#------------------------------------------------------------------------------
#$Date: 2023-08-16 04:49:24 +0300 (Wed, 16 Aug 2023) $
#$Revision: 285784 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/31/22/2312276.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2312276
loop_
_publ_author_name
'Treece, Megan M.'
'Kelly, Jordan C.'
'Rosello, Kate E.'
'Craig, Andrew J.'
'Aitken, Jennifer A.'
_publ_section_title
;
Accurate X-ray diffraction data required for proper evaluation of bond
valence sums and global instability indexes: redetermination of the
crystal structures of diamond-like Cu2CdSiS4 and
Cu2HgSnS4 as a case study.
;
_journal_coeditor_code VX3001
_journal_issue 9
_journal_name_full
'Acta crystallographica. Section C, Structural chemistry'
_journal_paper_doi 10.1107/S2053229623006848
_journal_volume 79
_journal_year 2023
_chemical_formula_iupac 'Cu2 Hg Sn S4'
_chemical_formula_moiety 'Cu2 Hg S4 Sn'
_chemical_formula_sum 'Cu2 Hg S4 Sn'
_chemical_formula_weight 574.60
_chemical_name_common 'Copper mercury tin sulfide'
_chemical_name_systematic 'Copper mercury tin sulfide'
_space_group_crystal_system tetragonal
_space_group_IT_number 121
_space_group_name_Hall 'I -4 2'
_space_group_name_H-M_alt 'I -4 2 m'
_atom_sites_solution_primary direct
_atom_sites_solution_secondary difmap
_audit_creation_method SHELXL-2018/3
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_formula_units_Z 2
_cell_length_a 5.5798(12)
_cell_length_b 5.5798(12)
_cell_length_c 10.860(3)
_cell_measurement_reflns_used 1625
_cell_measurement_temperature 296
_cell_measurement_theta_max 27.2661
_cell_measurement_theta_min 3.7525
_cell_volume 338.12(14)
_computing_cell_refinement
;
SAINT (Bruker, 2018)
;
_computing_data_collection
;
SMART (Bruker, 2001)
;
_computing_data_reduction
;
SAINT (Bruker, 2018)
;
_computing_molecular_graphics
;
ShelXle (H\"ubschle et al., 2011)
;
_computing_publication_material
;
SHELXL2018 (Sheldrick, 2015b)
;
_computing_structure_refinement
;
SHELXL2018 (Sheldrick, 2015b)
;
_computing_structure_solution
;
SHELXL2014 (Sheldrick, 2015a)
;
_diffrn_ambient_temperature 296
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type 'Bruker SMART APEXII CCD'
_diffrn_measurement_method '\f and \w scans'
_diffrn_radiation_type MoK\a
_diffrn_radiation_wavelength 0.71073
_diffrn_reflns_av_R_equivalents 0.0403
_diffrn_reflns_av_unetI/netI 0.0230
_diffrn_reflns_limit_h_max 7
_diffrn_reflns_limit_h_min -7
_diffrn_reflns_limit_k_max 7
_diffrn_reflns_limit_k_min -7
_diffrn_reflns_limit_l_max 14
_diffrn_reflns_limit_l_min -13
_diffrn_reflns_number 2088
_diffrn_reflns_theta_full 25.242
_diffrn_reflns_theta_max 27.266
_diffrn_reflns_theta_min 3.752
_diffrn_source 'fine focus sealed tube X-ray source'
_exptl_absorpt_coefficient_mu 33.598
_exptl_absorpt_correction_T_max 0.7456
_exptl_absorpt_correction_T_min 0.3518
_exptl_absorpt_correction_type multi-scan
_exptl_absorpt_process_details
;
(SADABS; Sheldrick, 2002)
;
_exptl_crystal_colour black
_exptl_crystal_density_diffrn 5.644
_exptl_crystal_density_method 'not measured'
_exptl_crystal_description prism
_exptl_crystal_F_000 504
_exptl_crystal_size_max 0.136
_exptl_crystal_size_mid 0.134
_exptl_crystal_size_min 0.076
_refine_diff_density_max 0.534
_refine_diff_density_min -0.855
_refine_ls_abs_structure_details
;
Flack x determined using 76 quotients [(I+)-(I-)]/[(I+)+(I-)]
(Parsons et al., 2013)
;
_refine_ls_abs_structure_Flack 0.021(11)
_refine_ls_extinction_coef 0.0232(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method
;
SHELXL2018 (Sheldrick, 2015b)
;
_refine_ls_goodness_of_fit_ref 1.080
_refine_ls_hydrogen_treatment undef
_refine_ls_matrix_type full
_refine_ls_number_parameters 14
_refine_ls_number_reflns 218
_refine_ls_number_restraints 0
_refine_ls_restrained_S_all 1.080
_refine_ls_R_factor_all 0.0141
_refine_ls_R_factor_gt 0.0141
_refine_ls_shift/su_max 0.000
_refine_ls_shift/su_mean 0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0124P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme calc
_refine_ls_wR_factor_gt 0.0317
_refine_ls_wR_factor_ref 0.0317
_reflns_number_gt 218
_reflns_number_total 218
_reflns_threshold_expression 'I > 2\s(I)'
_cod_data_source_file vx3001sup1.cif
_cod_data_source_block Cu2HgSnS4
_cod_original_cell_volume 338.11(17)
_cod_database_code 2312276
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min 0.092
_shelx_estimated_absorpt_t_max 0.184
_shelx_hkl_file
;
1 1 0 1862.91 109.39
1 1 0 1812.62 109.09
-1 -1 0 1833.32 108.49
-1 -1 0 1819.02 110.49
-1 -1 0 1834.52 108.79
1 -1 0 1953.80 108.69
1 -1 0 1927.41 110.59
1 -1 0 1694.43 110.89
2 0 0 4112.09 235.28
0 2 0 3553.34 232.88
2 0 0 3663.53 236.78
-2 0 0 4227.58 235.18
0 -2 0 4270.47 235.78
0 -2 0 3940.41 238.58
0 -2 0 3499.95 232.08
0 -2 0 4165.78 236.58
0 2 0 4341.17 237.58
-2 -2 0 8497.75 522.45
2 -2 0 9398.86 532.35
-2 -2 0 8905.11 526.45
-2 -2 0 8306.57 519.25
2 -2 0 9056.19 533.05
2 -2 0 8730.43 523.35
2 2 0 8473.75 524.85
2 2 0 9721.13 521.25
-3 -1 0 1410.06 91.39
3 1 0 1475.35 85.99
3 1 0 1427.46 87.09
1 -3 0 1434.56 86.49
-1 3 0 1442.16 86.19
1 -3 0 1449.55 92.49
3 1 0 1402.66 92.29
3 -1 0 1444.36 84.59
1 3 0 1240.18 83.49
-1 -3 0 1286.57 84.69
-1 -3 0 1323.17 83.89
3 -1 0 1342.27 85.59
1 3 0 1380.86 82.19
3 -1 0 1381.06 84.79
-1 -3 0 1389.36 81.39
3 -3 0 1121.59 69.19
3 3 0 1110.39 72.39
-3 -3 0 1095.39 70.69
3 -3 0 1092.09 76.19
-3 -3 0 1096.39 74.79
3 3 0 1121.39 70.59
3 -3 0 1065.59 68.99
4 2 0 2597.04 162.28
2 -4 0 2588.54 164.78
-4 -2 0 2482.65 162.58
4 2 0 2628.54 154.98
2 -4 0 2524.75 154.98
-2 4 0 2723.93 155.28
-4 0 0 7184.98 398.66
0 -4 0 6576.74 399.16
0 -4 0 6717.13 393.26
0 -4 0 6286.17 390.06
0 4 0 7025.60 392.66
4 0 0 6523.85 399.46
0 -4 0 6521.65 392.16
4 -2 0 2628.34 153.18
-2 -4 0 2395.46 154.18
4 -2 0 2638.44 156.78
-2 -4 0 2421.46 150.08
2 4 0 2491.45 151.68
4 -2 0 2434.36 152.88
2 4 0 2443.96 153.08
-2 -4 0 2513.85 153.48
-4 -4 0 4646.73 289.97
4 4 0 4924.41 292.97
4 -4 0 4887.51 298.37
4 4 0 4720.13 288.07
-4 -4 0 4791.82 295.07
4 -4 0 4714.63 287.57
-4 4 0 5012.50 287.47
3 -5 0 658.33 55.19
5 3 0 634.94 42.70
-5 -3 0 657.33 51.89
-3 5 0 604.24 42.80
5 3 0 588.64 49.70
-5 -1 0 841.32 61.59
5 1 0 866.01 61.69
-1 5 0 828.92 53.79
1 -5 0 816.72 63.19
-5 1 0 840.72 58.59
1 5 0 778.82 53.09
-1 -5 0 794.22 50.79
-1 -5 0 787.22 54.89
-1 -5 0 822.12 59.29
5 -1 0 898.71 61.29
3 5 0 556.94 44.20
5 -3 0 620.84 44.70
-3 -5 0 600.04 47.70
-5 3 0 617.74 45.70
3 5 0 572.84 44.40
-3 -5 0 546.45 42.10
5 -3 0 679.53 51.69
-5 -5 0 468.05 44.80
5 5 0 473.45 37.40
5 5 0 437.16 42.20
5 -5 0 489.05 50.09
-6 -2 0 3654.13 227.58
6 2 0 3699.73 225.38
2 -6 0 3450.75 230.48
6 0 0 1341.17 88.79
-6 0 0 1264.37 88.59
0 6 0 1197.68 79.99
0 -6 0 1278.17 90.69
-2 -6 0 3282.07 206.38
-2 -6 0 3395.06 215.48
-6 2 0 3579.34 216.18
6 -2 0 3669.23 216.38
2 6 0 3382.36 210.08
-7 -1 0 384.26 39.90
1 -7 0 398.76 43.30
7 1 0 438.36 38.80
7 -1 0 446.86 40.70
-7 1 0 399.36 39.50
-1 -7 0 395.26 40.60
0 -1 -1 339.67 24.80
0 -1 -1 365.06 22.60
0 1 -1 379.96 23.10
0 -1 -1 388.26 23.60
1 0 -1 369.46 24.50
0 -1 -1 402.66 22.90
1 0 -1 388.96 22.50
-1 0 -1 363.56 24.30
1 0 -1 413.06 23.80
1 0 -1 334.47 22.20
0 1 -1 368.36 22.90
0 1 1 401.26 22.40
1 0 1 363.96 22.50
0 -1 1 375.86 22.40
1 0 1 390.36 22.70
1 0 1 385.46 23.00
1 0 1 357.56 24.40
-1 0 1 348.47 24.30
0 -1 1 353.56 24.10
-2 -1 -1 409.16 28.40
2 1 -1 434.46 27.40
-2 -1 -1 364.86 26.70
-1 2 -1 361.96 24.50
1 -2 -1 336.17 28.00
-2 -1 1 358.06 27.00
1 -2 1 424.96 23.80
-2 -1 1 331.57 24.50
-2 -1 1 360.76 23.40
1 -2 1 413.26 27.80
2 1 1 371.66 24.90
-1 2 1 444.96 24.00
2 1 1 322.57 27.70
2 -1 -1 359.26 25.60
1 2 -1 390.46 26.00
-1 -2 -1 423.56 25.40
-2 1 -1 354.86 25.70
-1 -2 -1 411.56 27.50
-1 -2 -1 418.36 27.10
1 2 -1 429.76 25.60
1 2 1 367.76 25.20
2 -1 1 425.46 26.60
-1 -2 1 357.06 25.90
2 -1 1 438.06 27.00
1 2 1 328.77 25.60
-1 -2 1 332.47 26.00
-1 -2 1 365.36 24.60
3 2 -1 107.29 13.30
-3 -2 -1 109.49 14.50
2 -3 -1 149.99 11.80
3 2 -1 115.99 11.40
2 -3 -1 143.99 16.90
-2 3 -1 159.38 12.20
3 2 1 139.99 9.60
-3 -2 1 162.78 16.10
2 -3 1 108.79 14.40
3 2 1 156.68 12.50
2 -3 1 107.29 10.20
3 2 1 144.69 15.40
-3 -2 1 154.78 12.90
-2 3 1 113.99 10.50
3 0 -1 326.77 28.60
0 -3 -1 365.46 22.60
0 3 -1 345.87 23.70
0 -3 -1 348.37 28.00
0 3 -1 333.67 24.80
-3 0 -1 354.26 27.50
0 -3 -1 371.16 22.10
3 0 1 341.17 23.30
0 -3 1 346.67 23.20
-3 0 1 371.76 24.80
3 0 1 332.47 28.30
0 3 1 372.56 23.40
0 -3 1 364.66 23.50
-3 0 1 371.46 26.90
0 -3 1 372.36 27.70
0 -3 1 369.26 22.20
0 3 1 327.87 24.40
3 -2 -1 143.59 12.20
2 3 -1 112.49 11.70
3 -2 -1 122.09 11.40
-2 -3 -1 107.29 12.20
3 -2 -1 149.79 16.20
-2 -3 -1 100.49 11.10
2 3 -1 116.49 12.20
-2 -3 -1 102.29 13.40
-2 -3 1 138.89 11.30
3 -2 1 109.59 11.50
2 3 1 161.68 13.60
3 -2 1 105.89 11.70
2 3 1 148.89 13.00
-2 -3 1 146.39 14.40
-4 -3 -1 160.78 17.00
-3 4 -1 114.79 12.30
3 -4 -1 105.09 12.20
3 -4 -1 120.29 19.00
4 3 -1 171.48 18.30
4 3 1 117.29 16.40
4 3 1 119.49 12.70
-4 -3 1 119.19 16.60
4 1 -1 102.79 14.60
-4 -1 -1 100.09 13.90
1 -4 1 101.19 9.00
1 -4 1 109.89 14.60
-1 4 1 109.79 9.30
1 4 -1 105.89 10.50
1 4 -1 103.99 12.20
-1 -4 -1 101.49 9.20
-1 -4 -1 108.99 13.90
-4 1 1 121.89 14.90
4 -1 1 110.79 12.70
4 -1 1 113.59 14.60
4 -3 -1 131.89 19.10
4 -3 -1 109.89 12.80
4 -3 -1 95.49 11.70
-3 -4 1 120.99 16.20
3 4 1 132.19 15.10
-3 -4 1 105.89 12.20
3 4 1 123.59 14.10
-4 5 -1 41.70 9.40
4 -5 -1 72.09 20.50
5 4 1 41.10 9.50
-5 -4 1 45.30 13.30
5 4 1 52.69 14.30
5 2 -1 171.48 20.40
2 -5 -1 135.39 14.00
2 -5 -1 137.19 20.80
5 2 -1 181.28 12.30
-5 -2 -1 160.38 20.20
-2 5 -1 126.39 13.70
5 2 1 158.08 19.80
5 2 1 133.89 11.70
-5 -2 1 130.59 18.90
2 -5 1 157.48 21.90
-2 5 1 162.18 13.70
-5 0 -1 41.00 10.90
0 -5 -1 47.00 12.50
5 0 -1 46.40 11.80
0 -5 -1 40.90 7.50
0 5 -1 39.10 7.20
5 0 1 42.50 11.20
0 5 1 38.10 6.70
-5 0 1 42.00 10.30
-2 -5 -1 157.58 17.50
2 5 -1 158.78 15.50
-5 2 -1 126.39 16.40
-2 -5 -1 152.08 13.60
-2 -5 -1 157.88 18.60
5 -2 -1 139.79 17.00
2 5 -1 166.38 22.70
-2 -5 1 126.79 12.70
5 -2 1 157.58 18.30
2 5 1 125.09 14.50
-2 -5 1 121.79 15.70
-2 -5 1 137.89 17.30
5 -4 -1 36.10 9.80
5 -4 -1 42.20 15.10
-4 -5 1 35.80 12.00
4 5 1 41.90 12.30
4 5 1 44.70 10.60
-4 -5 1 37.60 10.00
-3 6 -1 54.69 10.20
3 -6 -1 71.39 21.20
6 3 1 44.50 12.80
6 3 1 52.79 6.90
-6 -3 1 56.29 15.20
-1 6 -1 34.50 7.60
1 -6 -1 39.70 13.50
-6 -1 1 43.10 12.80
6 1 1 53.29 13.90
-1 -6 -1 102.99 9.20
-1 -6 -1 104.19 17.90
1 6 -1 103.39 12.50
-6 1 1 116.79 17.10
6 -1 1 127.19 21.80
-3 -6 -1 4.50 6.90
3 6 -1 9.00 6.70
-3 -6 -1 1.90 3.90
-6 3 1 7.20 6.50
6 -3 1 15.50 8.70
-7 0 -1 74.79 18.00
0 -7 -1 90.99 22.20
0 7 -1 55.39 10.90
7 0 -1 56.79 15.30
7 0 1 58.19 15.90
0 -7 1 64.19 17.50
-7 0 1 67.99 17.50
0 0 -2 1463.75 88.19
0 0 -2 1499.35 87.59
0 0 -2 1483.05 87.79
0 0 2 1642.14 87.29
0 0 2 1335.77 89.49
1 1 -2 6604.84 423.36
-1 1 -2 7190.88 429.06
1 1 -2 7440.06 428.76
1 -1 -2 6352.96 424.26
1 -1 -2 7816.42 434.26
-1 -1 -2 6472.55 432.66
1 -1 2 6865.41 425.96
-1 -1 2 7626.04 433.76
-1 -1 2 8155.38 427.96
1 1 2 7256.97 429.86
1 -1 2 7627.34 435.16
1 1 2 7261.47 423.06
0 -2 -2 2127.89 119.19
0 -2 -2 2096.89 121.49
2 0 -2 2090.19 121.79
-2 0 -2 1999.30 123.09
2 0 -2 1883.61 123.19
0 2 -2 1952.40 120.39
0 -2 -2 1852.71 123.79
0 2 -2 2071.89 120.29
0 -2 -2 2014.70 119.19
0 2 2 2040.10 118.99
2 0 2 1944.81 118.59
0 2 2 2124.89 120.09
0 -2 2 2056.79 120.59
0 -2 2 2085.49 119.09
2 0 2 2158.28 118.69
0 -2 2 1957.10 119.59
2 0 2 1884.61 122.99
0 -2 2 2022.10 122.69
2 0 2 2093.89 120.09
-2 0 2 2016.30 122.89
2 2 -2 1123.59 70.99
2 -2 -2 1053.79 75.29
-2 2 -2 1146.89 69.59
2 2 -2 1206.58 70.89
-2 -2 -2 1069.69 72.19
2 -2 -2 1143.79 70.39
-2 -2 -2 1126.59 74.09
2 -2 2 1192.78 70.49
-2 -2 2 1132.69 69.89
-2 -2 2 1148.09 72.89
2 -2 2 1211.08 73.39
2 2 2 1106.99 70.99
2 2 2 1117.19 72.89
2 2 2 1140.89 71.09
-2 -2 2 1176.38 69.69
1 -3 -2 5979.70 384.56
-3 -1 -2 6851.41 383.96
1 -3 -2 6083.59 384.26
-1 3 -2 6247.78 377.96
3 1 -2 7270.27 383.76
3 1 -2 6434.36 377.16
3 1 -2 6454.65 380.26
-3 -1 -2 7340.97 382.56
-1 3 2 6601.54 380.26
3 1 2 6910.91 384.96
1 -3 2 6558.54 380.26
3 1 2 5617.44 378.46
3 1 2 6509.75 377.46
-3 -1 2 6001.20 377.86
-3 -1 2 6041.50 381.56
-3 -1 2 6207.18 379.96
1 -3 2 6618.54 382.96
-1 -3 -2 6485.35 367.06
3 -1 -2 6231.98 364.16
1 3 -2 6001.10 363.66
1 3 -2 6744.33 363.06
-1 -3 -2 6532.85 367.36
-3 1 -2 6289.17 365.46
-1 -3 -2 5703.63 364.76
3 -1 2 6163.88 365.76
-1 -3 2 5454.35 360.96
-3 1 2 6753.82 370.06
1 3 2 6165.38 362.46
-1 -3 2 5516.55 362.86
3 -1 2 6801.42 364.26
-1 -3 2 5629.64 364.56
1 3 2 6212.18 363.76
3 -3 -2 5239.28 294.97
3 -3 -2 5276.87 304.47
-3 -3 -2 4415.06 296.57
3 -3 -2 5234.18 292.67
-3 -3 -2 4593.94 299.77
3 3 -2 4952.50 296.37
3 3 -2 4601.54 294.67
3 -3 2 4976.20 300.17
-3 -3 2 4832.42 293.87
3 3 2 5093.89 295.47
3 3 2 5177.98 298.87
-3 -3 2 5206.78 299.57
4 2 -2 1154.98 72.09
4 2 -2 1102.09 78.09
-2 4 -2 1169.78 73.19
-4 -2 -2 1247.68 80.99
2 -4 -2 1147.89 82.69
-2 4 2 1171.08 71.19
-4 -2 2 1096.69 78.49
4 2 2 1196.28 72.49
4 2 2 1211.98 79.59
2 -4 2 1139.99 80.29
-4 0 -2 904.71 62.29
0 -4 -2 918.91 58.89
0 -4 -2 904.91 63.99
0 4 -2 910.31 57.19
4 0 -2 869.81 63.09
0 -4 -2 913.31 53.99
0 -4 -2 934.51 53.79
0 -4 2 887.41 55.29
0 -4 2 869.11 55.19
0 -4 2 927.31 62.49
4 0 2 873.91 63.09
0 4 2 862.61 55.69
-4 0 2 950.50 61.59
0 -4 2 875.21 53.99
-4 2 -2 1143.19 74.49
-2 -4 -2 1205.68 76.19
-2 -4 -2 1158.58 72.59
4 -2 -2 1082.29 73.39
2 4 -2 1167.58 72.99
-2 -4 -2 1119.79 76.19
2 4 -2 1090.29 73.79
2 4 2 1142.99 73.39
-2 -4 2 1097.69 70.99
-2 -4 2 1105.49 74.79
2 4 2 1049.70 73.59
4 -2 2 1210.88 75.89
-2 -4 2 1107.69 73.99
4 -2 2 1198.38 76.49
-4 2 2 1229.28 81.49
4 4 -2 527.65 40.00
4 -4 -2 540.65 49.70
4 4 -2 494.95 42.20
-4 4 -2 585.44 40.70
-4 -4 -2 528.85 43.00
4 -4 -2 537.95 39.80
-4 -4 -2 589.24 47.40
4 4 2 550.74 44.30
4 4 2 519.15 39.70
-4 -4 2 514.55 40.00
4 -4 2 593.84 48.50
-4 -4 2 570.14 45.80
-3 5 -2 2787.32 175.28
5 3 -2 2946.81 183.18
5 3 -2 3076.79 174.08
3 -5 -2 2738.83 175.88
-5 -3 -2 3215.28 186.58
3 -5 -2 2789.32 189.08
5 3 2 2742.53 173.68
5 3 2 2863.91 181.98
3 -5 2 2867.71 187.08
-5 -3 2 2843.12 183.88
1 -5 -2 4039.00 233.48
5 1 -2 3761.12 239.28
-1 5 -2 4045.10 232.18
-5 -1 -2 3643.24 239.08
1 -5 -2 4006.80 243.68
1 -5 2 3418.46 239.18
-5 -1 2 3936.31 239.48
5 1 2 4239.78 239.88
-5 1 -2 4002.90 220.88
-1 -5 -2 3257.57 216.38
1 5 -2 3305.27 213.68
5 -1 -2 3836.02 221.18
-1 -5 -2 3406.76 211.18
-1 -5 -2 3493.35 221.28
5 -1 2 3452.25 221.18
-1 -5 2 3470.75 210.88
-1 -5 2 3773.02 220.28
-5 1 2 3648.03 219.38
1 5 2 3693.33 213.88
5 -3 -2 2539.85 172.18
-3 -5 -2 2934.41 179.58
3 5 -2 2924.31 175.58
-3 -5 -2 2973.80 174.58
5 -3 -2 2713.33 174.88
3 5 -2 2934.91 175.08
3 5 2 2709.13 174.58
-3 -5 2 2617.14 171.68
5 -3 2 3329.47 181.98
-3 -5 2 2606.54 176.98
3 5 2 2677.73 175.48
5 -3 2 3055.99 176.98
-5 -5 -2 1725.23 131.69
-5 -5 -2 1565.14 115.39
5 5 -2 1542.15 112.29
5 5 -2 1615.94 106.89
-5 5 -2 1617.64 106.89
-5 5 2 1652.83 123.49
-5 -5 2 1808.82 116.69
5 5 2 1704.13 113.79
5 -5 2 1576.24 118.29
5 5 2 1741.73 106.79
2 -6 -2 448.76 45.20
-6 -2 -2 434.96 41.00
-2 6 -2 432.66 33.70
6 2 -2 424.26 39.80
-6 -2 2 437.06 41.20
6 2 2 457.45 39.20
2 -6 2 463.55 44.30
-6 0 -2 751.82 56.59
0 -6 -2 695.63 57.99
6 0 -2 685.63 54.59
0 -6 -2 761.52 53.19
0 6 -2 655.53 48.00
6 0 2 715.23 55.79
0 -6 2 697.53 57.09
-6 0 2 675.53 54.69
-6 2 -2 426.56 38.20
-2 -6 -2 425.96 37.60
6 -2 -2 448.86 37.70
-2 -6 -2 417.16 31.40
2 6 -2 418.16 33.90
-2 -6 2 404.76 30.50
6 -2 2 465.45 40.60
-6 2 2 465.55 39.10
-2 -6 2 442.96 38.50
7 1 -2 1812.12 113.29
1 -7 -2 1445.96 117.59
-7 -1 -2 1780.32 115.79
-1 7 -2 1517.75 104.69
-7 -1 2 1578.24 114.59
1 -7 2 1734.93 119.89
7 1 2 1678.43 111.89
1 7 -2 1612.34 105.29
7 -1 -2 1633.04 112.79
-7 1 -2 1555.04 112.99
-1 -7 -2 1722.13 116.59
7 -1 2 1826.02 115.19
-7 1 2 1751.02 115.19
-1 -7 2 1434.96 112.49
1 0 -3 452.15 28.80
1 0 -3 446.16 28.50
-1 0 -3 423.16 29.20
-1 0 -3 455.25 29.10
0 -1 -3 411.06 29.70
0 -1 -3 453.45 29.20
0 1 -3 427.16 27.80
1 0 -3 472.85 27.90
0 1 -3 485.65 28.60
-1 0 3 392.66 31.40
1 0 3 437.76 30.10
0 1 3 410.36 32.30
1 0 3 451.15 28.10
0 -1 3 455.15 30.40
0 1 3 485.05 27.90
1 0 3 447.36 28.30
-1 0 3 469.65 27.40
2 1 -3 254.67 16.50
1 -2 -3 215.68 16.90
-1 2 -3 205.88 15.90
-2 -1 -3 246.98 20.00
2 1 -3 255.27 17.60
-2 -1 3 210.78 15.50
1 -2 3 242.18 19.20
-2 -1 3 197.98 16.60
2 1 3 189.58 18.60
-1 2 3 259.57 14.00
2 1 3 192.68 16.10
-1 2 3 256.67 23.20
2 1 3 210.68 17.00
-2 1 -3 209.28 17.10
2 -1 -3 197.88 16.60
-1 -2 -3 247.08 18.80
1 2 -3 260.87 17.20
-1 -2 -3 222.98 17.60
2 -1 -3 225.58 17.10
1 2 -3 257.07 16.60
-1 -2 3 220.68 16.70
1 2 3 216.38 19.30
-1 -2 3 211.58 17.40
-1 -2 3 227.98 15.40
1 2 3 183.18 16.70
1 2 3 202.48 16.40
-2 1 3 211.68 21.50
2 -1 3 237.28 17.30
-3 -2 -3 261.47 24.90
-3 -2 -3 253.27 23.60
3 2 -3 273.97 20.70
3 2 -3 230.58 21.60
2 -3 -3 291.47 21.50
-2 3 -3 298.37 21.20
-3 -2 3 277.77 23.90
2 -3 3 259.17 24.10
-2 3 3 272.77 18.20
-3 -2 3 270.77 20.30
-3 -2 3 273.67 19.70
3 2 3 263.47 20.80
3 2 3 302.57 25.20
3 2 3 292.87 20.10
3 0 -3 117.49 12.00
0 3 -3 113.99 10.70
0 -3 -3 116.49 8.60
0 -3 -3 118.49 8.70
0 -3 -3 114.69 11.70
0 3 -3 120.79 10.30
-3 0 -3 119.59 13.20
3 0 -3 105.39 13.50
3 0 3 102.99 13.30
3 0 3 113.29 10.00
0 -3 3 117.29 8.60
0 -3 3 98.39 9.50
0 -3 3 117.79 7.90
0 3 3 114.79 9.00
-3 0 3 115.59 12.60
0 3 3 121.39 10.70
-2 -3 -3 253.47 23.50
3 -2 -3 248.98 19.10
-3 2 -3 261.57 21.00
3 -2 -3 289.77 21.50
2 3 -3 279.87 20.90
-2 -3 -3 236.88 21.50
2 3 -3 265.87 21.20
2 3 3 275.07 21.30
3 -2 3 255.67 22.60
-2 -3 3 267.37 21.00
-2 -3 3 283.47 19.70
2 3 3 238.78 21.60
-2 -3 3 282.87 22.70
2 3 3 271.17 22.80
3 -2 3 246.58 21.10
-3 2 3 254.67 27.40
-4 -3 -3 63.09 13.80
-4 -3 -3 64.89 13.30
-3 4 -3 26.90 6.90
3 -4 -3 27.90 6.90
4 3 3 29.80 9.90
4 3 3 30.60 7.40
-4 -3 3 29.10 9.70
1 -4 -3 190.98 16.60
4 1 -3 137.29 18.20
-1 4 -3 196.98 15.80
1 -4 -3 168.48 21.30
-4 -1 -3 134.89 18.10
1 -4 3 129.99 17.50
4 1 3 186.68 19.80
4 1 3 211.88 14.30
-4 -1 3 214.08 19.80
4 1 3 200.18 13.20
-4 1 -3 178.18 17.70
-1 -4 -3 144.69 13.00
-1 -4 -3 147.89 16.40
1 4 -3 132.09 13.70
4 -1 -3 188.78 17.10
1 4 -3 132.49 14.90
-4 1 3 138.69 18.00
4 -1 3 140.29 14.90
-1 -4 3 190.28 14.50
-1 -4 3 183.78 17.50
1 4 3 187.88 14.60
-1 -4 3 176.08 12.80
4 -1 3 131.49 16.80
-3 -4 -3 71.59 15.20
3 4 -3 66.79 10.30
3 4 -3 73.09 11.00
-3 -4 -3 79.59 14.10
-4 3 3 75.99 18.60
4 -3 3 71.29 10.80
4 -3 3 60.69 13.40
-5 -4 -3 78.69 18.00
-4 5 -3 87.19 12.80
5 4 -3 76.89 11.50
4 -5 -3 93.09 13.60
5 4 -3 65.99 15.30
5 4 3 87.69 11.80
-5 -4 3 85.19 18.10
5 4 3 111.79 19.90
-4 5 3 65.69 20.80
4 -5 3 68.89 18.50
2 -5 -3 11.40 9.20
-2 5 -3 10.40 4.90
-5 -2 -3 35.20 11.10
2 -5 -3 10.20 4.80
5 2 -3 30.10 10.40
5 2 3 13.70 7.10
5 2 3 11.70 3.50
2 -5 3 28.30 10.90
-5 -2 3 8.00 6.10
0 -5 -3 185.68 18.70
5 0 -3 198.58 22.50
-5 0 -3 190.98 21.70
0 -5 -3 195.28 23.70
0 5 -3 200.88 17.40
-5 0 3 182.68 20.50
0 -5 3 197.68 13.00
0 -5 3 189.18 22.00
5 0 3 189.48 22.20
-2 -5 -3 31.20 9.40
2 5 -3 21.90 6.40
2 5 -3 26.40 9.10
5 -2 -3 12.40 5.80
5 -2 -3 15.10 7.10
-5 2 -3 8.90 5.80
-2 -5 -3 24.30 6.20
-2 -5 3 13.80 4.40
2 5 3 8.90 5.50
5 -2 3 45.60 12.20
-2 -5 3 13.20 6.70
2 5 3 12.90 7.20
4 5 -3 67.69 13.30
-4 -5 -3 77.19 17.90
5 -4 -3 87.59 13.30
4 5 -3 86.49 16.50
-4 -5 -3 70.59 15.00
-5 4 -3 69.29 13.00
-4 -5 3 91.99 15.10
5 -4 3 80.99 19.20
-5 4 3 70.29 20.40
4 5 3 91.59 18.00
4 5 3 94.69 13.70
-3 6 -3 68.79 12.10
6 3 -3 32.20 5.70
6 3 -3 35.90 12.90
-6 -3 -3 38.70 13.70
3 -6 3 28.40 13.70
-6 -3 3 54.49 16.00
6 3 3 74.89 15.60
-1 6 -3 17.90 6.20
1 -6 -3 23.70 12.30
1 -6 -3 28.10 8.20
-6 -1 3 18.10 8.80
6 1 3 21.10 9.20
1 -6 3 56.49 15.10
-1 -6 -3 56.59 6.60
1 6 -3 61.79 11.20
-1 -6 -3 63.79 13.50
-6 1 3 59.49 14.50
6 -1 3 89.69 19.00
6 -3 -3 67.09 14.40
-3 -6 -3 36.50 12.80
3 6 -3 32.90 10.00
-3 -6 -3 43.80 10.50
6 -3 3 43.60 13.90
-3 -6 3 53.39 10.20
0 7 -3 9.10 5.90
-7 0 -3 14.50 9.70
7 0 -3 10.80 9.60
-7 0 3 14.10 10.00
0 -7 3 24.90 12.20
7 0 3 7.70 8.90
0 0 -4 4214.18 251.07
0 0 -4 4110.79 247.28
0 0 -4 4240.98 246.88
0 0 4 4614.24 250.47
0 0 4 3762.22 249.38
-1 1 -4 1622.94 97.99
1 -1 -4 1675.73 96.19
1 -1 -4 1386.36 96.59
-1 -1 -4 1735.53 101.99
1 1 -4 1783.32 98.99
1 1 -4 1886.51 98.29
1 -1 -4 1631.34 98.99
-1 1 -4 1655.73 98.19
-1 -1 -4 1675.93 100.39
1 -1 -4 1440.26 97.59
1 1 -4 1845.52 98.49
-1 1 -4 1524.15 97.09
-1 1 4 1364.26 103.69
-1 1 4 1776.62 96.79
1 1 4 1720.53 98.59
-1 -1 4 1538.45 100.69
1 -1 4 1732.53 97.69
1 1 4 1499.35 98.09
1 1 4 1494.55 101.79
1 -1 4 1612.44 100.79
-1 -1 4 1612.74 97.19
1 -1 4 1792.72 97.19
2 0 -4 9470.05 510.25
-2 0 -4 9301.07 510.15
0 -2 -4 8170.48 515.35
2 0 -4 9999.00 513.05
0 -2 -4 8520.95 516.95
0 2 -4 8755.02 508.95
0 2 -4 8542.85 516.55
-2 0 -4 8658.43 520.95
2 0 -4 7403.26 515.05
2 0 4 9725.93 519.75
-2 0 4 7531.45 513.05
2 0 4 7815.52 508.35
0 2 4 8688.53 516.05
2 0 4 8841.52 510.45
0 2 4 9372.96 516.75
2 0 4 8365.16 516.95
0 -2 4 8845.81 512.05
2 -2 -4 3652.93 212.18
-2 -2 -4 3666.43 219.88
-2 2 -4 3308.47 213.88
2 2 -4 3592.54 215.58
2 -2 -4 3743.63 216.28
-2 -2 -4 3727.63 219.58
2 2 -4 3980.00 216.08
2 2 4 3585.34 215.48
-2 2 4 3236.98 224.08
2 2 4 3853.01 218.68
2 2 4 3562.84 217.28
2 -2 4 3576.74 218.48
-2 -2 4 3466.65 215.98
-2 -2 4 3714.43 214.18
-2 -2 4 3718.43 216.98
1 -3 -4 1332.87 79.29
3 1 -4 1230.78 79.99
-1 3 -4 1354.66 77.89
3 1 -4 1188.18 80.19
-3 -1 -4 1200.28 82.49
3 1 -4 1227.68 76.99
-3 -1 -4 1177.78 80.69
1 -3 4 1170.48 81.59
3 1 4 1297.87 77.19
3 1 4 1308.87 77.39
-3 -1 4 1347.07 76.79
-3 -1 4 1282.97 78.49
-1 3 4 1145.49 86.29
3 1 4 1257.47 82.09
1 3 -4 1169.68 77.19
-3 1 -4 1289.57 79.49
3 -1 -4 1357.56 78.69
-1 -3 -4 1146.79 76.99
3 -1 -4 1279.57 79.29
-1 -3 -4 1249.57 80.29
1 3 -4 1251.27 76.79
3 -1 4 1182.68 78.99
1 3 4 1272.77 82.79
1 3 4 1051.69 76.39
-1 -3 4 1321.17 80.09
3 -1 4 1155.28 77.89
-1 -3 4 1263.97 76.39
-3 1 4 1178.08 83.99
-1 -3 4 1320.67 75.29
1 3 4 1279.77 77.39
3 -3 -4 875.81 59.99
3 3 -4 975.20 61.29
3 3 -4 978.90 60.19
-3 3 -4 887.51 59.99
-3 -3 -4 960.20 63.59
-3 -3 -4 956.90 65.69
-3 -3 4 842.72 58.49
3 -3 4 965.80 64.19
3 3 4 796.12 60.69
3 3 4 855.61 59.39
3 3 4 910.61 62.69
-3 -3 4 886.01 58.29
-3 3 4 935.61 71.29
4 2 -4 6027.80 357.86
4 2 -4 6123.89 363.46
2 -4 -4 5991.60 360.16
-2 4 -4 6095.19 358.96
-4 -2 -4 6258.97 367.06
-4 -2 4 5826.92 363.86
4 2 4 6785.02 365.06
4 2 4 6148.39 357.96
2 -4 4 5666.73 364.66
-2 4 4 5768.42 371.86
0 -4 -4 2551.94 151.18
0 4 -4 2552.84 154.98
0 -4 -4 2615.94 157.78
4 0 -4 2375.46 160.28
4 0 -4 2729.03 159.28
-4 0 -4 2599.14 160.48
-4 0 4 2621.64 157.28
0 4 4 2634.04 165.08
0 -4 4 2644.64 161.08
0 -4 4 2491.35 151.78
4 0 4 2448.85 160.88
2 4 -4 5533.65 340.57
-4 2 -4 5844.22 341.67
4 -2 -4 5154.78 338.17
2 4 -4 5952.30 339.77
-2 -4 -4 5667.63 344.47
4 -2 -4 5692.03 340.77
-2 -4 -4 5751.82 340.47
4 -2 4 5809.02 342.97
2 4 4 6037.10 344.87
4 -2 4 5840.12 341.97
-2 -4 4 5553.54 343.47
-2 -4 4 5740.53 341.77
-4 2 4 6140.89 351.36
2 4 4 6007.60 340.47
-2 -4 4 5565.44 337.17
2 4 4 5301.27 340.47
-4 -4 -4 1448.26 90.99
4 4 -4 1313.37 88.09
-4 4 -4 1309.57 86.19
4 4 -4 1284.67 85.29
4 -4 -4 1202.18 85.39
-4 -4 -4 1365.86 93.39
-4 -4 4 1214.38 89.19
4 4 4 1364.16 89.49
-4 4 4 1318.87 99.79
-4 -4 4 1238.18 84.49
4 4 4 1330.47 85.19
4 -4 4 1359.86 92.89
3 -5 -4 651.83 46.50
5 3 -4 603.74 43.20
5 3 -4 601.54 50.39
-3 5 -4 635.34 45.60
-5 -3 -4 643.34 53.69
3 -5 4 604.14 53.39
-5 -3 4 639.84 51.99
5 3 4 729.33 50.89
-3 5 4 553.94 56.89
5 3 4 657.93 43.60
1 -5 -4 713.33 52.39
-5 -1 -4 806.52 58.69
-1 5 -4 695.63 50.49
5 1 -4 803.02 57.99
5 1 4 753.32 56.39
1 -5 4 775.62 58.49
-5 -1 4 725.83 55.99
-1 5 4 787.42 63.29
-5 1 -4 698.63 52.99
1 5 -4 773.92 49.40
-1 -5 -4 736.53 46.10
5 -1 -4 683.73 51.89
-1 -5 -4 756.52 52.89
-1 -5 4 648.44 52.29
-1 -5 4 660.03 45.40
5 -1 4 759.62 55.59
1 5 4 734.83 57.39
3 5 -4 548.75 44.60
-3 -5 -4 585.94 45.50
3 5 -4 602.14 44.90
-3 -5 -4 589.34 49.20
5 -3 -4 589.44 44.80
5 -3 4 621.04 47.20
-3 -5 4 609.14 42.00
3 5 4 628.94 44.90
-5 3 4 582.94 53.69
6 2 -4 957.00 72.99
-2 6 -4 937.01 65.99
-6 -2 -4 979.80 74.59
2 -6 -4 981.00 67.39
2 -6 4 989.00 76.69
-6 -2 4 978.10 73.89
-2 6 4 972.30 81.69
6 2 4 1001.60 70.69
-6 0 -4 3594.24 219.18
0 6 -4 3389.56 211.28
6 0 -4 3303.77 217.08
0 -6 -4 3355.56 213.88
0 -6 4 3331.47 219.78
0 6 4 3646.04 225.98
-6 0 4 3465.15 218.58
6 0 4 3840.62 220.88
2 6 -4 901.41 64.29
-2 -6 -4 977.50 62.09
-2 -6 -4 998.80 70.39
6 -2 -4 895.11 67.49
6 -2 4 989.70 72.59
2 6 4 953.00 71.59
-2 -6 4 915.51 60.49
-2 -6 4 925.81 68.69
0 1 -5 277.07 18.70
0 -1 -5 282.47 20.80
1 0 -5 303.97 20.40
0 -1 -5 278.77 22.50
0 1 -5 291.67 19.30
-1 0 -5 289.17 21.40
-1 0 -5 270.47 20.40
0 -1 -5 279.97 17.40
0 1 -5 303.77 20.90
1 0 -5 282.27 21.10
0 1 5 255.67 25.20
0 -1 5 291.87 18.90
-1 0 5 289.87 18.80
1 0 5 280.87 19.20
-1 0 5 270.87 25.10
0 -1 5 289.07 23.40
1 0 5 290.17 23.50
0 1 5 281.27 19.20
1 0 5 269.77 19.10
2 1 -5 179.08 15.60
1 -2 -5 215.78 13.00
2 1 -5 184.38 16.00
2 1 -5 166.48 15.10
1 -2 -5 242.68 17.40
1 -2 -5 227.28 12.60
-2 -1 -5 164.58 17.50
-1 2 -5 217.38 15.50
-1 2 -5 231.38 15.50
-2 -1 -5 159.28 17.40
2 1 5 210.28 17.30
-2 -1 5 220.58 18.60
-1 2 5 164.98 13.70
2 1 5 215.18 15.60
-2 -1 5 238.18 15.00
1 -2 5 159.28 17.40
-1 2 5 160.68 20.70
1 -2 5 155.78 13.70
1 -2 5 171.38 13.40
2 1 5 216.18 18.20
1 2 -5 156.38 14.30
-1 -2 -5 167.68 16.80
2 -1 -5 204.58 16.00
2 -1 -5 223.28 16.30
-2 1 -5 211.78 16.10
1 2 -5 160.48 14.80
-1 -2 -5 160.38 17.00
2 -1 5 159.08 16.40
-1 -2 5 229.18 14.30
2 -1 5 169.38 15.00
2 -1 5 165.78 12.80
-2 1 5 150.08 20.10
-1 -2 5 223.58 18.20
1 2 5 223.08 15.80
1 2 5 204.78 19.10
2 -1 5 177.98 12.90
3 2 -5 173.78 15.50
-2 3 -5 125.39 12.90
2 -3 -5 138.89 14.10
-3 -2 -5 184.88 19.30
-3 -2 5 123.79 13.30
-3 -2 5 130.49 12.30
-3 -2 5 126.09 14.80
3 2 5 117.99 12.70
3 2 5 137.79 13.90
3 2 5 130.29 15.30
2 -3 5 179.08 18.30
-2 3 5 168.18 22.60
-3 0 -5 131.99 15.20
0 -3 -5 117.49 10.50
3 0 -5 120.39 14.40
0 3 -5 137.09 12.00
3 0 -5 125.59 13.10
0 -3 -5 142.69 14.10
0 3 -5 120.09 12.00
3 0 5 133.49 10.40
0 3 5 123.29 17.10
0 -3 5 129.19 10.20
0 -3 5 129.49 15.10
3 0 5 131.99 10.10
-3 0 5 136.79 16.10
3 0 5 129.99 12.70
3 0 5 123.39 13.90
-2 -3 -5 191.68 18.10
-2 -3 -5 186.08 18.50
3 -2 -5 133.99 14.60
2 3 -5 166.18 14.50
2 3 -5 191.18 15.90
-3 2 -5 118.39 18.30
2 3 5 142.59 15.40
-2 -3 5 132.49 12.50
-3 2 5 176.88 23.10
3 -2 5 176.68 17.50
2 3 5 127.89 15.40
-2 -3 5 123.89 14.70
2 3 5 126.99 13.60
-2 -3 5 128.49 14.60
3 -2 5 177.98 15.70
4 3 -5 34.20 7.90
-4 -3 -5 30.80 11.30
4 3 -5 32.50 9.30
3 -4 5 26.80 9.90
-3 4 5 28.40 13.40
1 -4 -5 78.09 11.00
-1 4 -5 88.19 10.30
4 1 5 86.39 8.30
4 1 5 83.09 14.90
-1 -4 -5 159.88 14.80
-1 -4 -5 166.58 18.40
1 4 -5 177.88 15.80
1 4 -5 160.68 16.40
4 -1 5 168.08 16.70
-4 1 5 183.28 22.30
4 -1 5 174.48 19.30
-3 -4 -5 24.00 9.30
3 4 -5 21.70 7.10
3 4 -5 29.30 8.10
-3 -4 -5 21.90 8.30
4 -3 5 31.30 10.10
-4 3 5 34.00 13.50
-5 -4 -5 70.49 17.50
5 4 -5 61.39 11.20
-4 5 -5 25.90 8.60
5 4 -5 52.39 13.10
4 -5 -5 30.80 9.70
5 4 5 28.70 8.20
-5 -4 5 23.80 11.00
4 -5 5 62.59 16.80
5 4 5 36.20 11.40
-4 5 5 55.79 19.30
-2 5 -5 50.59 10.10
5 2 -5 28.40 10.80
-5 -2 -5 21.10 9.80
2 -5 -5 47.10 10.40
-5 -2 5 39.70 11.60
-2 5 5 21.80 12.30
2 -5 5 34.00 11.50
5 2 5 57.29 13.20
5 2 5 45.20 6.40
0 -5 -5 90.49 13.40
5 0 -5 76.39 15.70
0 5 -5 94.29 11.60
5 0 -5 77.79 13.20
-5 0 -5 79.29 14.60
0 -5 5 91.49 15.30
0 5 5 77.19 18.20
0 -5 5 94.59 7.90
5 0 5 108.79 16.50
2 5 -5 19.10 6.40
5 -2 -5 40.70 9.60
-2 -5 -5 25.80 7.40
-2 -5 -5 22.40 9.50
5 -2 5 27.30 10.30
-2 -5 5 48.70 11.50
-2 -5 5 37.40 6.70
-4 -5 -5 92.49 18.40
4 5 -5 59.89 13.40
-4 -5 -5 80.69 18.60
4 5 -5 70.29 14.30
5 -4 5 69.49 16.70
-5 4 5 60.09 19.40
-6 -3 -5 85.99 19.90
6 3 -5 83.89 18.80
3 -6 5 66.89 18.90
-3 6 5 70.09 22.60
-1 6 -5 75.09 13.20
1 -6 -5 89.79 14.30
6 1 5 85.39 17.00
-6 -1 5 87.59 18.90
-6 1 -5 93.49 16.80
1 6 5 85.59 19.10
6 -1 5 23.90 11.50
-1 -6 5 84.09 17.50
3 6 -5 71.49 14.50
-3 -6 -5 72.09 18.40
6 -3 5 87.79 19.60
0 0 -6 2297.17 131.69
0 0 -6 2230.48 135.39
0 0 -6 2187.08 133.29
0 0 6 2117.29 139.79
0 0 6 2299.07 132.59
1 -1 -6 5709.53 346.47
1 1 -6 6237.18 348.57
1 -1 -6 6243.78 345.97
-1 -1 -6 6390.36 349.87
1 -1 -6 5627.34 347.97
1 -1 -6 5306.67 348.37
-1 1 -6 5709.53 345.77
-1 1 -6 5647.24 346.37
-1 -1 -6 6291.37 351.76
1 1 -6 6819.72 354.06
-1 1 -6 6016.20 347.87
1 1 6 5463.75 348.27
1 1 6 5330.37 352.36
-1 1 6 6394.56 345.77
-1 -1 6 5565.44 345.67
1 -1 6 6554.24 346.27
1 1 6 6245.58 346.97
-1 -1 6 5109.49 351.26
-1 1 6 5026.50 355.36
1 -1 6 6377.56 352.96
0 -2 -6 632.24 42.60
2 0 -6 626.34 41.50
2 0 -6 691.83 42.50
2 0 -6 583.54 38.00
-2 0 -6 573.84 42.20
0 -2 -6 620.14 42.50
0 2 -6 638.94 41.00
-2 0 -6 633.14 42.50
0 2 -6 629.24 40.20
-2 0 6 597.04 47.30
0 -2 6 619.34 39.00
0 -2 6 594.24 44.40
2 0 6 619.74 44.00
2 0 6 597.24 39.80
0 2 6 617.34 39.90
2 0 6 603.64 40.90
-2 0 6 615.24 38.80
0 2 6 615.84 47.60
-2 -2 -6 1672.03 110.09
-2 2 -6 1801.72 106.49
2 -2 -6 1687.73 107.09
2 2 -6 1792.72 105.99
2 2 -6 1688.73 106.29
-2 -2 -6 1894.11 110.99
-2 -2 6 1743.53 104.39
2 2 6 1665.63 105.49
2 -2 6 1693.43 109.79
-2 2 6 1681.83 117.29
2 2 6 1646.74 106.39
-2 -2 6 1635.14 108.19
2 2 6 1817.72 110.29
3 1 -6 4703.13 281.27
-1 3 -6 4814.72 279.77
1 -3 -6 4872.51 282.27
-3 -1 -6 4702.63 285.47
3 1 -6 4527.15 279.57
3 1 -6 4729.13 282.37
-3 -1 -6 4514.85 283.07
-3 -1 6 4526.15 282.57
1 -3 6 4647.53 276.27
3 1 6 5331.27 279.57
3 1 6 4620.54 283.07
3 1 6 4808.72 281.47
1 -3 6 4674.63 285.67
-1 3 6 4540.35 290.97
-1 -3 -6 4752.32 285.57
3 -1 -6 4964.70 285.37
1 3 -6 4639.14 283.07
1 3 -6 4522.25 283.77
-1 -3 -6 4559.34 286.87
-3 1 -6 5057.99 286.47
3 -1 -6 4498.95 284.47
-1 -3 6 4944.91 287.77
3 -1 6 4652.43 285.27
1 3 6 4965.20 283.87
-1 -3 6 4814.92 281.37
1 3 6 5239.58 291.17
-3 1 6 4463.05 293.67
-3 -3 -6 3813.22 228.58
-3 3 -6 3465.75 222.18
3 3 -6 3639.84 221.78
3 3 -6 4054.09 223.68
-3 -3 -6 4263.27 227.18
3 -3 -6 3463.65 222.38
3 3 6 3568.54 221.08
-3 -3 6 3560.44 224.48
3 -3 6 3946.51 227.68
-3 -3 6 3414.86 221.88
-3 3 6 4017.90 238.28
3 3 6 3276.37 224.88
-3 -3 6 3391.86 219.48
3 3 6 3798.42 223.38
-2 4 -6 364.46 29.10
4 2 -6 403.26 28.90
2 -4 -6 379.66 30.80
-4 -2 -6 385.46 35.70
4 2 -6 348.17 31.50
-4 -2 6 387.06 33.00
-2 4 6 374.46 40.50
4 2 6 383.96 32.50
4 2 6 380.06 28.10
2 -4 6 402.66 35.90
4 0 -6 1231.48 88.49
0 -4 -6 1349.77 80.59
0 -4 -6 1372.46 87.89
4 0 -6 1408.76 87.79
-4 0 -6 1401.36 90.39
0 4 -6 1306.67 84.09
-4 0 6 1313.47 88.39
0 -4 6 1330.17 90.19
4 0 6 1297.57 88.69
0 -4 6 1299.07 80.79
0 4 6 1333.37 94.39
2 4 -6 364.06 30.00
2 4 -6 363.86 28.90
-2 -4 -6 385.06 31.40
-2 -4 -6 368.06 33.80
4 -2 -6 352.96 29.80
-2 -4 6 396.86 32.10
4 -2 6 370.66 31.60
4 -2 6 363.56 31.30
-2 -4 6 356.26 26.60
2 4 6 386.16 29.40
-4 2 6 384.36 38.30
-4 4 -6 814.02 58.99
-4 -4 -6 853.71 65.49
-4 -4 -6 907.81 62.89
4 4 -6 817.22 60.19
4 4 -6 795.62 57.49
4 -4 -6 802.12 59.19
-4 4 6 851.91 72.99
-4 -4 6 778.62 56.19
4 -4 6 817.02 63.69
4 4 6 861.71 57.39
-5 -3 -6 2085.49 138.39
5 3 -6 1884.21 125.99
-3 5 -6 2120.59 129.59
3 -5 -6 2032.10 130.29
5 3 -6 1783.92 132.69
5 3 6 2333.67 126.89
-3 5 6 1835.82 144.09
3 -5 6 1800.72 135.99
5 3 6 2289.57 132.89
-5 -3 6 2224.18 136.89
-1 5 -6 2600.84 172.98
5 1 -6 2853.61 180.18
1 -5 -6 2697.93 176.28
-5 -1 -6 3154.68 183.18
-5 -1 6 2583.14 178.18
1 -5 6 2992.50 183.28
-1 5 6 2946.41 188.88
5 1 6 2957.10 179.88
1 5 -6 2786.72 169.58
-5 1 -6 2681.93 173.98
5 -1 -6 2598.74 172.48
-1 -5 -6 2911.01 175.48
-1 -5 -6 2878.31 166.68
-1 -5 6 2632.34 175.18
5 -1 6 3008.40 177.78
1 5 6 2670.63 178.38
-3 -5 -6 2025.20 132.09
3 5 -6 1808.02 124.79
5 -3 -6 1964.40 125.39
3 5 -6 1845.02 124.19
-3 -5 -6 2067.29 126.79
-5 3 6 1862.51 135.09
-3 -5 6 1933.91 120.79
3 5 6 2076.69 124.29
2 -6 -6 695.83 51.89
6 2 -6 601.84 54.89
-6 -2 -6 708.43 58.29
-2 6 -6 655.83 49.50
-2 6 6 648.34 63.29
-6 -2 6 640.34 55.89
6 2 6 731.23 54.09
2 -6 6 642.94 58.29
6 0 -6 243.38 28.20
0 -6 -6 234.08 25.60
-6 0 -6 235.18 27.90
0 6 -6 239.48 23.30
-6 0 6 264.87 28.80
0 6 6 254.47 32.80
6 0 6 250.87 28.40
0 -6 6 241.78 28.80
6 -2 -6 638.84 51.29
2 6 -6 601.44 47.50
-2 -6 -6 648.24 53.69
-2 -6 -6 680.73 46.00
-2 -6 6 627.84 43.70
6 -2 6 686.63 56.19
-2 -6 6 638.84 52.29
1 0 -7 125.99 10.30
0 -1 -7 137.89 9.40
0 -1 -7 139.59 12.90
-1 0 -7 118.69 12.00
0 1 -7 129.99 11.00
1 0 -7 129.79 13.40
0 -1 -7 126.99 14.60
0 1 -7 137.39 13.30
1 0 -7 133.19 12.30
-1 0 -7 128.39 13.60
-1 0 -7 130.09 10.90
0 1 7 131.89 11.20
-1 0 7 133.09 10.80
-1 0 7 115.89 16.90
0 -1 7 137.59 16.60
1 0 7 122.89 11.00
0 1 7 132.39 17.90
0 -1 7 133.49 11.00
1 0 7 137.29 16.60
1 -2 -7 153.08 15.20
-1 2 -7 155.48 13.40
2 1 -7 160.78 15.00
1 -2 -7 149.88 12.80
-2 -1 -7 157.68 16.80
2 1 -7 155.38 14.60
-2 -1 -7 148.89 16.90
2 1 -7 153.98 13.50
-1 2 -7 134.69 15.90
-2 -1 7 156.38 12.60
-1 2 7 167.28 22.10
-2 -1 7 156.68 18.10
2 1 7 160.18 17.20
2 1 7 132.59 13.30
1 -2 7 141.99 17.20
2 1 7 157.18 13.80
1 -2 7 158.88 12.30
1 2 -7 151.48 13.70
2 -1 -7 158.48 10.90
1 2 -7 169.48 15.40
-2 1 -7 155.58 14.10
2 -1 -7 149.99 12.60
2 -1 -7 152.58 14.90
1 2 -7 150.38 13.10
-1 -2 -7 159.48 17.20
-2 1 -7 156.38 14.30
-1 -2 -7 156.98 16.40
-1 -2 7 155.48 17.50
-2 1 7 160.18 22.60
-1 -2 7 148.39 12.50
2 -1 7 161.58 17.60
1 2 7 167.58 19.50
1 2 7 165.08 14.20
2 -1 7 150.98 12.60
-2 3 -7 29.40 7.00
3 2 -7 48.80 9.20
2 -3 -7 26.80 7.30
-3 -2 -7 45.80 11.30
-3 -2 -7 38.60 10.20
3 2 -7 33.90 7.60
3 2 7 25.50 7.90
-3 -2 7 31.80 7.10
3 2 7 31.80 7.20
-3 -2 7 26.60 7.80
2 -3 7 40.70 10.90
3 2 7 40.30 9.00
-2 3 7 43.80 15.10
0 -3 -7 164.78 17.80
0 3 -7 183.98 15.80
3 0 -7 169.48 17.00
-3 0 -7 178.98 19.00
0 -3 -7 175.08 15.40
3 0 -7 189.18 14.90
0 3 -7 177.38 17.90
3 0 -7 180.88 18.20
0 -3 7 187.18 20.50
0 3 7 180.08 22.10
3 0 7 177.58 14.30
3 0 7 157.48 17.00
3 0 7 191.98 18.50
0 -3 7 185.78 14.20
-3 0 7 188.78 22.10
-3 2 -7 29.00 7.90
-2 -3 -7 31.80 9.30
-2 -3 -7 43.00 11.00
2 3 -7 35.80 7.70
2 3 -7 38.10 8.50
3 -2 -7 33.70 8.30
-2 -3 7 29.80 8.50
-2 -3 7 32.20 6.50
-3 2 7 35.10 13.60
3 -2 7 37.90 9.60
2 3 7 25.30 8.00
2 3 7 26.60 6.70
4 3 -7 64.19 12.80
4 3 -7 83.29 11.90
-3 4 -7 77.19 11.70
-4 -3 -7 84.99 18.60
3 -4 -7 82.89 12.70
-3 4 7 71.59 20.30
4 3 7 88.99 13.80
4 3 7 78.79 11.10
3 -4 7 90.69 19.20
1 -4 -7 50.49 11.00
-4 -1 -7 62.39 13.70
4 1 -7 69.19 13.50
4 1 -7 40.60 10.60
4 1 -7 58.59 7.60
-1 4 -7 44.80 8.90
4 1 7 46.60 6.90
1 -4 7 45.00 12.80
4 1 7 35.20 10.00
1 -4 7 56.39 5.10
-1 4 7 61.79 16.80
-1 -4 -7 57.49 13.20
-1 -4 -7 56.69 10.10
1 4 -7 58.39 10.10
4 -1 -7 35.30 8.80
-4 1 -7 45.80 11.60
4 -1 7 61.69 11.40
1 4 7 40.00 11.70
-4 1 7 56.99 15.20
-1 -4 7 42.30 11.70
4 -1 7 62.29 12.70
3 4 -7 71.99 13.10
-3 -4 -7 74.49 14.80
3 4 -7 83.29 12.50
-4 3 -7 72.99 14.10
4 -3 -7 72.09 12.30
-3 -4 -7 84.09 18.20
4 -3 7 67.59 14.50
3 4 7 75.09 11.40
-4 3 7 66.89 19.50
-3 -4 7 72.89 9.80
-2 5 -7 92.69 13.20
5 2 -7 86.49 10.00
5 2 -7 110.09 20.00
2 -5 -7 82.79 13.90
-5 -2 -7 107.89 18.90
5 2 7 96.19 10.40
-5 -2 7 99.49 16.70
5 2 7 89.29 16.50
-2 5 7 95.19 23.60
2 -5 7 107.49 22.50
5 0 -7 10.90 10.10
0 5 -7 13.50 6.00
0 -5 -7 10.30 6.80
5 0 -7 10.50 6.60
-5 0 -7 8.10 7.60
0 5 7 8.40 7.90
0 -5 7 27.60 11.00
5 0 7 16.00 8.40
0 -5 7 13.10 3.60
-2 -5 -7 115.39 14.70
-2 -5 -7 91.99 16.60
5 -2 -7 90.29 14.20
2 5 -7 84.29 12.60
2 5 7 80.89 16.80
-2 -5 7 96.49 16.40
-2 -5 7 88.59 10.90
5 -2 7 112.79 20.30
6 1 -7 17.20 11.30
1 -6 -7 32.40 10.90
-1 6 -7 20.20 7.50
-6 -1 -7 29.50 12.30
-1 6 7 25.90 14.20
1 -6 7 21.50 11.20
-6 -1 7 34.50 12.90
6 1 7 40.10 12.70
6 -1 -7 39.50 12.40
-1 -6 -7 17.30 4.40
1 6 -7 23.40 8.50
-1 -6 -7 24.40 10.40
-1 -6 7 17.90 9.90
6 -1 7 22.90 11.80
1 6 7 32.90 13.90
-1 -6 7 27.60 5.70
0 0 -8 6430.56 376.56
0 0 -8 6445.26 373.86
0 0 -8 6481.55 371.36
0 0 8 6535.05 372.56
0 0 8 5787.12 381.86
-1 -1 -8 1030.70 72.99
1 1 -8 1021.60 72.59
1 -1 -8 1181.38 74.29
1 -1 -8 1207.18 72.89
1 1 -8 1130.49 71.39
-1 -1 -8 1045.70 68.69
-1 1 -8 1272.77 73.89
1 1 -8 1020.80 69.89
-1 1 -8 1228.98 70.59
-1 -1 -8 984.20 74.49
-1 1 -8 1190.98 70.29
-1 -1 8 1251.87 80.69
-1 1 8 948.31 80.89
-1 1 8 1046.30 69.49
1 1 8 1234.98 71.09
1 -1 8 1037.60 77.69
-1 -1 8 1289.57 70.49
1 1 8 1291.17 80.49
1 -1 8 1065.09 69.79
0 2 -8 2641.04 155.28
0 -2 -8 2495.75 155.98
2 0 -8 2634.24 155.38
2 0 -8 2570.04 155.68
2 0 -8 2326.77 152.08
-2 0 -8 2499.55 155.58
0 2 -8 2538.45 152.88
-2 0 -8 2673.13 157.08
0 -2 -8 2547.84 156.58
2 0 8 2626.04 159.88
0 2 8 2772.02 165.68
0 -2 8 2548.25 160.78
2 0 8 2311.47 152.48
-2 0 8 2398.66 163.48
0 -2 8 2497.65 151.78
2 0 8 2586.54 152.98
-2 -2 -8 5599.94 329.17
-2 2 -8 5368.36 323.17
2 2 -8 5138.39 324.37
-2 -2 -8 5985.30 328.97
2 -2 -8 5215.38 324.87
2 2 -8 5387.26 323.87
2 2 -8 5624.34 323.27
-2 -2 8 5224.58 328.47
2 -2 8 5503.85 319.87
-2 2 8 5154.48 338.27
2 2 8 5408.56 323.17
2 -2 8 5374.66 329.57
-2 -2 8 5363.26 321.57
2 2 8 5932.61 329.87
-1 3 -8 790.02 57.19
3 1 -8 980.90 59.29
3 1 -8 941.81 59.39
3 1 -8 1000.50 60.99
1 -3 -8 818.62 60.19
-3 -1 -8 972.30 64.09
1 -3 -8 751.02 52.89
-3 -1 8 759.82 61.99
1 -3 8 1045.90 66.89
3 1 8 729.83 58.09
1 -3 8 987.80 55.09
-1 3 8 1024.40 71.59
3 1 8 783.82 59.99
3 1 8 804.12 56.39
1 3 -8 992.70 60.89
-1 -3 -8 1029.80 66.19
3 -1 -8 833.82 62.09
-1 -3 -8 1004.20 63.59
1 3 -8 973.50 61.99
3 -1 8 981.70 56.49
1 3 8 770.32 59.79
-1 -3 8 827.12 58.19
3 -1 8 1019.00 65.49
-1 -3 8 760.62 63.99
-3 1 8 1009.40 74.99
1 3 8 832.82 66.99
3 -1 8 960.30 62.09
3 3 -8 638.44 49.99
3 -3 -8 721.83 51.59
-3 -3 -8 672.23 56.09
-3 -3 -8 705.73 53.19
-3 3 -8 761.12 51.29
3 3 -8 658.73 50.39
3 3 8 743.53 49.50
-3 -3 8 736.13 48.10
-3 -3 8 795.82 53.49
3 -3 8 704.83 55.79
-3 3 8 660.03 61.89
4 2 -8 1335.67 86.19
2 -4 -8 1309.67 89.39
4 2 -8 1326.17 89.69
-2 4 -8 1274.87 86.79
-4 -2 -8 1328.87 93.99
4 2 8 1401.36 89.59
-2 4 8 1357.46 101.99
2 -4 8 1363.06 95.29
4 2 8 1401.36 85.39
-4 -2 8 1335.87 90.89
0 4 -8 4096.39 250.87
4 0 -8 4042.30 253.67
-4 0 -8 4217.68 256.77
0 -4 -8 4091.79 255.17
0 -4 -8 4234.48 247.38
0 -4 8 3885.81 247.18
4 0 8 4144.59 255.17
4 0 8 4533.75 245.68
0 -4 8 4253.57 259.57
-4 0 8 4030.60 257.47
0 4 8 4472.55 263.37
2 4 -8 1206.68 85.39
-2 -4 -8 1385.66 87.69
-2 -4 -8 1328.07 91.29
4 -2 -8 1241.08 86.79
2 4 -8 1288.37 84.69
2 4 8 1236.68 84.59
-4 2 8 1326.87 99.59
2 4 8 1396.66 91.59
-2 -4 8 1296.57 89.29
-2 -4 8 1291.67 82.19
4 -2 8 1364.06 89.39
-4 -4 -8 2678.83 167.88
4 4 -8 2448.16 157.68
-4 4 -8 2352.16 158.08
4 -4 -8 2520.75 160.38
4 4 -8 2336.97 158.78
-4 -4 -8 2680.73 160.98
4 -4 8 2345.07 164.08
4 4 8 2588.44 155.98
-4 4 8 2669.63 176.18
-3 5 -8 375.66 34.70
3 -5 -8 362.46 35.70
-5 -3 -8 486.95 43.90
5 3 -8 472.75 33.70
5 3 -8 457.55 40.40
5 3 8 390.76 31.70
3 -5 8 457.55 43.80
-5 -3 8 385.86 39.60
-3 5 8 476.05 50.89
-1 5 -8 620.04 44.00
-5 -1 -8 541.05 49.10
1 -5 -8 636.24 48.10
5 1 8 649.74 48.20
-1 5 8 516.85 53.49
1 -5 8 532.65 50.49
-1 -5 -8 537.45 38.70
5 -1 -8 583.24 44.80
-1 -5 -8 506.25 45.30
1 5 -8 488.05 40.50
1 5 8 653.83 51.39
-1 -5 8 564.64 37.70
5 -1 8 508.55 46.00
-1 -5 8 584.74 47.90
3 5 -8 443.96 36.10
-3 -5 -8 491.05 38.20
-5 3 -8 378.26 37.20
5 -3 -8 344.57 34.90
3 5 -8 436.76 36.60
-3 -5 -8 480.35 42.90
3 5 8 371.86 33.70
-5 3 8 538.15 50.89
-3 -5 8 346.87 31.10
1 0 -9 87.89 10.70
1 0 -9 87.69 10.70
-1 0 -9 78.49 12.30
0 -1 -9 90.99 11.20
0 -1 -9 87.59 13.10
1 0 -9 91.49 12.40
-1 0 -9 97.39 11.20
0 1 -9 94.69 9.50
0 1 -9 93.29 12.20
0 1 -9 89.79 9.90
-1 0 -9 86.39 8.80
-1 0 9 82.39 9.00
1 0 9 102.99 16.30
0 -1 9 91.29 15.50
-1 0 9 101.19 20.20
0 1 9 87.09 18.60
0 1 9 87.39 9.60
0 -1 9 81.69 9.10
1 0 9 86.29 9.30
-1 2 -9 56.49 8.20
1 -2 -9 56.59 9.00
-2 -1 -9 95.69 14.00
2 1 -9 94.39 11.80
1 -2 -9 44.20 9.70
-2 -1 -9 95.89 13.00
-2 -1 9 82.89 17.10
2 1 9 53.29 12.70
-1 2 9 94.99 21.20
2 1 9 56.69 8.60
-2 -1 9 57.09 7.70
2 -1 -9 56.79 9.50
-1 -2 -9 93.79 13.30
1 2 -9 87.39 11.50
2 -1 -9 55.19 9.60
-2 1 -9 53.69 8.30
-1 -2 9 54.09 7.50
1 2 9 57.09 14.00
-1 -2 9 52.19 13.10
-2 1 9 90.69 21.10
1 2 9 53.29 8.50
3 2 -9 31.30 9.20
2 -3 -9 62.39 11.10
-3 -2 -9 34.80 10.90
3 2 -9 28.20 8.10
3 2 -9 33.30 9.10
-2 3 -9 46.30 9.00
3 2 9 59.49 10.10
-2 3 9 35.60 15.30
-3 -2 9 62.49 13.50
2 -3 9 40.60 13.10
3 2 9 61.29 12.00
0 3 -9 62.69 8.80
3 0 -9 51.19 9.10
0 -3 -9 62.89 12.70
0 -3 -9 53.19 10.00
-3 0 -9 53.59 11.50
3 0 9 63.39 13.30
0 3 9 42.10 13.60
-3 0 9 57.89 15.20
0 -3 9 62.69 14.90
0 -3 9 57.79 7.50
3 0 9 54.09 10.60
3 0 9 53.59 7.70
3 -2 -9 58.69 10.50
-2 -3 -9 31.50 10.50
-2 -3 -9 37.20 10.50
2 3 -9 30.70 7.70
-3 2 -9 59.89 11.30
2 3 -9 48.80 11.10
3 -2 9 34.50 10.90
2 3 9 49.40 9.50
-2 -3 9 56.79 13.00
-2 -3 9 54.49 7.90
2 3 9 57.09 13.20
-3 2 9 23.20 13.30
-4 -3 -9 68.89 16.80
4 3 -9 57.79 11.70
4 3 -9 56.39 13.20
3 -4 9 41.20 13.90
-3 4 9 55.39 19.40
-4 -1 -9 19.80 9.00
4 1 -9 23.60 9.20
4 1 -9 22.90 6.30
1 -4 9 22.50 11.00
-1 4 9 18.20 10.70
1 -4 9 20.60 4.20
1 4 -9 25.00 7.30
-1 -4 -9 27.10 7.80
-1 -4 -9 14.20 8.30
4 -1 9 24.10 8.80
1 4 9 63.79 14.50
4 -1 9 25.40 9.20
-4 1 9 20.40 11.50
3 4 -9 65.39 14.10
-3 -4 -9 51.89 13.20
-3 -4 -9 73.49 17.50
3 4 -9 51.49 11.50
4 -3 9 50.69 14.10
-4 3 9 88.69 24.80
5 2 -9 31.50 12.30
-5 -2 -9 30.60 11.80
5 2 -9 27.50 6.20
2 -5 -9 11.70 7.80
-2 5 9 36.50 16.10
-5 -2 9 8.40 8.20
5 2 9 15.30 8.90
2 -5 9 28.80 13.70
5 0 -9 15.30 7.80
0 -5 -9 25.30 10.00
0 5 -9 25.40 7.90
0 -5 9 16.70 9.40
0 -5 9 21.20 4.90
0 5 9 25.60 12.70
5 0 9 25.90 10.90
-2 -5 -9 41.40 14.10
2 5 -9 35.80 9.90
-2 -5 -9 35.80 9.90
0 0 -10 220.08 19.70
0 0 -10 213.68 22.00
0 0 10 212.38 18.00
0 0 10 264.57 29.30
-1 -1 -10 3151.98 198.18
1 1 -10 2963.40 195.38
1 1 -10 3144.79 191.58
1 -1 -10 3243.78 194.88
-1 -1 -10 3082.69 195.58
1 -1 -10 3455.05 197.28
-1 1 -10 3331.87 196.48
-1 1 -10 3163.68 191.78
1 1 -10 3130.29 193.28
1 -1 10 3252.67 204.18
1 1 10 3472.25 204.08
1 -1 10 2989.00 191.08
-1 -1 10 3411.26 206.58
-1 -1 10 3273.77 191.78
1 1 10 3306.77 192.58
-1 1 10 2902.91 206.88
0 -2 -10 1448.26 95.79
-2 0 -10 1431.56 94.49
2 0 -10 1507.05 94.59
0 -2 -10 1406.86 95.19
0 2 -10 1443.56 91.59
0 2 -10 1498.65 95.29
-2 0 -10 1459.45 91.69
2 0 -10 1438.66 95.19
2 0 10 1509.75 100.39
0 -2 10 1489.55 102.79
0 -2 10 1449.15 90.69
2 0 10 1393.46 91.49
0 2 10 1612.64 106.39
-2 0 10 1450.55 105.49
-2 2 -10 181.38 17.60
-2 -2 -10 186.68 21.50
-2 -2 -10 183.28 21.90
2 2 -10 182.58 17.60
2 2 -10 176.78 19.60
2 -2 -10 180.88 19.50
2 2 10 193.88 18.30
-2 -2 10 183.98 24.00
-2 2 10 197.48 30.40
2 -2 10 189.48 15.70
2 2 10 197.78 23.20
2 -2 10 181.38 23.70
3 1 -10 2491.55 156.98
1 -3 -10 2420.66 150.08
-1 3 -10 2283.87 153.98
-3 -1 -10 2719.53 162.08
1 -3 -10 2325.37 157.88
3 1 -10 2690.13 156.68
-1 3 10 2962.10 173.98
1 -3 10 2755.02 166.68
3 1 10 2442.66 159.18
3 1 10 2385.16 153.28
1 -3 10 2531.45 151.18
-3 -1 10 2342.37 162.98
-3 1 -10 2511.85 159.78
-1 -3 -10 2769.32 161.88
-1 -3 -10 2698.73 164.58
1 3 -10 2622.74 158.28
1 3 -10 2629.74 161.08
3 -1 -10 2441.56 160.88
1 3 10 2604.04 168.68
-1 -3 10 2293.37 155.48
3 -1 10 2746.43 154.58
-3 1 10 2629.64 175.78
3 -1 10 2706.63 165.38
-1 -3 10 2302.17 165.28
-3 -3 -10 1824.32 125.49
3 3 -10 1715.23 118.59
-3 -3 -10 1865.01 121.29
3 -3 -10 1772.02 119.69
3 3 -10 1740.03 118.09
-3 3 -10 1855.11 118.59
-3 -3 10 1902.11 122.79
-3 -3 10 1889.11 115.79
3 -3 10 1865.71 126.49
3 3 10 2028.20 117.29
-3 3 10 1879.01 137.19
-4 -2 -10 981.50 73.59
4 2 -10 890.21 66.89
2 -4 -10 919.71 68.09
4 2 -10 902.11 63.79
-2 4 -10 926.31 65.19
-2 4 10 1075.69 83.09
4 2 10 925.71 62.29
2 -4 10 932.21 74.59
0 -4 -10 149.99 19.90
0 4 -10 146.69 16.50
4 0 -10 131.99 18.00
0 -4 -10 152.08 14.30
0 -4 10 133.29 13.50
4 0 10 165.68 13.20
0 4 10 159.38 25.40
0 -4 10 162.48 23.30
4 0 10 138.19 18.30
-4 0 10 164.78 24.10
-2 -4 -10 955.90 65.29
4 -2 -10 840.22 64.99
-4 2 -10 879.81 65.79
2 4 -10 885.61 65.19
-2 -4 -10 951.30 70.89
2 4 -10 879.31 62.69
-2 -4 10 885.21 60.39
-2 -4 10 848.92 68.39
2 4 10 985.10 70.69
-4 2 10 958.60 80.59
4 -2 10 931.11 68.69
-1 0 -11 53.29 9.30
1 0 -11 52.19 9.40
0 -1 -11 52.59 12.20
-1 0 -11 46.30 11.90
0 1 -11 62.39 8.50
0 1 -11 57.29 12.10
1 0 -11 59.69 13.20
0 -1 -11 52.39 11.10
-1 0 11 59.69 18.50
0 -1 11 60.39 8.40
0 1 11 59.19 17.20
1 0 11 66.89 16.40
1 0 11 53.09 8.10
-1 0 11 53.69 8.40
0 -1 11 63.49 17.30
1 -2 -11 27.20 8.30
-2 -1 -11 24.50 9.10
2 1 -11 25.80 8.80
-1 2 -11 24.60 6.70
1 -2 -11 25.40 7.60
-2 -1 -11 24.10 9.60
1 -2 11 25.40 6.20
2 1 11 32.50 11.40
-1 2 11 29.90 14.00
-2 -1 11 32.40 13.60
2 1 11 30.10 7.40
1 -2 11 19.40 11.00
2 -1 -11 30.80 8.10
2 -1 -11 28.60 8.10
-1 -2 -11 22.00 8.70
-2 1 -11 22.40 6.40
-1 -2 -11 38.20 11.00
1 2 -11 19.00 8.10
2 -1 11 22.30 6.00
-1 -2 11 34.30 13.70
-1 -2 11 30.10 7.20
1 2 11 19.70 6.60
1 2 11 28.10 11.40
-2 1 11 13.50 11.90
2 -1 11 28.10 11.60
3 2 -11 51.59 12.10
-3 -2 -11 40.20 12.10
-2 3 -11 40.20 9.80
-3 -2 -11 51.69 14.60
2 -3 -11 52.79 12.90
2 -3 11 50.99 6.40
3 2 11 37.60 11.60
3 2 11 48.40 10.40
2 -3 11 54.39 16.10
-3 -2 11 42.50 14.10
-2 3 11 47.30 18.80
0 3 -11 9.90 5.20
-3 0 -11 13.50 6.30
0 -3 -11 11.70 7.20
3 0 -11 10.50 6.10
0 -3 -11 9.70 5.30
3 0 -11 10.60 5.20
0 -3 11 15.60 10.10
0 -3 11 11.30 4.60
3 0 11 13.30 5.00
3 0 11 10.80 7.90
0 3 11 12.70 9.90
-3 0 11 13.10 10.20
3 -2 -11 38.20 10.70
-2 -3 -11 47.70 14.30
2 3 -11 58.09 13.40
2 3 -11 43.90 9.60
-2 -3 -11 44.00 11.90
-3 2 -11 49.10 11.30
-3 2 11 46.40 18.80
-2 -3 11 27.50 11.50
-2 -3 11 39.10 8.80
2 3 11 60.09 15.20
3 -2 11 56.39 15.50
2 3 11 44.90 10.40
4 1 -11 30.90 10.60
-1 4 -11 14.90 7.00
4 1 -11 21.50 6.60
1 -4 -11 21.90 9.70
-4 -1 -11 27.70 12.00
1 -4 11 26.30 5.40
4 1 11 10.90 4.90
-1 4 11 24.60 12.90
1 -4 11 34.80 13.80
1 4 -11 25.40 8.00
-4 1 -11 10.20 7.30
4 -1 -11 13.20 7.50
-1 -4 -11 23.90 10.80
-1 -4 -11 28.50 8.60
-1 -4 11 15.90 10.30
1 4 11 9.70 9.20
-1 -4 11 18.20 5.90
-4 1 11 21.40 13.70
4 -1 11 24.60 10.70
0 0 -12 1373.26 92.89
0 0 12 1309.67 86.29
0 0 12 1425.36 102.79
1 -1 -12 565.94 46.70
1 -1 -12 591.04 47.90
-1 1 -12 588.84 48.60
-1 -1 -12 725.73 49.50
1 1 -12 731.43 50.59
-1 -1 -12 785.32 52.59
-1 -1 12 587.74 57.09
1 -1 12 698.03 44.30
1 1 12 610.24 54.69
-1 1 12 738.63 62.39
-1 -1 12 564.24 43.70
1 1 12 549.65 43.90
0 -2 -12 2874.11 171.78
2 0 -12 2664.63 171.08
0 -2 -12 2679.93 172.38
2 0 -12 2726.23 170.68
0 2 -12 2711.33 171.78
0 -2 12 2835.22 182.98
0 -2 12 2604.14 165.88
-2 0 12 2635.84 184.88
0 2 12 3016.40 184.68
2 0 12 2701.83 177.98
2 0 12 2700.53 167.18
-2 -2 -12 1062.89 72.99
-2 -2 -12 1003.30 74.09
2 2 -12 1007.10 71.19
-2 2 -12 985.80 67.89
2 -2 -12 989.60 70.89
2 -2 -12 965.80 61.49
-2 2 12 1025.10 86.89
2 2 12 967.10 67.59
2 -2 12 1059.29 79.39
-2 -2 12 962.10 78.39
2 2 12 1099.69 76.39
-2 -2 12 956.00 65.99
2 -2 12 1017.90 64.89
-3 -1 -12 478.45 46.30
-1 3 -12 610.04 43.00
1 -3 -12 564.84 37.60
3 1 -12 478.25 42.50
1 -3 -12 598.14 46.50
-1 3 12 562.04 56.49
3 1 12 593.64 41.10
1 -3 12 501.55 51.59
-3 -1 12 594.84 53.69
3 1 12 628.74 48.70
-1 -3 -12 497.85 40.40
1 3 -12 445.56 40.70
3 -1 -12 607.84 43.50
-1 -3 -12 445.76 42.70
1 3 -12 447.16 37.60
-3 1 -12 577.94 40.50
3 -1 12 455.05 34.30
3 -1 12 478.85 44.80
-3 1 12 464.85 52.69
-1 -3 12 605.74 50.89
0 1 -13 14.10 8.50
0 -1 -13 15.60 8.00
0 -1 -13 10.00 6.40
1 0 -13 15.80 8.50
-1 0 -13 15.10 9.40
0 1 13 15.70 11.60
1 0 13 17.20 11.10
1 0 13 14.70 5.90
0 1 13 10.70 5.60
0 -1 13 28.10 14.30
-1 0 13 16.10 13.00
0 -1 13 15.80 6.20
-2 -1 -13 4.70 6.60
1 -2 -13 29.90 10.20
2 1 -13 11.40 7.50
1 -2 -13 16.60 7.00
1 -2 13 8.50 9.50
1 -2 13 3.90 3.70
2 1 13 24.40 7.70
2 1 13 31.00 13.90
-1 2 13 0.90 8.20
-2 -1 13 35.50 16.10
1 2 -13 11.00 8.20
-1 -2 -13 14.40 8.00
2 -1 -13 25.80 7.60
-1 -2 -13 6.50 7.00
2 -1 -13 25.60 9.20
1 2 13 34.90 14.00
2 -1 13 6.90 9.20
-1 -2 13 24.90 14.10
-1 -2 13 25.00 7.30
2 -1 13 9.10 4.90
-2 1 13 7.50 11.60
1 2 13 23.80 7.90
0 0 14 994.00 83.89
0 0 0 0.00 0.00
_computing_structure_solution 'SHELXT 2014/5 (Sheldrick, 2014)'
;
_shelx_hkl_checksum 6352
_shelx_res_file
;
TITL JCK_MT58_1_Cu2HgSnS4_11162022__f.res in I-42m
JCK_MT58_1_Cu2HgSnS4_11162022.res
created by SHELXL-2018/3 at 14:55:16 on 29-Nov-2022
REM Old TITL JCK_MT58_1_Cu2HgSnS4_11162022_ in I-42m
REM SHELXT solution in I-42m
REM R1 0.066, Rweak 0.006, Alpha 0.063, Orientation as input
REM Flack x = -0.076 ( 0.020 ) from Parsons' quotients
REM Formula found by SHELXT: Cu2 Hg S4 Sn
CELL 0.71073 5.5798 5.5798 10.8597 90.000 90.000 90.000
ZERR 2.000 0.0012 0.0012 0.0028 0.000 0.000 0.000
LATT -2
SYMM -X, -Y, Z
SYMM Y, -X, -Z
SYMM -Y, X, -Z
SYMM -X, Y, -Z
SYMM X, -Y, -Z
SYMM -Y, -X, Z
SYMM Y, X, Z
SFAC CU HG S SN
UNIT 4 2 8 2
ACTA
TEMP 20.000
SIZE 0.076 0.134 0.136
L.S. 10
BOND $H
LIST 4
FMAP 2
PLAN 20
WGHT 0.012400
EXTI 0.023161
FVAR 0.39093
HG1 2 0.500000 0.500000 0.500000 10.12500 0.01857 0.01857 =
0.02142 0.00000 0.00000 0.00000
SN1 4 0.000000 0.000000 0.500000 10.12500 0.00643 0.00643 =
0.00669 0.00000 0.00000 0.00000
CU1 1 0.500000 0.000000 0.250000 10.25000 0.01717 0.01717 =
0.02002 0.00000 0.00000 0.00000
S1 3 0.240198 0.240198 0.363218 10.50000 0.00937 0.00937 =
0.00917 0.00141 0.00141 -0.00029
HKLF 4
REM JCK_MT58_1_Cu2HgSnS4_11162022__f.res in I-42m
REM wR2 = 0.0317, GooF = S = 1.080, Restrained GooF = 1.080 for all data
REM R1 = 0.0141 for 218 Fo > 4sig(Fo) and 0.0141 for all 218 data
REM 14 parameters refined using 0 restraints
END
WGHT 0.0122 0.0000
REM Highest difference peak 0.534, deepest hole -0.855, 1-sigma level 0.205
Q1 1 0.6202 0.6202 0.4262 10.50000 0.05 0.53
Q2 1 0.1347 0.1347 0.4330 10.50000 0.05 0.53
Q3 1 0.6242 0.6242 0.5749 10.50000 0.05 0.48
Q4 1 0.1395 0.3676 0.3021 11.00000 0.05 0.47
Q5 1 0.1271 0.1271 0.5768 10.50000 0.05 0.46
Q6 1 0.3756 0.1163 0.1757 11.00000 0.05 0.45
Q7 1 0.1450 0.1450 0.2989 10.50000 0.05 0.42
Q8 1 0.1513 0.1514 0.6626 10.50000 0.05 0.39
Q9 1 0.6519 0.1418 0.4025 11.00000 0.05 0.38
Q10 1 0.1387 0.3551 0.4259 11.00000 0.05 0.38
Q11 1 0.3840 0.1320 0.4996 11.00000 0.05 0.34
Q12 1 0.3570 0.3570 0.2401 10.50000 0.05 0.32
Q13 1 0.3607 0.3607 0.3220 10.50000 0.05 0.32
Q14 1 0.6392 0.6392 0.6647 10.50000 0.05 0.31
;
_shelx_res_checksum 95076
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'y, -x, -z'
'-y, x, -z'
'-x, y, -z'
'x, -y, -z'
'-y, -x, z'
'y, x, z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-y+1/2, -x+1/2, z+1/2'
'y+1/2, x+1/2, z+1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Hg Hg1 0.500000 0.500000 0.500000 0.0195(2) Uani d 1 . .
Sn Sn1 0.000000 0.000000 0.500000 0.00651(19) Uani d 1 . .
Cu Cu1 0.500000 0.000000 0.250000 0.0181(3) Uani d 1 . .
S S1 0.24020(16) 0.24020(16) 0.36322(16) 0.0093(4) Uani d 1 . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Hg1 0.0186(2) 0.0186(2) 0.0214(3) 0.000 0.000 0.000
Sn1 0.0064(2) 0.0064(2) 0.0067(3) 0.000 0.000 0.000
Cu1 0.0172(4) 0.0172(4) 0.0200(6) 0.000 0.000 0.000
S1 0.0094(6) 0.0094(6) 0.0092(8) -0.0003(6) 0.0014(3) 0.0014(3)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Hg Hg -2.3894 9.2266 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
S1 Hg1 S1 4_656 3_566 108.15(7) ?
S1 Hg1 S1 4_656 2_665 110.14(4) ?
S1 Hg1 S1 3_566 2_665 110.14(4) ?
S1 Hg1 S1 4_656 . 110.14(4) ?
S1 Hg1 S1 3_566 . 110.14(4) ?
S1 Hg1 S1 2_665 . 108.15(7) ?
S1 Sn1 S1 2 4_556 112.36(4) ?
S1 Sn1 S1 2 3_556 112.36(4) ?
S1 Sn1 S1 4_556 3_556 103.83(8) ?
S1 Sn1 S1 2 . 103.83(8) ?
S1 Sn1 S1 4_556 . 112.36(4) ?
S1 Sn1 S1 3_556 . 112.36(4) ?
S1 Cu1 S1 . 12_545 106.23(4) ?
S1 Cu1 S1 . 11 106.23(4) ?
S1 Cu1 S1 12_545 11 116.17(8) ?
S1 Cu1 S1 . 2_655 116.17(8) ?
S1 Cu1 S1 12_545 2_655 106.23(4) ?
S1 Cu1 S1 11 2_655 106.23(4) ?
Cu1 S1 Cu1 . 13 116.03(8) ?
Cu1 S1 Sn1 . . 110.63(3) ?
Cu1 S1 Sn1 13 . 110.63(3) ?
Cu1 S1 Hg1 . . 106.45(4) ?
Cu1 S1 Hg1 13 . 106.45(4) ?
Sn1 S1 Hg1 . . 105.99(7) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Hg1 S1 4_656 2.5317(17) ?
Hg1 S1 3_566 2.5317(17) ?
Hg1 S1 2_665 2.5317(17) ?
Hg1 S1 . 2.5317(17) ?
Sn1 S1 2 2.4081(14) ?
Sn1 S1 4_556 2.4081(14) ?
Sn1 S1 3_556 2.4081(14) ?
Sn1 S1 . 2.4081(14) ?
Cu1 S1 . 2.3258(10) ?
Cu1 S1 12_545 2.3258(10) ?
Cu1 S1 11 2.3258(10) ?
Cu1 S1 2_655 2.3258(10) ?
_cod_database_fobs_code 2312276