#------------------------------------------------------------------------------ #$Date: 2011-11-08 16:24:06 +0200 (Tue, 08 Nov 2011) $ #$Revision: 29951 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/21/2232106.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2232106_Fobs loop_ _publ_author_name 'Feizbakhsh Bazargani, Mona' 'Talavat, Laleh' 'Naderi, Soheila' 'Khavasi, Hamid Reza' _publ_section_title ; 2-[(1H-Imidazol-2-yl)disulfanyl]-1H-imidazole ; _journal_coeditor_code XU5318 _journal_issue 10 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o2585 _journal_volume 67 _journal_year 2011 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 122.292 _cell_angle_gamma 90.000 _cell_length_a 14.0825 _cell_length_b 6.3928 _cell_length_c 9.9223 _exptl_crystal_F_000 408.00 _reflns_d_resolution_high 0.7291 _[local]_cod_data_source_file xu5318Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' KH408H in C2/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 65.53 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 2418.48 3071.99 14.07 o 6 0 0 3730.87 4094.05 9.05 o 8 0 0 1802.08 2210.00 1124.07 o 10 0 0 498.26 492.24 7.78 o 12 0 0 33.79 26.57 1.16 o 14 0 0 26.27 24.36 1.15 o 16 0 0 15.78 16.52 1.30 o 1 1 0 2.18 52.94 2.18 o 5 1 0 830.06 548.86 3.04 o 9 1 0 0.44 1.50 1.38 o 11 1 0 2234.61 2500.58 367.29 o 13 1 0 167.61 183.61 1.36 o 15 1 0 173.80 160.71 1.41 o 2 2 0 30.70 21.84 7.09 o 4 2 0 1025.98 1396.04 23.25 o 6 2 0 8.24 1.82 0.67 o 8 2 0 19.84 9.19 0.72 o 10 2 0 134.99 148.21 22.65 o 12 2 0 109.70 115.36 17.73 o 14 2 0 321.11 297.51 1.56 o 1 3 0 150.48 195.07 2.08 o 3 3 0 605.76 730.62 32.77 o 5 3 0 9.44 9.57 0.61 o 7 3 0 520.22 560.57 6.23 o 9 3 0 8.73 6.09 0.65 o 11 3 0 152.22 150.26 25.53 o 13 3 0 4.58 3.90 0.71 o 15 3 0 15.78 11.91 0.81 o 0 4 0 708.24 968.95 3.90 o 2 4 0 9.02 6.32 0.79 o 4 4 0 544.57 679.69 10.06 o 6 4 0 19.03 14.28 0.72 o 8 4 0 323.99 355.15 5.99 o 10 4 0 0.04 0.62 1.30 o 12 4 0 137.89 145.43 22.13 o 14 4 0 14.95 12.02 2.34 o 1 5 0 897.57 856.33 181.39 o 3 5 0 27.97 25.17 4.25 o 5 5 0 830.10 827.20 9.21 o 7 5 0 229.36 229.18 26.19 o 9 5 0 104.83 103.42 9.14 o 11 5 0 184.70 175.56 47.62 o 13 5 0 1.77 1.25 0.77 o 0 6 0 2589.21 2786.50 680.23 o 2 6 0 209.79 214.13 45.04 o 4 6 0 1051.12 1062.51 223.32 o 6 6 0 649.68 688.09 73.73 o 8 6 0 6.82 4.39 0.92 o 10 6 0 158.71 156.90 13.98 o 1 7 0 195.67 206.90 32.26 o 3 7 0 44.81 39.08 9.10 o 5 7 0 217.77 221.48 24.91 o 7 7 0 408.46 393.54 46.00 o 9 7 0 0.77 1.39 0.60 o 0 8 0 220.99 208.95 53.61 o 2 8 0 24.27 24.39 4.13 o 4 8 0 48.94 44.24 5.74 o 6 8 0 45.37 43.50 4.94 o -15 1 1 78.75 80.17 2.44 o -13 1 1 240.94 248.44 37.82 o -11 1 1 995.70 1076.51 19.08 o -9 1 1 134.68 102.23 1.71 o -5 1 1 499.36 660.78 7.86 o 1 1 1 1057.30 1054.13 102.66 o 3 1 1 4250.93 4090.67 2522.12 o 5 1 1 77.72 54.74 7.12 o 7 1 1 378.79 349.86 37.19 o 9 1 1 47.46 44.74 0.85 o 11 1 1 5.00 2.34 0.73 o 13 1 1 0.84 2.11 1.02 o 15 1 1 2.85 2.50 0.99 o -16 2 1 3.07 4.23 0.79 o -14 2 1 178.87 170.99 26.44 o -12 2 1 257.27 248.53 1.80 o -10 2 1 12.05 17.12 2.40 o -8 2 1 395.52 302.74 9.16 o -6 2 1 1685.58 1596.12 170.95 o -4 2 1 248.51 462.61 31.30 o -2 2 1 2965.14 2868.00 7.25 o 0 2 1 3998.36 81.76 2.71 o 2 2 1 6.42 92.04 24.55 o 4 2 1 1783.71 2193.07 452.16 o 6 2 1 1392.15 1662.70 192.85 o 8 2 1 4.44 9.75 1.51 o 10 2 1 669.15 722.98 115.73 o 12 2 1 170.35 181.25 4.27 o 14 2 1 30.43 31.47 1.34 o -15 3 1 4.11 5.89 1.23 o -13 3 1 211.29 234.69 36.19 o -11 3 1 244.41 252.34 4.20 o -9 3 1 54.74 49.60 1.57 o -7 3 1 902.81 1003.42 12.89 o -5 3 1 894.35 923.14 3.35 o -3 3 1 2.38 0.23 0.85 o -1 3 1 2357.25 2575.45 22.79 o 1 3 1 3484.67 3766.52 1938.76 o 3 3 1 43.92 9.76 2.66 o 5 3 1 3354.76 3493.22 389.58 o 7 3 1 985.23 1062.64 84.91 o 9 3 1 316.16 309.56 36.09 o 11 3 1 886.91 902.44 140.80 o 13 3 1 78.34 79.02 1.71 o -14 4 1 126.76 104.58 17.61 o -12 4 1 292.47 314.99 4.96 o -10 4 1 32.34 37.56 0.98 o -8 4 1 408.67 397.36 7.04 o -6 4 1 1497.98 1495.91 17.90 o -4 4 1 201.66 249.31 5.50 o -2 4 1 1709.61 1656.17 25.04 o 0 4 1 3033.37 3680.14 1889.31 o 2 4 1 10.37 19.38 5.39 o 4 4 1 1879.16 2104.21 432.85 o 6 4 1 1086.83 1106.82 88.42 o 8 4 1 39.60 37.39 2.75 o 10 4 1 517.55 524.54 60.81 o 12 4 1 77.68 87.45 13.97 o -13 5 1 127.51 130.36 20.51 o -11 5 1 448.98 426.58 36.57 o -9 5 1 48.68 60.02 2.11 o -7 5 1 1704.96 1830.97 14.71 o -5 5 1 395.50 381.43 16.48 o -3 5 1 1190.34 1206.53 139.48 o -1 5 1 1724.75 1789.06 441.83 o 1 5 1 4.92 12.63 3.94 o 3 5 1 744.63 739.51 159.06 o 5 5 1 166.66 151.79 32.49 o 7 5 1 4.02 4.66 0.79 o 9 5 1 7.67 9.44 0.95 o 11 5 1 19.47 16.25 3.44 o -12 6 1 8.07 7.49 1.34 o -10 6 1 77.44 65.37 10.26 o -8 6 1 43.21 49.62 1.49 o -6 6 1 6.77 6.17 0.62 o -4 6 1 0.49 2.67 0.57 o -2 6 1 3.44 2.65 0.66 o 0 6 1 65.09 68.34 7.67 o 2 6 1 125.82 113.33 24.55 o 4 6 1 29.12 29.50 6.82 o 6 6 1 229.87 221.80 18.72 o 8 6 1 7.94 7.86 0.97 o 10 6 1 64.24 59.06 7.00 o -9 7 1 13.05 11.60 2.49 o -7 7 1 29.79 33.03 3.90 o -5 7 1 1.81 0.85 1.26 o -3 7 1 10.73 12.01 2.07 o -1 7 1 1.48 4.76 1.99 o 1 7 1 0.00 0.67 0.53 o 3 7 1 13.53 11.25 2.96 o 5 7 1 13.06 9.83 2.62 o 7 7 1 13.27 11.87 1.52 o -6 8 1 104.71 86.34 9.54 o -4 8 1 18.03 18.58 2.85 o -2 8 1 110.65 101.82 9.08 o 0 8 1 66.61 67.76 10.93 o 2 8 1 11.71 7.52 1.15 o 4 8 1 28.44 24.97 4.90 o -16 0 2 15.18 12.69 1.59 o -14 0 2 587.01 622.00 2.76 o -12 0 2 1477.34 1682.61 5.12 o -10 0 2 284.31 346.71 5.51 o -6 0 2 513.28 367.48 4.12 o -2 0 2 1990.43 2290.49 44.28 o 0 0 2 792.60 766.10 3.59 o 2 0 2 71.95 109.44 1.25 o 4 0 2 534.79 641.38 14.85 o 6 0 2 1575.37 1736.97 50.06 o 8 0 2 47.53 64.84 3.39 o 10 0 2 912.21 1033.20 3.79 o 12 0 2 83.46 94.61 1.47 o 14 0 2 49.36 50.46 1.86 o -17 1 2 18.04 22.22 1.10 o -15 1 2 225.38 235.20 6.89 o -13 1 2 393.69 401.96 33.35 o -11 1 2 0.87 1.34 0.68 o -9 1 2 310.24 257.93 2.61 o -7 1 2 920.64 1150.82 19.59 o -5 1 2 2060.91 2699.45 25.49 o -3 1 2 1198.85 1957.13 35.24 o 1 1 2 471.77 225.17 2.39 o 5 1 2 1814.63 1667.90 10.51 o 7 1 2 59.54 102.22 1.22 o 9 1 2 417.73 428.56 6.89 o 11 1 2 236.99 231.44 7.31 o 13 1 2 4.97 6.00 1.12 o -16 2 2 1.26 -0.36 0.74 o -14 2 2 1.59 2.15 1.40 o -12 2 2 281.78 276.54 4.01 o -10 2 2 151.58 151.42 23.02 o -8 2 2 1058.60 1045.75 24.56 o -6 2 2 2809.78 2950.76 48.40 o -4 2 2 96.29 102.89 2.59 o 0 2 2 2063.87 2366.87 66.78 o 2 2 2 474.23 334.98 3.38 o 4 2 2 2290.64 2572.47 41.05 o 6 2 2 491.81 591.20 1.63 o 8 2 2 346.46 361.00 7.12 o 10 2 2 581.42 629.91 3.30 o 12 2 2 0.25 3.30 1.05 o 14 2 2 89.72 75.56 2.80 o -15 3 2 28.29 30.51 1.24 o -13 3 2 46.72 49.03 0.99 o -11 3 2 15.00 21.58 0.76 o -9 3 2 105.21 91.70 3.47 o -7 3 2 14.59 5.11 1.14 o -5 3 2 3.57 5.18 2.08 o -3 3 2 36.62 25.03 1.37 o -1 3 2 189.66 210.88 1.33 o 1 3 2 23.41 16.67 3.15 o 3 3 2 179.93 179.27 29.54 o 5 3 2 85.06 67.21 11.54 o 7 3 2 10.80 9.51 1.49 o 9 3 2 10.59 10.03 0.58 o 11 3 2 0.56 0.92 1.03 o 13 3 2 1.70 2.33 0.84 o -14 4 2 0.30 0.56 1.04 o -12 4 2 25.21 24.26 0.79 o -10 4 2 29.76 28.13 0.93 o -8 4 2 2.59 3.53 0.75 o -6 4 2 209.18 238.38 5.87 o -4 4 2 241.95 277.85 7.70 o -2 4 2 195.33 256.98 3.06 o 0 4 2 1070.30 1006.35 625.18 o 2 4 2 0.02 4.06 0.65 o 4 4 2 943.76 1015.53 156.15 o 6 4 2 135.73 115.32 20.38 o 8 4 2 287.36 318.08 50.24 o 10 4 2 154.63 151.84 2.21 o 12 4 2 26.86 26.91 0.92 o -13 5 2 130.04 138.37 2.96 o -11 5 2 157.70 154.90 2.36 o -9 5 2 66.01 82.78 1.31 o -7 5 2 1094.66 1198.06 41.40 o -5 5 2 210.28 197.68 5.38 o -3 5 2 1300.85 1448.77 19.95 o -1 5 2 1271.86 1271.52 14.20 o 1 5 2 206.70 212.22 57.23 o 3 5 2 820.04 767.02 114.79 o 5 5 2 12.77 11.14 2.43 o 7 5 2 42.50 37.64 3.42 o 9 5 2 6.82 8.08 0.71 o 11 5 2 23.27 23.77 0.96 o -12 6 2 200.41 182.48 1.56 o -10 6 2 124.70 132.73 1.32 o -8 6 2 689.14 733.94 14.23 o -6 6 2 21.18 20.26 1.23 o -4 6 2 231.96 231.55 4.60 o -2 6 2 135.51 136.76 2.21 o 0 6 2 139.50 150.74 25.87 o 2 6 2 15.55 10.50 2.28 o 4 6 2 462.71 460.31 72.37 o 6 6 2 380.23 363.56 58.37 o 8 6 2 93.16 87.19 8.95 o 10 6 2 260.45 228.75 4.56 o -11 7 2 7.94 6.39 1.29 o -9 7 2 11.05 12.30 0.99 o -7 7 2 284.29 289.94 7.93 o -5 7 2 203.89 199.85 1.56 o -3 7 2 308.35 327.90 9.19 o -1 7 2 927.94 982.04 7.14 o 1 7 2 0.01 0.45 0.48 o 3 7 2 466.36 454.37 70.79 o 5 7 2 126.02 139.82 23.43 o 7 7 2 0.21 1.11 0.63 o -6 8 2 49.68 55.10 8.99 o -4 8 2 21.94 17.38 3.65 o -2 8 2 121.70 127.15 15.45 o 0 8 2 131.68 138.53 17.28 o 2 8 2 0.13 0.56 0.60 o 4 8 2 267.60 246.61 22.37 o -17 1 3 12.43 13.62 1.89 o -15 1 3 90.19 89.25 1.34 o -13 1 3 9.08 10.21 0.69 o -11 1 3 0.30 2.46 0.60 o -9 1 3 24.06 20.20 0.72 o -7 1 3 706.97 625.55 8.07 o -5 1 3 175.24 181.13 1.22 o -3 1 3 1893.44 2016.83 14.93 o -1 1 3 1019.81 1045.43 12.19 o 1 1 3 121.31 131.05 2.25 o 3 1 3 387.49 360.04 20.19 o 5 1 3 191.98 148.57 10.24 o 7 1 3 0.15 1.61 0.62 o 9 1 3 131.57 129.93 1.79 o 11 1 3 82.52 83.67 3.34 o 13 1 3 3.15 4.06 0.98 o -16 2 3 0.16 4.41 1.69 o -14 2 3 521.53 569.39 62.13 o -12 2 3 278.45 260.37 4.32 o -10 2 3 747.62 895.51 8.11 o -8 2 3 1481.87 1605.27 14.94 o -6 2 3 6.78 16.83 3.43 o -4 2 3 319.47 376.39 3.34 o -2 2 3 1863.55 1448.00 9.20 o 0 2 3 1963.32 2063.71 27.86 o 2 2 3 907.55 678.65 56.52 o 4 2 3 3445.80 3666.49 67.48 o 6 2 3 22.18 28.26 1.29 o 8 2 3 1017.02 1034.19 23.67 o 10 2 3 244.02 247.05 3.92 o 12 2 3 35.66 31.29 1.03 o -17 3 3 8.01 6.80 1.17 o -15 3 3 99.70 96.42 1.54 o -13 3 3 189.85 196.85 1.68 o -11 3 3 118.72 117.95 18.57 o -9 3 3 859.48 795.99 85.67 o -7 3 3 4293.81 4626.16 693.66 o -5 3 3 35.25 9.45 2.09 o -1 3 3 1811.27 2285.13 350.30 o 1 3 3 2792.31 3423.49 119.04 o 3 3 3 2045.28 2265.37 23.58 o 5 3 3 22.18 9.91 0.76 o 7 3 3 142.13 149.29 2.46 o 9 3 3 272.37 282.86 5.52 o 11 3 3 79.08 80.73 1.29 o -16 4 3 13.16 15.40 0.83 o -14 4 3 741.55 727.38 13.19 o -12 4 3 137.89 128.11 1.94 o -10 4 3 1328.84 1400.65 56.34 o -8 4 3 1231.58 1268.28 35.22 o -6 4 3 135.94 203.89 9.99 o -4 4 3 720.48 745.62 12.57 o -2 4 3 539.24 379.52 5.47 o 0 4 3 314.55 343.01 4.30 o 2 4 3 388.17 281.76 7.69 o 4 4 3 1579.70 1703.53 21.11 o 6 4 3 37.04 46.65 5.72 o 8 4 3 499.70 521.24 7.57 o 10 4 3 182.61 181.01 2.02 o -15 5 3 67.51 49.32 0.93 o -13 5 3 2.75 5.13 0.88 o -11 5 3 0.46 1.72 0.75 o -9 5 3 103.87 104.32 1.37 o -7 5 3 568.24 623.30 6.19 o -5 5 3 0.34 -0.23 0.72 o -3 5 3 1343.45 1496.84 46.03 o -1 5 3 356.18 441.63 9.59 o 1 5 3 254.19 280.11 5.26 o 3 5 3 314.23 336.53 2.91 o 5 5 3 64.38 64.58 7.64 o 7 5 3 0.07 0.22 0.60 o 9 5 3 87.07 98.76 1.04 o -12 6 3 0.17 0.65 0.83 o -10 6 3 39.24 39.67 1.22 o -8 6 3 8.37 9.44 1.11 o -6 6 3 0.01 1.83 1.11 o -4 6 3 3.89 4.87 1.08 o -2 6 3 88.97 96.90 2.02 o 0 6 3 223.06 240.30 5.87 o 2 6 3 51.41 54.56 2.79 o 4 6 3 363.44 372.96 31.24 o 6 6 3 2.70 2.01 0.55 o 8 6 3 116.02 112.90 2.47 o -11 7 3 0.12 2.51 2.07 o -9 7 3 6.90 9.14 0.96 o -7 7 3 0.31 1.91 1.25 o -5 7 3 45.95 41.87 1.02 o -3 7 3 11.68 17.91 1.32 o -1 7 3 60.17 49.11 2.50 o 1 7 3 21.01 23.35 1.32 o 3 7 3 37.78 34.28 2.85 o 5 7 3 14.75 12.70 1.36 o -6 8 3 48.27 46.06 2.19 o -4 8 3 22.49 29.92 1.02 o -2 8 3 108.73 107.87 3.63 o 0 8 3 19.49 15.00 2.51 o 2 8 3 38.81 37.98 4.70 o -18 0 4 29.07 26.83 1.20 o -16 0 4 134.30 134.92 1.44 o -14 0 4 1031.23 1015.41 13.40 o -12 0 4 45.88 55.23 1.26 o -10 0 4 3239.28 3258.60 197.31 o -8 0 4 3761.53 4741.31 10.28 o -6 0 4 939.44 995.45 3.77 o -2 0 4 1670.12 1455.04 11.98 o 0 0 4 1867.19 2356.77 31.62 o 2 0 4 2012.42 1737.71 22.52 o 4 0 4 261.84 204.59 32.64 o 6 0 4 5.42 2.33 0.73 o 8 0 4 377.84 398.08 15.31 o 10 0 4 411.92 409.56 2.47 o 12 0 4 4.41 2.01 1.72 o -17 1 4 101.96 98.04 1.62 o -15 1 4 314.30 308.40 6.43 o -13 1 4 30.81 30.64 0.73 o -11 1 4 172.50 184.70 2.16 o -9 1 4 945.46 780.92 2.96 o -7 1 4 1112.42 948.40 5.13 o -5 1 4 322.77 99.40 1.53 o -1 1 4 2009.48 3124.08 86.30 o 1 1 4 2417.69 2512.67 31.14 o 3 1 4 4177.23 5102.04 8.73 o 5 1 4 4.08 4.09 0.76 o 7 1 4 1288.34 1402.72 30.40 o 9 1 4 252.50 260.16 2.87 o 11 1 4 54.15 52.83 1.27 o -18 2 4 8.92 11.02 0.92 o -16 2 4 11.46 14.59 2.00 o -14 2 4 286.76 306.21 2.79 o -12 2 4 23.93 26.37 0.72 o -10 2 4 1039.64 1034.78 25.23 o -8 2 4 886.41 1034.39 13.61 o -6 2 4 654.13 776.87 14.83 o -4 2 4 1674.32 2300.31 16.48 o -2 2 4 12.29 1.01 0.59 o 0 2 4 120.03 220.89 2.24 o 2 2 4 131.11 103.78 12.11 o 4 2 4 222.61 183.60 2.67 o 6 2 4 14.76 18.77 0.79 o 8 2 4 173.97 177.41 3.43 o 10 2 4 158.22 160.06 4.66 o 12 2 4 7.81 8.34 0.87 o -17 3 4 68.14 57.38 1.14 o -15 3 4 25.00 22.16 0.92 o -13 3 4 108.59 96.02 15.48 o -11 3 4 62.94 65.13 6.98 o -9 3 4 93.70 89.01 3.61 o -7 3 4 2.96 8.34 0.56 o -5 3 4 165.93 176.54 1.71 o -3 3 4 69.30 59.62 4.83 o -1 3 4 308.45 340.55 54.36 o 1 3 4 49.90 50.84 4.28 o 3 3 4 206.42 221.05 3.68 o 5 3 4 0.00 -0.33 0.74 o 7 3 4 32.38 32.06 0.85 o 9 3 4 1.19 2.52 0.91 o 11 3 4 0.05 0.91 0.75 o -16 4 4 15.03 14.41 1.28 o -14 4 4 7.30 10.09 1.00 o -12 4 4 0.87 0.96 0.86 o -10 4 4 2.03 4.82 1.54 o -8 4 4 16.44 18.61 3.81 o -6 4 4 183.11 153.40 23.86 o -4 4 4 17.02 9.08 2.24 o -2 4 4 567.70 525.71 83.59 o 0 4 4 4.06 8.72 0.57 o 2 4 4 452.49 398.92 2.72 o 4 4 4 44.46 43.81 0.71 o 6 4 4 114.45 106.32 12.40 o 8 4 4 29.01 29.18 1.45 o 10 4 4 6.17 4.95 0.85 o -15 5 4 105.14 92.06 3.00 o -13 5 4 92.25 84.08 1.12 o -11 5 4 110.53 101.21 3.10 o -9 5 4 557.59 553.02 15.23 o -7 5 4 2.54 7.79 0.98 o -5 5 4 431.32 372.39 16.47 o -3 5 4 116.15 132.86 4.28 o -1 5 4 0.14 2.92 0.71 o 1 5 4 2.28 2.77 0.65 o 3 5 4 145.17 158.37 3.22 o 5 5 4 165.41 161.20 18.83 o 7 5 4 44.99 48.44 1.73 o 9 5 4 199.10 187.68 5.63 o -12 6 4 0.75 2.33 2.31 o -10 6 4 161.82 171.56 6.69 o -8 6 4 402.83 406.74 8.66 o -6 6 4 31.70 33.66 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