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Information card for entry 2020521
Preview
| Coordinates | 2020521.cif |
|---|---|
| Structure factors | 2020521.hkl |
| Original IUCr paper | HTML |
| Chemical name | Carbonyl(cyanotrihydridoborato-κ<i>N</i>)bis(triphenylphosphine-κ<i>P</i>)rhodium(I) |
|---|---|
| Formula | C38 H33 B N O P2 Rh |
| Calculated formula | C38 H33 B N O P2 Rh |
| Title of publication | Diminished electron density in the Vaska-type rhodium(I) complex <i>trans</i>-[Rh(NCBH~3~)(CO)(PPh~3~)~2~] |
| Authors of publication | Galding, M. R.; Virovets, A. V.; Kazakov, I. V.; Scheer, M.; Smirnov, S. N.; Timoshkin, A. Y. |
| Journal of publication | Acta Crystallographica Section C |
| Year of publication | 2016 |
| Journal volume | 72 |
| Journal issue | 7 |
| Pages of publication | 514 - 517 |
| a | 13.9227 ± 0.0001 Å |
| b | 12.35 ± 0.0001 Å |
| c | 19.7966 ± 0.0001 Å |
| α | 90° |
| β | 105.987 ± 0.001° |
| γ | 90° |
| Cell volume | 3272.28 ± 0.04 Å3 |
| Cell temperature | 123 ± 2 K |
| Ambient diffraction temperature | 123 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0222 |
| Residual factor for significantly intense reflections | 0.0207 |
| Weighted residual factors for significantly intense reflections | 0.0553 |
| Weighted residual factors for all reflections included in the refinement | 0.0559 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.078 |
| Diffraction radiation wavelength | 1.54178 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | Yes |
| Revision | Date | Message | Files |
|---|---|---|---|
| 185010 (current) | 2016-08-05 | cif/ Updating files of 2020521 Original log message: Adding full bibliography for 2020521.cif. |
2020521.cif 2020521.hkl |
| 183339 | 2016-06-11 | cif/ hkl/ Adding structures of 2020521 via cif-deposit CGI script. |
2020521.cif 2020521.hkl |
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Users of the data should acknowledge the original authors of the
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