Crystallography Open Database

Information card for entry 4086444

Preview

Coordinates	4086444.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C22 H42 O2 Si4 W
Calculated formula	C22 H42 O2 Si4 W
Title of publication	Synthesis of a Tungsten‒Silylyne Complex via Stepwise Proton and Hydride Abstraction from a Hydrido Hydrosilylene Complex
Authors of publication	Fukuda, Tetsuya; Yoshimoto, Takashi; Hashimoto, Hisako; Tobita, Hiromi
Journal of publication	Organometallics
Year of publication	2016
Journal volume	35
Journal issue	7
Pages of publication	921
a	9.259 ± 0.0011 Å
b	12.6926 ± 0.001 Å
c	13.2925 ± 0.0015 Å
α	68.987 ± 0.006°
β	89.604 ± 0.004°
γ	79.879 ± 0.003°
Cell volume	1432.9 ± 0.3 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	5
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0291
Residual factor for significantly intense reflections	0.0261
Weighted residual factors for significantly intense reflections	0.0718
Weighted residual factors for all reflections included in the refinement	0.081
Goodness-of-fit parameter for all reflections included in the refinement	1.204
Diffraction radiation wavelength	0.71069 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
182510 (current)	2016-05-04	cif/ Updating files of 4086443, 4086444 Original log message: Adding full bibliography for 4086443--4086444.cif.	4086444.cif
180588	2016-03-30	cif/ Adding structures of 4086444 via cif-deposit CGI script.	4086444.cif