#------------------------------------------------------------------------------
#$Date: 2010-01-30 15:59:17 +0200 (Sat, 30 Jan 2010) $
#$Revision: 966 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/2012797.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2012797
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2002
_journal_volume  58
_journal_page_first  i101
_journal_page_last  i102
_publ_section_title
;
Germanium(IV) chloride at 193 K
;
_space_group_IT_number           14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_[local]_cod_cif_authors_sg_H-M  'P 21/c'
loop_
_publ_author_name
  'Merz, Klaus'
  'Driess, Matthias'
_chemical_formula_moiety  'Ge Cl4'
_chemical_formula_sum            'Cl4 Ge'
_[local]_cod_chemical_formula_sum_orig 'Ge Cl4'
_chemical_formula_structural  'Ge Cl4'
_chemical_formula_iupac  'Ge Cl4'
_chemical_formula_weight  214.39
_symmetry_cell_setting  monoclinic
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, y+1/2, -z+1/2'
  '-x, -y, -z'
  'x, -y-1/2, z-1/2'
_cell_length_a  9.690(3)
_cell_length_b  6.451(2)
_cell_length_c  9.774(3)
_cell_angle_alpha  90.00
_cell_angle_beta  103.075(6)
_cell_angle_gamma  90.00
_cell_volume  595.1(4)
_cell_formula_units_Z  4
_cell_measurement_temperature  193(2)
_exptl_crystal_density_diffrn  2.393
_diffrn_ambient_temperature  193(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Ge1 0.25164(4) 0.57350(5) 0.63977(4) 0.0232(2) Uani d . 1 . . Ge
  Cl2 0.30205(13) 0.42188(16) 0.46770(11) 0.0426(3) Uani d . 1 . . Cl
  Cl3 0.42835(11) 0.56946(15) 0.80965(10) 0.0375(3) Uani d . 1 . . Cl
  Cl4 0.08347(12) 0.41974(16) 0.69787(12) 0.0428(3) Uani d . 1 . . Cl
  Cl1 0.19210(12) 0.87990(15) 0.58530(11) 0.0405(3) Uani d . 1 . . Cl
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Ge1 0.0252(3) 0.0219(3) 0.0212(3) 0.00010(13) 0.00244(17) 0.00034(13)
  Cl2 0.0510(7) 0.0467(6) 0.0293(5) 0.0089(5) 0.0076(5) -0.0102(4)
  Cl3 0.0330(6) 0.0420(6) 0.0312(5) 0.0006(4) -0.0059(4) -0.0024(4)
  Cl4 0.0347(7) 0.0493(7) 0.0439(6) -0.0103(4) 0.0079(5) 0.0119(4)
  Cl1 0.0504(7) 0.0248(5) 0.0439(6) 0.0056(4) 0.0058(5) 0.0055(4)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Ge1 Cl4 . 2.0930(12) yes
  Ge1 Cl1 . 2.0938(12) yes
  Ge1 Cl2 . 2.0966(12) yes
  Ge1 Cl3 . 2.0984(12) yes
_cod_database_code 2012797