#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/27/2012721.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2012721_Fobs loop_ _publ_author_name 'Low, John N.' 'Quesada, Antonio' 'Marchal, Antonio' 'Melguizo, Manuel' 'Nogueras, Manuel' 'Glidewell, Christopher' _publ_section_title ; Hydrogen bonding in 2-amino-4,6-dimethoxypyrimidine, 2-benzylamino-4,6-bis(benzyloxy)pyrimidine and 2-amino-4,6-bis(N-pyrrolidino)pyrimidine: chains of fused rings and a centrosymmetric dimer ; _journal_issue 5 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first o289 _journal_page_last o294 _journal_volume 58 _journal_year 2002 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 106.585 _cell_angle_gamma 90.000 _cell_length_a 12.3971 _cell_length_b 8.3608 _cell_length_c 14.5237 _exptl_crystal_F_000 656.00 _reflns_d_resolution_high 0.7701 _[local]_cod_data_source_file sk1546Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' amaqdimetoxy' _shelx_refln_list_code 4 _shelx_f_calc_maximum 225.79 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 28835.56 21219.19 1345.12 o 4 0 0 470.30 340.16 15.55 o 6 0 0 14.31 10.94 7.74 o 8 0 0 129.34 115.28 15.51 o 10 0 0 6.49 0.00 16.44 o 12 0 0 974.76 827.54 98.20 o 14 0 0 39.17 54.22 32.55 o 1 1 0 2012.05 1619.25 131.21 o 3 1 0 1172.79 1080.36 26.64 o 5 1 0 1713.16 1963.63 47.82 o 7 1 0 5089.66 5737.74 141.16 o 9 1 0 0.12 2.19 7.33 o 11 1 0 347.64 331.45 21.83 o 13 1 0 169.30 107.10 26.78 o 15 1 0 4.12 12.40 27.05 o 0 2 0 579.09 550.82 18.79 o 4 2 0 2.55 10.99 6.35 o 6 2 0 650.34 697.77 22.02 o 8 2 0 379.54 403.97 13.25 o 10 2 0 10.29 7.83 6.63 o 12 2 0 91.63 71.16 27.44 o 14 2 0 11.10 6.23 26.18 o 1 3 0 273.02 226.51 5.62 o 3 3 0 671.57 607.00 15.45 o 5 3 0 512.45 590.77 17.59 o 7 3 0 120.67 153.32 11.04 o 9 3 0 3.73 3.68 6.98 o 11 3 0 4.62 -3.67 6.96 o 13 3 0 3.55 -11.05 15.59 o 0 4 0 2320.63 2211.32 83.00 o 2 4 0 1016.72 980.53 24.81 o 4 4 0 1079.58 1075.86 53.28 o 6 4 0 1192.25 1201.66 41.91 o 8 4 0 0.00 1.83 11.24 o 10 4 0 1432.63 1435.76 62.94 o 12 4 0 0.00 2.80 9.14 o 14 4 0 45.92 10.89 32.77 o 1 5 0 23.86 13.98 5.61 o 3 5 0 2722.84 2752.54 77.64 o 5 5 0 100.66 111.98 11.13 o 7 5 0 0.62 0.00 5.54 o 9 5 0 2.09 -0.02 7.03 o 11 5 0 306.89 263.20 28.91 o 13 5 0 14.90 -11.00 32.88 o 0 6 0 138.67 166.75 28.52 o 2 6 0 161.88 170.55 11.18 o 4 6 0 251.37 280.52 16.74 o 6 6 0 562.28 527.46 26.05 o 8 6 0 2440.13 2659.16 113.55 o 10 6 0 2068.27 2163.02 145.23 o 12 6 0 52.46 39.05 31.55 o 1 7 0 360.41 381.03 21.28 o 3 7 0 654.88 654.29 30.07 o 5 7 0 836.87 908.45 44.90 o 7 7 0 43.89 50.13 27.76 o 9 7 0 28.16 22.32 15.78 o 11 7 0 13.20 22.26 44.75 o 0 8 0 413.77 493.50 63.85 o 2 8 0 53.36 66.38 14.59 o 4 8 0 34.69 20.72 10.06 o 6 8 0 179.75 171.27 26.73 o 8 8 0 117.28 100.27 44.64 o 10 8 0 24.26 33.31 33.31 o 1 9 0 16.94 -6.70 13.11 o 3 9 0 78.07 63.91 24.15 o 5 9 0 58.00 53.64 21.46 o 7 9 0 17.56 28.66 26.73 o 0 10 0 87.09 110.94 33.31 o 2 10 0 9.96 99.79 77.63 o 4 10 0 79.27 70.36 66.74 o 6 10 0 23.33 -11.10 33.42 o -15 1 1 6.00 -17.06 26.02 o -13 1 1 74.03 65.30 23.09 o -11 1 1 860.76 849.49 37.82 o -9 1 1 47.98 41.90 5.33 o -7 1 1 1943.75 2168.39 46.28 o -5 1 1 7050.69 7299.01 180.02 o -3 1 1 1996.63 1958.23 60.08 o -1 1 1 3830.08 2967.44 639.09 o 1 1 1 2248.05 2093.73 81.13 o 3 1 1 5842.13 5326.36 133.23 o 5 1 1 132.13 170.00 6.95 o 7 1 1 1812.08 2075.61 43.16 o 9 1 1 65.11 76.09 6.95 o 11 1 1 232.35 181.07 18.96 o 13 1 1 70.81 92.45 23.09 o 15 1 1 398.08 390.85 76.10 o -14 2 1 0.00 -18.18 18.18 o -12 2 1 13.45 10.94 12.66 o -10 2 1 48.61 59.85 8.28 o -8 2 1 1617.53 1743.33 44.88 o -6 2 1 72.88 88.60 5.48 o -4 2 1 148.40 126.49 9.00 o -2 2 1 8456.99 7180.16 171.07 o 0 2 1 18453.11 16112.27 382.38 o 2 2 1 676.61 676.15 22.39 o 4 2 1 556.24 522.50 15.01 o 6 2 1 776.27 822.29 23.08 o 8 2 1 1137.76 1136.48 39.87 o 10 2 1 211.11 219.56 12.04 o 12 2 1 388.62 381.50 38.72 o 14 2 1 0.72 -16.38 27.22 o -15 3 1 342.61 350.24 76.65 o -13 3 1 8.43 43.77 21.88 o -11 3 1 14.23 25.60 6.92 o -9 3 1 99.56 99.72 10.87 o -7 3 1 6.21 5.53 5.53 o -5 3 1 162.16 174.03 9.49 o -3 3 1 1037.58 970.50 27.67 o -1 3 1 3.08 11.10 7.85 o 1 3 1 1421.03 1254.94 30.60 o 3 3 1 100.01 87.26 5.55 o 5 3 1 402.87 419.59 11.91 o 7 3 1 1126.22 1155.90 34.28 o 9 3 1 120.30 120.37 11.87 o 11 3 1 458.35 503.00 33.60 o 13 3 1 65.31 94.52 44.58 o -14 4 1 10.54 21.88 32.77 o -12 4 1 205.26 211.58 20.76 o -10 4 1 1273.99 1317.44 52.25 o -8 4 1 617.68 647.45 32.92 o -6 4 1 140.32 123.58 12.72 o -4 4 1 422.30 401.22 14.69 o -2 4 1 5.96 11.18 11.26 o 0 4 1 142.85 138.39 6.19 o 2 4 1 1.66 0.00 5.59 o 4 4 1 298.44 327.03 14.11 o 6 4 1 667.24 716.03 25.62 o 8 4 1 223.92 220.52 14.56 o 10 4 1 12.55 3.69 14.03 o 12 4 1 14.06 17.99 14.48 o 14 4 1 1.99 -10.89 43.77 o -13 5 1 303.09 317.58 65.76 o -11 5 1 97.43 79.50 15.78 o -9 5 1 180.13 193.72 18.18 o -7 5 1 6.04 3.16 6.43 o -5 5 1 1081.72 1253.42 71.33 o -3 5 1 1229.26 1190.81 31.97 o -1 5 1 53.37 57.35 6.43 o 1 5 1 1003.90 1017.71 28.88 o 3 5 1 36.63 35.35 11.55 o 5 5 1 8.71 3.70 6.98 o 7 5 1 1745.43 1850.61 95.73 o 9 5 1 802.21 888.60 51.92 o 11 5 1 463.06 422.35 45.73 o 13 5 1 0.15 16.70 23.66 o -12 6 1 159.24 110.07 54.98 o -10 6 1 18.82 22.35 20.08 o -8 6 1 263.64 251.80 22.60 o -6 6 1 96.21 120.26 11.97 o -4 6 1 64.79 70.62 8.45 o -2 6 1 1063.88 1082.19 36.01 o 0 6 1 0.51 0.00 5.58 o 2 6 1 91.53 86.54 12.84 o 4 6 1 99.17 103.91 14.11 o 6 6 1 454.14 413.04 24.54 o 8 6 1 736.20 751.65 50.98 o 10 6 1 1080.55 1122.74 87.01 o 12 6 1 111.27 111.70 31.55 o -11 7 1 7.84 0.00 44.31 o -9 7 1 2.47 22.21 33.31 o -7 7 1 93.66 101.10 16.15 o -5 7 1 1.13 0.00 8.45 o -3 7 1 1000.86 1052.33 52.47 o -1 7 1 686.03 712.71 41.85 o 1 7 1 285.87 271.64 18.37 o 3 7 1 233.87 250.23 17.74 o 5 7 1 43.49 36.72 17.68 o 7 7 1 47.28 50.12 15.74 o 9 7 1 758.67 830.76 61.81 o 11 7 1 4.56 -11.21 67.07 o -10 8 1 220.03 200.32 55.63 o -8 8 1 793.79 952.63 80.35 o -6 8 1 115.97 133.48 44.37 o -4 8 1 26.92 23.33 12.03 o -2 8 1 107.83 140.27 16.75 o 0 8 1 250.29 242.84 22.95 o 2 8 1 24.50 22.34 13.19 o 4 8 1 21.99 18.08 14.23 o 6 8 1 111.93 134.49 23.63 o 8 8 1 132.42 126.24 27.98 o 10 8 1 21.39 -11.10 33.31 o -7 9 1 4.42 33.42 33.42 o -5 9 1 3.10 24.90 17.13 o -3 9 1 5.62 13.96 14.29 o -1 9 1 0.50 13.39 13.11 o 1 9 1 61.22 89.54 25.83 o 3 9 1 245.91 275.85 27.45 o 5 9 1 14.61 3.20 26.71 o 7 9 1 6.63 16.71 27.82 o -6 10 1 18.04 0.00 44.64 o -4 10 1 2.81 12.52 28.58 o -2 10 1 157.51 123.05 31.41 o 0 10 1 15.96 26.68 22.26 o 2 10 1 3.96 11.10 23.56 o 4 10 1 0.01 -23.60 23.60 o -14 0 2 1.60 -21.67 21.67 o -12 0 2 232.39 240.94 23.21 o -10 0 2 35.24 34.44 11.00 o -8 0 2 4015.71 4083.13 147.50 o -6 0 2 1045.83 1091.99 81.71 o -4 0 2 3076.73 2828.06 91.00 o -2 0 2 8339.83 6824.55 450.49 o 0 0 2 6261.27 5257.32 2194.10 o 2 0 2 4521.82 4097.49 132.37 o 4 0 2 77.77 109.36 7.74 o 6 0 2 2713.26 2896.14 118.60 o 8 0 2 991.69 995.28 49.97 o 10 0 2 0.27 -9.75 9.75 o 12 0 2 250.88 260.86 43.55 o 14 0 2 6.81 32.44 32.44 o -15 1 2 381.62 459.47 57.20 o -13 1 2 2.01 -5.47 16.28 o -11 1 2 186.93 178.93 12.90 o -9 1 2 217.77 238.67 10.42 o -7 1 2 3186.34 3574.20 84.89 o -5 1 2 2.59 11.10 11.10 o -3 1 2 514.14 452.40 12.72 o -1 1 2 149.12 131.59 5.58 o 1 1 2 612.15 613.31 16.50 o 3 1 2 142.84 142.15 4.88 o 5 1 2 7449.01 8249.04 190.34 o 7 1 2 416.58 442.45 17.44 o 9 1 2 19.83 5.44 7.89 o 11 1 2 927.20 836.44 57.59 o 13 1 2 75.27 76.13 19.46 o -14 2 2 50.48 61.17 18.22 o -12 2 2 23.67 5.51 8.96 o -10 2 2 310.60 325.61 14.55 o -8 2 2 483.24 497.59 17.10 o -6 2 2 123.52 130.83 7.98 o -4 2 2 330.49 244.01 7.01 o -2 2 2 12922.57 11262.57 256.70 o 0 2 2 26729.38 23456.64 578.21 o 2 2 2 3224.45 3220.02 125.53 o 4 2 2 942.30 1115.04 27.44 o 6 2 2 1014.29 1068.04 28.58 o 8 2 2 0.20 -1.57 6.08 o 10 2 2 331.06 290.33 16.22 o 12 2 2 192.84 202.53 30.95 o 14 2 2 6.85 16.32 23.13 o -15 3 2 6.18 32.88 21.88 o -13 3 2 166.20 142.71 16.12 o -11 3 2 2375.55 2547.28 87.97 o -9 3 2 515.48 511.92 20.31 o -7 3 2 6.76 2.77 5.54 o -5 3 2 359.57 346.64 11.97 o -3 3 2 4424.96 4213.35 102.36 o -1 3 2 4167.31 4093.43 97.41 o 1 3 2 217.77 204.75 5.62 o 3 3 2 0.54 2.76 5.53 o 5 3 2 199.41 165.55 12.51 o 7 3 2 430.13 471.47 25.42 o 9 3 2 27.42 38.52 11.01 o 11 3 2 0.04 -4.41 11.43 o 13 3 2 129.04 158.50 26.45 o -14 4 2 24.46 32.88 32.88 o -12 4 2 104.51 97.46 11.94 o -10 4 2 3463.24 3859.73 138.01 o -8 4 2 54.54 47.24 9.57 o -6 4 2 417.45 428.82 16.64 o -4 4 2 71.72 78.94 5.59 o -2 4 2 758.78 754.95 27.68 o 0 4 2 382.85 450.49 14.32 o 2 4 2 4818.14 4652.65 100.55 o 4 4 2 725.90 778.88 23.34 o 6 4 2 136.35 114.28 8.42 o 8 4 2 3624.39 3848.32 141.85 o 10 4 2 0.35 0.00 21.88 o 12 4 2 36.67 4.80 26.78 o -13 5 2 0.14 -21.88 21.88 o -11 5 2 0.72 -5.58 15.78 o -9 5 2 308.56 330.00 19.47 o -7 5 2 84.47 80.12 13.27 o -5 5 2 581.48 564.62 22.30 o -3 5 2 226.10 218.95 13.61 o -1 5 2 1053.00 1014.30 31.31 o 1 5 2 3179.24 3402.55 80.14 o 3 5 2 1913.65 2011.58 57.28 o 5 5 2 78.27 78.79 12.80 o 7 5 2 320.55 342.08 34.10 o 9 5 2 33.79 47.00 43.82 o 11 5 2 0.19 21.88 21.88 o 13 5 2 54.55 95.80 31.57 o -10 6 2 0.17 11.16 15.78 o -8 6 2 372.47 385.75 23.21 o -6 6 2 248.89 249.28 16.66 o -4 6 2 62.07 67.22 12.84 o -2 6 2 141.86 161.61 19.72 o 0 6 2 0.39 2.79 5.58 o 2 6 2 248.64 232.02 11.17 o 4 6 2 360.37 347.49 20.38 o 6 6 2 140.73 134.20 13.06 o 8 6 2 2052.44 2271.26 153.87 o 10 6 2 934.05 1005.75 79.11 o 12 6 2 38.85 16.76 23.70 o -11 7 2 13.25 99.84 44.42 o -9 7 2 136.47 106.17 23.67 o -7 7 2 615.66 635.41 35.90 o -5 7 2 85.56 76.32 11.15 o -3 7 2 22.99 22.39 8.14 o -1 7 2 82.73 89.09 13.14 o 1 7 2 16.84 6.39 6.17 o 3 7 2 539.45 515.27 27.08 o 5 7 2 84.12 83.96 14.56 o 7 7 2 12.50 8.89 18.52 o 9 7 2 0.60 22.30 23.67 o 11 7 2 0.13 -7.47 34.99 o -10 8 2 31.26 55.74 44.53 o -8 8 2 1525.31 1856.99 148.81 o -4 8 2 96.03 80.13 13.11 o -2 8 2 20.26 11.23 12.95 o 0 8 2 153.03 169.07 22.39 o 2 8 2 14.43 -3.34 13.11 o 4 8 2 161.89 156.11 17.68 o 6 8 2 224.18 200.78 31.49 o 8 8 2 0.78 -17.50 26.71 o -7 9 2 3.01 11.21 27.87 o -5 9 2 118.09 113.74 22.99 o -3 9 2 670.81 669.27 47.12 o -1 9 2 427.93 459.61 38.66 o 1 9 2 0.10 -2.78 11.16 o 3 9 2 18.76 -8.35 14.23 o 5 9 2 15.11 11.10 33.37 o 7 9 2 14.23 16.67 23.60 o -6 10 2 175.46 55.85 55.85 o -4 10 2 193.33 192.51 34.79 o -2 10 2 844.76 985.29 144.15 o 0 10 2 322.32 445.48 47.19 o 2 10 2 4.30 -4.46 18.52 o 4 10 2 1.84 19.07 26.71 o -15 1 3 0.41 0.02 23.02 o -13 1 3 3.11 -0.04 12.59 o -11 1 3 469.57 408.55 19.29 o -9 1 3 36.57 31.81 4.49 o -7 1 3 283.31 316.50 9.02 o -5 1 3 2135.09 2210.45 60.88 o -3 1 3 3775.47 3223.30 71.20 o -1 1 3 3030.12 2911.04 63.64 o 1 1 3 8614.59 8102.34 166.34 o 3 1 3 48.35 28.49 6.33 o 5 1 3 1924.73 2042.97 49.66 o 7 1 3 1293.73 1446.51 39.75 o 9 1 3 33.26 28.45 9.41 o 11 1 3 452.45 512.98 38.61 o 13 1 3 50.05 43.42 26.02 o -14 2 3 5.29 0.05 15.47 o -12 2 3 120.69 81.32 10.97 o -10 2 3 2211.60 2316.41 56.75 o -8 2 3 95.64 120.87 7.90 o -6 2 3 26.69 21.93 4.91 o -4 2 3 1852.63 1931.15 59.76 o -2 2 3 7508.59 7230.06 162.43 o 0 2 3 50981.29 44518.43 1258.01 o 2 2 3 119.53 104.86 5.50 o 4 2 3 698.84 772.82 24.18 o 6 2 3 1932.31 1996.62 54.76 o 8 2 3 17.95 21.91 5.48 o 10 2 3 23.12 9.13 7.76 o 12 2 3 68.62 54.70 27.44 o 14 2 3 0.68 16.39 38.16 o -15 3 3 81.50 76.75 32.88 o -13 3 3 466.85 376.14 33.74 o -11 3 3 25.24 22.08 6.38 o -9 3 3 5.22 15.45 4.94 o -7 3 3 4514.26 4932.51 131.86 o -5 3 3 5618.83 5620.23 140.91 o -3 3 3 4494.99 4412.60 118.33 o -1 3 3 4575.63 4337.36 117.04 o 1 3 3 2705.93 2709.95 63.91 o 3 3 3 1419.94 1315.34 36.66 o 5 3 3 4.71 18.81 6.36 o 7 3 3 32.95 31.63 5.88 o 9 3 3 33.88 33.00 12.76 o 11 3 3 0.32 -15.49 18.40 o 13 3 3 57.82 92.83 26.45 o -14 4 3 2.58 0.00 32.88 o -12 4 3 556.00 561.53 48.71 o -10 4 3 1310.71 1344.04 52.85 o -8 4 3 148.44 138.68 11.94 o -6 4 3 81.83 71.01 6.14 o -4 4 3 252.22 257.38 11.18 o -2 4 3 26.63 24.04 6.97 o 0 4 3 573.60 501.16 17.78 o 2 4 3 52.27 47.25 6.43 o 4 4 3 350.51 354.21 14.53 o 6 4 3 1230.23 1303.21 45.67 o 8 4 3 1177.24 1129.65 51.02 o 10 4 3 96.17 62.55 17.53 o 12 4 3 78.79 83.31 23.55 o -13 5 3 62.43 120.63 32.88 o -11 5 3 83.00 75.11 25.04 o -9 5 3 94.14 97.15 13.03 o -7 5 3 241.74 224.56 14.52 o -5 5 3 898.09 958.57 29.85 o -3 5 3 2.55 0.00 6.45 o -1 5 3 17.73 11.16 5.59 o 1 5 3 613.47 630.39 20.52 o 3 5 3 100.47 122.84 11.13 o 5 5 3 357.18 354.94 18.82 o 7 5 3 190.47 180.06 14.55 o 9 5 3 214.99 231.66 24.28 o 11 5 3 25.09 44.68 23.70 o -12 6 3 59.93 72.78 44.15 o -10 6 3 571.47 585.01 41.57 o -8 6 3 106.90 113.87 16.04 o -6 6 3 56.53 51.67 12.78 o -4 6 3 112.23 96.38 11.58 o -2 6 3 3.73 -6.46 6.46 o 0 6 3 999.83 1017.90 35.34 o 2 6 3 281.36 277.02 16.74 o 4 6 3 61.87 51.92 9.51 o 6 6 3 543.14 517.88 36.48 o 8 6 3 6.87 5.55 15.78 o 10 6 3 44.21 61.50 23.70 o -11 7 3 46.14 11.10 33.31 o -9 7 3 84.45 93.01 18.56 o -7 7 3 0.73 11.10 9.10 o -5 7 3 4.44 0.01 12.92 o -3 7 3 177.99 172.45 13.19 o -1 7 3 12.90 5.58 7.04 o 1 7 3 17.05 2.23 11.15 o 3 7 3 273.75 310.09 27.92 o 5 7 3 343.60 371.20 32.06 o 7 7 3 139.23 95.31 23.56 o 9 7 3 118.86 107.95 28.86 o -10 8 3 80.57 66.96 55.74 o -8 8 3 47.65 44.64 19.96 o -6 8 3 36.75 51.97 12.89 o -4 8 3 259.18 287.17 34.74 o -2 8 3 37.53 38.04 13.16 o 0 8 3 0.14 -5.07 12.04 o 2 8 3 69.75 46.90 13.16 o 4 8 3 27.46 -3.20 16.16 o 6 8 3 0.51 0.00 15.70 o 8 8 3 353.40 316.69 50.75 o -9 9 3 199.91 335.33 78.28 o -7 9 3 37.27 -2.25 18.58 o -5 9 3 86.18 136.83 27.60 o -3 9 3 29.87 37.31 19.38 o -1 9 3 12.16 0.02 15.73 o 1 9 3 5.07 -3.17 16.15 o 3 9 3 230.95 216.31 39.30 o 5 9 3 433.62 462.41 47.11 o 7 9 3 8.28 22.21 23.56 o -6 10 3 29.53 89.49 44.75 o -4 10 3 433.89 485.47 63.15 o -2 10 3 1019.59 1296.28 101.54 o 0 10 3 16.45 25.47 26.74 o 2 10 3 0.11 -11.10 38.87 o 4 10 3 63.15 57.75 44.42 o -16 0 4 279.98 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