data_2000783
_journal_name_full  'Acta Cryst.'
_journal_year  1992
_journal_volume  C48
_journal_page_first  1311
_journal_page_last  1312
loop_
_publ_author_name
 'Tortorelli, L.J.'
 'Woods, C.'
 'Campana, C.F.'
_chemical_formula_moiety  'C65 H69 N4 P4 Rh2,2(F6 P1)'
_chemical_formula_sum  'C65 H69 F12 N4 P10 Rh2'
_chemical_formula_weight  1525.9
_symmetry_cell_setting  tetragonal
_symmetry_space_group_name_H-M  'I -42d'
_symmetry_space_group_name_Hall  'I -4 2bw'
_cell_length_a  21.817(3)
_cell_length_b  30.658(5)
_cell_length_c  30.658(5)
_cell_angle_alpha  90.
_cell_angle_beta  90.
_cell_angle_gamma  120
_cell_volume  14592(5)
_cell_formula_units_Z  8
_exptl_crystal_density_diffrn  1.389
_exptl_crystal_density_meas  ?
_exptl_crystal_F_000  6200
_exptl_absorpt_coefficient_mu  6.4
_diffrn_radiation_type  Mo
_diffrn_radiation_wavelength  0.71073
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
 Rh .25000(10)
    .18770(10)
       .11220(10)
          .0300(10)
 N(1) .1610(3) .2206(3) .1182(2) .032(2)
 C(1) .1028(4) .2021(4) .1126(3) .044(4)
 C(2) .0864(5) .1406(5) .0953(3) .056(4)
 C(3) .0655(6) .2500 .1250 .053(5)
 C(4) .3336(5) .1617(4) .1060(3) .039(3)
 N(2) .3843(4) .1480(4) .0996(3) .047(3)
 C(5) .4456(4) .1255(5) .0891(4) .054(4)
 C(6) .4623(4) .0750(5) .1198(4) .072(5)
 C(7) .4901(5) .1776(5) .0923(5) .097(6)
 C(8) .4427(6) .1027(6) .0422(4) .082(5)
 P(1) .23310(10)
      .35150(10)
         .06700(10)
         .0340(10)
 C(9) .1745(4) .4107(4) .0703(3) .030(3)
 C(10) .1212(5) .4102(5) .0457(3) .048(4)
 C(11) .0791(5) .4568(6) .0507(4) .065(5)
 C(12) .0894(6) .5048(6) .0790(4) .066(5)
 C(13) .1432(5) .5060(6) .1028(3) .063(4)
 C(14) .1857(5) .4593(4) .0989(3) .045(4)
 C(15) .2910(5) .3891(4) .0333(3) .045(4)
 C(16) .3343(5) .4268(5) .0535(4) .053(4)
 C(17) .3779(6) .4553(6) .0289(6) .084(6)
 C(18) .3793(7) .4514(6) -.0151(6) .092(7)
 C(19) .3362(7) .4141(6) -.0364(5) .082(6)
 C(20) .2924(5) .3852(5) -.0119(4) .058(4)
 C(21) .1998(4) .2901(4) .0342(3) .037(3)
 P(2) .24390(10)
      .21890(10)
         .04080(10)
         .0350(10)
 C(22) .3122(5) .2320(4) .0088(3) .050(4)
 C(23) .3627(5) .2599(5) .0277(4) .053(4)
 C(24) .4129(6) .2749(5) .0017(5) .075(5)
 C(25) .4140(7) .2647(6) -.0419(5) .091(7)
 C(26) .3637(8) .2375(7) -.0604(4) .101(7)
 C(27) .3123(6) .2201(5) -.0361(3) .069(5)
 C(28) .2010(5) .1608(4) .0112(3) .045(4)
 C(29) .1495(6) .1728(5) -.0138(3) .065(4)
 C(30) .1168(7) .1261(6) -.0319(4) .093(6)
 C(31) .1367(8) .0670(7) -.0266(5) .116(8)
 C(32) .1892(7) .0528(5) -.0035(5) .106(7)
 C(33) .2199(6) .1002(5) .0152(4) .072(5)
 P(3) .0633(2) .17190(10)
         .32330(10)
         .0590(10)
 F(1) .0738(4) .2392(3) .3412(2) .104(3)
 F(2) .0526(3) .1054(3) .3060(3) .094(3)
 F(3) .0712(4) .1447(4) .3698(3) .125(4)
 F(4) .0558(4) .1983(3) .2759(2) .101(3)
 F(5) -.0079(3) .1788(4) .3317(3) .109(4)
 F(6) .1338(3) .1655(5) .3140(3) .122(4)
 H(2A) .0426 .1369 .0941 ?
 H(2B) .1027 .1093 .1140 ?
 H(2C) .1030 .1359 .0665 ?
 H(3) .021(6)   .2500 .1250 ?
 H(6A) .5026 .0602 .1130 ?
 H(6B) .4334 .0421 .1169 ?
 H(6C) .4618 .0900 .1492 ?
 H(7A) .5304 .1630 .0854 ?
 H(7B) .4899 .1939 .1214 ?
 H(7C) .4787 .2091 .0721 ?
 H(8A) .4822 .0876 .0338 ?
 H(8B) .4311 .1358 .0233 ?
 H(8C) .4131 .0704 .0400 ?
 H(10A) .1138 .3777 .0252 ?
 H(11A) .0418 .4558 .0340 ?
 H(12A) .0597 .5370 .0821 ?
 H(13A) .1511 .5394 .1223 ?
 H(14A) .2229 .4603 .1156 ?
 H(16A) .3333 .4327 .0845 ?
 H(17A) .4087 .4793 .0434 ?
 H(18A) .4097 .4733 -.0315 ?
 H(19A) .3372 .4095 -.0676 ?
 H(20A) .2617 .3613 -.0265 ?
 H(21A) .1583 .2832 .0434 ?
 H(21B) .2001 .3019 .0040 ?
 H(23A) .3630 .2686 .0584 ?
 H(24A) .4480 .2934 .0153 ?
 H(25A) .4486 .2763 -.0594 ?
 H(26A) .3637 .2299 -.0912 ?
 H(27A) .2780 .2004 -.0498 ?
 H(29A) .1368 .2145 -.0184 ?
 H(30A) .0801 .1346 -.0481 ?
 H(31A) .1133 .0343 -.0394 ?
 H(32A) .2034 .0113 -.0009 ?
 H(33A) .2559 .0914 .0321 ?