#------------------------------------------------------------------------------
#$Date: 2009-11-18 16:56:34 +0200 (Wed, 18 Nov 2009) $
#$Revision: 858 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/2004077.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2004077
_journal_name_full               'Acta Crystallographica C'
_journal_volume                  51
_journal_year        1995
_journal_page_first     2207
_journal_page_last     2210
_publ_section_title
;
NaM^II^Zr~2~F~11~ (M^II^ = Mn, Fe, Co, Ni, Zn) Fluorides
;
_chemical_formula_sum            'Co F11 Na Zr2'
_[local]_cod_chemical_formula_sum_orig 'Na Co Zr2 F11'
_chemical_formula_weight     473.35
_symmetry_cell_setting    'monoclinic'
_space_group_IT_number           12
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_[local]_cod_cif_authors_sg_H-M  'C 2/m'
loop_
_symmetry_equiv_pos_as_xyz
'x,y,z'
'x,-y,z'
'-x,-y,-z'
'-x,y,-z'
'1/2+x,1/2+y,z'
'1/2+x,1/2-y,z'
'1/2-x,1/2-y,-z'
'1/2-x,1/2+y,-z'
_cell_length_a     9.0370(10)
_cell_length_b     6.7000(10)
_cell_length_c     7.725(2)
_cell_angle_alpha     90
_cell_angle_beta     116.260(10)
_cell_angle_gamma     90
_cell_volume     419.50(10)
_cell_formula_units_Z     2
_exptl_crystal_density_diffrn     3.75
_cell_measurement_temperature     293
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_B_iso_or_equiv
Na .0 .0 .0 3.73(6)
Co .0 .0 .5  .642(6)
Zr  .50490(2) .0  .23574(3)  .541(3)
F(1) .0 .5 .5 3.01(6)
F(2) .0  .3292(3) .0 1.31(2)
F(3)  .2479(2) .0  .6494(3) 1.66(3)
F(4)  .2668(3) .0  .1095(4) 2.43(4)
F(5)  .01540(10)
                .2066(2)  .3124(2) 1.38(2)