#------------------------------------------------------------------------------
#$Date: 2019-11-17 07:20:13 +0200 (Sun, 17 Nov 2019) $
#$Revision: 228632 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/54/94/1549464.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1549464
loop_
_publ_author_name
'Salvati, Anna E.'
'Law, James A.'
'Liriano, Josue'
'Frederich, James H.'
_publ_section_title
;
 Modular access to functionalized 5-8-5 fused ring systems <i>via</i> a
 photoinduced cycloisomerization reaction.
;
_journal_issue                   24
_journal_name_full               'Chemical science'
_journal_page_first              5389
_journal_page_last               5393
_journal_paper_doi               10.1039/c8sc00999f
_journal_volume                  9
_journal_year                    2018
_chemical_absolute_configuration unk
_chemical_formula_moiety         'C15 H20 O2'
_chemical_formula_sum            'C15 H20 O2'
_chemical_formula_weight         232.31
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-01-11 deposited with the CCDC.
2018-05-23 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.3761(13)
_cell_length_b                   10.8200(14)
_cell_length_c                   10.8988(14)
_cell_measurement_reflns_used    5280
_cell_measurement_temperature    103(2)
_cell_measurement_theta_max      28.04
_cell_measurement_theta_min      2.65
_cell_volume                     1223.6(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      103(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0332
_diffrn_reflns_av_unetI/netI     0.0259
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            14255
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.205
_diffrn_reflns_theta_min         2.653
_exptl_absorpt_coefficient_mu    0.082
_exptl_absorpt_correction_T_max  0.9918
_exptl_absorpt_correction_T_min  0.8656
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.261
_exptl_crystal_description       irregular
_exptl_crystal_F_000             504
_exptl_crystal_size_max          0.164
_exptl_crystal_size_mid          0.144
_exptl_crystal_size_min          0.064
_exptl_transmission_factor_max   0.9918
_exptl_transmission_factor_min   0.8656
_refine_diff_density_max         0.257
_refine_diff_density_min         -0.166
_refine_diff_density_rms         0.036
_refine_ls_abs_structure_details unk
_refine_ls_abs_structure_Flack   0.4(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     155
_refine_ls_number_reflns         3004
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0369
_refine_ls_R_factor_gt           0.0329
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0433P)^2^+0.2141P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0802
_refine_ls_wR_factor_ref         0.0827
_reflns_Friedel_coverage         0.730
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.989
_reflns_number_gt                2789
_reflns_number_total             3004
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8sc00999f2.cif
_cod_data_source_block           fred15
_cod_depositor_comments
'Adding full bibliography for 1549457--1549464.cif.'
_cod_database_code               1549464
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.987
_shelx_estimated_absorpt_t_max   0.995
_shelx_res_file
; 
  
    fred15.res created by SHELXL-2014/7 
  
  
TITL fred15a in P2(1)2(1)2(1) 
CELL 0.71073  10.37610  10.82000  10.89880  90.0000  90.0000  90.0000 
ZERR    4.00   0.00130   0.00140   0.00140   0.0000   0.0000   0.0000 
LATT -1 
SYMM 0.5-X, -Y, 0.5+Z 
SYMM -X, 0.5+Y, 0.5-Z 
SYMM 0.5+X, 0.5-Y, -Z 
SFAC C  H  O 
UNIT 60  80  8 
L.S. 10 
ACTA 
BOND $H 
FMAP 2 
PLAN 10 
SIZE 0.064 0.144 0.164 
CONF 
MERG 2 
TEMP -170.000 
WGHT    0.043300    0.214100 
FVAR       0.85254 
MOLE 1 
C1    1    0.131838    1.044321   -0.046970    11.00000    0.01663    0.01727 = 
         0.01960    0.00273   -0.00258   -0.00375 
AFIX  13 
H1    2    0.164746    0.999651   -0.120932    11.00000   -1.20000 
AFIX   0 
C2    1    0.200912    1.170066   -0.041460    11.00000    0.02230    0.01966 = 
         0.03933    0.00871   -0.00675   -0.00662 
AFIX  23 
H2A   2    0.149891    1.230216    0.006767    11.00000   -1.20000 
H2B   2    0.214184    1.203597   -0.125026    11.00000   -1.20000 
AFIX   0 
C3    1    0.332124    1.144035    0.021739    11.00000    0.01887    0.01865 = 
         0.02644   -0.00096    0.00114   -0.00519 
AFIX  23 
H3A   2    0.404314    1.161960   -0.034927    11.00000   -1.20000 
H3B   2    0.342019    1.195806    0.096041    11.00000   -1.20000 
AFIX   0 
C4    1    0.330189    1.005438    0.056206    11.00000    0.01476    0.01882 = 
         0.02613   -0.00045   -0.00114   -0.00113 
AFIX  23 
H4A   2    0.370812    0.954373   -0.008488    11.00000   -1.20000 
H4B   2    0.374862    0.990551    0.135098    11.00000   -1.20000 
AFIX   0 
C5    1    0.186289    0.978469    0.066582    11.00000    0.01534    0.01375 = 
         0.01910    0.00069   -0.00148   -0.00079 
C6    1    0.124561    1.023572    0.183465    11.00000    0.01829    0.02351 = 
         0.01914   -0.00373   -0.00370    0.00076 
AFIX  43 
H6    2    0.144275    1.098894    0.224133    11.00000   -1.20000 
AFIX   0 
C7    1    0.038457    0.941318    0.220316    11.00000    0.01923    0.03147 = 
         0.01450    0.00051   -0.00159    0.00096 
AFIX  43 
H7    2   -0.014580    0.948875    0.290969    11.00000   -1.20000 
AFIX   0 
C8    1    0.037866    0.833626    0.132335    11.00000    0.01407    0.01880 = 
         0.02154    0.00514    0.00000    0.00081 
AFIX  13 
H8    2    0.040462    0.754470    0.179633    11.00000   -1.20000 
AFIX   0 
C9    1   -0.079819    0.832880    0.045010    11.00000    0.01495    0.01472 = 
         0.01892    0.00003    0.00139   -0.00012 
AFIX  13 
H9    2   -0.085927    0.746744    0.012264    11.00000   -1.20000 
AFIX   0 
C10   1   -0.083189    0.919839   -0.069588    11.00000    0.01400    0.01830 = 
         0.01815    0.00212   -0.00194   -0.00229 
C11   1   -0.015119    1.046829   -0.055598    11.00000    0.01674    0.01662 = 
         0.02197    0.00535   -0.00359   -0.00077 
AFIX  23 
H11A  2   -0.039407    1.099010   -0.126541    11.00000   -1.20000 
H11B  2   -0.049055    1.087489    0.019087    11.00000   -1.20000 
AFIX   0 
C12   1   -0.032249    0.851430   -0.182548    11.00000    0.02245    0.03022 = 
         0.01915   -0.00267   -0.00113   -0.00425 
AFIX 137 
H12A  2   -0.042811    0.903670   -0.255311    11.00000   -1.50000 
H12B  2   -0.080612    0.774437   -0.193625    11.00000   -1.50000 
H12C  2    0.059291    0.832385   -0.171029    11.00000   -1.50000 
AFIX   0 
C13   1   -0.230594    0.943527   -0.084590    11.00000    0.01585    0.02471 = 
         0.02897    0.00747   -0.00611   -0.00283 
AFIX  23 
H13A  2   -0.245905    1.023621   -0.126014    11.00000   -1.20000 
H13B  2   -0.270596    0.877110   -0.134118    11.00000   -1.20000 
AFIX   0 
C14   1   -0.287482    0.945081    0.044824    11.00000    0.01705    0.02524 = 
         0.03698    0.00503    0.00253    0.00273 
AFIX  23 
H14A  2   -0.282635    1.028879    0.081004    11.00000   -1.20000 
H14B  2   -0.378536    0.917754    0.044110    11.00000   -1.20000 
AFIX   0 
C15   1   -0.204149    0.855201    0.115308    11.00000    0.01610    0.01719 = 
         0.02230   -0.00138    0.00071   -0.00354 
O1    3   -0.230279    0.808708    0.213613    11.00000    0.02288    0.02815 = 
         0.02417    0.00241    0.00497   -0.00546 
O2    3    0.156150    0.848327    0.065367    11.00000    0.01427    0.01349 = 
         0.02720    0.00177    0.00220    0.00053 
HKLF 4 
  
REM  fred15a in P2(1)2(1)2(1) 
REM R1 =  0.0329 for    2789 Fo > 4sig(Fo)  and  0.0369 for all    3004 data 
REM    155 parameters refined using      0 restraints 
  
END 
  
WGHT      0.0433      0.2142 
  
REM Highest difference peak  0.257,  deepest hole -0.166,  1-sigma level  0.036 
Q1    1  -0.2495  0.8982  0.0799  11.00000  0.05    0.26 
Q2    1  -0.0442  0.9798 -0.0626  11.00000  0.05    0.24 
Q3    1  -0.0751  0.8756 -0.0115  11.00000  0.05    0.24 
Q4    1   0.1595  1.0039  0.0022  11.00000  0.05    0.23 
Q5    1   0.3347  1.0762  0.0476  11.00000  0.05    0.22 
Q6    1  -0.1596  0.9300 -0.0741  11.00000  0.05    0.21 
Q7    1   0.1657  1.1080 -0.0384  11.00000  0.05    0.20 
Q8    1   0.1563  1.0128  0.1187  11.00000  0.05    0.19 
Q9    1   0.0609  1.0455 -0.0448  11.00000  0.05    0.19 
Q10   1   0.2600  0.9820  0.0628  11.00000  0.05    0.18 
;
_shelx_res_checksum              6051
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 0.13184(15) 1.04432(14) -0.04697(15) 0.0178(3) Uani 1 1 d . .
H1 H 0.1647 0.9997 -0.1209 0.021 Uiso 1 1 calc R U
C2 C 0.20091(17) 1.17007(16) -0.0415(2) 0.0271(4) Uani 1 1 d . .
H2A H 0.1499 1.2302 0.0068 0.033 Uiso 1 1 calc R U
H2B H 0.2142 1.2036 -0.1250 0.033 Uiso 1 1 calc R U
C3 C 0.33212(16) 1.14404(15) 0.02174(17) 0.0213(3) Uani 1 1 d . .
H3A H 0.4043 1.1620 -0.0349 0.026 Uiso 1 1 calc R U
H3B H 0.3420 1.1958 0.0960 0.026 Uiso 1 1 calc R U
C4 C 0.33019(16) 1.00544(14) 0.05621(17) 0.0199(3) Uani 1 1 d . .
H4A H 0.3708 0.9544 -0.0085 0.024 Uiso 1 1 calc R U
H4B H 0.3749 0.9906 0.1351 0.024 Uiso 1 1 calc R U
C5 C 0.18629(15) 0.97847(13) 0.06658(16) 0.0161(3) Uani 1 1 d . .
C6 C 0.12456(16) 1.02357(16) 0.18347(16) 0.0203(3) Uani 1 1 d . .
H6 H 0.1443 1.0989 0.2241 0.024 Uiso 1 1 calc R U
C7 C 0.03846(17) 0.94132(17) 0.22032(15) 0.0217(3) Uani 1 1 d . .
H7 H -0.0146 0.9489 0.2910 0.026 Uiso 1 1 calc R U
C8 C 0.03787(15) 0.83363(15) 0.13234(15) 0.0181(3) Uani 1 1 d . .
H8 H 0.0405 0.7545 0.1796 0.022 Uiso 1 1 calc R U
C9 C -0.07982(15) 0.83288(14) 0.04501(14) 0.0162(3) Uani 1 1 d . .
H9 H -0.0859 0.7467 0.0123 0.019 Uiso 1 1 calc R U
C10 C -0.08319(15) 0.91984(14) -0.06959(15) 0.0168(3) Uani 1 1 d . .
C11 C -0.01512(15) 1.04683(15) -0.05560(16) 0.0184(3) Uani 1 1 d . .
H11A H -0.0394 1.0990 -0.1265 0.022 Uiso 1 1 calc R U
H11B H -0.0491 1.0875 0.0191 0.022 Uiso 1 1 calc R U
C12 C -0.03225(18) 0.85143(18) -0.18255(16) 0.0239(4) Uani 1 1 d . .
H12A H -0.0428 0.9037 -0.2553 0.036 Uiso 1 1 calc R U
H12B H -0.0806 0.7744 -0.1936 0.036 Uiso 1 1 calc R U
H12C H 0.0593 0.8324 -0.1710 0.036 Uiso 1 1 calc R U
C13 C -0.23059(16) 0.94353(16) -0.08459(17) 0.0232(4) Uani 1 1 d . .
H13A H -0.2459 1.0236 -0.1260 0.028 Uiso 1 1 calc R U
H13B H -0.2706 0.8771 -0.1341 0.028 Uiso 1 1 calc R U
C14 C -0.28748(17) 0.94508(17) 0.04482(19) 0.0264(4) Uani 1 1 d . .
H14A H -0.2826 1.0289 0.0810 0.032 Uiso 1 1 calc R U
H14B H -0.3785 0.9178 0.0441 0.032 Uiso 1 1 calc R U
C15 C -0.20415(15) 0.85520(15) 0.11531(16) 0.0185(3) Uani 1 1 d . .
O1 O -0.23028(12) 0.80871(12) 0.21361(12) 0.0251(3) Uani 1 1 d . .
O2 O 0.15615(10) 0.84833(9) 0.06537(11) 0.0183(2) Uani 1 1 d . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
C1 0.0166(7) 0.0173(7) 0.0196(8) 0.0027(6) -0.0026(6) -0.0038(6)
C2 0.0223(8) 0.0197(8) 0.0393(11) 0.0087(7) -0.0068(8) -0.0066(7)
C3 0.0189(8) 0.0186(7) 0.0264(9) -0.0010(7) 0.0011(7) -0.0052(7)
C4 0.0148(7) 0.0188(7) 0.0261(8) -0.0004(7) -0.0011(7) -0.0011(6)
C5 0.0153(7) 0.0138(6) 0.0191(7) 0.0007(6) -0.0015(6) -0.0008(5)
C6 0.0183(8) 0.0235(8) 0.0191(8) -0.0037(6) -0.0037(6) 0.0008(6)
C7 0.0192(8) 0.0315(9) 0.0145(8) 0.0005(7) -0.0016(6) 0.0010(7)
C8 0.0141(7) 0.0188(7) 0.0215(8) 0.0051(6) 0.0000(6) 0.0008(6)
C9 0.0149(7) 0.0147(7) 0.0189(8) 0.0000(6) 0.0014(6) -0.0001(6)
C10 0.0140(7) 0.0183(7) 0.0181(7) 0.0021(6) -0.0019(6) -0.0023(6)
C11 0.0167(7) 0.0166(7) 0.0220(8) 0.0053(7) -0.0036(6) -0.0008(6)
C12 0.0224(8) 0.0302(9) 0.0191(8) -0.0027(7) -0.0011(7) -0.0042(8)
C13 0.0158(8) 0.0247(8) 0.0290(9) 0.0075(7) -0.0061(7) -0.0028(6)
C14 0.0170(8) 0.0252(8) 0.0370(11) 0.0050(8) 0.0025(7) 0.0027(7)
C15 0.0161(7) 0.0172(7) 0.0223(8) -0.0014(6) 0.0007(6) -0.0035(6)
O1 0.0229(6) 0.0282(6) 0.0242(6) 0.0024(5) 0.0050(5) -0.0055(5)
O2 0.0143(5) 0.0135(5) 0.0272(6) 0.0018(5) 0.0022(5) 0.0005(4)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C11 C1 C5 115.15(14)
C11 C1 C2 116.84(14)
C5 C1 C2 101.97(13)
C11 C1 H1 107.4
C5 C1 H1 107.4
C2 C1 H1 107.4
C1 C2 C3 105.40(13)
C1 C2 H2A 110.7
C3 C2 H2A 110.7
C1 C2 H2B 110.7
C3 C2 H2B 110.7
H2A C2 H2B 108.8
C4 C3 C2 105.82(13)
C4 C3 H3A 110.6
C2 C3 H3A 110.6
C4 C3 H3B 110.6
C2 C3 H3B 110.6
H3A C3 H3B 108.7
C5 C4 C3 102.49(13)
C5 C4 H4A 111.3
C3 C4 H4A 111.3
C5 C4 H4B 111.3
C3 C4 H4B 111.3
H4A C4 H4B 109.2
O2 C5 C6 103.40(13)
O2 C5 C4 113.47(12)
C6 C5 C4 114.63(14)
O2 C5 C1 111.45(13)
C6 C5 C1 112.00(13)
C4 C5 C1 102.22(13)
C7 C6 C5 109.01(15)
C7 C6 H6 125.5
C5 C6 H6 125.5
C6 C7 C8 109.22(15)
C6 C7 H7 125.4
C8 C7 H7 125.4
O2 C8 C7 103.52(13)
O2 C8 C9 111.23(13)
C7 C8 C9 113.44(13)
O2 C8 H8 109.5
C7 C8 H8 109.5
C9 C8 H8 109.5
C15 C9 C8 111.03(13)
C15 C9 C10 106.74(13)
C8 C9 C10 120.36(13)
C15 C9 H9 105.9
C8 C9 H9 105.9
C10 C9 H9 105.9
C12 C10 C11 110.48(13)
C12 C10 C13 109.50(14)
C11 C10 C13 108.12(13)
C12 C10 C9 110.10(13)
C11 C10 C9 116.35(13)
C13 C10 C9 101.80(13)
C1 C11 C10 116.38(13)
C1 C11 H11A 108.2
C10 C11 H11A 108.2
C1 C11 H11B 108.2
C10 C11 H11B 108.2
H11A C11 H11B 107.3
C10 C12 H12A 109.5
C10 C12 H12B 109.5
H12A C12 H12B 109.5
C10 C12 H12C 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
C14 C13 C10 106.48(14)
C14 C13 H13A 110.4
C10 C13 H13A 110.4
C14 C13 H13B 110.4
C10 C13 H13B 110.4
H13A C13 H13B 108.6
C15 C14 C13 103.94(14)
C15 C14 H14A 111.0
C13 C14 H14A 111.0
C15 C14 H14B 111.0
C13 C14 H14B 111.0
H14A C14 H14B 109.0
O1 C15 C14 125.97(15)
O1 C15 C9 124.65(15)
C14 C15 C9 109.37(14)
C8 O2 C5 106.77(11)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 C11 1.528(2)
C1 C5 1.536(2)
C1 C2 1.539(2)
C1 H1 1.0000
C2 C3 1.552(2)
C2 H2A 0.9900
C2 H2B 0.9900
C3 C4 1.546(2)
C3 H3A 0.9900
C3 H3B 0.9900
C4 C5 1.526(2)
C4 H4A 0.9900
C4 H4B 0.9900
C5 O2 1.4425(18)
C5 C6 1.507(2)
C6 C7 1.323(3)
C6 H6 0.9500
C7 C8 1.509(2)
C7 H7 0.9500
C8 O2 1.437(2)
C8 C9 1.548(2)
C8 H8 1.0000
C9 C15 1.520(2)
C9 C10 1.564(2)
C9 H9 1.0000
C10 C12 1.531(2)
C10 C11 1.552(2)
C10 C13 1.559(2)
C11 H11A 0.9900
C11 H11B 0.9900
C12 H12A 0.9800
C12 H12B 0.9800
C12 H12C 0.9800
C13 C14 1.529(3)
C13 H13A 0.9900
C13 H13B 0.9900
C14 C15 1.511(2)
C14 H14A 0.9900
C14 H14B 0.9900
C15 O1 1.214(2)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C11 C1 C2 C3 156.08(15)
C5 C1 C2 C3 29.63(18)
C1 C2 C3 C4 -2.90(19)
C2 C3 C4 C5 -25.18(18)
C3 C4 C5 O2 164.10(14)
C3 C4 C5 C6 -77.42(17)
C3 C4 C5 C1 43.97(16)
C11 C1 C5 O2 65.08(18)
C2 C1 C5 O2 -167.38(13)
C11 C1 C5 C6 -50.22(18)
C2 C1 C5 C6 77.32(16)
C11 C1 C5 C4 -173.40(14)
C2 C1 C5 C4 -45.86(16)
O2 C5 C6 C7 -17.85(17)
C4 C5 C6 C7 -141.87(15)
C1 C5 C6 C7 102.26(16)
C5 C6 C7 C8 1.14(19)
C6 C7 C8 O2 16.07(18)
C6 C7 C8 C9 -104.60(17)
O2 C8 C9 C15 -163.38(12)
C7 C8 C9 C15 -47.16(17)
O2 C8 C9 C10 -37.74(19)
C7 C8 C9 C10 78.48(19)
C15 C9 C10 C12 -138.79(13)
C8 C9 C10 C12 93.60(17)
C15 C9 C10 C11 94.56(15)
C8 C9 C10 C11 -33.1(2)
C15 C9 C10 C13 -22.71(16)
C8 C9 C10 C13 -150.32(14)
C5 C1 C11 C10 -64.2(2)
C2 C1 C11 C10 176.18(14)
C12 C10 C11 C1 -56.83(19)
C13 C10 C11 C1 -176.65(15)
C9 C10 C11 C1 69.64(19)
C12 C10 C13 C14 150.39(15)
C11 C10 C13 C14 -89.19(16)
C9 C10 C13 C14 33.87(17)
C10 C13 C14 C15 -32.07(18)
C13 C14 C15 O1 -163.73(16)
C13 C14 C15 C9 17.25(18)
C8 C9 C15 O1 -42.3(2)
C10 C9 C15 O1 -175.20(15)
C8 C9 C15 C14 136.76(14)
C10 C9 C15 C14 3.84(17)
C7 C8 O2 C5 -27.20(15)
C9 C8 O2 C5 94.96(14)
C6 C5 O2 C8 27.86(15)
C4 C5 O2 C8 152.63(14)
C1 C5 O2 C8 -92.63(15)