#------------------------------------------------------------------------------ #$Date: 2023-11-28 09:31:58 +0200 (Tue, 28 Nov 2023) $ #$Revision: 287825 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/31/23/2312359.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2312359 loop_ _publ_author_name 'Kitahara, Koichi' 'Takakura, Hiroyuki' 'Iwasaki, Yutaka' 'Kimura, Kaoru' _publ_section_title ; Crystal structures of five compounds in the aluminium-ruthenium-silicon system. ; _journal_coeditor_code WM5690 _journal_issue 'Pt 10' _journal_name_full 'Acta crystallographica. Section E, Crystallographic communications' _journal_page_first 946 _journal_page_last 951 _journal_paper_doi 10.1107/S2056989023008393 _journal_volume 79 _journal_year 2023 _chemical_formula_iupac '\\sim Ru9 (Al0.70 Si0.30)32' _chemical_formula_moiety 'Al22.40 Ru9 Si9.60' _chemical_formula_sum 'Al22.4 Ru9 Si9.6' _chemical_formula_weight 1783.65 _chemical_name_systematic ; Docosaaluminium nonaruthenium decasilicon ; _space_group_crystal_system trigonal _space_group_IT_number 148 _space_group_name_Hall '-R 3' _space_group_name_H-M_alt 'R -3 :H' _atom_sites_solution_primary dual _audit_creation_method SHELXL-2019/3 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 120 _cell_formula_units_Z 3 _cell_length_a 10.4479(2) _cell_length_b 10.4479(2) _cell_length_c 19.6774(4) _cell_measurement_reflns_used 10605 _cell_measurement_temperature 295.9(2) _cell_measurement_theta_max 30.7050 _cell_measurement_theta_min 3.8570 _cell_volume 1860.19(6) _computing_cell_refinement ; CrysAlis PRO (Matsumoto et al., 2021) ; _computing_data_collection ; CrysAlis PRO (Matsumoto et al., 2021) ; _computing_data_reduction ; CrysAlis PRO (Matsumoto et al., 2021) ; _computing_molecular_graphics ; VESTA (Momma & Izumi, 2011) ; _computing_publication_material ; publCIF (Westrip, 2010) ; _computing_structure_refinement ; SHELXL (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXT (Sheldrick, 2015a) ; _diffrn_ambient_temperature 295.9(2) _diffrn_detector 'Hybrid Pixel Array Detector' _diffrn_detector_area_resol_mean 10.0000 _diffrn_measured_fraction_theta_full 0.996 _diffrn_measured_fraction_theta_max 0.921 _diffrn_measurement_device 'four-circle diffractometer' _diffrn_measurement_device_type 'XtaLAB Synergy R, HyPix' _diffrn_measurement_method '\w scans' _diffrn_radiation_monochromator mirror _diffrn_radiation_probe x-ray _diffrn_radiation_type 'Mo K\a' _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0267 _diffrn_reflns_av_unetI/netI 0.0142 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_h_min -14 _diffrn_reflns_limit_k_max 14 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_l_max 28 _diffrn_reflns_limit_l_min -27 _diffrn_reflns_number 14255 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 30.781 _diffrn_reflns_theta_min 3.901 _diffrn_source 'micro-focus sealed X-ray tube' _exptl_absorpt_coefficient_mu 6.591 _exptl_absorpt_correction_T_max 0.879 _exptl_absorpt_correction_T_min 0.868 _exptl_absorpt_correction_type gaussian _exptl_absorpt_process_details ; (CrysAlisPro; Matsumoto et al., 2021) ; _exptl_crystal_colour 'metallic light silver' _exptl_crystal_density_diffrn 4.777 _exptl_crystal_density_method 'not measured' _exptl_crystal_description irregular _exptl_crystal_F_000 2436.84 _exptl_crystal_size_max 0.031 _exptl_crystal_size_mid 0.029 _exptl_crystal_size_min 0.026 _refine_diff_density_max 0.447 _refine_diff_density_min -0.526 _refine_ls_extinction_coef 0.000262(16) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_extinction_method ; SHELXL-2019/3 (Sheldrick, 2015b) ; _refine_ls_goodness_of_fit_ref 1.080 _refine_ls_hydrogen_treatment undef _refine_ls_matrix_type full _refine_ls_number_parameters 66 _refine_ls_number_reflns 1193 _refine_ls_number_restraints 2 _refine_ls_restrained_S_all 1.079 _refine_ls_R_factor_all 0.0144 _refine_ls_R_factor_gt 0.0126 _refine_ls_shift/su_max 0.002 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0111P)^2^+0.5812P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0232 _refine_ls_wR_factor_ref 0.0237 _reflns_number_gt 1127 _reflns_number_total 1193 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file wm5690sup1.cif _cod_data_source_block II _cod_original_cell_volume 1860.17(7) _cod_original_sg_symbol_H-M 'R -3' _cod_original_formula_sum 'Al22.40 Ru9 Si9.60' _cod_database_code 2312359 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_hkl_file ; 0 0 6 3094.07 41.20 0 0 -6 3028.60 41.33 0 0 -6 3082.28 41.03 0 0 -6 3081.74 36.95 0 0 6 3111.67 41.44 0 0 9 1296.69 32.80 0 0 -9 1278.34 33.22 0 0 9 1308.26 29.18 0 0 -9 1300.90 32.61 0 0 9 1262.14 29.04 0 0 12 27.18 5.41 0 0 -12 25.45 5.87 0 0 12 17.28 4.09 0 0 -12 28.44 6.03 0 0 -15 5654.22 88.43 0 0 -15 5556.30 90.96 0 0 15 5588.93 78.31 0 0 15 5753.95 78.84 0 0 -15 5420.33 77.43 0 0 15 5649.06 77.04 0 0 -18 79.73 12.32 0 0 18 71.56 6.10 0 0 -18 64.99 11.07 0 0 18 65.12 6.07 0 0 18 66.33 9.58 0 0 18 73.45 10.60 0 0 18 65.41 9.63 0 0 -18 50.86 8.79 0 0 -21 1099.48 40.76 0 0 -21 1086.03 46.00 0 0 -21 1080.92 47.43 0 0 21 1073.41 47.06 0 0 21 1040.11 21.36 0 0 21 1102.97 21.44 0 0 21 1044.84 39.78 0 0 21 1050.84 39.42 0 0 21 1092.04 39.70 0 0 24 2485.87 57.95 0 0 -24 2377.17 75.47 0 0 24 2531.21 77.23 0 0 24 2449.21 64.37 0 0 -24 2536.45 74.53 0 0 -24 2506.31 65.08 0 0 27 972.96 42.31 0 1 26 101.14 13.17 1 -1 26 81.75 12.99 -1 0 26 93.40 13.59 1 0 -26 90.28 14.40 -1 1 -26 95.18 13.89 -1 1 -26 95.83 15.70 1 -1 23 98.20 12.69 0 1 23 94.57 10.67 -1 1 -23 132.72 17.23 1 0 -23 96.90 15.36 0 -1 -23 98.01 15.47 -1 1 -23 85.99 14.43 1 -1 23 70.63 12.41 0 -1 -23 104.76 16.65 0 1 23 92.51 5.22 0 1 23 88.76 5.21 -1 0 23 95.35 8.18 -1 0 23 96.95 8.40 1 -1 23 103.07 13.79 -1 0 23 96.52 13.02 0 1 23 92.24 12.13 1 -1 23 86.21 12.13 0 1 23 92.95 11.89 0 1 23 89.40 11.55 1 -1 23 84.50 11.44 -1 1 -23 84.29 12.25 0 -1 -23 126.91 14.39 1 0 -23 105.34 14.67 1 -1 20 403.72 23.72 -1 0 20 457.29 18.53 0 1 20 458.32 24.24 -1 1 -20 468.16 26.07 1 0 -20 419.21 25.95 -1 0 20 440.14 25.48 0 -1 -20 459.34 24.60 0 1 20 438.21 21.34 -1 1 -20 427.23 29.89 0 -1 -20 494.23 31.29 1 -1 20 374.39 27.05 0 1 20 434.11 14.80 1 -1 20 465.50 26.26 0 1 20 490.36 25.52 -1 0 20 460.65 26.86 -1 1 -20 430.52 27.64 0 -1 -20 475.09 29.73 1 0 -20 431.45 29.42 0 1 20 452.44 24.89 -1 0 20 407.31 25.30 1 -1 20 456.61 25.23 1 -1 17 339.40 20.20 0 -1 -17 308.52 18.82 1 0 -17 371.30 23.18 0 1 17 373.85 18.46 0 -1 -17 347.35 24.53 -1 1 -17 331.96 24.30 1 -1 17 354.31 24.50 -1 0 17 325.58 23.90 1 -1 17 353.98 8.99 1 -1 17 367.45 8.89 0 1 17 368.41 14.35 -1 0 17 325.68 21.51 0 1 17 365.96 20.32 1 -1 17 371.72 21.62 1 -1 17 344.35 20.44 -1 0 17 357.43 22.02 0 1 17 371.11 20.69 1 0 -17 360.75 25.04 -1 1 -17 357.92 23.61 0 -1 -17 380.15 24.61 0 -1 -14 524.16 22.18 1 0 -14 498.83 24.31 1 0 -14 537.68 27.57 0 -1 -14 571.27 27.56 -1 1 -14 576.67 26.92 0 -1 -14 522.05 27.25 -1 1 -14 523.70 27.32 1 -1 14 536.93 26.82 -1 0 14 510.41 26.66 1 -1 14 560.42 11.91 0 1 14 540.50 16.86 -1 0 14 548.61 25.15 1 -1 14 520.46 23.30 0 1 14 583.04 22.99 1 -1 14 555.98 23.66 0 1 14 570.46 23.21 1 -1 14 551.50 23.43 -1 0 14 589.31 26.02 -1 1 -11 23.86 4.81 0 -1 -11 16.03 5.44 0 1 11 12.04 3.61 1 0 -11 13.90 4.79 -1 0 11 24.09 4.74 -1 1 -11 23.45 5.32 1 -1 11 23.89 2.53 0 1 11 13.42 2.82 0 -1 -11 16.91 5.14 -1 0 11 25.98 6.15 -1 0 11 21.26 5.25 -1 1 -11 18.73 5.09 1 -1 11 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10 2071.57 45.86 3 1 -10 1948.69 48.99 -1 4 10 1976.78 35.53 4 -3 10 1977.18 46.40 -1 4 10 1964.04 46.33 1 -4 -10 1990.19 47.78 3 1 -10 2019.35 44.06 1 -4 -10 1999.85 48.06 4 -3 10 1974.84 37.25 -3 -1 10 2036.71 49.48 -4 3 -10 2074.69 38.02 -1 4 10 2010.24 35.69 3 1 -13 775.33 34.47 -1 4 13 822.25 28.45 -4 3 -13 829.38 28.99 1 -4 -13 833.04 28.52 -3 -1 13 836.15 30.43 3 1 -13 801.70 34.43 4 -3 13 840.12 33.55 3 1 -13 854.68 32.65 -1 4 13 848.45 33.66 1 -4 -13 860.77 35.05 1 -4 -13 850.89 34.30 4 -3 13 826.80 32.60 -1 4 13 803.65 25.58 -4 3 -13 822.16 28.38 4 -3 16 523.14 23.70 3 1 -16 557.07 31.80 -1 4 16 526.45 23.21 -1 4 16 521.01 22.07 -3 -1 16 535.28 30.18 -4 3 -16 468.13 23.37 -3 -1 16 534.63 29.49 1 -4 -16 523.98 24.62 -3 -1 16 543.03 25.28 3 1 -16 582.61 31.37 4 -3 16 560.37 29.34 1 -4 -16 547.60 30.62 -4 3 -16 545.66 30.78 3 1 -16 508.08 28.36 -1 4 16 520.04 28.67 1 -4 -16 514.02 29.28 -3 -1 16 458.05 28.38 4 -3 16 513.52 27.42 4 -3 16 490.57 27.13 -1 4 16 509.73 22.49 -1 4 19 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8.48 -6 -4 1 47.40 7.40 -6 -4 1 62.86 11.92 -10 6 -1 43.47 4.56 -6 -4 1 46.63 7.54 -4 10 1 44.26 9.88 -4 10 1 51.20 10.67 -6 -4 1 70.19 11.98 -6 -4 1 43.43 6.82 6 4 -1 41.56 7.30 4 -10 -1 51.92 9.45 -6 -4 1 39.30 7.17 -10 6 -1 68.49 11.47 -10 6 -1 30.60 7.46 4 -10 -1 53.10 8.50 -6 -4 1 55.36 7.39 10 -6 1 33.52 8.75 -4 10 1 36.30 9.74 -10 6 -1 55.44 8.89 10 -6 1 53.78 5.47 10 -6 1 46.18 5.48 -6 -4 1 36.72 6.75 10 -6 4 674.61 30.38 -6 -4 4 756.14 31.56 -6 -4 4 676.54 34.59 -4 10 4 679.85 36.79 -10 6 -4 703.23 22.16 4 -10 -4 680.37 26.69 -6 -4 4 673.78 36.32 6 4 -4 671.50 31.91 -6 -4 4 705.77 31.18 -4 10 4 693.87 32.07 4 -10 -4 686.32 29.96 10 -6 4 691.75 35.11 10 -6 4 693.22 34.49 6 4 -4 704.95 31.16 -6 -4 4 696.61 30.12 -10 6 -4 729.08 37.70 -4 10 4 640.67 32.36 -10 6 -4 721.42 34.61 -4 10 4 663.43 29.10 -6 -4 4 704.74 31.66 4 -10 -7 3.45 3.30 -6 -4 7 11.69 5.42 10 -6 7 3.03 3.10 -6 -4 7 4.87 5.05 -10 6 -7 4.20 4.63 -6 -4 7 7.25 5.43 6 4 -7 10.29 4.38 4 -10 -7 1.65 1.85 4 -10 -7 3.91 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11.01 -5 -5 0 99.08 10.21 10 -5 0 85.61 6.58 5 -10 0 107.87 13.66 -5 -5 0 70.05 10.19 -5 10 3 76.25 12.33 -5 -5 3 117.51 14.16 5 5 -3 82.54 10.76 -5 -5 3 103.27 11.34 -10 5 -3 86.27 13.57 5 -10 -3 87.95 9.31 -5 -5 3 91.59 11.09 -10 5 -3 96.66 8.89 -5 -5 3 111.72 14.85 -5 -5 3 76.92 10.11 -5 -5 3 92.77 11.11 10 -5 3 76.11 9.98 -5 10 3 89.08 12.59 5 -10 -3 99.00 13.52 5 -10 -3 90.31 12.16 -5 10 3 106.29 12.92 -10 5 -3 87.46 12.70 10 -5 3 81.07 12.10 5 5 -6 828.35 37.79 5 -10 -6 851.43 26.55 -5 -5 6 831.39 36.04 10 -5 6 840.37 31.22 -5 -5 6 905.91 36.17 5 -10 -6 897.95 23.77 5 5 -6 825.46 35.73 -10 5 -6 879.64 37.12 -5 10 6 840.66 34.32 5 5 -6 875.70 16.85 -5 -5 6 925.03 38.62 -5 -5 6 863.90 35.75 5 -10 -6 869.28 35.01 10 -5 6 803.69 36.53 5 -10 -9 31.92 5.71 -5 -5 9 34.47 8.13 -5 10 9 37.72 10.11 -5 -5 9 43.63 10.21 5 5 -9 31.20 8.46 -5 10 9 24.35 8.05 -5 10 9 41.93 8.36 10 -5 9 30.34 9.18 -10 5 -9 31.29 8.15 5 5 -9 28.44 4.81 5 -10 -9 33.75 8.95 -5 -5 9 33.55 8.53 10 -5 9 23.51 5.55 5 5 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782.14 37.37 4 6 4 816.64 22.31 -10 4 4 866.72 37.02 -10 4 4 911.28 40.24 -10 4 4 852.83 17.61 6 -10 4 821.09 35.90 4 6 4 839.50 19.61 -10 4 4 848.17 28.79 6 -10 4 870.02 39.91 -10 4 4 846.12 37.38 6 -10 4 859.23 36.88 -4 -6 -4 850.97 34.74 -6 10 -1 -1.44 4.75 4 6 1 -1.46 6.52 -4 -6 -1 2.66 4.57 -10 4 1 -1.16 4.22 4 6 1 8.16 3.70 -10 4 1 17.42 7.35 6 -10 1 -2.05 3.34 6 -10 1 -1.22 5.08 -4 -6 -1 7.51 5.03 6 -10 1 5.42 4.92 -10 4 1 2.50 4.62 4 6 1 3.04 1.88 -10 4 1 5.91 3.29 -10 4 1 3.63 2.39 -4 -6 -1 4.33 1.82 -6 10 -1 1.28 5.93 -6 10 -1 -2.71 5.24 -4 -6 -1 5.38 2.71 10 -4 -1 2.21 4.16 6 -10 1 7.55 4.78 -4 -6 -1 6.85 3.50 10 -4 2 130.07 12.99 -10 4 -2 143.32 12.11 6 -10 -2 120.92 14.91 -4 -6 2 142.20 17.26 -4 -6 2 127.85 12.95 -6 10 2 133.04 16.64 -4 -6 2 109.37 13.89 -4 -6 2 115.74 12.06 10 -4 2 134.75 14.84 -4 -6 2 114.02 14.29 -4 -6 2 86.33 11.63 6 -10 -2 135.89 12.02 4 6 -2 130.71 6.65 -10 4 -2 141.51 11.96 6 -10 -2 118.44 14.13 -6 10 2 118.63 13.83 -10 4 -2 136.40 14.68 -4 -6 2 124.36 12.47 -4 -6 5 191.93 17.48 10 -4 5 249.90 16.21 -6 10 5 224.34 21.60 -4 -6 5 222.22 17.89 6 -10 -5 240.98 13.93 -10 4 -5 203.81 20.40 4 6 -5 232.35 11.12 -10 4 -5 229.49 18.55 -6 10 5 220.38 18.32 4 6 -5 234.78 11.04 -4 -6 5 208.99 17.66 4 6 -5 180.78 18.28 -4 -6 5 220.97 21.42 -10 4 -5 224.82 16.78 10 -4 5 241.48 19.64 6 -10 -5 216.86 18.59 4 6 -8 18.31 7.72 -4 -6 8 15.35 7.19 -6 10 8 20.03 8.07 -10 4 -8 26.82 8.74 10 -4 8 7.23 3.50 6 -10 -8 25.68 7.17 -10 4 -8 21.94 7.16 -6 10 8 13.12 5.99 4 6 -8 12.77 3.59 6 -10 -8 7.46 2.73 -4 -6 8 16.66 7.32 6 -10 -8 12.19 6.92 -4 -6 8 13.17 6.51 10 -4 8 7.49 3.30 10 -4 11 642.29 31.65 -6 10 11 682.87 38.28 4 6 -11 653.40 25.85 -4 -6 11 676.84 36.83 -10 4 -11 726.71 29.21 -6 10 11 644.09 38.11 4 6 -11 687.11 38.42 6 -10 -11 696.68 23.74 10 -4 11 644.74 20.98 6 -10 -11 756.35 39.00 -6 10 11 674.20 32.11 -4 -6 14 158.82 19.23 -6 10 14 134.03 17.31 -10 4 -14 152.47 13.88 4 6 -14 132.05 17.83 -6 10 14 143.18 18.71 10 -4 14 130.63 6.13 -6 10 14 152.84 15.59 4 6 -14 113.23 15.95 10 -4 14 156.34 16.06 4 6 -14 150.06 13.69 -10 4 -14 167.21 17.20 10 -4 14 154.37 8.47 6 -10 -14 152.21 17.92 10 -4 17 403.25 26.11 6 -10 -17 385.17 29.28 -6 10 17 437.74 31.67 4 6 -17 405.83 25.61 -10 4 -17 425.95 28.81 4 6 -20 41.29 9.87 10 -3 -20 298.46 24.78 -3 -7 -17 704.07 34.43 10 -3 -17 719.29 35.42 10 -3 -17 765.54 41.72 3 7 17 676.11 32.07 3 7 17 729.76 40.14 -7 10 -14 83.84 10.49 3 7 14 80.46 11.71 -7 10 -14 80.52 13.86 -10 3 14 88.60 14.13 3 7 14 80.94 13.20 10 -3 -14 87.13 14.69 -3 -7 -14 96.53 12.49 3 7 14 68.86 9.98 10 -3 -14 95.80 12.03 10 -3 -14 78.74 14.16 7 -10 14 110.99 17.62 -3 -7 -11 248.07 16.91 -10 3 11 216.01 20.21 7 -10 11 267.41 24.84 3 7 11 217.09 15.60 -10 3 11 253.24 17.48 -3 -7 -11 237.41 19.79 -7 10 -11 242.49 19.00 3 7 11 244.86 20.64 -3 -7 -11 231.16 19.63 -7 10 -11 206.88 16.28 -3 -7 -11 209.65 21.39 10 -3 -11 207.89 16.29 10 -3 -11 169.66 16.92 10 -3 -11 228.88 21.96 -7 10 -11 210.28 21.45 10 -3 -8 1010.99 36.78 -7 10 -8 934.48 38.40 3 7 8 1013.05 42.44 -3 -7 -8 1012.36 40.90 -7 10 -8 996.47 31.25 -3 -7 -8 1021.84 39.73 -3 -7 -8 914.12 43.13 -3 -7 -8 1008.63 35.66 -10 3 8 997.82 43.00 7 -10 8 921.73 38.24 3 7 8 988.90 30.23 -10 3 8 1039.16 32.06 -10 3 8 944.04 40.39 10 -3 -8 1035.53 44.02 -7 10 -8 1018.39 46.10 7 -10 8 938.65 44.19 7 -10 8 1016.77 39.21 -3 -7 -5 219.31 19.10 -7 10 -5 233.14 20.38 -3 -7 -5 186.52 19.35 -7 10 -5 215.56 12.32 -10 3 5 262.26 22.26 -10 3 5 242.96 20.03 7 -10 5 235.36 18.74 7 -10 5 258.06 20.49 3 7 5 261.77 14.27 -10 3 5 252.30 14.58 10 -3 -5 244.70 20.15 3 7 5 238.53 21.55 7 -10 5 226.74 21.45 -10 3 5 219.01 19.32 -3 -7 -5 220.95 18.57 7 -10 5 273.32 20.54 -7 10 -2 3790.38 82.50 -3 -7 -2 3897.37 82.01 3 7 2 3720.27 83.73 -10 3 2 3741.33 73.70 -10 3 2 3768.88 83.93 -3 -7 -2 3666.06 74.20 7 -10 2 3807.82 73.00 7 -10 2 3674.96 73.76 -10 3 2 3643.03 51.65 3 7 2 3748.89 48.66 10 -3 -2 3630.13 71.50 -3 -7 -2 3636.43 83.50 7 -10 2 3883.32 76.25 -10 3 2 3720.09 65.03 -3 -7 -2 3705.77 42.63 -7 10 -2 3903.01 81.78 -10 3 2 3729.84 76.28 10 -3 -2 3668.83 48.27 7 -10 2 3699.72 82.12 -3 -7 -2 3868.40 77.40 3 7 -1 110.82 11.19 10 -3 1 123.11 12.28 -10 3 -1 87.46 10.14 -3 -7 1 94.60 11.10 -7 10 1 69.22 12.24 -3 -7 1 76.79 12.30 -10 3 -1 108.45 12.51 7 -10 -1 120.02 12.35 -3 -7 1 102.60 12.86 -10 3 -1 98.18 8.51 3 7 -1 89.92 7.60 -10 3 -1 90.33 12.13 -7 10 1 99.21 13.44 7 -10 -1 96.95 13.53 -3 -7 1 119.09 10.52 7 -10 -1 106.55 13.25 -3 -7 1 120.11 14.18 10 -3 4 2005.88 43.76 -7 10 4 2006.78 63.30 -10 3 -4 2012.26 50.89 3 7 -4 2108.06 64.49 -10 3 -4 2122.51 50.50 7 -10 -4 2038.44 43.70 -10 3 -4 2035.19 64.22 -3 -7 4 2069.70 57.59 3 7 -4 2026.15 37.74 -10 3 -4 2050.89 40.77 3 7 -4 2006.49 52.20 -3 -7 4 2041.79 55.03 10 -3 4 1971.43 53.30 7 -10 -4 1956.30 57.58 -10 3 -4 1976.13 52.70 -7 10 4 2038.37 58.21 7 -10 -7 23.64 7.79 10 -3 7 21.76 4.37 -7 10 7 13.30 6.90 -10 3 -7 13.82 5.74 -3 -7 7 2.51 4.91 -10 3 -7 16.67 8.07 -7 10 7 8.72 4.95 -7 10 7 16.93 5.31 -10 3 -7 5.33 3.67 7 -10 -7 4.04 5.53 10 -3 7 14.40 6.11 3 7 -7 12.49 5.86 3 7 -7 12.47 5.45 -3 -7 7 6.86 3.59 -7 10 10 3.47 7.33 -10 3 -10 4.92 4.08 3 7 -10 1.69 6.20 -10 3 -10 5.23 7.32 -7 10 10 1.58 4.47 10 -3 10 2.18 3.39 -7 10 10 2.65 4.70 -10 3 -10 -2.88 4.19 3 7 -10 4.41 3.30 7 -10 -10 -4.94 7.18 10 -3 10 5.29 2.24 -3 -7 10 -4.69 5.59 -10 3 -10 -1.63 3.92 7 -10 -10 3.74 2.10 10 -3 13 530.49 27.20 -7 10 13 572.28 35.32 3 7 -13 540.23 27.04 -10 3 -13 551.07 28.07 -3 -7 13 540.03 34.65 3 7 -13 567.21 36.66 7 -10 -13 540.86 19.64 -7 10 13 589.70 36.91 7 -10 -13 544.80 34.42 3 7 -16 76.46 11.77 -10 3 -16 77.94 12.11 -7 10 16 102.10 15.26 -7 10 16 73.46 13.45 7 -10 -16 78.93 14.60 10 -3 16 71.92 10.35 3 7 -19 1199.99 47.06 2 8 18 362.91 24.57 10 -2 -18 332.71 23.75 -2 -8 -18 319.70 24.78 2 8 15 103.61 14.19 10 -2 -15 115.95 13.12 -8 10 -15 101.96 15.60 2 8 15 128.40 17.73 8 -10 12 1008.53 38.45 10 -2 -12 958.47 45.80 2 8 12 1087.71 47.42 2 8 12 982.94 36.31 -10 2 12 963.98 46.47 -2 -8 -12 984.69 46.26 10 -2 -12 1013.62 38.82 -8 10 -12 1009.51 36.97 2 8 12 935.94 41.58 -8 10 -12 1013.97 47.74 2 8 9 7.48 6.53 -8 10 -9 16.89 6.99 -8 10 -9 5.11 5.40 -10 2 9 15.58 6.35 -2 -8 -9 15.76 4.57 8 -10 9 14.17 5.15 8 -10 9 17.52 6.51 2 8 9 9.17 3.36 -8 10 -9 12.94 3.76 -2 -8 -9 8.13 5.20 10 -2 -9 9.16 6.52 -8 10 -6 448.17 27.44 2 8 6 399.06 27.93 8 -10 6 440.97 25.00 -10 2 6 414.28 26.58 10 -2 -6 428.56 22.42 8 -10 6 487.09 31.95 -10 2 6 466.74 30.38 8 -10 6 406.24 24.06 -10 2 6 438.01 17.21 2 8 6 468.71 21.73 -2 -8 -6 472.88 31.05 -8 10 -6 384.53 15.48 -2 -8 -6 454.84 27.72 2 8 6 428.71 16.79 10 -2 -6 442.74 27.40 -10 2 6 432.18 26.16 10 -2 -3 25.05 6.54 -2 -8 -3 24.20 8.50 -10 2 3 21.69 5.76 2 8 3 23.17 7.44 -8 10 -3 15.59 5.46 -10 2 3 8.24 4.91 -10 2 3 10.92 5.72 -2 -8 -3 10.35 5.76 8 -10 3 19.47 7.64 8 -10 3 10.94 5.20 -10 2 3 9.75 5.31 8 -10 3 24.90 7.62 -2 -8 -3 12.50 2.45 -10 2 3 17.74 3.53 2 8 3 19.77 5.01 8 -10 3 16.91 5.57 -2 -8 -3 22.75 6.25 10 -2 -3 17.17 4.44 2 8 3 12.47 4.17 8 -10 0 245.07 21.26 -10 2 0 265.07 20.15 -2 -8 0 282.94 22.16 -10 2 0 254.11 18.63 8 -10 0 281.66 19.67 -2 -8 0 249.18 20.35 2 8 0 250.26 14.77 -10 2 0 260.44 10.84 2 8 0 249.88 17.14 -8 10 0 272.93 23.28 -10 2 0 283.04 20.05 -2 -8 0 243.16 21.93 8 -10 0 234.33 18.79 -2 -8 0 253.61 15.09 10 -2 0 244.24 17.27 10 -2 3 262.88 15.80 -8 10 3 244.59 22.32 2 8 -3 311.03 25.10 -10 2 -3 260.61 20.48 8 -10 -3 264.27 17.36 -10 2 -3 280.34 18.14 -10 2 -3 281.55 24.13 -2 -8 3 216.94 19.41 -10 2 -3 270.55 11.92 2 8 -3 264.50 15.66 2 8 -3 290.10 20.03 -10 2 -3 252.72 19.48 -2 -8 3 280.34 23.92 -8 10 3 249.57 21.10 -2 -8 3 240.81 17.12 -10 2 -3 283.02 19.45 8 -10 -3 257.32 22.05 -10 2 -6 114.87 13.73 8 -10 -6 149.73 18.18 -8 10 6 131.85 17.63 -10 2 -6 116.14 13.05 2 8 -6 102.73 15.38 -10 2 -6 128.81 11.66 -10 2 -6 128.74 16.55 -10 2 -6 129.47 9.77 -2 -8 6 119.14 14.58 -10 2 -6 120.82 12.65 8 -10 -6 127.44 15.29 10 -2 6 125.74 9.05 2 8 -6 126.65 14.58 -10 2 -9 621.41 27.10 2 8 -9 558.24 35.42 10 -2 9 648.92 28.24 -8 10 9 619.00 34.31 -10 2 -9 641.33 37.57 -10 2 -9 624.75 24.15 -2 -8 9 672.54 36.39 2 8 -9 648.18 37.49 -10 2 -9 636.41 27.66 8 -10 -9 568.87 34.97 10 -2 12 793.66 30.88 -10 2 -12 752.40 41.95 -8 10 12 799.96 40.88 -10 2 -12 772.24 30.25 2 8 -12 804.70 34.38 -2 -8 12 755.25 41.00 8 -10 -12 892.50 45.04 -8 10 12 808.99 43.51 2 8 -15 39.01 8.61 10 -2 15 36.47 7.16 8 -10 -15 18.65 8.17 -8 10 15 30.70 10.08 2 8 -18 57.66 10.84 10 -1 -16 150.77 14.57 1 9 16 137.33 16.24 1 9 13 35.91 8.44 -9 10 -13 36.18 8.98 9 -10 13 50.53 12.59 1 9 13 50.52 11.83 -10 1 13 49.34 9.14 -1 -9 -13 38.01 10.60 9 -10 13 49.47 7.86 -10 1 13 42.11 9.76 10 -1 -13 51.09 11.27 9 -10 10 11.08 4.49 -10 1 10 8.31 6.44 1 9 10 16.39 3.10 -10 1 10 18.04 5.25 1 9 10 20.68 6.25 10 -1 -10 20.74 7.84 1 9 10 12.74 6.17 -9 10 -10 24.36 7.06 -1 -9 -10 13.56 4.50 10 -1 -10 7.39 4.68 -1 -9 -10 9.79 4.32 -1 -9 -7 -3.11 6.18 1 9 7 8.08 5.21 -9 10 -7 7.80 5.04 1 9 7 10.34 3.56 9 -10 7 10.43 5.85 -10 1 7 6.62 7.59 9 -10 7 3.49 5.41 -10 1 7 9.63 3.63 1 9 7 4.84 3.78 10 -1 -7 11.47 5.46 9 -10 7 5.10 3.71 -10 1 7 11.66 5.94 1 9 4 1939.54 62.99 -9 10 -4 1912.43 58.54 -10 1 4 1931.66 54.38 9 -10 4 1982.07 51.37 10 -1 -4 1923.49 43.50 9 -10 4 2022.62 64.79 -1 -9 -4 1960.89 30.83 9 -10 4 1999.18 58.22 -10 1 4 1959.22 63.56 9 -10 4 2022.85 50.91 1 9 4 1971.66 47.02 10 -1 -4 1957.01 54.40 1 9 4 2056.65 44.94 -10 1 4 1979.89 52.73 -1 -9 -4 1976.13 61.57 -10 1 4 1981.90 56.24 -9 10 -1 19.77 6.31 10 -1 -1 19.93 3.82 9 -10 1 14.21 5.55 9 -10 1 17.74 6.10 1 9 1 12.38 4.72 1 9 1 21.30 5.06 -10 1 1 12.50 4.00 -1 -9 -1 16.63 6.56 -1 -9 -1 13.82 4.18 9 -10 1 11.21 6.41 -10 1 1 12.29 5.63 -10 1 -2 871.57 42.94 9 -10 -2 890.03 34.03 -1 -9 2 885.99 32.21 -10 1 -2 861.20 33.33 1 9 -2 882.62 31.15 1 9 -2 911.41 35.88 -10 1 -2 892.67 38.45 -10 1 -2 866.76 37.21 -1 -9 2 857.28 41.14 -9 10 2 898.09 42.71 1 9 -2 918.22 44.06 9 -10 -2 836.23 40.92 -9 10 5 630.69 37.32 -10 1 -5 554.40 30.69 1 9 -5 601.10 31.33 -10 1 -5 583.83 29.40 1 9 -5 613.66 36.01 -10 1 -5 600.62 36.08 -10 1 -5 557.73 12.26 9 -10 -5 621.39 35.13 9 -10 -5 568.83 34.66 -10 1 -5 585.52 26.05 -1 -9 5 683.24 31.74 9 -10 -8 1529.82 58.60 -10 1 -8 1593.82 58.96 -9 10 8 1552.85 52.14 -10 1 -8 1659.38 41.68 -1 -9 8 1595.00 52.24 9 -10 -8 1548.30 49.92 -10 1 -8 1618.12 54.84 1 9 -8 1600.93 58.64 -9 10 8 1572.69 60.22 -10 1 -8 1566.58 45.86 -1 -9 11 345.81 27.01 9 -10 -11 304.89 26.37 1 9 -11 280.41 25.11 -1 -9 11 311.23 26.18 -9 10 11 302.02 24.78 -10 1 -11 303.13 26.85 -9 10 14 -3.98 8.06 1 9 -14 -1.37 5.73 -9 10 14 -1.70 7.35 1 9 -17 251.97 21.96 0 10 17 30.68 8.82 10 0 -14 390.60 28.97 0 -10 -14 373.55 28.76 0 10 14 402.08 29.16 -10 10 -14 419.97 31.37 10 0 -11 740.08 36.50 10 -10 11 761.13 43.59 10 -10 11 829.57 32.61 0 -10 -11 716.45 31.00 -10 0 11 707.07 39.49 0 -10 -11 795.87 40.50 0 10 11 769.44 40.71 -10 10 -11 835.82 34.38 -10 10 -11 768.45 41.79 10 -10 8 199.57 15.83 0 10 8 171.64 16.38 -10 0 8 183.58 13.97 -10 0 8 211.93 20.66 0 10 8 183.02 12.86 0 -10 -8 157.88 18.48 0 10 8 174.90 20.29 -10 10 -8 177.76 17.17 10 0 -8 156.35 15.66 0 10 5 108.43 16.14 -10 10 -5 108.97 14.88 -10 0 5 133.60 14.34 -10 0 5 121.05 14.48 10 -10 5 142.30 17.98 0 -10 -5 135.31 16.55 0 10 5 111.53 11.31 0 10 5 121.34 12.69 10 -10 5 128.95 12.82 10 0 -5 165.70 14.34 -10 0 5 129.60 15.39 -10 0 2 1010.63 35.43 0 10 2 1045.11 36.58 -10 0 2 1008.33 39.17 0 10 2 1084.62 37.24 -10 0 2 948.22 45.71 0 -10 -2 996.45 43.60 10 0 -2 1017.45 29.59 -10 0 2 1031.80 43.07 10 -10 2 995.92 35.46 -10 10 -2 1098.60 46.31 10 -10 2 1053.13 47.43 0 -10 -2 983.64 29.94 -10 0 2 920.33 35.98 10 -10 -1 344.10 27.12 -10 0 -1 339.69 27.33 10 -10 -1 327.56 21.96 -10 0 -1 377.68 21.96 0 -10 1 346.75 20.69 0 10 -1 374.45 22.25 -10 0 -1 375.41 22.07 0 10 -1 418.67 24.65 -10 0 -1 335.54 24.79 10 -10 -1 407.38 24.11 0 -10 1 382.11 27.52 -10 10 1 372.45 28.52 0 10 -1 359.64 28.05 10 -10 -1 358.01 27.87 -10 10 4 1076.94 49.10 0 10 -4 1087.81 48.80 -10 0 -4 1026.75 33.46 0 -10 4 1016.57 38.79 0 10 -4 1039.10 37.25 -10 0 -4 1083.08 45.10 -10 0 -4 1071.31 32.93 10 -10 -4 971.92 45.52 -10 0 -4 1051.36 48.57 -10 10 7 126.23 14.72 10 -10 -7 144.75 15.18 -10 0 -7 126.71 16.64 -10 0 -7 128.04 14.48 -10 10 7 140.30 19.38 0 10 -7 121.51 16.74 0 -10 7 134.46 15.52 -10 0 -7 136.92 17.76 -10 10 10 75.56 12.20 -10 0 -10 92.37 15.43 -10 0 -10 61.99 12.47 10 -10 -10 79.94 14.19 0 -10 10 105.68 15.11 -10 10 10 88.46 15.85 0 10 -10 87.03 14.46 -10 10 13 881.50 42.25 -10 0 -13 824.67 43.79 0 -10 13 947.00 46.09 0 10 -16 116.71 16.02 -11 10 15 8.18 6.34 1 -11 12 60.82 12.65 -1 11 -12 55.21 11.90 -10 -1 -12 63.16 11.72 -11 10 12 52.77 10.57 -11 10 9 1980.74 56.86 1 -11 9 1983.81 63.33 -10 -1 -9 1960.56 67.15 -10 -1 -9 2012.66 67.82 -1 11 -9 1898.40 65.37 -11 10 9 1925.43 70.42 -10 -1 -6 70.58 13.36 -10 -1 -6 54.79 12.52 11 -10 -6 57.37 11.73 11 -10 -6 59.68 9.66 -11 10 6 63.36 13.85 -1 11 -6 57.85 12.71 1 -11 6 43.53 8.97 11 -10 -3 1299.20 54.30 -10 -1 -3 1368.98 55.78 1 -11 3 1248.12 43.44 -1 11 -3 1309.73 44.36 11 -10 -3 1308.15 39.49 -10 -1 -3 1319.72 36.71 -10 -1 -3 1233.42 50.17 11 -10 -3 1290.90 53.87 -11 10 3 1390.44 56.27 -1 11 -3 1347.80 55.73 11 -10 0 65.88 12.27 1 -11 0 71.92 12.23 -10 -1 0 84.25 13.98 -1 11 0 82.05 11.51 -1 11 0 83.95 14.44 -11 10 0 105.27 15.52 -1 11 0 79.74 12.12 -10 -1 0 77.99 13.38 -10 -1 0 89.92 11.55 -1 11 0 87.52 11.67 11 -10 0 85.91 10.75 11 -10 0 67.83 13.57 1 -11 0 73.62 10.07 -11 10 -3 444.27 29.99 10 1 -3 427.14 21.63 1 -11 -3 399.39 27.23 -10 -1 3 459.52 30.88 -10 -1 3 534.80 26.85 -1 11 3 475.21 26.48 -10 -1 3 474.20 26.15 1 -11 -3 478.66 21.88 11 -10 3 449.21 22.29 -10 -1 3 438.44 26.69 -1 11 3 439.26 24.83 -10 -1 3 417.12 31.02 -1 11 3 495.51 27.33 -10 -1 6 888.78 40.50 -1 11 6 834.72 32.19 1 -11 -6 878.02 40.59 10 1 -6 827.19 34.08 11 -10 6 789.18 28.14 -1 11 6 808.90 43.72 -11 10 -6 811.02 38.14 -1 11 6 886.72 34.01 -10 -1 9 8.20 6.44 11 -10 9 3.82 5.80 -11 10 -9 7.54 5.42 -1 11 9 5.49 7.28 -1 11 9 8.72 4.40 10 1 -9 4.00 4.59 1 -11 -9 9.16 6.11 1 -11 -12 730.98 38.39 10 1 -12 787.26 39.39 -11 10 -12 807.48 43.15 -1 11 12 805.06 43.09 -11 9 16 392.28 28.19 2 -11 13 387.10 30.36 -2 11 -13 418.70 29.73 -11 9 13 311.69 23.84 -9 -2 -13 407.33 29.98 -11 9 10 211.46 18.21 2 -11 10 180.24 19.73 11 -9 -10 182.62 16.47 -9 -2 -10 188.80 20.22 -9 -2 -10 165.87 19.93 -11 9 10 166.42 20.60 -2 11 -10 202.31 20.99 -9 -2 -7 6.91 6.37 -9 -2 -7 5.14 4.73 -11 9 7 3.16 3.69 2 -11 7 15.01 7.14 11 -9 -7 -0.99 4.23 -11 9 7 -3.80 7.75 -2 11 -7 8.60 4.75 11 -9 -7 1.81 4.85 -9 -2 -4 1142.04 49.57 -2 11 -4 1146.00 47.46 11 -9 -4 1111.56 49.02 2 -11 4 1111.97 42.87 11 -9 -4 1118.23 34.48 -9 -2 -4 1102.91 29.12 -9 -2 -4 1077.55 47.46 -2 11 -4 1087.37 48.82 -11 9 4 1025.44 48.10 11 -9 -4 1064.52 48.28 -9 -2 -1 54.99 11.97 -2 11 -1 22.66 7.80 -11 9 1 36.63 9.12 -2 11 -1 29.61 8.10 -9 -2 -1 6.87 7.12 -9 -2 -1 31.02 6.32 11 -9 -1 30.16 6.02 -2 11 -1 58.35 10.31 11 -9 -1 27.40 8.65 -9 -2 -1 41.17 7.39 11 -9 -1 29.25 9.33 2 -11 1 24.13 7.32 -9 -2 2 1845.49 47.52 2 -11 -2 1811.78 46.77 -9 -2 2 1826.24 44.98 -2 11 2 1880.43 54.18 -2 11 2 1879.19 53.18 -9 -2 2 1806.32 50.41 -2 11 2 1899.27 55.74 -9 -2 2 1927.06 62.57 2 -11 -2 1888.14 56.15 11 -9 2 1886.00 42.07 -9 -2 2 2071.11 49.90 11 -9 2 1856.69 60.08 -2 11 2 1774.94 63.08 -11 9 -2 1855.36 60.04 2 -11 -5 70.78 11.83 -2 11 5 69.76 10.35 -9 -2 5 82.13 11.26 -9 -2 5 73.67 11.88 -9 -2 5 57.18 9.28 2 -11 -5 64.70 8.54 11 -9 5 92.18 15.30 -2 11 5 87.22 11.66 -9 -2 5 78.46 11.35 -11 9 -5 100.72 14.20 9 2 -5 78.75 10.93 11 -9 5 71.63 7.76 -11 9 -8 1475.33 47.50 -2 11 8 1456.76 57.22 2 -11 -8 1401.29 48.91 -2 11 8 1335.09 40.88 -9 -2 8 1246.79 49.41 -9 -2 8 1438.64 47.89 11 -9 8 1438.61 30.03 11 -9 8 1260.24 53.82 9 2 -8 1426.06 48.85 -2 11 8 1321.85 41.82 -2 11 11 219.49 22.44 2 -11 -11 214.92 19.13 -9 -2 11 213.74 18.21 2 -11 -11 192.86 18.76 -9 -2 11 214.10 22.26 -2 11 11 212.00 15.79 11 -9 11 220.18 22.76 9 2 -11 170.60 18.58 -9 -2 14 55.15 11.35 2 -11 -14 22.74 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1184.57 48.02 2 -12 -7 1147.08 45.98 10 2 -7 1095.98 41.71 -2 12 7 1116.90 39.97 -12 10 -7 1203.64 46.65 2 -12 -10 121.67 15.03 10 2 -10 125.75 15.61 -10 -2 10 140.35 17.82 2 -12 -10 131.04 16.13 2 -12 -13 73.30 12.18 12 -9 -12 27.95 8.86 -3 12 -12 25.86 9.12 -9 -3 -12 24.46 8.56 3 -12 9 373.45 28.62 -9 -3 -9 377.79 29.53 12 -9 -9 359.40 25.48 -3 12 -9 422.75 30.92 12 -9 -6 191.24 21.49 -3 12 -6 243.20 23.46 -12 9 6 216.37 23.99 3 -12 6 165.24 18.60 -9 -3 -6 212.33 23.01 -3 12 -6 176.54 20.33 -9 -3 -6 176.94 20.48 -3 12 -3 17.98 7.49 -9 -3 -3 21.46 9.15 3 -12 3 13.90 5.93 12 -9 -3 3.47 8.00 -9 -3 -3 17.93 8.64 -3 12 -3 9.18 5.39 -12 9 3 7.39 5.10 -3 12 0 786.49 38.85 -12 9 0 784.79 41.85 -3 12 0 721.60 41.51 -9 -3 0 727.34 29.74 12 -9 0 750.58 39.71 3 -12 0 747.03 33.99 12 -9 0 729.58 26.18 -9 -3 0 709.57 40.10 -9 -3 0 725.96 40.80 -3 12 3 82.38 12.47 -9 -3 3 98.06 12.56 12 -9 3 95.93 16.23 3 -12 -3 100.26 11.86 12 -9 3 100.72 14.67 -12 9 -3 122.63 16.06 -3 12 3 105.95 16.07 -9 -3 3 112.72 16.42 3 -12 -3 111.26 14.04 -12 9 -6 200.01 19.31 -9 -3 6 200.96 19.12 12 -9 6 189.73 22.05 12 -9 6 213.20 20.22 3 -12 -6 208.81 18.68 9 3 -6 213.10 19.07 -3 12 6 186.62 17.54 -3 12 6 162.52 20.03 -9 -3 9 363.14 27.39 -3 12 9 348.50 23.15 12 -9 9 327.43 28.43 12 -9 9 359.13 25.79 9 3 -9 355.30 26.58 3 -12 -9 368.04 24.94 9 3 -12 1.68 6.53 -12 9 -12 3.41 7.23 3 -12 -12 16.41 6.68 3 -12 -12 6.00 4.70 3 -12 -15 204.18 20.22 12 -8 -13 41.17 11.07 -4 12 -13 54.64 10.83 -8 -4 -13 28.95 7.81 -12 8 13 42.78 8.48 -12 8 10 2764.29 67.08 4 -12 10 2788.88 79.98 -8 -4 -10 2674.95 74.38 -4 12 -10 2788.24 76.91 12 -8 -10 2886.11 72.25 -12 8 7 164.51 17.93 4 -12 7 174.49 19.88 12 -8 -7 178.13 20.39 -4 12 -7 176.92 20.87 -8 -4 -7 175.72 19.72 -8 -4 -7 201.55 22.60 -4 12 -7 174.02 19.84 12 -8 -7 183.75 17.14 -4 12 -4 469.21 32.25 -8 -4 -4 495.53 32.86 -12 8 4 494.32 30.84 4 -12 4 426.38 28.93 12 -8 -4 503.99 32.99 -8 -4 -4 448.92 32.70 -4 12 -4 467.77 32.87 12 -8 -4 427.83 22.86 4 -12 1 153.74 17.06 12 -8 -1 139.42 11.24 12 -8 -1 154.73 18.69 -8 -4 -1 151.66 12.82 12 -8 -1 164.96 18.69 -8 -4 -1 160.18 19.91 -4 12 -1 180.36 20.27 -4 12 -1 175.44 19.24 -12 8 -2 118.62 15.23 -4 12 2 88.46 14.08 -4 12 2 86.92 13.49 -8 -4 2 93.27 12.21 12 -8 2 94.24 7.19 4 -12 -2 87.40 11.88 12 -8 2 78.15 13.00 -8 -4 2 101.07 11.93 12 -8 2 95.12 13.28 12 -8 2 93.53 6.85 -8 -4 2 86.57 13.66 -8 -4 5 3299.16 72.29 -4 12 5 3389.14 77.55 -8 -4 5 3303.92 73.87 -8 -4 5 3354.18 70.80 12 -8 5 3327.39 75.82 8 4 -5 3327.70 74.16 4 -12 -5 3410.13 68.32 4 -12 -5 3310.48 67.30 12 -8 5 3272.07 84.88 -12 8 -5 3306.70 76.94 8 4 -8 104.33 14.37 12 -8 8 106.47 16.46 -8 -4 8 137.58 16.59 4 -12 -8 112.64 12.98 12 -8 8 141.29 15.53 8 4 -8 141.69 16.59 -12 8 -8 123.09 14.22 -4 12 8 99.38 16.51 12 -8 11 1035.69 48.42 -8 -4 11 1126.98 49.85 4 -12 -11 1094.60 40.13 8 4 -11 1088.47 48.15 12 -8 11 1102.72 40.85 4 -12 -11 1029.43 45.71 8 4 -11 1025.43 47.45 4 -12 -14 72.87 11.22 -12 8 -14 85.36 13.60 4 -12 -14 82.47 14.13 -12 7 14 199.39 17.79 12 -7 -14 201.28 21.75 -5 12 -14 197.64 19.02 5 -12 11 320.19 27.77 -5 12 -11 373.46 27.76 12 -7 -11 361.40 25.86 -12 7 11 381.63 25.73 -7 -5 -11 344.42 26.06 -5 12 -8 7.50 4.75 -7 -5 -8 35.35 8.88 -12 7 8 34.63 9.17 5 -12 8 17.56 7.85 -7 -5 -8 13.41 6.53 -5 12 -8 13.11 7.96 12 -7 -8 14.25 7.31 12 -7 -8 27.48 6.50 12 -7 -5 1907.01 62.98 -5 12 -5 1967.87 64.66 -7 -5 -5 2085.11 69.87 -5 12 -5 1962.28 66.56 -7 -5 -5 1997.40 62.82 -12 7 5 2064.51 63.03 -12 7 5 1994.08 54.28 5 -12 5 2085.17 64.92 12 -7 -5 2081.71 49.46 -5 12 -2 22.76 8.06 -5 12 -2 8.36 4.96 -12 7 2 19.44 8.10 5 -12 2 13.34 6.33 -12 7 2 20.63 7.43 -7 -5 -2 18.13 8.92 -7 -5 -2 19.91 5.16 12 -7 -2 21.19 4.81 12 -7 -2 19.65 7.86 12 -7 1 82.17 12.52 -7 -5 1 69.09 9.43 -5 12 1 91.93 14.97 7 5 -1 72.41 9.82 -5 12 1 69.87 12.34 -12 7 -1 109.66 17.23 -7 -5 1 59.86 8.96 5 -12 -1 75.63 11.68 12 -7 1 81.89 14.51 -12 7 -1 73.48 11.06 -7 -5 1 67.13 12.83 -7 -5 1 83.92 10.88 12 -7 1 63.12 4.91 -7 -5 1 81.64 11.38 12 -7 1 67.41 4.86 -7 -5 4 156.95 15.47 12 -7 4 175.47 17.30 -7 -5 4 152.12 15.01 -5 12 4 157.37 19.29 7 5 -4 177.95 16.32 -7 -5 4 177.12 16.32 -7 -5 4 158.37 16.43 -12 7 -4 158.69 16.01 -7 -5 4 140.63 18.63 5 -12 -4 162.97 16.52 -7 -5 4 156.94 15.71 12 -7 4 164.76 18.85 7 5 -7 98.15 14.42 12 -7 7 112.46 13.37 12 -7 7 101.80 15.03 5 -12 -7 97.05 12.90 -7 -5 7 114.30 14.78 -5 12 7 109.12 12.53 5 -12 -7 117.45 11.93 -12 7 -7 120.14 14.94 7 5 -7 142.50 17.09 12 -7 10 1413.56 54.43 -5 12 10 1367.91 43.55 -7 -5 10 1424.58 54.79 5 -12 -10 1400.28 40.84 7 5 -10 1348.23 54.06 12 -7 10 1347.36 42.68 5 -12 -10 1295.65 52.13 7 5 -10 1498.69 56.02 -5 12 10 1390.54 58.50 5 -12 -13 5.19 4.43 5 -12 -13 11.79 8.05 -12 7 -13 7.07 6.70 12 -7 13 5.05 5.38 -12 6 15 8.22 5.28 12 -6 -15 6.79 4.75 -6 12 -12 66.55 12.23 12 -6 -12 46.80 8.61 -12 6 12 63.57 12.22 -6 -6 -12 61.00 11.42 12 -6 -9 770.59 34.67 6 -12 9 753.61 41.97 -6 12 -9 781.67 39.44 12 -6 -9 799.61 42.61 -6 -6 -9 760.56 36.75 -12 6 9 785.24 38.74 -6 -6 -9 752.58 43.29 -6 -6 -6 44.82 11.84 12 -6 -6 44.02 10.49 -6 12 -6 53.00 13.58 -6 -6 -6 38.38 8.93 -12 6 6 54.97 11.52 6 -12 6 68.66 12.31 -6 12 -6 52.18 10.39 12 -6 -6 57.11 8.79 -6 -6 -6 44.97 8.88 -6 -6 -3 94.90 15.38 12 -6 -3 94.49 13.72 -6 12 -3 124.35 17.24 -6 12 -3 118.54 16.59 -12 6 3 139.37 17.66 6 -12 3 122.81 16.11 -12 6 3 111.37 12.47 12 -6 -3 127.19 10.26 -6 -6 -3 125.54 14.29 -6 12 0 -7.09 5.14 6 6 0 2.64 3.93 -12 6 0 8.60 6.93 6 -12 0 3.29 4.58 -6 -6 0 9.00 5.35 6 -12 0 4.42 6.56 -12 6 0 2.01 4.44 -6 -6 0 3.65 3.27 12 -6 0 2.67 4.05 -6 -6 0 -1.86 3.97 -6 -6 0 -5.47 4.47 12 -6 0 4.58 1.47 12 -6 0 2.97 1.45 -6 -6 3 155.29 20.13 12 -6 3 160.58 16.06 -6 -6 3 146.33 14.91 -6 -6 3 158.48 14.99 -6 12 3 113.45 16.65 6 6 -3 132.72 13.86 -6 -6 3 156.12 15.40 -12 6 -3 120.87 16.33 -12 6 -3 160.05 14.79 -6 -6 3 154.93 15.03 12 -6 3 146.41 17.65 6 -12 -3 165.56 17.05 6 -12 -6 986.12 40.71 12 -6 6 991.87 44.12 -6 -6 6 937.20 40.55 12 -6 6 909.60 35.00 6 6 -6 1028.02 45.20 6 6 -6 967.31 40.62 -6 12 6 904.00 46.58 6 -12 -9 112.61 9.83 12 -6 9 98.72 14.60 -6 -6 9 100.21 14.68 6 6 -9 121.61 16.08 -12 6 -9 86.92 11.25 -6 12 9 59.97 13.49 6 6 -9 103.86 14.94 12 -6 9 96.47 10.67 6 -12 -9 99.09 15.43 -6 -6 12 53.83 12.74 6 6 -12 74.00 13.60 6 6 -12 65.25 12.42 12 -6 12 94.51 14.11 6 -12 -12 97.24 15.17 12 -6 15 -3.14 6.16 -12 5 16 124.34 15.94 12 -5 -13 -1.50 5.93 -12 5 13 9.24 5.68 7 -12 10 203.31 22.53 5 7 10 188.71 19.77 -12 5 10 176.31 19.52 -5 -7 -10 166.63 16.57 12 -5 -10 198.24 21.53 12 -5 -10 182.76 17.49 -7 12 -10 189.61 18.90 7 -12 7 201.74 21.84 5 7 7 225.66 21.89 -12 5 7 232.29 21.88 -5 -7 -7 261.88 21.48 12 -5 -7 220.07 21.85 12 -5 -7 230.00 16.75 -7 12 -7 220.65 21.29 -7 12 -4 153.22 18.68 5 7 4 149.65 18.58 -12 5 4 151.54 18.30 5 7 4 137.09 9.55 -7 12 -4 124.88 17.47 -5 -7 -4 141.64 15.27 7 -12 4 146.31 17.97 12 -5 -4 135.61 16.27 -7 12 -1 95.71 14.97 -5 -7 -1 92.54 12.92 -12 5 1 95.70 14.49 7 -12 1 84.67 11.36 7 -12 1 106.53 14.50 5 7 1 95.38 10.02 12 -5 -1 87.97 5.15 12 -5 -1 117.66 14.61 5 7 -2 36.44 8.25 -12 5 -2 38.07 9.17 7 -12 -2 30.13 8.94 -5 -7 2 23.30 6.04 12 -5 2 35.40 7.75 -5 -7 2 19.00 5.13 -12 5 -2 37.27 7.30 -5 -7 2 51.67 12.30 -7 12 2 63.32 12.38 -5 -7 5 799.16 35.68 12 -5 5 783.73 38.15 7 -12 -5 779.03 37.90 -5 -7 5 819.03 37.31 12 -5 5 827.14 31.91 -12 5 -5 820.74 31.33 -7 12 5 788.61 43.08 5 7 -5 818.26 36.95 -12 5 -5 814.25 35.26 5 7 -8 144.82 17.51 -5 -7 8 191.37 19.58 -12 5 -8 170.44 15.67 7 -12 -8 172.75 20.24 12 -5 8 174.15 13.29 7 -12 -8 167.16 17.54 5 7 -8 124.84 17.14 12 -5 8 194.39 18.93 -12 5 -8 147.77 19.32 -7 12 11 13.36 7.49 -5 -7 11 12.21 6.48 5 7 -11 -1.71 5.68 5 7 -11 20.68 7.94 12 -5 11 8.55 6.89 7 -12 -11 9.20 7.50 12 -5 14 435.20 28.14 12 -4 -14 142.16 17.60 4 8 14 166.60 18.47 -12 4 14 154.67 18.08 12 -4 -11 992.83 48.18 -8 12 -11 963.66 41.41 -12 4 11 936.62 44.74 4 8 11 985.77 44.82 -4 -8 -8 9.91 5.49 -12 4 8 17.07 7.56 8 -12 8 7.65 5.75 12 -4 -8 36.41 10.95 -4 -8 -8 15.20 6.59 4 8 8 18.39 7.81 -8 12 -8 10.64 6.66 -8 12 -8 44.65 11.52 4 8 5 2320.75 70.80 12 -4 -5 2243.42 64.62 -8 12 -5 2348.56 69.34 -4 -8 -5 2372.29 74.21 -12 4 5 2372.04 72.19 4 8 5 2289.96 36.49 12 -4 -5 2311.58 47.20 8 -12 5 2264.57 71.92 -8 12 -2 104.40 16.57 4 8 2 65.82 12.63 4 8 2 100.12 10.34 -12 4 2 100.10 15.33 4 8 2 93.53 6.22 12 -4 -2 84.86 6.17 12 -4 -2 109.02 13.66 -4 -8 -2 104.53 15.64 8 -12 2 66.29 12.38 8 -12 -1 472.64 31.04 -12 4 -1 604.82 37.79 8 -12 -1 519.61 26.68 -4 -8 1 503.48 26.65 4 8 -1 539.28 14.42 -12 4 -1 513.66 25.55 -8 12 1 591.36 36.67 12 -4 1 536.08 27.60 -12 4 -4 16.17 5.62 -12 4 -4 15.03 5.46 -4 -8 4 16.05 5.02 -4 -8 4 15.65 5.54 8 -12 -4 26.77 9.63 4 8 -4 15.73 3.15 4 8 -4 22.96 3.72 -8 12 4 28.16 8.65 12 -4 4 8.30 3.12 -12 4 -7 491.76 35.11 4 8 -7 441.63 17.70 -4 -8 7 423.70 28.82 8 -12 -7 370.78 29.56 12 -4 7 379.67 18.22 -12 4 -7 405.95 25.11 -8 12 7 390.13 31.15 12 -4 7 433.45 26.90 8 -12 -7 420.71 28.71 -4 -8 10 1826.37 63.14 4 8 -10 1693.95 64.29 -12 4 -10 1761.57 54.66 12 -4 10 1788.74 54.21 4 8 -10 1837.37 40.95 -8 12 10 1785.66 64.30 12 -4 13 26.81 7.62 3 9 15 188.03 20.15 -12 3 12 71.23 13.42 3 9 12 53.33 11.40 3 9 9 55.33 11.78 -9 12 -9 73.10 12.59 12 -3 -9 67.93 12.41 -12 3 9 80.90 13.85 12 -3 -9 47.46 8.32 -3 -9 -9 62.92 13.88 3 9 6 371.49 29.35 12 -3 -6 403.22 27.70 -9 12 -6 362.27 27.21 -3 -9 -6 423.36 31.61 3 9 6 376.61 15.12 -12 3 6 374.82 29.37 12 -3 -6 408.37 21.05 9 -12 6 438.25 32.86 -12 3 3 27.65 8.92 3 9 3 20.02 7.77 -9 12 -3 13.55 7.11 12 -3 -3 24.86 6.75 9 -12 3 19.89 9.64 12 -3 -3 17.74 3.84 -3 -9 -3 25.67 9.63 12 -3 0 1224.40 41.08 3 9 0 1179.43 29.25 -12 3 0 1232.75 42.60 -3 -9 0 1250.51 53.51 9 -12 0 1176.56 50.76 -9 12 0 1266.64 53.64 9 -12 0 1204.92 42.44 -12 3 0 1198.38 53.44 -9 12 3 131.59 18.32 3 9 -3 140.44 19.26 12 -3 3 108.51 11.00 9 -12 -3 113.44 16.01 -3 -9 3 118.51 12.19 -3 -9 3 140.66 19.23 -12 3 -3 93.50 12.32 -9 12 6 290.26 27.37 -12 3 -6 310.50 22.93 9 -12 -6 340.32 27.27 -12 3 -6 353.62 29.59 -3 -9 6 331.95 22.73 3 9 -6 345.02 29.24 12 -3 6 312.96 15.63 9 -12 -6 285.61 26.75 -12 3 -9 22.91 7.90 -3 -9 9 35.69 8.77 3 9 -9 21.65 5.08 -12 3 -12 80.60 12.34 12 -3 12 59.70 9.75 12 -2 -13 84.45 12.62 12 -2 -10 36.32 8.59 -2 -10 -7 217.82 22.87 -12 2 7 199.98 22.40 12 -2 -7 215.98 16.62 2 10 7 203.70 22.40 -10 12 -7 203.17 20.31 12 -2 -4 451.59 19.30 -2 -10 -4 458.13 32.42 -12 2 4 511.57 35.04 10 -12 4 454.69 33.02 -10 12 -4 511.71 33.29 2 10 4 500.78 34.69 -2 -10 -1 118.58 16.66 -12 2 1 78.20 11.91 -10 12 -1 80.41 14.47 2 10 1 117.52 12.41 10 -12 1 105.14 16.84 -12 2 -2 49.18 12.06 -2 -10 2 52.00 11.69 -12 2 -2 42.34 8.64 -10 12 2 58.45 12.36 2 10 -2 46.42 12.68 10 -12 -2 70.46 12.83 -12 2 -5 27.18 7.86 -10 12 5 27.75 8.87 2 10 -5 31.39 10.04 -2 -10 5 18.82 6.74 10 -12 -5 5.39 4.96 -2 -10 8 36.78 7.70 -12 2 -8 32.29 9.35 2 10 -11 49.61 9.16 -10 12 11 46.86 10.24 -12 2 -11 31.47 10.10 -2 -10 11 52.41 11.86 12 -1 -11 10.92 4.10 -12 1 8 -6.94 7.99 -11 12 -8 -6.05 6.06 -1 -11 -5 711.95 40.34 -11 12 -5 712.49 38.79 -12 1 5 704.72 37.38 -12 1 2 19.31 6.76 -1 -11 -2 23.42 9.97 -12 1 2 15.01 5.97 -11 12 -2 17.84 8.02 -1 -11 1 25.63 8.67 -12 1 -1 21.25 7.44 -11 12 1 9.50 6.64 -12 1 -4 1.56 5.15 -12 1 -7 97.08 14.25 -1 -11 7 138.80 16.11 -1 -11 10 244.56 23.06 -12 12 -6 817.51 41.25 -12 0 6 712.31 38.12 0 -12 -3 1.77 6.48 -12 12 -3 10.70 7.86 -12 0 3 12.64 6.35 -12 0 0 2765.01 76.65 -12 0 -3 1.71 5.31 2 -13 -3 731.32 38.11 -2 13 3 694.70 35.03 -13 11 -3 675.91 39.11 -2 13 6 28.42 6.86 -11 -2 6 25.99 7.33 -13 11 -6 22.32 7.24 2 -13 -6 32.52 8.05 2 -13 -9 402.58 28.85 13 -10 -10 247.28 21.99 3 -13 7 796.09 41.49 13 -10 -7 858.23 38.14 3 -13 4 39.06 10.32 -3 13 -4 19.57 5.96 13 -10 -1 754.98 41.80 -3 13 -1 681.93 38.15 3 -13 1 770.12 35.84 -13 10 1 791.61 44.14 -13 10 -2 323.08 27.26 13 -10 2 291.61 25.89 -3 13 2 286.69 23.66 -10 -3 5 7.02 5.48 -13 10 -5 -6.40 7.05 3 -13 -5 -1.37 4.39 -3 13 5 -2.78 4.90 13 -10 5 -1.64 4.47 -10 -3 8 11.32 5.70 3 -13 -8 4.16 4.30 -3 13 8 13.83 4.68 10 3 -8 11.36 4.84 13 -10 8 17.17 7.84 3 -13 -11 347.44 25.29 10 3 -11 354.93 26.81 13 -10 11 369.20 26.95 13 -9 -11 42.89 10.09 13 -9 -8 197.40 17.97 4 -13 8 240.93 23.40 -9 -4 -8 200.16 22.00 13 -9 -5 813.20 33.27 -9 -4 -5 845.21 44.59 -4 13 -5 801.11 44.06 4 -13 5 913.53 43.75 -4 13 -2 199.47 21.47 -13 9 2 186.61 21.51 4 -13 2 171.49 17.82 13 -9 -2 217.25 22.85 -9 -4 -2 178.75 20.59 4 -13 -1 91.04 12.66 -4 13 1 103.79 15.13 -9 -4 1 69.89 13.81 13 -9 1 69.13 12.34 -13 9 -1 47.67 10.68 -9 -4 4 41.53 9.12 -4 13 4 24.23 8.93 13 -9 4 24.73 7.88 -13 9 -4 41.71 9.81 13 -9 7 107.52 14.40 -9 -4 7 126.31 16.57 -13 9 -7 131.40 15.51 9 4 -7 95.83 14.49 -4 13 7 123.00 15.55 4 -13 -7 124.78 14.15 -4 13 10 556.30 30.51 9 4 -10 518.78 32.85 4 -13 -10 547.06 34.67 13 -9 10 557.61 31.02 13 -8 -12 -1.53 6.21 -8 -5 -12 3.28 5.09 -13 8 12 9.56 6.67 -5 13 -9 182.07 21.00 -13 8 9 194.46 19.91 -8 -5 -9 210.12 21.50 13 -8 -9 207.99 18.50 5 -13 6 258.90 23.83 -5 13 -6 271.79 25.67 13 -8 -6 282.73 26.09 13 -8 -6 252.98 18.37 -8 -5 -6 319.52 26.99 -13 8 6 252.62 22.82 -5 13 -3 25.40 7.53 -8 -5 -3 19.62 7.86 -13 8 3 13.55 7.58 5 -13 3 30.28 8.34 13 -8 -3 -1.70 5.04 -5 13 -3 15.17 7.25 13 -8 -3 11.58 4.33 -5 13 0 2833.40 78.26 -5 13 0 2879.20 83.81 -8 -5 0 2808.83 83.34 13 -8 0 2842.65 75.20 13 -8 0 2898.36 82.53 5 -13 0 2886.86 72.66 13 -8 3 1.46 4.94 5 -13 -3 7.89 5.13 13 -8 3 1.82 5.88 -8 -5 3 2.39 4.55 -8 -5 3 -3.95 6.56 -13 8 -3 -4.89 5.88 -5 13 3 6.51 5.64 -8 -5 6 193.14 18.77 13 -8 6 202.28 22.21 -13 8 -6 253.17 22.23 13 -8 6 200.71 18.67 8 5 -6 195.32 19.22 8 5 -9 142.74 18.36 13 -8 9 165.60 16.71 -8 -5 9 146.71 17.69 8 5 -9 178.37 18.98 13 -7 -13 34.15 8.86 -13 7 13 53.62 10.61 -6 13 -10 221.12 21.77 -13 7 10 236.63 22.29 -7 -6 -10 251.58 22.41 13 -7 -10 257.04 20.39 6 -13 7 724.29 41.37 -6 13 -7 746.77 40.80 13 -7 -7 726.31 41.09 13 -7 -7 772.58 31.92 -7 -6 -7 707.01 38.19 -13 7 7 788.82 40.39 -6 13 -4 33.91 9.19 -7 -6 -4 33.66 10.73 -13 7 4 32.69 8.40 6 -13 4 29.07 9.24 -6 13 -4 45.77 11.26 13 -7 -4 40.52 6.65 13 -7 -4 39.78 9.41 13 -7 -1 722.08 37.43 -6 13 -1 666.68 40.27 -7 -6 -1 694.65 41.89 -13 7 1 815.33 43.17 -6 13 -1 632.72 38.40 6 -13 1 710.25 37.64 -13 7 -2 26.60 10.27 6 -13 -2 21.92 6.95 13 -7 2 36.71 11.22 -6 13 2 33.23 9.46 -7 -6 2 7.93 6.27 13 -7 2 35.94 8.23 7 6 -2 23.75 6.20 -7 -6 5 71.52 11.99 7 6 -5 63.46 10.53 13 -7 5 66.20 10.34 13 -7 5 55.16 12.12 6 -13 -5 68.55 11.34 -7 -6 8 285.14 23.82 13 -7 8 325.47 26.95 7 6 -8 256.06 23.16 7 6 -8 290.98 25.12 13 -7 8 271.14 19.91 13 -6 -14 3.15 6.58 -13 6 14 -3.10 5.10 -13 6 11 217.94 21.61 -7 13 -11 196.02 20.22 13 -6 -11 194.85 18.24 -7 13 -8 525.51 34.14 13 -6 -8 474.68 25.45 -6 -7 -8 491.16 30.38 -13 6 8 521.56 33.61 13 -6 -8 518.52 34.43 13 -6 -5 544.87 33.80 -7 13 -5 537.75 34.73 -6 -7 -5 574.83 34.06 7 -13 5 507.25 34.74 -13 6 5 555.80 35.44 -13 6 2 1564.81 60.15 13 -6 -2 1513.64 53.23 -7 13 -2 1577.50 60.68 6 7 2 1523.68 36.80 -6 -7 -2 1533.43 62.25 7 -13 2 1417.57 55.29 -7 13 -2 1471.84 59.45 -13 6 -1 17.20 8.50 7 -13 -1 14.33 7.02 6 7 -1 11.08 4.79 -6 -7 1 21.87 8.15 -7 13 1 9.67 6.53 13 -6 1 17.22 4.92 -6 -7 4 1973.77 56.79 -13 6 -4 1916.25 69.37 13 -6 4 1929.37 63.34 7 -13 -4 1965.29 61.47 6 7 -4 1896.38 54.88 13 -6 4 1993.94 53.87 -6 -7 7 139.88 16.37 6 7 -7 122.71 15.87 13 -6 7 125.03 12.85 7 -13 -7 113.56 14.79 13 -6 7 128.94 16.65 13 -6 10 36.51 8.67 -6 -7 10 31.14 9.12 6 7 -10 20.27 9.00 13 -6 13 39.27 9.81 5 8 9 6.98 7.81 -8 13 -9 -4.86 6.32 -13 5 9 -3.54 5.32 13 -5 -6 120.00 15.95 -8 13 -6 110.64 16.03 5 8 6 92.84 15.10 -5 -8 -6 136.41 15.81 -13 5 6 118.26 16.81 -8 13 -3 14.62 7.49 8 -13 3 14.45 6.62 13 -5 -3 5.90 5.02 -13 5 3 9.36 5.80 13 -5 0 555.17 30.39 8 -13 0 560.48 35.15 -8 13 0 571.92 37.42 5 8 0 601.72 26.87 -13 5 0 615.55 38.90 5 8 -3 1.21 4.19 -5 -8 3 -3.75 4.84 13 -5 3 -1.11 3.86 8 -13 -3 -3.29 5.50 5 8 -6 342.84 25.32 -5 -8 6 371.43 26.42 13 -5 6 381.84 21.14 8 -13 -6 329.25 26.36 13 -5 9 214.18 20.63 5 8 -9 169.51 18.60 -5 -8 9 162.47 19.60 13 -5 12 77.99 12.92 -9 13 -10 478.27 30.85 -9 13 -7 58.65 11.73 13 -4 -7 44.86 10.19 -9 13 -4 78.80 14.57 13 -4 -4 111.70 15.04 -9 13 -1 286.70 25.91 9 -13 1 254.25 24.51 13 -4 -1 242.12 19.89 4 9 1 272.18 17.96 9 -13 -2 14.13 6.52 13 -4 2 7.46 3.60 9 -13 -5 1096.71 48.90 -4 -9 8 38.21 11.41 -10 13 -8 618.87 35.91 13 -3 -8 578.27 35.68 -10 13 -5 370.03 28.55 13 -3 -5 341.68 25.55 -10 13 -2 593.65 37.69 13 -3 -2 581.30 30.77 13 -3 1 -1.05 3.58 -11 13 -6 115.07 16.13 -13 2 -3 867.00 40.42 -13 2 -6 422.10 29.08 -13 1 -2 9.82 6.34 -3 14 4 655.42 34.98 -4 14 3 406.47 28.95 14 -10 6 209.46 21.16 -4 14 6 213.71 20.69 5 -14 4 903.17 44.39 5 -14 1 7.65 4.80 -14 9 -2 328.07 27.70 -5 14 2 350.18 28.08 14 -9 2 333.00 26.31 -14 9 -5 115.19 16.50 14 -9 5 98.65 13.86 -5 14 5 84.91 13.72 -5 14 8 352.70 26.55 -14 8 8 45.19 10.56 6 -14 2 263.57 23.61 14 -8 -2 250.25 23.16 6 -14 -1 173.77 18.81 14 -8 1 171.33 18.69 14 -8 4 240.12 20.61 -14 8 -4 238.28 22.60 8 6 -7 238.34 22.44 -7 -7 -6 405.55 29.58 14 -7 -3 573.03 35.13 14 -7 0 21.00 7.29 7 -14 0 16.75 6.79 7 -14 -3 870.78 41.70 7 7 -3 886.58 36.50 14 -7 3 820.50 37.55 7 7 -6 93.20 13.30 14 -6 -4 6.56 6.40 14 -6 -1 179.41 18.27 6 8 -2 -1.13 4.00 14 -6 2 -6.46 5.54 8 -14 -2 1.71 7.30 6 8 -5 2.75 4.64 8 -14 -5 18.07 8.25 14 -5 -5 -1.63 5.96 14 -5 -2 292.26 23.92 14 -5 1 385.98 24.90 5 9 -4 19.97 7.24 5 9 -7 934.85 43.10 14 -4 -3 278.91 22.61 4 10 -3 13.07 5.58 0 0 0 0.00 0.00 TITL asr-158-a01_autored in R-3 REM R-3 (#148 in standard setting) CELL 0.71073 10.447857 10.447857 19.677433 90.0000 90.0000 120.0000 ZERR 1.00 0.000232 0.000232 0.000438 0.0000 0.0000 0.0000 LATT 3 SYMM -y, x-y, z SYMM -x+y,-x, z SFAC Al Si Ru UNIT 63.41 32.59 27.00 REM CrysAlisPro recorded range (K): Min=295.7; max=296.0; aver:295.9 TEMP 23 SIZE 0.03 0.03 0.03 TREF HKLF 4 END _computing_structure_solution 'SHELXT 2018/2 (Sheldrick, 2018)' ; _shelx_hkl_checksum 33363 _shelx_res_file ; TITL asr-158-a01_a.res in R-3 asr-158-a01_a.res created by SHELXL-2019/3 at 20:22:45 on 22-Aug-2023 REM Old TITL asr-158-a01_autored in R-3 REM SHELXT solution in R-3: R1 0.027, Rweak 0.003, Alpha 0.012 REM 0.000 for 0 systematic absences, Orientation as input REM Formula found by SHELXT: Ru9 Si32 CELL 0.71073 10.447857 10.447857 19.677433 90.0000 90.0000 120.0000 ZERR 3.00 0.000232 0.000232 0.000438 0.0000 0.0000 0.0000 LATT 3 SYMM -Y, X-Y, Z SYMM -X+Y, -X, Z SFAC AL RU SI UNIT 67.20 27.00 28.80 TEMP 23 SIZE 0.026 0.029 0.031 L.S. 30 ACTA MORE -1 REM Al 55.24(58) Ru 21.61(33) Si 23.15(64) / 100 REM Al 22.65(24) Ru 8.86(14) Si 9.49(26) / 41 SUMP 8.65 0.24 6 2 6 3 SUMP -8.51 0.26 -6 2 -6 3 WGHT 0.011100 0.581200 EXTI 0.000262 FVAR 0.12167 0.58500 0.82313 RU1 2 0.000000 0.000000 0.500000 10.16667 0.00464 0.00464 = 0.00459 0.00000 0.00000 0.00232 RU2 2 0.000000 0.000000 0.288325 10.33333 0.00444 0.00444 = 0.00667 0.00000 0.00000 0.00222 RU3 2 0.243683 0.249157 0.091714 11.00000 0.00486 0.00394 = 0.00529 0.00006 0.00054 0.00224 AL4 1 0.000000 0.000000 0.125543 10.33333 0.00657 0.00657 = 0.01889 0.00000 0.00000 0.00329 SI5 3 0.068452 0.253941 0.295408 11.00000 0.01086 0.00543 = 0.01007 -0.00003 -0.00401 0.00405 AL6 1 0.229150 0.165119 0.214325 21.00000 0.00760 0.00961 = 0.00727 0.00249 0.00127 0.00483 SI6 3 0.229150 0.165119 0.214325 -21.00000 0.00760 0.00961 = 0.00727 0.00249 0.00127 0.00483 EXYZ AL6 SI6 EADP AL6 SI6 AL7 1 0.001434 0.210881 0.039582 31.00000 0.00592 0.01022 = 0.00612 -0.00019 0.00001 0.00357 SI7 3 0.001434 0.210881 0.039582 -31.00000 0.00592 0.01022 = 0.00612 -0.00019 0.00001 0.00357 EXYZ AL7 SI7 EADP AL7 SI7 AL8 1 0.165042 0.124479 0.390210 11.00000 0.00742 0.00884 = 0.00760 -0.00055 -0.00180 0.00063 AL9 1 0.126272 0.371484 0.162747 11.00000 0.00983 0.00970 = 0.01208 -0.00117 0.00506 0.00420 HKLF 4 REM asr-158-a01_a.res in R-3 REM wR2 = 0.0237, GooF = S = 1.080, Restrained GooF = 1.079 for all data REM R1 = 0.0126 for 1127 Fo > 4sig(Fo) and 0.0144 for all 1193 data REM 66 parameters refined using 2 restraints END WGHT 0.0111 0.5812 REM Highest difference peak 0.447, deepest hole -0.526, 1-sigma level 0.118 Q1 1 0.3112 0.3552 0.1355 11.00000 0.05 0.45 Q2 1 0.3283 0.2991 0.0390 11.00000 0.05 0.41 Q3 1 0.2024 0.2835 0.1446 11.00000 0.05 0.40 Q4 1 0.1469 0.1751 0.1367 11.00000 0.05 0.40 Q5 1 0.2496 0.1561 0.0436 11.00000 0.05 0.39 Q6 1 0.1635 0.3249 0.0829 11.00000 0.05 0.39 Q7 1 0.1059 0.1368 0.2548 11.00000 0.05 0.38 Q8 1 0.1033 0.3172 0.3491 11.00000 0.05 0.37 Q9 1 -0.0837 -0.1438 0.2780 11.00000 0.05 0.37 Q10 1 0.1646 0.2736 0.0489 11.00000 0.05 0.37 Q11 1 0.0796 0.1588 0.1023 11.00000 0.05 0.37 Q12 1 -0.0803 0.1806 0.0705 11.00000 0.05 0.36 Q13 1 0.1643 0.2504 0.3238 11.00000 0.05 0.36 Q14 1 0.0000 0.0000 0.0804 10.33333 0.05 0.36 Q15 1 0.3013 0.2976 0.1579 11.00000 0.05 0.36 Q16 1 -0.1092 -0.1259 0.4816 11.00000 0.05 0.35 Q17 1 0.2817 0.1830 0.1156 11.00000 0.05 0.34 Q18 1 0.0567 0.1869 0.3649 11.00000 0.05 0.34 Q19 1 -0.0763 0.0918 0.0703 11.00000 0.05 0.33 Q20 1 0.1632 0.2564 0.1038 11.00000 0.05 0.33 ; _shelx_res_checksum 45529 loop_ _space_group_symop_operation_xyz 'x, y, z' '-y, x-y, z' '-x+y, -x, z' 'x+2/3, y+1/3, z+1/3' '-y+2/3, x-y+1/3, z+1/3' '-x+y+2/3, -x+1/3, z+1/3' 'x+1/3, y+2/3, z+2/3' '-y+1/3, x-y+2/3, z+2/3' '-x+y+1/3, -x+2/3, z+2/3' '-x, -y, -z' 'y, -x+y, -z' 'x-y, x, -z' '-x+2/3, -y+1/3, -z+1/3' 'y+2/3, -x+y+1/3, -z+1/3' 'x-y+2/3, x+1/3, -z+1/3' '-x+1/3, -y+2/3, -z+2/3' 'y+1/3, -x+y+2/3, -z+2/3' 'x-y+1/3, x+2/3, -z+2/3' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Ru Ru1 0.000000 0.000000 0.500000 0.00463(7) Uani d 1 . . Ru Ru2 0.000000 0.000000 0.28833(2) 0.00519(6) Uani d 1 . . Ru Ru3 0.24368(2) 0.24916(2) 0.09171(2) 0.00467(5) Uani d 1 . . Al Al4 0.000000 0.000000 0.12554(5) 0.01068(17) Uani d 1 . . Si Si5 0.06845(5) 0.25394(5) 0.29541(2) 0.00880(9) Uani d 1 . . Al Al6 0.22915(5) 0.16512(5) 0.21432(2) 0.0079(2) Uani d 0.58(4) . . Si Si6 0.22915(5) 0.16512(5) 0.21432(2) 0.0079(2) Uani d 0.42(4) . . Al Al7 0.00143(5) 0.21088(5) 0.03958(2) 0.0076(2) Uani d 0.82(4) . . Si Si7 0.00143(5) 0.21088(5) 0.03958(2) 0.0076(2) Uani d 0.18(4) . . Al Al8 0.16504(5) 0.12448(5) 0.39021(2) 0.00948(10) Uani d 1 . . Al Al9 0.12627(6) 0.37148(6) 0.16275(2) 0.01084(11) Uani d 1 . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Ru1 0.00464(9) 0.00464(9) 0.00459(13) 0.00232(5) 0.000 0.000 Ru2 0.00444(7) 0.00444(7) 0.00667(10) 0.00222(4) 0.000 0.000 Ru3 0.00486(7) 0.00394(7) 0.00529(7) 0.00224(5) 0.00054(4) 0.00006(4) Al4 0.0066(2) 0.0066(2) 0.0189(4) 0.00329(12) 0.000 0.000 Si5 0.0109(2) 0.0054(2) 0.0101(2) 0.00405(18) -0.00401(16) -0.00003(16) Al6 0.0076(3) 0.0096(3) 0.0073(3) 0.0048(2) 0.00127(16) 0.00249(17) Si6 0.0076(3) 0.0096(3) 0.0073(3) 0.0048(2) 0.00127(16) 0.00249(17) Al7 0.0059(3) 0.0102(3) 0.0061(3) 0.0036(2) 0.00001(16) -0.00019(17) Si7 0.0059(3) 0.0102(3) 0.0061(3) 0.0036(2) 0.00001(16) -0.00019(17) Al8 0.0074(2) 0.0088(2) 0.0076(2) 0.00063(19) -0.00180(18) -0.00055(17) Al9 0.0098(2) 0.0097(2) 0.0121(2) 0.0042(2) 0.00506(18) -0.00117(19) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag Al8 Ru1 Al8 12_556 3 180.0 ? Al8 Ru1 Al8 12_556 10_556 60.824(17) ? Al8 Ru1 Al8 3 10_556 119.176(17) ? Al8 Ru1 Al8 12_556 2 119.176(17) ? Al8 Ru1 Al8 3 2 60.824(17) ? Al8 Ru1 Al8 10_556 2 119.176(17) ? Al8 Ru1 Al8 12_556 11_556 60.824(17) ? Al8 Ru1 Al8 3 11_556 119.176(17) ? Al8 Ru1 Al8 10_556 11_556 60.824(17) ? Al8 Ru1 Al8 2 11_556 180.000(12) ? Al8 Ru1 Al8 12_556 . 119.177(17) ? Al8 Ru1 Al8 3 . 60.823(17) ? Al8 Ru1 Al8 10_556 . 179.999(12) ? Al8 Ru1 Al8 2 . 60.824(17) ? Al8 Ru1 Al8 11_556 . 119.176(17) ? Al8 Ru1 Al9 12_556 17_445 89.014(15) ? Al8 Ru1 Al9 3 17_445 90.986(15) ? Al8 Ru1 Al9 10_556 17_445 57.891(14) ? Al8 Ru1 Al9 2 17_445 61.286(14) ? Al8 Ru1 Al9 11_556 17_445 118.714(14) ? Al8 Ru1 Al9 . 17_445 122.110(14) ? Al8 Ru1 Al9 12_556 5 90.986(15) ? Al8 Ru1 Al9 3 5 89.014(15) ? Al8 Ru1 Al9 10_556 5 122.109(14) ? Al8 Ru1 Al9 2 5 118.714(14) ? Al8 Ru1 Al9 11_556 5 61.286(14) ? Al8 Ru1 Al9 . 5 57.890(14) ? Al9 Ru1 Al9 17_445 5 180.0 ? Al8 Ru1 Al9 12_556 4_445 122.109(14) ? Al8 Ru1 Al9 3 4_445 57.891(14) ? Al8 Ru1 Al9 10_556 4_445 61.285(14) ? Al8 Ru1 Al9 2 4_445 89.013(15) ? Al8 Ru1 Al9 11_556 4_445 90.987(15) ? Al8 Ru1 Al9 . 4_445 118.714(14) ? Al9 Ru1 Al9 17_445 4_445 60.0770(10) ? Al9 Ru1 Al9 5 4_445 119.9230(10) ? Al8 Ru1 Al9 12_556 16 57.891(14) ? Al8 Ru1 Al9 3 16 122.109(14) ? Al8 Ru1 Al9 10_556 16 118.715(14) ? Al8 Ru1 Al9 2 16 90.987(15) ? Al8 Ru1 Al9 11_556 16 89.013(15) ? Al8 Ru1 Al9 . 16 61.286(14) ? Al9 Ru1 Al9 17_445 16 119.9230(10) ? Al9 Ru1 Al9 5 16 60.0770(10) ? Al9 Ru1 Al9 4_445 16 180.0 ? Al8 Ru1 Al9 12_556 18_545 118.713(14) ? Al8 Ru1 Al9 3 18_545 61.287(14) ? Al8 Ru1 Al9 10_556 18_545 89.012(15) ? Al8 Ru1 Al9 2 18_545 122.111(14) ? Al8 Ru1 Al9 11_556 18_545 57.889(14) ? Al8 Ru1 Al9 . 18_545 90.987(15) ? Al9 Ru1 Al9 17_445 18_545 119.9210(10) ? Al9 Ru1 Al9 5 18_545 60.0790(10) ? Al9 Ru1 Al9 4_445 18_545 60.0790(10) ? Al9 Ru1 Al9 16 18_545 119.9210(10) ? Al8 Ru1 Al9 12_556 6_455 61.287(14) ? Al8 Ru1 Al9 3 6_455 118.713(14) ? Al8 Ru1 Al9 10_556 6_455 90.988(15) ? Al8 Ru1 Al9 2 6_455 57.889(14) ? Al8 Ru1 Al9 11_556 6_455 122.111(14) ? Al8 Ru1 Al9 . 6_455 89.013(15) ? Al9 Ru1 Al9 17_445 6_455 60.0790(10) ? Al9 Ru1 Al9 5 6_455 119.9210(10) ? Al9 Ru1 Al9 4_445 6_455 119.9210(10) ? Al9 Ru1 Al9 16 6_455 60.0790(10) ? Al9 Ru1 Al9 18_545 6_455 180.0 ? Si5 Ru2 Si5 3 . 119.661(2) ? Si5 Ru2 Si5 3 2 119.662(2) ? Si5 Ru2 Si5 . 2 119.659(2) ? Si5 Ru2 Al8 3 . 70.202(16) ? Si5 Ru2 Al8 . . 68.549(15) ? Si5 Ru2 Al8 2 . 124.453(17) ? Si5 Ru2 Al8 3 3 68.549(15) ? Si5 Ru2 Al8 . 3 124.452(17) ? Si5 Ru2 Al8 2 3 70.202(16) ? Al8 Ru2 Al8 . 3 64.153(18) ? Si5 Ru2 Al8 3 2 124.453(17) ? Si5 Ru2 Al8 . 2 70.202(16) ? Si5 Ru2 Al8 2 2 68.548(15) ? Al8 Ru2 Al8 . 2 64.153(18) ? Al8 Ru2 Al8 3 2 64.152(18) ? Si5 Ru2 Al6 3 3 68.158(15) ? Si5 Ru2 Al6 . 3 149.111(17) ? Si5 Ru2 Al6 2 3 67.213(15) ? Al8 Ru2 Al6 . 3 135.530(15) ? Al8 Ru2 Al6 3 3 86.437(15) ? Al8 Ru2 Al6 2 3 132.991(15) ? Si5 Ru2 Al6 3 2 149.112(17) ? Si5 Ru2 Al6 . 2 67.211(15) ? Si5 Ru2 Al6 2 2 68.157(15) ? Al8 Ru2 Al6 . 2 132.990(15) ? Al8 Ru2 Al6 3 2 135.529(15) ? Al8 Ru2 Al6 2 2 86.436(15) ? Al6 Ru2 Al6 3 2 91.441(15) ? Si5 Ru2 Al6 3 . 67.213(15) ? Si5 Ru2 Al6 . . 68.157(15) ? Si5 Ru2 Al6 2 . 149.112(17) ? Al8 Ru2 Al6 . . 86.435(15) ? Al8 Ru2 Al6 3 . 132.991(15) ? Al8 Ru2 Al6 2 . 135.529(15) ? Al6 Ru2 Al6 3 . 91.442(15) ? Al6 Ru2 Al6 2 . 91.441(15) ? Si5 Ru3 Al8 15 9_554 65.551(15) ? Si5 Ru3 Al6 15 . 120.406(15) ? Al8 Ru3 Al6 9_554 . 124.414(16) ? Si5 Ru3 Al7 15 . 122.217(15) ? Al8 Ru3 Al7 9_554 . 73.932(16) ? Al6 Ru3 Al7 . . 116.122(15) ? Si5 Ru3 Al9 15 15 68.678(16) ? Al8 Ru3 Al9 9_554 15 65.586(16) ? Al6 Ru3 Al9 . 15 67.410(16) ? Al7 Ru3 Al9 . 15 127.455(16) ? Si5 Ru3 Al9 15 . 119.665(16) ? Al8 Ru3 Al9 9_554 . 61.760(16) ? Al6 Ru3 Al9 . . 72.324(16) ? Al7 Ru3 Al9 . . 67.560(16) ? Al9 Ru3 Al9 15 . 64.436(17) ? Si5 Ru3 Al6 15 13 66.289(14) ? Al8 Ru3 Al6 9_554 13 127.640(16) ? Al6 Ru3 Al6 . 13 67.389(17) ? Al7 Ru3 Al6 . 13 153.459(16) ? Al9 Ru3 Al6 15 13 78.881(16) ? Al9 Ru3 Al6 . 13 133.370(16) ? Si5 Ru3 Al7 15 11 71.465(15) ? Al8 Ru3 Al7 9_554 11 80.729(15) ? Al6 Ru3 Al7 . 11 154.440(16) ? Al7 Ru3 Al7 . 11 62.594(14) ? Al9 Ru3 Al7 15 11 135.585(16) ? Al9 Ru3 Al7 . 11 123.870(16) ? Al6 Ru3 Al7 13 11 102.325(15) ? Si5 Ru3 Al4 15 . 156.665(16) ? Al8 Ru3 Al4 9_554 . 133.431(13) ? Al6 Ru3 Al4 . . 64.05(2) ? Al7 Ru3 Al4 . . 63.982(15) ? Al9 Ru3 Al4 15 . 127.93(2) ? Al9 Ru3 Al4 . . 83.669(15) ? Al6 Ru3 Al4 13 . 98.593(12) ? Al7 Ru3 Al4 11 . 96.13(2) ? Si5 Ru3 Al7 15 3 93.941(15) ? Al8 Ru3 Al7 9_554 3 141.416(15) ? Al6 Ru3 Al7 . 3 94.038(15) ? Al7 Ru3 Al7 . 3 93.18(2) ? Al9 Ru3 Al7 15 3 139.245(16) ? Al9 Ru3 Al7 . 3 146.275(16) ? Al6 Ru3 Al7 13 3 60.377(15) ? Al7 Ru3 Al7 11 3 61.353(14) ? Al4 Ru3 Al7 . 3 62.748(15) ? Ru3 Al4 Ru3 . 2 113.957(15) ? Ru3 Al4 Ru3 . 3 113.956(15) ? Ru3 Al4 Ru3 2 3 113.956(15) ? Ru3 Al4 Al6 . 2 109.230(14) ? Ru3 Al4 Al6 2 2 55.974(11) ? Ru3 Al4 Al6 3 2 134.84(2) ? Ru3 Al4 Al6 . 3 134.84(2) ? Ru3 Al4 Al6 2 3 109.230(14) ? Ru3 Al4 Al6 3 3 55.974(11) ? Al6 Al4 Al6 2 3 84.26(3) ? Ru3 Al4 Al6 . . 55.973(11) ? Ru3 Al4 Al6 2 . 134.84(2) ? Ru3 Al4 Al6 3 . 109.231(14) ? Al6 Al4 Al6 2 . 84.26(3) ? Al6 Al4 Al6 3 . 84.26(3) ? Ru3 Al4 Al7 . . 56.440(13) ? Ru3 Al4 Al7 2 . 58.708(14) ? Ru3 Al4 Al7 3 . 127.88(3) ? Al6 Al4 Al7 2 . 87.091(13) ? Al6 Al4 Al7 3 . 167.862(14) ? Al6 Al4 Al7 . . 103.356(14) ? Ru3 Al4 Al7 . 2 127.88(3) ? Ru3 Al4 Al7 2 2 56.439(13) ? Ru3 Al4 Al7 3 2 58.708(14) ? Al6 Al4 Al7 2 2 103.357(14) ? Al6 Al4 Al7 3 2 87.091(13) ? Al6 Al4 Al7 . 2 167.862(14) ? Al7 Al4 Al7 . 2 86.64(2) ? Ru3 Al4 Al7 . 3 58.708(14) ? Ru3 Al4 Al7 2 3 127.88(3) ? Ru3 Al4 Al7 3 3 56.439(13) ? Al6 Al4 Al7 2 3 167.862(14) ? Al6 Al4 Al7 3 3 103.357(14) ? Al6 Al4 Al7 . 3 87.091(13) ? Al7 Al4 Al7 . 3 86.64(2) ? Al7 Al4 Al7 2 3 86.64(2) ? Ru2 Si5 Si5 . 16 118.81(3) ? Ru2 Si5 Ru3 . 14_455 119.762(18) ? Si5 Si5 Ru3 16 14_455 120.64(3) ? Ru2 Si5 Al8 . 16 167.65(2) ? Si5 Si5 Al8 16 16 65.93(2) ? Ru3 Si5 Al8 14_455 16 58.956(14) ? Ru2 Si5 Al6 . 2 59.969(14) ? Si5 Si5 Al6 16 2 177.02(3) ? Ru3 Si5 Al6 14_455 2 60.159(14) ? Al8 Si5 Al6 16 2 115.87(2) ? Ru2 Si5 Al8 . . 58.394(14) ? Si5 Si5 Al8 16 . 61.71(2) ? Ru3 Si5 Al8 14_455 . 159.94(2) ? Al8 Si5 Al8 16 . 127.637(19) ? Al6 Si5 Al8 2 . 116.45(2) ? Ru2 Si5 Al6 . . 59.434(14) ? Si5 Si5 Al6 16 . 97.84(3) ? Ru3 Si5 Al6 14_455 . 119.201(19) ? Al8 Si5 Al6 16 . 109.51(2) ? Al6 Si5 Al6 2 . 83.85(2) ? Al8 Si5 Al6 . . 78.242(18) ? Ru2 Si5 Al9 . . 108.102(19) ? Si5 Si5 Al9 16 . 110.55(3) ? Ru3 Si5 Al9 14_455 . 58.171(14) ? Al8 Si5 Al9 16 . 60.157(17) ? Al6 Si5 Al9 2 . 72.378(18) ? Al8 Si5 Al9 . . 141.66(2) ? Al6 Si5 Al9 . . 65.278(17) ? Ru2 Si5 Al8 . 2 57.488(14) ? Si5 Si5 Al8 16 2 99.22(3) ? Ru3 Si5 Al8 14_455 2 103.669(19) ? Al8 Si5 Al8 16 2 134.55(2) ? Al6 Si5 Al8 2 2 77.825(18) ? Al8 Si5 Al8 . 2 57.48(2) ? Al6 Si5 Al8 . 2 115.13(2) ? Al9 Si5 Al8 . 2 150.02(2) ? Ru3 Al6 Ru2 . . 129.707(19) ? Ru3 Al6 Ru3 . 13 112.612(17) ? Ru2 Al6 Ru3 . 13 106.091(16) ? Ru3 Al6 Al7 . 15 116.69(2) ? Ru2 Al6 Al7 . 15 109.655(19) ? Ru3 Al6 Al7 13 15 60.806(14) ? Ru3 Al6 Si5 . 3 143.99(2) ? Ru2 Al6 Si5 . 3 52.818(13) ? Ru3 Al6 Si5 13 3 53.554(13) ? Al7 Al6 Si5 15 3 86.919(19) ? Ru3 Al6 Al4 . . 59.976(17) ? Ru2 Al6 Al4 . . 73.471(19) ? Ru3 Al6 Al4 13 . 119.885(18) ? Al7 Al6 Al4 15 . 176.66(3) ? Si5 Al6 Al4 3 . 96.03(2) ? Ru3 Al6 Si5 . . 111.671(19) ? Ru2 Al6 Si5 . . 52.410(13) ? Ru3 Al6 Si5 13 . 133.10(2) ? Al7 Al6 Si5 15 . 85.969(18) ? Si5 Al6 Si5 3 . 95.90(2) ? Al4 Al6 Si5 . . 95.257(19) ? Ru3 Al6 Al9 . 15 56.713(13) ? Ru2 Al6 Al9 . 15 144.13(2) ? Ru3 Al6 Al9 13 15 99.795(18) ? Al7 Al6 Al9 15 15 62.748(17) ? Si5 Al6 Al9 3 15 148.12(2) ? Al4 Al6 Al9 . 15 114.07(2) ? Si5 Al6 Al9 . 15 91.741(19) ? Ru3 Al6 Al6 . 13 57.391(15) ? Ru2 Al6 Al6 . 13 145.22(3) ? Ru3 Al6 Al6 13 13 55.221(15) ? Al7 Al6 Al6 15 13 87.39(2) ? Si5 Al6 Al6 3 13 100.23(2) ? Al4 Al6 Al6 . 13 90.54(2) ? Si5 Al6 Al6 . 13 162.19(3) ? Al9 Al6 Al6 15 13 70.54(2) ? Ru3 Al7 Ru3 . 12 117.649(18) ? Ru3 Al7 Al6 . 14_455 116.63(2) ? Ru3 Al7 Al6 12 14_455 119.15(2) ? Ru3 Al7 Ru3 . 2 116.862(18) ? Ru3 Al7 Ru3 12 2 114.346(17) ? Al6 Al7 Ru3 14_455 2 58.818(14) ? Ru3 Al7 Al7 . 12 134.381(13) ? Ru3 Al7 Al7 12 12 57.944(19) ? Al6 Al7 Al7 14_455 12 99.12(2) ? Ru3 Al7 Al7 2 12 58.365(12) ? Ru3 Al7 Al7 . 11 59.461(12) ? Ru3 Al7 Al7 12 11 60.283(19) ? Al6 Al7 Al7 14_455 11 168.67(2) ? Ru3 Al7 Al7 2 11 132.432(13) ? Al7 Al7 Al7 12 11 89.88(2) ? Ru3 Al7 Al4 . . 59.578(10) ? Ru3 Al7 Al4 12 . 135.92(2) ? Al6 Al7 Al4 14_455 . 94.86(2) ? Ru3 Al7 Al4 2 . 58.545(10) ? Al7 Al7 Al4 12 . 91.721(15) ? Al7 Al7 Al4 11 . 91.721(15) ? Ru3 Al7 Al9 . . 56.394(14) ? Ru3 Al7 Al9 12 . 142.61(2) ? Al6 Al7 Al9 14_455 . 61.810(17) ? Ru3 Al7 Al9 2 . 97.917(17) ? Al7 Al7 Al9 12 . 156.03(3) ? Al7 Al7 Al9 11 . 111.07(2) ? Al4 Al7 Al9 . . 76.65(2) ? Ru3 Al8 Ru2 5 . 143.54(2) ? Ru3 Al8 Al9 5 5 60.306(15) ? Ru2 Al8 Al9 . 5 145.45(2) ? Ru3 Al8 Ru1 5 . 109.918(17) ? Ru2 Al8 Ru1 . . 106.409(17) ? Al9 Al8 Ru1 5 . 62.599(15) ? Ru3 Al8 Si5 5 16 55.492(14) ? Ru2 Al8 Si5 . 16 104.439(19) ? Al9 Al8 Si5 5 16 109.63(2) ? Ru1 Al8 Si5 . 16 117.12(2) ? Ru3 Al8 Al8 5 3 149.08(3) ? Ru2 Al8 Al8 . 3 57.924(9) ? Al9 Al8 Al8 5 3 91.00(2) ? Ru1 Al8 Al8 . 3 59.587(8) ? Si5 Al8 Al8 16 3 155.06(3) ? Ru3 Al8 Al8 5 2 143.73(3) ? Ru2 Al8 Al8 . 2 57.925(9) ? Al9 Al8 Al8 5 2 122.187(15) ? Ru1 Al8 Al8 . 2 59.588(8) ? Si5 Al8 Al8 16 2 96.24(3) ? Al8 Al8 Al8 3 2 60.0 ? Ru3 Al8 Al9 5 16 58.136(15) ? Ru2 Al8 Al9 . 16 145.13(2) ? Al9 Al8 Al9 5 16 61.411(12) ? Ru1 Al8 Al9 . 16 60.799(14) ? Si5 Al8 Al9 16 16 62.510(18) ? Al8 Al8 Al9 3 16 120.386(14) ? Al8 Al8 Al9 2 16 90.01(2) ? Ru3 Al8 Si5 5 . 104.754(19) ? Ru2 Al8 Si5 . . 53.057(13) ? Al9 Al8 Si5 5 . 161.49(2) ? Ru1 Al8 Si5 . . 118.64(2) ? Si5 Al8 Si5 16 . 52.363(19) ? Al8 Al8 Si5 3 . 105.493(16) ? Al8 Al8 Si5 2 . 62.348(19) ? Al9 Al8 Si5 16 . 102.09(2) ? Ru3 Al8 Si5 5 3 111.11(2) ? Ru2 Al8 Si5 . 3 52.311(13) ? Al9 Al8 Si5 5 3 101.04(2) ? Ru1 Al8 Si5 . 3 116.598(19) ? Si5 Al8 Si5 16 3 125.72(2) ? Al8 Al8 Si5 3 3 60.177(19) ? Al8 Al8 Si5 2 3 103.902(16) ? Al9 Al8 Si5 16 3 162.00(2) ? Si5 Al8 Si5 . 3 94.55(2) ? Ru3 Al9 Ru3 14_455 . 147.99(2) ? Ru3 Al9 Al8 14_455 9_554 148.40(2) ? Ru3 Al9 Al8 . 9_554 57.934(15) ? Ru3 Al9 Ru1 14_455 7_554 105.884(17) ? Ru3 Al9 Ru1 . 7_554 105.607(17) ? Al8 Al9 Ru1 9_554 7_554 59.509(15) ? Ru3 Al9 Al9 14_455 15 138.86(3) ? Ru3 Al9 Al9 . 15 57.609(18) ? Al8 Al9 Al9 9_554 15 61.789(18) ? Ru1 Al9 Al9 7_554 15 59.9590(10) ? Ru3 Al9 Al9 14_455 14_455 57.955(19) ? Ru3 Al9 Al9 . 14_455 148.22(3) ? Al8 Al9 Al9 9_554 14_455 91.89(2) ? Ru1 Al9 Al9 7_554 14_455 60.0 ? Al9 Al9 Al9 15 14_455 119.687(4) ? Ru3 Al9 Al8 14_455 16 56.276(14) ? Ru3 Al9 Al8 . 16 143.01(2) ? Al8 Al9 Al8 9_554 16 117.42(3) ? Ru1 Al9 Al8 7_554 16 57.913(14) ? Al9 Al9 Al8 15 16 87.05(2) ? Al9 Al9 Al8 14_455 16 56.799(18) ? Ru3 Al9 Si5 14_455 . 53.152(13) ? Ru3 Al9 Si5 . . 109.71(2) ? Al8 Al9 Si5 9_554 . 154.89(3) ? Ru1 Al9 Si5 7_554 . 109.909(19) ? Al9 Al9 Si5 15 . 93.10(3) ? Al9 Al9 Si5 14_455 . 102.00(3) ? Al8 Al9 Si5 16 . 57.332(16) ? Ru3 Al9 Al6 14_455 14_455 55.877(14) ? Ru3 Al9 Al6 . 14_455 110.10(2) ? Al8 Al9 Al6 9_554 14_455 105.54(2) ? Ru1 Al9 Al6 7_554 14_455 121.90(2) ? Al9 Al9 Al6 15 14_455 165.26(3) ? Al9 Al9 Al6 14_455 14_455 65.56(2) ? Al8 Al9 Al6 16 14_455 106.35(2) ? Si5 Al9 Al6 . 14_455 99.26(2) ? Ru3 Al9 Al7 14_455 . 108.93(2) ? Ru3 Al9 Al7 . . 56.047(14) ? Al8 Al9 Al7 9_554 . 67.695(18) ? Ru1 Al9 Al7 7_554 . 123.68(2) ? Al9 Al9 Al7 15 . 110.49(3) ? Al9 Al9 Al7 14_455 . 105.97(3) ? Al8 Al9 Al7 16 . 160.85(2) ? Si5 Al9 Al7 . . 126.36(2) ? Al6 Al9 Al7 14_455 . 55.443(16) ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag Ru1 Al8 12_556 2.6625(5) ? Ru1 Al8 3 2.6625(5) ? Ru1 Al8 10_556 2.6625(5) ? Ru1 Al8 2 2.6626(5) ? Ru1 Al8 11_556 2.6626(5) ? Ru1 Al8 . 2.6626(5) ? Ru1 Al9 17_445 2.7432(5) ? Ru1 Al9 5 2.7432(5) ? Ru1 Al9 4_445 2.7432(5) ? Ru1 Al9 16 2.7432(5) ? Ru1 Al9 18_545 2.7433(5) ? Ru1 Al9 6_455 2.7433(5) ? Ru2 Si5 3 2.3817(4) ? Ru2 Si5 . 2.3817(4) ? Ru2 Si5 2 2.3817(4) ? Ru2 Al8 . 2.5380(5) ? Ru2 Al8 3 2.5380(5) ? Ru2 Al8 2 2.5381(5) ? Ru2 Al6 3 2.5880(5) ? Ru2 Al6 2 2.5880(5) ? Ru2 Al6 . 2.5881(5) ? Ru3 Si5 15 2.4214(4) ? Ru3 Al8 9_554 2.5175(5) ? Ru3 Al6 . 2.5459(5) ? Ru3 Al7 . 2.5702(5) ? Ru3 Al9 15 2.5708(5) ? Ru3 Al9 . 2.5806(5) ? Ru3 Al6 13 2.6110(5) ? Ru3 Al7 11 2.6119(5) ? Ru3 Al4 . 2.6597(3) ? Ru3 Al7 3 2.6643(5) ? Al4 Al6 2 2.7622(7) ? Al4 Al6 3 2.7622(7) ? Al4 Al6 . 2.7622(7) ? Al4 Al7 . 2.7718(7) ? Al4 Al7 2 2.7718(7) ? Al4 Al7 3 2.7718(7) ? Si5 Si5 16 2.4056(9) ? Si5 Al8 16 2.6749(6) ? Si5 Al6 2 2.7560(6) ? Si5 Al8 . 2.7736(6) ? Si5 Al6 . 2.7899(6) ? Si5 Al9 . 2.8188(7) ? Si5 Al8 2 2.8319(7) ? Al6 Al7 15 2.6531(6) ? Al6 Al9 15 2.8394(7) ? Al6 Al6 13 2.8614(9) ? Al7 Al7 12 2.6922(6) ? Al7 Al7 11 2.6922(6) ? Al7 Al9 . 2.8639(7) ? Al8 Al9 5 2.6172(7) ? Al8 Al8 3 2.6956(8) ? Al8 Al8 2 2.6957(8) ? Al8 Al9 16 2.7562(7) ? Al9 Al9 15 2.7465(5) ? Al9 Al9 14_455 2.7465(5) ? _cod_database_fobs_code 2312359