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#$Date: 2011-09-17 23:27:16 +0300 (Sat, 17 Sep 2011) $
#$Revision: 26029 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/2000784.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2000784
loop_
_publ_author_name
'Jones, P. G.'
'Th\"one, C.'
_publ_section_title
;
 \m-[Bis(diphenylphosphino)methane]-bis[pentafluorophenylgold(I)] at
 178 K
;
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1312
_journal_page_last               1314
_journal_volume                  48
_journal_year                    1992
_chemical_formula_sum            'C37 H22 Au2 F10 P2'
_chemical_formula_weight         1112.4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 95.85(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.141(4)
_cell_length_b                   20.209(5)
_cell_length_c                   14.207(4)
_cell_volume                     4039
_diffrn_radiation_type           monoclinic
_diffrn_radiation_wavelength     0.71069
_exptl_absorpt_coefficient_mu    7.4
_exptl_crystal_density_diffrn    1.829
_exptl_crystal_F_000             2088
_[local]_cod_data_source_file    ha0092.cif
_[local]_cod_data_source_block   ha0092a
_[local]_cod_cif_authors_sg_H-M  'P 21/c'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Au(1) .56013(3) .20638(2) .72207(3) .0313(2)
C(11) .6881(8) .2561(6) .7408(8) .032(3)
C(12) .6928(9) .3250(6) .7426(8) .031(3)
C(13) .7767(8) .3592(6) .7547(8) .031(3)
C(14) .8624(9) .3242(6) .7625(9) .038(3)
C(15) .8592(10) .2567(7) .7616(9) .042(3)
C(16) .7741(9) .2248(6) .7531(8) .033(3)
F(12) .6123(6) .3615(4) .7317(6) .053(3)
F(13) .7798(6) .4251(4) .7579(6) .063(3)
F(14) .9465(5) .3569(4) .7698(7) .070(4)
F(15) .9419(6) .2219(5) .7707(7) .077(4)
F(16) .7762(6) .1576(4) .7543(6) .061(3)
Au(2) .56419(3) .18212(3) .50258(3) .0306(2)
C(21) .6965(8) .2244(6) .5022(8) .029(3)
C(22) .7112(9) .2912(6) .5108(8) .035(3)
C(23) .8006(9) .3210(6) .5166(9) .036(3)
C(24) .8790(10) .2819(7) .5098(9) .041(3)
C(25) .8669(10) .2153(7) .4972(9) .043(3)
C(26) .7768(8) .1895(6) .4941(8) .030(3)
F(22) .6361(5) .3337(4) .5219(5) .047(3)
F(23) .8113(6) .3872(4) .5252(6) .058(3)
F(24) .9643(5) .3097(4) .5144(7) .065(4)
F(25) .9423(5) .1762(4) .4904(7) .068(4)
F(26) .7701(6) .1225(4) .4831(6) .054(3)
P(1) .4165(2) .1533(2) .7100(2) .0290(10)
C(1) .3973(8) .0941(6) .6119(7) .028(3)
C(112) .3272(5) .2467(4) .4629(6) .037(3)
C(113) .2478 .2860 .4366 .045(3)
C(114) .1602 .2566 .4086 .050(4)
C(115) .1519 .1879 .4068 .057(4)
C(116) .2313 .1485 .4331 .042(3)
C(111) .3189 .1779 .4612 .031(3)
C(122) .4516(5) .0701(3) .3298(5) .037(3)
C(123) .4357 .0242 .2565 .042(3)
C(124) .3815 -.0323 .2687 .039(3)
C(125) .3433 -.0429 .3542 .034(3)
C(126) .3592 .0030 .4275 .036(3)
C(121) .4134 .0595 .4153 .028(3)
P(2) .4220(2) .1286(2) .4980(2) .0275(10)
C(212) .3363(5) .2781(4) .7052(6) .038(3)
C(213) .2620 .3236 .6923 .053(4)
C(214) .1692 .3017 .6679 .057(4)
C(215) .1507 .2342 .6564 .044(3)
C(216) .2250 .1887 .6693 .037(3)
C(211) .3178 .2106 .6937 .034(3)
C(222) .4560(5) .1190(4) .8972(5) .033(3)
C(223) .4425 .0851 .9804 .047(4)
C(224) .3719 .0369 .9801 .052(4)
C(225) .3148 .0225 .8966 .054(4)
C(226) .3284 .0563 .8135 .039(3)
C(221) .3990 .1046 .8138 .028(3)
H(1A) .3328 .0787 .6073 .0327
H(1B) .4381 .0567 .6258 .0327
H(112) .3875 .2669 .4822 .0454
H(113) .2535 .3334 .4378 .0581
H(114) .1056 .2837 .3905 .0598
H(115) .0917 .1676 .3875 .0604
H(116) .2256 .1011 .4319 .0361
H(122) .4889 .1089 .3214 .0446
H(123) .4620 .0315 .1977 .0529
H(124) .3705 -.0638 .2183 .0522
H(125) .3060 -.0817 .3626 .0408
H(126) .3329 -.0043 .4863 .0416
H(212) .4002 .2932 .7220 .0452
H(213) .2747 .3701 .7002 .0624
H(214) .1181 .3331 .6590 .0625
H(215) .0868 .2192 .6396 .0562
H(216) .2123 .1423 .6614 .0437
H(222) .5046 .1522 .8974 .0397
H(223) .4817 .0950 1.0378 .0609
H(224) .3625 .0136 1.0373 .0634
H(225) .2663 -.0107 .8964 .0610
H(226) .2891 .0464 .7560 .0511
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Au(1) C(11) 2.063(12)
Au(1) P(1) 2.288(3)
Au(2) P(2) 2.279(3)
P(1) C(211) 1.811(8)
C(1) P(2) 1.828(11)
C(121) P(2) 1.821(7)
Au(1) Au(2) 3.1630(10)
Au(2) C(21) 2.058(12)
P(1) C(1) 1.834(11)
P(1) C(221) 1.811(8)
C(111) P(2) 1.799(7)
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C11) Au(1) P(1) 176.6(3)
C(21) Au(2) P(2) 175.8(3)
Au(1) P(1) C(1) 115.1(4)
C(1) P(1) C(211) 105.5(4)
C(1) P(1) C(221) 104.0(4)
P(1) C(1) P(2) 113.4(6)
Au(2) P(2) C(111) 115.6(3)
Au(2) P(2) C(121) 112.5(3)
C(111) P(2) C(121) 103.8(4)
C(12) C(11) C(16) 114.8(11)
C(22) C(21) C(26) 113.6(11)
Au(1) P(1) C(211) 112.1(3)
Au(1) P(1) C(221) 112.8(3)
C(211) P(1) C(221) 106.5(4)
Au(2) P(2) C(1) 113.8(4)
C(1) P(2) C(111) 104.2(5)
C(1) P(2) C(121) 105.9(4)
_cod_database_code 2000784