#------------------------------------------------------------------------------
#$Date: 2008-01-14 00:15:36 +0200 (Mon, 14 Jan 2008) $
#$Revision: 14 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/2014565.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2014565
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2004
_journal_volume  60
_journal_page_first  m567
_journal_page_last  m568
_publ_section_title
;
catena-Poly[[di-\m-benzoato-\k^4^O:O'-disilver(I)]-\m-N,N'-
bis(2-fluorobenzylidene)butane-1,4-diamine-\k^2^N:N']
;
loop_
_publ_author_name
  'You, Zhong-Lu'
  'Zhu, Hai-Liang'
_chemical_formula_moiety  'C32 H28 Ag2 F2 N2 O4'
_chemical_formula_sum  'C32 H28 Ag2 F2 N2 O4'
_chemical_formula_iupac  '[Ag2 (C7 H5 O2)2 (C18 H18 F2 N2)]'
_chemical_formula_weight  758.30
_symmetry_cell_setting  triclinic
_symmetry_space_group_name_H-M  'P -1'
_symmetry_space_group_name_Hall  '-P 1'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, -y, -z'
_cell_length_a  5.703(3)
_cell_length_b  10.313(5)
_cell_length_c  12.805(6)
_cell_angle_alpha  86.978(6)
_cell_angle_beta  84.452(7)
_cell_angle_gamma  77.115(7)
_cell_volume  730.4(6)
_cell_formula_units_Z  1
_cell_measurement_temperature  293(2)
_exptl_crystal_density_diffrn  1.724
_diffrn_ambient_temperature  293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Ag1 0.75137(11) 0.91168(6) 0.50699(4) 0.0652(4) Uani d . 1 . . Ag
  F1 0.8616(16) 0.7128(9) 0.9210(5) 0.116(2) Uani d . 1 . . F
  N1 0.9338(12) 0.7175(7) 0.6085(5) 0.0612(16) Uani d . 1 . . N
  O1 0.8060(10) 1.0757(6) 0.6018(5) 0.0657(14) Uani d . 1 . . O
  O2 0.4124(10) 1.1708(7) 0.6162(5) 0.0757(17) Uani d . 1 . . O
  C1 0.8822(17) 0.6933(9) 0.7067(7) 0.067(2) Uani d . 1 . . C
  H1 0.9872 0.6262 0.7411 0.080 Uiso calc R 1 . . H
  C2 0.6675(18) 0.7660(9) 0.7664(7) 0.068(2) Uani d . 1 . . C
  C3 0.662(2) 0.7753(11) 0.8737(8) 0.088(3) Uani d . 1 . . C
  C4 0.462(3) 0.8432(16) 0.9346(11) 0.119(5) Uani d . 1 . . C
  H4 0.4675 0.8514 1.0062 0.143 Uiso calc R 1 . . H
  C5 0.261(3) 0.8967(14) 0.8869(12) 0.116(5) Uani d . 1 . . C
  H5 0.1226 0.9381 0.9271 0.139 Uiso calc R 1 . . H
  C6 0.256(2) 0.8913(11) 0.7785(11) 0.097(3) Uani d . 1 . . C
  H6 0.1186 0.9326 0.7457 0.116 Uiso calc R 1 . . H
  C7 0.4581(17) 0.8236(9) 0.7213(7) 0.070(2) Uani d . 1 . . C
  H7 0.4534 0.8163 0.6495 0.084 Uiso calc R 1 . . H
  C8 1.1502(16) 0.6318(8) 0.5563(7) 0.065(2) Uani d . 1 . . C
  H8A 1.2391 0.5734 0.6078 0.078 Uiso calc R 1 . . H
  H8B 1.2550 0.6860 0.5213 0.078 Uiso calc R 1 . . H
  C9 1.0707(17) 0.5497(8) 0.4766(6) 0.065(2) Uani d . 1 . . C
  H9A 0.9725 0.6098 0.4290 0.078 Uiso calc R 1 . . H
  H9B 1.2130 0.5024 0.4356 0.078 Uiso calc R 1 . . H
  C10 0.6218(13) 1.1569(7) 0.6407(6) 0.0528(17) Uani d . 1 . . C
  C11 0.6576(13) 1.2485(7) 0.7235(5) 0.0484(16) Uani d . 1 . . C
  C12 0.8733(17) 1.2292(9) 0.7694(7) 0.066(2) Uani d . 1 . . C
  H12 1.0031 1.1616 0.7472 0.079 Uiso calc R 1 . . H
  C13 0.8947(19) 1.3119(11) 0.8492(7) 0.080(3) Uani d . 1 . . C
  H13 1.0382 1.2980 0.8813 0.096 Uiso calc R 1 . . H
  C14 0.708(2) 1.4121(10) 0.8802(8) 0.082(3) Uani d . 1 . . C
  H14 0.7223 1.4653 0.9346 0.098 Uiso calc R 1 . . H
  C15 0.502(2) 1.4354(10) 0.8334(8) 0.080(3) Uani d . 1 . . C
  H15 0.3781 1.5078 0.8525 0.096 Uiso calc R 1 . . H
  C16 0.4713(16) 1.3516(9) 0.7562(7) 0.066(2) Uani d . 1 . . C
  H16 0.3246 1.3654 0.7268 0.079 Uiso calc R 1 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Ag1 0.0608(5) 0.0685(5) 0.0709(5) -0.0200(3) -0.0106(3) -0.0098(3)
  F1 0.130(6) 0.168(7) 0.064(3) -0.065(5) -0.019(4) 0.007(4)
  N1 0.058(4) 0.058(4) 0.067(4) -0.010(3) -0.006(3) -0.001(3)
  O1 0.051(3) 0.068(3) 0.081(4) -0.016(3) 0.000(3) -0.023(3)
  O2 0.050(3) 0.102(5) 0.078(4) -0.013(3) -0.013(3) -0.030(3)
  C1 0.063(5) 0.072(5) 0.067(5) -0.021(4) -0.008(4) 0.004(4)
  C2 0.070(6) 0.071(5) 0.066(5) -0.028(4) -0.001(4) 0.000(4)
  C3 0.098(8) 0.103(8) 0.077(6) -0.051(7) -0.005(6) -0.005(6)
  C4 0.143(13) 0.143(12) 0.093(8) -0.087(11) 0.037(9) -0.047(8)
  C5 0.107(11) 0.119(11) 0.129(12) -0.059(9) 0.053(10) -0.041(9)
  C6 0.071(7) 0.084(7) 0.134(10) -0.020(6) 0.010(7) -0.007(7)
  C7 0.066(6) 0.074(6) 0.074(5) -0.025(4) 0.000(5) -0.001(4)
  C8 0.055(5) 0.063(5) 0.075(5) -0.011(4) -0.005(4) 0.004(4)
  C9 0.069(5) 0.052(4) 0.067(5) -0.007(4) 0.014(4) -0.008(3)
  C10 0.044(4) 0.063(4) 0.055(4) -0.018(3) -0.003(3) -0.001(3)
  C11 0.041(4) 0.058(4) 0.051(4) -0.020(3) -0.001(3) -0.004(3)
  C12 0.058(5) 0.083(6) 0.062(5) -0.026(4) -0.006(4) -0.008(4)
  C13 0.071(6) 0.115(8) 0.070(5) -0.047(6) -0.024(5) -0.005(5)
  C14 0.091(7) 0.088(7) 0.076(6) -0.038(6) 0.001(5) -0.027(5)
  C15 0.080(7) 0.079(6) 0.085(6) -0.023(5) 0.001(5) -0.024(5)
  C16 0.060(5) 0.068(5) 0.070(5) -0.010(4) -0.011(4) -0.014(4)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Ag1 O2 2_676 2.206(6) yes
  Ag1 O1 . 2.227(5) yes
  Ag1 N1 . 2.417(7) yes
  Ag1 Ag1 2_676 3.051(2) yes
  F1 C3 . 1.357(14) ?
  N1 C1 . 1.287(10) yes
  N1 C8 . 1.472(10) yes
  O1 C10 . 1.266(9) ?
  O2 C10 . 1.240(9) ?
  O2 Ag1 2_676 2.206(6) ?
  C1 C2 . 1.455(13) ?
  C1 H1 . 0.9300 ?
  C2 C7 . 1.376(13) ?
  C2 C3 . 1.378(14) ?
  C3 C4 . 1.387(19) ?
  C4 C5 . 1.35(2) ?
  C4 H4 . 0.9300 ?
  C5 C6 . 1.396(18) ?
  C5 H5 . 0.9300 ?
  C6 C7 . 1.373(14) ?
  C6 H6 . 0.9300 ?
  C7 H7 . 0.9300 ?
  C8 C9 . 1.522(12) ?
  C8 H8A . 0.9700 ?
  C8 H8B . 0.9700 ?
  C9 C9 2_766 1.507(17) ?
  C9 H9A . 0.9700 ?
  C9 H9B . 0.9700 ?
  C10 C11 . 1.514(10) ?
  C11 C16 . 1.376(11) ?
  C11 C12 . 1.384(11) ?
  C12 C13 . 1.396(12) ?
  C12 H12 . 0.9300 ?
  C13 C14 . 1.355(14) ?
  C13 H13 . 0.9300 ?
  C14 C15 . 1.339(14) ?
  C14 H14 . 0.9300 ?
  C15 C16 . 1.394(13) ?
  C15 H15 . 0.9300 ?
  C16 H16 . 0.9300 ?