#------------------------------------------------------------------------------ #$Date: 2016-04-02 21:36:46 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180792 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/23/2012378.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2012378_Fobs loop_ _publ_author_name 'Rolland, Marc' 'Kassem, Tarek' 'Rolland, Val\'erie' 'Martinez, Jean' _publ_section_title ; Full stereochemical understanding in a new (2R,3R,4R)-4-hydroxyisoleucine synthesis ; _journal_issue 12 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first 1415 _journal_page_last 1417 _journal_volume 57 _journal_year 2001 _space_group_IT_number 19 _symmetry_space_group_name_Hall 'P 2ac 2ab' _symmetry_space_group_name_H-M 'P 21 21 21' _cod_data_source_file gd1165Vsup3.hkl _cod_data_source_block V loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_meas _refln_F_squared_calc _refln_F_squared_sigma 0 0 2 141.8 134.6 7.6 0 0 4 157.4 165.4 5.5 0 0 8 665.8 653.6 21.0 0 0 10 24.2 24.3 1.2 0 0 12 102.1 126.3 4.0 0 0 14 13.1 11.4 1.0 0 1 3 139.5 143.7 3.4 0 1 4 952.2 1050.5 26.2 0 1 7 446.4 451.6 9.3 0 1 8 50.7 50.4 1.2 0 1 9 49.1 51.7 1.3 0 1 10 20.9 19.3 0.7 0 1 11 32.8 27.2 1.1 0 1 12 152.6 154.1 3.6 0 1 14 18.6 19.6 1.1 0 1 15 4.9 2.6 0.8 0 2 2 178.7 201.4 4.5 0 2 3 271.6 303.0 6.7 0 2 4 534.5 582.4 12.4 0 2 5 6.0 8.4 0.4 0 2 7 92.8 92.7 2.1 0 2 8 368.9 353.2 8.3 0 2 10 24.2 26.9 0.9 0 2 11 9.9 9.1 0.7 0 2 12 5.0 4.9 0.6 0 2 13 13.9 16.8 0.8 0 2 15 4.7 2.5 0.8 0 3 2 26.0 18.7 0.6 0 3 3 584.3 586.1 14.7 0 3 4 23.8 25.6 0.7 0 3 5 121.0 104.1 2.5 0 3 6 925.5 939.9 26.4 0 3 7 134.0 135.3 3.0 0 3 8 14.7 14.7 0.6 0 3 9 9.0 12.2 0.5 0 3 10 70.0 61.9 1.8 0 3 11 44.5 48.9 1.5 0 3 12 3.4 3.8 0.7 0 3 13 13.4 16.3 0.8 0 3 14 5.0 2.7 0.8 0 4 1 1097.4 1156.6 27.8 0 4 2 85.1 82.7 1.8 0 4 3 943.1 949.6 19.7 0 4 4 49.4 52.2 1.0 0 4 6 13.6 4.9 0.6 0 4 7 352.8 361.8 8.9 0 4 8 7.0 10.6 0.6 0 4 9 28.2 31.0 0.9 0 4 10 126.6 134.0 3.3 0 4 11 18.5 16.4 1.0 0 4 12 7.8 6.5 0.7 0 4 13 2.0 0.8 0.6 0 4 14 17.1 18.5 1.0 0 4 15 4.0 5.0 0.8 0 5 1 533.8 531.6 11.7 0 5 2 684.1 660.5 13.8 0 5 3 302.6 288.1 5.9 0 5 4 76.1 56.7 1.6 0 5 5 177.7 148.7 3.7 0 5 6 25.6 21.4 0.9 0 5 7 3.3 6.2 0.5 0 5 8 118.4 114.9 3.3 0 5 9 34.3 33.5 1.0 0 5 10 11.4 10.2 0.8 0 5 11 138.9 136.7 4.0 0 5 13 23.4 22.8 1.1 0 5 14 4.2 7.1 0.8 0 6 0 314.1 326.7 8.9 0 6 1 667.7 597.3 13.5 0 6 3 17.0 13.8 0.6 0 6 4 16.0 11.2 0.6 0 6 5 136.1 122.7 3.1 0 6 6 131.8 116.6 3.6 0 6 7 92.9 105.7 2.3 0 6 9 16.0 19.4 0.8 0 6 10 217.5 215.3 5.3 0 6 12 17.5 18.1 1.0 0 6 13 16.3 13.7 1.0 0 6 14 2.6 3.4 0.8 0 7 1 25.0 35.3 0.7 0 7 2 74.7 80.9 1.7 0 7 3 245.2 254.0 5.3 0 7 4 161.8 158.2 3.7 0 7 5 59.2 62.9 1.6 0 7 6 21.9 19.6 0.8 0 7 7 24.0 27.5 0.9 0 7 8 158.3 145.9 3.9 0 7 9 50.0 45.5 1.5 0 7 10 191.8 181.5 4.6 0 7 11 27.3 29.7 1.0 0 7 12 8.2 7.3 0.9 0 7 14 3.0 2.4 0.9 0 8 0 494.6 479.2 15.2 0 8 1 15.9 8.4 0.7 0 8 2 1.7 1.9 0.5 0 8 3 51.6 53.0 1.3 0 8 4 85.3 82.6 2.3 0 8 5 255.5 247.4 6.3 0 8 6 5.3 2.3 0.6 0 8 7 185.6 174.7 4.3 0 8 8 179.2 192.2 4.3 0 8 9 6.3 6.1 0.8 0 8 10 8.5 5.4 0.6 0 8 11 62.0 71.8 1.9 0 8 13 3.2 1.9 0.9 0 9 1 90.5 95.2 1.9 0 9 2 277.1 285.3 5.9 0 9 4 101.8 105.7 2.5 0 9 5 8.0 6.9 0.6 0 9 7 125.5 131.5 3.1 0 9 8 30.9 30.3 1.2 0 9 9 3.7 2.4 0.7 0 9 10 18.7 14.7 1.0 0 9 12 2.8 2.5 0.7 0 10 0 64.9 79.1 2.2 0 10 1 123.7 121.0 2.7 0 10 2 33.1 39.6 1.0 0 10 3 124.3 123.8 2.9 0 10 7 39.2 36.5 1.2 0 10 8 2.6 0.8 0.6 0 10 9 8.9 9.0 0.8 0 10 10 5.1 7.4 0.8 0 10 11 9.2 13.2 1.0 0 11 3 27.3 27.8 1.1 0 11 4 28.8 22.3 1.2 0 11 5 7.9 8.6 0.7 0 11 6 71.7 67.7 2.0 0 11 7 41.1 44.3 1.4 0 11 8 12.2 11.6 0.9 0 11 9 12.2 10.8 0.9 0 11 10 5.1 4.4 0.8 0 12 0 5.0 3.5 1.3 0 12 1 3.3 2.3 0.7 0 12 2 177.8 190.0 4.0 0 12 3 26.0 28.0 1.1 0 12 5 16.4 14.0 0.9 0 12 7 57.2 57.0 1.7 0 12 8 5.3 5.1 1.0 0 12 9 21.7 22.2 1.3 0 13 1 6.0 5.3 0.8 0 13 2 15.2 14.7 0.9 0 13 3 10.0 9.7 0.9 0 13 5 9.7 11.4 1.0 0 14 1 8.9 12.8 1.0 0 14 2 19.8 29.5 1.2 0 14 4 15.9 20.8 1.3 1 0 4 538.9 557.7 15.3 1 0 5 984.7 974.2 21.6 1 0 6 142.3 166.2 4.2 1 0 7 59.6 49.3 1.4 1 0 8 3.2 1.9 0.4 1 0 9 33.4 32.5 1.1 1 0 10 69.8 56.9 1.9 1 0 11 99.3 97.3 4.2 1 0 12 15.6 13.7 0.9 1 0 13 12.5 10.9 0.7 1 0 14 2.5 3.2 0.7 1 1 1 48.7 56.1 1.4 1 1 3 53.3 55.3 1.0 1 1 4 802.8 814.9 13.7 1 1 5 188.2 205.3 2.9 1 1 6 905.2 835.4 26.0 1 1 7 648.9 643.2 10.4 1 1 8 228.4 237.4 3.7 1 1 9 89.0 83.9 1.6 1 1 10 22.9 22.8 0.6 1 1 11 42.5 38.3 0.9 1 1 12 98.1 101.9 1.9 1 1 13 14.3 18.9 0.5 1 1 14 19.2 16.2 0.7 1 1 15 4.1 4.2 0.5 1 2 2 1746.2 2014.5 79.2 1 2 3 333.5 368.8 5.9 1 2 4 266.9 259.7 4.2 1 2 5 839.1 858.5 12.6 1 2 7 173.1 185.9 2.7 1 2 8 24.7 19.0 0.5 1 2 9 91.5 97.8 1.7 1 2 10 32.5 31.6 0.8 1 2 11 15.2 16.6 0.5 1 2 12 52.7 60.4 1.1 1 2 13 12.0 12.7 0.6 1 2 14 15.5 15.2 0.6 1 3 0 15.4 6.8 0.6 1 3 1 273.2 296.4 4.5 1 3 2 269.4 269.4 4.4 1 3 4 199.4 185.3 3.3 1 3 5 43.5 33.1 0.7 1 3 6 114.3 115.7 1.7 1 3 7 231.6 225.4 3.6 1 3 8 63.8 62.6 1.2 1 3 9 28.9 29.2 0.7 1 3 10 26.5 22.4 0.7 1 3 11 50.1 50.8 1.1 1 3 12 42.9 46.9 1.0 1 3 13 22.9 26.4 0.8 1 3 14 3.2 2.4 0.5 1 4 0 184.9 192.0 4.0 1 4 1 556.2 602.3 8.6 1 4 2 1144.0 1197.0 19.0 1 4 3 683.0 681.2 10.3 1 4 4 298.0 284.3 4.3 1 4 5 809.5 771.8 13.4 1 4 6 370.6 376.3 5.7 1 4 7 246.6 250.0 4.5 1 4 8 328.1 309.6 5.4 1 4 9 18.4 21.2 0.5 1 4 10 104.4 112.4 1.9 1 4 11 37.7 38.1 0.9 1 4 12 30.0 31.3 0.8 1 4 13 11.8 14.6 0.6 1 4 14 18.9 21.5 0.7 1 5 0 171.6 197.3 3.6 1 5 1 6.2 14.2 0.3 1 5 3 696.8 667.3 9.7 1 5 4 395.0 380.3 5.7 1 5 5 102.0 102.4 1.6 1 5 6 29.6 23.7 0.6 1 5 7 157.5 150.7 2.5 1 5 8 177.6 175.3 3.4 1 5 9 257.8 233.8 4.1 1 5 10 61.0 65.5 1.3 1 5 11 8.9 8.8 0.5 1 5 12 6.4 5.8 0.5 1 5 13 12.0 10.5 0.6 1 5 14 2.0 1.4 0.6 1 5 15 2.9 3.3 0.6 1 6 0 4.6 9.4 0.4 1 6 2 32.7 29.4 0.6 1 6 3 63.4 57.8 1.0 1 6 4 87.6 87.5 1.4 1 6 5 64.5 63.6 1.1 1 6 6 30.2 28.5 0.6 1 6 7 21.8 27.3 0.6 1 6 8 447.7 448.2 7.3 1 6 9 220.5 215.7 3.9 1 6 10 15.3 21.2 0.6 1 6 11 78.6 82.4 1.4 1 6 12 4.3 3.4 0.5 1 6 13 1.6 0.6 0.5 1 6 14 20.3 20.5 0.7 1 7 0 42.8 30.3 1.1 1 7 1 406.4 397.5 5.7 1 7 2 551.4 561.9 8.0 1 7 3 110.6 92.0 1.8 1 7 4 178.3 176.9 3.0 1 7 5 180.3 177.5 3.2 1 7 6 13.8 16.6 0.5 1 7 7 193.4 199.2 3.2 1 7 8 30.8 29.5 0.8 1 7 10 20.5 22.8 0.7 1 7 11 7.0 9.0 0.5 1 7 12 6.8 8.1 0.5 1 8 0 2.9 1.5 0.5 1 8 1 114.0 113.3 1.8 1 8 2 73.7 78.6 1.2 1 8 3 49.7 50.3 0.9 1 8 4 178.3 172.7 3.0 1 8 5 16.8 15.4 0.5 1 8 6 2.9 1.6 0.5 1 8 7 114.7 113.5 2.1 1 8 8 4.8 4.6 0.4 1 8 9 22.2 23.4 0.7 1 8 10 14.7 14.3 0.7 1 8 12 4.8 4.1 0.5 1 8 13 3.4 3.5 0.6 1 9 0 26.3 25.1 1.0 1 9 1 78.6 73.2 1.3 1 9 2 9.4 10.0 0.5 1 9 3 36.8 38.4 0.8 1 9 4 13.9 16.1 0.5 1 9 5 3.7 5.1 0.4 1 9 6 122.0 123.2 2.2 1 9 7 9.2 11.3 0.6 1 9 9 2.4 2.9 0.6 1 9 10 17.3 19.9 0.7 1 9 11 1.6 1.0 0.5 1 10 0 49.9 53.8 1.7 1 10 1 73.6 75.7 1.3 1 10 2 209.8 197.3 3.4 1 10 3 15.7 15.3 0.6 1 10 4 105.5 105.3 1.9 1 10 5 28.8 29.4 0.8 1 10 7 10.6 10.6 0.6 1 10 8 6.2 7.0 0.5 1 10 10 18.5 20.5 0.7 1 10 11 2.6 2.8 0.6 1 11 0 14.7 17.2 0.8 1 11 1 13.9 9.5 0.6 1 11 2 115.4 116.2 1.9 1 11 3 28.2 28.9 0.8 1 11 4 3.1 3.5 0.4 1 11 5 3.5 3.9 0.5 1 11 6 3.0 2.9 0.5 1 11 7 9.5 10.8 0.6 1 11 8 2.0 2.6 0.5 1 11 9 2.7 2.5 0.5 1 11 10 8.8 10.0 0.6 1 12 0 25.9 31.4 1.1 1 12 1 90.4 91.3 1.6 1 12 2 47.9 49.4 1.0 1 12 3 5.0 8.5 0.6 1 12 4 30.2 32.3 0.9 1 12 5 3.3 3.8 0.5 1 12 6 22.9 25.2 0.8 1 12 7 10.6 9.5 0.8 1 12 8 2.0 0.7 0.6 1 12 9 4.2 3.9 0.8 1 13 0 19.8 19.4 1.1 1 13 2 21.4 22.1 0.7 1 13 3 26.3 24.7 0.8 1 13 4 1.8 2.1 0.5 1 13 5 1.8 3.1 0.6 1 13 6 8.5 9.9 0.6 1 13 7 1.9 3.9 0.6 1 14 0 14.2 18.6 1.0 1 14 3 6.7 10.4 0.6 1 14 4 4.8 3.9 0.8 1 14 5 15.1 21.6 1.2 2 0 3 427.9 449.8 9.7 2 0 4 44.2 34.2 1.0 2 0 5 73.2 87.3 1.5 2 0 6 821.0 810.5 17.1 2 0 7 202.2 182.9 4.8 2 0 8 35.8 33.4 0.9 2 0 9 34.2 23.6 1.1 2 0 11 13.4 14.8 0.8 2 0 12 2.9 3.4 0.7 2 0 13 21.6 24.2 0.9 2 0 14 1.8 2.6 0.6 2 1 0 4.7 6.9 0.2 2 1 5 655.0 666.0 11.1 2 1 6 124.2 131.2 2.0 2 1 7 348.2 337.1 5.2 2 1 8 12.5 10.9 0.5 2 1 9 147.5 132.8 2.6 2 1 10 39.8 33.3 0.8 2 1 11 100.8 102.4 1.9 2 1 12 71.6 67.7 1.3 2 1 13 1.5 2.2 0.4 2 1 14 4.3 4.1 0.5 2 1 15 1.9 1.3 0.5 2 2 2 300.5 317.7 5.4 2 2 3 513.8 548.4 8.3 2 2 4 134.0 133.0 2.1 2 2 5 344.2 333.5 5.1 2 2 6 464.2 430.8 7.0 2 2 7 141.2 133.7 2.2 2 2 8 35.5 37.5 0.7 2 2 9 106.8 107.3 1.9 2 2 10 51.5 54.0 1.1 2 2 11 65.8 59.7 1.3 2 2 12 18.5 19.9 0.7 2 2 13 24.6 26.9 0.7 2 2 14 14.9 13.4 0.7 2 2 15 5.8 7.5 0.7 2 3 0 168.4 173.0 3.8 2 3 3 344.9 341.5 6.0 2 3 4 310.0 295.4 4.6 2 3 5 474.6 494.1 7.0 2 3 6 283.1 253.9 4.2 2 3 7 85.6 81.6 1.5 2 3 8 142.6 129.6 2.4 2 3 9 98.8 90.1 1.8 2 3 10 4.3 3.4 0.4 2 3 11 6.4 8.4 0.5 2 3 12 11.9 8.3 0.5 2 3 13 9.1 8.3 0.5 2 3 14 10.8 11.4 0.5 2 3 15 2.5 2.9 0.6 2 4 0 1061.3 1104.9 22.3 2 4 1 559.3 528.1 8.3 2 4 2 9.9 10.0 0.3 2 4 3 1299.4 1325.7 31.6 2 4 4 90.4 80.0 1.4 2 4 5 1059.0 1045.0 29.2 2 4 6 242.3 246.1 3.8 2 4 7 2.8 5.9 0.4 2 4 8 33.5 31.2 0.8 2 4 9 427.0 425.9 8.0 2 4 10 34.9 41.3 0.8 2 4 11 60.5 67.4 1.2 2 4 12 10.3 9.2 0.6 2 4 13 42.2 43.0 1.0 2 4 15 15.0 17.6 0.7 2 5 0 225.0 221.9 4.6 2 5 1 8.7 1.1 0.3 2 5 2 1073.4 1096.0 15.6 2 5 3 947.3 936.2 13.2 2 5 4 225.0 224.7 3.2 2 5 5 381.2 414.4 5.3 2 5 6 33.2 28.3 0.7 2 5 7 88.4 84.9 1.6 2 5 8 278.1 265.5 5.2 2 5 9 126.0 108.6 2.0 2 5 10 49.9 50.2 1.1 2 5 11 21.2 19.8 0.6 2 5 12 8.3 7.8 0.5 2 5 13 19.8 21.1 0.8 2 5 14 6.8 8.7 0.6 2 6 0 1.4 0.1 0.3 2 6 1 9.3 10.6 0.3 2 6 2 288.5 305.7 4.0 2 6 3 227.6 212.1 3.3 2 6 4 210.5 227.9 3.1 2 6 5 172.0 168.4 2.8 2 6 6 89.9 83.7 1.5 2 6 7 227.4 228.2 3.9 2 6 8 93.6 89.6 1.6 2 6 9 91.8 97.9 1.7 2 6 11 9.0 7.0 0.5 2 6 12 4.1 3.1 0.5 2 6 13 3.9 3.0 0.5 2 6 14 4.0 3.5 0.6 2 7 0 53.7 44.2 1.4 2 7 1 207.0 218.8 2.9 2 7 2 36.1 30.1 0.7 2 7 3 72.5 62.3 1.2 2 7 4 349.4 351.2 5.5 2 7 5 3.6 4.8 0.3 2 7 6 193.5 197.0 3.4 2 7 7 98.0 90.7 1.8 2 7 8 28.4 24.1 0.7 2 7 9 20.2 23.4 0.6 2 7 10 86.6 82.8 1.7 2 7 11 7.6 8.1 0.5 2 7 12 9.2 10.7 0.6 2 7 13 5.1 5.3 0.5 2 8 0 62.4 77.9 1.6 2 8 1 147.9 147.0 2.3 2 8 2 94.5 89.3 1.5 2 8 3 102.4 94.3 1.7 2 8 4 124.9 122.0 2.1 2 8 5 184.8 185.7 3.2 2 8 6 10.1 12.3 0.5 2 8 7 68.8 69.5 1.2 2 8 8 132.8 130.0 2.3 2 8 9 21.8 23.2 0.7 2 8 10 26.8 26.2 0.9 2 8 11 11.2 13.6 0.6 2 8 12 2.9 3.4 0.5 2 8 13 5.2 7.9 0.6 2 9 0 12.0 11.3 0.6 2 9 1 13.2 11.8 0.5 2 9 2 166.3 169.1 2.5 2 9 3 153.3 142.7 2.6 2 9 4 37.7 38.1 0.8 2 9 5 36.2 42.2 0.8 2 9 6 7.5 7.6 0.5 2 9 7 110.5 107.3 1.9 2 9 8 27.8 32.5 0.8 2 9 10 27.5 23.5 0.8 2 9 11 13.1 11.7 0.7 2 9 12 4.3 5.1 0.6 2 10 0 7.8 7.4 0.6 2 10 1 111.8 106.7 1.8 2 10 2 40.1 48.1 0.9 2 10 3 96.0 85.3 1.8 2 10 4 42.6 37.1 0.9 2 10 6 4.4 5.7 0.5 2 10 7 74.2 72.3 1.4 2 10 8 9.4 11.4 0.5 2 10 9 12.8 14.7 0.6 2 10 10 15.7 16.2 0.7 2 10 11 6.0 7.7 0.7 2 11 0 12.7 13.9 0.7 2 11 1 40.6 41.1 0.9 2 11 2 43.9 45.5 1.0 2 11 3 33.7 33.7 0.8 2 11 4 18.0 23.4 0.6 2 11 5 5.9 2.5 0.5 2 11 6 25.6 27.4 0.8 2 11 7 21.5 18.6 0.7 2 11 8 5.2 5.8 0.5 2 11 9 16.6 17.4 0.7 2 11 10 4.1 5.3 0.8 2 12 0 2.6 0.6 0.8 2 12 1 6.7 9.9 0.5 2 12 2 20.6 21.0 0.7 2 12 3 24.2 22.3 0.8 2 12 4 22.5 20.9 0.8 2 12 5 23.6 22.1 0.8 2 12 6 3.7 3.4 0.6 2 12 7 11.4 12.8 0.6 2 12 8 4.1 7.3 0.5 2 12 9 5.3 4.4 0.8 2 13 1 15.0 15.9 0.7 2 13 2 7.8 11.2 0.7 2 13 3 20.0 23.2 0.7 2 13 6 4.2 5.4 0.6 2 14 0 4.9 3.1 1.1 2 14 1 2.7 4.0 0.6 2 14 2 8.2 10.3 0.7 2 14 3 5.9 5.6 0.7 2 14 4 13.9 17.6 1.0 3 0 2 121.8 122.3 4.1 3 0 3 239.1 230.7 5.3 3 0 4 516.2 514.3 13.5 3 0 5 347.2 344.5 7.6 3 0 6 72.1 76.2 1.6 3 0 8 48.8 45.7 1.3 3 0 9 113.7 101.7 3.1 3 0 10 264.4 286.1 7.1 3 0 11 27.9 24.2 1.1 3 0 12 1.7 0.9 0.5 3 0 13 1.6 0.1 0.5 3 0 14 4.0 4.8 0.5 3 1 0 553.4 542.2 20.8 3 1 1 650.7 715.3 17.9 3 1 2 597.7 614.1 13.7 3 1 3 912.8 927.7 22.7 3 1 4 1058.5 1097.2 42.3 3 1 5 80.7 79.1 1.2 3 1 6 93.2 93.7 1.6 3 1 7 103.8 96.6 1.6 3 1 8 128.9 128.0 2.1 3 1 9 22.9 22.9 0.6 3 1 10 15.0 14.0 0.5 3 1 11 24.2 22.3 0.7 3 1 12 2.8 1.5 0.4 3 1 13 7.5 6.1 0.5 3 1 14 4.5 5.1 0.4 3 1 15 3.4 1.7 0.5 3 2 0 208.2 228.3 5.7 3 2 2 160.6 167.9 2.5 3 2 3 959.2 969.7 20.5 3 2 4 1050.3 1081.9 30.6 3 2 5 107.8 109.9 1.7 3 2 6 168.6 152.0 2.8 3 2 7 448.4 455.2 7.0 3 2 8 30.3 31.2 0.7 3 2 9 302.1 297.5 5.3 3 2 10 33.9 35.9 0.7 3 2 11 70.9 73.2 1.3 3 2 12 51.6 55.5 1.1 3 2 13 4.7 3.9 0.5 3 2 15 8.9 11.0 0.6 3 3 0 735.3 779.4 15.7 3 3 1 885.3 879.2 14.3 3 3 4 46.6 41.2 0.8 3 3 5 85.3 89.2 1.5 3 3 6 84.0 99.0 1.3 3 3 7 64.9 51.3 1.1 3 3 8 76.4 73.6 1.3 3 3 10 99.5 113.1 1.8 3 3 11 23.9 27.3 0.8 3 3 12 1.8 1.7 0.4 3 3 13 11.9 15.2 0.5 3 3 14 6.4 5.1 0.5 3 3 15 4.1 1.6 0.6 3 4 0 22.6 21.9 0.7 3 4 1 953.3 977.6 14.0 3 4 2 3.4 8.7 0.3 3 4 3 925.1 895.9 16.0 3 4 4 185.4 167.0 2.8 3 4 5 124.4 106.1 1.9 3 4 6 42.7 40.3 0.8 3 4 7 123.5 114.0 2.1 3 4 8 150.6 146.3 2.5 3 4 9 466.8 447.9 8.5 3 4 10 112.3 119.7 2.0 3 4 11 41.5 43.9 0.9 3 4 12 7.3 10.2 0.5 3 4 13 12.9 11.8 0.5 3 4 14 8.6 8.4 0.6 3 5 0 20.0 11.9 0.6 3 5 1 476.5 451.9 6.5 3 5 2 848.4 858.4 11.5 3 5 3 313.0 314.3 4.1 3 5 4 339.8 303.0 5.2 3 5 5 480.2 460.5 7.1 3 5 6 34.0 32.6 0.7 3 5 7 200.7 187.6 3.4 3 5 8 129.2 122.9 2.2 3 5 9 2.4 0.4 0.4 3 5 10 80.8 81.6 1.5 3 5 11 13.6 14.2 0.5 3 5 12 11.9 11.5 0.6 3 5 13 6.0 5.9 0.5 3 5 14 1.6 2.7 0.5 3 6 0 604.9 595.1 11.8 3 6 1 8.8 10.6 0.3 3 6 2 147.2 148.4 2.1 3 6 3 69.7 78.5 1.1 3 6 4 279.7 254.7 4.1 3 6 5 129.9 144.0 2.3 3 6 6 170.0 163.1 2.9 3 6 7 41.1 42.0 0.8 3 6 8 30.4 33.8 0.7 3 6 9 110.9 106.8 1.9 3 6 10 29.8 34.5 0.8 3 6 11 4.9 3.9 0.4 3 6 12 6.3 6.2 0.5 3 6 13 3.5 3.2 0.5 3 7 0 77.7 89.2 1.9 3 7 1 14.5 11.8 0.4 3 7 2 129.7 136.4 2.1 3 7 3 451.2 458.3 6.9 3 7 4 14.2 16.2 0.5 3 7 5 29.1 26.4 0.7 3 7 6 104.5 109.7 1.9 3 7 7 61.4 59.0 1.3 3 7 8 45.6 48.4 1.0 3 7 9 18.5 19.4 0.7 3 7 10 22.0 19.5 0.7 3 7 11 2.3 1.6 0.5 3 7 12 4.6 3.0 0.5 3 7 13 2.9 4.6 0.5 3 8 0 100.7 95.0 2.2 3 8 1 196.4 192.0 3.0 3 8 2 163.3 176.0 2.8 3 8 3 60.5 61.2 1.2 3 8 4 83.0 76.8 1.5 3 8 5 115.3 112.4 2.0 3 8 6 114.7 101.8 2.2 3 8 7 9.8 9.5 0.5 3 8 8 1.8 0.9 0.4 3 8 9 35.5 37.1 0.8 3 8 10 6.9 7.8 0.5 3 8 11 25.5 24.4 0.8 3 9 0 502.7 483.1 10.2 3 9 1 87.3 83.0 1.4 3 9 2 147.4 147.9 2.3 3 9 3 136.1 137.2 2.5 3 9 4 68.5 67.0 1.4 3 9 5 21.4 15.5 0.7 3 9 6 97.4 99.0 1.8 3 9 7 55.7 61.0 1.1 3 9 8 22.3 24.1 0.7 3 9 9 16.2 14.5 0.7 3 9 10 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3 14 8.9 9.4 0.5 4 4 0 17.6 22.1 0.5 4 4 1 796.6 766.2 10.9 4 4 2 845.2 838.6 11.5 4 4 3 280.4 271.6 4.0 4 4 4 405.5 369.3 5.9 4 4 5 150.3 143.5 2.3 4 4 6 66.7 60.4 1.1 4 4 7 251.3 257.3 4.1 4 4 8 31.1 37.5 0.7 4 4 9 74.3 81.7 1.3 4 4 10 276.8 266.7 4.5 4 4 11 25.2 21.5 0.7 4 4 12 6.1 5.0 0.4 4 4 13 2.4 1.2 0.5 4 4 14 2.1 1.4 0.5 4 5 0 4.2 4.4 0.3 4 5 1 536.6 525.4 7.1 4 5 2 492.7 479.7 6.9 4 5 3 127.1 122.1 1.9 4 5 4 41.2 34.2 0.8 4 5 5 75.4 73.4 1.3 4 5 6 51.4 46.3 0.9 4 5 7 80.7 74.2 1.4 4 5 8 13.7 15.6 0.4 4 5 9 7.1 4.9 0.4 4 5 10 20.7 20.1 0.7 4 5 11 15.7 17.7 0.6 4 5 12 12.8 11.6 0.6 4 5 13 9.1 10.7 0.6 4 5 14 2.5 1.5 0.6 4 6 0 60.1 55.7 1.3 4 6 1 18.1 12.1 0.4 4 6 2 125.1 116.2 1.9 4 6 3 4.3 3.2 0.3 4 6 4 93.9 90.2 1.5 4 6 5 138.8 134.3 2.3 4 6 6 23.1 25.8 0.6 4 6 7 63.9 57.2 1.3 4 6 8 40.4 40.8 0.8 4 6 9 48.2 47.0 1.0 4 6 10 5.2 4.6 0.4 4 6 11 3.2 2.8 0.4 4 6 12 2.9 3.2 0.5 4 6 13 1.9 2.5 0.5 4 7 0 85.5 89.6 1.9 4 7 1 89.9 92.9 1.5 4 7 2 29.4 25.9 0.6 4 7 3 186.3 173.4 2.9 4 7 4 2.1 1.6 0.3 4 7 5 26.3 23.0 0.7 4 7 6 16.4 18.6 0.6 4 7 7 103.5 105.5 1.9 4 7 8 4.4 5.7 0.4 4 7 9 5.1 5.1 0.4 4 7 10 3.9 4.9 0.4 4 7 11 11.3 10.4 0.6 4 7 12 13.9 13.6 0.6 4 8 0 261.1 286.3 5.4 4 8 1 393.6 364.8 5.8 4 8 2 67.9 59.3 1.2 4 8 3 175.6 179.3 2.8 4 8 4 33.4 32.1 0.7 4 8 5 81.8 76.4 1.6 4 8 6 15.1 13.8 0.5 4 8 7 34.4 31.0 0.8 4 8 8 70.9 70.9 1.3 4 8 9 12.2 11.1 0.6 4 8 10 6.3 4.7 0.5 4 8 11 21.7 24.4 0.7 4 8 12 6.6 5.9 0.6 4 9 0 86.7 90.8 1.9 4 9 1 102.7 101.9 1.6 4 9 2 184.6 180.8 2.8 4 9 3 71.4 75.3 1.3 4 9 4 29.7 37.2 0.7 4 9 5 56.6 61.3 1.2 4 9 6 54.1 68.2 1.1 4 9 7 11.1 12.1 0.5 4 9 8 21.5 26.2 0.7 4 9 9 12.7 12.4 0.6 4 9 10 14.5 13.9 0.6 4 9 11 12.9 12.3 0.8 4 10 0 286.4 267.2 5.8 4 10 1 14.6 14.4 0.5 4 10 2 233.4 229.6 3.6 4 10 3 124.0 130.0 2.1 4 10 4 13.3 15.2 0.5 4 10 5 12.2 17.7 0.5 4 10 6 6.5 5.7 0.5 4 10 7 26.5 23.8 0.7 4 10 8 4.3 5.0 0.5 4 10 9 20.9 21.5 0.8 4 10 10 7.3 5.8 0.6 4 11 1 43.4 43.4 1.0 4 11 2 26.9 28.1 0.8 4 11 3 6.5 4.3 0.5 4 11 4 7.0 6.7 0.5 4 11 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10 33.0 31.3 0.7 6 1 11 1.9 2.4 0.4 6 1 12 8.4 8.8 0.4 6 1 13 5.8 5.1 0.4 6 2 0 1.7 1.1 0.2 6 2 1 247.6 237.6 3.7 6 2 2 145.9 136.3 2.4 6 2 3 596.5 607.5 10.0 6 2 4 244.1 222.6 4.5 6 2 5 11.8 11.6 0.4 6 2 6 114.6 103.6 2.3 6 2 7 29.4 25.1 0.5 6 2 8 1.6 1.0 0.3 6 2 9 32.5 30.2 0.7 6 2 10 32.9 31.1 0.7 6 2 11 12.4 14.5 0.5 6 2 12 17.5 16.4 0.5 6 2 13 3.9 5.4 0.6 6 3 0 749.2 728.0 15.5 6 3 1 140.8 140.8 2.1 6 3 2 70.6 67.1 1.2 6 3 3 621.1 611.9 10.9 6 3 4 78.9 71.8 1.5 6 3 5 12.4 13.0 0.4 6 3 6 178.5 180.2 3.4 6 3 7 104.5 102.5 1.8 6 3 8 14.0 15.2 0.4 6 3 9 19.3 19.9 0.5 6 3 10 19.0 16.2 0.5 6 3 11 32.7 35.3 0.8 6 3 12 2.9 2.6 0.4 6 3 13 3.5 3.6 0.6 6 4 0 12.2 7.6 0.4 6 4 1 54.4 57.6 0.9 6 4 2 71.8 65.0 1.2 6 4 3 105.1 97.2 1.8 6 4 4 61.9 61.6 1.1 6 4 5 10.6 11.8 0.3 6 4 6 105.9 105.4 1.8 6 4 7 61.6 70.9 1.1 6 4 8 112.3 110.4 2.0 6 4 9 17.2 20.9 0.5 6 4 10 2.7 1.6 0.3 6 4 11 25.8 24.4 0.6 6 4 12 1.6 0.5 0.4 6 4 13 4.2 3.6 0.6 6 5 0 1.4 0.4 0.3 6 5 1 15.6 14.8 0.4 6 5 2 23.8 17.9 0.5 6 5 3 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9 7.4 9.3 0.5 6 9 10 7.6 5.8 1.0 6 10 0 5.7 4.9 0.6 6 10 1 9.5 10.9 0.5 6 10 2 24.2 26.4 0.6 6 10 3 1.9 2.2 0.4 6 10 4 12.8 13.2 0.5 6 10 5 1.7 1.9 0.5 6 10 6 15.1 15.3 0.6 6 10 7 7.7 5.7 0.5 6 10 9 7.6 7.3 0.8 6 11 1 16.2 14.5 0.6 6 11 2 40.2 43.1 0.9 6 11 3 13.2 16.3 0.5 6 11 4 20.4 18.6 0.7 6 11 5 10.0 11.0 0.6 6 11 6 13.7 16.5 0.6 6 11 7 4.9 4.2 0.6 6 12 0 33.7 26.2 1.3 6 12 1 10.6 7.0 0.7 6 12 2 37.2 32.0 0.9 6 12 3 18.4 21.0 0.7 6 12 4 7.7 8.2 0.6 6 12 5 8.7 10.9 0.6 6 13 0 9.1 7.2 1.1 6 13 1 13.2 13.0 0.6 7 0 2 39.0 34.4 1.0 7 0 3 170.5 179.5 5.4 7 0 4 109.9 107.8 3.6 7 0 5 6.9 3.5 0.9 7 0 6 20.1 17.5 1.1 7 0 7 5.2 4.1 1.2 7 0 8 1.9 0.7 0.2 7 0 9 2.1 1.1 0.4 7 0 10 6.5 5.1 0.5 7 0 11 12.0 13.4 0.6 7 0 13 7.8 3.3 1.8 7 1 0 36.5 41.6 0.9 7 1 1 103.9 95.5 1.6 7 1 2 409.7 410.5 7.4 7 1 3 83.2 93.6 1.5 7 1 4 143.7 130.8 3.2 7 1 5 40.4 46.1 0.9 7 1 6 98.2 104.5 2.0 7 1 7 123.4 128.2 2.6 7 1 8 180.7 180.8 3.5 7 1 9 55.7 57.7 1.0 7 1 10 44.1 41.6 0.8 7 1 11 9.5 10.5 0.4 7 1 13 9.5 6.9 1.5 7 2 0 142.7 143.3 3.2 7 2 1 6.9 4.3 0.2 7 2 2 43.2 42.4 0.8 7 2 3 237.4 247.6 4.3 7 2 4 89.3 104.9 1.8 7 2 5 152.2 151.7 3.3 7 2 6 5.6 4.5 0.3 7 2 7 31.9 29.4 0.8 7 2 8 122.4 124.1 2.7 7 2 9 13.3 12.7 0.6 7 2 10 18.7 19.7 0.5 7 2 11 5.1 6.8 0.3 7 3 0 60.2 56.0 1.3 7 3 1 5.6 6.0 0.2 7 3 2 2.5 2.3 0.3 7 3 3 40.1 43.5 0.9 7 3 4 34.0 33.7 0.8 7 3 5 21.1 20.5 0.6 7 3 6 201.1 205.2 3.8 7 3 7 26.0 26.9 0.8 7 3 9 11.1 9.8 0.6 7 3 10 3.3 3.7 0.2 7 3 11 6.1 6.0 0.4 7 3 12 4.8 5.7 0.7 7 4 0 125.0 127.5 2.9 7 4 1 57.9 58.9 1.0 7 4 2 99.4 107.7 1.8 7 4 3 9.4 10.5 0.4 7 4 4 115.2 103.0 2.4 7 4 5 43.7 44.0 1.0 7 4 6 39.3 45.3 0.9 7 4 7 15.3 17.7 0.6 7 4 8 4.0 4.7 0.4 7 4 9 15.0 16.4 0.6 7 4 10 2.7 1.5 0.3 7 4 11 9.6 10.6 0.6 7 4 12 7.1 7.3 0.6 7 5 0 864.4 845.8 35.5 7 5 1 98.8 96.7 1.6 7 5 2 40.3 45.6 0.8 7 5 3 104.6 100.5 1.8 7 5 4 55.4 58.6 1.1 7 5 5 18.9 17.0 0.7 7 5 6 36.4 48.5 1.0 7 5 7 21.5 17.6 0.7 7 5 8 3.4 3.5 0.2 7 5 9 3.5 3.7 0.3 7 5 10 12.1 11.9 0.4 7 5 11 6.5 6.9 0.6 7 5 12 4.2 5.1 0.6 7 6 0 82.3 89.4 2.0 7 6 1 186.7 175.4 2.9 7 6 2 57.1 54.4 1.1 7 6 3 44.8 43.1 0.9 7 6 4 78.3 77.5 1.5 7 6 5 7.0 6.9 0.4 7 6 6 50.7 49.7 0.9 7 6 7 48.3 55.5 0.9 7 6 8 20.0 21.7 0.5 7 6 9 1.1 1.1 0.2 7 6 10 3.8 3.0 0.7 7 6 11 11.5 14.9 0.7 7 7 0 24.5 20.5 0.9 7 7 1 241.9 243.2 3.9 7 7 2 12.6 10.9 0.4 7 7 3 115.3 114.0 2.1 7 7 4 40.6 38.3 0.8 7 7 5 43.1 50.7 0.9 7 7 6 50.4 51.7 0.9 7 7 7 29.0 30.5 0.6 7 7 8 3.7 2.0 0.4 7 7 9 13.5 12.2 0.8 7 7 10 5.9 7.2 0.6 7 7 11 2.9 5.0 0.7 7 8 0 26.2 29.2 0.8 7 8 1 55.1 56.7 1.1 7 8 2 13.9 12.2 0.5 7 8 3 22.4 23.8 0.6 7 8 4 7.8 7.6 0.4 7 8 5 12.4 12.9 0.4 7 8 6 23.8 25.2 0.6 7 8 7 19.8 18.9 0.7 7 8 8 5.0 5.4 0.3 7 8 9 9.0 12.7 0.7 7 9 1 9.4 12.3 0.5 7 9 2 13.0 11.9 0.5 7 9 3 13.1 12.3 0.5 7 9 4 3.1 2.5 0.4 7 9 5 1.9 0.8 0.4 7 9 6 3.0 3.5 0.4 7 9 7 20.1 20.6 0.6 7 9 8 11.7 10.3 0.8 7 9 9 3.1 4.6 0.8 7 10 0 2.5 0.2 0.5 7 10 1 14.0 11.8 0.5 7 10 2 24.3 22.6 0.7 7 10 3 11.0 9.2 0.5 7 10 4 15.0 15.6 0.5 7 10 5 1.4 0.5 0.4 7 10 6 1.8 3.3 0.4 7 10 7 5.3 6.1 0.7 7 11 0 2.4 0.0 0.6 7 11 1 15.0 12.1 0.6 7 11 2 23.9 23.6 0.7 7 11 3 1.7 1.4 0.4 7 11 4 18.9 22.8 0.6 7 12 0 3.3 1.9 0.8 7 12 1 7.5 6.4 0.6 7 12 2 9.6 8.9 0.6 7 12 3 3.1 1.7 0.6 8 0 0 259.5 254.4 7.1 8 0 2 163.3 168.1 5.5 8 0 3 261.2 244.1 8.6 8 0 4 53.4 63.1 2.0 8 0 5 5.9 2.3 0.8 8 0 6 13.4 12.7 0.9 8 0 7 33.0 29.2 1.5 8 0 8 2.6 1.2 0.8 8 0 9 156.4 169.7 5.3 8 0 12 11.2 13.8 1.3 8 1 0 3.7 3.0 0.3 8 1 1 7.8 4.6 0.2 8 1 2 63.1 71.5 1.2 8 1 3 44.4 47.7 0.9 8 1 4 20.3 17.4 0.8 8 1 5 59.2 66.8 1.5 8 1 6 61.6 58.4 2.0 8 1 7 9.6 7.2 0.8 8 1 8 18.3 19.9 0.8 8 1 9 26.5 24.3 0.7 8 1 10 4.6 5.8 0.3 8 1 11 3.0 1.0 0.8 8 1 12 3.3 1.9 1.1 8 2 0 46.1 42.5 1.1 8 2 1 223.7 230.0 3.3 8 2 2 130.2 127.7 2.4 8 2 3 4.0 2.7 0.3 8 2 4 10.3 12.4 0.4 8 2 5 31.0 33.7 0.8 8 2 6 58.6 55.3 1.2 8 2 7 4.0 4.7 0.3 8 2 8 32.7 32.9 0.8 8 2 9 16.9 19.8 0.5 8 2 10 3.2 3.2 0.5 8 2 11 8.8 7.4 0.8 8 2 12 9.1 8.8 1.1 8 3 0 397.0 393.6 7.9 8 3 1 446.7 438.7 7.4 8 3 2 155.1 155.4 3.1 8 3 3 6.7 6.8 0.3 8 3 4 7.1 8.6 0.4 8 3 5 11.9 12.2 0.4 8 3 6 71.0 76.0 1.5 8 3 7 22.4 26.0 0.7 8 3 8 8.8 8.5 0.5 8 3 9 15.2 16.1 0.6 8 3 10 2.6 2.5 0.4 8 3 11 3.0 3.0 0.6 8 4 0 2.3 0.5 0.4 8 4 1 142.3 140.8 2.2 8 4 2 50.5 54.5 1.0 8 4 3 14.5 16.0 0.5 8 4 4 51.4 49.7 1.1 8 4 5 26.5 30.6 0.7 8 4 6 71.1 73.0 1.6 8 4 7 68.0 75.4 1.4 8 4 8 19.7 21.7 0.8 8 4 9 7.9 9.0 0.5 8 4 10 4.1 3.4 0.5 8 4 11 12.9 15.5 0.7 8 5 0 377.1 367.3 8.5 8 5 1 310.8 309.2 5.6 8 5 2 28.9 29.3 0.6 8 5 3 31.3 26.7 0.8 8 5 4 75.6 74.0 1.6 8 5 5 6.6 6.4 0.4 8 5 6 38.8 42.6 1.0 8 5 7 21.1 20.0 0.7 8 5 8 11.6 10.2 0.6 8 5 9 4.1 3.7 0.5 8 5 10 12.0 11.6 0.6 8 6 0 392.4 377.5 8.1 8 6 1 10.0 11.1 0.4 8 6 2 24.1 21.2 0.6 8 6 3 25.9 27.1 0.6 8 6 4 18.7 20.6 0.5 8 6 5 15.2 18.9 0.5 8 6 6 16.7 21.8 0.7 8 6 7 16.0 14.5 0.7 8 6 8 6.2 4.6 0.6 8 6 9 20.0 19.6 0.7 8 6 10 7.3 7.2 0.6 8 7 0 65.7 72.1 1.6 8 7 1 68.3 62.6 1.2 8 7 2 29.3 27.4 0.6 8 7 3 12.9 11.4 0.4 8 7 4 7.0 4.8 0.3 8 7 5 7.0 7.8 0.4 8 7 6 62.4 64.3 1.1 8 7 7 9.3 9.3 0.6 8 7 9 6.9 6.9 0.6 8 7 10 14.8 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