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Information card for entry 1521287
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| Coordinates | 1521287.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Chemical name | bis[(μ-chloro-carbonylrhodium(I))-μ-carbido-dichlorobistricyclohexylphosphinruthenium(VI)] |
|---|---|
| Formula | C81.47 H144.4 Cl8.53 O3.16 P4 Rh2 Ru2 |
| Calculated formula | C81.468 H144.404 Cl8.532 O3.156 P4 Rh2 Ru2 |
| Title of publication | Carbide complexes as π-acceptor ligands |
| Authors of publication | Reinholdt, Anders; Vibenholt, Johan E.; Morsing, Thorbjørn J.; Schau-Magnussen, Magnus; Reeler, Nini E. A.; Bendix, Jesper |
| Journal of publication | Chem. Sci. |
| Year of publication | 2015 |
| Journal volume | 6 |
| Journal issue | 10 |
| Pages of publication | 5815 |
| a | 32.65 ± 0.02 Å |
| b | 13.4 ± 0.02 Å |
| c | 23.89 ± 0.02 Å |
| α | 90° |
| β | 109.79 ± 0.02° |
| γ | 90° |
| Cell volume | 9835 ± 18 Å3 |
| Cell temperature | 123 ± 2 K |
| Ambient diffraction temperature | 123 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0668 |
| Residual factor for significantly intense reflections | 0.0471 |
| Weighted residual factors for significantly intense reflections | 0.1313 |
| Weighted residual factors for all reflections included in the refinement | 0.1474 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.193 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 176429 (current) | 2016-02-13 | cif/ (antanas@kurmis) Replacing _cod_chemical_formula_sum_orig tag with _cod_original_formula_sum tag in multiple entries since the replaced tag is deprecated according to the COD CIF dictionary. |
1521287.cif |
| 176428 | 2016-02-13 | Replaced deprecated COD CIF data names with their more modern alternatives. The _cod_cif_authors_sg_Hall and _cod_cif_authors_sg_H-M data items were renamed to _cod_original_sg_symbol_Hall and _cod_cif_authors_sg_H-M respectively. |
1521287.cif |
| 170949 | 2015-12-09 | cif/ Updating files of 1521279, 1521280, 1521281, 1521282, 1521283, 1521284, 1521285, 1521286, 1521287, 1521288, 1521289, 1521290 Original log message: Adding full bibliography for 1521279--1521290.cif. |
1521287.cif |
| 141002 | 2015-07-08 | cif/ Adding structures of 1521279, 1521280, 1521281, 1521282, 1521283, 1521284, 1521285, 1521286, 1521287, 1521288, 1521289, 1521290 via cif-deposit CGI script. |
1521287.cif |
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Users of the data should acknowledge the original authors of the
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