#------------------------------------------------------------------------------ #$Date: 2016-11-19 03:59:36 +0200 (Sat, 19 Nov 2016) $ #$Revision: 188576 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/24/19/2241955.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2241955 loop_ _publ_author_name Siqingaowa 'Tsumuki, Takehiro' 'Ogata, Kazuki' 'Yonezawa, Noriyuki' 'Okamoto, Akiko' _publ_section_title ; 1-[(Anthracen-9-yl)carbonyl]-2,7-dimethoxynaphthalene: a chain-like structure composed of face-to-face type dimeric molecular aggregates ; _journal_coeditor_code IS5460 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first 1819 _journal_page_last 1823 _journal_paper_doi 10.1107/S2056989016018077 _journal_volume 72 _journal_year 2016 _chemical_formula_iupac 'C27 H20 O3' _chemical_formula_moiety 'C27 H20 O3' _chemical_formula_sum 'C27 H20 O3' _chemical_formula_weight 392.43 _chemical_melting_point_gt 444.8 _chemical_melting_point_lt 446.9 _chemical_name_systematic ; 1-[(Anthracen-9-yl)carbonyl]-2,7-dimethoxynaphthalene ; _space_group_IT_number 14 _symmetry_cell_setting monoclinic _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _audit_creation_method SHELXL-97 _cell_angle_alpha 90.00 _cell_angle_beta 96.3650(7) _cell_angle_gamma 90.00 _cell_formula_units_Z 8 _cell_length_a 18.5975(3) _cell_length_b 12.9604(2) _cell_length_c 16.8900(3) _cell_measurement_reflns_used 45896 _cell_measurement_temperature 193(2) _cell_measurement_theta_max 68.22 _cell_measurement_theta_min 3.36 _cell_volume 4045.92(12) _computing_cell_refinement ; PROCESS-AUTO (Rigaku, 1998) ; _computing_data_collection ; PROCESS-AUTO (Rigaku, 1998) ; _computing_data_reduction ; CrystalStructure (Rigaku, 2010) ; _computing_molecular_graphics ; ORTEPIII (Burnett & Johnson, 1996) ; _computing_publication_material ; SHELXL97 (Sheldrick, 2008) ; _computing_structure_refinement ; SHELXL97 (Sheldrick, 2008) ; _computing_structure_solution ; Il Milione (Burla et al., 2007) ; _diffrn_ambient_temperature 193(2) _diffrn_detector_area_resol_mean 10.00 _diffrn_measured_fraction_theta_full 0.998 _diffrn_measured_fraction_theta_max 0.998 _diffrn_measurement_device_type 'Rigaku R-AXIS RAPID' _diffrn_measurement_method \w _diffrn_radiation_monochromator graphite _diffrn_radiation_source 'rotating anode' _diffrn_radiation_type CuK\a _diffrn_radiation_wavelength 1.54187 _diffrn_reflns_av_R_equivalents 0.0698 _diffrn_reflns_av_sigmaI/netI 0.0952 _diffrn_reflns_limit_h_max 22 _diffrn_reflns_limit_h_min -22 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_k_min -15 _diffrn_reflns_limit_l_max 20 _diffrn_reflns_limit_l_min -20 _diffrn_reflns_number 59215 _diffrn_reflns_theta_full 68.22 _diffrn_reflns_theta_max 68.22 _diffrn_reflns_theta_min 4.17 _exptl_absorpt_coefficient_mu 0.663 _exptl_absorpt_correction_T_max 0.9367 _exptl_absorpt_correction_T_min 0.6918 _exptl_absorpt_correction_type numerical _exptl_absorpt_process_details ; (NUMABS; Higashi, 1999) ; _exptl_crystal_colour yellow _exptl_crystal_density_diffrn 1.289 _exptl_crystal_density_method 'not measured' _exptl_crystal_description platelet _exptl_crystal_F_000 1648 _exptl_crystal_size_max 0.60 _exptl_crystal_size_mid 0.30 _exptl_crystal_size_min 0.10 _refine_diff_density_max 0.313 _refine_diff_density_min -0.219 _refine_ls_extinction_coef 0.00184(13) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_extinction_method ; SHELXL97 (Sheldrick, 2008) ; _refine_ls_goodness_of_fit_ref 0.972 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 546 _refine_ls_number_reflns 7401 _refine_ls_number_restraints 7 _refine_ls_restrained_S_all 0.975 _refine_ls_R_factor_all 0.0675 _refine_ls_R_factor_gt 0.0402 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0601P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1054 _refine_ls_wR_factor_ref 0.1127 _reflns_number_gt 4629 _reflns_number_total 7401 _reflns_threshold_expression >2\s(I) _iucr_refine_instructions_details ; TITL yonezawalab_120724_2_ CELL 1.54187 18.59745 12.96042 16.89001 90.000 96.365 90.000 ZERR 8 0.00030 0.00020 0.00030 0.000 0.000 0.000 LATT 1 SYMM -X, .50+Y, .50-Z SFAC C H O UNIT 216 160 24 SHEL 99999.000000 0.000000 L.S. 30 FMAP 2 PLAN -37 WPDB -2 HTAB BOND $H CONF LIST 4 TEMP -80.0 ACTA SIZE 0.600 0.300 0.100 DELU 0.001 0.001 O3 C8 DELU 0.001 0.001 C1 C2 DELU 0.001 0.001 C2 C3 DELU 0.001 0.001 C4 C5 DELU 0.001 0.001 C5 C6 DELU 0.001 0.001 C7 C8 DELU 0.001 0.001 C9 C10 WGHT 0.060100 EXTI 0.001843 FVAR 0.34933 O1 3 0.305255 0.718058 0.041261 11.00000 0.04971 0.04811 = 0.09858 -0.00400 0.01597 -0.00315 O2 3 0.430476 0.880977 -0.073482 11.00000 0.06891 0.05544 = 0.07140 0.01084 0.01132 0.00067 O3 3 0.193081 0.913627 0.239305 11.00000 0.07968 0.11548 = 0.08151 -0.01714 0.01328 0.03061 O4 3 0.106793 0.238021 0.229053 11.00000 0.05277 0.05666 = 0.04663 0.01054 0.00004 -0.00161 O5 3 0.039566 0.491252 0.155998 11.00000 0.05074 0.04693 = 0.08622 -0.00422 -0.00332 0.00965 O6 3 -0.036438 -0.052708 0.096423 11.00000 0.06148 0.05768 = 0.09306 -0.00368 0.00644 -0.01302 C1 1 0.354778 0.884850 0.029035 11.00000 0.04206 0.04312 = 0.06223 -0.00293 -0.01056 0.00463 C2 1 0.392954 0.937657 -0.026049 11.00000 0.05188 0.04441 = 0.06436 0.00712 -0.01454 -0.00271 C3 1 0.387796 1.046142 -0.032832 11.00000 0.07479 0.04725 = 0.08666 0.00391 -0.00727 0.00019 AFIX 43 H3 2 0.413066 1.081859 -0.070341 11.00000 -1.20000 AFIX 0 C4 1 0.346833 1.098274 0.014246 11.00000 0.07987 0.04583 = 0.09267 0.00167 -0.01757 0.00212 AFIX 43 H4 2 0.344042 1.171168 0.008839 11.00000 -1.20000 AFIX 0 C5 1 0.307953 1.051155 0.070931 11.00000 0.05746 0.05703 = 0.07588 -0.01293 -0.01942 0.01402 C6 1 0.265935 1.106058 0.119513 11.00000 0.07586 0.07682 = 0.08952 -0.02492 -0.01913 0.02381 AFIX 43 H6 2 0.263523 1.178953 0.113937 11.00000 -1.20000 AFIX 0 C7 1 0.228371 1.061166 0.174218 11.00000 0.06652 0.09094 = 0.07954 -0.03618 -0.01398 0.03882 AFIX 43 H7 2 0.200200 1.101240 0.206383 11.00000 -1.20000 AFIX 0 C8 1 0.232327 0.951468 0.182208 11.00000 0.05595 0.09434 = 0.06903 -0.01937 -0.00638 0.02309 C9 1 0.272452 0.893124 0.136654 11.00000 0.04764 0.06215 = 0.06359 -0.01477 -0.00915 0.01679 AFIX 43 H9 2 0.274622 0.820442 0.143811 11.00000 -1.20000 AFIX 0 C10 1 0.311024 0.940197 0.078590 11.00000 0.04514 0.05121 = 0.06732 -0.00707 -0.01804 0.00775 C11 1 0.358541 0.770295 0.032503 11.00000 0.04363 0.04489 = 0.05474 0.00190 -0.00165 -0.00111 C12 1 0.429578 0.718281 0.025016 11.00000 0.04401 0.03862 = 0.05113 0.00581 0.00453 0.00047 C13 1 0.437208 0.653825 -0.040573 11.00000 0.05400 0.04249 = 0.04579 0.00573 0.00433 -0.00501 C14 1 0.378836 0.629725 -0.100210 11.00000 0.06300 0.05507 = 0.05536 0.00367 0.00058 -0.00425 AFIX 43 H14 2 0.332409 0.658898 -0.096857 11.00000 -1.20000 AFIX 0 C15 1 0.389159 0.565276 -0.161849 11.00000 0.08306 0.06609 = 0.04988 0.00326 -0.00267 -0.01456 AFIX 43 H15 2 0.349595 0.549126 -0.200377 11.00000 -1.20000 AFIX 0 C16 1 0.457626 0.522459 -0.169064 11.00000 0.09266 0.06257 = 0.04999 -0.00415 0.01813 -0.01076 AFIX 43 H16 2 0.463638 0.477096 -0.212019 11.00000 -1.20000 AFIX 0 C17 1 0.514548 0.544999 -0.115922 11.00000 0.07490 0.05821 = 0.05462 -0.00130 0.02277 -0.00426 AFIX 43 H17 2 0.560504 0.516050 -0.122187 11.00000 -1.20000 AFIX 0 C18 1 0.507082 0.612075 -0.049853 11.00000 0.05694 0.04623 = 0.04802 0.00371 0.01458 -0.00235 C19 1 0.565174 0.634942 0.005995 11.00000 0.04967 0.05263 = 0.06020 0.00034 0.01382 0.00269 AFIX 43 H19 2 0.611848 0.610161 -0.002212 11.00000 -1.20000 AFIX 0 C20 1 0.557306 0.692861 0.073481 11.00000 0.04629 0.04547 = 0.05771 0.00217 0.00528 0.00118 C21 1 0.615927 0.709884 0.133978 11.00000 0.04788 0.05833 = 0.07706 -0.00409 -0.00278 0.00710 AFIX 43 H21 2 0.662743 0.685221 0.126247 11.00000 -1.20000 AFIX 0 C22 1 0.606409 0.760030 0.201668 11.00000 0.06326 0.06817 = 0.07481 -0.01246 -0.01694 0.01139 AFIX 43 H22 2 0.646178 0.770072 0.241313 11.00000 -1.20000 AFIX 0 C23 1 0.537461 0.797686 0.213807 11.00000 0.07334 0.06352 = 0.06030 -0.01308 -0.00699 0.01504 AFIX 43 H23 2 0.530735 0.830797 0.262624 11.00000 -1.20000 AFIX 0 C24 1 0.480514 0.787388 0.156845 11.00000 0.05418 0.05130 = 0.05850 -0.00429 0.00274 0.01153 AFIX 43 H24 2 0.435001 0.815846 0.165650 11.00000 -1.20000 AFIX 0 C25 1 0.487581 0.734742 0.084058 11.00000 0.04517 0.03775 = 0.05194 0.00232 0.00434 0.00194 C26 1 0.471454 0.930938 -0.129407 11.00000 0.06364 0.08011 = 0.08019 0.01942 0.00808 -0.01260 AFIX 137 H26A 2 0.506180 0.978677 -0.101072 11.00000 -1.20000 H26B 2 0.438662 0.969348 -0.168198 11.00000 -1.20000 H26C 2 0.497556 0.878969 -0.157213 11.00000 -1.20000 AFIX 0 C27 1 0.192359 0.805192 0.252399 11.00000 0.09948 0.13080 = 0.08638 -0.00368 0.03278 0.00154 AFIX 137 H27A 2 0.241678 0.781224 0.269170 11.00000 -1.20000 H27B 2 0.173577 0.770192 0.202960 11.00000 -1.20000 H27C 2 0.161326 0.789481 0.294086 11.00000 -1.20000 AFIX 0 C28 1 0.019979 0.316428 0.133948 11.00000 0.03597 0.05055 = 0.04227 0.00282 0.00736 0.00272 C29 1 -0.004185 0.416581 0.120934 11.00000 0.04133 0.05320 = 0.05375 0.00056 0.00664 0.00470 C30 1 -0.071036 0.437975 0.076414 11.00000 0.04657 0.06130 = 0.07075 0.00574 0.00291 0.01454 AFIX 43 H30 2 -0.086931 0.507156 0.067914 11.00000 -1.20000 AFIX 0 C31 1 -0.112530 0.357906 0.045745 11.00000 0.03783 0.08432 = 0.06099 0.00390 -0.00015 0.00958 AFIX 43 H31 2 -0.157200 0.372415 0.014794 11.00000 -1.20000 AFIX 0 C32 1 -0.091597 0.254682 0.058271 11.00000 0.03539 0.06764 = 0.05070 0.00050 0.00699 0.00077 C33 1 -0.134724 0.172396 0.024898 11.00000 0.04031 0.08841 = 0.06012 -0.00457 0.00231 -0.00577 AFIX 43 H33 2 -0.178921 0.187242 -0.006854 11.00000 -1.20000 AFIX 0 C34 1 -0.114396 0.073004 0.037214 11.00000 0.04649 0.08031 = 0.06589 -0.01127 0.00648 -0.01812 AFIX 43 H34 2 -0.143570 0.018759 0.013360 11.00000 -1.20000 AFIX 0 C35 1 -0.049457 0.050290 0.085810 11.00000 0.04869 0.05834 = 0.06257 -0.00195 0.01355 -0.00700 C36 1 -0.005654 0.127039 0.118681 11.00000 0.04026 0.05545 = 0.05134 -0.00018 0.00750 -0.00402 AFIX 43 H36 2 0.038094 0.110167 0.150558 11.00000 -1.20000 AFIX 0 C37 1 -0.025170 0.231918 0.105452 11.00000 0.03561 0.05747 = 0.04388 0.00221 0.00904 -0.00114 C38 1 0.094653 0.299096 0.174210 11.00000 0.04129 0.04341 = 0.04068 -0.00060 0.00542 0.00297 C39 1 0.155477 0.357872 0.142717 11.00000 0.03370 0.04099 = 0.04238 0.00199 0.00215 0.00610 C40 1 0.198920 0.425320 0.192882 11.00000 0.03605 0.04748 = 0.04269 0.00005 0.00161 0.00674 C41 1 0.191069 0.439164 0.275616 11.00000 0.05022 0.06855 = 0.04427 -0.00476 0.00313 0.00110 AFIX 43 H41 2 0.155300 0.400959 0.299036 11.00000 -1.20000 AFIX 0 C42 1 0.233749 0.505694 0.320783 11.00000 0.05959 0.08667 = 0.04630 -0.01244 -0.00036 0.00190 AFIX 43 H42 2 0.228171 0.512227 0.375791 11.00000 -1.20000 AFIX 0 C43 1 0.286381 0.565671 0.288219 11.00000 0.05466 0.07278 = 0.05987 -0.01597 -0.00757 -0.00307 AFIX 43 H43 2 0.315723 0.612226 0.321067 11.00000 -1.20000 AFIX 0 C44 1 0.295037 0.556770 0.209902 11.00000 0.04615 0.05940 = 0.06027 -0.00746 -0.00307 -0.00489 AFIX 43 H44 2 0.330304 0.597793 0.188066 11.00000 -1.20000 AFIX 0 C45 1 0.251983 0.486746 0.159870 11.00000 0.03774 0.04621 = 0.04720 -0.00279 -0.00095 0.00238 C46 1 0.259689 0.479026 0.078974 11.00000 0.03680 0.04579 = 0.05302 0.00171 0.00593 -0.00162 AFIX 43 H46 2 0.293940 0.521813 0.057061 11.00000 -1.20000 AFIX 0 C47 1 0.218651 0.410464 0.029494 11.00000 0.03411 0.04083 = 0.04443 0.00045 0.00308 0.00515 C48 1 0.227523 0.401959 -0.053103 11.00000 0.03957 0.05597 = 0.04579 0.00414 0.00848 -0.00121 AFIX 43 H48 2 0.260162 0.446827 -0.075627 11.00000 -1.20000 AFIX 0 C49 1 0.190198 0.331043 -0.099766 11.00000 0.04426 0.06642 = 0.04217 -0.00540 0.00755 -0.00184 AFIX 43 H49 2 0.196834 0.326286 -0.154612 11.00000 -1.20000 AFIX 0 C50 1 0.141410 0.264077 -0.067210 11.00000 0.03992 0.05324 = 0.04829 -0.00967 0.00572 -0.00180 AFIX 43 H50 2 0.116665 0.212890 -0.100024 11.00000 -1.20000 AFIX 0 C51 1 0.129342 0.271770 0.010321 11.00000 0.03453 0.04417 = 0.04863 -0.00121 0.00447 0.00097 AFIX 43 H51 2 0.095623 0.226574 0.030688 11.00000 -1.20000 AFIX 0 C52 1 0.166311 0.346405 0.061795 11.00000 0.03230 0.03816 = 0.04236 0.00154 0.00259 0.00546 C53 1 0.019749 0.596954 0.145411 11.00000 0.07206 0.05093 = 0.09737 0.00207 0.00382 0.01189 AFIX 137 H53A 2 -0.025764 0.609511 0.168020 11.00000 -1.20000 H53B 2 0.013519 0.613414 0.088431 11.00000 -1.20000 H53C 2 0.057860 0.640644 0.172499 11.00000 -1.20000 AFIX 0 C54 1 0.025834 -0.082165 0.147382 11.00000 0.07370 0.05283 = 0.09638 0.00213 0.00941 -0.00266 AFIX 137 H54A 2 0.069195 -0.056080 0.125946 11.00000 -1.20000 H54B 2 0.028182 -0.157591 0.150870 11.00000 -1.20000 H54C 2 0.023206 -0.053204 0.200581 11.00000 -1.20000 HKLF 4 REM YonezawaLab_120724_2_ REM R1 = 0.0402 for 4629 Fo > 4sig(Fo) and 0.0675 for all 7401 data REM 546 parameters refined using 7 restraints END WGHT 0.0617 0.0000 REM Highest difference peak 0.313, deepest hole -0.219, 1-sigma level 0.040 Q1 1 0.1931 1.0261 0.2165 11.00000 0.05 0.31 Q2 1 0.1594 0.8651 0.2696 11.00000 0.05 0.27 Q3 1 0.4436 0.9836 -0.0927 11.00000 0.05 0.25 Q4 1 0.2792 1.0320 0.1089 11.00000 0.05 0.23 Q5 1 0.3145 1.1137 0.0563 11.00000 0.05 0.18 Q6 1 0.2013 0.9188 0.2241 11.00000 0.05 0.18 Q7 1 0.3980 0.7407 0.0375 11.00000 0.05 0.17 Q8 1 0.3711 0.9511 0.0113 11.00000 0.05 0.16 Q9 1 0.0482 0.3120 0.1650 11.00000 0.05 0.16 Q10 1 0.1914 0.8023 -0.0035 11.00000 0.05 0.15 Q11 1 -0.0054 0.2807 0.1335 11.00000 0.05 0.15 Q12 1 0.1598 0.2293 0.2577 11.00000 0.05 0.14 Q13 1 0.3394 0.8996 0.0722 11.00000 0.05 0.14 Q14 1 0.0982 0.2657 0.1873 11.00000 0.05 0.14 Q15 1 -0.0672 0.2423 0.0911 11.00000 0.05 0.14 Q16 1 0.5194 0.5969 -0.0765 11.00000 0.05 0.14 Q17 1 0.1235 0.3395 0.1589 11.00000 0.05 0.14 Q18 1 -0.0408 0.2564 0.0783 11.00000 0.05 0.13 Q19 1 -0.1414 -0.0211 0.0318 11.00000 0.05 0.13 Q20 1 0.2134 0.4190 -0.0052 11.00000 0.05 0.13 Q21 1 0.1931 0.7003 -0.0105 11.00000 0.05 0.13 Q22 1 0.2489 0.8609 0.1728 11.00000 0.05 0.13 Q23 1 0.3000 1.0458 0.0464 11.00000 0.05 0.13 Q24 1 0.0414 0.5239 0.1572 11.00000 0.05 0.13 Q25 1 0.2391 0.7649 0.0010 11.00000 0.05 0.13 Q26 1 -0.0147 0.1944 0.1207 11.00000 0.05 0.13 Q27 1 0.3104 0.5716 -0.2118 11.00000 0.05 0.13 Q28 1 0.1757 0.6472 -0.0224 11.00000 0.05 0.13 Q29 1 0.6737 0.7818 0.2137 11.00000 0.05 0.13 Q30 1 0.4610 0.7508 0.0408 11.00000 0.05 0.13 Q31 1 0.3600 1.0651 0.0151 11.00000 0.05 0.12 Q32 1 0.1659 0.7357 0.2612 11.00000 0.05 0.12 Q33 1 0.4282 0.6790 0.0145 11.00000 0.05 0.12 Q34 1 -0.0293 0.6197 0.1156 11.00000 0.05 0.12 Q35 1 0.2367 0.3772 -0.0031 11.00000 0.05 0.12 Q36 1 0.2177 0.4705 0.0478 11.00000 0.05 0.12 Q37 1 0.0172 0.3329 0.1197 11.00000 0.05 0.12 ; _cod_data_source_file is5460sup1.cif _cod_data_source_block I _cod_original_sg_symbol_H-M 'P 21/c' _cod_database_code 2241955 loop_ _symmetry_equiv_pos_site_id _symmetry_equiv_pos_as_xyz 1 +X,+Y,+Z 2 -X,1/2+Y,1/2-Z 3 -X,-Y,-Z 4 +X,1/2-Y,1/2+Z loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_refinement_flags _atom_site_occupancy _atom_site_symmetry_multiplicity O O1 0.30526(6) 0.71806(9) 0.04126(8) 0.0649(4) Uani d . 1 1 O O2 0.43048(7) 0.88098(9) -0.07348(7) 0.0650(4) Uani d . 1 1 O O3 0.19308(8) 0.91363(15) 0.23930(9) 0.0919(5) Uani d U 1 1 O O4 0.10679(6) 0.23802(9) 0.22905(6) 0.0524(3) Uani d . 1 1 O O5 0.03957(6) 0.49125(9) 0.15600(7) 0.0621(3) Uani d . 1 1 O O6 -0.03644(7) -0.05271(10) 0.09642(8) 0.0709(4) Uani d . 1 1 C C1 0.35478(8) 0.88485(13) 0.02904(10) 0.0504(4) Uani d U 1 1 C C2 0.39295(9) 0.93766(14) -0.02605(11) 0.0551(4) Uani d U 1 1 C C3 0.38780(11) 1.04614(15) -0.03283(13) 0.0708(6) Uani d U 1 1 H H3 0.4131 1.0819 -0.0703 0.085 Uiso calc R 1 1 C C4 0.34683(12) 1.09827(16) 0.01425(13) 0.0748(6) Uani d U 1 1 H H4 0.3440 1.1712 0.0088 0.090 Uiso calc R 1 1 C C5 0.30795(10) 1.05116(15) 0.07093(12) 0.0655(5) Uani d U 1 1 C C6 0.26594(12) 1.10606(18) 0.11951(15) 0.0829(7) Uani d U 1 1 H H6 0.2635 1.1790 0.1139 0.099 Uiso calc R 1 1 C C7 0.22837(12) 1.06117(19) 0.17422(14) 0.0807(7) Uani d U 1 1 H H7 0.2002 1.1012 0.2064 0.097 Uiso calc R 1 1 C C8 0.23233(11) 0.95147(18) 0.18221(12) 0.0741(5) Uani d U 1 1 C C9 0.27245(9) 0.89312(15) 0.13665(10) 0.0589(5) Uani d U 1 1 H H9 0.2746 0.8204 0.1438 0.071 Uiso calc R 1 1 C C10 0.31102(9) 0.94020(14) 0.07859(11) 0.0564(4) Uani d U 1 1 C C11 0.35854(9) 0.77030(13) 0.03250(10) 0.0483(4) Uani d . 1 1 C C12 0.42958(8) 0.71828(12) 0.02502(10) 0.0446(4) Uani d . 1 1 C C13 0.43721(9) 0.65382(13) -0.04057(9) 0.0475(4) Uani d . 1 1 C C14 0.37884(10) 0.62973(14) -0.10021(10) 0.0583(5) Uani d . 1 1 H H14 0.3324 0.6589 -0.0969 0.070 Uiso calc R 1 1 C C15 0.38916(12) 0.56528(15) -0.16185(11) 0.0671(5) Uani d . 1 1 H H15 0.3496 0.5491 -0.2004 0.081 Uiso calc R 1 1 C C16 0.45763(12) 0.52246(16) -0.16906(11) 0.0676(5) Uani d . 1 1 H H16 0.4636 0.4771 -0.2120 0.081 Uiso calc R 1 1 C C17 0.51455(11) 0.54500(15) -0.11592(11) 0.0614(5) Uani d . 1 1 H H17 0.5605 0.5161 -0.1222 0.074 Uiso calc R 1 1 C C18 0.50708(9) 0.61207(13) -0.04985(10) 0.0497(4) Uani d . 1 1 C C19 0.56517(9) 0.63494(13) 0.00600(10) 0.0536(4) Uani d . 1 1 H H19 0.6118 0.6102 -0.0022 0.064 Uiso calc R 1 1 C C20 0.55731(9) 0.69286(13) 0.07348(10) 0.0499(4) Uani d . 1 1 C C21 0.61593(10) 0.70988(14) 0.13398(12) 0.0618(5) Uani d . 1 1 H H21 0.6627 0.6852 0.1262 0.074 Uiso calc R 1 1 C C22 0.60641(11) 0.76003(15) 0.20167(12) 0.0706(6) Uani d . 1 1 H H22 0.6462 0.7701 0.2413 0.085 Uiso calc R 1 1 C C23 0.53746(11) 0.79769(15) 0.21381(11) 0.0668(5) Uani d . 1 1 H H23 0.5307 0.8308 0.2626 0.080 Uiso calc R 1 1 C C24 0.48051(9) 0.78739(13) 0.15684(10) 0.0549(5) Uani d . 1 1 H H24 0.4350 0.8158 0.1656 0.066 Uiso calc R 1 1 C C25 0.48758(8) 0.73474(12) 0.08406(10) 0.0450(4) Uani d . 1 1 C C26 0.47145(10) 0.93094(16) -0.12941(12) 0.0746(6) Uani d . 1 1 H H26A 0.5062 0.9787 -0.1011 0.090 Uiso calc R 1 1 H H26B 0.4387 0.9693 -0.1682 0.090 Uiso calc R 1 1 H H26C 0.4976 0.8790 -0.1572 0.090 Uiso calc R 1 1 C C27 0.19236(14) 0.8052(2) 0.25240(14) 0.1039(8) Uani d . 1 1 H H27A 0.2417 0.7812 0.2692 0.125 Uiso calc R 1 1 H H27B 0.1736 0.7702 0.2030 0.125 Uiso calc R 1 1 H H27C 0.1613 0.7895 0.2941 0.125 Uiso calc R 1 1 C C28 0.01998(8) 0.31643(13) 0.13395(9) 0.0427(4) Uani d . 1 1 C C29 -0.00418(8) 0.41658(14) 0.12093(9) 0.0493(4) Uani d . 1 1 C C30 -0.07104(9) 0.43797(15) 0.07641(11) 0.0598(5) Uani d . 1 1 H H30 -0.0869 0.5072 0.0679 0.072 Uiso calc R 1 1 C C31 -0.11253(9) 0.35791(17) 0.04575(10) 0.0615(5) Uani d . 1 1 H H31 -0.1572 0.3724 0.0148 0.074 Uiso calc R 1 1 C C32 -0.09160(8) 0.25468(15) 0.05827(10) 0.0511(4) Uani d . 1 1 C C33 -0.13472(9) 0.17240(18) 0.02490(11) 0.0632(5) Uani d . 1 1 H H33 -0.1789 0.1872 -0.0069 0.076 Uiso calc R 1 1 C C34 -0.11440(9) 0.07300(18) 0.03721(11) 0.0642(5) Uani d . 1 1 H H34 -0.1436 0.0188 0.0134 0.077 Uiso calc R 1 1 C C35 -0.04946(9) 0.05029(15) 0.08581(11) 0.0560(5) Uani d . 1 1 C C36 -0.00565(8) 0.12704(14) 0.11868(9) 0.0488(4) Uani d . 1 1 H H36 0.0381 0.1102 0.1506 0.059 Uiso calc R 1 1 C C37 -0.02517(8) 0.23192(13) 0.10545(9) 0.0453(4) Uani d . 1 1 C C38 0.09465(8) 0.29910(13) 0.17421(9) 0.0417(4) Uani d . 1 1 C C39 0.15548(7) 0.35787(12) 0.14272(9) 0.0392(4) Uani d . 1 1 C C40 0.19892(8) 0.42532(12) 0.19288(9) 0.0423(4) Uani d . 1 1 C C41 0.19107(9) 0.43916(14) 0.27562(10) 0.0545(5) Uani d . 1 1 H H41 0.1553 0.4010 0.2990 0.065 Uiso calc R 1 1 C C42 0.23375(10) 0.50569(15) 0.32078(11) 0.0647(5) Uani d . 1 1 H H42 0.2282 0.5122 0.3758 0.078 Uiso calc R 1 1 C C43 0.28638(10) 0.56567(15) 0.28822(11) 0.0635(5) Uani d . 1 1 H H43 0.3157 0.6122 0.3211 0.076 Uiso calc R 1 1 C C44 0.29504(9) 0.55677(14) 0.20990(10) 0.0559(5) Uani d . 1 1 H H44 0.3303 0.5978 0.1881 0.067 Uiso calc R 1 1 C C45 0.25198(8) 0.48675(12) 0.15987(9) 0.0441(4) Uani d . 1 1 C C46 0.25969(8) 0.47903(12) 0.07897(9) 0.0451(4) Uani d . 1 1 H H46 0.2939 0.5218 0.0571 0.054 Uiso calc R 1 1 C C47 0.21865(8) 0.41046(12) 0.02949(9) 0.0399(4) Uani d . 1 1 C C48 0.22752(8) 0.40196(13) -0.05310(9) 0.0468(4) Uani d . 1 1 H H48 0.2602 0.4468 -0.0756 0.056 Uiso calc R 1 1 C C49 0.19020(8) 0.33104(14) -0.09977(9) 0.0507(4) Uani d . 1 1 H H49 0.1968 0.3263 -0.1546 0.061 Uiso calc R 1 1 C C50 0.14141(8) 0.26408(13) -0.06721(10) 0.0471(4) Uani d . 1 1 H H50 0.1167 0.2129 -0.1000 0.057 Uiso calc R 1 1 C C51 0.12934(8) 0.27177(12) 0.01032(9) 0.0425(4) Uani d . 1 1 H H51 0.0956 0.2266 0.0307 0.051 Uiso calc R 1 1 C C52 0.16631(7) 0.34640(11) 0.06179(9) 0.0377(4) Uani d . 1 1 C C53 0.01975(11) 0.59695(14) 0.14541(13) 0.0739(6) Uani d . 1 1 H H53A -0.0258 0.6095 0.1680 0.089 Uiso calc R 1 1 H H53B 0.0135 0.6134 0.0884 0.089 Uiso calc R 1 1 H H53C 0.0579 0.6406 0.1725 0.089 Uiso calc R 1 1 C C54 0.02583(11) -0.08217(15) 0.14738(13) 0.0743(6) Uani d . 1 1 H H54A 0.0692 -0.0561 0.1259 0.089 Uiso calc R 1 1 H H54B 0.0282 -0.1576 0.1509 0.089 Uiso calc R 1 1 H H54C 0.0232 -0.0532 0.2006 0.089 Uiso calc R 1 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 O1 0.0497(7) 0.0481(8) 0.0986(10) -0.0031(6) 0.0160(6) -0.0040(7) O2 0.0689(8) 0.0554(8) 0.0714(8) 0.0007(7) 0.0113(7) 0.0108(7) O3 0.0797(10) 0.1155(14) 0.0815(10) 0.0306(10) 0.0133(7) -0.0171(10) O4 0.0528(7) 0.0567(8) 0.0466(6) -0.0016(6) 0.0000(5) 0.0105(6) O5 0.0507(7) 0.0469(8) 0.0862(9) 0.0097(6) -0.0033(6) -0.0042(6) O6 0.0615(8) 0.0577(9) 0.0931(10) -0.0130(7) 0.0064(7) -0.0037(7) C1 0.0421(9) 0.0431(11) 0.0622(11) 0.0046(7) -0.0106(7) -0.0029(8) C2 0.0519(10) 0.0444(9) 0.0644(11) -0.0027(8) -0.0145(8) 0.0071(9) C3 0.0748(13) 0.0473(9) 0.0867(14) 0.0002(11) -0.0073(11) 0.0039(11) C4 0.0799(14) 0.0458(12) 0.0927(15) 0.0021(11) -0.0176(11) 0.0017(11) C5 0.0575(11) 0.0570(13) 0.0759(13) 0.0140(9) -0.0194(8) -0.0129(9) C6 0.0759(14) 0.0768(16) 0.0895(16) 0.0238(12) -0.0191(12) -0.0249(12) C7 0.0665(13) 0.0909(13) 0.0795(15) 0.0388(13) -0.0140(11) -0.0362(13) C8 0.0559(11) 0.0943(13) 0.0690(12) 0.0231(11) -0.0064(8) -0.0194(11) C9 0.0476(10) 0.0622(13) 0.0636(11) 0.0168(9) -0.0091(8) -0.0148(9) C10 0.0451(9) 0.0512(12) 0.0673(11) 0.0077(8) -0.0180(7) -0.0071(9) C11 0.0436(9) 0.0449(11) 0.0547(10) -0.0011(8) -0.0016(8) 0.0019(8) C12 0.0440(9) 0.0386(10) 0.0511(9) 0.0005(7) 0.0045(7) 0.0058(8) C13 0.0540(10) 0.0425(10) 0.0458(9) -0.0050(8) 0.0043(8) 0.0057(8) C14 0.0630(11) 0.0551(12) 0.0554(11) -0.0042(9) 0.0006(9) 0.0037(9) C15 0.0831(14) 0.0661(14) 0.0499(11) -0.0146(12) -0.0027(10) 0.0033(10) C16 0.0927(16) 0.0626(13) 0.0500(11) -0.0108(12) 0.0181(11) -0.0042(10) C17 0.0749(13) 0.0582(12) 0.0546(11) -0.0043(10) 0.0228(10) -0.0013(10) C18 0.0569(10) 0.0462(11) 0.0480(10) -0.0024(8) 0.0146(8) 0.0037(8) C19 0.0497(10) 0.0526(11) 0.0602(11) 0.0027(9) 0.0138(8) 0.0003(9) C20 0.0463(9) 0.0455(10) 0.0577(10) 0.0012(8) 0.0053(8) 0.0022(9) C21 0.0479(10) 0.0583(12) 0.0771(13) 0.0071(9) -0.0028(9) -0.0041(10) C22 0.0633(12) 0.0682(14) 0.0748(14) 0.0114(11) -0.0169(10) -0.0125(11) C23 0.0733(13) 0.0635(13) 0.0603(11) 0.0150(11) -0.0070(10) -0.0131(10) C24 0.0542(10) 0.0513(11) 0.0585(11) 0.0115(9) 0.0027(9) -0.0043(9) C25 0.0452(9) 0.0378(10) 0.0519(10) 0.0019(7) 0.0043(7) 0.0023(8) C26 0.0636(12) 0.0801(15) 0.0802(14) -0.0126(11) 0.0081(10) 0.0194(12) C27 0.0995(19) 0.131(3) 0.0864(17) 0.0015(18) 0.0328(14) -0.0037(17) C28 0.0360(8) 0.0505(11) 0.0423(9) 0.0027(8) 0.0074(7) 0.0028(8) C29 0.0413(9) 0.0532(12) 0.0538(10) 0.0047(8) 0.0066(8) 0.0006(9) C30 0.0466(10) 0.0613(13) 0.0708(12) 0.0145(9) 0.0029(9) 0.0057(10) C31 0.0378(9) 0.0843(15) 0.0610(11) 0.0096(10) -0.0002(8) 0.0039(11) C32 0.0354(8) 0.0676(13) 0.0507(10) 0.0008(9) 0.0070(7) 0.0005(9) C33 0.0403(9) 0.0884(16) 0.0601(11) -0.0058(10) 0.0023(8) -0.0046(11) C34 0.0465(10) 0.0803(16) 0.0659(12) -0.0181(10) 0.0065(9) -0.0113(11) C35 0.0487(10) 0.0583(13) 0.0626(11) -0.0070(9) 0.0135(8) -0.0020(9) C36 0.0403(9) 0.0555(12) 0.0513(10) -0.0040(8) 0.0075(7) -0.0002(8) C37 0.0356(8) 0.0575(12) 0.0439(9) -0.0011(8) 0.0090(7) 0.0022(8) C38 0.0413(9) 0.0434(10) 0.0407(9) 0.0030(7) 0.0054(7) -0.0006(8) C39 0.0337(7) 0.0410(9) 0.0424(8) 0.0061(7) 0.0021(6) 0.0020(7) C40 0.0361(8) 0.0475(10) 0.0427(9) 0.0067(7) 0.0016(7) 0.0000(8) C41 0.0502(10) 0.0685(13) 0.0443(9) 0.0011(9) 0.0031(8) -0.0048(9) C42 0.0596(11) 0.0867(15) 0.0463(10) 0.0019(11) -0.0004(9) -0.0124(10) C43 0.0547(11) 0.0728(13) 0.0599(12) -0.0031(10) -0.0076(9) -0.0160(10) C44 0.0461(9) 0.0594(12) 0.0603(11) -0.0049(9) -0.0031(8) -0.0075(9) C45 0.0377(8) 0.0462(10) 0.0472(9) 0.0024(7) -0.0010(7) -0.0028(8) C46 0.0368(8) 0.0458(10) 0.0530(10) -0.0016(7) 0.0059(7) 0.0017(8) C47 0.0341(8) 0.0408(9) 0.0444(9) 0.0052(7) 0.0031(7) 0.0005(7) C48 0.0396(8) 0.0560(11) 0.0458(9) -0.0012(8) 0.0085(7) 0.0041(8) C49 0.0443(9) 0.0664(12) 0.0422(9) -0.0018(9) 0.0075(7) -0.0054(9) C50 0.0399(8) 0.0532(11) 0.0483(10) -0.0018(8) 0.0057(7) -0.0097(8) C51 0.0345(8) 0.0442(10) 0.0486(9) 0.0010(7) 0.0045(7) -0.0012(8) C52 0.0323(7) 0.0382(9) 0.0424(9) 0.0055(7) 0.0026(6) 0.0015(7) C53 0.0721(13) 0.0509(13) 0.0974(15) 0.0119(10) 0.0038(11) 0.0021(11) C54 0.0737(14) 0.0528(13) 0.0964(15) -0.0027(11) 0.0094(12) 0.0021(11) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle C2 O2 C26 119.82(15) C8 O3 C27 118.70(17) C29 O5 C53 119.77(14) C35 O6 C54 117.68(14) C2 C1 C10 120.40(16) C2 C1 C11 119.08(16) C10 C1 C11 120.47(16) O2 C2 C1 117.57(15) O2 C2 C3 122.18(17) C1 C2 C3 120.15(18) C4 C3 C2 119.4(2) C4 C3 H3 120.3 C2 C3 H3 120.3 C3 C4 C5 123.7(2) C3 C4 H4 118.2 C5 C4 H4 118.2 C6 C5 C4 123.1(2) C6 C5 C10 118.4(2) C4 C5 C10 118.46(18) C7 C6 C5 123.4(2) C7 C6 H6 118.3 C5 C6 H6 118.3 C6 C7 C8 117.9(2) C6 C7 H7 121.0 C8 C7 H7 121.0 C9 C8 O3 124.8(2) C9 C8 C7 121.7(2) O3 C8 C7 113.5(2) C8 C9 C10 120.29(19) C8 C9 H9 119.9 C10 C9 H9 119.9 C9 C10 C1 123.81(17) C9 C10 C5 118.23(17) C1 C10 C5 117.93(17) O1 C11 C1 121.49(15) O1 C11 C12 119.62(15) C1 C11 C12 118.89(14) C25 C12 C13 120.90(14) C25 C12 C11 119.13(14) C13 C12 C11 119.97(14) C12 C13 C14 123.29(15) C12 C13 C18 118.84(15) C14 C13 C18 117.85(15) C15 C14 C13 120.70(18) C15 C14 H14 119.6 C13 C14 H14 119.6 C14 C15 C16 120.85(18) C14 C15 H15 119.6 C16 C15 H15 119.6 C17 C16 C15 120.71(18) C17 C16 H16 119.6 C15 C16 H16 119.6 C16 C17 C18 121.03(19) C16 C17 H17 119.5 C18 C17 H17 119.5 C19 C18 C13 119.55(15) C19 C18 C17 121.62(16) C13 C18 C17 118.80(16) C18 C19 C20 122.03(16) C18 C19 H19 119.0 C20 C19 H19 119.0 C19 C20 C21 122.07(16) C19 C20 C25 119.11(15) C21 C20 C25 118.80(16) C22 C21 C20 121.47(17) C22 C21 H21 119.3 C20 C21 H21 119.3 C21 C22 C23 119.97(18) C21 C22 H22 120.0 C23 C22 H22 120.0 C24 C23 C22 120.98(18) C24 C23 H23 119.5 C22 C23 H23 119.5 C23 C24 C25 121.32(16) C23 C24 H24 119.3 C25 C24 H24 119.3 C12 C25 C24 123.32(14) C12 C25 C20 119.25(15) C24 C25 C20 117.36(14) O2 C26 H26A 109.5 O2 C26 H26B 109.5 H26A C26 H26B 109.5 O2 C26 H26C 109.5 H26A C26 H26C 109.5 H26B C26 H26C 109.5 O3 C27 H27A 109.5 O3 C27 H27B 109.5 H27A C27 H27B 109.5 O3 C27 H27C 109.5 H27A C27 H27C 109.5 H27B C27 H27C 109.5 C29 C28 C37 119.79(14) C29 C28 C38 118.86(15) C37 C28 C38 121.28(14) O5 C29 C28 115.55(14) O5 C29 C30 122.95(16) C28 C29 C30 121.47(17) C31 C30 C29 118.89(17) C31 C30 H30 120.6 C29 C30 H30 120.6 C30 C31 C32 122.25(16) C30 C31 H31 118.9 C32 C31 H31 118.9 C31 C32 C33 121.58(16) C31 C32 C37 119.39(16) C33 C32 C37 119.03(17) C34 C33 C32 121.39(17) C34 C33 H33 119.3 C32 C33 H33 119.3 C33 C34 C35 119.60(18) C33 C34 H34 120.2 C35 C34 H34 120.2 C36 C35 O6 124.78(16) C36 C35 C34 121.17(18) O6 C35 C34 114.05(17) C35 C36 C37 120.26(16) C35 C36 H36 119.9 C37 C36 H36 119.9 C36 C37 C32 118.52(15) C36 C37 C28 123.39(14) C32 C37 C28 118.02(15) O4 C38 C28 121.83(14) O4 C38 C39 120.82(13) C28 C38 C39 117.33(13) C40 C39 C52 120.94(13) C40 C39 C38 120.26(13) C52 C39 C38 118.78(13) C39 C40 C45 119.09(14) C39 C40 C41 123.44(14) C45 C40 C41 117.42(14) C42 C41 C40 120.96(17) C42 C41 H41 119.5 C40 C41 H41 119.5 C41 C42 C43 121.50(17) C41 C42 H42 119.3 C43 C42 H42 119.3 C44 C43 C42 119.81(17) C44 C43 H43 120.1 C42 C43 H43 120.1 C43 C44 C45 120.90(17) C43 C44 H44 119.5 C45 C44 H44 119.5 C46 C45 C44 121.03(15) C46 C45 C40 119.57(14) C44 C45 C40 119.39(15) C47 C46 C45 121.78(14) C47 C46 H46 119.1 C45 C46 H46 119.1 C46 C47 C48 121.48(14) C46 C47 C52 119.53(14) C48 C47 C52 118.99(14) C49 C48 C47 121.00(15) C49 C48 H48 119.5 C47 C48 H48 119.5 C48 C49 C50 120.14(15) C48 C49 H49 119.9 C50 C49 H49 119.9 C51 C50 C49 120.90(15) C51 C50 H50 119.6 C49 C50 H50 119.6 C50 C51 C52 121.23(14) C50 C51 H51 119.4 C52 C51 H51 119.4 C39 C52 C51 123.45(13) C39 C52 C47 118.93(13) C51 C52 C47 117.59(13) O5 C53 H53A 109.5 O5 C53 H53B 109.5 H53A C53 H53B 109.5 O5 C53 H53C 109.5 H53A C53 H53C 109.5 H53B C53 H53C 109.5 O6 C54 H54A 109.5 O6 C54 H54B 109.5 H54A C54 H54B 109.5 O6 C54 H54C 109.5 H54A C54 H54C 109.5 H54B C54 H54C 109.5 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance O1 C11 1.2226(18) O2 C2 1.339(2) O2 C26 1.432(2) O3 C8 1.364(2) O3 C27 1.423(3) O4 C38 1.2203(17) O5 C29 1.3574(19) O5 C53 1.425(2) O6 C35 1.365(2) O6 C54 1.417(2) C1 C2 1.409(2) C1 C10 1.424(2) C1 C11 1.487(2) C2 C3 1.413(3) C3 C4 1.343(3) C3 H3 0.9500 C4 C5 1.402(3) C4 H4 0.9500 C5 C6 1.390(3) C5 C10 1.444(3) C6 C7 1.350(3) C6 H6 0.9500 C7 C8 1.429(3) C7 H7 0.9500 C8 C9 1.359(2) C9 C10 1.416(2) C9 H9 0.9500 C11 C12 1.501(2) C12 C25 1.402(2) C12 C13 1.407(2) C13 C14 1.431(2) C13 C18 1.432(2) C14 C15 1.365(2) C14 H14 0.9500 C15 C16 1.407(3) C15 H15 0.9500 C16 C17 1.342(3) C16 H16 0.9500 C17 C18 1.433(2) C17 H17 0.9500 C18 C19 1.385(2) C19 C20 1.386(2) C19 H19 0.9500 C20 C21 1.426(2) C20 C25 1.435(2) C21 C22 1.344(2) C21 H21 0.9500 C22 C23 1.408(3) C22 H22 0.9500 C23 C24 1.356(2) C23 H23 0.9500 C24 C25 1.425(2) C24 H24 0.9500 C26 H26A 0.9800 C26 H26B 0.9800 C26 H26C 0.9800 C27 H27A 0.9800 C27 H27B 0.9800 C27 H27C 0.9800 C28 C29 1.383(2) C28 C37 1.431(2) C28 C38 1.494(2) C29 C30 1.407(2) C30 C31 1.361(3) C30 H30 0.9500 C31 C32 1.403(2) C31 H31 0.9500 C32 C33 1.414(2) C32 C37 1.425(2) C33 C34 1.352(3) C33 H33 0.9500 C34 C35 1.414(2) C34 H34 0.9500 C35 C36 1.364(2) C36 C37 1.418(2) C36 H36 0.9500 C38 C39 1.509(2) C39 C40 1.408(2) C39 C52 1.4113(19) C40 C45 1.428(2) C40 C41 1.432(2) C41 C42 1.350(2) C41 H41 0.9500 C42 C43 1.409(3) C42 H42 0.9500 C43 C44 1.355(2) C43 H43 0.9500 C44 C45 1.424(2) C44 H44 0.9500 C45 C46 1.393(2) C46 C47 1.389(2) C46 H46 0.9500 C47 C48 1.427(2) C47 C52 1.433(2) C48 C49 1.351(2) C48 H48 0.9500 C49 C50 1.410(2) C49 H49 0.9500 C50 C51 1.357(2) C50 H50 0.9500 C51 C52 1.425(2) C51 H51 0.9500 C53 H53A 0.9800 C53 H53B 0.9800 C53 H53C 0.9800 C54 H54A 0.9800 C54 H54B 0.9800 C54 H54C 0.9800 loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_D _geom_hbond_site_symmetry_H _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_publ_flag C7 H7 O4 1_555 1_555 1_545 0.95 2.54 3.419(3) 154 y C46 H46 O1 1_555 1_555 1_555 0.95 2.57 3.2925(19) 133 y C49 H49 O4 1_555 1_555 4_554 0.95 2.57 3.2515(19) 128 y C50 H50 O6 1_555 1_555 3_555 0.95 2.56 3.368(2) 143 y C3 H3 Cg1 1_555 1_555 3_675 0.95 2.68 3.557(2) 153 y C26 H26A Cg2 1_555 1_555 3_675 0.98 2.87 3.730(2) 147 y C30 H30 Cg3 1_555 1_555 3_565 0.95 2.71 3.602(2) 157 y loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion C26 O2 C2 C1 -178.71(14) C26 O2 C2 C3 4.7(2) C10 C1 C2 O2 -176.99(14) C11 C1 C2 O2 0.7(2) C10 C1 C2 C3 -0.3(2) C11 C1 C2 C3 177.33(15) O2 C2 C3 C4 177.20(17) C1 C2 C3 C4 0.7(3) C2 C3 C4 C5 0.0(3) C3 C4 C5 C6 179.76(19) C3 C4 C5 C10 -1.0(3) C4 C5 C6 C7 -179.99(19) C10 C5 C6 C7 0.7(3) C5 C6 C7 C8 0.0(3) C27 O3 C8 C9 -1.0(3) C27 O3 C8 C7 179.54(18) C6 C7 C8 C9 0.1(3) C6 C7 C8 O3 179.52(17) O3 C8 C9 C10 179.69(16) C7 C8 C9 C10 -0.9(3) C8 C9 C10 C1 179.38(15) C8 C9 C10 C5 1.6(2) C2 C1 C10 C9 -178.42(15) C11 C1 C10 C9 4.0(2) C2 C1 C10 C5 -0.7(2) C11 C1 C10 C5 -178.28(14) C6 C5 C10 C9 -1.5(2) C4 C5 C10 C9 179.16(16) C6 C5 C10 C1 -179.42(16) C4 C5 C10 C1 1.3(2) C2 C1 C11 O1 -139.85(17) C10 C1 C11 O1 37.8(2) C2 C1 C11 C12 40.1(2) C10 C1 C11 C12 -142.21(15) O1 C11 C12 C25 -115.57(18) C1 C11 C12 C25 64.4(2) O1 C11 C12 C13 64.3(2) C1 C11 C12 C13 -115.69(17) C25 C12 C13 C14 176.42(15) C11 C12 C13 C14 -3.4(2) C25 C12 C13 C18 -5.3(2) C11 C12 C13 C18 174.81(14) C12 C13 C14 C15 -178.89(16) C18 C13 C14 C15 2.8(2) C13 C14 C15 C16 -1.1(3) C14 C15 C16 C17 -0.8(3) C15 C16 C17 C18 0.8(3) C12 C13 C18 C19 0.7(2) C14 C13 C18 C19 179.03(15) C12 C13 C18 C17 178.94(14) C14 C13 C18 C17 -2.7(2) C16 C17 C18 C19 179.17(17) C16 C17 C18 C13 0.9(3) C13 C18 C19 C20 3.5(3) C17 C18 C19 C20 -174.67(15) C18 C19 C20 C21 175.16(16) C18 C19 C20 C25 -3.1(2) C19 C20 C21 C22 -175.28(18) C25 C20 C21 C22 3.0(3) C20 C21 C22 C23 -0.4(3) C21 C22 C23 C24 -2.3(3) C22 C23 C24 C25 2.5(3) C13 C12 C25 C24 -171.16(15) C11 C12 C25 C24 8.7(2) C13 C12 C25 C20 5.8(2) C11 C12 C25 C20 -174.35(15) C23 C24 C25 C12 177.12(17) C23 C24 C25 C20 0.1(3) C19 C20 C25 C12 -1.6(2) C21 C20 C25 C12 -179.88(15) C19 C20 C25 C24 175.54(15) C21 C20 C25 C24 -2.8(2) C53 O5 C29 C28 179.33(15) C53 O5 C29 C30 -2.8(2) C37 C28 C29 O5 174.52(13) C38 C28 C29 O5 -8.5(2) C37 C28 C29 C30 -3.4(2) C38 C28 C29 C30 173.60(14) O5 C29 C30 C31 -177.69(16) C28 C29 C30 C31 0.1(3) C29 C30 C31 C32 1.3(3) C30 C31 C32 C33 -178.92(16) C30 C31 C32 C37 0.8(3) C31 C32 C33 C34 -179.90(16) C37 C32 C33 C34 0.4(2) C32 C33 C34 C35 1.4(3) C54 O6 C35 C36 2.2(2) C54 O6 C35 C34 -177.12(16) C33 C34 C35 C36 -2.0(3) C33 C34 C35 O6 177.34(15) O6 C35 C36 C37 -178.40(14) C34 C35 C36 C37 0.9(2) C35 C36 C37 C32 0.8(2) C35 C36 C37 C28 -176.15(14) C31 C32 C37 C36 178.80(15) C33 C32 C37 C36 -1.5(2) C31 C32 C37 C28 -4.0(2) C33 C32 C37 C28 175.70(14) C29 C28 C37 C36 -177.69(14) C38 C28 C37 C36 5.4(2) C29 C28 C37 C32 5.3(2) C38 C28 C37 C32 -171.61(13) C29 C28 C38 O4 132.66(16) C37 C28 C38 O4 -50.4(2) C29 C28 C38 C39 -49.21(19) C37 C28 C38 C39 127.73(15) O4 C38 C39 C40 -61.2(2) C28 C38 C39 C40 120.68(15) O4 C38 C39 C52 120.84(16) C28 C38 C39 C52 -57.30(19) C52 C39 C40 C45 3.4(2) C38 C39 C40 C45 -174.59(13) C52 C39 C40 C41 -179.19(14) C38 C39 C40 C41 2.9(2) C39 C40 C41 C42 -179.32(16) C45 C40 C41 C42 -1.8(2) C40 C41 C42 C43 1.5(3) C41 C42 C43 C44 -0.2(3) C42 C43 C44 C45 -0.5(3) C43 C44 C45 C46 178.61(16) C43 C44 C45 C40 0.1(2) C39 C40 C45 C46 0.1(2) C41 C40 C45 C46 -177.49(14) C39 C40 C45 C44 178.65(14) C41 C40 C45 C44 1.0(2) C44 C45 C46 C47 179.37(15) C40 C45 C46 C47 -2.1(2) C45 C46 C47 C48 -179.13(14) C45 C46 C47 C52 0.7(2) C46 C47 C48 C49 176.31(15) C52 C47 C48 C49 -3.5(2) C47 C48 C49 C50 0.2(2) C48 C49 C50 C51 2.2(2) C49 C50 C51 C52 -1.1(2) C40 C39 C52 C51 173.22(14) C38 C39 C52 C51 -8.8(2) C40 C39 C52 C47 -4.8(2) C38 C39 C52 C47 173.18(13) C50 C51 C52 C39 179.70(14) C50 C51 C52 C47 -2.3(2) C46 C47 C52 C39 2.8(2) C48 C47 C52 C39 -177.42(13) C46 C47 C52 C51 -175.36(13) C48 C47 C52 C51 4.5(2) _cod_database_fobs_code 2241955