#------------------------------------------------------------------------------ #$Date: 2019-02-15 05:36:06 +0200 (Fri, 15 Feb 2019) $ #$Revision: 213659 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/15/2021512.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2021512 loop_ _publ_author_name 'Powers, Kyle A.' 'Geiger, David K.' _publ_section_title ; Hydrogen bonding in two benzene-1,2-diaminium pyridine-2-carboxylate salts and a cocrystal of benzene-1,2-diamine and benzoic acid ; _journal_coeditor_code FN3292 _journal_issue 3 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S2053229619002262 _journal_volume 75 _journal_year 2019 _chemical_formula_iupac '0.5C6 H10 N2 2+, C6 H4 N O2 -' _chemical_formula_moiety '0.5(C6 H10 N2 2+), C6 H4 N O2 -' _chemical_formula_sum 'C9 H9 N2 O2' _chemical_formula_weight 177.18 _chemical_name_common KAP12082016 _chemical_name_systematic ; Benzene-1,2-diaminium bis(pyridine-2-carboxylate) ; _space_group_crystal_system monoclinic _space_group_IT_number 15 _space_group_name_Hall '-C 2yc' _space_group_name_H-M_alt 'C 1 2/c 1' _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _atom_sites_solution_hydrogens mixed _cell_angle_alpha 90 _cell_angle_beta 125.362(7) _cell_angle_gamma 90 _cell_formula_units_Z 8 _cell_length_a 21.467(5) _cell_length_b 7.675(2) _cell_length_c 12.837(3) _cell_measurement_reflns_used 2197 _cell_measurement_temperature 200.(2) _cell_measurement_theta_max 23.0495 _cell_measurement_theta_min 2.3234 _cell_volume 1724.8(7) _computing_cell_refinement ; APEX2 (Bruker, 2015) ; _computing_data_collection ; APEX2 (Bruker, 2015) ; _computing_data_reduction ; SAINT (Bruker, 2015) ; _computing_molecular_graphics ; PLATON (Spek, 2009) and Mercury (Macrae et al., 2008) ; _computing_publication_material ; publCIF (Westrip, 2010) ; _computing_structure_refinement ; SHELXL2014 (Sheldrick, 2015) ; _computing_structure_solution ; SHELXS97 (Sheldrick, 2008) ; _diffrn_ambient_temperature 200.(2) _diffrn_detector_area_resol_mean 8.3330 _diffrn_measured_fraction_theta_full 0.997 _diffrn_measured_fraction_theta_max 0.997 _diffrn_measurement_device_type 'Bruker SMART X2S benchtop' _diffrn_measurement_method \w _diffrn_radiation_monochromator 'doubly curved silicon crystal' _diffrn_radiation_type MoKa _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0634 _diffrn_reflns_av_unetI/netI 0.0546 _diffrn_reflns_limit_h_max 25 _diffrn_reflns_limit_h_min -25 _diffrn_reflns_limit_k_max 6 _diffrn_reflns_limit_k_min -9 _diffrn_reflns_limit_l_max 14 _diffrn_reflns_limit_l_min -15 _diffrn_reflns_number 8287 _diffrn_reflns_theta_full 25.35 _diffrn_reflns_theta_max 25.35 _diffrn_reflns_theta_min 2.33 _diffrn_source 'XOS X-beam microfocus source' _exptl_absorpt_coefficient_mu 0.099 _exptl_absorpt_correction_T_max 0.98 _exptl_absorpt_correction_T_min 0.61 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (SADABS; Bruker, 2015) ; _exptl_crystal_colour 'clear brown' _exptl_crystal_density_diffrn 1.365 _exptl_crystal_density_method 'not measured' _exptl_crystal_description prism _exptl_crystal_F_000 744 _exptl_crystal_size_max 0.500 _exptl_crystal_size_mid 0.300 _exptl_crystal_size_min 0.250 _refine_diff_density_max 0.198 _refine_diff_density_min -0.257 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.042 _refine_ls_hydrogen_treatment mixed _refine_ls_matrix_type full _refine_ls_number_parameters 130 _refine_ls_number_reflns 1573 _refine_ls_number_restraints 3 _refine_ls_restrained_S_all 1.046 _refine_ls_R_factor_all 0.0649 _refine_ls_R_factor_gt 0.0466 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0685P)^2^+0.2917P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1226 _refine_ls_wR_factor_ref 0.1377 _reflns_number_gt 1161 _reflns_number_total 1573 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file fn3292sup1.cif _cod_data_source_block 1 _cod_database_code 2021512 _shelx_hkl_file ; 2 0 0 7.80 1.20 4 0 0 443.86 46.10 -4 0 0 448.46 46.20 -4 0 0 468.25 46.00 -4 0 0 442.06 46.30 4 0 0 422.56 46.30 4 0 0 436.26 46.00 6 0 0 290.27 34.90 6 0 0 324.07 34.50 -6 0 0 335.37 34.50 -6 0 0 354.26 34.80 -6 0 0 363.56 34.90 6 0 0 325.37 34.70 -8 0 0 252.97 26.30 -8 0 0 277.57 26.90 -8 0 0 256.87 26.60 8 0 0 218.98 26.80 -10 0 0 533.55 55.89 -10 0 0 564.74 56.19 -10 0 0 507.85 55.59 -12 0 0 48.60 5.80 -12 0 0 45.60 6.20 -12 0 0 60.09 6.70 -14 0 0 1.50 1.40 -14 0 0 4.80 2.30 -14 0 0 3.40 1.20 -16 0 0 3.20 1.40 -16 0 0 8.40 2.90 -16 0 0 8.40 2.60 -18 0 0 20.70 4.80 -18 0 0 42.90 6.40 -18 0 0 28.40 4.10 -20 0 0 3.10 2.90 -20 0 0 2.80 1.60 1 -1 0 782.72 83.39 1 -1 0 817.32 83.49 -1 -1 0 802.72 83.49 -1 -1 0 824.72 83.39 1 -1 0 702.93 83.49 1 1 0 863.71 83.49 1 1 0 820.92 83.39 -1 1 0 758.52 83.39 1 1 0 882.11 83.49 3 -1 0 389.16 36.60 -3 -1 0 329.97 37.00 3 -1 0 384.76 36.90 -3 -1 0 363.76 36.90 -3 -1 0 340.57 36.70 -3 1 0 318.17 36.90 3 1 0 305.47 36.90 3 1 0 387.56 36.70 -3 1 0 362.76 36.60 3 1 0 347.77 37.00 -5 -1 0 205.78 21.20 5 -1 0 221.38 21.20 -5 -1 0 179.38 21.00 -5 -1 0 182.48 21.40 5 -1 0 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5.30 2.80 7 -5 -12 4.00 4.00 5 -5 -12 -1.70 3.20 -5 -5 12 -1.60 2.20 -5 -5 12 1.30 1.20 5 -5 -12 5.80 4.00 24 0 -13 -1.60 1.90 -24 0 13 -0.50 2.00 -22 0 13 -1.30 1.60 22 0 -13 1.50 1.70 20 0 -13 0.50 1.30 -20 0 13 0.60 1.60 18 0 -13 1.30 2.00 -18 0 13 -0.80 1.20 18 0 -13 -1.40 1.10 16 0 -13 0.80 2.20 16 0 -13 -0.80 1.00 14 0 -13 1.40 2.40 12 0 -13 0.20 2.40 10 0 -13 0.70 1.60 8 0 -13 -0.10 2.10 6 0 -13 1.90 2.30 4 0 -13 0.50 2.40 2 0 -13 2.80 3.50 23 -1 -13 41.70 6.10 -23 -1 13 36.50 6.40 -23 1 13 44.00 6.70 23 1 -13 39.30 6.10 21 -1 -13 8.10 2.90 -21 -1 13 10.10 3.10 21 -1 -13 16.60 3.00 -21 1 13 9.40 2.90 21 1 -13 10.70 2.70 -19 -1 13 -0.30 1.60 19 -1 -13 0.50 1.30 19 -1 -13 3.20 2.40 19 1 -13 -1.00 1.20 -19 1 13 0.40 1.50 17 -1 -13 -0.30 2.10 -17 -1 13 0.80 1.50 17 -1 -13 0.50 1.20 17 1 -13 1.50 1.20 -15 -1 13 4.40 1.70 15 -1 -13 -0.10 2.30 13 -1 -13 2.70 2.40 11 -1 -13 22.10 4.50 11 -1 -13 29.10 5.60 9 -1 -13 49.90 9.30 9 -1 -13 79.59 9.10 7 -1 -13 2.60 2.50 5 -1 -13 13.70 4.50 5 1 -13 17.10 4.30 3 -1 -13 2.10 3.40 3 1 -13 2.90 3.50 22 -2 -13 37.80 5.40 -22 -2 13 32.80 5.90 22 -2 -13 28.70 5.60 22 2 -13 37.20 5.30 -22 2 13 28.00 5.60 -20 -2 13 -0.90 1.60 20 -2 -13 1.60 2.30 20 -2 -13 -0.50 1.50 -20 2 13 0.10 2.10 20 2 -13 1.90 1.40 -18 -2 13 8.80 2.60 18 -2 -13 5.70 2.00 18 -2 -13 6.70 2.90 18 2 -13 7.50 1.80 -16 -2 13 1.30 1.60 16 -2 -13 4.30 2.70 16 2 -13 -0.70 0.90 -14 -2 13 6.30 2.20 14 -2 -13 3.40 2.70 12 -2 -13 5.50 3.00 12 -2 -13 4.50 2.60 10 -2 -13 -0.60 2.70 -10 -2 13 1.90 2.20 10 -2 -13 -0.30 2.30 8 -2 -13 36.20 7.50 8 -2 -13 53.39 7.90 6 -2 -13 1.70 3.10 4 -2 -13 9.60 4.20 4 2 -13 3.00 2.40 21 -3 -13 2.20 2.00 -21 -3 13 1.00 2.40 21 -3 -13 4.90 2.90 19 -3 -13 23.10 5.10 -19 -3 13 21.00 4.80 19 -3 -13 34.30 4.60 17 -3 -13 5.30 2.90 -17 -3 13 4.40 2.40 -15 -3 13 38.80 5.80 15 -3 -13 31.80 6.30 -13 -3 13 11.60 3.00 13 -3 -13 11.60 4.10 11 -3 -13 31.30 5.80 11 -3 -13 19.20 5.20 9 -3 -13 7.10 4.00 -9 -3 13 13.30 2.60 9 -3 -13 11.80 4.40 -9 -3 13 5.90 2.90 7 -3 -13 11.80 4.50 -7 -3 13 1.80 2.20 7 -3 -13 7.80 4.20 -5 -3 13 2.70 2.30 5 -3 -13 9.00 4.30 18 -4 -13 12.80 4.20 -18 -4 13 7.90 3.30 16 -4 -13 35.50 6.60 -16 -4 13 34.20 6.00 14 -4 -13 3.70 3.50 -14 -4 13 7.80 2.90 12 -4 -13 3.70 3.60 -12 -4 13 6.80 2.60 12 -4 -13 7.70 3.70 -12 -4 13 8.10 2.50 10 -4 -13 3.50 3.40 -10 -4 13 -1.10 1.00 10 -4 -13 -2.20 3.20 8 -4 -13 3.10 4.20 -8 -4 13 4.00 1.40 8 -4 -13 6.30 4.00 6 -4 -13 11.40 4.80 -6 -4 13 4.80 3.20 6 -4 -13 8.10 4.30 -6 -4 13 18.50 2.60 -13 -5 13 -0.70 1.30 13 -5 -13 4.00 3.60 -13 -5 13 -1.80 2.20 13 -5 -13 1.50 3.50 -22 0 14 1.20 1.90 22 0 -14 3.30 1.80 20 0 -14 1.00 1.60 18 0 -14 1.20 1.40 16 0 -14 8.80 3.80 14 0 -14 25.50 5.20 8 0 -14 2.30 2.40 6 0 -14 -0.30 2.60 21 -1 -14 8.80 2.60 -21 -1 14 8.80 2.90 21 1 -14 9.40 2.30 19 -1 -14 1.60 2.40 19 -1 -14 -1.60 1.20 19 1 -14 -0.20 1.20 17 -1 -14 18.50 4.40 15 -1 -14 -1.60 2.60 13 -1 -14 5.30 3.20 11 -1 -14 31.30 6.30 9 -1 -14 0.60 2.70 7 -1 -14 2.40 2.90 5 -1 -14 6.40 3.90 -20 -2 14 9.00 3.00 20 -2 -14 7.20 3.40 20 -2 -14 5.40 2.10 20 2 -14 10.40 2.50 18 -2 -14 16.00 4.20 16 -2 -14 -2.30 2.60 14 -2 -14 5.70 3.30 12 -2 -14 2.10 3.20 10 -2 -14 7.20 3.70 10 -2 -14 -0.60 2.60 8 -2 -14 -0.30 3.10 6 -2 -14 0.10 3.20 19 -3 -14 34.60 6.40 -19 -3 14 27.60 5.30 17 -3 -14 10.20 4.20 15 -3 -14 13.30 4.30 13 -3 -14 2.70 3.60 11 -3 -14 5.30 4.10 11 -3 -14 0.50 3.10 9 -3 -14 34.60 7.00 9 -3 -14 23.20 6.30 17 -1 -15 17.00 4.80 15 -1 -15 4.20 3.60 13 -1 -15 4.10 3.50 16 -2 -15 34.90 7.00 14 -2 -15 2.20 3.50 _computing_structure_solution 'SHELXT 2014/4 (Sheldrick, 2014)' ; _shelx_hkl_checksum 87414 _shelx_res_file ; scan_0m_a.res created by SHELXL-2014/7 TITL scan_0m_a.res in C2/c CELL 0.71073 21.4671 7.6753 12.8369 90.000 125.362 90.000 ZERR 8.000 0.0051 0.0021 0.0026 0.000 0.007 0.000 LATT 7 SYMM -X, Y, 1/2-Z SFAC C H N O UNIT 36 36 8 8 L.S. 10 TEMP -73 ACTA DFIX 0.91 N1 H1A N1 H1B N1 H1C HTAB EQIV $1 -x+1, -y+1, -z+1 HTAB N1 O1_$1 HTAB N1 N2_$1 EQIV $2 -x+1, y, -z+3/2 HTAB N1 O2_$2 HTAB N1 O1 CONF MPLA N2 C5 C6 C7 C8 c9 MPLA C4 O1 O2 BOND $H FMAP 2 PLAN 20 SIZE 0.250 0.300 0.500 WGHT 0.068500 0.291700 FVAR 0.37707 N1 3 0.452664 0.538655 0.613124 11.00000 0.03432 0.04851 = 0.02997 -0.00008 0.01913 0.00005 H1A 2 0.418490 0.558700 0.526452 11.00000 0.05797 H1B 2 0.426678 0.463560 0.635595 11.00000 0.05837 H1C 2 0.493832 0.469869 0.623704 11.00000 0.08180 C1 1 0.477806 0.701510 0.683822 11.00000 0.02816 0.04624 = 0.03422 -0.00062 0.02040 -0.00114 C2 1 0.457149 0.857812 0.618331 11.00000 0.04846 0.05409 = 0.03881 0.00544 0.02124 0.00129 AFIX 43 H2 2 0.427843 0.858491 0.527684 11.00000 -1.20000 AFIX 0 C3 1 0.479229 1.012801 0.685036 11.00000 0.07894 0.04638 = 0.05410 0.00829 0.02592 0.00216 AFIX 43 H3 2 0.465377 1.120206 0.640072 11.00000 -1.20000 AFIX 0 O1 4 0.570101 0.386795 0.632836 11.00000 0.03528 0.08749 = 0.04183 -0.00029 0.02281 0.00814 O2 4 0.642094 0.369814 0.845179 11.00000 0.05544 0.08758 = 0.04454 0.01126 0.03622 0.01836 C4 1 0.632916 0.372488 0.739923 11.00000 0.04258 0.04788 = 0.03954 0.00301 0.02679 0.00705 N2 3 0.692289 0.385560 0.627888 11.00000 0.03667 0.06529 = 0.03708 0.00155 0.02267 0.00452 C5 1 0.703850 0.360060 0.741232 11.00000 0.03628 0.04329 = 0.03258 -0.00006 0.02064 0.00447 C6 1 0.775141 0.327979 0.851233 11.00000 0.04277 0.06666 = 0.03659 0.00086 0.02045 0.00981 AFIX 43 H6 2 0.781706 0.309985 0.930256 11.00000 -1.20000 AFIX 0 C7 1 0.836883 0.322536 0.844152 11.00000 0.03500 0.08401 = 0.05222 -0.00409 0.01779 0.01266 AFIX 43 H7 2 0.886557 0.298465 0.918313 11.00000 -1.20000 AFIX 0 C8 1 0.826081 0.351909 0.730138 11.00000 0.04043 0.08459 = 0.06359 -0.00579 0.03492 0.00538 AFIX 43 H8 2 0.868058 0.350931 0.723870 11.00000 -1.20000 AFIX 0 C9 1 0.753749 0.382785 0.625036 11.00000 0.04967 0.08114 = 0.04998 0.00147 0.03613 0.00580 AFIX 43 H9 2 0.746568 0.403372 0.545772 11.00000 -1.20000 AFIX 0 HKLF 4 REM scan_0m_a.res in C2/c REM R1 = 0.0466 for 1161 Fo > 4sig(Fo) and 0.0649 for all 1573 data REM 130 parameters refined using 3 restraints END WGHT 0.0684 0.2917 REM Instructions for potential hydrogen bonds HTAB N1 O1_$1 HTAB N1 N2_$1 HTAB N1 O2_$2 HTAB N1 O1 REM Highest difference peak 0.198, deepest hole -0.257, 1-sigma level 0.049 Q1 1 0.6414 0.4101 0.5412 11.00000 0.05 0.20 Q2 1 0.6486 0.5127 0.8435 11.00000 0.05 0.19 Q3 1 0.5734 0.5192 0.6287 11.00000 0.05 0.17 Q4 1 0.4488 0.7123 0.6211 11.00000 0.05 0.17 Q5 1 0.3886 0.8098 0.5177 11.00000 0.05 0.16 Q6 1 0.5773 0.2280 0.6308 11.00000 0.05 0.14 Q7 1 0.6865 0.5310 0.6365 11.00000 0.05 0.14 Q8 1 0.6875 0.2242 0.6362 11.00000 0.05 0.14 Q9 1 0.4623 0.8569 0.5724 11.00000 0.05 0.13 Q10 1 0.8905 0.2352 0.9629 11.00000 0.05 0.13 Q11 1 0.9093 0.3773 0.9327 11.00000 0.05 0.12 Q12 1 0.6432 0.2023 0.8329 11.00000 0.05 0.12 Q13 1 0.7279 0.5176 0.4800 11.00000 0.05 0.12 Q14 1 0.7768 0.4341 0.8476 11.00000 0.05 0.12 Q15 1 0.7887 0.3964 0.9594 11.00000 0.05 0.12 Q16 1 0.5091 0.4022 0.4896 11.00000 0.05 0.12 Q17 1 0.4399 0.9789 0.6325 11.00000 0.05 0.11 Q18 1 0.7588 0.3485 1.0223 11.00000 0.05 0.11 Q19 1 0.5322 0.2941 0.6409 11.00000 0.05 0.11 Q20 1 0.9583 0.4036 0.9631 11.00000 0.05 0.11 ; _shelx_res_checksum 42718 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy N N1 0.45266(9) 0.5387(2) 0.61312(15) 0.0373(4) Uani d 1 H H1A 0.4185(11) 0.559(3) 0.5265(15) 0.058(6) Uiso d 1 H H1B 0.4267(11) 0.464(2) 0.6356(19) 0.058(6) Uiso d 1 H H1C 0.4938(12) 0.470(3) 0.624(2) 0.082(7) Uiso d 1 C C1 0.47781(9) 0.7015(2) 0.68382(16) 0.0348(4) Uani d 1 C C2 0.45715(11) 0.8578(2) 0.6183(2) 0.0494(5) Uani d 1 H H2 0.4278 0.8585 0.5277 0.059 Uiso calc 1 C C3 0.47923(14) 1.0128(3) 0.6850(2) 0.0671(6) Uani d 1 H H3 0.4654 1.1202 0.6401 0.081 Uiso calc 1 O O1 0.57010(7) 0.38679(19) 0.63284(13) 0.0546(4) Uani d 1 O O2 0.64209(8) 0.36981(19) 0.84518(13) 0.0583(5) Uani d 1 C C4 0.63292(11) 0.3725(2) 0.73992(18) 0.0416(5) Uani d 1 N N2 0.69229(9) 0.3856(2) 0.62789(14) 0.0456(4) Uani d 1 C C5 0.70385(10) 0.3601(2) 0.74123(16) 0.0370(4) Uani d 1 C C6 0.77514(11) 0.3280(3) 0.85123(18) 0.0501(5) Uani d 1 H H6 0.7817 0.31 0.9303 0.06 Uiso calc 1 C C7 0.83688(11) 0.3225(3) 0.8442(2) 0.0614(6) Uani d 1 H H7 0.8866 0.2985 0.9183 0.074 Uiso calc 1 C C8 0.82608(12) 0.3519(3) 0.7301(2) 0.0601(6) Uani d 1 H H8 0.8681 0.3509 0.7239 0.072 Uiso calc 1 C C9 0.75375(12) 0.3828(3) 0.6250(2) 0.0560(6) Uani d 1 H H9 0.7466 0.4034 0.5458 0.067 Uiso calc 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 N1 0.0343(8) 0.0485(9) 0.0300(9) 0.0001(6) 0.0191(7) -0.0001(7) C1 0.0282(8) 0.0462(10) 0.0342(9) -0.0011(7) 0.0204(7) -0.0006(7) C2 0.0485(11) 0.0541(12) 0.0388(12) 0.0013(9) 0.0212(10) 0.0054(9) C3 0.0789(15) 0.0464(12) 0.0541(13) 0.0022(11) 0.0259(12) 0.0083(10) O1 0.0353(7) 0.0875(11) 0.0418(9) 0.0081(6) 0.0228(7) -0.0003(7) O2 0.0554(9) 0.0876(11) 0.0445(9) 0.0184(7) 0.0362(8) 0.0113(7) C4 0.0426(11) 0.0479(10) 0.0395(12) 0.0071(8) 0.0268(10) 0.0030(8) N2 0.0367(8) 0.0653(11) 0.0371(10) 0.0045(7) 0.0227(8) 0.0015(7) C5 0.0363(10) 0.0433(10) 0.0326(11) 0.0045(7) 0.0206(9) -0.0001(7) C6 0.0428(11) 0.0667(13) 0.0366(11) 0.0098(9) 0.0204(9) 0.0009(9) C7 0.0350(11) 0.0840(16) 0.0522(14) 0.0127(10) 0.0178(10) -0.0041(11) C8 0.0404(11) 0.0846(16) 0.0636(15) 0.0054(10) 0.0349(11) -0.0058(11) C9 0.0497(12) 0.0811(15) 0.0500(13) 0.0058(10) 0.0361(11) 0.0015(11) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle C1 N1 H1A . . 111.0(14) C1 N1 H1B . . 113.7(12) H1A N1 H1B . . 105.6(18) C1 N1 H1C . . 113.7(15) H1A N1 H1C . . 106.5(18) H1B N1 H1C . . 105.9(19) C2 C1 C1 . 2_656 119.77(11) C2 C1 N1 . . 119.62(16) C1 C1 N1 2_656 . 120.61(9) C3 C2 C1 . . 119.8(2) C3 C2 H2 . . 120.1 C1 C2 H2 . . 120.1 C3 C3 C2 2_656 . 120.42(12) C3 C3 H3 2_656 . 119.8 C2 C3 H3 . . 119.8 O2 C4 O1 . . 125.73(16) O2 C4 C5 . . 117.31(17) O1 C4 C5 . . 116.96(15) C9 N2 C5 . . 117.39(17) N2 C5 C6 . . 122.46(16) N2 C5 C4 . . 115.13(16) C6 C5 C4 . . 122.40(16) C5 C6 C7 . . 118.53(18) C5 C6 H6 . . 120.7 C7 C6 H6 . . 120.7 C8 C7 C6 . . 119.54(19) C8 C7 H7 . . 120.2 C6 C7 H7 . . 120.2 C7 C8 C9 . . 118.68(18) C7 C8 H8 . . 120.7 C9 C8 H8 . . 120.7 N2 C9 C8 . . 123.38(19) N2 C9 H9 . . 118.3 C8 C9 H9 . . 118.3 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance N1 C1 . 1.453(2) N1 H1A . 0.925(16) N1 H1B . 0.955(15) N1 H1C . 0.969(16) C1 C2 . 1.382(2) C1 C1 2_656 1.386(3) C2 C3 . 1.380(3) C2 H2 . 0.95 C3 C3 2_656 1.362(5) C3 H3 . 0.95 O1 C4 . 1.255(2) O2 C4 . 1.248(2) C4 C5 . 1.516(2) N2 C9 . 1.341(2) N2 C5 . 1.341(2) C5 C6 . 1.377(3) C6 C7 . 1.381(3) C6 H6 . 0.95 C7 C8 . 1.362(3) C7 H7 . 0.95 C8 C9 . 1.365(3) C8 H8 . 0.95 C9 H9 . 0.95 loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_publ_flag N1 H1A O1 5_666 0.925(16) 2.235(17) 2.958(2) 134.5(16) y N1 H1A N2 5_666 0.925(16) 2.076(18) 2.907(2) 148.8(17) y N1 H1B O2 2_656 0.955(15) 1.783(16) 2.7137(19) 163.7(18) y N1 H1C O1 . 0.969(16) 1.697(17) 2.6533(19) 168.(2) y C8 H8 Cg(bdaH~2~^2+^) 3_545 0.95 2.65 3.592(3) 170 y loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_4 _geom_torsion C1 C1 C2 C3 2_656 . -1.6(3) N1 C1 C2 C3 . . 178.30(17) C1 C2 C3 C3 . 2_656 -0.5(4) C9 N2 C5 C6 . . -1.5(3) C9 N2 C5 C4 . . 177.41(16) O2 C4 C5 N2 . . -171.91(16) O1 C4 C5 N2 . . 7.2(2) O2 C4 C5 C6 . . 7.0(3) O1 C4 C5 C6 . . -173.88(18) N2 C5 C6 C7 . . 0.2(3) C4 C5 C6 C7 . . -178.61(18) C5 C6 C7 C8 . . 1.2(3) C6 C7 C8 C9 . . -1.2(3) C5 N2 C9 C8 . . 1.5(3) C7 C8 C9 N2 . . -0.1(4) _cod_database_fobs_code 2021512