 5 7 0 124.639 17.2853 1 5 7 1 35.6474 11.1343 1 5 7 2 101.836 14.0704 1 5 7 3 98.5959 11.6837 1 5 7 4 32.0504 8.09539 1 5 7 5 41.1637 6.98296 1 5 7 6 52.4868 12.7667 1 5 7 7 57.6209 15.8615 1 5 7 8 61.5501 14.6941 1 5 8 -6 12.3885 24.4036 1 5 8 -5 7.71399 12.4962 1 5 8 -4 47.413 13.9822 1 5 8 -3 6.72427 9.98379 1 5 8 -2 36.7888 16.2064 1 5 8 -1 82.9274 18.9525 1 5 8 0 7.73357 23.6866 1 5 8 1 75.58 17.6948 1 5 8 2 48.3702 10.038 1 5 8 3 11.8346 9.90162 1 5 8 4 45.2442 16.164 1 5 8 5 26.0019 11.4435 1 5 8 6 12.1877 12.2412 1 5 9 -3-13.3428 19.9202 1 5 9 -2-7.39075 44.0655 1 5 9 -1-0.82028 20.2634 1 5 9 0-26.8824 18.0279 1 5 9 2 12.2919 11.9371 1 5 9 3 6.59118 10.1217 1 5 9 4 53.2364 18.543 1 6 0 0 0.72076 15.3283 1 6 0 1-8.21924 30.9185 1 6 1 -1 11.1931 12.7234 1 6 1 0 55.4195 16.5892 1 6 1 1 11.2557 11.3371 1 0 0 0 0.00 0.00 1 ; #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' 'x+1/2, -y+1/2, -z' '-x, y+1/2, -z+1/2' loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_calc_flag O1 O 1.2141(5) 0.85846(14) 0.81370(12) 0.0203(7) Uani 1 d O2 O 1.0758(5) 0.71908(15) 0.88635(13) 0.0232(7) Uani 1 d H2O H 1.0174 0.6885 0.9168 0.035 Uiso 1 calc O3 O 1.3270(5) 0.90094(16) 1.02110(13) 0.0304(8) Uani 1 d H3O H 1.2957 0.945 1.0409 0.046 Uiso 1 calc O4 O 1.1709(6) 1.04200(16) 0.97802(13) 0.0331(8) Uani 1 d C1 C 0.8519(8) 0.8670(2) 0.75036(17) 0.0207(10) Uani 1 d H1 H 0.6802 0.8557 0.7598 0.025 Uiso 1 calc C2 C 1.0081(7) 0.8109(2) 0.79456(19) 0.0200(11) Uani 1 d H2 H 1.0653 0.7668 0.763 0.024 Uiso 1 calc C3 C 0.8915(8) 0.7698(2) 0.85786(18) 0.0197(11) Uani 1 d C4 C 0.7935(8) 0.8264(2) 0.91523(18) 0.0227(11) Uani 1 d H4A H 0.7457 0.8777 0.8927 0.027 Uiso 1 calc H4B H 0.6475 0.8015 0.9344 0.027 Uiso 1 calc C5 C 0.9566(8) 0.8470(2) 0.9763(2) 0.0248(11) Uani 1 d H5A H 0.8641 0.8792 1.0103 0.03 Uiso 1 calc H5B H 1.0012 0.7958 0.9997 0.03 Uiso 1 calc C6 C 1.1834(8) 0.8928(2) 0.95978(18) 0.0211(10) Uani 1 d H6 H 1.2755 0.8599 0.9254 0.025 Uiso 1 calc C7 C 1.1432(8) 0.9768(2) 0.92719(18) 0.0224(11) Uani 1 d C8 C 1.2627(8) 0.9942(2) 0.85934(18) 0.0239(11) Uani 1 d H8A H 1.4359 0.9862 0.8654 0.029 Uiso 1 calc H8B H 1.2367 1.0518 0.8477 0.029 Uiso 1 calc C9 C 1.1803(8) 0.9432(2) 0.79788(19) 0.0210(10) Uani 1 d H9 H 1.2791 0.9572 0.7562 0.025 Uiso 1 calc C10 C 0.9181(7) 0.9520(2) 0.7784(2) 0.0203(10) Uani 1 d H10 H 0.8269 0.9608 0.8226 0.024 Uiso 1 calc C11 C 0.8650(8) 1.0218(2) 0.73043(19) 0.0220(10) Uani 1 d C12 C 0.9255(9) 1.0075(2) 0.65553(19) 0.0296(12) Uani 1 d H12A H 1.1004 1.0044 0.6501 0.036 Uiso 1 calc H12B H 0.8671 1.0532 0.6269 0.036 Uiso 1 calc C13 C 0.8135(9) 0.9295(2) 0.63020(19) 0.0296(12) Uani 1 d H13A H 0.8522 0.9215 0.5803 0.036 Uiso 1 calc H13B H 0.6384 0.9333 0.6346 0.036 Uiso 1 calc C14 C 0.9031(8) 0.8570(2) 0.67234(18) 0.0230(10) Uani 1 d H14 H 1.08 0.8566 0.6673 0.028 Uiso 1 calc C15 C 0.8133(8) 0.7753(2) 0.64274(19) 0.0256(11) Uani 1 d H15 H 0.8719 0.732 0.6747 0.031 Uiso 1 calc C16 C 0.5436(8) 0.7688(3) 0.6406(2) 0.0338(12) Uani 1 d H16A H 0.4983 0.7143 0.6255 0.051 Uiso 1 calc H16B H 0.4801 0.8085 0.6076 0.051 Uiso 1 calc H16C H 0.4788 0.7792 0.6872 0.051 Uiso 1 calc C17 C 0.9148(9) 0.7577(3) 0.5708(2) 0.0362(12) Uani 1 d H17A H 0.8536 0.7973 0.5373 0.054 Uiso 1 calc H17B H 0.8677 0.7033 0.5562 0.054 Uiso 1 calc H17C H 1.0887 0.7612 0.5725 0.054 Uiso 1 calc C18 C 0.6910(8) 0.7166(2) 0.83096(19) 0.0246(11) Uani 1 d H18A H 0.6388 0.68 0.8682 0.037 Uiso 1 calc H18B H 0.7476 0.6849 0.7911 0.037 Uiso 1 calc H18C H 0.5573 0.7506 0.8163 0.037 Uiso 1 calc C19 C 0.9396(9) 1.0272(3) 0.9489(2) 0.0316(12) Uani 1 d H19A H 0.8769 1.0669 0.9149 0.038 Uiso 1 calc H19B H 0.8182 1.0023 0.9795 0.038 Uiso 1 calc C20 C 0.7647(8) 1.0892(3) 0.7524(2) 0.0293(11) Uani 1 d H20A H 0.728 1.1309 0.7202 0.035 Uiso 1 calc H20B H 0.729 1.0959 0.8006 0.035 Uiso 1 calc loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 O1 0.0188(17) 0.0191(16) 0.0230(15) 0.0025(12) -0.0029(13) 0.0026(14) O2 0.0232(18) 0.0234(17) 0.0230(15) 0.0066(13) 0.0001(14) 0.0033(15) O3 0.038(2) 0.0320(17) 0.0213(15) -0.0030(12) -0.0090(16) 0.0022(17) O4 0.042(2) 0.0295(17) 0.0277(15) -0.0074(13) -0.0093(17) -0.0001(16) C1 0.022(3) 0.021(2) 0.019(2) 0.0044(19) 0.001(2) 0.000(2) C2 0.018(3) 0.025(2) 0.017(2) -0.0036(19) -0.0043(19) -0.001(2) C3 0.017(3) 0.024(2) 0.018(2) 0.0019(19) -0.003(2) 0.007(2) C4 0.025(3) 0.023(2) 0.020(2) 0.0042(18) 0.002(2) 0.004(2) C5 0.033(3) 0.025(2) 0.016(2) -0.0001(19) -0.001(2) 0.006(2) C6 0.022(3) 0.026(2) 0.015(2) 0.0006(17) -0.004(2) 0.002(2) C7 0.029(3) 0.021(2) 0.017(2) -0.0035(19) -0.002(2) 0.002(2) C8 0.025(3) 0.024(2) 0.024(2) 0.0005(19) -0.004(2) 0.000(2) C9 0.023(3) 0.021(2) 0.018(2) 0.0068(18) 0.001(2) 0.004(2) C10 0.018(3) 0.024(2) 0.019(2) 0.0030(19) 0.0034(19) -0.002(2) C11 0.020(3) 0.024(3) 0.022(2) 0.007(2) -0.001(2) -0.001(2) C12 0.035(3) 0.030(3) 0.024(2) 0.010(2) 0.003(2) 0.002(2) C13 0.034(3) 0.033(3) 0.022(2) 0.004(2) 0.000(2) 0.002(3) C14 0.020(3) 0.031(3) 0.018(2) 0.0030(19) -0.001(2) 0.000(2) C15 0.028(3) 0.026(2) 0.022(2) 0.0020(19) -0.005(2) -0.001(2) C16 0.030(3) 0.041(3) 0.030(3) -0.003(2) -0.002(2) -0.004(3) C17 0.033(3) 0.047(3) 0.029(2) -0.011(2) -0.002(2) 0.000(2) C18 0.027(3) 0.023(2) 0.024(2) 0.0035(19) -0.001(2) -0.003(2) C19 0.037(3) 0.032(3) 0.027(2) -0.001(2) -0.001(2) 0.005(3) C20 0.033(3) 0.029(3) 0.025(2) 0.010(2) -0.001(2) 0.004(2) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle C9 O1 C2 111.7(3) C3 O2 H2O 109.5 C6 O3 H3O 109.5 C19 O4 C7 61.3(3) C14 C1 C2 111.5(3) C14 C1 C10 113.0(3) C2 C1 C10 102.7(3) C14 C1 H1 109.8 C2 C1 H1 109.8 C10 C1 H1 109.8 O1 C2 C1 105.6(3) O1 C2 C3 112.5(3) C1 C2 C3 117.3(3) O1 C2 H2 107 C1 C2 H2 107 C3 C2 H2 107 O2 C3 C18 108.9(3) O2 C3 C2 104.4(3) C18 C3 C2 107.8(3) O2 C3 C4 109.9(3) C18 C3 C4 109.1(3) C2 C3 C4 116.4(3) C5 C4 C3 117.8(3) C5 C4 H4A 107.9 C3 C4 H4A 107.9 C5 C4 H4B 107.9 C3 C4 H4B 107.9 H4A C4 H4B 107.2 C6 C5 C4 117.2(3) C6 C5 H5A 108 C4 C5 H5A 108 C6 C5 H5B 108 C4 C5 H5B 108 H5A C5 H5B 107.2 O3 C6 C5 110.5(3) O3 C6 C7 109.3(3) C5 C6 C7 114.4(3) O3 C6 H6 107.5 C5 C6 H6 107.5 C7 C6 H6 107.5 O4 C7 C19 58.5(2) O4 C7 C8 113.0(3) C19 C7 C8 119.0(3) O4 C7 C6 112.3(3) C19 C7 C6 120.6(4) C8 C7 C6 117.5(3) C7 C8 C9 115.5(3) C7 C8 H8A 108.4 C9 C8 H8A 108.4 C7 C8 H8B 108.4 C9 C8 H8B 108.4 H8A C8 H8B 107.5 O1 C9 C8 109.6(3) O1 C9 C10 105.7(3) C8 C9 C10 115.4(3) O1 C9 H9 108.6 C8 C9 H9 108.6 C10 C9 H9 108.6 C11 C10 C9 114.4(3) C11 C10 C1 115.9(3) C9 C10 C1 103.3(3) C11 C10 H10 107.6 C9 C10 H10 107.6 C1 C10 H10 107.6 C20 C11 C12 122.6(4) C20 C11 C10 122.5(4) C12 C11 C10 114.8(4) C11 C12 C13 110.3(4) C11 C12 H12A 109.6 C13 C12 H12A 109.6 C11 C12 H12B 109.6 C13 C12 H12B 109.6 H12A C12 H12B 108.1 C12 C13 C14 111.2(3) C12 C13 H13A 109.4 C14 C13 H13A 109.4 C12 C13 H13B 109.4 C14 C13 H13B 109.4 H13A C13 H13B 108 C1 C14 C13 111.6(3) C1 C14 C15 113.0(3) C13 C14 C15 112.5(3) C1 C14 H14 106.4 C13 C14 H14 106.4 C15 C14 H14 106.4 C16 C15 C17 109.6(4) C16 C15 C14 113.4(4) C17 C15 C14 112.1(4) C16 C15 H15 107.1 C17 C15 H15 107.1 C14 C15 H15 107.1 C15 C16 H16A 109.5 C15 C16 H16B 109.5 H16A C16 H16B 109.5 C15 C16 H16C 109.5 H16A C16 H16C 109.5 H16B C16 H16C 109.5 C15 C17 H17A 109.5 C15 C17 H17B 109.5 H17A C17 H17B 109.5 C15 C17 H17C 109.5 H17A C17 H17C 109.5 H17B C17 H17C 109.5 C3 C18 H18A 109.5 C3 C18 H18B 109.5 H18A C18 H18B 109.5 C3 C18 H18C 109.5 H18A C18 H18C 109.5 H18B C18 H18C 109.5 O4 C19 C7 60.2(3) O4 C19 H19A 117.7 C7 C19 H19A 117.7 O4 C19 H19B 117.7 C7 C19 H19B 117.7 H19A C19 H19B 114.9 C11 C20 H20A 120 C11 C20 H20B 120 H20A C20 H20B 120 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance O1 C9 1.447(4) O1 C2 1.448(5) O2 C3 1.441(5) O2 H2O 0.84 O3 C6 1.432(5) O3 H3O 0.84 O4 C19 1.436(6) O4 C7 1.462(4) C1 C14 1.531(5) C1 C2 1.534(5) C1 C10 1.551(5) C1 H1 1 C2 C3 1.537(5) C2 H2 1 C3 C18 1.521(6) C3 C4 1.546(5) C4 C5 1.525(5) C4 H4A 0.99 C4 H4B 0.99 C5 C6 1.517(6) C5 H5A 0.99 C5 H5B 0.99 C6 C7 1.540(5) C6 H6 1 C7 C19 1.477(6) C7 C8 1.492(5) C8 C9 1.522(5) C8 H8A 0.99 C8 H8B 0.99 C9 C10 1.528(6) C9 H9 1 C10 C11 1.507(5) C10 H10 1 C11 C20 1.318(5) C11 C12 1.494(5) C12 C13 1.516(6) C12 H12A 0.99 C12 H12B 0.99 C13 C14 1.532(5) C13 H13A 0.99 C13 H13B 0.99 C14 C15 1.551(6) C14 H14 1 C15 C16 1.521(6) C15 C17 1.521(6) C15 H15 1 C16 H16A 0.98 C16 H16B 0.98 C16 H16C 0.98 C17 H17A 0.98 C17 H17B 0.98 C17 H17C 0.98 C18 H18A 0.98 C18 H18B 0.98 C18 H18C 0.98 C19 H19A 0.99 C19 H19B 0.99 C20 H20A 0.95 C20 H20B 0.95 loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion C9 O1 C2 C1 11.6(4) C9 O1 C2 C3 -117.5(3) C14 C1 C2 O1 93.7(3) C10 C1 C2 O1 -27.7(4) C14 C1 C2 C3 -140.1(4) C10 C1 C2 C3 98.5(4) O1 C2 C3 O2 -59.8(4) C1 C2 C3 O2 177.5(3) O1 C2 C3 C18 -175.6(3) C1 C2 C3 C18 61.7(4) O1 C2 C3 C4 61.5(4) C1 C2 C3 C4 -61.2(5) O2 C3 C4 C5 25.3(5) C18 C3 C4 C5 144.7(3) C2 C3 C4 C5 -93.1(4) C3 C4 C5 C6 63.0(5) C4 C5 C6 O3 -174.7(3) C4 C5 C6 C7 61.5(4) C19 O4 C7 C8 111.0(4) C19 O4 C7 C6 -113.2(4) O3 C6 C7 O4 -23.3(5) C5 C6 C7 O4 101.2(4) O3 C6 C7 C19 -88.9(5) C5 C6 C7 C19 35.5(5) O3 C6 C7 C8 110.3(4) C5 C6 C7 C8 -125.2(4) O4 C7 C8 C9 -161.9(3) C19 C7 C8 C9 -96.3(5) C6 C7 C8 C9 64.8(5) C2 O1 C9 C8 134.9(3) C2 O1 C9 C10 9.9(4) C7 C8 C9 O1 -57.6(5) C7 C8 C9 C10 61.5(5) O1 C9 C10 C11 -153.6(3) C8 C9 C10 C11 85.1(4) O1 C9 C10 C1 -26.8(4) C8 C9 C10 C1 -148.1(3) C14 C1 C10 C11 38.7(5) C2 C1 C10 C11 158.9(3) C14 C1 C10 C9 -87.2(4) C2 C1 C10 C9 33.0(4) C9 C10 C11 C20 -104.6(5) C1 C10 C11 C20 135.4(4) C9 C10 C11 C12 77.8(5) C1 C10 C11 C12 -42.2(5) C20 C11 C12 C13 -125.3(4) C10 C11 C12 C13 52.2(5) C11 C12 C13 C14 -60.3(5) C2 C1 C14 C13 -161.3(3) C10 C1 C14 C13 -46.1(5) C2 C1 C14 C15 70.7(4) C10 C1 C14 C15 -174.1(3) C12 C13 C14 C1 58.0(5) C12 C13 C14 C15 -173.8(4) C1 C14 C15 C16 68.6(5) C13 C14 C15 C16 -58.8(5) C1 C14 C15 C17 -166.5(3) C13 C14 C15 C17 66.0(5) C8 C7 C19 O4 -100.6(4) C6 C7 C19 O4 99.0(4)