#------------------------------------------------------------------------------ #$Date: 2023-08-17 04:48:28 +0300 (Thu, 17 Aug 2023) $ #$Revision: 285801 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/28/2022839.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2022839 loop_ _publ_author_name 'Achyuta, Nagaraj' 'Kanagasabai, Somarathinam' 'Vinayagam, Pavunkumar' 'Mohanakrishnan, Arasambattu K.' 'Gautham, Namasivayam' 'Gunasekaran, Krishnasamy' _publ_section_title ; Crystal structure and Hirshfeld surface analysis of 3-(bromomethyl)-2-[1,2-dibromo-2-(6-nitrobenzo[d][1,3]dioxol-5-yl)ethyl]-1-(phenylsulfonyl)-1H-indole chloroform 0.585-solvate ; _journal_coeditor_code HB8071 _journal_issue 9 _journal_name_full 'Acta Crystallographica Section E Crystallographic Communications' _journal_paper_doi 10.1107/S2056989023007120 _journal_volume 79 _journal_year 2023 _chemical_formula_iupac 'C24 H17 Br3 N2 O6 S, 0.585C H Cl3' _chemical_formula_moiety 'C24 H17 Br3 N2 O6 S, 0.585(C H Cl3)' _chemical_formula_sum 'C24.58 H17.58 Br3 Cl1.75 N2 O6 S' _chemical_formula_weight 771.02 _chemical_name_systematic '3-(Bromomethyl)-2-[1,2-dibromo-2-(6-nitrobenzo[d][1,3]dioxol-5-yl)ethyl]-1-(phenylsulfonyl)-1H-indole chloroform 0.585-solvate' _space_group_crystal_system triclinic _space_group_IT_number 2 _space_group_name_Hall '-P 1' _space_group_name_H-M_alt 'P -1' _atom_sites_solution_hydrogens geom _audit_creation_method ; Olex2 1.5 (compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748) ; _cell_angle_alpha 99.448(3) _cell_angle_beta 110.701(3) _cell_angle_gamma 100.696(3) _cell_formula_units_Z 2 _cell_length_a 10.0987(3) _cell_length_b 12.2744(4) _cell_length_c 12.4842(5) _cell_measurement_reflns_used 10304 _cell_measurement_temperature 100.01(10) _cell_measurement_theta_max 77.2740 _cell_measurement_theta_min 3.7730 _cell_volume 1377.27(9) _computing_cell_refinement ; CrysAlisPro 1.171.42.36a (Rigaku OD, 2021) ; _computing_data_collection ; CrysAlisPro 1.171.42.36a (Rigaku OD, 2021) ; _computing_data_reduction ; CrysAlisPro 1.171.42.36a (Rigaku OD, 2021) ; _computing_molecular_graphics ; Olex2 1.5 (Dolomanov et al., 2009) ; _computing_publication_material ; Olex2 1.5 (Dolomanov et al., 2009) ; _computing_structure_refinement ; SHELXL2018/3 (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXT2018/2 (Sheldrick, 2015a) ; _diffrn_ambient_temperature 100.01(10) _diffrn_detector 'Hybrid Pixel Array Detector' _diffrn_detector_area_resol_mean 10.0000 _diffrn_measured_fraction_theta_full 1.000 _diffrn_measured_fraction_theta_max 0.983 _diffrn_measurement_device 'four-circle diffractometer' _diffrn_measurement_device_type 'SuperNova, Dual, Cu at home/near, HyPix' _diffrn_measurement_method '\w scans' _diffrn_radiation_monochromator mirror _diffrn_radiation_probe x-ray _diffrn_radiation_type 'Cu K\a' _diffrn_radiation_wavelength 1.54184 _diffrn_reflns_av_R_equivalents 0.0578 _diffrn_reflns_av_unetI/netI 0.0372 _diffrn_reflns_limit_h_max 12 _diffrn_reflns_limit_h_min -12 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_k_min -15 _diffrn_reflns_limit_l_max 15 _diffrn_reflns_limit_l_min -15 _diffrn_reflns_number 32306 _diffrn_reflns_theta_full 67.684 _diffrn_reflns_theta_max 77.781 _diffrn_reflns_theta_min 3.785 _diffrn_source 'micro-focus sealed X-ray tube' _exptl_absorpt_coefficient_mu 8.090 _exptl_absorpt_correction_T_max 0.918 _exptl_absorpt_correction_T_min 0.679 _exptl_absorpt_correction_type gaussian _exptl_absorpt_process_details ; (CrysAlisPro; Rigaku OD, 2021) ; _exptl_crystal_colour yellow _exptl_crystal_density_diffrn 1.859 _exptl_crystal_description block _exptl_crystal_F_000 756 _exptl_crystal_size_max 0.091 _exptl_crystal_size_mid 0.067 _exptl_crystal_size_min 0.042 _refine_diff_density_max 2.451 _refine_diff_density_min -1.182 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.070 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 362 _refine_ls_number_reflns 5783 _refine_ls_number_restraints 15 _refine_ls_restrained_S_all 1.069 _refine_ls_R_factor_all 0.0493 _refine_ls_R_factor_gt 0.0437 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0756P)^2^+3.2347P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1271 _refine_ls_wR_factor_ref 0.1336 _reflns_number_gt 5068 _reflns_number_total 5783 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file hb8071sup1.cif _cod_data_source_block I _cod_database_code 2022839 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_min 0.526 _shelx_estimated_absorpt_t_max 0.727 _shelx_hkl_file ; 0 0 -1 349.22 20.82 0 0 -1 364.84 20.95 0 0 1 364.54 21.15 0 0 -2 104.32 10.55 0 0 2 96.47 10.51 0 0 2 96.87 10.46 0 0 2 90.63 10.31 0 0 3 4.99 4.75 0 0 -3 2.51 3.42 0 0 3 2.89 1.69 0 0 3 1.55 2.98 0 0 -3 13.87 5.31 0 0 -4 967.24 60.12 0 0 4 903.15 58.41 0 0 4 905.69 46.98 0 0 -4 891.22 55.75 0 0 4 920.43 46.86 0 0 4 798.72 57.75 0 0 4 857.57 57.74 0 0 -4 886.53 58.15 0 0 5 447.17 25.95 0 0 -5 463.67 26.83 0 0 -5 448.82 26.76 0 0 5 400.83 25.99 0 0 5 453.46 25.91 0 0 5 423.12 25.56 0 0 5 437.22 25.46 0 0 6 175.65 13.40 0 0 6 176.79 13.25 0 0 6 162.62 13.86 0 0 -6 151.94 13.77 0 0 -6 191.84 14.81 0 0 6 163.04 13.37 0 0 -6 175.38 13.72 0 0 -7 2.43 3.14 0 0 7 -1.05 2.01 0 0 7 0.99 2.09 0 0 7 2.27 2.40 0 0 -7 -2.37 3.39 0 0 7 -1.04 2.01 0 0 -7 4.19 2.70 0 0 8 1.27 2.70 0 0 -8 2.94 3.11 0 0 -8 6.43 3.67 0 0 -8 7.55 3.60 0 0 8 11.99 4.14 0 0 -8 4.25 3.24 0 0 8 4.06 2.62 0 0 8 8.86 3.62 0 0 9 29.47 6.48 0 0 -9 29.26 7.26 0 0 -9 23.19 5.74 0 0 9 27.84 6.39 0 0 -9 37.50 7.55 0 0 9 28.35 6.56 0 0 9 25.06 6.02 0 0 10 8.17 4.22 0 0 10 3.20 3.08 0 0 -10 8.77 4.53 0 0 10 1.65 2.47 0 0 -10 1.56 2.33 0 0 10 1.49 2.56 0 0 10 1.64 3.15 0 0 -10 1.74 3.36 0 0 -11 575.85 38.49 0 0 -11 617.13 39.07 0 0 -11 569.21 39.13 0 0 11 485.99 37.37 0 0 11 541.73 38.19 0 0 -11 559.53 39.15 0 0 11 568.88 38.52 0 0 -11 630.75 39.63 0 0 -11 574.56 38.13 0 0 11 585.50 38.58 0 0 12 23.08 5.59 0 0 12 18.33 5.23 0 0 -12 14.85 5.20 0 0 -12 19.76 5.40 0 0 -12 20.63 5.73 0 0 13 39.15 6.42 0 0 -13 61.36 7.71 0 0 -13 41.20 6.46 0 0 -13 57.23 7.17 0 0 14 72.07 6.42 0 0 -14 77.63 6.81 0 0 -14 66.14 6.20 0 -1 14 0.57 1.97 0 1 -14 1.65 1.96 0 1 -14 -0.58 1.72 0 1 -14 -0.48 1.77 0 -1 13 5.89 3.24 0 -1 13 6.81 3.56 0 1 -13 4.71 3.37 0 1 -13 1.90 2.85 0 1 -13 2.09 3.00 0 1 -12 1.42 2.74 0 -1 12 2.38 2.90 0 1 -12 1.45 3.54 0 1 -12 -1.42 3.67 0 1 -12 1.31 3.19 0 1 -12 3.09 3.52 0 1 -11 4.55 4.33 0 1 -11 -1.75 3.98 0 -1 11 1.68 2.89 0 -1 11 3.11 3.54 0 1 -11 1.77 3.05 0 1 -11 1.66 3.51 0 1 -11 -1.62 3.41 0 -1 10 66.00 10.16 0 -1 10 52.95 9.17 0 1 -10 54.18 9.57 0 1 -10 63.26 10.07 0 -1 10 63.77 9.96 0 1 -10 49.92 9.62 0 -1 9 339.57 26.14 0 1 -9 356.59 26.54 0 1 -9 313.53 26.20 0 -1 9 337.85 24.84 0 1 -9 341.27 27.24 0 -1 9 341.46 25.86 0 1 -9 357.34 27.32 0 -1 9 367.68 27.55 0 1 -9 395.92 28.39 0 -1 8 2.70 2.86 0 1 -8 5.67 3.46 0 -1 8 6.23 3.87 0 -1 8 6.17 3.36 0 1 -8 4.26 3.24 0 -1 8 1.12 2.37 0 1 -8 3.85 3.32 0 1 -8 9.05 4.50 0 1 -7 849.26 49.91 0 -1 7 903.23 49.92 0 -1 7 832.28 50.30 0 -1 7 893.92 49.71 0 1 -7 907.53 51.01 0 -1 7 862.05 48.86 0 1 -6 67.52 7.78 0 -1 6 68.80 8.16 0 -1 6 58.15 7.15 0 1 -6 80.14 8.63 0 -1 6 66.91 7.30 0 -1 5 158.58 12.35 0 1 -5 161.44 12.59 0 1 -5 164.10 12.54 0 -1 5 151.18 11.69 0 -1 5 165.18 11.62 0 -1 4 3047.19 171.91 0 -1 4 3148.74 173.32 0 1 -4 3065.84 172.86 0 1 -4 3281.33 169.34 0 -1 4 3144.39 170.78 0 -1 4 3685.44 171.06 0 -1 4 3269.40 159.77 0 -1 3 1142.27 70.63 0 -1 3 1324.47 68.56 0 1 -3 1273.12 68.12 0 -1 3 1185.07 69.30 0 1 -2 9.82 2.85 0 -1 2 10.06 3.56 0 -1 2 13.17 3.15 0 1 -2 11.73 4.53 0 1 -1 889.51 47.77 0 1 -1 908.48 47.97 0 1 -1 948.39 48.19 0 1 0 264.88 14.02 0 1 0 221.45 14.29 0 1 0 252.83 14.22 0 1 1 613.04 33.24 0 1 1 588.94 35.54 0 -1 -1 614.63 33.95 0 1 1 650.31 33.32 0 -1 -1 633.11 33.54 0 1 1 575.52 33.20 0 1 2 398.57 27.26 0 -1 -2 422.66 26.79 0 1 2 385.10 26.70 0 1 2 430.53 29.45 0 -1 -2 448.91 27.89 0 1 3 3.13 4.47 0 -1 -3 1.97 4.48 0 -1 -3 2.77 3.37 0 1 3 1.66 4.30 0 -1 -3 -1.66 3.77 0 -1 -4 60.33 6.16 0 1 4 58.91 11.06 0 -1 -4 83.72 12.32 0 -1 -4 62.24 11.98 0 1 4 67.54 6.23 0 1 4 65.34 12.70 0 -1 -4 54.57 11.82 0 1 5 32.94 4.88 0 1 5 30.29 4.66 0 1 5 19.20 4.28 0 -1 -5 37.77 5.50 0 -1 -5 45.52 5.48 0 -1 -5 44.21 5.33 0 -1 -6 803.59 43.75 0 -1 -6 772.82 42.96 0 1 6 719.22 43.45 0 -1 -6 780.59 44.40 0 1 6 736.83 43.42 0 1 6 748.92 43.23 0 1 6 804.86 43.78 0 1 6 775.12 43.12 0 -1 -7 663.63 37.02 0 1 7 646.28 37.05 0 1 7 545.71 36.37 0 -1 -7 558.14 36.65 0 1 7 609.21 36.82 0 1 7 583.06 36.31 0 1 7 573.64 35.94 0 1 8 436.85 29.92 0 -1 -8 472.27 31.01 0 1 8 450.52 30.42 0 1 8 439.10 30.00 0 -1 -8 413.22 29.21 0 -1 -8 423.42 31.78 0 -1 -8 412.60 30.16 0 1 8 436.23 30.01 0 -1 -9 13.15 5.16 0 1 9 10.54 4.17 0 -1 -9 14.08 4.91 0 -1 -9 17.39 5.50 0 1 9 12.34 4.47 0 1 9 25.25 6.18 0 -1 -10 5.20 3.68 0 1 10 12.52 4.28 0 -1 -10 17.10 5.37 0 -1 -10 8.85 4.04 0 1 10 8.27 4.29 0 1 10 6.35 3.88 0 1 10 4.74 3.35 0 1 10 6.46 3.70 0 -1 -10 8.16 4.23 0 1 10 8.27 4.29 0 -1 -10 6.56 3.76 0 1 10 22.14 6.23 0 -1 -11 214.24 19.80 0 1 11 196.75 18.50 0 1 11 203.05 19.20 0 -1 -11 190.76 18.68 0 -1 -11 214.17 18.61 0 1 11 220.71 19.92 0 1 12 -2.66 3.03 0 -1 -12 2.74 3.34 0 -1 -12 -1.26 3.08 0 -1 -12 -1.08 2.62 0 -1 -13 3.11 2.08 0 -1 -13 3.46 2.79 0 -1 -13 0.83 2.57 0 -1 -14 8.96 2.20 0 2 -14 20.34 4.16 0 -2 14 21.18 3.98 0 -2 14 17.54 3.16 0 2 -14 18.76 3.65 0 2 -13 201.82 16.86 0 2 -13 173.72 14.77 0 2 -13 210.50 17.11 0 -2 13 201.68 16.57 0 2 -13 173.19 16.38 0 -2 13 209.99 16.05 0 -2 13 180.13 15.57 0 2 -12 -1.54 2.97 0 -2 12 1.45 3.05 0 -2 12 -1.31 2.51 0 2 -12 -1.54 3.98 0 -2 12 1.25 3.05 0 2 -12 -1.52 2.93 0 2 -12 1.49 3.62 0 2 -12 -1.25 3.05 0 2 -11 362.81 27.40 0 2 -11 379.80 29.03 0 -2 11 357.32 28.45 0 2 -11 384.46 29.61 0 -2 11 340.78 27.05 0 2 -11 384.86 29.56 0 2 -11 366.58 28.49 0 -2 11 365.05 28.02 0 -2 11 356.29 27.10 0 -2 10 153.50 16.12 0 2 -10 172.34 17.39 0 2 -10 172.21 17.88 0 -2 10 195.52 17.99 0 -2 10 182.29 17.81 0 -2 9 229.39 18.96 0 2 -9 202.88 19.51 0 2 -9 256.06 21.44 0 -2 9 214.03 19.29 0 2 -9 263.79 20.82 0 2 -9 203.75 19.35 0 -2 9 204.39 18.87 0 -2 9 225.41 20.03 0 2 -9 219.26 20.20 0 2 -8 583.25 38.45 0 -2 8 577.50 37.90 0 2 -8 612.86 38.92 0 -2 8 630.54 37.99 0 -2 8 583.65 37.77 0 -2 8 634.83 39.37 0 2 -8 661.97 40.10 0 -2 7 122.22 12.03 0 -2 7 136.34 12.18 0 2 -7 132.05 12.80 0 2 -7 123.58 12.63 0 -2 7 153.38 13.51 0 -2 7 130.25 12.14 0 2 -6 159.26 13.49 0 2 -6 156.63 13.53 0 2 -6 183.79 14.50 0 -2 6 172.16 12.75 0 2 -5 66.42 7.26 0 -2 5 65.70 6.53 0 2 -5 66.41 7.48 0 -2 4 6.86 5.92 0 2 -4 9.05 5.51 0 -2 4 2.11 4.82 0 -2 3 1990.96 108.66 0 2 -3 1937.31 109.00 0 -2 3 2160.05 110.71 0 -2 2 1.08 3.09 0 -2 2 1.06 2.73 0 2 -2 1.06 3.15 0 -2 2 2.96 2.69 0 2 -2 8.67 4.07 0 -2 1 451.54 25.18 0 -2 1 448.76 24.79 0 2 -1 448.39 25.05 0 -2 1 451.49 26.48 0 -2 1 441.65 24.50 0 2 -1 396.55 26.04 0 2 0 3.61 2.78 0 2 0 1.24 1.68 0 2 0 0.44 0.86 0 -2 0 4.83 2.26 0 2 0 0.54 1.82 0 -2 0 2.15 2.69 0 2 1 424.06 24.95 0 -2 -1 394.55 28.06 0 -2 -1 433.43 23.66 0 2 1 452.65 26.85 0 -2 -1 406.61 24.87 0 2 1 383.36 27.83 0 2 1 407.37 23.26 0 2 2 7137.90 337.32 0 2 2 6632.20 336.45 0 2 2 6442.92 342.55 0 -2 -2 6875.03 337.19 0 2 2 7010.25 338.97 0 2 3 1628.30 98.80 0 -2 -3 1539.43 98.14 0 2 3 1684.19 93.25 0 2 3 1738.47 92.95 0 -2 -3 1861.48 95.21 0 -2 -4 2246.45 104.81 0 2 4 2052.66 113.70 0 -2 -4 2131.96 117.16 0 2 4 1946.36 114.72 0 2 4 1972.87 102.82 0 -2 -4 2090.59 103.88 0 -2 -4 1997.76 104.31 0 2 5 0.73 1.78 0 -2 -5 1.53 1.98 0 -2 -5 2.47 2.46 0 -2 -5 1.54 1.99 0 2 5 6.78 2.60 0 2 6 11.94 3.60 0 -2 -6 21.10 4.42 0 -2 -6 14.52 3.87 0 -2 -6 8.64 3.28 0 -2 -6 17.07 3.87 0 2 6 11.30 3.40 0 2 6 13.14 3.58 0 2 7 393.09 26.75 0 2 7 389.29 27.05 0 2 7 395.42 26.82 0 2 7 400.57 27.28 0 -2 -7 404.59 27.13 0 -2 -7 428.26 26.71 0 2 7 373.38 26.61 0 -2 -7 374.37 26.35 0 2 7 416.65 27.06 0 -2 -7 384.70 26.82 0 2 8 347.13 25.69 0 -2 -8 287.65 24.35 0 2 8 339.40 25.25 0 -2 -8 310.42 24.10 0 2 8 378.77 26.25 0 2 8 366.97 25.62 0 -2 -8 357.40 26.41 0 -2 -9 14.77 4.64 0 2 9 14.33 5.18 0 2 9 14.19 5.48 0 -2 -9 8.20 5.14 0 -2 -9 22.95 5.62 0 2 9 18.22 5.44 0 2 10 51.22 9.09 0 2 10 47.89 8.94 0 -2 -10 58.37 9.83 0 -2 -10 60.32 10.07 0 2 10 65.16 9.90 0 -2 -10 51.88 9.27 0 2 11 1.59 3.36 0 -2 -11 -1.47 3.58 0 -2 -11 5.21 3.88 0 -2 -11 4.57 4.15 0 2 11 1.40 3.18 0 2 11 -3.03 3.45 0 2 12 2.41 2.75 0 -2 -12 -2.31 3.44 0 -2 -12 -0.93 2.65 0 -2 -12 1.08 3.47 0 -2 -13 128.49 10.84 0 2 13 132.09 10.41 0 -2 -13 131.27 11.09 0 3 -14 57.00 6.29 0 -3 14 75.43 7.45 0 -3 14 68.27 6.80 0 -3 14 66.60 6.55 0 -3 14 77.86 7.82 0 3 -13 16.19 4.93 0 -3 13 6.86 3.18 0 -3 13 14.62 4.24 0 3 -13 5.87 3.81 0 -3 13 11.49 4.04 0 3 -13 3.49 2.86 0 -3 12 -1.32 3.42 0 3 -12 1.65 3.48 0 -3 12 -1.29 3.51 0 3 -12 -1.49 3.14 0 3 -12 1.58 2.72 0 3 -12 -1.50 4.08 0 3 -11 84.41 12.03 0 3 -11 126.00 14.50 0 -3 11 98.41 11.85 0 -3 11 95.53 12.32 0 3 -11 101.14 13.81 0 3 -11 88.59 12.53 0 -3 11 107.50 13.19 0 -3 11 102.69 12.47 0 3 -10 41.02 7.85 0 -3 10 29.98 6.56 0 3 -10 26.59 7.12 0 3 -10 26.65 6.70 0 -3 10 19.84 5.73 0 3 -9 236.93 20.81 0 -3 9 216.75 19.85 0 3 -9 290.78 22.69 0 3 -9 238.72 21.31 0 -3 9 264.33 20.11 0 3 -9 238.50 20.74 0 3 -8 6.80 3.53 0 -3 8 7.94 3.96 0 3 -8 6.97 3.62 0 -3 8 4.75 3.41 0 3 -8 5.18 3.36 0 -3 8 10.66 3.69 0 -3 7 1044.17 59.12 0 3 -7 1026.09 59.58 0 3 -7 1049.42 59.24 0 -3 7 1045.71 57.90 0 -3 7 1022.07 58.41 0 -3 7 1136.58 60.11 0 3 -7 1162.62 60.72 0 -3 6 304.72 22.24 0 3 -6 371.90 23.54 0 3 -6 349.54 23.36 0 -3 6 329.72 22.68 0 3 -6 343.04 22.76 0 -3 6 377.66 22.19 0 -3 5 1264.08 65.56 0 3 -5 1246.25 65.70 0 3 -5 1227.06 65.00 0 -3 4 1158.07 68.56 0 -3 4 1094.80 67.84 0 3 -4 1010.31 67.47 0 -3 3 327.57 26.20 0 3 -3 335.55 25.94 0 3 -3 279.42 25.18 0 -3 3 356.34 26.69 0 -3 3 333.46 25.38 0 3 -2 2848.88 142.43 0 -3 2 2934.94 142.00 0 3 -2 2710.68 143.90 0 -3 2 2624.26 143.20 0 -3 1 58.40 5.32 0 -3 1 55.02 5.33 0 3 -1 50.90 7.13 0 -3 1 65.52 6.79 0 -3 1 54.00 7.49 0 3 0 1193.71 62.74 0 -3 0 1223.06 64.65 0 3 0 1142.22 63.24 0 -3 0 1177.36 62.48 0 3 0 1111.35 63.97 0 3 1 10.54 4.26 0 -3 -1 8.21 4.02 0 3 1 7.40 3.31 0 3 1 11.48 2.16 0 3 1 13.15 5.31 0 -3 -1 13.12 3.54 0 3 1 6.03 1.56 0 3 2 334.55 25.81 0 3 2 299.01 22.80 0 -3 -2 258.35 26.65 0 3 2 337.90 21.34 0 3 2 344.02 26.93 0 3 2 350.21 21.78 0 3 2 265.32 27.09 0 -3 -3 47.03 6.00 0 -3 -3 44.83 5.76 0 -3 -3 51.35 5.60 0 3 3 56.09 8.80 0 3 3 44.36 7.60 0 3 3 48.04 8.49 0 3 3 55.92 10.87 0 -3 -4 5.96 2.55 0 -3 -4 7.86 2.63 0 3 4 2.98 2.58 0 3 5 -0.87 2.11 0 3 5 3.74 4.56 0 -3 -5 2.92 1.88 0 -3 -5 0.71 1.36 0 -3 -5 4.01 2.59 0 -3 -5 0.88 2.01 0 -3 -5 0.74 1.68 0 3 5 1.44 1.39 0 3 6 766.42 45.52 0 -3 -6 792.30 44.85 0 -3 -6 797.07 44.52 0 -3 -6 803.25 46.46 0 -3 -6 740.28 45.37 0 -3 -6 811.95 44.92 0 -3 -7 27.56 6.01 0 3 7 24.72 5.75 0 3 7 21.64 5.41 0 3 7 36.68 6.66 0 3 8 176.51 16.58 0 -3 -8 151.84 15.84 0 3 8 171.12 16.66 0 3 8 157.95 15.70 0 3 9 1113.13 67.32 0 -3 -9 1326.62 68.91 0 3 9 1153.90 67.87 0 3 9 1091.65 66.22 0 -3 -9 1121.51 67.28 0 3 10 137.52 14.35 0 -3 -10 126.23 14.38 0 -3 -10 108.14 13.65 0 3 10 127.25 14.32 0 -3 -11 50.94 8.11 0 3 11 43.07 7.71 0 -3 -12 2.79 3.58 0 -3 -12 -2.98 3.08 0 -3 -12 5.06 3.08 0 -3 -13 71.62 6.59 0 -3 -13 64.66 6.23 0 3 13 53.43 5.22 0 4 -14 30.24 4.89 0 -4 14 25.87 4.51 0 -4 14 19.07 4.02 0 -4 14 18.75 3.24 0 -4 14 18.75 3.82 0 -4 13 207.67 16.22 0 4 -13 182.53 16.25 0 4 -13 184.95 15.85 0 -4 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288.40 22.75 0 -5 -1 254.69 17.29 0 -5 -1 249.70 17.69 0 -5 -1 249.26 17.12 0 5 2 1334.32 66.73 0 5 2 1196.61 78.81 0 -5 -2 1311.16 67.29 0 -5 -2 1183.29 67.84 0 -5 -2 1265.00 67.20 0 5 3 738.15 54.61 0 5 3 667.08 38.83 0 -5 -3 705.00 39.83 0 5 4 37.98 6.08 0 5 4 57.91 6.89 0 -5 -4 46.88 7.57 0 -5 -4 54.32 7.69 0 5 5 45.69 6.95 0 -5 -5 35.29 7.23 0 -5 -5 35.88 6.54 0 5 6 46.19 7.75 0 5 6 27.86 6.43 0 -5 -6 50.47 8.61 0 -5 -6 51.02 8.04 0 5 7 3.03 2.94 0 5 7 9.33 4.03 0 -5 -7 6.76 4.13 0 -5 -7 12.34 4.61 0 -5 -8 43.17 8.95 0 -5 -8 56.73 9.42 0 -5 -8 46.05 9.04 0 5 8 41.63 8.07 0 5 8 39.27 8.03 0 5 8 57.69 9.28 0 -5 -8 61.02 9.78 0 -5 -8 49.56 9.40 0 -5 -8 64.81 10.22 0 -5 -8 72.64 10.12 0 -5 -9 94.79 11.98 0 -5 -9 88.10 12.05 0 -5 -9 91.50 12.53 0 -5 -9 86.40 11.52 0 -5 -9 103.53 12.56 0 5 9 101.17 12.60 0 -5 -10 21.60 6.14 0 -5 -10 28.43 6.35 0 -5 -10 28.15 6.37 0 5 10 25.98 5.86 0 -5 -10 33.51 6.70 0 -5 -10 29.70 6.17 0 -5 -11 221.39 16.78 0 -5 -11 218.22 16.36 0 -5 -11 214.28 16.56 0 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38.68 8.47 0 -6 -6 58.04 9.31 0 6 6 40.77 7.71 0 6 6 60.42 9.15 0 -6 -7 682.98 44.27 0 -6 -7 638.17 44.95 0 -6 -7 699.01 43.55 0 6 7 681.26 44.33 0 -6 -7 638.85 45.11 0 -6 -7 803.50 46.36 0 -6 -7 722.58 45.59 0 -6 -7 654.46 45.17 0 -6 -7 717.33 43.74 0 -6 -7 675.59 44.21 0 -6 -8 1.72 3.32 0 -6 -8 5.52 3.57 0 -6 -8 3.40 5.28 0 -6 -8 4.08 4.06 0 -6 -8 6.56 4.24 0 -6 -8 10.05 5.00 0 6 8 3.11 3.55 0 -6 -9 68.81 10.24 0 -6 -9 87.83 11.15 0 -6 -9 75.27 9.87 0 -6 -9 69.76 10.18 0 -6 -9 71.97 9.99 0 -6 -10 72.93 9.71 0 -6 -10 105.98 10.64 0 -6 -10 92.03 10.55 0 -6 -10 95.93 10.66 0 -6 -10 98.35 10.19 0 -6 -11 49.51 6.05 0 -6 -11 53.31 6.37 0 -6 -11 49.78 5.73 0 7 -14 41.70 4.88 0 7 -14 26.05 3.46 0 -7 14 35.85 4.46 0 7 -13 19.08 4.67 0 7 -13 24.17 5.29 0 -7 13 24.68 4.39 0 7 -13 29.03 5.04 0 7 -13 30.50 5.28 0 -7 13 34.19 5.55 0 7 -12 60.27 9.55 0 -7 12 83.10 9.53 0 7 -12 79.24 10.35 0 7 -12 82.66 9.68 0 7 -12 73.69 10.06 0 7 -12 83.06 10.70 0 -7 12 100.77 11.00 0 7 -11 629.85 39.75 0 -7 11 511.72 35.25 0 -7 11 574.56 37.66 0 7 -11 576.77 38.28 0 -7 11 562.03 35.73 0 7 -11 539.43 37.42 0 7 -11 556.70 37.60 0 7 -11 568.61 37.94 0 7 -10 23.08 6.73 0 7 -10 45.40 8.87 0 7 -10 39.62 7.97 0 7 -10 27.67 7.99 0 -7 10 36.89 7.71 0 7 -10 43.36 8.78 0 -7 10 38.68 7.60 0 -7 10 40.16 7.34 0 -7 10 34.17 6.67 0 7 -9 51.43 8.68 0 7 -9 61.36 9.61 0 -7 9 56.43 8.62 0 7 -8 64.25 9.45 0 -7 8 56.09 8.52 0 7 -8 68.93 9.78 0 -7 8 64.87 8.87 0 -7 7 46.65 7.65 0 7 -7 73.96 9.85 0 7 -7 65.84 9.18 0 7 -7 54.12 7.85 0 -7 7 42.48 6.86 0 -7 6 155.60 14.77 0 7 -6 161.08 15.65 0 -7 6 196.30 15.89 0 7 -6 186.91 16.00 0 7 -6 176.36 15.25 0 -7 5 829.29 48.00 0 7 -5 885.84 48.89 0 7 -5 799.02 46.98 0 -7 4 169.67 14.60 0 7 -4 169.35 14.78 0 7 -4 161.73 13.36 0 7 -4 180.90 14.69 0 7 -3 96.65 9.65 0 7 -3 93.52 10.06 0 -7 3 93.30 9.93 0 7 -3 90.00 9.84 0 7 -2 95.83 9.72 0 -7 2 78.05 8.80 0 7 -2 88.31 9.43 0 -7 2 81.56 9.18 0 7 -1 3.65 2.09 0 -7 1 4.51 2.34 0 -7 1 3.01 2.87 0 -7 1 1.97 2.08 0 -7 1 7.88 2.72 0 -7 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2.97 3.96 -4 -8 13 11.73 3.35 4 8 -13 12.89 4.13 4 8 -13 3.64 2.73 -4 -8 12 260.70 19.56 4 8 -12 291.16 21.66 4 8 -12 286.92 20.73 -4 -8 12 241.09 19.99 4 8 -12 298.99 21.94 -4 -8 12 283.30 20.38 -4 -8 12 272.61 20.08 4 8 -12 300.64 21.91 -4 -8 11 21.11 5.41 -4 -8 11 12.97 4.50 -4 -8 11 17.18 4.90 4 8 -11 28.46 6.96 4 8 -11 18.61 5.84 4 8 -11 19.23 5.97 -4 -8 11 16.57 4.96 -4 -8 11 14.56 4.63 -4 -8 10 131.98 13.58 -4 -8 10 164.91 15.44 4 8 -10 122.68 13.79 4 8 -10 104.24 12.92 4 8 -10 135.14 14.90 4 8 -10 113.13 13.71 -4 -8 10 120.71 13.14 -4 -8 10 114.55 13.16 -4 -8 10 136.86 13.74 4 8 -10 119.55 13.97 4 8 -9 13.39 5.59 4 8 -9 4.28 3.70 -4 -8 9 3.03 2.93 4 8 -9 8.23 4.92 -4 -8 9 4.16 3.97 -4 -8 9 3.11 3.29 4 8 -9 9.80 4.46 -4 -8 9 9.85 5.01 -4 -8 9 6.95 4.16 4 8 -8 31.81 7.50 4 8 -8 25.59 6.74 4 8 -8 26.53 6.88 -4 -8 8 33.78 7.03 4 8 -8 36.39 7.94 -4 -8 8 29.80 6.75 -4 -8 8 41.37 7.65 4 8 -8 23.76 6.54 -4 -8 8 28.44 6.76 -4 -8 8 27.52 6.76 4 8 -8 43.66 7.67 4 8 -7 1348.57 76.68 -4 -8 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3.09 2.66 7 7 -4 3.39 3.27 7 7 -3 50.21 9.04 7 7 -3 39.53 7.88 7 7 -3 50.63 9.02 -7 -7 3 31.20 6.60 -7 -7 3 36.60 7.30 -7 -7 3 31.39 6.97 -7 -7 3 40.82 7.64 -7 -7 3 35.21 7.32 7 7 -3 34.21 7.38 7 7 -2 14.98 4.70 7 7 -2 17.58 4.99 7 7 -2 17.72 5.73 -7 -7 2 16.97 5.32 -7 -7 2 17.34 5.67 -7 -7 2 15.28 5.90 7 7 -2 6.48 4.00 -7 -7 2 20.86 5.53 -7 -7 2 9.80 4.28 7 7 -2 14.25 5.28 -7 -7 2 20.89 5.65 -7 -7 1 22.31 5.84 -7 -7 1 23.06 5.93 -7 -7 1 24.93 5.78 7 7 -1 17.84 5.38 -7 -7 1 18.57 5.09 7 7 -1 20.27 5.31 7 7 -1 18.54 5.33 -7 -7 1 34.15 6.56 -7 -7 0 150.94 13.72 -7 -7 0 126.70 13.01 7 7 0 134.81 14.05 -7 -7 0 125.01 12.82 -7 -7 0 120.69 12.89 7 7 0 142.57 13.90 7 7 0 136.57 12.94 7 7 0 126.27 13.61 -7 -7 0 148.13 13.84 7 7 1 65.67 8.71 -7 -7 -1 52.07 7.46 -7 -7 -1 51.08 7.43 -7 -7 -1 64.21 8.33 7 7 1 39.78 6.96 -7 -7 -1 53.97 7.45 7 7 2 9.06 3.18 -7 -7 -2 14.88 3.63 7 7 2 14.03 4.16 -7 -7 -2 18.84 4.35 7 7 3 1.30 2.45 7 7 3 0.52 1.61 -7 -7 -3 1.24 2.00 7 8 -13 15.31 2.83 -7 -8 13 12.95 2.73 7 8 -13 18.12 3.23 7 8 -12 8.90 3.04 -7 -8 12 12.54 3.45 7 8 -12 13.10 3.45 -7 -8 11 57.57 7.15 -7 -8 11 44.88 5.77 7 8 -11 50.56 6.62 7 8 -11 51.54 6.75 7 8 -11 62.84 7.82 7 8 -11 46.09 6.74 7 8 -10 127.29 12.71 7 8 -10 139.51 11.78 7 8 -10 138.92 12.61 -7 -8 10 131.97 12.49 7 8 -10 123.72 11.96 -7 -8 10 132.16 12.37 -7 -8 10 115.77 10.45 7 8 -10 125.00 11.89 7 8 -9 255.70 19.50 -7 -8 9 238.19 19.09 -7 -8 9 224.19 17.03 -7 -8 9 248.23 19.06 7 8 -9 233.75 18.52 7 8 -9 266.40 19.99 -7 -8 9 200.44 17.85 7 8 -8 -1.02 2.63 7 8 -8 3.69 2.99 -7 -8 8 1.30 2.24 7 8 -8 -2.52 4.06 -7 -8 8 -0.94 2.92 -7 -8 8 -1.17 2.84 -7 -8 8 -3.62 4.02 7 8 -7 72.64 9.94 -7 -8 7 78.83 9.93 7 8 -7 76.77 10.53 -7 -8 7 82.16 10.14 7 8 -7 53.03 8.09 -7 -8 7 63.87 9.48 7 8 -7 66.64 9.07 -7 -8 7 66.54 8.50 -7 -8 7 54.80 8.29 7 8 -7 78.10 10.52 7 8 -6 5.95 3.63 7 8 -6 1.37 3.13 -7 -8 6 -5.57 6.00 -7 -8 6 10.42 4.77 7 8 -6 10.02 4.28 -7 -8 6 7.77 4.99 7 8 -6 10.68 4.15 -7 -8 6 12.58 4.52 7 8 -6 5.69 4.07 7 8 -5 271.15 22.00 7 8 -5 255.53 21.48 -7 -8 5 260.44 21.48 7 8 -5 255.75 21.70 -7 -8 5 298.47 22.79 7 8 -5 280.90 22.32 7 8 -5 264.26 22.26 7 8 -4 315.78 23.60 -7 -8 4 333.98 24.30 -7 -8 4 344.00 24.53 7 8 -4 270.08 23.70 -7 -8 4 305.89 22.62 7 8 -4 297.22 24.33 -7 -8 4 321.04 24.41 7 8 -4 323.09 24.37 -7 -8 3 51.16 7.34 7 8 -3 49.89 8.26 7 8 -3 42.41 7.86 -7 -8 3 53.58 8.37 -7 -8 3 55.02 7.78 7 8 -3 49.40 8.27 -7 -8 3 58.64 8.74 -7 -8 3 58.08 8.65 -7 -8 2 -1.00 2.59 7 8 -2 -1.37 2.89 -7 -8 2 2.14 2.06 7 8 -2 1.23 3.19 -7 -8 2 2.25 3.49 -7 -8 2 7.06 4.18 7 8 -2 2.08 2.54 -7 -8 1 45.16 6.65 -7 -8 1 49.54 6.70 -7 -8 1 49.66 7.51 7 8 -1 35.75 6.44 7 8 0 110.52 10.03 7 8 0 95.51 10.51 -7 -8 0 91.92 9.93 -7 -8 0 97.85 10.03 -7 -8 0 115.06 10.13 -7 -8 0 102.51 9.82 7 8 1 4.44 2.92 -7 -8 -1 0.66 2.13 -7 -8 -1 -1.30 2.68 -7 -8 -2 15.60 2.92 7 8 2 13.17 2.86 -7 -8 -2 19.32 3.14 7 9 -12 161.56 10.77 -7 -9 12 140.62 10.07 7 9 -12 145.07 9.93 7 9 -11 138.68 11.19 7 9 -11 154.07 10.86 7 9 -11 138.59 10.32 -7 -9 11 153.87 11.24 -7 -9 11 126.00 10.24 7 9 -10 56.42 6.05 7 9 -10 57.40 7.05 7 9 -10 59.13 6.48 7 9 -10 44.53 6.24 -7 -9 10 44.58 5.54 -7 -9 10 42.06 6.12 -7 -9 10 51.85 6.15 7 9 -9 219.95 16.41 7 9 -9 237.05 17.02 7 9 -9 240.13 17.49 -7 -9 9 225.18 16.15 -7 -9 9 193.62 15.49 7 9 -8 91.11 9.83 7 9 -8 98.63 9.40 7 9 -8 103.79 10.69 7 9 -8 105.14 11.08 -7 -9 8 97.36 10.07 7 9 -7 118.16 12.04 7 9 -7 161.28 14.38 -7 -9 7 148.92 13.14 7 9 -6 0.91 2.47 -7 -9 6 0.95 3.38 7 9 -6 4.58 3.41 -7 -9 6 -1.05 3.49 7 9 -6 3.46 3.14 7 9 -6 -1.08 3.22 -7 -9 5 -1.96 3.05 7 9 -5 3.25 2.79 7 9 -5 1.14 3.25 7 9 -5 -1.13 3.07 -7 -9 4 114.92 10.99 7 9 -4 94.18 10.18 7 9 -4 112.56 11.39 7 9 -4 92.69 10.68 -7 -9 3 17.78 4.68 7 9 -3 21.95 5.10 7 9 -3 20.27 4.72 7 9 -2 10.95 3.75 -7 -9 2 19.52 5.11 -7 -9 2 15.28 4.13 7 9 -1 51.02 6.33 7 9 -1 52.61 7.05 -7 -9 1 55.34 6.80 -7 -9 1 62.31 7.13 7 9 0 17.16 3.60 -7 -9 0 24.89 3.99 7 10 -10 2.40 1.71 7 10 -10 0.48 1.56 -7 -10 10 1.93 1.91 7 10 -9 15.86 3.42 7 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5.98 -8 12 -3 59.45 6.78 -8 12 -4 3.79 1.64 -8 12 -4 2.23 1.80 8 -11 -8 32.28 3.96 8 -11 -8 30.01 3.99 8 -11 -7 1.39 2.54 8 -11 -6 390.02 24.02 8 -11 -6 376.94 24.85 8 -11 -6 407.15 25.45 8 -11 -5 8.78 4.23 8 -11 -5 7.37 3.58 8 -11 -5 8.06 3.81 8 -11 -5 13.24 3.74 -8 11 5 17.09 4.52 -8 11 4 17.58 4.89 8 -11 -4 13.48 4.34 8 -11 -4 10.46 3.82 -8 11 4 16.87 4.51 8 -11 -4 16.67 5.05 8 -11 -4 20.30 4.62 8 -11 -3 19.70 5.04 -8 11 3 13.52 4.08 8 -11 -3 16.50 5.16 -8 11 3 15.96 4.79 8 -11 -3 18.71 4.64 8 -11 -2 71.57 8.82 -8 11 2 57.37 9.02 8 -11 -2 83.06 9.64 8 -11 -2 65.00 8.67 -8 11 2 48.87 7.84 8 -11 -1 31.54 6.33 8 -11 -1 39.54 5.92 8 -11 -1 45.90 7.40 -8 11 1 33.87 6.37 8 -11 0 126.83 11.81 8 -11 0 108.20 10.53 -8 11 0 120.87 12.03 8 -11 0 90.62 10.95 -8 11 -1 38.83 6.44 8 -11 1 39.25 6.40 -8 11 -1 28.00 6.59 -8 11 -1 28.79 6.22 8 -11 1 32.43 5.59 -8 11 -1 37.11 7.40 8 -11 1 37.67 6.74 -8 11 -2 0.98 2.23 -8 11 -2 1.14 2.19 8 -11 2 1.69 2.31 -8 11 -2 1.12 3.73 -8 11 -2 -1.23 3.52 8 -11 2 1.68 2.90 8 -11 2 2.54 3.34 8 -11 3 55.88 6.69 -8 11 -3 40.65 7.02 8 -11 3 53.42 6.48 8 -11 3 53.18 6.80 8 -11 4 79.12 7.52 -8 11 -4 76.53 8.13 8 -11 4 101.44 8.42 -8 11 -4 93.79 9.84 8 -11 5 101.22 7.57 8 -11 5 120.99 8.71 -8 11 -5 101.03 8.91 8 -10 -9 0.92 1.86 8 -10 -9 -0.57 1.89 8 -10 -8 0.81 2.71 8 -10 -8 1.38 2.84 8 -10 -8 3.13 2.94 8 -10 -8 0.76 2.71 -8 10 8 1.63 2.44 8 -10 -7 0.95 2.95 8 -10 -7 3.94 3.17 8 -10 -7 4.36 3.52 -8 10 7 -3.12 2.69 -8 10 6 14.53 4.59 8 -10 -6 10.99 4.58 8 -10 -6 12.87 4.01 8 -10 -6 19.30 4.84 8 -10 -6 11.56 5.02 8 -10 -6 14.25 5.00 8 -10 -5 49.86 7.77 8 -10 -5 49.34 7.89 8 -10 -5 45.32 6.99 -8 10 5 54.83 8.40 8 -10 -4 100.24 11.57 8 -10 -4 119.49 11.93 -8 10 4 109.57 12.66 -8 10 4 115.87 13.26 -8 10 4 107.20 12.63 -8 10 3 35.38 7.29 8 -10 -3 29.50 6.96 -8 10 3 22.14 5.92 -8 10 3 16.69 5.53 -8 10 3 40.55 7.82 8 -10 -3 21.89 6.17 8 -10 -3 32.25 7.43 -8 10 2 100.27 12.04 8 -10 -2 126.95 13.29 -8 10 2 90.43 11.76 -8 10 2 94.92 12.54 8 -10 -2 114.88 12.11 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21.37 4.72 8 -10 5 15.76 3.78 8 -10 5 24.20 4.25 -8 10 -6 5.13 2.14 8 -10 6 7.38 2.33 8 -10 6 7.36 2.12 8 -9 -10 -1.20 2.42 8 -9 -10 -0.60 2.30 8 -9 -9 279.37 18.30 8 -9 -9 270.46 19.18 8 -9 -9 270.39 18.49 8 -9 -9 276.64 19.42 8 -9 -8 416.86 26.88 -8 9 8 408.00 26.85 8 -9 -8 381.78 25.35 8 -9 -8 411.89 26.65 8 -9 -8 357.63 25.78 8 -9 -7 14.11 4.23 -8 9 7 10.22 4.28 8 -9 -7 8.47 4.06 8 -9 -7 7.51 4.15 8 -9 -7 4.68 3.52 8 -9 -7 12.50 4.59 -8 9 6 19.51 5.29 8 -9 -6 15.90 4.44 8 -9 -6 11.63 4.78 8 -9 -6 13.84 4.53 -8 9 6 17.02 5.22 -8 9 6 16.90 5.20 8 -9 -6 18.03 5.90 8 -9 -5 10.32 5.01 8 -9 -5 13.60 5.28 8 -9 -5 15.82 5.24 8 -9 -5 11.69 4.66 -8 9 5 18.05 5.69 -8 9 5 14.71 4.95 -8 9 5 16.46 5.51 8 -9 -5 12.56 4.76 8 -9 -4 588.45 38.42 -8 9 4 618.86 39.86 8 -9 -4 505.04 36.24 8 -9 -4 628.44 36.84 -8 9 4 521.98 38.28 -8 9 4 523.04 37.52 8 -9 -4 662.75 38.66 8 -9 -4 579.78 38.64 8 -9 -4 526.70 36.27 -8 9 4 582.04 38.52 8 -9 -3 247.27 22.27 -8 9 3 269.31 23.21 -8 9 3 281.65 22.76 8 -9 -3 241.72 21.67 8 -9 -3 251.39 20.31 8 -9 -3 245.95 21.98 -8 9 3 266.01 22.07 -8 9 3 254.80 22.56 -8 9 3 241.16 21.86 8 -9 -3 278.19 22.46 8 -9 -2 19.96 6.64 -8 9 2 12.07 5.38 -8 9 2 13.28 4.98 8 -9 -2 10.37 5.29 8 -9 -2 13.13 4.93 -8 9 2 19.32 5.57 -8 9 2 6.11 3.99 -8 9 2 9.49 4.55 -8 9 2 10.37 4.97 -8 9 1 15.30 5.79 8 -9 -1 8.40 4.56 8 -9 -1 14.70 4.82 8 -9 -1 18.41 5.80 -8 9 1 18.88 6.65 8 -9 -1 21.93 6.65 -8 9 1 16.48 5.54 8 -9 -1 8.79 5.29 -8 9 1 15.54 5.06 8 -9 -1 21.70 5.43 -8 9 1 11.01 5.29 -8 9 1 15.30 5.33 8 -9 0 71.48 9.71 8 -9 0 51.23 9.61 -8 9 0 60.03 9.48 -8 9 0 67.30 10.22 -8 9 0 69.27 10.57 8 -9 0 63.23 9.94 -8 9 0 46.19 9.09 -8 9 0 58.77 9.56 -8 9 0 52.98 8.69 8 -9 0 70.69 9.52 8 -9 0 64.20 10.03 8 -9 0 53.41 8.09 -8 9 0 48.56 8.83 8 -9 1 8.45 4.54 8 -9 1 6.00 3.87 8 -9 1 15.37 5.38 -8 9 -1 11.47 4.89 8 -9 1 1.61 3.10 -8 9 -1 -1.36 2.34 -8 9 -1 2.90 3.06 -8 9 -1 1.62 2.80 8 -9 1 3.83 2.70 -8 9 -1 12.56 5.06 8 -9 1 1.37 2.64 -8 9 -2 148.98 14.93 -8 9 -2 137.95 14.71 -8 9 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3.55 8 -8 -7 1.31 3.20 -8 8 7 3.24 3.42 -8 8 7 3.13 3.81 -8 8 7 1.57 3.02 8 -8 -7 -1.21 4.16 8 -8 -7 2.73 4.08 8 -8 -6 64.27 9.47 8 -8 -6 45.15 8.72 -8 8 6 44.51 8.78 8 -8 -6 51.94 8.36 -8 8 6 58.05 9.33 8 -8 -6 40.85 7.78 -8 8 6 31.52 7.65 -8 8 6 62.54 9.89 8 -8 -6 53.72 8.84 -8 8 5 35.40 7.52 8 -8 -5 27.76 6.35 8 -8 -5 24.39 6.70 -8 8 5 29.02 7.61 8 -8 -5 35.86 7.63 -8 8 5 31.71 7.01 8 -8 -5 16.49 5.78 8 -8 -5 24.63 5.92 -8 8 5 39.10 7.58 8 -8 -5 23.82 6.63 -8 8 4 100.23 12.52 8 -8 -4 122.63 14.21 -8 8 4 119.32 14.57 8 -8 -4 125.91 14.50 -8 8 4 125.75 14.65 8 -8 -4 120.82 13.67 8 -8 -4 124.16 14.53 8 -8 -4 105.60 13.27 8 -8 -4 139.16 15.39 -8 8 3 80.52 12.29 -8 8 3 90.95 13.08 8 -8 -3 88.29 12.38 -8 8 3 125.06 14.35 8 -8 -3 85.50 12.09 -8 8 3 73.11 11.20 8 -8 -3 97.52 13.14 8 -8 -3 101.29 12.96 8 -8 -3 102.19 12.85 8 -8 -3 115.03 13.50 8 -8 -2 177.99 18.39 8 -8 -2 200.25 19.39 -8 8 2 195.00 20.25 -8 8 2 196.05 19.63 8 -8 -2 205.01 19.51 -8 8 2 194.78 18.99 -8 8 2 203.29 19.86 -8 8 2 186.64 18.45 -8 8 2 211.89 20.08 8 -8 -2 211.64 19.60 8 -8 -1 -1.38 3.13 8 -8 -1 -1.20 2.54 8 -8 -1 3.20 4.35 -8 8 1 1.68 2.90 8 -8 -1 2.88 3.51 -8 8 1 -1.77 3.73 8 -8 -1 -3.24 4.18 -8 8 1 -3.70 6.17 -8 8 1 -3.58 4.62 8 -8 -1 1.72 3.30 -8 8 1 -1.68 3.24 -8 8 1 -1.56 2.68 8 -8 -1 3.63 3.13 -8 8 1 1.73 5.58 -8 8 1 1.74 2.99 -8 8 0 443.60 33.34 8 -8 0 519.24 35.24 8 -8 0 470.68 33.32 8 -8 0 490.84 31.77 8 -8 0 431.19 32.62 -8 8 0 485.94 35.05 -8 8 0 496.04 34.50 -8 8 0 409.01 32.56 -8 8 0 426.75 31.47 8 -8 0 449.70 31.93 -8 8 0 448.38 33.01 -8 8 0 440.83 33.11 8 -8 1 47.14 8.41 8 -8 1 43.69 7.74 8 -8 1 41.73 8.20 8 -8 1 39.91 7.25 -8 8 -1 50.70 9.00 -8 8 -1 41.36 8.76 8 -8 1 42.51 8.18 -8 8 -1 39.93 8.07 -8 8 -1 48.72 8.78 8 -8 1 54.18 9.09 -8 8 -1 48.35 8.61 8 -8 1 52.23 9.09 8 -8 2 44.74 7.66 -8 8 -2 41.78 7.93 8 -8 2 34.15 7.04 -8 8 -2 45.04 8.78 -8 8 -2 25.49 6.47 -8 8 -2 46.87 8.49 -8 8 -2 39.27 8.44 8 -8 2 34.89 7.64 8 -8 2 38.31 7.60 8 -8 2 50.72 8.10 -8 8 -2 42.09 8.38 8 -8 2 41.63 7.97 8 -8 3 379.04 27.14 -8 8 -3 368.05 28.43 8 -8 3 338.12 25.53 8 -8 3 398.59 26.76 -8 8 -3 412.75 30.19 -8 8 -3 365.52 27.48 -8 8 -3 358.87 27.32 -8 8 -3 350.04 27.30 -8 8 -4 28.52 6.29 8 -8 4 26.85 5.22 -8 8 -4 33.51 7.03 8 -8 4 34.78 7.17 -8 8 -4 25.17 6.22 -8 8 -4 41.97 8.17 8 -8 4 35.89 6.59 8 -8 5 3.07 2.88 -8 8 -5 1.09 2.96 -8 8 -5 7.42 3.69 -8 8 -5 1.02 2.64 8 -8 5 3.12 2.97 8 -8 5 1.83 2.85 -8 8 -5 2.59 3.87 8 -8 6 3.67 2.58 -8 8 -6 -0.83 2.36 -8 8 -6 2.78 2.32 -8 8 -6 -0.90 2.18 8 -8 6 2.08 2.54 8 -8 6 0.78 2.75 -8 8 -6 1.44 2.05 8 -8 7 38.86 4.42 8 -8 7 48.43 4.66 -8 8 -7 35.77 4.79 8 -8 7 40.32 4.43 -8 8 -7 43.89 5.00 8 -7 -12 150.31 10.01 8 -7 -12 104.95 8.59 8 -7 -11 4.05 2.96 8 -7 -11 1.61 2.60 8 -7 -10 3.33 2.79 8 -7 -10 12.55 4.51 8 -7 -10 7.27 3.27 8 -7 -9 63.53 8.03 -8 7 9 54.23 8.91 8 -7 -9 29.41 6.51 8 -7 -9 59.89 8.48 8 -7 -9 50.01 8.07 8 -7 -8 2.63 3.59 8 -7 -8 7.99 4.18 8 -7 -8 1.34 4.31 -8 7 8 6.68 4.32 8 -7 -8 8.46 4.55 8 -7 -7 -1.47 3.57 8 -7 -7 -1.39 5.48 8 -7 -7 3.81 3.94 8 -7 -7 1.49 3.39 -8 7 7 -1.75 4.26 -8 7 7 3.53 4.55 8 -7 -6 736.63 45.98 -8 7 6 875.87 49.39 8 -7 -6 677.55 45.65 8 -7 -6 667.52 44.25 -8 7 6 762.14 45.92 8 -7 -6 621.91 43.72 8 -7 -6 698.58 44.82 8 -7 -6 717.01 44.45 -8 7 6 730.23 47.32 -8 7 6 735.91 47.31 8 -7 -5 14.16 5.47 8 -7 -5 13.42 5.22 8 -7 -5 8.38 4.83 -8 7 5 5.39 4.11 8 -7 -5 17.09 6.14 -8 7 5 9.13 4.73 -8 7 5 1.81 3.51 8 -7 -5 10.16 4.86 8 -7 -5 13.20 5.33 -8 7 5 3.60 4.12 -8 7 5 13.37 4.63 8 -7 -4 93.17 12.14 8 -7 -4 72.52 10.60 -8 7 4 69.90 11.09 8 -7 -4 66.21 10.40 -8 7 4 73.49 11.61 -8 7 4 70.21 10.80 8 -7 -4 93.47 12.51 -8 7 4 100.26 13.17 8 -7 -4 74.34 10.79 8 -7 -4 67.02 10.56 8 -7 -3 63.97 9.82 -8 7 3 26.78 8.91 8 -7 -3 44.21 8.93 -8 7 3 58.16 10.79 -8 7 3 69.74 10.95 8 -7 -3 54.10 9.52 -8 7 3 71.27 10.81 8 -7 -3 45.16 9.01 8 -7 -3 48.17 8.86 8 -7 -2 181.57 18.09 -8 7 2 183.45 18.99 -8 7 2 186.86 18.73 -8 7 2 176.31 18.07 -8 7 2 151.89 17.29 -8 7 2 143.99 15.89 8 -7 -2 209.21 18.85 8 -7 -2 157.83 16.32 8 -7 -2 147.47 16.99 8 -7 -1 699.33 45.99 -8 7 1 798.00 49.17 8 -7 -1 838.30 50.13 8 -7 -1 700.18 47.07 8 -7 -1 646.89 44.01 8 -7 -1 787.44 48.31 -8 7 1 767.99 49.38 -8 7 1 751.29 48.98 -8 7 1 758.50 48.30 -8 7 1 650.57 47.25 -8 7 1 774.69 46.99 8 -7 -1 844.58 49.62 -8 7 1 751.27 47.90 -8 7 1 767.69 49.18 8 -7 -1 765.59 46.65 8 -7 0 35.52 7.97 -8 7 0 52.66 9.58 -8 7 0 46.69 8.71 -8 7 0 20.98 6.97 8 -7 0 39.17 8.15 -8 7 0 36.26 8.43 -8 7 0 28.07 7.16 8 -7 0 29.83 7.23 8 -7 0 32.40 6.81 8 -7 0 30.01 7.51 8 -7 0 38.18 8.35 -8 7 0 37.12 8.47 8 -7 0 40.56 7.32 8 -7 1 1.70 3.60 -8 7 -1 3.47 3.95 -8 7 -1 5.07 3.85 -8 7 -1 -1.89 3.25 8 -7 1 1.48 3.84 -8 7 -1 -1.58 3.05 8 -7 1 4.58 3.95 8 -7 1 3.99 3.62 8 -7 1 3.04 3.71 -8 7 -1 7.36 4.48 8 -7 1 1.43 3.02 8 -7 2 17.40 5.11 8 -7 2 11.95 4.73 8 -7 2 11.35 5.05 -8 7 -2 14.56 5.04 -8 7 -2 11.95 5.00 -8 7 -2 12.91 5.52 -8 7 -2 14.39 5.38 -8 7 -2 6.35 4.34 8 -7 2 13.70 5.57 -8 7 -2 13.52 6.01 8 -7 2 4.98 4.31 8 -7 2 4.30 3.29 -8 7 -2 1.47 2.87 -8 7 -3 2.90 3.75 -8 7 -3 10.51 5.01 -8 7 -3 10.27 4.20 -8 7 -3 1.71 3.31 -8 7 -3 18.26 6.86 8 -7 3 6.39 3.66 -8 7 -3 4.50 3.18 -8 7 -3 8.01 4.37 -8 7 -4 11.46 5.82 8 -7 4 3.51 3.04 -8 7 -4 1.33 3.46 -8 7 -4 8.00 4.58 8 -7 4 5.33 3.82 -8 7 -4 6.42 4.43 -8 7 -4 13.11 5.03 8 -7 4 7.88 3.61 8 -7 5 92.07 9.37 -8 7 -5 82.42 10.76 8 -7 5 71.28 9.04 -8 7 -5 75.80 9.29 8 -7 5 77.13 9.66 -8 7 -5 92.65 10.94 -8 7 -5 71.51 9.49 -8 7 -5 94.08 11.34 8 -7 6 13.25 3.62 -8 7 -6 27.41 5.07 -8 7 -6 19.47 4.77 8 -7 6 21.62 4.57 -8 7 -6 20.15 4.04 -8 7 -6 26.62 5.32 8 -7 6 20.29 4.30 -8 7 -7 1.72 1.85 8 -7 7 -0.50 1.81 8 -7 7 1.02 2.15 -8 7 -7 0.67 2.17 -8 7 -7 -0.62 1.84 -8 7 -7 -0.71 1.85 8 -7 7 -0.51 1.71 8 -6 -12 -0.69 2.57 8 -6 -12 -1.45 2.33 8 -6 -11 5.04 3.98 8 -6 -11 -0.99 2.83 -8 6 11 -1.02 2.32 8 -6 -10 200.65 16.47 -8 6 10 197.02 16.63 -8 6 10 159.47 16.38 8 -6 -10 169.99 14.42 -8 6 10 142.13 15.02 8 -6 -9 343.28 27.58 -8 6 9 438.18 30.64 -8 6 9 448.70 32.18 8 -6 -9 449.49 30.27 8 -6 -9 475.83 31.00 -8 6 9 436.67 30.53 -8 6 8 270.23 23.12 8 -6 -8 291.34 23.12 8 -6 -8 280.32 21.46 -8 6 8 277.79 23.41 -8 6 8 299.04 24.99 8 -6 -8 267.99 22.34 -8 6 8 300.63 25.35 8 -6 -8 279.06 23.25 -8 6 7 16.90 6.10 8 -6 -7 8.41 4.42 -8 6 7 22.13 6.20 -8 6 7 17.68 5.59 8 -6 -7 18.05 5.70 -8 6 7 23.82 6.31 8 -6 -7 13.80 5.35 8 -6 -7 20.00 6.54 -8 6 6 43.25 9.17 8 -6 -6 48.31 8.86 8 -6 -6 48.55 8.63 -8 6 6 49.85 9.69 8 -6 -6 49.88 8.49 8 -6 -6 46.13 8.36 8 -6 -6 50.75 9.45 -8 6 6 42.67 8.16 -8 6 6 54.27 9.11 8 -6 -6 54.51 9.10 8 -6 -5 18.61 5.99 -8 6 5 9.32 4.84 -8 6 5 5.48 3.88 -8 6 5 13.02 5.09 8 -6 -5 9.69 4.20 -8 6 5 8.82 4.58 -8 6 5 11.23 4.86 8 -6 -5 8.37 4.58 -8 6 4 243.35 21.90 -8 6 4 274.45 23.89 -8 6 4 315.73 25.18 -8 6 4 300.71 24.62 8 -6 -4 251.38 22.94 8 -6 -4 254.61 22.68 -8 6 4 301.68 24.98 8 -6 -4 251.31 22.88 -8 6 3 91.20 11.83 8 -6 -3 104.03 13.47 -8 6 3 90.88 13.20 8 -6 -3 92.39 12.83 -8 6 3 106.48 13.24 8 -6 -3 104.93 13.20 -8 6 3 102.91 13.97 8 -6 -3 97.29 11.78 -8 6 2 51.35 8.26 8 -6 -2 34.63 7.37 -8 6 2 52.57 9.50 8 -6 -2 54.52 9.54 -8 6 2 42.43 8.93 8 -6 -2 41.69 8.06 -8 6 2 51.40 9.74 -8 6 2 48.86 8.46 -8 6 1 36.87 7.18 8 -6 -1 22.29 6.00 -8 6 1 20.68 5.55 -8 6 1 35.67 8.18 -8 6 1 38.22 8.09 8 -6 -1 18.99 5.90 8 -6 -1 44.28 8.85 -8 6 1 31.98 7.22 -8 6 1 16.60 6.67 -8 6 1 24.14 6.48 8 -6 0 159.02 17.03 -8 6 0 153.01 17.33 -8 6 0 159.83 16.51 8 -6 0 181.36 18.35 -8 6 0 131.57 15.13 -8 6 0 162.19 16.20 -8 6 0 180.14 18.53 8 -6 0 147.39 15.79 8 -6 1 82.12 11.30 8 -6 1 94.32 12.73 -8 6 -1 94.71 12.24 -8 6 -1 82.81 11.52 -8 6 -1 111.64 13.88 8 -6 1 91.35 12.20 8 -6 1 98.89 12.16 -8 6 -1 75.74 10.90 8 -6 1 69.43 10.47 -8 6 -1 84.42 12.49 -8 6 -2 283.23 25.16 8 -6 2 305.73 23.64 -8 6 -2 326.53 25.12 8 -6 2 306.09 24.32 8 -6 2 258.48 23.29 -8 6 -2 285.25 23.81 8 -6 2 284.90 23.94 -8 6 -2 258.40 24.48 -8 6 -2 301.64 24.08 8 -6 3 29.61 7.35 -8 6 -3 25.49 7.44 8 -6 3 27.64 5.87 -8 6 -3 28.85 7.07 8 -6 3 39.29 7.77 -8 6 -3 27.47 6.25 -8 6 -3 33.74 7.57 -8 6 -3 29.39 7.87 8 -6 3 28.67 6.89 -8 6 -3 19.82 6.00 -8 6 -4 -1.57 3.30 8 -6 4 -3.22 3.20 -8 6 -4 3.00 4.29 -8 6 -4 1.65 3.48 8 -6 4 -1.39 2.94 -8 6 -5 310.14 23.20 -8 6 -5 267.54 22.51 8 -6 5 294.67 21.08 8 -6 5 314.51 22.71 8 -6 6 -0.68 2.11 8 -6 6 4.19 3.15 8 -6 6 0.92 2.25 -8 6 -6 1.06 2.89 8 -6 6 6.46 3.11 -8 6 -6 5.47 3.77 8 -6 7 75.28 6.86 -8 6 -7 64.21 7.21 8 -6 7 54.57 5.85 -8 6 -7 76.29 7.56 8 -6 7 61.78 6.21 8 -5 -13 115.42 9.21 8 -5 -13 142.02 10.33 8 -5 -12 28.97 5.38 8 -5 -12 24.87 4.99 -8 5 12 12.85 3.83 8 -5 -11 -2.34 3.34 -8 5 11 7.93 3.77 8 -5 -11 -1.13 3.07 -8 5 11 3.89 3.16 -8 5 10 139.38 15.32 8 -5 -10 158.14 15.59 8 -5 -10 161.88 15.38 -8 5 10 158.69 15.92 -8 5 9 10.87 4.70 -8 5 9 11.81 4.83 -8 5 9 5.00 4.33 8 -5 -9 4.48 4.09 8 -5 -9 13.04 4.65 8 -5 -9 6.93 3.79 8 -5 -8 23.89 5.98 -8 5 8 11.21 5.39 8 -5 -8 24.49 6.50 8 -5 -8 14.53 4.75 8 -5 -8 20.60 5.99 -8 5 8 15.49 6.51 -8 5 8 10.42 4.79 -8 5 7 237.05 21.72 -8 5 7 242.19 21.83 8 -5 -7 228.69 20.59 8 -5 -7 257.64 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4 1 37.12 7.47 8 4 2 15.19 4.48 -8 -4 -2 21.00 5.31 8 4 2 20.40 5.65 -8 -4 -2 16.43 4.84 8 4 2 16.97 4.53 -8 -4 -2 26.33 6.27 -8 -4 -2 26.97 5.93 8 4 2 22.85 5.44 8 4 3 59.34 7.96 8 4 3 73.18 8.87 8 4 3 78.12 8.62 -8 -4 -3 61.57 8.24 -8 -4 -3 74.84 8.92 8 4 4 13.88 3.23 -8 -4 -4 11.29 3.29 -8 -4 -4 12.27 3.34 8 5 -14 180.10 12.09 -8 -5 14 183.34 11.52 -8 -5 14 163.04 11.23 -8 -5 13 2.76 2.46 8 5 -13 5.62 3.10 8 5 -13 2.38 2.83 -8 -5 13 4.11 2.71 -8 -5 13 2.60 2.11 8 5 -12 89.76 9.63 8 5 -12 78.13 8.00 -8 -5 12 86.89 9.27 8 5 -12 73.28 9.44 -8 -5 12 70.71 8.78 8 5 -12 74.74 9.34 -8 -5 12 78.25 8.36 8 5 -11 2.45 2.58 -8 -5 11 2.29 2.79 8 5 -11 3.29 3.14 -8 -5 11 2.23 3.47 8 5 -11 2.58 3.68 -8 -5 11 4.02 3.46 -8 -5 11 2.17 3.38 8 5 -11 3.57 3.40 -8 -5 10 9.37 4.43 -8 -5 10 8.57 4.25 8 5 -10 12.90 4.87 -8 -5 10 11.38 4.78 -8 -5 10 14.21 4.62 8 5 -10 17.15 5.11 8 5 -10 14.83 4.82 8 5 -10 7.16 4.31 8 5 -10 12.97 4.58 8 5 -9 266.66 21.76 -8 -5 9 261.19 21.39 -8 -5 9 296.63 22.20 -8 -5 9 300.27 22.46 -8 -5 9 253.84 21.38 8 5 -9 263.67 22.44 8 5 -9 248.30 21.94 8 5 -9 257.68 21.12 -8 -5 8 138.00 14.65 8 5 -8 105.46 12.87 8 5 -8 125.58 12.88 -8 -5 8 115.72 13.20 -8 -5 8 117.52 13.40 -8 -5 8 128.34 13.88 -8 -5 8 105.12 12.72 -8 -5 8 118.70 13.21 8 5 -8 121.86 14.07 8 5 -8 111.85 13.46 8 5 -7 26.11 6.41 -8 -5 7 23.93 6.34 8 5 -7 24.45 6.11 -8 -5 7 31.40 6.84 -8 -5 7 36.27 7.45 -8 -5 7 28.96 6.94 8 5 -7 37.05 7.94 -8 -5 7 29.47 6.66 -8 -5 7 37.14 7.81 8 5 -7 31.50 6.99 8 5 -6 -1.73 2.98 8 5 -6 1.57 3.58 -8 -5 6 4.89 3.71 8 5 -6 4.80 3.37 -8 -5 6 6.44 3.92 -8 -5 6 1.51 3.67 8 5 -6 -1.67 4.55 8 5 -6 1.68 3.55 -8 -5 6 -4.26 4.58 -8 -5 6 6.04 5.20 8 5 -6 2.85 3.25 8 5 -5 10.61 5.06 8 5 -5 3.29 4.27 -8 -5 5 13.07 5.09 8 5 -5 11.96 4.89 -8 -5 5 8.14 4.22 -8 -5 5 3.02 4.12 8 5 -5 4.99 4.31 8 5 -5 12.92 5.40 -8 -5 5 7.13 4.93 -8 -5 5 6.08 5.56 8 5 -5 11.01 4.71 -8 -5 4 533.96 36.08 -8 -5 4 542.40 36.56 8 5 -4 519.32 36.99 -8 -5 4 489.79 35.05 8 5 -4 502.60 35.81 8 5 -4 542.99 35.96 -8 -5 4 565.85 36.34 -8 -5 4 542.53 35.43 8 5 -4 446.97 35.46 -8 -5 4 553.31 36.86 8 5 -4 493.76 36.25 8 5 -3 134.33 14.75 -8 -5 3 105.00 13.07 8 5 -3 106.46 13.68 -8 -5 3 108.79 13.40 -8 -5 3 97.24 12.44 8 5 -3 110.52 13.51 -8 -5 3 122.01 13.91 -8 -5 3 109.10 12.91 8 5 -3 116.84 14.19 8 5 -3 121.90 13.63 -8 -5 2 20.27 5.56 8 5 -2 13.42 5.23 -8 -5 2 25.45 6.59 8 5 -2 18.98 5.51 8 5 -2 12.10 4.72 -8 -5 2 4.02 4.03 8 5 -2 4.58 3.26 8 5 -1 227.85 18.52 -8 -5 1 231.21 19.18 8 5 -1 184.56 18.05 8 5 -1 188.15 17.60 8 5 -1 179.93 16.79 -8 -5 1 182.00 17.57 -8 -5 1 167.33 15.95 -8 -5 1 180.44 16.34 8 5 -1 194.39 18.48 -8 -5 1 170.04 16.28 8 5 0 30.28 6.39 8 5 0 25.78 5.86 8 5 0 12.53 5.37 -8 -5 0 30.05 5.98 8 5 0 26.79 5.89 8 5 0 37.07 7.07 8 5 1 101.80 11.44 -8 -5 -1 128.39 12.48 8 5 1 102.75 11.39 -8 -5 -1 132.15 12.93 -8 -5 -1 116.47 11.79 8 5 1 88.17 11.07 -8 -5 -2 45.67 7.06 8 5 2 72.38 8.31 -8 -5 -2 52.57 7.07 8 5 2 44.52 6.56 8 5 2 68.77 8.38 8 5 2 57.50 7.56 -8 -5 -3 32.54 4.81 -8 -5 -3 28.22 4.87 8 5 3 37.13 5.10 8 5 4 2.09 1.57 -8 -5 -4 -0.80 1.55 -8 -6 13 96.49 7.70 -8 -6 13 81.21 7.38 8 6 -13 101.03 8.60 -8 -6 13 93.15 8.03 -8 -6 12 82.81 8.47 8 6 -12 79.74 7.69 8 6 -12 100.59 9.79 8 6 -12 102.78 9.72 -8 -6 12 84.70 8.80 8 6 -11 112.09 11.50 8 6 -11 135.66 12.21 -8 -6 11 158.05 12.69 8 6 -11 120.98 12.44 8 6 -11 114.32 11.74 -8 -6 11 114.99 11.58 8 6 -10 79.30 9.56 -8 -6 10 86.00 10.27 -8 -6 10 97.22 10.41 -8 -6 10 63.60 8.95 8 6 -10 72.36 9.70 8 6 -10 90.68 9.99 8 6 -10 90.23 10.69 -8 -6 9 3.63 3.76 -8 -6 9 3.56 3.69 -8 -6 9 3.88 2.95 -8 -6 9 2.46 2.60 -8 -6 9 1.20 3.42 8 6 -9 4.16 3.78 8 6 -9 2.53 3.27 8 6 -9 1.33 3.62 8 6 -8 350.27 26.43 -8 -6 8 336.85 26.16 8 6 -8 380.24 25.63 -8 -6 8 372.08 26.51 -8 -6 8 385.06 26.61 -8 -6 8 405.20 27.35 8 6 -8 296.15 25.00 8 6 -8 354.34 27.10 -8 -6 8 333.64 25.54 8 6 -8 371.87 27.04 -8 -6 8 363.22 26.14 8 6 -7 4.02 3.07 -8 -6 7 7.00 3.63 -8 -6 7 7.12 3.69 8 6 -7 9.29 4.63 8 6 -7 9.35 4.66 -8 -6 7 5.32 4.45 -8 -6 7 7.95 4.58 8 6 -7 10.79 4.20 8 6 -6 1.47 3.58 -8 -6 6 -1.36 4.37 8 6 -6 1.50 2.89 -8 -6 6 4.33 3.73 -8 -6 6 2.90 3.94 8 6 -6 -1.63 3.14 8 6 -6 1.55 3.78 -8 -6 6 -1.36 4.21 8 6 -6 2.63 3.20 8 6 -6 -1.56 3.79 8 6 -5 61.34 9.94 -8 -6 5 83.53 11.00 8 6 -5 60.83 9.67 -8 -6 5 80.68 10.51 -8 -6 5 58.01 9.29 8 6 -5 54.52 9.31 -8 -6 5 61.53 9.42 8 6 -5 71.14 10.37 -8 -6 5 72.19 9.89 8 6 -5 64.11 9.82 8 6 -5 59.91 9.78 8 6 -4 7.29 4.36 8 6 -4 7.67 4.19 -8 -6 4 4.55 3.47 8 6 -4 8.17 4.23 -8 -6 4 8.80 4.20 -8 -6 4 4.30 4.10 8 6 -4 4.84 3.94 8 6 -4 4.04 3.68 -8 -6 4 14.81 4.93 -8 -6 4 6.98 4.82 8 6 -4 13.76 5.28 -8 -6 4 10.88 5.12 8 6 -3 7.38 4.70 -8 -6 3 34.02 6.94 8 6 -3 19.96 6.01 8 6 -3 21.08 5.89 8 6 -3 27.24 6.98 -8 -6 3 23.63 5.96 -8 -6 3 21.62 5.65 8 6 -3 23.68 5.98 -8 -6 3 37.08 7.38 8 6 -2 29.31 6.23 -8 -6 2 39.42 6.96 -8 -6 2 29.15 6.26 8 6 -2 33.93 6.96 -8 -6 2 34.93 6.83 8 6 -2 27.08 6.50 -8 -6 2 17.99 5.38 8 6 -1 2.69 3.06 -8 -6 1 5.15 3.13 8 6 -1 -1.28 2.69 -8 -6 1 2.37 3.23 -8 -6 1 -1.06 3.16 8 6 -1 1.18 3.21 -8 -6 1 -1.20 3.10 8 6 -1 -1.35 3.84 -8 -6 0 25.23 5.33 8 6 0 18.63 4.82 -8 -6 0 20.49 5.11 -8 -6 0 14.02 4.33 8 6 0 23.11 4.89 8 6 0 22.43 4.98 8 6 0 23.02 5.44 -8 -6 0 36.32 6.26 8 6 1 85.62 9.47 -8 -6 -1 103.57 10.23 -8 -6 -1 112.02 10.60 8 6 1 97.49 10.02 8 6 2 12.90 3.18 -8 -6 -2 7.75 3.01 8 6 2 7.33 2.39 8 6 2 11.42 3.22 8 6 3 83.17 6.91 8 7 -13 14.38 2.66 8 7 -12 210.22 13.87 -8 -7 12 230.69 14.68 -8 -7 12 235.79 15.27 8 7 -12 237.71 15.51 8 7 -12 242.58 16.00 -8 -7 12 217.86 14.10 8 7 -11 7.69 3.06 -8 -7 11 7.72 3.14 8 7 -11 6.70 3.03 -8 -7 11 13.42 4.04 -8 -7 11 9.17 3.01 8 7 -11 5.33 2.98 8 7 -10 -2.04 3.29 8 7 -10 -1.01 3.02 -8 -7 10 0.92 2.87 -8 -7 10 -1.63 2.98 8 7 -10 1.71 2.66 -8 -7 9 24.89 5.61 8 7 -9 36.99 6.31 8 7 -9 29.68 6.54 -8 -7 9 30.21 6.06 -8 -7 9 26.28 5.37 8 7 -9 35.51 6.31 8 7 -8 36.72 6.18 -8 -7 8 43.59 6.71 -8 -7 8 41.43 7.00 8 7 -8 34.80 6.52 8 7 -8 32.54 6.73 -8 -7 8 41.74 7.01 -8 -7 8 48.36 7.20 8 7 -8 59.05 8.57 8 7 -7 102.69 12.41 -8 -7 7 125.40 12.94 -8 -7 7 112.51 12.21 -8 -7 7 111.87 11.66 8 7 -7 107.19 11.54 -8 -7 7 105.83 12.05 -8 -7 7 119.79 12.00 8 7 -7 122.28 12.27 8 7 -6 247.41 19.97 -8 -7 6 240.50 19.14 8 7 -6 245.50 19.97 -8 -7 6 252.91 20.15 8 7 -6 241.61 18.99 8 7 -6 218.07 19.75 -8 -7 6 244.17 19.81 -8 -7 6 238.96 19.65 -8 -7 6 236.75 19.12 8 7 -6 242.80 20.37 8 7 -5 4.01 3.46 8 7 -5 8.41 4.01 -8 -7 5 4.85 2.96 -8 -7 5 -3.91 5.26 8 7 -5 8.76 4.18 8 7 -5 3.78 3.26 -8 -7 5 4.85 4.90 -8 -7 5 7.53 3.74 -8 -7 5 -1.13 4.56 8 7 -5 10.62 4.72 8 7 -4 77.07 10.23 -8 -7 4 88.58 10.52 8 7 -4 90.59 10.98 -8 -7 4 66.20 9.44 -8 -7 4 64.96 8.95 8 7 -4 76.69 10.27 8 7 -4 80.67 10.52 8 7 -3 10.78 3.95 8 7 -3 1.36 2.37 -8 -7 3 15.10 4.91 8 7 -3 5.76 2.99 -8 -7 3 10.93 3.52 -8 -7 3 14.28 4.93 -8 -7 3 2.27 3.80 8 7 -3 6.24 3.41 -8 -7 3 4.31 3.09 8 7 -3 16.79 5.22 -8 -7 2 154.06 13.45 8 7 -2 158.40 13.84 -8 -7 2 124.26 11.89 -8 -7 2 146.17 12.93 8 7 -2 117.37 12.43 -8 -7 2 135.26 12.63 -8 -7 2 117.49 12.10 8 7 -2 130.65 13.59 8 7 -1 232.73 17.65 8 7 -1 226.47 17.45 8 7 -1 258.96 19.10 -8 -7 1 225.68 17.20 -8 -7 1 224.41 17.19 -8 -7 1 273.15 18.05 -8 -7 1 252.42 17.97 8 7 0 3.39 2.74 -8 -7 0 2.26 2.44 -8 -7 0 4.38 2.86 -8 -7 0 6.61 3.04 -8 -7 -1 14.50 2.84 8 7 1 21.36 3.92 -8 -7 -1 16.39 3.38 8 7 1 19.84 3.59 8 7 1 21.26 3.97 -8 -8 12 2.67 1.80 8 8 -12 0.44 1.55 8 8 -11 15.59 3.21 -8 -8 11 29.84 4.23 -8 -8 11 23.15 3.51 8 8 -11 22.35 4.13 8 8 -10 180.47 12.79 8 8 -10 190.05 13.71 -8 -8 10 160.16 11.59 8 8 -10 170.30 13.49 -8 -8 10 175.44 13.06 -8 -8 10 173.82 13.38 8 8 -9 55.44 7.24 8 8 -9 77.33 7.87 -8 -8 9 50.46 6.03 -8 -8 9 75.01 7.92 -8 -8 9 47.64 6.88 8 8 -8 45.26 6.73 8 8 -8 38.12 5.56 8 8 -8 40.45 6.84 -8 -8 8 41.35 6.56 -8 -8 8 32.22 5.86 -8 -8 8 27.00 4.77 8 8 -7 159.24 13.90 -8 -8 7 143.87 12.96 8 8 -7 136.57 12.57 8 8 -6 73.90 9.67 8 8 -6 85.73 8.83 8 8 -6 63.12 8.59 -8 -8 6 86.49 9.76 -8 -8 6 95.52 10.25 8 8 -6 79.60 9.36 8 8 -5 102.48 11.16 8 8 -5 103.71 11.18 8 8 -5 125.35 11.50 8 8 -5 103.66 10.65 -8 -8 5 107.04 11.17 -8 -8 5 110.93 10.05 8 8 -4 33.26 6.06 8 8 -4 32.09 5.76 8 8 -4 27.27 5.50 -8 -8 4 28.50 5.73 -8 -8 4 20.25 5.13 -8 -8 4 20.00 4.21 8 8 -3 12.34 4.09 8 8 -3 20.57 4.92 8 8 -3 21.49 4.36 -8 -8 3 18.68 4.75 -8 -8 3 16.00 3.80 8 8 -2 -1.59 2.06 -8 -8 2 -1.48 2.70 8 8 -2 0.88 2.85 -8 -8 2 -0.75 2.57 -8 -8 2 1.94 1.93 8 8 -1 16.82 3.40 8 8 -1 18.07 4.09 -8 -8 1 16.78 3.14 -8 -8 1 20.97 3.00 -8 -8 1 26.85 4.25 8 8 0 0.96 1.60 8 8 0 0.81 1.48 8 8 0 1.02 1.75 -8 -8 0 -0.87 1.40 8 9 -10 236.27 14.29 -8 -9 10 198.84 12.97 -8 -9 10 232.50 14.21 -8 -9 9 44.12 4.74 -8 -9 9 48.46 5.29 -8 -9 9 55.56 6.01 8 9 -9 45.23 5.34 -8 -9 8 16.90 3.39 8 9 -8 10.97 3.16 -8 -9 8 13.90 3.53 8 9 -8 12.12 2.60 8 9 -8 11.81 3.24 -8 -9 7 15.00 3.54 8 9 -7 13.59 3.73 -8 -9 7 12.58 3.51 8 9 -7 15.43 3.38 8 9 -7 7.64 3.28 8 9 -6 51.92 6.39 -8 -9 6 55.84 6.30 8 9 -6 45.67 6.08 8 9 -6 45.07 5.15 8 9 -6 50.97 6.57 8 9 -5 16.67 3.51 -8 -9 5 16.47 3.85 8 9 -5 24.44 4.33 8 9 -5 15.87 3.52 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42.06 7.01 -9 -5 2 51.46 7.13 9 5 -2 53.75 8.60 9 5 -2 52.87 7.43 9 5 -2 60.42 8.55 9 5 -2 51.00 8.10 -9 -5 1 2.07 2.96 -9 -5 1 3.14 3.25 9 5 -1 -1.13 2.91 9 5 -1 -0.91 2.34 -9 -5 0 3.50 2.73 -9 -5 0 6.31 3.39 -9 -5 0 9.28 3.15 9 5 0 4.54 3.33 9 5 0 8.10 3.13 -9 -5 -1 31.51 4.17 -9 -5 -1 44.37 5.55 9 5 1 41.01 5.16 9 5 1 33.72 4.98 9 5 1 44.98 5.83 9 5 2 14.33 2.87 9 5 2 20.59 2.99 -9 -6 12 59.56 5.36 9 6 -12 57.58 5.45 9 6 -12 74.31 6.85 -9 -6 12 63.06 5.85 9 6 -11 6.65 2.94 9 6 -11 7.46 2.49 -9 -6 11 5.81 2.81 9 6 -11 9.04 3.02 -9 -6 11 12.83 3.08 9 6 -10 0.84 2.52 9 6 -10 1.58 2.55 -9 -6 10 -1.60 2.83 9 6 -10 -0.92 2.63 -9 -6 10 0.74 2.47 9 6 -9 161.44 13.83 -9 -6 9 167.82 14.00 9 6 -9 170.66 14.71 -9 -6 8 7.42 3.31 -9 -6 8 12.02 4.06 -9 -6 8 6.36 3.67 9 6 -8 4.69 3.37 -9 -6 8 7.58 3.67 9 6 -8 7.90 4.25 9 6 -8 7.20 3.21 -9 -6 7 37.20 6.55 -9 -6 7 35.93 6.68 -9 -6 7 30.89 5.99 9 6 -7 40.82 7.18 -9 -6 7 29.08 5.68 9 6 -7 27.62 6.31 9 6 -7 30.01 6.04 9 6 -6 21.07 5.63 -9 -6 6 23.28 5.23 9 6 -6 30.03 5.63 -9 -6 6 26.61 6.07 9 6 -6 17.43 5.03 -9 -6 6 29.76 5.90 9 6 -6 20.59 5.63 -9 -6 6 21.65 5.31 9 6 -5 -1.26 2.88 -9 -6 5 2.34 2.66 9 6 -5 -2.31 3.15 9 6 -5 1.05 2.56 -9 -6 5 1.08 3.21 9 6 -5 -1.12 2.72 9 6 -4 3.46 3.72 -9 -6 4 0.99 3.52 -9 -6 4 1.00 3.23 9 6 -4 -1.17 3.63 9 6 -4 -1.03 3.56 -9 -6 4 2.28 2.60 9 6 -3 192.88 16.27 -9 -6 3 188.46 15.18 -9 -6 3 190.26 15.30 -9 -6 3 199.54 15.43 9 6 -3 224.79 17.37 -9 -6 3 195.92 16.29 -9 -6 3 206.01 16.26 -9 -6 2 15.66 4.34 -9 -6 2 7.53 3.14 9 6 -2 9.16 3.95 -9 -6 2 8.10 3.67 9 6 -2 10.92 4.02 9 6 -1 4.24 3.02 9 6 -1 1.85 2.39 -9 -6 1 0.56 1.94 9 6 -1 4.83 3.10 -9 -6 1 8.73 3.26 -9 -6 1 3.84 3.03 9 6 0 30.46 4.47 9 6 0 28.64 4.14 -9 -6 0 32.34 4.52 9 7 -11 25.09 3.57 -9 -7 11 24.16 3.68 9 7 -11 26.46 3.60 -9 -7 11 22.73 3.30 9 7 -10 -0.57 2.02 9 7 -10 1.67 2.03 -9 -7 10 1.90 2.32 9 7 -10 -0.69 2.31 -9 -7 10 4.57 2.74 -9 -7 10 0.52 1.86 9 7 -9 7.65 3.24 -9 -7 9 5.15 2.50 9 7 -9 7.53 3.07 -9 -7 9 8.25 2.98 -9 -7 8 67.71 7.39 9 7 -8 60.40 7.91 -9 -7 8 57.63 7.11 -9 -7 8 57.88 7.42 9 7 -7 597.84 35.70 9 7 -7 634.42 36.74 9 7 -7 587.43 36.08 -9 -7 7 656.66 36.58 -9 -7 7 591.89 35.61 9 7 -6 -0.95 3.16 9 7 -6 1.76 2.27 -9 -7 6 1.77 2.96 9 7 -6 2.76 2.74 9 7 -6 0.73 1.89 9 7 -5 6.16 3.33 -9 -7 5 13.25 4.36 9 7 -5 6.75 2.99 -9 -7 5 11.07 3.83 -9 -7 5 13.17 3.43 9 7 -5 6.70 3.17 9 7 -4 38.77 5.96 9 7 -4 33.41 5.31 9 7 -4 41.93 6.29 -9 -7 4 48.33 6.39 -9 -7 4 50.40 6.41 -9 -7 4 45.48 5.99 -9 -7 3 64.65 7.12 9 7 -3 69.33 7.81 -9 -7 3 77.59 7.48 9 7 -3 56.36 7.09 9 7 -2 54.07 6.27 -9 -7 2 32.11 4.62 -9 -7 2 35.90 4.67 9 7 -2 44.12 5.47 -9 -7 2 36.91 4.90 -9 -7 2 48.56 4.76 9 7 -1 0.49 1.45 9 7 -1 -1.03 1.53 9 8 -10 76.93 6.42 -9 -8 9 60.47 5.73 9 8 -9 72.43 6.76 -9 -8 9 62.89 6.13 9 8 -9 68.89 6.39 -9 -8 8 2.61 2.29 9 8 -8 1.85 1.99 9 8 -7 166.57 12.75 -9 -8 7 188.63 13.18 9 8 -7 190.99 13.45 9 8 -6 28.80 4.62 9 8 -6 25.03 4.12 -9 -8 6 33.62 4.77 9 8 -6 19.85 3.62 -9 -8 6 29.15 4.55 9 8 -5 2.22 2.08 -9 -8 5 3.72 1.64 9 8 -5 5.01 2.16 -9 -8 5 1.13 2.13 -9 -8 5 2.90 2.50 9 8 -4 7.79 2.38 9 8 -4 2.86 2.22 -9 -8 4 5.49 2.29 -9 -8 4 7.39 2.41 9 8 -3 29.82 3.95 10 -11 -5 52.99 5.14 10 -11 -5 46.20 5.07 10 -11 -4 2.44 2.34 -10 11 4 2.92 1.61 10 -11 -4 6.56 2.23 -10 11 3 112.24 8.94 -10 11 3 72.89 6.82 -10 11 2 193.56 13.63 -10 11 2 176.95 13.62 -10 11 2 177.59 12.00 -10 11 1 20.45 4.02 -10 11 1 24.30 4.46 -10 11 1 22.44 3.33 10 -11 -1 33.46 4.43 -10 11 0 4.61 2.24 10 -11 0 10.50 2.77 -10 11 0 9.63 3.00 10 -11 1 6.82 2.11 -10 11 -1 3.62 2.10 10 -10 -7 29.91 4.30 -10 10 7 21.78 3.59 10 -10 -7 27.67 3.43 10 -10 -6 125.88 9.98 -10 10 6 92.14 9.00 10 -10 -6 114.15 8.97 10 -10 -5 6.52 3.06 10 -10 -5 2.53 2.51 -10 10 5 5.22 2.81 -10 10 5 5.19 2.99 -10 10 4 81.05 8.97 10 -10 -4 103.09 9.41 -10 10 4 101.23 10.03 -10 10 3 4.19 3.06 10 -10 -3 2.23 3.01 -10 10 3 -0.97 2.64 10 -10 -2 44.41 6.54 -10 10 2 28.95 5.47 -10 10 2 30.87 5.63 -10 10 2 26.57 5.18 -10 10 1 148.33 13.67 10 -10 -1 161.83 12.92 -10 10 1 149.47 13.07 -10 10 1 150.55 12.65 -10 10 1 153.61 12.52 -10 10 0 119.56 11.00 10 -10 0 95.77 7.53 -10 10 0 95.18 9.72 10 -10 0 122.31 9.85 -10 10 0 97.05 9.11 -10 10 0 88.98 8.95 10 -10 1 1.60 1.58 -10 10 -1 1.77 2.10 10 -10 1 0.57 2.32 -10 10 -1 0.58 1.86 10 -10 2 1.34 2.00 -10 10 -2 3.79 1.63 -10 10 -2 1.85 2.26 10 -10 2 4.01 1.61 10 -9 -8 20.82 4.50 10 -9 -8 22.56 3.66 -10 9 7 105.29 10.40 10 -9 -7 120.45 9.05 10 -9 -7 87.37 8.43 10 -9 -6 0.70 2.58 -10 9 6 6.97 3.09 -10 9 6 5.36 3.20 10 -9 -5 1.62 3.20 -10 9 5 -1.05 3.14 -10 9 5 1.09 2.65 -10 9 5 1.08 2.29 -10 9 5 1.17 2.85 10 -9 -5 2.79 3.31 10 -9 -4 7.04 3.73 -10 9 4 9.94 4.37 -10 9 4 11.46 4.43 -10 9 4 11.08 3.84 -10 9 4 1.23 3.36 10 -9 -4 11.47 4.23 10 -9 -3 173.35 14.74 -10 9 3 169.76 15.40 -10 9 3 150.60 14.12 -10 9 3 165.58 15.06 10 -9 -3 180.48 14.78 -10 9 3 144.67 14.19 -10 9 2 27.12 5.90 10 -9 -2 10.78 4.37 10 -9 -2 22.12 5.64 -10 9 2 22.11 5.56 -10 9 2 28.90 5.35 10 -9 -1 1.01 3.01 10 -9 -1 3.03 3.25 -10 9 1 -1.18 2.88 -10 9 1 0.99 2.94 10 -9 -1 0.89 2.98 -10 9 1 1.06 2.88 -10 9 0 228.38 18.40 10 -9 0 232.17 17.28 10 -9 0 234.16 15.11 10 -9 0 205.03 16.26 -10 9 0 190.44 16.95 -10 9 0 207.66 16.30 10 -9 0 216.15 15.75 -10 9 0 234.52 17.42 -10 9 -1 -3.03 3.25 10 -9 1 0.76 2.46 10 -9 1 -0.58 1.74 10 -9 1 -0.68 2.11 -10 9 -1 0.97 2.50 10 -9 1 -0.71 1.93 -10 9 -1 -1.43 2.30 -10 9 -1 4.27 2.94 10 -9 2 22.23 4.35 -10 9 -2 10.54 3.54 10 -9 2 21.14 3.61 -10 9 -2 22.51 4.42 -10 9 -2 21.59 4.08 10 -9 2 20.03 3.81 -10 9 -2 18.76 3.39 10 -9 3 7.07 2.11 10 -9 3 9.15 2.56 10 -9 3 10.89 2.77 -10 9 -3 11.80 2.68 10 -8 -10 53.23 5.07 10 -8 -9 161.58 12.27 10 -8 -9 178.68 12.62 10 -8 -8 4.40 2.61 10 -8 -8 1.50 2.24 10 -8 -7 360.23 23.95 10 -8 -7 388.25 25.72 10 -8 -7 396.03 23.80 -10 8 7 410.08 27.18 -10 8 7 354.61 25.91 10 -8 -6 10.07 4.72 -10 8 6 13.28 4.47 10 -8 -6 16.63 4.65 -10 8 6 10.16 3.83 -10 8 5 11.28 4.57 10 -8 -5 9.13 3.83 10 -8 -5 10.18 4.23 10 -8 -5 3.52 4.07 10 -8 -5 13.16 4.81 -10 8 5 12.15 4.53 -10 8 5 8.72 3.74 -10 8 4 363.12 27.31 -10 8 4 418.30 29.09 10 -8 -4 406.30 28.02 -10 8 4 458.46 30.23 10 -8 -4 386.71 27.23 10 -8 -4 405.25 27.14 10 -8 -4 355.96 27.54 -10 8 4 453.27 29.52 10 -8 -4 394.52 28.45 -10 8 3 7.25 3.45 -10 8 3 -2.81 5.67 -10 8 3 1.47 5.50 10 -8 -3 1.21 3.28 10 -8 -3 2.83 2.98 10 -8 -3 2.09 3.49 -10 8 3 2.69 4.78 10 -8 -3 1.14 3.09 -10 8 2 4.15 5.47 10 -8 -2 21.12 5.57 -10 8 2 6.62 5.11 10 -8 -2 5.16 3.10 10 -8 -2 11.57 4.89 -10 8 2 5.77 5.13 10 -8 -2 6.19 3.86 10 -8 -1 45.27 7.63 -10 8 1 40.15 7.38 10 -8 -1 53.46 7.83 10 -8 -1 36.11 6.82 10 -8 -1 37.26 5.90 -10 8 1 30.44 6.19 -10 8 1 38.04 7.46 10 -8 -1 29.56 6.38 -10 8 0 33.52 5.86 10 -8 0 28.37 5.27 10 -8 0 20.53 5.32 -10 8 0 32.25 6.42 10 -8 0 21.09 4.31 10 -8 0 34.09 6.22 -10 8 0 33.04 6.86 -10 8 0 25.95 6.23 10 -8 1 7.03 3.13 -10 8 -1 8.56 3.08 10 -8 1 2.47 2.57 -10 8 -1 8.44 3.64 -10 8 -1 -1.15 3.15 10 -8 1 9.10 3.76 10 -8 1 2.91 2.52 10 -8 2 45.45 6.45 -10 8 -2 62.47 7.83 -10 8 -2 48.75 7.12 10 -8 2 71.11 6.98 10 -8 2 52.28 6.49 10 -8 3 3.17 2.11 -10 8 -3 0.69 2.23 10 -8 3 2.64 2.08 10 -8 4 5.83 1.94 10 -8 4 3.79 1.63 -10 8 -4 1.30 1.50 10 -7 -10 5.05 2.68 10 -7 -10 5.55 2.16 10 -7 -9 2.39 2.65 -10 7 9 -1.04 2.53 -10 7 9 -1.06 2.90 10 -7 -8 153.20 14.27 10 -7 -8 183.47 14.50 -10 7 8 171.85 15.76 -10 7 8 190.01 16.37 10 -7 -7 3.07 2.96 10 -7 -7 5.81 3.88 10 -7 -7 5.66 3.45 -10 7 7 5.66 3.86 10 -7 -7 2.82 2.92 -10 7 7 -1.38 3.15 10 -7 -6 56.42 7.71 -10 7 6 50.47 8.57 10 -7 -6 55.45 7.28 10 -7 -6 46.69 7.94 -10 7 6 59.32 9.51 10 -7 -6 46.45 7.64 -10 7 6 56.34 9.11 -10 7 5 122.28 13.65 10 -7 -5 105.87 11.47 -10 7 5 101.62 12.77 10 -7 -5 92.04 11.62 -10 7 5 109.84 13.11 10 -7 -5 99.37 11.04 10 -7 -5 90.06 11.41 10 -7 -5 85.88 11.28 10 -7 -4 32.61 6.45 -10 7 4 37.79 7.84 10 -7 -4 35.02 7.22 -10 7 4 31.61 7.48 -10 7 4 44.79 7.59 10 -7 -4 29.59 6.54 -10 7 4 27.54 7.27 10 -7 -4 27.34 7.12 10 -7 -4 19.55 5.16 -10 7 4 39.42 7.71 10 -7 -4 33.23 7.28 10 -7 -3 6.68 4.76 -10 7 3 8.11 5.04 -10 7 3 15.13 5.98 10 -7 -3 9.02 4.25 10 -7 -3 3.72 3.71 -10 7 3 4.75 4.53 10 -7 -3 4.65 4.44 10 -7 -2 61.40 9.61 10 -7 -2 60.41 8.88 -10 7 2 62.03 10.11 10 -7 -2 56.75 9.18 -10 7 2 68.27 10.00 10 -7 -2 65.45 8.69 -10 7 2 49.75 9.25 -10 7 1 155.10 14.21 10 -7 -1 142.73 13.35 10 -7 -1 170.61 15.62 10 -7 -1 169.95 16.09 10 -7 -1 133.13 14.19 -10 7 1 161.72 14.69 -10 7 1 171.05 16.48 -10 7 1 128.24 14.86 10 -7 0 176.60 15.34 -10 7 0 179.78 17.10 10 -7 0 231.29 17.46 10 -7 0 189.14 14.71 10 -7 0 176.44 16.40 -10 7 0 150.53 14.87 10 -7 0 185.17 15.93 -10 7 0 168.51 16.72 -10 7 0 203.96 17.83 -10 7 -1 18.47 5.16 10 -7 1 21.80 4.60 10 -7 1 16.33 4.65 -10 7 -1 13.51 4.29 10 -7 1 22.19 4.73 -10 7 -1 16.74 5.16 10 -7 1 24.27 5.08 -10 7 -1 15.64 5.05 -10 7 -2 27.78 5.64 10 -7 2 34.27 5.42 10 -7 2 37.08 5.46 -10 7 -2 44.92 6.39 -10 7 -2 28.77 5.70 10 -7 2 36.26 5.91 -10 7 -2 27.93 5.65 -10 7 -3 3.54 2.59 -10 7 -3 0.83 2.47 10 -7 3 1.88 2.16 10 -7 4 27.06 3.88 -10 7 -4 40.54 4.96 -10 7 -4 38.99 4.39 10 -7 4 46.27 5.00 10 -6 -11 11.33 3.03 -10 6 11 9.36 2.66 10 -6 -10 17.69 3.61 10 -6 -10 21.64 4.52 -10 6 10 21.86 4.56 -10 6 9 171.85 14.73 10 -6 -9 169.56 14.65 -10 6 9 186.62 15.39 -10 6 9 190.82 16.55 10 -6 -9 189.20 14.99 -10 6 8 4.26 4.24 -10 6 8 1.11 3.04 10 -6 -8 2.04 2.93 -10 6 8 1.43 3.49 -10 6 8 7.20 3.43 10 -6 -8 6.88 3.23 10 -6 -8 5.74 3.70 -10 6 7 62.35 10.01 -10 6 7 79.73 10.26 10 -6 -7 57.35 8.40 10 -6 -7 56.64 9.02 10 -6 -7 66.79 8.33 -10 6 7 82.88 10.11 10 -6 -6 144.97 13.92 10 -6 -6 135.93 14.29 -10 6 6 141.64 14.60 10 -6 -6 134.24 14.18 -10 6 6 136.55 15.65 10 -6 -6 179.74 14.86 10 -6 -6 165.27 15.75 10 -6 -5 281.46 21.27 10 -6 -5 272.12 21.49 10 -6 -5 284.10 22.84 -10 6 5 273.70 22.08 10 -6 -5 305.75 22.96 -10 6 5 238.97 22.91 -10 6 5 234.15 21.08 10 -6 -5 253.51 19.96 10 -6 -5 290.80 22.71 10 -6 -4 5.53 4.30 10 -6 -4 1.61 3.40 -10 6 4 -1.71 4.67 -10 6 4 1.36 3.32 -10 6 4 5.68 3.87 10 -6 -4 7.28 4.52 10 -6 -4 5.02 3.90 -10 6 4 -3.25 6.41 10 -6 -4 1.10 3.69 10 -6 -4 1.37 3.54 10 -6 -3 90.44 11.50 10 -6 -3 98.91 11.97 -10 6 3 119.92 13.23 10 -6 -3 105.34 12.88 -10 6 3 122.71 14.51 10 -6 -3 106.64 13.46 -10 6 3 112.57 13.98 -10 6 3 139.21 14.96 10 -6 -3 139.11 13.69 10 -6 -3 119.50 13.40 10 -6 -2 213.66 19.32 -10 6 2 207.46 18.14 10 -6 -2 207.88 18.43 -10 6 2 163.36 17.96 -10 6 2 174.49 18.17 10 -6 -1 111.23 12.82 10 -6 -1 102.04 11.88 10 -6 -1 97.09 10.89 -10 6 1 66.29 9.91 10 -6 -1 70.83 10.37 -10 6 1 87.97 11.71 -10 6 1 93.01 12.26 10 -6 0 110.31 12.09 10 -6 0 79.08 9.84 -10 6 0 68.94 9.82 10 -6 0 89.66 10.59 -10 6 0 70.36 10.82 -10 6 0 88.73 11.31 10 -6 0 79.06 9.14 -10 6 0 72.91 10.68 10 -6 0 94.21 11.10 10 -6 1 1.11 2.86 -10 6 -1 -1.23 2.98 10 -6 1 -0.99 2.82 -10 6 -1 -1.35 3.08 -10 6 -1 -2.60 3.53 -10 6 -1 2.44 3.49 10 -6 1 7.36 3.36 10 -6 1 -1.10 3.13 -10 6 -2 17.15 4.65 10 -6 2 25.29 5.17 10 -6 2 19.15 4.39 -10 6 -2 18.26 4.80 -10 6 -2 16.30 4.79 10 -6 2 16.93 4.54 10 -6 3 0.70 2.24 -10 6 -3 1.74 2.37 -10 6 -4 2.48 2.27 10 -6 4 2.39 2.24 10 -5 -12 39.06 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582.53 36.49 10 2 -9 575.21 35.89 -10 -2 9 541.11 35.63 10 2 -8 18.40 5.52 -10 -2 8 15.49 5.08 -10 -2 8 22.33 5.72 -10 -2 8 16.97 5.47 10 2 -8 19.60 5.35 -10 -2 8 21.70 5.68 10 2 -7 56.45 9.24 -10 -2 7 62.73 9.39 10 2 -7 47.57 7.83 -10 -2 7 42.58 7.83 10 2 -7 59.03 8.73 10 2 -7 56.14 8.94 10 2 -7 39.07 7.62 -10 -2 7 59.52 9.16 10 2 -6 195.53 17.90 -10 -2 6 189.03 17.79 10 2 -6 175.95 17.22 -10 -2 6 201.56 17.94 10 2 -6 216.10 17.64 10 2 -6 167.77 17.43 -10 -2 6 191.82 17.67 10 2 -6 202.70 18.19 -10 -2 5 21.32 5.92 10 2 -5 11.19 4.57 -10 -2 5 19.09 5.57 10 2 -5 13.76 4.99 10 2 -5 18.17 5.83 10 2 -5 21.60 5.84 -10 -2 5 14.69 5.92 10 2 -5 14.51 5.14 10 2 -4 103.95 11.94 -10 -2 4 103.25 12.18 -10 -2 4 105.95 11.92 -10 -2 4 107.62 12.47 10 2 -4 94.44 12.19 10 2 -4 95.62 11.89 10 2 -4 93.59 12.09 -10 -2 4 116.74 13.09 -10 -2 3 8.19 3.92 -10 -2 3 4.18 3.62 10 2 -3 8.72 4.87 -10 -2 3 5.49 3.76 10 2 -3 18.01 5.50 10 2 -3 14.14 4.44 -10 -2 2 27.89 6.50 10 2 -2 28.74 6.89 10 2 -2 28.46 6.09 -10 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27.85 6.12 10 4 -7 144.45 14.38 10 4 -7 144.81 14.12 -10 -4 7 166.31 14.17 -10 -4 7 152.55 14.44 -10 -4 6 195.86 17.37 -10 -4 6 232.05 18.46 10 4 -6 225.39 17.91 -10 -4 6 205.16 16.87 10 4 -6 237.69 18.71 10 4 -6 210.98 16.87 -10 -4 5 36.60 6.32 -10 -4 5 28.77 5.32 10 4 -5 20.07 5.02 10 4 -5 13.92 4.34 -10 -4 5 23.18 4.99 10 4 -5 31.16 6.31 10 4 -4 37.37 5.61 -10 -4 4 22.40 4.66 10 4 -4 28.74 5.98 -10 -4 4 28.26 5.86 10 4 -4 17.47 4.51 -10 -4 3 6.11 3.83 -10 -4 3 1.70 2.54 10 4 -3 3.33 3.17 10 4 -3 6.25 2.88 -10 -4 2 118.61 11.02 10 4 -2 105.52 10.14 10 4 -2 104.65 10.67 -10 -4 2 95.04 9.49 -10 -4 1 34.03 5.34 -10 -4 1 37.50 5.81 10 4 -1 38.68 5.51 10 4 -1 38.68 5.68 10 4 -1 26.78 4.12 -10 -4 0 26.00 3.96 10 4 0 25.65 4.11 10 4 0 21.68 3.69 -10 -4 0 15.73 3.07 -10 -5 11 196.21 13.01 10 5 -11 192.03 13.04 -10 -5 11 181.40 12.98 10 5 -10 229.24 15.69 -10 -5 9 17.29 4.22 10 5 -9 18.61 4.49 10 5 -9 24.84 4.88 -10 -5 8 19.43 4.39 10 5 -8 29.68 5.52 -10 -5 7 5.18 3.03 10 5 -7 19.24 4.50 10 5 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149.10 9.89 -10 -7 8 132.75 9.59 10 7 -8 156.75 10.18 -10 -7 7 11.69 2.59 -10 -7 7 10.01 2.36 10 7 -7 11.05 2.68 -10 -7 6 10.07 2.31 10 7 -6 6.94 2.06 -11 10 4 6.39 1.97 -11 10 3 1.17 1.94 -11 10 3 0.44 1.38 11 -10 -3 0.71 1.53 -11 10 2 2.90 1.68 11 -10 -2 1.42 1.65 -11 9 7 23.10 3.52 11 -9 -7 31.24 3.91 -11 9 6 96.68 8.51 11 -9 -6 101.13 8.49 11 -9 -5 31.52 4.02 -11 9 5 35.04 5.09 -11 9 4 46.03 5.93 11 -9 -4 73.68 7.34 -11 9 4 69.54 7.63 -11 9 4 67.71 7.24 11 -9 -4 63.28 6.27 -11 9 3 3.22 2.17 11 -9 -3 7.02 2.96 -11 9 3 -0.81 2.71 -11 9 3 2.93 2.60 11 -9 -3 1.06 2.33 -11 9 2 45.42 5.77 11 -9 -2 40.08 5.08 11 -9 -2 37.95 5.21 -11 9 2 26.06 3.77 -11 9 2 26.26 5.23 11 -9 -1 252.37 15.71 -11 9 1 258.66 16.46 11 -9 -1 243.19 15.88 -11 9 1 216.91 16.30 -11 9 0 -3.09 1.89 11 -9 0 0.41 1.87 -11 9 0 -1.07 1.85 -11 8 8 54.42 6.02 11 -8 -8 59.47 5.89 -11 8 7 28.99 5.07 -11 8 6 22.02 4.82 11 -8 -6 23.26 4.07 -11 8 6 30.67 5.32 -11 8 5 64.39 7.95 11 -8 -5 61.54 7.28 -11 8 5 65.30 7.99 11 -8 -5 50.42 7.18 11 -8 -5 55.79 6.18 -11 8 4 5.12 3.20 11 -8 -4 14.00 4.07 -11 8 4 2.85 3.39 11 -8 -4 8.04 2.99 -11 8 4 6.02 3.25 11 -8 -4 11.06 3.55 -11 8 3 6.61 3.55 11 -8 -3 12.40 3.65 11 -8 -3 5.31 3.15 -11 8 3 6.11 3.40 -11 8 3 2.54 2.27 11 -8 -3 1.68 2.90 -11 8 2 6.33 3.67 11 -8 -2 11.70 3.47 -11 8 2 7.73 3.45 11 -8 -2 5.86 3.41 -11 8 2 9.73 3.48 -11 8 1 0.83 2.57 11 -8 -1 -0.61 2.36 11 -8 -1 0.73 2.51 -11 8 1 4.45 2.86 -11 8 1 5.08 2.82 11 -8 -1 -0.76 2.44 -11 8 0 1.42 2.38 11 -8 0 4.29 2.77 11 -8 0 2.16 1.86 11 -8 0 2.93 1.57 -11 8 0 -0.67 2.24 11 -8 0 3.14 2.23 11 -8 1 42.77 4.63 -11 8 -1 37.84 4.94 11 -7 -9 5.37 2.23 -11 7 9 8.54 2.89 -11 7 8 0.80 2.59 11 -7 -8 1.40 2.55 -11 7 7 6.60 3.73 -11 7 7 3.98 2.99 11 -7 -7 10.60 2.96 11 -7 -6 225.98 17.62 -11 7 6 263.82 18.79 11 -7 -6 236.16 17.12 -11 7 6 204.11 17.69 -11 7 5 82.26 10.21 11 -7 -5 83.54 9.63 11 -7 -5 78.68 8.82 11 -7 -5 97.23 10.15 -11 7 5 86.90 10.22 11 -7 -4 120.57 10.58 11 -7 -4 118.89 11.85 11 -7 -4 136.57 12.28 11 -7 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-4 -7 25.87 5.44 -11 4 7 21.33 5.64 11 -4 -7 25.48 5.90 -11 4 7 14.75 4.72 -11 4 7 28.25 6.25 11 -4 -6 4.83 3.60 -11 4 6 1.17 2.66 -11 4 6 6.83 3.90 -11 4 6 -2.38 4.10 11 -4 -6 9.59 4.84 -11 4 6 -1.27 3.96 11 -4 -6 2.01 3.00 -11 4 6 5.19 3.16 -11 4 5 90.27 11.80 11 -4 -5 127.57 12.97 -11 4 5 99.18 11.79 11 -4 -5 92.51 11.36 -11 4 5 92.06 11.05 -11 4 5 112.86 12.56 11 -4 -5 123.70 12.92 11 -4 -5 119.73 11.94 -11 4 5 128.71 13.24 -11 4 4 123.02 13.44 11 -4 -4 131.40 13.68 -11 4 4 119.87 13.04 11 -4 -4 131.99 13.14 11 -4 -4 146.59 14.71 11 -4 -4 136.28 13.43 -11 4 4 126.67 13.36 -11 4 4 140.67 14.27 -11 4 4 122.17 12.82 -11 4 3 136.77 13.69 11 -4 -3 149.74 13.15 -11 4 3 152.33 14.91 -11 4 3 108.46 12.42 11 -4 -3 176.06 15.12 -11 4 3 142.82 14.03 -11 4 2 33.65 6.15 11 -4 -2 45.57 7.46 -11 4 2 24.65 5.76 11 -4 -2 32.72 6.63 -11 4 2 28.50 6.60 -11 4 2 34.96 6.05 -11 4 1 6.03 4.02 -11 4 1 2.98 2.97 11 -4 -1 1.07 4.78 11 -4 -1 4.46 2.98 -11 4 1 4.07 3.16 -11 4 0 7.49 3.84 11 -4 0 21.35 4.39 -11 4 0 10.70 3.52 11 -4 0 7.31 2.58 11 -4 0 11.87 3.97 11 -4 0 12.71 3.62 -11 4 0 17.43 4.01 -11 4 -1 37.28 5.87 11 -4 1 31.89 4.50 11 -4 1 32.53 5.10 11 -4 1 42.06 5.73 -11 4 -1 37.49 5.23 -11 4 -2 9.12 2.89 11 -4 2 8.49 2.65 11 -4 2 6.87 2.09 -11 3 12 339.96 19.66 11 -3 -11 0.62 2.32 11 -3 -11 3.35 2.26 -11 3 11 0.72 2.25 11 -3 -10 -0.85 2.63 11 -3 -10 -1.49 2.40 11 -3 -10 0.69 2.05 -11 3 10 3.78 3.55 11 -3 -9 118.17 11.41 -11 3 9 122.28 12.25 -11 3 9 85.03 10.77 11 -3 -9 127.77 11.91 11 -3 -8 154.06 13.64 -11 3 8 117.95 12.77 11 -3 -8 127.41 11.39 -11 3 8 116.96 11.41 11 -3 -8 134.02 12.98 -11 3 8 104.69 11.27 -11 3 8 122.83 13.25 11 -3 -7 83.13 10.31 -11 3 7 74.04 10.03 -11 3 7 61.64 8.47 -11 3 7 52.93 8.09 -11 3 7 71.38 10.04 11 -3 -6 9.18 3.98 -11 3 6 19.37 4.94 -11 3 6 17.10 5.53 -11 3 6 10.93 5.04 11 -3 -6 15.71 5.15 11 -3 -6 24.65 5.86 -11 3 6 15.30 4.47 -11 3 5 93.70 11.16 -11 3 5 115.68 12.92 -11 3 5 98.60 11.05 11 -3 -5 128.06 12.59 -11 3 5 107.37 12.45 11 -3 -5 85.76 10.69 11 -3 -4 34.53 7.05 -11 3 4 18.61 5.63 11 -3 -4 29.35 6.03 -11 3 4 21.18 5.39 -11 3 4 24.40 6.50 11 -3 -4 22.22 6.12 11 -3 -3 23.36 6.05 -11 3 3 11.19 4.21 -11 3 3 9.70 3.76 -11 3 3 11.72 4.79 11 -3 -3 11.12 5.35 11 -3 -2 122.63 11.28 -11 3 2 141.11 13.78 11 -3 -2 131.31 12.93 -11 3 2 109.27 12.26 -11 3 2 99.36 10.94 11 -3 -1 106.22 10.50 11 -3 -1 127.86 12.32 -11 3 1 118.85 11.79 -11 3 1 87.37 9.69 11 -3 0 6.05 2.79 -11 3 0 0.74 2.10 -11 3 0 0.92 2.51 11 -3 0 7.25 3.66 11 -3 1 15.51 3.72 -11 3 -1 13.82 3.71 -11 3 -1 15.55 2.98 11 -3 1 13.51 3.41 -11 3 -2 4.81 2.26 11 -3 2 2.30 1.63 11 -3 2 3.86 2.02 11 -2 -12 68.45 6.15 -11 2 12 68.21 6.43 11 -2 -11 0.47 1.63 11 -2 -11 -0.73 2.25 11 -2 -11 -0.60 2.42 -11 2 11 0.52 2.12 -11 2 10 0.70 2.70 -11 2 10 -1.99 2.57 11 -2 -10 -1.42 2.45 11 -2 -10 -0.80 2.67 11 -2 -9 -1.01 2.88 -11 2 9 3.45 3.84 -11 2 9 -1.16 4.01 -11 2 9 -0.82 2.64 11 -2 -8 44.46 7.46 -11 2 8 42.12 7.34 -11 2 8 28.39 6.44 11 -2 -7 17.92 5.24 11 -2 -7 22.02 5.43 -11 2 7 13.57 5.16 -11 2 7 16.50 5.49 11 -2 -6 196.26 17.90 11 -2 -6 231.17 18.33 11 -2 -6 175.69 15.93 -11 2 6 194.70 17.91 -11 2 6 205.14 18.25 11 -2 -5 23.72 5.95 -11 2 5 36.68 7.43 11 -2 -5 28.15 6.38 11 -2 -5 33.82 6.97 11 -2 -4 83.02 10.55 -11 2 4 97.21 11.88 11 -2 -4 76.93 10.52 11 -2 -4 85.93 10.22 11 -2 -3 -2.47 4.98 -11 2 3 6.67 3.81 -11 2 3 -1.38 3.14 11 -2 -2 7.46 3.22 11 -2 -2 2.34 4.05 -11 2 2 12.44 4.43 -11 2 2 3.88 3.71 11 -2 -1 189.52 14.77 11 -2 -1 172.55 15.13 -11 2 1 158.76 15.07 -11 2 1 176.41 15.67 11 -2 0 -0.85 2.31 -11 2 0 0.94 2.70 11 -2 0 2.62 2.91 -11 2 0 1.99 2.96 11 -2 1 -2.12 2.51 -11 2 -1 -0.76 2.28 11 -2 1 2.50 2.53 -11 2 -2 7.38 2.16 -11 2 -2 5.30 2.01 11 -1 -12 -0.42 1.57 -11 1 12 1.89 1.82 11 -1 -11 9.83 2.84 11 -1 -11 14.47 3.75 -11 1 11 11.23 3.27 11 -1 -11 13.24 3.12 -11 1 11 10.45 3.13 11 -1 -10 164.43 14.11 -11 1 10 178.18 14.68 -11 1 10 150.38 13.22 11 -1 -10 183.01 13.95 11 -1 -9 53.19 7.69 -11 1 9 34.84 6.58 11 -1 -9 45.87 7.32 -11 1 9 41.88 6.49 -11 1 9 36.54 6.77 -11 1 8 76.30 10.02 11 -1 -8 100.26 11.14 -11 1 7 59.16 8.70 11 -1 -7 59.19 8.85 11 -1 -7 56.12 8.73 11 -1 -6 12.92 4.76 11 -1 -6 13.54 5.00 11 -1 -6 12.69 4.68 -11 1 6 10.89 4.42 -11 1 5 88.83 11.76 11 -1 -5 100.88 11.45 11 -1 -5 112.56 12.42 11 -1 -5 106.68 11.64 11 -1 -4 12.65 4.89 11 -1 -4 7.55 3.85 -11 1 4 10.90 4.56 11 -1 -4 6.10 4.35 -11 1 4 9.57 5.01 -11 1 3 36.30 7.22 11 -1 -3 32.59 6.66 -11 1 3 26.20 6.15 11 -1 -2 3.67 2.97 -11 1 2 5.96 4.11 11 -1 -2 3.41 3.25 -11 1 2 6.09 3.64 11 -1 -1 -0.89 2.30 -11 1 1 -2.09 3.36 -11 1 1 1.09 3.50 11 -1 -1 -4.00 3.55 11 -1 0 8.74 3.26 11 -1 0 12.92 3.92 -11 1 0 16.34 4.39 -11 1 0 12.64 3.88 11 -1 1 38.33 4.75 -11 1 -1 30.98 4.47 -11 1 -1 29.08 4.19 11 0 -12 212.87 13.90 -11 0 11 24.57 4.50 11 0 -11 25.53 4.55 11 0 -11 20.78 3.57 11 0 -11 16.88 3.43 -11 0 11 16.73 3.24 -11 0 11 22.32 4.07 11 0 -10 64.16 8.09 -11 0 10 75.72 7.67 -11 0 10 64.77 8.02 11 0 -10 70.15 7.96 11 0 -9 133.23 12.45 -11 0 9 112.43 11.44 -11 0 9 129.63 11.43 -11 0 9 125.85 12.29 11 0 -9 135.58 12.62 -11 0 8 1.11 2.52 11 0 -8 1.12 3.06 -11 0 8 0.90 2.68 -11 0 8 -3.49 4.13 11 0 -7 -1.18 3.51 11 0 -7 2.39 3.56 -11 0 7 -2.50 3.23 -11 0 7 -1.19 2.89 -11 0 7 1.11 2.34 -11 0 7 -2.85 3.47 11 0 -6 154.09 14.25 -11 0 6 139.69 13.19 11 0 -6 136.54 13.67 -11 0 6 132.77 12.41 11 0 -6 134.85 12.83 -11 0 6 149.36 14.76 -11 0 5 42.12 7.28 11 0 -5 28.36 6.13 -11 0 5 30.16 7.12 11 0 -5 36.75 6.71 11 0 -5 25.00 6.07 -11 0 4 115.42 12.35 11 0 -4 111.73 11.97 11 0 -4 111.79 11.77 11 0 -4 106.20 10.96 -11 0 3 212.52 17.34 11 0 -3 198.30 17.11 -11 0 2 74.16 8.96 11 0 -2 63.63 8.03 -11 0 2 87.36 10.09 11 0 -2 71.33 9.10 -11 0 1 7.54 3.26 11 0 -1 12.31 3.56 -11 0 1 12.92 4.30 11 0 -1 6.41 3.47 -11 0 0 0.59 1.97 11 0 0 2.11 2.27 -11 0 0 4.05 2.61 11 0 0 -1.42 2.73 -11 0 -1 48.84 5.81 -11 0 -1 44.16 4.70 11 0 1 49.77 5.36 11 1 -12 44.97 4.61 -11 -1 11 30.05 4.07 11 1 -11 33.71 4.23 -11 -1 11 32.14 4.42 11 1 -11 31.46 4.71 11 1 -11 21.58 3.51 11 1 -10 70.63 7.81 -11 -1 10 66.28 7.33 -11 -1 10 65.25 7.42 11 1 -10 71.21 7.74 11 1 -9 2.87 3.20 11 1 -9 1.82 3.13 -11 -1 9 1.80 3.10 -11 -1 9 0.84 2.60 11 1 -8 57.37 7.71 -11 -1 8 53.23 7.35 -11 -1 8 49.18 7.51 11 1 -7 125.15 12.56 11 1 -7 143.32 12.81 -11 -1 7 120.68 11.79 -11 -1 7 95.83 11.13 -11 -1 7 133.25 12.69 11 1 -6 122.66 11.80 -11 -1 6 142.75 13.53 11 1 -6 162.64 14.05 11 1 -6 118.19 12.03 -11 -1 6 136.39 12.63 -11 -1 6 116.85 12.19 -11 -1 6 140.45 13.19 11 1 -5 6.32 3.85 -11 -1 5 7.59 3.50 11 1 -5 11.09 4.26 -11 -1 5 6.54 3.26 11 1 -5 5.28 3.53 -11 -1 5 -1.17 3.36 11 1 -4 63.00 7.89 -11 -1 4 55.86 7.82 -11 -1 4 65.63 8.99 11 1 -4 68.99 8.86 -11 -1 3 72.33 8.73 11 1 -3 90.02 10.13 -11 -1 3 93.82 10.30 11 1 -3 70.75 7.79 -11 -1 2 -1.98 2.95 11 1 -2 -2.87 3.39 -11 -1 2 2.22 2.29 11 1 -2 0.77 2.30 -11 -1 2 1.49 2.49 11 1 -1 0.70 2.34 -11 -1 1 2.52 2.90 11 1 -1 2.38 2.73 -11 -1 1 -1.71 1.96 -11 -1 0 0.60 1.93 11 1 0 -0.57 1.76 11 1 0 -0.56 2.22 11 2 -11 10.32 2.47 -11 -2 11 10.32 2.86 11 2 -11 12.41 2.63 11 2 -10 248.06 15.66 -11 -2 10 244.02 16.24 -11 -2 10 200.12 14.37 11 2 -10 245.69 16.29 11 2 -9 52.83 6.44 -11 -2 9 52.37 7.04 -11 -2 9 65.19 6.91 11 2 -9 52.10 7.04 11 2 -8 15.58 3.84 -11 -2 8 11.54 3.67 -11 -2 8 8.76 3.42 11 2 -8 14.72 4.59 -11 -2 7 244.90 18.48 11 2 -7 271.92 19.77 -11 -2 7 258.33 18.70 -11 -2 7 250.40 18.17 -11 -2 6 -0.93 3.59 11 2 -6 4.05 3.15 -11 -2 6 0.85 2.54 11 2 -6 4.15 2.86 -11 -2 6 1.92 2.49 11 2 -5 32.32 5.90 -11 -2 5 34.19 5.50 -11 -2 5 44.87 6.70 11 2 -5 25.25 5.46 11 2 -4 85.52 8.68 11 2 -4 105.05 10.46 -11 -2 4 86.55 9.60 11 2 -3 71.58 7.30 -11 -2 3 77.75 8.22 11 2 -3 85.99 9.22 -11 -2 3 77.02 8.61 11 2 -2 -1.25 2.02 -11 -2 2 2.00 2.43 -11 -2 2 4.65 2.67 11 2 -2 -2.40 2.67 11 2 -1 70.16 6.67 -11 -2 1 64.08 6.20 11 2 -1 81.14 7.53 -11 -2 0 12.21 2.53 -11 -3 11 15.00 2.63 -11 -3 11 16.68 2.95 -11 -3 10 6.73 2.41 -11 -3 10 2.92 2.53 11 3 -10 2.83 2.29 -11 -3 9 8.95 2.87 -11 -3 9 18.15 3.94 11 3 -9 12.60 3.77 11 3 -8 60.88 7.73 -11 -3 8 78.37 7.51 -11 -3 8 74.46 7.93 11 3 -8 75.36 8.40 -11 -3 7 -0.82 2.73 11 3 -7 -0.89 2.95 11 3 -7 0.84 3.06 -11 -3 7 -0.63 2.12 11 3 -6 0.86 2.95 -11 -3 6 1.38 2.31 11 3 -6 2.68 2.45 11 3 -5 63.00 7.42 11 3 -5 74.69 7.92 -11 -3 5 76.67 7.80 -11 -3 4 29.59 4.63 11 3 -4 24.39 5.04 -11 -3 4 34.61 5.24 -11 -3 3 70.15 6.92 11 3 -3 66.49 7.24 -11 -3 3 58.42 6.14 -11 -3 2 14.41 3.42 11 3 -2 8.83 2.22 -11 -3 2 11.56 2.83 11 3 -2 7.26 2.70 -11 -4 10 2.63 1.62 -11 -4 10 -0.44 1.74 11 4 -10 3.94 1.52 -11 -4 9 32.24 4.20 -11 -4 9 38.66 4.86 11 4 -9 35.60 4.86 11 4 -8 77.62 7.68 -11 -4 8 72.40 6.71 11 4 -7 169.58 12.21 -11 -4 7 127.48 9.91 11 4 -6 5.85 2.87 -11 -4 6 6.83 2.50 11 4 -6 6.78 2.08 11 4 -5 77.04 6.89 -11 -4 5 75.57 7.29 11 4 -4 25.36 4.18 -11 -4 4 28.64 4.29 -11 -4 3 19.39 3.06 -11 -4 3 16.63 3.04 11 4 -3 10.88 2.72 11 5 -8 11.00 2.51 11 5 -7 8.58 2.26 -11 -5 7 6.58 2.06 -12 7 6 56.37 5.81 12 -7 -5 2.13 2.01 -12 7 5 1.73 2.22 -12 7 4 24.00 3.98 12 -7 -4 28.48 3.99 12 -7 -3 11.60 2.93 -12 7 3 6.08 2.33 12 -7 -3 12.45 3.06 -12 7 2 9.98 2.47 -12 6 7 78.72 7.31 12 -6 -7 92.89 8.07 -12 6 6 7.30 2.29 12 -6 -6 10.38 2.97 -12 6 6 8.04 2.70 12 -6 -6 11.30 3.32 -12 6 5 13.13 3.14 12 -6 -5 7.45 2.93 -12 6 5 14.54 3.47 12 -6 -5 12.29 3.12 -12 6 4 -1.21 2.01 -12 6 4 1.98 2.55 12 -6 -4 1.54 1.98 12 -6 -4 1.87 2.21 -12 6 3 0.59 1.91 12 -6 -3 5.31 2.75 -12 6 3 4.96 2.45 12 -6 -3 6.99 2.80 -12 6 2 2.12 2.04 12 -6 -2 0.56 1.98 -12 6 2 -2.14 2.40 12 -6 -2 -2.33 2.13 12 -6 -1 76.10 6.68 -12 5 8 -0.95 1.48 12 -5 -8 0.88 1.65 -12 5 8 0.51 1.81 -12 5 7 5.68 2.43 12 -5 -7 1.05 2.03 -12 5 7 1.66 2.08 12 -5 -7 4.81 2.84 12 -5 -7 0.58 2.01 -12 5 7 1.80 2.01 -12 5 6 5.81 2.66 12 -5 -6 4.88 2.55 -12 5 6 0.64 2.20 12 -5 -6 0.72 2.32 -12 5 6 6.45 2.78 12 -5 -6 5.18 2.11 -12 5 5 289.64 18.96 12 -5 -5 270.79 18.78 -12 5 5 254.46 17.84 12 -5 -5 270.65 18.27 12 -5 -5 281.23 18.08 -12 5 5 294.01 18.28 -12 5 4 0.79 2.25 -12 5 4 5.32 2.69 12 -5 -4 1.17 2.01 -12 5 4 3.62 2.26 12 -5 -4 -1.43 2.38 -12 5 3 8.32 3.09 12 -5 -3 12.52 3.45 -12 5 3 9.83 2.89 12 -5 -3 10.01 3.24 -12 5 2 53.29 6.21 12 -5 -2 55.09 6.14 -12 5 2 37.82 4.82 12 -5 -2 54.22 6.23 -12 5 1 -0.56 1.81 12 -5 -1 1.05 2.07 -12 4 9 456.82 26.21 12 -4 -9 482.11 26.49 12 -4 -9 418.89 25.77 -12 4 9 516.73 26.98 -12 4 8 -0.69 1.87 12 -4 -8 -1.27 2.25 -12 4 8 1.37 2.28 -12 4 7 1.60 2.29 12 -4 -7 6.32 2.62 12 -4 -7 8.32 3.26 12 -4 -7 2.96 2.56 -12 4 7 7.64 3.09 -12 4 6 33.89 5.52 12 -4 -6 32.59 5.15 -12 4 6 26.02 4.02 12 -4 -6 27.14 5.06 12 -4 -6 32.16 5.54 -12 4 6 32.17 5.37 12 -4 -6 25.92 4.18 -12 4 5 56.68 7.51 12 -4 -5 66.23 7.60 -12 4 5 50.16 5.96 12 -4 -5 53.47 6.75 12 -4 -5 61.31 6.99 -12 4 5 67.62 7.60 -12 4 4 51.76 6.84 12 -4 -4 60.24 7.14 -12 4 4 36.06 4.88 12 -4 -4 34.46 5.01 -12 4 4 49.11 6.43 12 -4 -4 44.67 6.14 -12 4 3 27.94 5.17 12 -4 -3 30.99 5.13 -12 4 3 22.81 3.79 -12 4 3 35.71 5.09 12 -4 -3 27.36 4.91 -12 4 2 18.19 4.04 12 -4 -2 14.20 3.51 -12 4 2 17.26 3.37 12 -4 -2 13.78 3.69 -12 4 1 0.62 2.07 12 -4 -1 1.10 2.17 -12 3 10 39.66 4.54 12 -3 -9 37.69 4.99 12 -3 -9 25.44 4.21 -12 3 9 32.69 4.81 -12 3 8 34.13 5.20 12 -3 -8 25.44 4.62 12 -3 -8 27.20 4.63 -12 3 8 25.62 4.77 -12 3 7 1.77 2.86 12 -3 -7 4.86 2.87 12 -3 -7 5.56 3.62 -12 3 7 -0.85 2.65 -12 3 6 2.82 2.69 12 -3 -6 3.28 2.92 12 -3 -6 9.61 3.39 -12 3 6 7.13 3.52 12 -3 -6 6.74 2.85 -12 3 5 21.93 4.72 12 -3 -5 21.59 4.28 -12 3 5 16.01 4.21 12 -3 -5 12.67 3.49 -12 3 4 12.08 4.08 12 -3 -4 19.56 3.70 -12 3 4 21.26 4.59 12 -3 -4 15.06 4.00 -12 3 3 71.02 8.32 12 -3 -3 78.82 8.24 -12 3 3 71.08 7.91 12 -3 -2 3.82 2.57 -12 3 2 1.95 2.31 12 -3 -2 0.69 2.45 12 -3 -1 34.06 4.44 -12 3 1 25.29 3.71 12 -2 -9 3.73 2.46 12 -2 -9 0.65 2.11 -12 2 9 2.05 2.20 12 -2 -8 1.98 1.66 12 -2 -8 10.45 3.47 12 -2 -8 6.12 3.17 -12 2 8 11.25 3.73 -12 2 7 291.69 19.47 12 -2 -7 285.85 18.77 12 -2 -7 250.74 18.37 -12 2 7 232.32 18.50 12 -2 -6 88.62 9.28 12 -2 -6 111.38 10.24 12 -2 -6 88.23 8.16 -12 2 6 89.70 9.75 12 -2 -5 36.99 5.43 -12 2 5 25.54 5.47 12 -2 -5 29.04 5.18 -12 2 4 18.85 4.51 -12 2 4 12.20 4.19 12 -2 -4 20.38 4.50 -12 2 3 20.39 4.30 12 -2 -3 18.11 4.49 -12 2 2 51.48 6.13 -12 2 2 46.70 6.01 12 -2 -2 48.10 5.84 -12 2 1 5.45 2.18 12 -2 -1 2.97 2.05 12 -1 -10 1.46 1.68 -12 1 10 2.84 1.83 12 -1 -9 28.96 4.66 12 -1 -9 34.85 4.87 -12 1 9 30.43 4.61 12 -1 -8 8.09 3.11 -12 1 8 7.91 3.06 12 -1 -8 2.97 2.15 12 -1 -8 8.06 3.35 12 -1 -7 11.73 3.75 -12 1 7 17.89 4.20 12 -1 -7 12.62 3.78 -12 1 6 21.83 4.66 12 -1 -6 28.25 4.96 12 -1 -6 17.79 4.21 12 -1 -6 13.39 3.25 -12 1 5 6.84 3.04 12 -1 -5 4.71 2.90 -12 1 5 -0.87 2.72 12 -1 -5 2.82 2.50 -12 1 4 0.79 2.37 -12 1 4 -0.83 2.37 12 -1 -4 2.22 2.63 -12 1 3 33.04 4.97 -12 1 3 35.95 5.44 12 -1 -3 32.20 5.05 -12 1 2 4.18 2.12 -12 1 2 3.10 2.14 12 -1 -2 5.31 2.60 -12 0 9 68.73 6.96 12 0 -9 63.37 6.66 -12 0 8 3.38 2.67 12 0 -8 0.68 2.50 12 0 -8 1.26 2.17 -12 0 8 6.67 2.64 -12 0 7 36.94 5.35 12 0 -7 36.13 5.30 12 0 -7 22.85 4.38 -12 0 7 29.75 4.97 -12 0 6 12.38 3.40 12 0 -6 8.25 3.26 -12 0 6 4.68 2.79 12 0 -6 7.09 2.34 -12 0 5 69.50 7.07 12 0 -5 53.54 6.17 -12 0 5 60.51 7.16 12 0 -5 67.56 7.01 -12 0 4 105.69 9.00 12 0 -4 102.60 9.23 12 0 -3 17.42 3.61 12 0 -2 0.47 1.53 -12 -1 8 8.33 2.19 12 1 -8 3.56 2.18 12 1 -8 3.47 1.88 -12 -1 8 4.45 2.14 12 1 -7 75.46 7.34 -12 -1 7 91.29 7.57 12 1 -6 3.40 2.13 -12 -1 6 1.88 1.68 -12 -1 6 5.53 2.70 -12 -1 5 4.25 2.23 12 1 -5 3.01 2.08 12 1 -5 3.41 1.81 -12 -1 5 5.56 2.08 12 1 -4 30.69 4.16 -12 -1 4 28.91 4.41 -12 -1 3 0.45 1.46 12 1 -3 -1.82 1.76 12 2 -8 14.13 2.80 12 2 -7 52.81 5.40 -12 -2 6 19.32 3.10 0 0 0 0.00 0.00 TITL SK_929_C2_red1_abs1 in P-1 REM P-1 (#2 in standard setting) CELL 1.54184 10.098681 12.274358 12.484186 99.4482 110.7013 100.6963 ZERR 2.00 0.000332 0.000396 0.000454 0.0029 0.0032 0.0027 LATT 1 SFAC C H N O Br UNIT 44.00 34.00 6.00 12.00 6.00 REM CrysAlisPro recorded range (K): Min=100.0; max=100.0; aver:100.0 TEMP -173 SIZE 0.04 0.07 0.09 TREF HKLF 4 END _computing_structure_solution 'SHELXT 2018/2 (Sheldrick, 2018)' _computing_structure_solution 'SHELXT 2018/2 (Sheldrick, 2018)' ; _shelx_hkl_checksum 87558 _shelx_res_file ; TITL sk_929_c2_red1_abs1_a.res in P-1 sk_929_c2_red1_abs1.res created by SHELXL-2018/3 at 11:40:50 on 06-Jul-2023 REM Old TITL sk_929_c2_red1_abs1_a.res in P-1 REM SHELXT solution in P-1: R1 0.192, Rweak 0.008, Alpha 0.043 REM 0.000 for 0 systematic absences, Orientation as input REM Formula found by SHELXT: C24 N4 O8 Br3 CELL 1.54184 10.0987 12.2744 12.4842 99.448 110.701 100.696 ZERR 2 0.0003 0.0004 0.0005 0.003 0.003 0.003 LATT 1 SFAC C H Br Cl N O S UNIT 49.17 35.17 6 3.51 4 12 2 RIGU C1A Cl2 Cl3 Cl1 L.S. 99 PLAN 2 SIZE 0.042 0.067 0.091 TEMP -173 CONF MORE -1 BOND $H LIST 4 fmap 2 53 53 acta MERG 2 REM REM REM WGHT 0.075600 3.234700 FVAR 0.37393 0.58531 BR1 3 0.584506 0.421318 0.593149 11.00000 0.03644 0.02050 = 0.03326 0.01161 0.02579 0.00951 BR2 3 0.731536 0.149553 0.792059 11.00000 0.04078 0.02585 = 0.03375 0.01486 0.02483 0.01040 BR3 3 1.007618 0.568298 0.866218 11.00000 0.03905 0.02536 = 0.02701 0.00274 0.01907 0.00873 S1 7 0.681282 0.126265 0.413637 11.00000 0.03312 0.01679 = 0.02325 0.00413 0.01908 0.00631 O2 6 0.634457 0.043006 0.469546 11.00000 0.03816 0.01652 = 0.02692 0.00530 0.02063 0.00526 O4 6 0.113242 0.145379 0.775355 11.00000 0.03184 0.03806 = 0.03574 0.01147 0.02367 0.00236 O1 6 0.747874 0.097262 0.332894 11.00000 0.03738 0.02124 = 0.02803 0.00345 0.02318 0.00862 O3 6 0.120702 0.096351 0.590344 11.00000 0.02985 0.02303 = 0.03158 0.00499 0.01813 0.00180 O6 6 0.671298 0.495979 0.922758 11.00000 0.03292 0.02399 = 0.03067 0.00150 0.02103 0.00371 O5 6 0.604949 0.418486 1.045745 11.00000 0.03762 0.04547 = 0.02263 0.00511 0.01831 0.00785 N1 5 0.805720 0.236665 0.521882 11.00000 0.02971 0.02039 = 0.02131 0.00466 0.01821 0.00503 N2 5 0.594323 0.419551 0.944921 11.00000 0.02985 0.02725 = 0.02487 0.00489 0.01826 0.00859 C20 1 0.245140 0.202154 0.778237 11.00000 0.02769 0.02685 = 0.03366 0.01303 0.02184 0.00843 C19 1 0.249640 0.171748 0.667803 11.00000 0.03035 0.01719 = 0.02551 0.00566 0.01578 0.00505 C2 1 0.942852 0.349724 0.706617 11.00000 0.03137 0.02057 = 0.02689 0.00907 0.02074 0.00910 C9 1 0.535455 0.183222 0.345180 11.00000 0.03460 0.01900 = 0.02433 0.00322 0.01764 0.00960 C8 1 1.159598 0.441791 0.658572 11.00000 0.02860 0.02332 = 0.02724 0.00584 0.01832 0.00750 AFIX 43 H8 2 1.219006 0.487579 0.736352 11.00000 -1.20000 AFIX 0 C10 1 0.559267 0.266248 0.285832 11.00000 0.03862 0.02040 = 0.03027 0.00638 0.02205 0.00843 AFIX 43 H10 2 0.651715 0.290181 0.281265 11.00000 -1.20000 AFIX 0 C24 1 1.002159 0.404414 0.836088 11.00000 0.03453 0.02335 = 0.02553 0.00602 0.01958 0.00533 AFIX 23 H24A 2 1.102550 0.395934 0.874397 11.00000 -1.20000 H24B 2 0.939908 0.364847 0.871497 11.00000 -1.20000 AFIX 0 C16 1 0.628530 0.334246 0.715645 11.00000 0.03259 0.01784 = 0.02289 0.00498 0.02102 0.00706 AFIX 13 H16 2 0.708992 0.384543 0.790336 11.00000 -1.20000 AFIX 0 C15 1 0.681009 0.233880 0.667916 11.00000 0.03325 0.01751 = 0.02347 0.00579 0.01993 0.00682 AFIX 13 H15 2 0.598316 0.182040 0.595478 11.00000 -1.20000 AFIX 0 C21 1 0.357787 0.281956 0.870059 11.00000 0.03563 0.03123 = 0.02649 0.01006 0.02325 0.00922 AFIX 43 H21 2 0.354011 0.304239 0.945258 11.00000 -1.20000 AFIX 0 C7 1 1.206060 0.445772 0.566790 11.00000 0.02949 0.02376 = 0.03811 0.00851 0.02338 0.00529 AFIX 43 H7 2 1.298673 0.494833 0.581795 11.00000 -1.20000 AFIX 0 C4 1 0.937680 0.300243 0.519350 11.00000 0.03012 0.01981 = 0.02589 0.00753 0.01863 0.00775 C3 1 1.022612 0.368330 0.633231 11.00000 0.02980 0.02061 = 0.02730 0.00929 0.01926 0.00964 C17 1 0.490854 0.295963 0.738047 11.00000 0.03349 0.01756 = 0.02589 0.00767 0.02199 0.00693 C22 1 0.480513 0.329599 0.846839 11.00000 0.03012 0.02057 = 0.02589 0.00660 0.01934 0.00586 C18 1 0.370262 0.215408 0.645644 11.00000 0.03137 0.01985 = 0.02409 0.00382 0.01838 0.00688 AFIX 43 H18 2 0.372040 0.191755 0.569903 11.00000 -1.20000 AFIX 0 C23 1 0.038760 0.068130 0.660692 11.00000 0.02994 0.02271 = 0.03496 0.00779 0.01948 0.00287 AFIX 23 H23A 2 -0.062233 0.075806 0.623430 11.00000 -1.20000 H23B 2 0.032817 -0.011831 0.667024 11.00000 -1.20000 AFIX 0 C6 1 1.117943 0.378290 0.452381 11.00000 0.03846 0.02582 = 0.03097 0.01100 0.02696 0.01033 AFIX 43 H6 2 1.151707 0.383937 0.390962 11.00000 -1.20000 AFIX 0 C1 1 0.810233 0.272419 0.637766 11.00000 0.03306 0.02145 = 0.02258 0.00741 0.02018 0.00735 C5 1 0.982340 0.303055 0.425336 11.00000 0.03661 0.02528 = 0.02511 0.00697 0.02156 0.00875 AFIX 43 H5 2 0.923686 0.256456 0.347776 11.00000 -1.20000 AFIX 0 C11 1 0.446287 0.313396 0.233594 11.00000 0.05238 0.02534 = 0.03629 0.01129 0.02586 0.01472 AFIX 43 H11 2 0.460782 0.370752 0.193161 11.00000 -1.20000 AFIX 0 C14 1 0.400904 0.145514 0.352201 11.00000 0.04081 0.02083 = 0.03548 0.00485 0.02617 0.00686 AFIX 43 H14 2 0.386714 0.088451 0.393030 11.00000 -1.20000 AFIX 0 C12 1 0.311042 0.276788 0.240232 11.00000 0.04659 0.03203 = 0.04689 0.01078 0.02393 0.01857 AFIX 43 H12 2 0.233581 0.309611 0.204504 11.00000 -1.20000 AFIX 0 C13 1 0.288500 0.192458 0.298828 11.00000 0.03831 0.03613 = 0.05651 0.01292 0.03035 0.01266 AFIX 43 H13 2 0.195483 0.167228 0.302029 11.00000 -1.20000 AFIX 0 CL2 4 0.302774 0.054732 0.034310 21.00000 0.15354 0.04410 = 0.06022 0.02126 0.04937 0.01848 CL3 4 0.052636 -0.112192 -0.114466 21.00000 0.07943 0.10254 = 0.12378 0.05090 0.03905 0.01477 CL1 4 0.320472 -0.170960 -0.063882 21.00000 0.17534 0.08245 = 0.06213 0.04917 0.09055 0.08503 C1A 1 0.246668 -0.053930 -0.077199 21.00000 0.15225 0.05057 = 0.04437 0.01411 0.05350 0.02105 AFIX 13 H1A 2 0.257878 -0.026390 -0.145381 21.00000 -1.20000 AFIX 0 HKLF 4 REM sk_929_c2_red1_abs1_a.res in P-1 REM wR2 = 0.1336, GooF = S = 1.070, Restrained GooF = 1.069 for all data REM R1 = 0.0437 for 5068 Fo > 4sig(Fo) and 0.0493 for all 5783 data REM 362 parameters refined using 15 restraints END WGHT 0.0756 3.2348 REM Highest difference peak 2.451, deepest hole -1.182, 1-sigma level 0.145 Q1 1 0.4678 0.0063 -0.0483 11.00000 0.05 2.45 Q2 1 0.2367 0.0169 -0.0217 11.00000 0.05 1.48 ; _shelx_res_checksum 32886 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, -y, -z' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Br Br1 0.58451(5) 0.42132(3) 0.59315(4) 0.02570(13) Uani d 1 . . Br Br2 0.73154(5) 0.14955(4) 0.79206(4) 0.02939(13) Uani d 1 . . Br Br3 1.00762(5) 0.56830(4) 0.86622(4) 0.02920(13) Uani d 1 . . S S1 0.68128(11) 0.12626(8) 0.41364(8) 0.0223(2) Uani d 1 . . O O2 0.6345(3) 0.0430(2) 0.4695(3) 0.0253(6) Uani d 1 . . O O4 0.1132(3) 0.1454(3) 0.7754(3) 0.0330(7) Uani d 1 . . O O1 0.7479(3) 0.0973(2) 0.3329(3) 0.0262(6) Uani d 1 . . O O3 0.1207(3) 0.0964(3) 0.5903(3) 0.0274(6) Uani d 1 . . O O6 0.6713(3) 0.4960(3) 0.9228(3) 0.0280(6) Uani d 1 . . O O5 0.6049(4) 0.4185(3) 1.0457(3) 0.0343(7) Uani d 1 . . N N1 0.8057(4) 0.2367(3) 0.5219(3) 0.0218(7) Uani d 1 . . N N2 0.5943(4) 0.4196(3) 0.9449(3) 0.0252(7) Uani d 1 . . C C20 0.2451(5) 0.2022(4) 0.7782(4) 0.0257(8) Uani d 1 . . C C19 0.2496(4) 0.1717(3) 0.6678(4) 0.0231(8) Uani d 1 . . C C2 0.9429(5) 0.3497(3) 0.7066(4) 0.0229(8) Uani d 1 . . C C9 0.5355(5) 0.1832(3) 0.3452(4) 0.0242(8) Uani d 1 . . C C8 1.1596(5) 0.4418(4) 0.6586(4) 0.0243(8) Uani d 1 . . H H8 1.219006 0.487579 0.736352 0.029 Uiso calc 1 . . C C10 0.5593(5) 0.2662(4) 0.2858(4) 0.0272(8) Uani d 1 . . H H10 0.651715 0.290181 0.281265 0.033 Uiso calc 1 . . C C24 1.0022(5) 0.4044(4) 0.8361(4) 0.0259(8) Uani d 1 . . H H24A 1.102550 0.395934 0.874397 0.031 Uiso calc 1 . . H H24B 0.939908 0.364847 0.871497 0.031 Uiso calc 1 . . C C16 0.6285(4) 0.3342(3) 0.7156(3) 0.0215(7) Uani d 1 . . H H16 0.708992 0.384543 0.790336 0.026 Uiso calc 1 . . C C15 0.6810(5) 0.2339(3) 0.6679(4) 0.0221(8) Uani d 1 . . H H15 0.598316 0.182040 0.595478 0.027 Uiso calc 1 . . C C21 0.3578(5) 0.2820(4) 0.8701(4) 0.0275(9) Uani d 1 . . H H21 0.354011 0.304239 0.945258 0.033 Uiso calc 1 . . C C7 1.2061(5) 0.4458(4) 0.5668(4) 0.0277(9) Uani d 1 . . H H7 1.298673 0.494833 0.581795 0.033 Uiso calc 1 . . C C4 0.9377(4) 0.3002(3) 0.5193(4) 0.0227(8) Uani d 1 . . C C3 1.0226(4) 0.3683(3) 0.6332(4) 0.0228(8) Uani d 1 . . C C17 0.4909(5) 0.2960(3) 0.7380(4) 0.0224(8) Uani d 1 . . C C22 0.4805(5) 0.3296(3) 0.8468(4) 0.0232(8) Uani d 1 . . C C18 0.3703(5) 0.2154(3) 0.6456(4) 0.0232(8) Uani d 1 . . H H18 0.372040 0.191755 0.569903 0.028 Uiso calc 1 . . C C23 0.0388(5) 0.0681(4) 0.6607(4) 0.0278(8) Uani d 1 . . H H23A -0.062233 0.075806 0.623430 0.033 Uiso calc 1 . . H H23B 0.032817 -0.011831 0.667024 0.033 Uiso calc 1 . . C C6 1.1179(5) 0.3783(4) 0.4524(4) 0.0272(9) Uani d 1 . . H H6 1.151707 0.383937 0.390962 0.033 Uiso calc 1 . . C C1 0.8102(5) 0.2724(3) 0.6378(4) 0.0228(8) Uani d 1 . . C C5 0.9823(5) 0.3031(4) 0.4253(4) 0.0261(8) Uani d 1 . . H H5 0.923686 0.256456 0.347776 0.031 Uiso calc 1 . . C C11 0.4463(6) 0.3134(4) 0.2336(4) 0.0345(10) Uani d 1 . . H H11 0.460782 0.370752 0.193161 0.041 Uiso calc 1 . . C C14 0.4009(5) 0.1455(4) 0.3522(4) 0.0296(9) Uani d 1 . . H H14 0.386714 0.088451 0.393030 0.036 Uiso calc 1 . . C C12 0.3110(6) 0.2768(4) 0.2402(5) 0.0390(11) Uani d 1 . . H H12 0.233581 0.309611 0.204504 0.047 Uiso calc 1 . . C C13 0.2885(6) 0.1925(4) 0.2988(5) 0.0397(11) Uani d 1 . . H H13 0.195483 0.167228 0.302029 0.048 Uiso calc 1 . . Cl Cl2 0.3028(5) 0.0547(3) 0.0343(3) 0.0840(13) Uani d 0.585(4) . . Cl Cl3 0.0526(5) -0.1122(4) -0.1145(5) 0.1007(15) Uani d 0.585(4) . . Cl Cl1 0.3205(5) -0.1710(3) -0.0639(3) 0.0828(13) Uani d 0.585(4) . . C C1A 0.247(2) -0.0539(11) -0.0772(11) 0.079(4) Uani d 0.585(4) . . H H1A 0.257878 -0.026390 -0.145381 0.094 Uiso calc 0.585(4) . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Br1 0.0364(2) 0.0205(2) 0.0333(2) 0.00951(17) 0.02579(19) 0.01161(17) Br2 0.0408(3) 0.0259(2) 0.0337(2) 0.01040(18) 0.0248(2) 0.01486(19) Br3 0.0391(3) 0.0254(2) 0.0270(2) 0.00873(18) 0.01907(19) 0.00274(17) S1 0.0331(5) 0.0168(4) 0.0233(4) 0.0063(4) 0.0191(4) 0.0041(4) O2 0.0382(16) 0.0165(13) 0.0269(14) 0.0053(11) 0.0206(12) 0.0053(11) O4 0.0318(16) 0.0381(18) 0.0357(17) 0.0024(13) 0.0237(14) 0.0115(14) O1 0.0374(16) 0.0212(14) 0.0280(14) 0.0086(12) 0.0232(13) 0.0034(12) O3 0.0298(14) 0.0230(14) 0.0316(15) 0.0018(11) 0.0181(12) 0.0050(12) O6 0.0329(15) 0.0240(14) 0.0307(15) 0.0037(12) 0.0210(13) 0.0015(12) O5 0.0376(17) 0.0455(19) 0.0226(15) 0.0078(14) 0.0183(13) 0.0051(14) N1 0.0297(17) 0.0204(16) 0.0213(16) 0.0050(13) 0.0182(13) 0.0047(13) N2 0.0299(17) 0.0273(18) 0.0249(17) 0.0086(14) 0.0183(14) 0.0049(14) C20 0.028(2) 0.027(2) 0.034(2) 0.0084(16) 0.0218(17) 0.0130(17) C19 0.030(2) 0.0172(18) 0.0255(19) 0.0051(15) 0.0158(16) 0.0057(15) C2 0.031(2) 0.0206(18) 0.027(2) 0.0091(15) 0.0207(17) 0.0091(16) C9 0.035(2) 0.0190(18) 0.0243(19) 0.0096(16) 0.0176(16) 0.0032(15) C8 0.0286(19) 0.0233(19) 0.027(2) 0.0075(16) 0.0183(16) 0.0058(16) C10 0.039(2) 0.0204(19) 0.030(2) 0.0084(17) 0.0221(18) 0.0064(17) C24 0.035(2) 0.023(2) 0.026(2) 0.0053(16) 0.0196(17) 0.0060(16) C16 0.033(2) 0.0178(17) 0.0229(18) 0.0071(15) 0.0210(16) 0.0050(15) C15 0.033(2) 0.0175(18) 0.0235(18) 0.0068(15) 0.0199(16) 0.0058(15) C21 0.036(2) 0.031(2) 0.026(2) 0.0092(18) 0.0232(18) 0.0101(17) C7 0.029(2) 0.024(2) 0.038(2) 0.0053(16) 0.0234(18) 0.0085(18) C4 0.030(2) 0.0198(18) 0.0259(19) 0.0078(15) 0.0186(16) 0.0075(15) C3 0.0298(19) 0.0206(18) 0.027(2) 0.0096(15) 0.0193(16) 0.0093(16) C17 0.033(2) 0.0176(17) 0.0259(19) 0.0069(15) 0.0220(17) 0.0077(15) C22 0.030(2) 0.0206(18) 0.0259(19) 0.0059(15) 0.0193(16) 0.0066(16) C18 0.031(2) 0.0198(18) 0.0241(19) 0.0069(15) 0.0184(16) 0.0038(15) C23 0.030(2) 0.023(2) 0.035(2) 0.0029(16) 0.0195(18) 0.0078(17) C6 0.038(2) 0.026(2) 0.031(2) 0.0103(17) 0.0270(18) 0.0110(17) C1 0.033(2) 0.0214(18) 0.0226(19) 0.0074(16) 0.0202(16) 0.0074(15) C5 0.037(2) 0.025(2) 0.0251(19) 0.0087(17) 0.0216(17) 0.0070(16) C11 0.052(3) 0.025(2) 0.036(2) 0.015(2) 0.026(2) 0.0113(19) C14 0.041(2) 0.0208(19) 0.035(2) 0.0069(17) 0.026(2) 0.0049(17) C12 0.047(3) 0.032(2) 0.047(3) 0.019(2) 0.024(2) 0.011(2) C13 0.038(2) 0.036(3) 0.057(3) 0.013(2) 0.030(2) 0.013(2) Cl2 0.154(4) 0.0441(15) 0.0602(18) 0.0185(18) 0.049(2) 0.0213(13) Cl3 0.079(2) 0.103(3) 0.124(4) 0.015(2) 0.039(2) 0.051(3) Cl1 0.175(4) 0.082(2) 0.0621(17) 0.085(2) 0.091(2) 0.0492(16) C1A 0.152(14) 0.051(6) 0.044(6) 0.021(8) 0.054(8) 0.014(5) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Br Br -0.6763 1.2805 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _exptl_crystal_face_index_h _exptl_crystal_face_index_k _exptl_crystal_face_index_l _exptl_crystal_face_perp_dist -1 -4 -4 0.0229 6 -5 -1 0.0418 1 4 4 0.0355 -5 6 1 0.0303 3 -2 -7 0.0378 1 7 -3 0.0176 -3 2 7 0.0436 -2 -7 3 0.0240 2 -8 3 0.0245 0 3 -7 0.0262 0 1 7 0.0350 0 -5 7 0.0247 loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag O2 S1 O1 . . 120.07(17) ? O2 S1 N1 . . 106.78(17) ? O2 S1 C9 . . 109.47(19) ? O1 S1 N1 . . 105.88(17) ? O1 S1 C9 . . 109.04(19) ? N1 S1 C9 . . 104.44(18) ? C20 O4 C23 . . 105.7(3) ? C19 O3 C23 . . 105.4(3) ? C4 N1 S1 . . 125.3(3) ? C1 N1 S1 . . 126.2(3) ? C1 N1 C4 . . 107.8(3) ? O6 N2 C22 . . 118.8(3) ? O5 N2 O6 . . 122.9(4) ? O5 N2 C22 . . 118.2(3) ? O4 C20 C19 . . 109.9(4) ? C21 C20 O4 . . 128.3(4) ? C21 C20 C19 . . 121.7(4) ? O3 C19 C20 . . 110.1(3) ? O3 C19 C18 . . 127.6(4) ? C18 C19 C20 . . 122.3(4) ? C3 C2 C24 . . 123.9(4) ? C1 C2 C24 . . 128.1(3) ? C1 C2 C3 . . 108.0(4) ? C10 C9 S1 . . 118.3(3) ? C10 C9 C14 . . 121.9(4) ? C14 C9 S1 . . 119.8(3) ? C7 C8 H8 . . 121.0 ? C7 C8 C3 . . 118.1(4) ? C3 C8 H8 . . 121.0 ? C9 C10 H10 . . 120.6 ? C11 C10 C9 . . 118.8(4) ? C11 C10 H10 . . 120.6 ? Br3 C24 H24A . . 109.3 ? Br3 C24 H24B . . 109.3 ? C2 C24 Br3 . . 111.4(3) ? C2 C24 H24A . . 109.3 ? C2 C24 H24B . . 109.3 ? H24A C24 H24B . . 108.0 ? Br1 C16 H16 . . 109.5 ? C15 C16 Br1 . . 106.4(2) ? C15 C16 H16 . . 109.5 ? C17 C16 Br1 . . 108.4(3) ? C17 C16 H16 . . 109.5 ? C17 C16 C15 . . 113.4(3) ? Br2 C15 H15 . . 108.9 ? C16 C15 Br2 . . 106.6(3) ? C16 C15 H15 . . 108.9 ? C1 C15 Br2 . . 110.4(3) ? C1 C15 C16 . . 112.9(3) ? C1 C15 H15 . . 108.9 ? C20 C21 H21 . . 121.9 ? C20 C21 C22 . . 116.2(4) ? C22 C21 H21 . . 121.9 ? C8 C7 H7 . . 119.7 ? C8 C7 C6 . . 120.7(4) ? C6 C7 H7 . . 119.7 ? C3 C4 N1 . . 107.0(3) ? C3 C4 C5 . . 122.4(4) ? C5 C4 N1 . . 130.5(4) ? C8 C3 C2 . . 131.0(4) ? C4 C3 C2 . . 108.6(4) ? C4 C3 C8 . . 120.4(4) ? C22 C17 C16 . . 124.1(4) ? C22 C17 C18 . . 118.3(4) ? C18 C17 C16 . . 117.4(3) ? C21 C22 N2 . . 114.4(3) ? C17 C22 N2 . . 122.5(3) ? C17 C22 C21 . . 123.1(4) ? C19 C18 C17 . . 118.2(4) ? C19 C18 H18 . . 120.9 ? C17 C18 H18 . . 120.9 ? O4 C23 O3 . . 107.8(3) ? O4 C23 H23A . . 110.1 ? O4 C23 H23B . . 110.1 ? O3 C23 H23A . . 110.1 ? O3 C23 H23B . . 110.1 ? H23A C23 H23B . . 108.5 ? C7 C6 H6 . . 118.8 ? C5 C6 C7 . . 122.3(4) ? C5 C6 H6 . . 118.8 ? N1 C1 C15 . . 122.1(4) ? C2 C1 N1 . . 108.5(3) ? C2 C1 C15 . . 129.2(4) ? C4 C5 H5 . . 122.0 ? C6 C5 C4 . . 116.0(4) ? C6 C5 H5 . . 122.0 ? C10 C11 H11 . . 120.0 ? C10 C11 C12 . . 119.9(4) ? C12 C11 H11 . . 120.0 ? C9 C14 H14 . . 120.6 ? C13 C14 C9 . . 118.8(4) ? C13 C14 H14 . . 120.6 ? C11 C12 H12 . . 119.8 ? C13 C12 C11 . . 120.5(5) ? C13 C12 H12 . . 119.8 ? C14 C13 C12 . . 120.1(5) ? C14 C13 H13 . . 120.0 ? C12 C13 H13 . . 120.0 ? Cl2 C1A Cl3 . . 106.5(9) ? Cl2 C1A Cl1 . . 120.0(9) ? Cl2 C1A H1A . . 108.5 ? Cl3 C1A H1A . . 108.5 ? Cl1 C1A Cl3 . . 104.4(7) ? Cl1 C1A H1A . . 108.5 ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag Br1 C16 . 1.978(4) ? Br2 C15 . 1.974(4) ? Br3 C24 . 1.971(4) ? S1 O2 . 1.429(3) ? S1 O1 . 1.430(3) ? S1 N1 . 1.676(3) ? S1 C9 . 1.754(4) ? O4 C20 . 1.369(5) ? O4 C23 . 1.429(6) ? O3 C19 . 1.362(5) ? O3 C23 . 1.443(5) ? O6 N2 . 1.236(5) ? O5 N2 . 1.227(5) ? N1 C4 . 1.427(5) ? N1 C1 . 1.423(5) ? N2 C22 . 1.459(5) ? C20 C19 . 1.387(6) ? C20 C21 . 1.365(6) ? C19 C18 . 1.376(5) ? C2 C24 . 1.494(6) ? C2 C3 . 1.436(5) ? C2 C1 . 1.371(6) ? C9 C10 . 1.389(6) ? C9 C14 . 1.390(6) ? C8 H8 . 0.9500 ? C8 C7 . 1.388(6) ? C8 C3 . 1.400(6) ? C10 H10 . 0.9500 ? C10 C11 . 1.380(7) ? C24 H24A . 0.9900 ? C24 H24B . 0.9900 ? C16 H16 . 1.0000 ? C16 C15 . 1.542(5) ? C16 C17 . 1.519(5) ? C15 H15 . 1.0000 ? C15 C1 . 1.498(5) ? C21 H21 . 0.9500 ? C21 C22 . 1.415(5) ? C7 H7 . 0.9500 ? C7 C6 . 1.399(6) ? C4 C3 . 1.392(6) ? C4 C5 . 1.401(5) ? C17 C22 . 1.399(5) ? C17 C18 . 1.406(6) ? C18 H18 . 0.9500 ? C23 H23A . 0.9900 ? C23 H23B . 0.9900 ? C6 H6 . 0.9500 ? C6 C5 . 1.394(6) ? C5 H5 . 0.9500 ? C11 H11 . 0.9500 ? C11 C12 . 1.392(7) ? C14 H14 . 0.9500 ? C14 C13 . 1.378(7) ? C12 H12 . 0.9500 ? C12 C13 . 1.392(7) ? C13 H13 . 0.9500 ? Cl2 C1A . 1.609(12) ? Cl3 C1A . 1.815(18) ? Cl1 C1A . 1.742(15) ? C1A H1A . 1.0000 ? loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA C8 H8 O5 2_767 0.95 2.58 3.525(6) 170 C13 H13 Cl13 2_555 0.95 2.63 3.244(8) 123 C14 H14 O2 2_656 0.95 2.57 3.518(6) 172 C1A H1A O1 2_655 1.00 2.34 3.169(15) 140 C5 H5 O1 . 0.95 2.32 2.865(6) 116 C15 H15 O2 . 1.00 2.30 2.950(5) 122 C16 H16 O6 . 1.00 2.16 2.832(5) 123 C24 H24B Br2 . 0.99 2.83 3.572(4) 132 loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag Br1 C16 C15 Br2 . . . . 178.14(17) ? Br1 C16 C15 C1 . . . . 56.7(4) ? Br1 C16 C17 C22 . . . . -118.0(4) ? Br1 C16 C17 C18 . . . . 66.7(4) ? Br2 C15 C1 N1 . . . . 119.7(4) ? Br2 C15 C1 C2 . . . . -65.5(5) ? S1 N1 C4 C3 . . . . -168.6(3) ? S1 N1 C4 C5 . . . . 13.3(6) ? S1 N1 C1 C2 . . . . 168.0(3) ? S1 N1 C1 C15 . . . . -16.3(6) ? S1 C9 C10 C11 . . . . -178.7(3) ? S1 C9 C14 C13 . . . . 179.3(4) ? O2 S1 N1 C4 . . . . 139.8(3) ? O2 S1 N1 C1 . . . . -30.3(4) ? O2 S1 C9 C10 . . . . 179.9(3) ? O2 S1 C9 C14 . . . . 0.4(4) ? O4 C20 C19 O3 . . . . 1.0(5) ? O4 C20 C19 C18 . . . . -179.4(4) ? O4 C20 C21 C22 . . . . -178.1(4) ? O1 S1 N1 C4 . . . . 10.7(4) ? O1 S1 N1 C1 . . . . -159.3(3) ? O1 S1 C9 C10 . . . . -47.0(4) ? O1 S1 C9 C14 . . . . 133.6(3) ? O3 C19 C18 C17 . . . . 177.7(4) ? O6 N2 C22 C21 . . . . -150.6(4) ? O6 N2 C22 C17 . . . . 27.7(6) ? O5 N2 C22 C21 . . . . 26.3(5) ? O5 N2 C22 C17 . . . . -155.4(4) ? N1 S1 C9 C10 . . . . 65.9(4) ? N1 S1 C9 C14 . . . . -113.6(3) ? N1 C4 C3 C2 . . . . -1.4(4) ? N1 C4 C3 C8 . . . . -179.5(4) ? N1 C4 C5 C6 . . . . 178.0(4) ? C20 O4 C23 O3 . . . . -10.0(4) ? C20 C19 C18 C17 . . . . -1.8(6) ? C20 C21 C22 N2 . . . . 176.4(4) ? C20 C21 C22 C17 . . . . -1.9(6) ? C19 O3 C23 O4 . . . . 10.5(4) ? C19 C20 C21 C22 . . . . -1.5(6) ? C9 S1 N1 C4 . . . . -104.3(3) ? C9 S1 N1 C1 . . . . 85.7(4) ? C9 C10 C11 C12 . . . . -0.5(7) ? C9 C14 C13 C12 . . . . -0.6(7) ? C8 C7 C6 C5 . . . . -1.3(7) ? C10 C9 C14 C13 . . . . -0.2(7) ? C10 C11 C12 C13 . . . . -0.3(8) ? C24 C2 C3 C8 . . . . -4.9(7) ? C24 C2 C3 C4 . . . . 177.2(4) ? C24 C2 C1 N1 . . . . -175.3(4) ? C24 C2 C1 C15 . . . . 9.4(7) ? C16 C15 C1 N1 . . . . -121.0(4) ? C16 C15 C1 C2 . . . . 53.7(6) ? C16 C17 C22 N2 . . . . 10.0(6) ? C16 C17 C22 C21 . . . . -171.8(4) ? C16 C17 C18 C19 . . . . 174.1(4) ? C15 C16 C17 C22 . . . . 124.1(4) ? C15 C16 C17 C18 . . . . -51.3(5) ? C21 C20 C19 O3 . . . . -176.2(4) ? C21 C20 C19 C18 . . . . 3.4(7) ? C7 C8 C3 C2 . . . . -176.6(4) ? C7 C8 C3 C4 . . . . 1.1(6) ? C7 C6 C5 C4 . . . . 1.1(6) ? C4 N1 C1 C2 . . . . -3.5(4) ? C4 N1 C1 C15 . . . . 172.2(4) ? C3 C2 C24 Br3 . . . . 73.2(5) ? C3 C2 C1 N1 . . . . 2.6(5) ? C3 C2 C1 C15 . . . . -172.7(4) ? C3 C8 C7 C6 . . . . 0.1(6) ? C3 C4 C5 C6 . . . . 0.1(6) ? C17 C16 C15 Br2 . . . . -62.8(4) ? C17 C16 C15 C1 . . . . 175.8(3) ? C22 C17 C18 C19 . . . . -1.5(6) ? C18 C17 C22 N2 . . . . -174.7(4) ? C18 C17 C22 C21 . . . . 3.5(6) ? C23 O4 C20 C19 . . . . 5.7(5) ? C23 O4 C20 C21 . . . . -177.4(4) ? C23 O3 C19 C20 . . . . -7.1(4) ? C23 O3 C19 C18 . . . . 173.3(4) ? C1 N1 C4 C3 . . . . 2.9(4) ? C1 N1 C4 C5 . . . . -175.1(4) ? C1 C2 C24 Br3 . . . . -109.2(4) ? C1 C2 C3 C8 . . . . 177.1(4) ? C1 C2 C3 C4 . . . . -0.8(5) ? C5 C4 C3 C2 . . . . 176.9(4) ? C5 C4 C3 C8 . . . . -1.3(6) ? C11 C12 C13 C14 . . . . 0.9(8) ? C14 C9 C10 C11 . . . . 0.8(6) ? _cod_database_fobs_code 2022839