Crystallography Open Database

Information card for entry 2023525

2023524 << 2023525 >> 2023526

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Coordinates	2023525.cif
Original IUCr paper	HTML

Structure parameters

Chemical name	Di-μ-acetato-bis({<i>N</i>,<i>N</i>-dimethyl-2-[phenyl(pyridin-2-yl)methylidene]hydrazine-1-carbothioamidato}zinc(II))
Formula	C34 H36 N8 O4 S2 Zn2
Calculated formula	C34 H36 N8 O4 S2 Zn2
Title of publication	Syntheses and structures of dinuclear zinc(II) acetate-bridged coordination compounds with the aromatic Schiff base chelators N,N-dimethyl-2-[phenyl(pyridin-2-yl)methylidene]hydrazine-1-carbothioamide and N-ethyl-2-[phenyl(pyridin-2-yl)methylidene]hydrazine-1-carbothioamide
Authors of publication	Parry, Christian S.; Abraham, Alex R.; Kwofie, Samuel K.; Wilson, Michael D.; Ramadhar, Timothy R.; Butcher, Raymond J.
Journal of publication	Acta Crystallographica Section E Crystallographic Communications
Year of publication	2025
Journal volume	81
Journal issue	7
a	10.8384 ± 0.0001 Å
b	20.0381 ± 0.0002 Å
c	8.2914 ± 0.0001 Å
α	90°
β	91.342 ± 0.001°
γ	90°
Cell volume	1800.24 ± 0.03 Å³
Cell temperature	295.8 ± 0.3 K
Ambient diffraction temperature	295.8 ± 0.3 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0783
Residual factor for significantly intense reflections	0.0687
Weighted residual factors for significantly intense reflections	0.2048
Weighted residual factors for all reflections included in the refinement	0.2166
Goodness-of-fit parameter for all reflections included in the refinement	1.049
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
300213 (current)	2025-06-26	cif/ Adding structures of 2023525, 2023526 via cif-deposit CGI script.	2023525.cif