#------------------------------------------------------------------------------ #$Date: 2009-12-10 09:06:56 +0200 (Thu, 10 Dec 2009) $ #$Revision: 927 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2223859.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2223859_Fobs loop_ _publ_author_name 'Zhang, Chang-Hua' 'Tan, Xue-Jie' 'Xing, Dian-Xiang' _publ_section_title ; Methyl pyrazine-2-carboxylate ; _journal_coeditor_code IM2150 _journal_issue 11 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o2902 _journal_volume 65 _journal_year 2009 _space_group_IT_number 19 _symmetry_space_group_name_Hall 'P 2ac 2ab' _symmetry_space_group_name_H-M 'P 21 21 21' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 3.8652 _cell_length_b 6.6897 _cell_length_c 24.9205 _exptl_crystal_F_000 288.00 _reflns_d_resolution_high 0.8257 _[local]_cod_data_source_file im2150Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 90918bm in P2(1)2(1)2(1)' _shelx_refln_list_code 4 _shelx_f_calc_maximum 76.72 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 127.38 129.05 13.70 o 4 0 0 17.51 17.81 5.15 o 1 1 0 247.40 227.77 6.52 o 2 1 0 91.72 124.33 11.52 o 3 1 0 13.63 19.30 5.25 o 4 1 0 0.78 8.25 2.32 o 0 2 0 1663.28 2199.18 27.21 o 1 2 0 113.62 108.38 3.52 o 2 2 0 162.12 148.76 7.47 o 3 2 0 28.05 23.76 5.75 o 4 2 0 7.19 14.67 7.10 o 1 3 0 150.14 155.17 5.81 o 2 3 0 21.51 19.18 3.50 o 3 3 0 8.51 9.23 3.50 o 4 3 0 1.03 12.58 7.83 o 0 4 0 8.53 8.78 3.51 o 1 4 0 103.33 109.76 5.11 o 2 4 0 41.73 40.40 5.35 o 3 4 0 16.64 20.47 5.41 o 4 4 0 8.28 16.06 7.02 o 1 5 0 69.69 68.75 5.59 o 2 5 0 185.83 151.03 10.87 o 3 5 0 3.25 7.65 4.64 o 0 6 0 990.90 1280.63 55.16 o 1 6 0 139.24 127.90 11.99 o 2 6 0 41.01 29.48 8.60 o 3 6 0 17.82 18.35 6.20 o 1 7 0 0.05 9.35 6.61 o 2 7 0 4.36 9.37 7.84 o 0 8 0 47.83 50.24 16.74 o 1 0 1 36.77 33.93 3.85 o 2 0 1 42.24 60.86 7.32 o 3 0 1 50.37 40.14 13.28 o 4 0 1 15.14 13.17 3.24 o 0 1 1 617.09 758.29 7.45 o 1 1 1 3833.85 3751.60 46.91 o 2 1 1 750.59 722.75 14.38 o 3 1 1 54.72 54.88 9.85 o 4 1 1 0.69 6.90 3.01 o 0 2 1 889.96 1190.79 18.57 o 1 2 1 144.20 142.16 2.72 o 2 2 1 150.60 143.89 5.38 o 3 2 1 29.28 21.75 3.87 o 4 2 1 0.15 6.64 2.07 o 0 3 1 33.37 40.41 2.91 o 1 3 1 15.50 18.64 1.65 o 2 3 1 12.34 10.99 1.94 o 3 3 1 4.01 4.07 2.19 o 4 3 1 1.38 11.31 4.70 o 0 4 1 77.60 95.05 4.93 o 1 4 1 60.83 60.42 3.04 o 2 4 1 24.35 24.14 3.08 o 3 4 1 61.32 65.17 6.20 o 4 4 1 5.26 12.66 4.68 o 0 5 1 3.38 1.15 2.91 o 1 5 1 240.07 239.24 6.53 o 2 5 1 209.14 179.62 7.93 o 3 5 1 22.96 20.30 4.31 o 0 6 1 110.96 121.85 9.17 o 1 6 1 37.56 35.19 4.55 o 2 6 1 0.54 3.40 3.39 o 3 6 1 8.58 10.51 3.94 o 0 7 1 131.67 160.92 23.60 o 1 7 1 63.17 71.38 8.60 o 2 7 1 21.35 23.91 6.06 o 0 8 1 3.45 9.99 7.10 o 0 0 2 12.85 5.97 5.51 o 1 0 2 5885.83 5588.26 208.79 o 2 0 2 32.43 26.73 5.00 o 3 0 2 18.40 27.44 5.95 o 4 0 2 4.02 8.85 4.30 o 0 1 2 342.35 346.40 4.39 o 1 1 2 3333.72 3171.55 40.34 o 2 1 2 33.42 38.60 4.15 o 3 1 2 19.07 18.17 4.26 o 4 1 2 3.86 7.96 2.23 o 0 2 2 118.00 138.69 4.16 o 1 2 2 174.90 180.59 3.06 o 2 2 2 67.62 83.09 6.61 o 3 2 2 25.19 27.44 3.89 o 4 2 2 5.99 14.34 2.81 o 0 3 2 170.37 214.35 8.26 o 1 3 2 140.33 140.10 3.15 o 2 3 2 94.56 99.30 4.17 o 3 3 2 4.74 5.67 2.41 o 4 3 2 42.05 37.74 7.86 o 0 4 2 0.07 0.45 2.05 o 1 4 2 109.63 109.21 4.09 o 2 4 2 72.94 76.46 4.80 o 3 4 2 19.75 24.00 4.39 o 4 4 2 5.02 9.10 4.68 o 0 5 2 1.32 5.62 2.98 o 1 5 2 144.65 139.58 5.74 o 2 5 2 70.64 67.03 5.62 o 3 5 2 5.30 3.09 2.83 o 0 6 2 1.46 2.43 3.24 o 1 6 2 254.41 228.16 10.48 o 2 6 2 0.11 2.12 3.15 o 3 6 2 1.41 2.59 3.34 o 0 7 2 8.24 11.50 5.45 o 1 7 2 54.36 48.99 7.22 o 2 7 2 3.02 2.13 4.43 o 0 8 2 0.08 5.41 6.11 o 1 0 3 785.50 699.13 26.83 o 2 0 3 7.73 4.33 3.10 o 3 0 3 1.75 6.20 3.36 o 4 0 3 8.07 8.29 3.62 o 0 1 3 1425.21 1584.07 18.02 o 1 1 3 1750.13 1623.24 49.35 o 2 1 3 128.64 130.54 5.37 o 3 1 3 18.81 15.67 3.49 o 4 1 3 1.46 4.54 2.04 o 0 2 3 7.18 7.50 1.29 o 1 2 3 188.61 171.36 2.99 o 2 2 3 618.66 600.79 13.53 o 3 2 3 68.27 60.88 4.90 o 4 2 3 15.41 16.19 3.23 o 0 3 3 206.20 220.58 5.31 o 1 3 3 93.05 101.62 2.76 o 2 3 3 13.70 13.91 2.15 o 3 3 3 30.65 33.84 4.24 o 4 3 3 1.87 16.19 6.60 o 0 4 3 179.95 218.45 6.50 o 1 4 3 114.28 113.72 3.91 o 2 4 3 121.30 112.00 5.75 o 3 4 3 84.27 84.11 7.52 o 4 4 3 11.96 12.00 5.08 o 0 5 3 43.56 52.37 5.26 o 1 5 3 54.71 59.24 4.46 o 2 5 3 123.68 100.79 6.12 o 3 5 3 7.45 4.90 3.07 o 0 6 3 7.87 9.64 5.25 o 1 6 3 38.79 41.83 4.94 o 2 6 3 16.75 15.35 4.29 o 3 6 3 2.20 1.96 3.55 o 0 7 3 54.62 76.60 10.42 o 1 7 3 41.77 39.67 6.85 o 2 7 3 5.01 3.48 4.46 o 0 8 3 0.65 5.45 6.22 o 0 0 4 3418.60 3038.53 36.44 o 1 0 4 0.00 -0.92 0.97 o 2 0 4 445.52 423.04 27.84 o 3 0 4 0.18 -2.68 2.40 o 4 0 4 7.18 10.17 4.29 o 0 1 4 4688.38 4454.55 38.50 o 1 1 4 536.81 497.42 12.54 o 2 1 4 198.62 192.51 7.12 o 3 1 4 18.93 18.06 3.68 o 4 1 4 3.99 4.55 2.76 o 0 2 4 5.99 6.44 1.38 o 1 2 4 41.57 39.56 1.83 o 2 2 4 490.04 492.32 13.51 o 3 2 4 66.05 60.20 6.23 o 4 2 4 0.22 4.37 4.39 o 0 3 4 1195.15 1525.08 16.34 o 1 3 4 40.10 50.25 2.56 o 2 3 4 31.30 28.77 2.93 o 3 3 4 153.43 149.63 7.93 o 4 3 4 8.43 21.39 7.28 o 0 4 4 60.19 66.28 4.40 o 1 4 4 123.29 114.57 3.89 o 2 4 4 74.15 72.08 5.41 o 3 4 4 36.80 40.83 5.47 o 4 4 4 2.35 18.29 6.93 o 0 5 4 14.20 19.54 3.45 o 1 5 4 33.65 32.70 3.65 o 2 5 4 59.64 49.89 5.06 o 3 5 4 5.20 9.46 3.95 o 0 6 4 74.93 89.60 9.74 o 1 6 4 70.43 72.20 5.80 o 2 6 4 8.81 9.09 3.79 o 3 6 4 11.38 14.42 4.73 o 0 7 4 142.84 143.88 13.13 o 1 7 4 0.21 1.90 3.67 o 2 7 4 6.66 7.48 5.10 o 0 8 4 0.37 4.20 6.99 o 1 0 5 24.20 23.78 2.88 o 2 0 5 25.45 26.56 4.25 o 3 0 5 3.18 1.93 3.27 o 4 0 5 1.91 3.92 3.69 o 0 1 5 149.54 126.78 4.24 o 1 1 5 430.03 401.01 10.60 o 2 1 5 19.13 21.61 2.68 o 3 1 5 56.57 54.19 6.74 o 4 1 5 0.50 3.95 2.65 o 0 2 5 272.35 257.76 4.80 o 1 2 5 676.79 654.63 6.35 o 2 2 5 42.84 44.17 3.79 o 3 2 5 66.36 62.78 5.03 o 4 2 5 4.55 11.22 3.99 o 0 3 5 12.49 12.99 1.84 o 1 3 5 27.31 22.17 1.97 o 2 3 5 42.01 40.48 4.01 o 3 3 5 6.44 11.81 2.96 o 4 3 5 31.62 46.74 7.19 o 0 4 5 1.52 5.21 2.65 o 1 4 5 181.01 177.16 4.75 o 2 4 5 5.61 8.64 2.41 o 3 4 5 65.41 70.01 9.59 o 0 5 5 134.07 134.38 10.03 o 1 5 5 19.38 17.73 2.95 o 2 5 5 26.71 21.81 3.65 o 3 5 5 2.68 8.59 3.86 o 0 6 5 0.43 6.05 4.22 o 1 6 5 9.46 9.09 2.79 o 2 6 5 2.00 2.34 3.25 o 3 6 5 3.83 3.19 4.37 o 0 7 5 37.15 36.74 7.18 o 1 7 5 13.65 12.64 4.64 o 2 7 5 4.10 6.07 4.58 o 0 0 6 50.23 45.23 4.41 o 1 0 6 1153.19 1109.07 19.32 o 2 0 6 3.96 4.92 1.98 o 3 0 6 5.28 6.47 4.30 o 4 0 6 7.29 7.18 4.26 o 0 1 6 12.07 13.49 2.33 o 1 1 6 13.96 18.16 1.89 o 2 1 6 19.43 19.55 2.71 o 3 1 6 18.41 17.36 3.45 o 4 1 6 2.37 6.06 3.07 o 0 2 6 78.87 81.49 3.65 o 1 2 6 500.13 450.04 6.73 o 2 2 6 120.96 111.16 4.92 o 3 2 6 14.11 11.38 2.81 o 4 2 6 2.66 4.22 5.20 o 0 3 6 554.81 582.37 11.98 o 1 3 6 889.79 905.53 9.69 o 2 3 6 62.48 65.50 4.98 o 3 3 6 2.92 5.37 2.57 o 4 3 6 75.31 95.38 10.68 o 0 4 6 29.04 41.05 4.47 o 1 4 6 0.86 1.71 1.52 o 2 4 6 37.45 37.93 4.11 o 3 4 6 5.86 10.71 3.31 o 0 5 6 6.00 9.16 3.71 o 1 5 6 10.02 5.70 2.72 o 2 5 6 9.00 5.97 2.90 o 3 5 6 6.79 10.59 4.01 o 0 6 6 0.13 3.92 3.48 o 1 6 6 4.63 7.47 2.96 o 2 6 6 6.87 4.85 3.73 o 3 6 6 2.61 1.90 4.24 o 0 7 6 0.30 4.44 4.57 o 1 7 6 9.56 10.78 4.33 o 2 7 6 2.16 6.37 5.23 o 1 0 7 99.44 94.36 3.73 o 2 0 7 68.98 69.54 4.64 o 3 0 7 3.61 6.85 4.32 o 4 0 7 0.11 2.30 3.83 o 0 1 7 19.69 17.62 2.68 o 1 1 7 537.66 539.14 6.59 o 2 1 7 86.50 99.43 5.34 o 3 1 7 0.04 2.69 2.31 o 4 1 7 7.50 9.08 3.33 o 0 2 7 131.54 130.40 6.30 o 1 2 7 326.01 319.02 5.74 o 2 2 7 389.40 368.47 12.11 o 3 2 7 6.30 6.42 2.48 o 4 2 7 7.28 8.55 5.60 o 0 3 7 238.24 258.00 5.22 o 1 3 7 110.29 113.51 3.88 o 2 3 7 22.09 24.42 3.47 o 3 3 7 69.59 70.20 6.71 o 4 3 7 3.52 17.08 4.90 o 0 4 7 139.62 141.04 9.45 o 1 4 7 131.57 137.45 4.62 o 2 4 7 140.95 117.91 6.67 o 3 4 7 20.13 33.29 4.90 o 0 5 7 87.95 76.63 6.99 o 1 5 7 33.01 30.59 3.98 o 2 5 7 3.97 7.31 2.96 o 3 5 7 1.97 6.70 3.58 o 0 6 7 9.28 5.97 3.77 o 1 6 7 3.96 2.05 3.18 o 2 6 7 3.83 0.68 4.05 o 0 7 7 38.59 42.24 8.06 o 1 7 7 8.07 12.85 4.21 o 2 7 7 5.33 16.93 6.63 o 0 0 8 512.97 518.14 12.60 o 1 0 8 45.09 41.83 3.11 o 2 0 8 289.67 284.35 9.29 o 3 0 8 30.82 25.85 6.59 o 4 0 8 0.17 4.78 4.97 o 0 1 8 974.56 1010.69 13.07 o 1 1 8 30.94 32.16 2.07 o 2 1 8 107.27 111.98 5.20 o 3 1 8 25.15 21.08 3.88 o 4 1 8 0.77 0.24 3.12 o 0 2 8 1137.91 1222.80 28.89 o 1 2 8 274.73 270.10 6.85 o 2 2 8 113.44 108.34 4.91 o 3 2 8 28.23 29.15 4.21 o 4 2 8 1.67 4.59 4.59 o 0 3 8 808.41 810.78 33.29 o 1 3 8 43.28 47.80 3.69 o 2 3 8 15.92 17.83 3.26 o 3 3 8 101.14 90.62 7.37 o 4 3 8 7.29 27.66 7.28 o 0 4 8 394.73 334.77 12.44 o 1 4 8 45.86 48.66 3.32 o 2 4 8 0.45 -0.27 2.13 o 3 4 8 24.42 26.73 4.81 o 0 5 8 84.43 76.27 8.62 o 1 5 8 4.71 3.61 2.72 o 2 5 8 2.30 0.89 3.73 o 3 5 8 6.79 11.83 4.43 o 0 6 8 9.86 11.51 4.27 o 1 6 8 14.25 14.74 3.94 o 2 6 8 7.56 9.14 5.46 o 0 7 8 0.51 5.64 4.57 o 1 7 8 0.35 5.98 3.96 o 2 7 8 9.53 18.25 7.18 o 1 0 9 27.85 33.54 4.60 o 2 0 9 16.68 17.15 2.86 o 3 0 9 1.14 -2.79 3.00 o 4 0 9 10.08 16.28 6.07 o 0 1 9 11.75 11.90 2.36 o 1 1 9 130.00 122.74 3.39 o 2 1 9 151.83 142.38 5.35 o 3 1 9 24.41 23.59 4.09 o 4 1 9 6.97 4.87 3.91 o 0 2 9 54.11 55.74 4.08 o 1 2 9 56.08 63.70 3.60 o 2 2 9 105.97 111.99 4.95 o 3 2 9 10.97 14.48 3.63 o 4 2 9 15.91 26.95 10.96 o 0 3 9 10.22 19.34 3.93 o 1 3 9 32.12 36.93 3.81 o 2 3 9 2.72 1.12 2.00 o 3 3 9 2.42 0.76 2.54 o 4 3 9 4.38 22.25 12.80 o 0 4 9 1.26 -0.43 3.20 o 1 4 9 2.98 3.10 1.86 o 2 4 9 23.88 26.69 4.63 o 3 4 9 11.65 14.73 4.28 o 0 5 9 0.00 0.51 3.71 o 1 5 9 16.07 15.89 3.33 o 2 5 9 27.46 26.23 4.95 o 3 5 9 8.37 17.93 5.03 o 0 6 9 1.72 8.87 3.99 o 1 6 9 4.10 2.89 3.29 o 2 6 9 0.15 2.54 4.73 o 0 7 9 2.33 3.37 4.80 o 1 7 9 1.44 1.63 3.67 o 0 0 10 1037.93 969.77 20.34 o 1 0 10 198.28 202.41 7.35 o 2 0 10 77.52 72.92 4.74 o 3 0 10 17.07 9.30 5.83 o 4 0 10 46.78 40.55 9.06 o 0 1 10 42.31 37.53 3.35 o 1 1 10 313.13 280.27 5.19 o 2 1 10 159.88 144.41 8.16 o 3 1 10 12.77 13.95 3.51 o 4 1 10 5.98 9.90 4.34 o 0 2 10 538.24 526.29 15.60 o 1 2 10 164.31 150.95 4.81 o 2 2 10 14.25 16.72 2.59 o 3 2 10 2.65 2.73 2.83 o 4 2 10 1.01 6.48 6.54 o 0 3 10 44.65 44.91 4.16 o 1 3 10 3.09 0.50 1.93 o 2 3 10 24.40 21.64 3.40 o 3 3 10 27.09 30.84 4.45 o 4 3 10 6.60 13.67 6.40 o 0 4 10 207.08 196.84 11.17 o 1 4 10 79.27 82.95 6.02 o 2 4 10 21.29 20.17 4.35 o 3 4 10 2.97 8.68 6.96 o 0 5 10 7.53 8.31 4.50 o 1 5 10 7.64 5.72 2.96 o 2 5 10 88.29 84.49 7.42 o 3 5 10 0.50 -1.88 4.12 o 0 6 10 25.24 26.90 5.29 o 1 6 10 27.79 24.40 5.27 o 2 6 10 7.82 2.24 4.29 o 0 7 10 0.13 5.22 6.35 o 1 7 10 6.30 7.78 4.13 o 1 0 11 1.52 -1.68 1.81 o 2 0 11 4.07 4.69 2.35 o 3 0 11 43.65 46.45 9.08 o 4 0 11 9.77 15.10 6.46 o 0 1 11 6.30 8.41 2.49 o 1 1 11 976.16 921.41 10.29 o 2 1 11 22.74 19.43 2.79 o 3 1 11 31.01 31.54 4.54 o 4 1 11 5.25 7.31 5.03 o 0 2 11 79.83 77.76 7.63 o 1 2 11 115.24 120.44 5.10 o 2 2 11 39.98 40.56 3.54 o 3 2 11 8.72 12.29 3.48 o 4 2 11 6.61 24.96 16.52 o 0 3 11 9.08 6.59 2.48 o 1 3 11 133.17 131.86 6.17 o 2 3 11 10.00 14.63 3.21 o 3 3 11 2.36 2.09 2.81 o 4 3 11 0.77 0.86 4.98 o 0 4 11 5.04 4.53 4.09 o 1 4 11 58.26 53.76 5.31 o 2 4 11 20.07 18.13 3.73 o 3 4 11 19.06 19.43 4.76 o 0 5 11 15.98 14.12 5.95 o 1 5 11 59.37 51.71 5.60 o 2 5 11 13.58 17.15 4.29 o 3 5 11 2.07 2.44 4.85 o 0 6 11 0.00 4.33 3.18 o 1 6 11 12.30 7.36 4.15 o 2 6 11 4.87 2.35 4.86 o 0 7 11 33.03 33.19 9.99 o 1 7 11 24.03 26.92 5.44 o 0 0 12 2872.16 2820.39 42.91 o 1 0 12 33.55 41.84 4.21 o 2 0 12 15.56 14.60 3.78 o 3 0 12 121.84 123.61 13.02 o 4 0 12 23.97 32.60 16.93 o 0 1 12 9.36 7.18 2.77 o 1 1 12 117.49 122.83 5.60 o 2 1 12 8.84 7.78 2.08 o 3 1 12 26.25 32.92 4.66 o 4 1 12 0.47 4.44 4.53 o 0 2 12 90.65 83.82 4.28 o 1 2 12 8.84 14.11 2.66 o 2 2 12 31.17 32.43 3.40 o 3 2 12 6.18 5.51 3.18 o 4 2 12 0.41 3.52 7.70 o 0 3 12 81.11 86.56 8.48 o 1 3 12 62.41 64.37 5.35 o 2 3 12 42.86 35.77 4.29 o 3 3 12 2.88 4.89 3.42 o 0 4 12 2.95 5.60 3.98 o 1 4 12 8.47 6.30 3.85 o 2 4 12 8.85 8.24 3.13 o 3 4 12 2.80 5.83 3.62 o 0 5 12 4.56 1.82 4.41 o 1 5 12 57.02 47.81 5.67 o 2 5 12 5.94 1.99 3.66 o 3 5 12 15.36 8.97 5.35 o 0 6 12 74.84 57.57 8.62 o 1 6 12 32.78 23.64 5.74 o 2 6 12 9.81 7.00 5.19 o 0 7 12 0.21 5.33 6.34 o 1 7 12 1.43 7.55 3.67 o 1 0 13 4.61 6.13 2.70 o 2 0 13 68.72 72.46 6.55 o 3 0 13 3.25 6.76 5.30 o 4 0 13 18.99 13.69 7.74 o 0 1 13 15.39 21.94 3.50 o 1 1 13 109.23 120.08 4.29 o 2 1 13 102.16 94.93 4.94 o 3 1 13 27.70 34.80 4.96 o 4 1 13 14.86 18.13 6.06 o 0 2 13 53.76 58.50 4.47 o 1 2 13 9.53 7.35 2.39 o 2 2 13 4.00 1.77 2.04 o 3 2 13 8.25 9.20 3.54 o 4 2 13 1.55 7.49 5.79 o 0 3 13 0.62 3.39 3.76 o 1 3 13 12.59 11.84 3.13 o 2 3 13 9.77 7.85 2.72 o 3 3 13 1.29 2.11 3.14 o 0 4 13 0.65 -0.45 3.94 o 1 4 13 12.51 15.85 4.25 o 2 4 13 7.79 4.71 3.08 o 3 4 13 7.76 4.75 3.30 o 0 5 13 0.40 1.67 4.06 o 1 5 13 46.45 40.03 5.53 o 2 5 13 20.99 20.94 4.85 o 3 5 13 5.96 10.45 5.30 o 0 6 13 4.90 9.24 5.08 o 1 6 13 0.54 4.24 4.39 o 2 6 13 7.11 4.75 5.24 o 0 7 13 17.27 16.28 8.21 o 1 7 13 4.73 9.94 4.74 o 0 0 14 168.94 160.06 9.79 o 1 0 14 172.28 174.93 6.98 o 2 0 14 18.93 14.01 3.99 o 3 0 14 60.31 71.53 10.78 o 4 0 14 19.19 23.09 7.86 o 0 1 14 0.50 -0.87 2.66 o 1 1 14 82.17 81.89 4.21 o 2 1 14 19.79 22.97 3.11 o 3 1 14 33.38 38.29 6.03 o 4 1 14 5.07 6.21 4.88 o 0 2 14 0.00 -1.29 2.39 o 1 2 14 154.12 151.29 5.75 o 2 2 14 80.07 66.57 5.18 o 3 2 14 1.47 3.01 3.50 o 0 3 14 100.50 96.66 9.45 o 1 3 14 33.14 33.67 4.12 o 2 3 14 27.49 29.13 4.12 o 3 3 14 8.99 10.13 3.88 o 0 4 14 2.04 2.53 4.25 o 1 4 14 95.97 94.59 7.74 o 2 4 14 36.56 30.53 5.08 o 3 4 14 3.97 3.69 3.32 o 0 5 14 0.70 0.45 3.54 o 1 5 14 4.53 6.02 3.63 o 2 5 14 59.29 51.95 6.57 o 0 6 14 18.62 14.90 5.66 o 1 6 14 23.05 19.52 4.56 o 2 6 14 7.07 2.98 4.70 o 0 7 14 8.51 12.96 6.98 o 1 0 15 16.97 20.08 3.91 o 2 0 15 15.81 17.50 4.45 o 3 0 15 7.76 4.53 5.24 o 4 0 15 8.73 19.86 7.86 o 0 1 15 211.52 221.78 7.91 o 1 1 15 46.06 45.90 4.37 o 2 1 15 92.80 87.55 5.12 o 3 1 15 52.13 48.01 8.29 o 4 1 15 1.81 7.32 18.31 o 0 2 15 5.19 3.66 2.94 o 1 2 15 70.15 66.47 4.69 o 2 2 15 111.92 93.95 6.23 o 3 2 15 2.99 -0.69 3.04 o 0 3 15 36.51 35.88 7.20 o 1 3 15 6.91 6.33 2.77 o 2 3 15 0.15 0.50 2.23 o 3 3 15 7.71 11.90 4.20 o 0 4 15 130.11 124.09 11.03 o 1 4 15 98.10 99.57 8.08 o 2 4 15 13.61 15.90 4.60 o 3 4 15 3.03 4.07 3.82 o 0 5 15 4.83 4.22 4.85 o 1 5 15 6.19 6.52 3.77 o 2 5 15 49.82 55.67 6.87 o 0 6 15 1.17 5.61 4.79 o 1 6 15 2.40 14.29 4.62 o 2 6 15 0.36 9.31 5.23 o 0 7 15 23.60 17.45 8.11 o 0 0 16 214.31 236.57 12.29 o 1 0 16 18.31 17.49 4.09 o 2 0 16 3.73 2.79 3.98 o 3 0 16 0.18 1.13 4.58 o 0 1 16 46.00 48.07 5.34 o 1 1 16 3.94 4.53 2.36 o 2 1 16 14.51 12.63 3.38 o 3 1 16 13.70 13.24 4.37 o 0 2 16 80.09 78.59 14.68 o 1 2 16 59.98 57.17 5.12 o 2 2 16 72.28 67.47 5.43 o 3 2 16 2.01 1.69 3.32 o 1 3 16 129.96 114.55 6.88 o 2 3 16 17.00 13.90 3.34 o 3 3 16 3.89 4.11 3.77 o 0 4 16 89.47 80.04 12.92 o 1 4 16 44.71 44.19 6.05 o 2 4 16 16.60 16.76 4.65 o 3 4 16 2.01 9.12 4.28 o 0 5 16 8.60 17.54 5.77 o 1 5 16 0.37 -0.39 3.69 o 2 5 16 8.38 13.39 5.54 o 0 6 16 16.30 12.18 5.71 o 1 6 16 21.73 25.56 5.80 o 1 0 17 15.06 14.67 4.12 o 2 0 17 7.16 12.37 4.92 o 3 0 17 1.32 -2.07 4.88 o 0 1 17 61.42 62.70 6.16 o 1 1 17 45.18 46.92 4.31 o 2 1 17 38.16 40.84 4.57 o 3 1 17 16.63 21.58 5.23 o 0 2 17 14.85 12.25 4.81 o 1 2 17 163.95 148.82 7.80 o 2 2 17 60.57 56.20 5.11 o 3 2 17 29.73 42.19 6.04 o 0 3 17 65.28 59.92 11.47 o 1 3 17 9.70 8.15 3.02 o 2 3 17 1.01 0.27 2.42 o 3 3 17 12.95 10.34 6.15 o 0 4 17 1.05 4.06 5.12 o 1 4 17 88.86 82.79 7.69 o 2 4 17 47.50 53.36 6.52 o 3 4 17 8.56 11.79 5.22 o 0 5 17 7.63 4.34 4.88 o 1 5 17 15.59 19.37 4.94 o 2 5 17 13.09 13.48 5.21 o 0 6 17 4.30 7.92 5.29 o 1 6 17 4.49 9.74 4.67 o 0 0 18 33.35 32.07 7.82 o 1 0 18 13.55 12.98 3.94 o 2 0 18 13.10 17.85 5.46 o 3 0 18 8.30 15.05 8.24 o 0 1 18 30.19 33.91 5.43 o 1 1 18 3.33 2.39 2.69 o 2 1 18 18.28 20.12 3.95 o 3 1 18 18.61 26.26 6.30 o 0 2 18 77.59 79.39 8.16 o 1 2 18 88.55 85.52 6.95 o 2 2 18 21.79 20.84 3.69 o 3 2 18 0.18 0.71 4.01 o 1 3 18 310.50 278.90 11.11 o 2 3 18 11.02 10.18 3.47 o 3 3 18 2.60 3.74 4.01 o 0 4 18 52.95 68.56 11.97 o 1 4 18 1.17 0.93 3.70 o 2 4 18 15.50 11.04 5.32 o 0 5 18 11.39 19.70 6.64 o 1 5 18 4.52 3.76 4.10 o 2 5 18 4.98 8.08 4.40 o 0 6 18 3.58 11.85 6.12 o 1 6 18 0.50 2.64 3.69 o 1 0 19 3.50 4.02 4.47 o 2 0 19 0.86 1.21 4.04 o 3 0 19 2.75 3.76 5.54 o 0 1 19 0.00 1.48 3.99 o 1 1 19 18.49 21.36 3.71 o 2 1 19 20.92 25.34 4.33 o 3 1 19 7.21 6.21 4.59 o 0 2 19 106.88 111.73 9.64 o 1 2 19 75.18 70.52 5.74 o 2 2 19 164.30 137.82 8.05 o 3 2 19 6.21 9.74 4.45 o 0 3 19 22.03 34.91 10.30 o 1 3 19 64.57 66.65 7.13 o 2 3 19 3.60 4.56 3.03 o 3 3 19 0.24 1.99 3.92 o 0 4 19 92.77 83.71 13.29 o 1 4 19 65.03 72.15 7.58 o 2 4 19 22.43 22.37 4.91 o 0 5 19 6.09 9.37 5.50 o 1 5 19 19.39 19.69 4.88 o 2 5 19 1.97 7.27 6.36 o 0 6 19 3.32 8.26 5.58 o 1 6 19 0.24 5.06 4.40 o 0 0 20 5.17 3.06 8.04 o 1 0 20 0.11 0.57 4.25 o 2 0 20 6.64 10.28 4.76 o 3 0 20 1.79 10.34 8.32 o 0 1 20 30.22 20.74 6.27 o 1 1 20 35.24 32.69 4.10 o 2 1 20 14.12 16.49 3.98 o 3 1 20 15.98 20.28 5.78 o 0 2 20 35.38 40.21 7.93 o 1 2 20 61.50 69.11 6.78 o 2 2 20 7.66 11.95 3.77 o 3 2 20 2.70 -1.45 4.48 o 0 3 20 186.50 183.12 17.02 o 1 3 20 95.47 97.89 9.40 o 2 3 20 14.50 13.22 3.77 o 3 3 20 1.74 2.49 4.06 o 0 4 20 53.66 59.75 12.46 o 1 4 20 28.52 32.37 5.90 o 2 4 20 5.11 7.33 3.93 o 0 5 20 0.48 -2.69 7.87 o 1 5 20 6.76 9.46 4.47 o 0 6 20 0.14 6.56 5.77 o 1 0 21 30.82 28.73 6.48 o 2 0 21 0.78 2.35 4.77 o 3 0 21 15.97 23.77 9.62 o 0 1 21 4.85 4.15 5.28 o 1 1 21 57.91 59.72 5.01 o 2 1 21 8.83 15.96 4.34 o 3 1 21 13.96 25.83 10.23 o 0 2 21 48.96 51.69 11.30 o 1 2 21 95.31 94.33 8.60 o 2 2 21 7.57 8.41 3.98 o 3 2 21 6.18 10.75 5.37 o 0 3 21 6.86 8.45 8.34 o 1 3 21 11.28 19.32 5.93 o 2 3 21 8.85 10.54 6.18 o 0 4 21 3.59 5.03 8.68 o 1 4 21 23.56 24.78 5.31 o 2 4 21 2.96 9.31 4.23 o 0 5 21 1.37 5.86 7.64 o 1 5 21 13.86 18.03 4.95 o 0 0 22 35.89 34.32 8.71 o 1 0 22 39.63 39.09 7.15 o 2 0 22 21.08 18.17 5.94 o 3 0 22 12.33 24.61 8.94 o 0 1 22 2.06 8.72 5.31 o 1 1 22 6.42 6.53 2.94 o 2 1 22 52.67 48.57 6.29 o 3 1 22 8.01 18.08 6.70 o 0 2 22 90.40 121.24 14.53 o 1 2 22 17.95 25.86 4.83 o 2 2 22 1.62 6.85 3.53 o 0 3 22 25.20 28.41 11.11 o 1 3 22 3.91 9.03 5.54 o 2 3 22 1.35 5.96 5.66 o 0 4 22 96.03 93.64 14.68 o 1 4 22 22.75 24.61 6.80 o 2 4 22 0.57 5.15 4.01 o 0 5 22 1.02 11.77 8.10 o 1 5 22 18.58 20.03 5.19 o 1 0 23 0.14 2.71 4.82 o 2 0 23 9.12 8.90 5.40 o 3 0 23 5.28 9.09 7.73 o 0 1 23 43.99 48.70 7.95 o 1 1 23 8.88 12.62 3.74 o 2 1 23 45.45 41.05 5.92 o 0 2 23 0.73 0.49 7.08 o 1 2 23 11.70 11.94 4.34 o 2 2 23 4.83 5.59 5.07 o 0 3 23 0.92 6.52 8.27 o 1 3 23 14.11 17.07 5.83 o 2 3 23 5.00 9.44 7.05 o 0 4 23 8.94 13.85 15.52 o 1 4 23 1.19 12.03 6.27 o 0 5 23 16.39 29.14 9.70 o 0 0 24 46.58 41.83 13.38 o 1 0 24 86.58 75.20 9.12 o 2 0 24 0.00 -6.43 4.29 o 0 1 24 3.92 11.87 5.78 o 1 1 24 3.87 3.90 4.41 o 2 1 24 10.02 12.16 4.30 o 0 2 24 0.03 12.61 8.51 o 1 2 24 1.06 3.88 4.56 o 2 2 24 3.06 3.09 4.56 o 0 3 24 4.98 15.10 9.33 o 1 3 24 1.21 8.82 5.25 o 2 3 24 2.96 9.49 8.86 o 0 4 24 8.36 18.12 9.27 o 1 4 24 2.26 3.78 6.41 o 1 0 25 3.11 8.23 5.62 o 2 0 25 0.35 0.33 4.90 o 0 1 25 9.24 7.54 5.41 o 1 1 25 18.09 23.92 5.84 o 2 1 25 16.30 13.56 4.82 o 0 2 25 0.56 2.54 7.74 o 1 2 25 7.81 19.23 6.01 o 2 2 25 3.27 6.57 5.43 o 0 3 25 0.55 -0.81 7.74 o 1 3 25 4.56 13.98 5.70 o 0 4 25 7.76 20.98 9.29 o 1 4 25 2.33 17.32 6.46 o 0 0 26 41.04 37.50 12.57 o 1 0 26 6.01 7.94 5.26 o 2 0 26 13.58 15.80 7.65 o 0 1 26 41.85 51.73 11.54 o 1 1 26 4.81 11.59 4.96 o 2 1 26 0.14 -1.32 3.68 o 0 2 26 0.37 -0.58 6.78 o 1 2 26 4.73 7.24 6.76 o 2 2 26 1.22 10.31 5.27 o 0 3 26 2.70 8.55 8.53 o 1 3 26 3.01 9.74 5.27 o 0 4 26 1.42 6.09 8.27 o 1 0 27 3.26 12.08 7.58 o 2 0 27 1.58 11.10 9.18 o 0 1 27 0.25 7.81 8.47 o 1 1 27 4.40 13.34 5.10 o 2 1 27 0.36 5.45 5.00 o 0 2 27 7.11 5.61 9.46 o 1 2 27 5.03 12.04 6.78 o 0 3 27 0.03 9.91 8.39 o 1 3 27 1.09 10.37 5.62 o 0 0 28 0.08 10.47 7.59 o 1 0 28 0.50 9.05 6.30 o 0 1 28 0.09 10.21 8.82 o 1 1 28 13.39 24.62 5.67 o 0 2 28 1.58 18.04 12.87 o 1 2 28 0.31 0.13 5.30 o 0 3 28 0.72 16.01 8.90 o 1 0 29 4.38 17.20 7.52 o 0 1 29 0.12 16.28 10.54 o 1 1 29 0.28 6.94 4.65 o 0 2 29 0.63 7.80 8.93 o 0 0 30 4.53 10.91 8.84 o