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Information card for entry 1565347
Preview
| Coordinates | 1565347.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C58 H42 Cl18 O12 P2 Pt12 Sn10 |
|---|---|
| Calculated formula | C58 H42 Cl18 O12 P2 Pt12 Sn10 |
| SMILES | C(#[O])[Pt]12345[Pt]6789%10%11%12%13[Pt]%14%15%16%17%18%19%20%21[Pt]%22%2317(C#[O])[Sn]%14([OH][Sn]4(Cl)Cl)(Cl)(Cl)[Pt]5%11%17%22(C#[O])[Sn]1%20(Cl)[Pt]45%13([Pt]76(C#[O])(C#[O])[Pt]6%11%13%14%17%10%154[Pt]4%10%15(C#[O])([Pt]%20%166(C#[O])([Pt]%181%134(C#[O])[Sn]%21%20([OH][Sn]%15(Cl)Cl)(Cl)Cl)[Sn]%19%23(Cl)[Pt]%127%11([Sn]28(Cl)Cl)(C#[O])[Sn]%17%10(Cl)Cl)[Sn]5%14(Cl)Cl)([Sn]39(Cl)Cl)C#[O].[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1 |
| Title of publication | Reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, Br) with Acids: Syntheses and molecular structures of [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– And [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– Platinum carbonyl clusters decorated by Sn(II)-Fragments |
| Authors of publication | Berti, Beatrice; Bortoluzzi, Marco; Cesari, Cristiana; Femoni, Cristina; Iapalucci, Maria Carmela; Zacchini, Stefano |
| Journal of publication | Inorganica Chimica Acta |
| Year of publication | 2020 |
| Journal volume | 503 |
| Pages of publication | 119432 |
| a | 17.2741 ± 0.0005 Å |
| b | 20.8585 ± 0.0005 Å |
| c | 27.3924 ± 0.0008 Å |
| α | 90° |
| β | 95.259 ± 0.002° |
| γ | 90° |
| Cell volume | 9828.3 ± 0.5 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0482 |
| Residual factor for significantly intense reflections | 0.0398 |
| Weighted residual factors for significantly intense reflections | 0.1102 |
| Weighted residual factors for all reflections included in the refinement | 0.1173 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.036 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 270824 (current) | 2021-11-23 | cif/ Adding structures of 1565347, 1565348, 1565349, 1565350, 1565351 via cif-deposit CGI script. |
1565347.cif |
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Users of the data should acknowledge the original authors of the
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