#------------------------------------------------------------------------------ #$Date: 2016-03-22 11:26:18 +0200 (Tue, 22 Mar 2016) $ #$Revision: 178899 $ #$URL: file:///home/coder/svn-repositories/cod/cif/4/11/28/4112800.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_4112800 loop_ _publ_author_name 'Trevor L. Dzwiniel' 'Jeffrey M. Stryker' _publ_contact_author_address ; Department of Chemistry University of Alberta Edmonton, Alberta T6G 2G2 Canada ; _publ_contact_author_email jeff.stryker@ualberta.ca _publ_contact_author_fax 1(780)4928231 _publ_contact_author_name 'Dr. Jeffrey M. Stryker' _publ_contact_author_phone 1(780)4923981 _publ_section_title ; Cobalt-Mediated Two-Carbon Ring Expansion of Five-Membered Rings. Electrophilic Carbon-Carbon Bond Activation in the Synthesis of Seven-Membered Rings ; _journal_name_full 'Journal of the American Chemical Society' _journal_page_first 9184 _journal_page_last 9185 _journal_paper_doi 10.1021/ja047852+ _journal_volume 126 _journal_year 2004 _chemical_formula_moiety 'C24 H35 Co O4' _chemical_formula_sum 'C24 H35 Co O4' _chemical_formula_weight 446.45 _space_group_IT_number 14 _symmetry_cell_setting monoclinic _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _audit_creation_method 'manual editing of SHELXL template' _cell_angle_alpha 90.00 _cell_angle_beta 100.458(4) _cell_angle_gamma 90.00 _cell_formula_units_Z 4 _cell_length_a 16.4190(7) _cell_length_b 8.6648(3) _cell_length_c 16.2655(7) _cell_measurement_reflns_used 32 _cell_measurement_temperature 213(2) _cell_measurement_theta_max 29.45 _cell_measurement_theta_min 29.21 _cell_volume 2275.61(16) _computing_cell_refinement 'Siemens XSCANS (Siemens, 1994)' _computing_data_collection 'Siemens XSCANS (Siemens, 1994)' _computing_data_reduction 'Siemens XSCANS (Siemens, 1994)' _computing_molecular_graphics 'Siemens SHELXTL (Sheldrick, 1996)' _computing_publication_material 'Siemens SHELXTL (Sheldrick, 1996)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _diffrn_ambient_temperature 213(2) _diffrn_measured_fraction_theta_full 0.996 _diffrn_measured_fraction_theta_max 0.996 _diffrn_measurement_device_type 'Siemens P4/RA' _diffrn_measurement_method '2\q/\w scans' _diffrn_radiation_monochromator graphite _diffrn_radiation_source 'fine-focus rotating anode' _diffrn_radiation_type CuK\a _diffrn_radiation_wavelength 1.54178 _diffrn_reflns_av_R_equivalents 0.0362 _diffrn_reflns_av_sigmaI/netI 0.0342 _diffrn_reflns_limit_h_max 17 _diffrn_reflns_limit_h_min 0 _diffrn_reflns_limit_k_max 9 _diffrn_reflns_limit_k_min 0 _diffrn_reflns_limit_l_max 17 _diffrn_reflns_limit_l_min -17 _diffrn_reflns_number 3158 _diffrn_reflns_theta_full 56.74 _diffrn_reflns_theta_max 56.74 _diffrn_reflns_theta_min 2.74 _diffrn_standards_decay_% 7.90 _diffrn_standards_interval_count 197 _diffrn_standards_number 3 _exptl_absorpt_coefficient_mu 6.116 _exptl_absorpt_correction_T_max 0.2603 _exptl_absorpt_correction_T_min 0.1308 _exptl_absorpt_correction_type psi-scan _exptl_absorpt_process_details 'Siemens SHELXTL (Sheldrick, 1996)' _exptl_crystal_colour orange _exptl_crystal_density_diffrn 1.303 _exptl_crystal_description fragment _exptl_crystal_F_000 952 _exptl_crystal_size_max 0.44 _exptl_crystal_size_mid 0.38 _exptl_crystal_size_min 0.22 _refine_diff_density_max 0.428 _refine_diff_density_min -0.310 _refine_diff_density_rms 0.051 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.042 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 271 _refine_ls_number_reflns 3036 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.042 _refine_ls_R_factor_all 0.0596 _refine_ls_R_factor_gt 0.0467 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0595P)^2^+2.0798P] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1089 _refine_ls_wR_factor_ref 0.1152 _reflns_number_gt 2550 _reflns_number_total 3036 _reflns_threshold_expression I>2\s(I) _cod_data_source_file ja0478522Bsi20040614_121939_1.cif _cod_data_source_block compound(3a) _cod_original_sg_symbol_H-M 'P 21/c' _cod_database_code 4112800 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags Co Co 0.32212(3) 0.32561(6) 0.14695(3) 0.0258(2) Uani 1 1 d . O1 O 0.10594(18) 0.1860(3) -0.0861(2) 0.0608(9) Uani 1 1 d . O2 O -0.00955(16) 0.3171(3) -0.08100(18) 0.0492(8) Uani 1 1 d . O3 O 0.10751(18) 0.5205(3) -0.19537(16) 0.0508(8) Uani 1 1 d . O4 O 0.07238(17) 0.7004(3) -0.10955(17) 0.0436(7) Uani 1 1 d . C1 C 0.3441(2) 0.5472(4) 0.1292(2) 0.0360(9) Uani 1 1 d . H1 H 0.3979 0.5801 0.1624 0.043 Uiso 1 1 calc R C2 C 0.2822(2) 0.5278(4) 0.1813(2) 0.0335(9) Uani 1 1 d . C3 C 0.2150(2) 0.4278(4) 0.1499(2) 0.0295(8) Uani 1 1 d . C4 C 0.2141(2) 0.3597(4) 0.0688(2) 0.0269(8) Uani 1 1 d . H4 H 0.1806 0.2641 0.0621 0.032 Uiso 1 1 calc R C5 C 0.2059(2) 0.4453(4) -0.0132(2) 0.0287(8) Uani 1 1 d . H5 H 0.2330 0.3840 -0.0520 0.034 Uiso 1 1 calc R C6 C 0.2444(2) 0.6055(4) -0.0046(2) 0.0334(9) Uani 1 1 d . H6A H 0.2422 0.6495 -0.0604 0.040 Uiso 1 1 calc R H6B H 0.2114 0.6720 0.0255 0.040 Uiso 1 1 calc R C7 C 0.3328(2) 0.6061(4) 0.0409(2) 0.0379(9) Uani 1 1 d . H7A H 0.3660 0.5426 0.0096 0.046 Uiso 1 1 calc R H7B H 0.3541 0.7119 0.0419 0.046 Uiso 1 1 calc R C8 C 0.2963(3) 0.5907(5) 0.2689(2) 0.0533(12) Uani 1 1 d . H8A H 0.3547 0.6121 0.2872 0.064 Uiso 1 1 calc R H8B H 0.2783 0.5153 0.3060 0.064 Uiso 1 1 calc R H8C H 0.2648 0.6852 0.2701 0.064 Uiso 1 1 calc R C9 C 0.1522(2) 0.3772(5) 0.2021(2) 0.0450(10) Uani 1 1 d . H9A H 0.1352 0.2720 0.1877 0.054 Uiso 1 1 calc R H9B H 0.1043 0.4447 0.1910 0.054 Uiso 1 1 calc R H9C H 0.1768 0.3827 0.2609 0.054 Uiso 1 1 calc R C10 C 0.1128(2) 0.4585(4) -0.0501(2) 0.0273(8) Uani 1 1 d . H10 H 0.0850 0.5062 -0.0073 0.033 Uiso 1 1 calc R C11 C 0.0724(2) 0.3038(4) -0.0734(2) 0.0327(9) Uani 1 1 d . C12 C -0.0580(3) 0.1784(6) -0.1005(3) 0.0689(15) Uani 1 1 d . H12A H -0.1164 0.2033 -0.1075 0.083 Uiso 1 1 calc R H12B H -0.0437 0.1047 -0.0553 0.083 Uiso 1 1 calc R H12C H -0.0463 0.1339 -0.1519 0.083 Uiso 1 1 calc R C13 C 0.0966(2) 0.5592(4) -0.1274(2) 0.0330(9) Uani 1 1 d . C14 C 0.0629(3) 0.8121(5) -0.1769(3) 0.0616(13) Uani 1 1 d . H14A H 0.0582 0.9147 -0.1545 0.074 Uiso 1 1 calc R H14B H 0.0134 0.7885 -0.2173 0.074 Uiso 1 1 calc R H14C H 0.1108 0.8076 -0.2040 0.074 Uiso 1 1 calc R C20 C 0.3264(2) 0.0887(4) 0.1595(2) 0.0305(9) Uani 1 1 d . C21 C 0.3585(2) 0.1553(4) 0.2382(2) 0.0323(9) Uani 1 1 d . C22 C 0.4259(2) 0.2496(5) 0.2283(2) 0.0390(10) Uani 1 1 d . C23 C 0.4371(2) 0.2389(5) 0.1438(3) 0.0415(10) Uani 1 1 d . C24 C 0.3757(2) 0.1389(4) 0.1007(2) 0.0378(10) Uani 1 1 d . C25 C 0.2542(3) -0.0214(5) 0.1407(3) 0.0494(11) Uani 1 1 d . H25A H 0.2234 -0.0013 0.0850 0.059 Uiso 1 1 calc R H25B H 0.2183 -0.0069 0.1813 0.059 Uiso 1 1 calc R H25C H 0.2746 -0.1267 0.1438 0.059 Uiso 1 1 calc R C26 C 0.3247(3) 0.1298(5) 0.3164(2) 0.0504(11) Uani 1 1 d . H26A H 0.2668 0.1007 0.3021 0.060 Uiso 1 1 calc R H26B H 0.3298 0.2242 0.3490 0.060 Uiso 1 1 calc R H26C H 0.3556 0.0481 0.3489 0.060 Uiso 1 1 calc R C27 C 0.4790(3) 0.3423(5) 0.2966(3) 0.0646(14) Uani 1 1 d . H27A H 0.5061 0.4250 0.2717 0.078 Uiso 1 1 calc R H27B H 0.5204 0.2756 0.3287 0.078 Uiso 1 1 calc R H27C H 0.4444 0.3857 0.3332 0.078 Uiso 1 1 calc R C28 C 0.5040(3) 0.3152(6) 0.1056(4) 0.0755(17) Uani 1 1 d . H28A H 0.5262 0.4028 0.1395 0.091 Uiso 1 1 calc R H28B H 0.4809 0.3501 0.0495 0.091 Uiso 1 1 calc R H28C H 0.5480 0.2416 0.1030 0.091 Uiso 1 1 calc R C29 C 0.3659(3) 0.0876(5) 0.0119(3) 0.0655(15) Uani 1 1 d . H29A H 0.3075 0.0766 -0.0115 0.079 Uiso 1 1 calc R H29B H 0.3936 -0.0108 0.0094 0.079 Uiso 1 1 calc R H29C H 0.3904 0.1637 -0.0200 0.079 Uiso 1 1 calc R loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Co 0.0256(3) 0.0285(3) 0.0231(3) 0.0014(3) 0.0035(2) -0.0003(3) O1 0.0499(19) 0.0425(18) 0.082(2) -0.0259(16) -0.0083(16) 0.0035(15) O2 0.0332(16) 0.0518(18) 0.064(2) -0.0208(15) 0.0136(14) -0.0121(13) O3 0.071(2) 0.0556(18) 0.0269(16) 0.0047(14) 0.0106(14) 0.0150(16) O4 0.0523(17) 0.0349(16) 0.0419(17) 0.0055(13) 0.0043(13) 0.0096(13) C1 0.031(2) 0.033(2) 0.039(2) -0.0013(18) -0.0062(17) -0.0069(17) C2 0.041(2) 0.030(2) 0.027(2) -0.0039(17) -0.0015(17) 0.0038(18) C3 0.032(2) 0.032(2) 0.024(2) 0.0033(16) 0.0055(16) 0.0064(16) C4 0.0266(19) 0.0289(19) 0.025(2) 0.0072(16) 0.0042(15) -0.0012(16) C5 0.0299(19) 0.033(2) 0.0236(19) -0.0026(16) 0.0060(15) 0.0041(16) C6 0.035(2) 0.034(2) 0.031(2) 0.0088(17) 0.0044(17) -0.0015(17) C7 0.035(2) 0.032(2) 0.046(2) 0.0062(19) 0.0058(18) -0.0065(17) C8 0.069(3) 0.050(3) 0.037(3) -0.012(2) 0.000(2) 0.004(2) C9 0.045(2) 0.059(3) 0.034(2) 0.006(2) 0.0157(19) 0.007(2) C10 0.034(2) 0.0299(19) 0.0190(19) -0.0039(16) 0.0059(15) 0.0028(16) C11 0.038(2) 0.037(2) 0.020(2) -0.0025(17) -0.0007(16) -0.0012(19) C12 0.058(3) 0.073(4) 0.079(4) -0.028(3) 0.022(3) -0.029(3) C13 0.030(2) 0.038(2) 0.029(2) 0.0013(18) 0.0021(17) 0.0005(17) C14 0.074(3) 0.045(3) 0.067(3) 0.024(2) 0.014(3) 0.012(2) C20 0.036(2) 0.029(2) 0.027(2) 0.0012(16) 0.0056(17) 0.0047(17) C21 0.036(2) 0.035(2) 0.025(2) 0.0025(17) 0.0030(16) 0.0039(17) C22 0.031(2) 0.040(2) 0.043(3) 0.007(2) -0.0022(18) 0.0050(19) C23 0.033(2) 0.038(2) 0.057(3) 0.017(2) 0.017(2) 0.0070(19) C24 0.049(2) 0.041(2) 0.025(2) 0.0093(18) 0.0135(18) 0.017(2) C25 0.055(3) 0.034(2) 0.058(3) -0.001(2) 0.005(2) -0.007(2) C26 0.064(3) 0.059(3) 0.031(2) 0.007(2) 0.015(2) 0.009(2) C27 0.046(3) 0.056(3) 0.076(4) -0.007(3) -0.032(2) 0.003(2) C28 0.043(3) 0.079(4) 0.113(5) 0.043(3) 0.036(3) 0.011(3) C29 0.112(4) 0.055(3) 0.036(3) 0.007(2) 0.032(3) 0.025(3) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Co Co -2.3653 3.6143 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle C3 Co C1 75.89(15) C3 Co C2 42.05(15) C1 Co C2 42.73(15) C3 Co C4 42.47(14) C1 Co C4 85.90(14) C2 Co C4 75.48(14) C3 Co C23 175.00(15) C1 Co C23 99.16(16) C2 Co C23 133.32(16) C4 Co C23 138.86(16) C3 Co C24 143.67(16) C1 Co C24 127.52(16) C2 Co C24 170.25(16) C4 Co C24 105.81(15) C23 Co C24 40.48(16) C3 Co C20 117.25(15) C1 Co C20 166.75(15) C2 Co C20 149.01(15) C4 Co C20 102.67(14) C23 Co C20 67.72(15) C24 Co C20 40.64(14) C3 Co C22 139.52(15) C1 Co C22 104.54(15) C2 Co C22 112.16(15) C4 Co C22 169.56(15) C23 Co C22 40.52(16) C24 Co C22 67.94(16) C20 Co C22 67.05(15) C3 Co C21 115.91(14) C1 Co C21 138.29(15) C2 Co C21 119.14(14) C4 Co C21 130.97(14) C23 Co C21 67.27(15) C24 Co C21 67.61(14) C20 Co C21 39.75(14) C22 Co C21 39.49(15) C11 O2 C12 117.0(3) C13 O4 C14 116.3(3) C2 C1 C7 128.4(3) C2 C1 Co 68.7(2) C7 C1 Co 118.3(3) C3 C2 C1 116.3(3) C3 C2 C8 122.4(4) C1 C2 C8 120.6(3) C3 C2 Co 68.6(2) C1 C2 Co 68.6(2) C8 C2 Co 125.7(3) C2 C3 C4 117.1(3) C2 C3 C9 122.6(3) C4 C3 C9 119.9(3) C2 C3 Co 69.3(2) C4 C3 Co 69.91(19) C9 C3 Co 125.7(3) C3 C4 C5 126.3(3) C3 C4 Co 67.62(19) C5 C4 Co 123.9(2) C4 C5 C6 113.4(3) C4 C5 C10 107.7(3) C6 C5 C10 109.5(3) C7 C6 C5 113.3(3) C1 C7 C6 114.1(3) C11 C10 C13 107.5(3) C11 C10 C5 113.0(3) C13 C10 C5 112.2(3) O1 C11 O2 123.2(3) O1 C11 C10 127.2(3) O2 C11 C10 109.6(3) O3 C13 O4 123.8(3) O3 C13 C10 124.8(3) O4 C13 C10 111.3(3) C21 C20 C24 108.6(3) C21 C20 C25 126.2(3) C24 C20 C25 125.2(3) C21 C20 Co 71.6(2) C24 C20 Co 69.1(2) C25 C20 Co 126.7(3) C22 C21 C20 107.7(3) C22 C21 C26 127.2(4) C20 C21 C26 125.1(4) C22 C21 Co 68.9(2) C20 C21 Co 68.7(2) C26 C21 Co 127.1(3) C21 C22 C23 108.3(3) C21 C22 C27 125.8(4) C23 C22 C27 125.9(4) C21 C22 Co 71.6(2) C23 C22 Co 68.8(2) C27 C22 Co 126.8(3) C24 C23 C22 108.3(3) C24 C23 C28 124.8(4) C22 C23 C28 126.9(4) C24 C23 Co 70.1(2) C22 C23 Co 70.7(2) C28 C23 Co 126.5(3) C23 C24 C20 107.1(3) C23 C24 C29 127.1(4) C20 C24 C29 125.7(4) C23 C24 Co 69.5(2) C20 C24 Co 70.2(2) C29 C24 Co 127.8(3) loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance Co C3 1.977(3) Co C1 1.985(4) Co C2 1.986(4) Co C4 2.008(3) Co C23 2.041(4) Co C24 2.049(4) Co C20 2.063(4) Co C22 2.067(4) Co C21 2.101(4) O1 C11 1.195(4) O2 C11 1.333(4) O2 C12 1.445(5) O3 C13 1.200(4) O4 C13 1.334(4) O4 C14 1.449(5) C1 C2 1.447(5) C1 C7 1.503(5) C2 C3 1.422(5) C2 C8 1.505(5) C3 C4 1.443(5) C3 C9 1.515(5) C4 C5 1.510(5) C5 C6 1.522(5) C5 C10 1.541(5) C6 C7 1.505(5) C10 C11 1.513(5) C10 C13 1.513(5) C20 C21 1.416(5) C20 C24 1.428(5) C20 C25 1.509(5) C21 C22 1.409(5) C21 C26 1.493(5) C22 C23 1.423(6) C22 C27 1.511(6) C23 C24 1.415(6) C23 C28 1.510(5) C24 C29 1.492(5) loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion C3 Co C1 C2 31.1(2) C4 Co C1 C2 73.0(2) C23 Co C1 C2 -148.2(2) C24 Co C1 C2 179.8(2) C20 Co C1 C2 -156.1(6) C22 Co C1 C2 -107.1(2) C21 Co C1 C2 -82.2(3) C3 Co C1 C7 -92.1(3) C2 Co C1 C7 -123.2(4) C4 Co C1 C7 -50.2(3) C23 Co C1 C7 88.7(3) C24 Co C1 C7 56.6(4) C20 Co C1 C7 80.7(7) C22 Co C1 C7 129.8(3) C21 Co C1 C7 154.7(3) C7 C1 C2 C3 58.9(5) Co C1 C2 C3 -51.0(3) C7 C1 C2 C8 -130.4(4) Co C1 C2 C8 119.8(3) C7 C1 C2 Co 109.8(4) C1 Co C2 C3 131.6(3) C4 Co C2 C3 31.7(2) C23 Co C2 C3 177.3(2) C24 Co C2 C3 130.6(9) C20 Co C2 C3 -58.8(4) C22 Co C2 C3 -140.8(2) C21 Co C2 C3 -97.4(2) C3 Co C2 C1 -131.6(3) C4 Co C2 C1 -99.9(2) C23 Co C2 C1 45.7(3) C24 Co C2 C1 -1.0(10) C20 Co C2 C1 169.6(3) C22 Co C2 C1 87.6(2) C21 Co C2 C1 131.0(2) C3 Co C2 C8 115.3(4) C1 Co C2 C8 -113.1(4) C4 Co C2 C8 147.0(4) C23 Co C2 C8 -67.4(4) C24 Co C2 C8 -114.1(9) C20 Co C2 C8 56.5(5) C22 Co C2 C8 -25.5(4) C21 Co C2 C8 17.9(4) C1 C2 C3 C4 -1.8(5) C8 C2 C3 C4 -172.3(3) Co C2 C3 C4 -52.7(3) C1 C2 C3 C9 170.9(3) C8 C2 C3 C9 0.3(5) Co C2 C3 C9 119.9(3) C1 C2 C3 Co 50.9(3) C8 C2 C3 Co -119.6(4) C1 Co C3 C2 -31.6(2) C4 Co C3 C2 -131.1(3) C23 Co C3 C2 -23.0(19) C24 Co C3 C2 -167.5(2) C20 Co C3 C2 150.3(2) C22 Co C3 C2 64.4(3) C21 Co C3 C2 105.6(2) C1 Co C3 C4 99.5(2) C2 Co C3 C4 131.1(3) C23 Co C3 C4 108.0(18) C24 Co C3 C4 -36.4(3) C20 Co C3 C4 -78.6(2) C22 Co C3 C4 -164.5(2) C21 Co C3 C4 -123.3(2) C1 Co C3 C9 -147.5(3) C2 Co C3 C9 -115.9(4) C4 Co C3 C9 113.0(4) C23 Co C3 C9 -139.0(17) C24 Co C3 C9 76.6(4) C20 Co C3 C9 34.4(4) C22 Co C3 C9 -51.5(4) C21 Co C3 C9 -10.3(4) C2 C3 C4 C5 -64.1(5) C9 C3 C4 C5 123.0(4) Co C3 C4 C5 -116.5(3) C2 C3 C4 Co 52.4(3) C9 C3 C4 Co -120.4(3) C1 Co C4 C3 -73.5(2) C2 Co C4 C3 -31.4(2) C23 Co C4 C3 -172.8(2) C24 Co C4 C3 158.6(2) C20 Co C4 C3 116.7(2) C22 Co C4 C3 106.7(8) C21 Co C4 C3 84.7(2) C3 Co C4 C5 119.6(4) C1 Co C4 C5 46.1(3) C2 Co C4 C5 88.1(3) C23 Co C4 C5 -53.2(4) C24 Co C4 C5 -81.8(3) C20 Co C4 C5 -123.7(3) C22 Co C4 C5 -133.7(7) C21 Co C4 C5 -155.7(3) C3 C4 C5 C6 32.0(5) Co C4 C5 C6 -53.7(4) C3 C4 C5 C10 -89.4(4) Co C4 C5 C10 -175.1(2) C4 C5 C6 C7 52.5(4) C10 C5 C6 C7 172.8(3) C2 C1 C7 C6 -16.9(6) Co C1 C7 C6 67.3(4) C5 C6 C7 C1 -61.0(4) C4 C5 C10 C11 -65.2(4) C6 C5 C10 C11 171.1(3) C4 C5 C10 C13 173.0(3) C6 C5 C10 C13 49.3(4) C12 O2 C11 O1 3.9(6) C12 O2 C11 C10 -178.1(3) C13 C10 C11 O1 104.1(4) C5 C10 C11 O1 -20.3(5) C13 C10 C11 O2 -73.8(4) C5 C10 C11 O2 161.8(3) C14 O4 C13 O3 -2.9(6) C14 O4 C13 C10 174.1(3) C11 C10 C13 O3 -48.6(5) C5 C10 C13 O3 76.3(5) C11 C10 C13 O4 134.5(3) C5 C10 C13 O4 -100.7(3) C3 Co C20 C21 -98.6(2) C1 Co C20 C21 89.3(7) C2 Co C20 C21 -58.5(4) C4 Co C20 C21 -141.3(2) C23 Co C20 C21 80.8(2) C24 Co C20 C21 119.1(3) C22 Co C20 C21 36.7(2) C3 Co C20 C24 142.3(2) C1 Co C20 C24 -29.8(7) C2 Co C20 C24 -177.6(3) C4 Co C20 C24 99.6(2) C23 Co C20 C24 -38.3(2) C22 Co C20 C24 -82.4(2) C21 Co C20 C24 -119.1(3) C3 Co C20 C25 23.2(4) C1 Co C20 C25 -148.9(6) C2 Co C20 C25 63.3(5) C4 Co C20 C25 -19.5(3) C23 Co C20 C25 -157.4(4) C24 Co C20 C25 -119.1(4) C22 Co C20 C25 158.5(4) C21 Co C20 C25 121.8(4) C24 C20 C21 C22 1.5(4) C25 C20 C21 C22 179.5(4) Co C20 C21 C22 -58.0(3) C24 C20 C21 C26 -179.3(3) C25 C20 C21 C26 -1.3(6) Co C20 C21 C26 121.2(4) C24 C20 C21 Co 59.5(2) C25 C20 C21 Co -122.5(4) C3 Co C21 C22 -137.7(2) C1 Co C21 C22 -39.8(3) C2 Co C21 C22 -90.1(3) C4 Co C21 C22 173.9(2) C23 Co C21 C22 38.0(2) C24 Co C21 C22 82.0(2) C20 Co C21 C22 120.0(3) C3 Co C21 C20 102.2(2) C1 Co C21 C20 -159.8(2) C2 Co C21 C20 149.8(2) C4 Co C21 C20 53.9(3) C23 Co C21 C20 -82.0(2) C24 Co C21 C20 -38.0(2) C22 Co C21 C20 -120.0(3) C3 Co C21 C26 -16.4(4) C1 Co C21 C26 81.5(4) C2 Co C21 C26 31.2(4) C4 Co C21 C26 -64.8(4) C23 Co C21 C26 159.4(4) C24 Co C21 C26 -156.6(4) C20 Co C21 C26 -118.6(4) C22 Co C21 C26 121.4(4) C20 C21 C22 C23 -1.3(4) C26 C21 C22 C23 179.5(4) Co C21 C22 C23 -59.2(3) C20 C21 C22 C27 -179.6(4) C26 C21 C22 C27 1.2(6) Co C21 C22 C27 122.6(4) C20 C21 C22 Co 57.8(2) C26 C21 C22 Co -121.3(4) C3 Co C22 C21 68.7(3) C1 Co C22 C21 153.9(2) C2 Co C22 C21 109.4(2) C4 Co C22 C21 -26.3(9) C23 Co C22 C21 -119.0(3) C24 Co C22 C21 -81.1(2) C20 Co C22 C21 -37.0(2) C3 Co C22 C23 -172.3(2) C1 Co C22 C23 -87.1(3) C2 Co C22 C23 -131.6(2) C4 Co C22 C23 92.7(8) C24 Co C22 C23 37.9(2) C20 Co C22 C23 82.0(2) C21 Co C22 C23 119.0(3) C3 Co C22 C27 -52.6(5) C1 Co C22 C27 32.5(4) C2 Co C22 C27 -11.9(4) C4 Co C22 C27 -147.7(7) C23 Co C22 C27 119.7(5) C24 Co C22 C27 157.6(4) C20 Co C22 C27 -158.3(4) C21 Co C22 C27 -121.3(5) C21 C22 C23 C24 0.7(4) C27 C22 C23 C24 178.9(4) Co C22 C23 C24 -60.3(3) C21 C22 C23 C28 -177.4(4) C27 C22 C23 C28 0.9(6) Co C22 C23 C28 121.7(4) C21 C22 C23 Co 60.9(3) C27 C22 C23 Co -120.8(4) C3 Co C23 C24 -147.9(17) C1 Co C23 C24 -139.6(2) C2 Co C23 C24 -169.1(2) C4 Co C23 C24 -45.3(3) C20 Co C23 C24 38.5(2) C22 Co C23 C24 118.7(3) C21 Co C23 C24 81.6(2) C3 Co C23 C22 93.3(18) C1 Co C23 C22 101.7(2) C2 Co C23 C22 72.2(3) C4 Co C23 C22 -164.0(2) C24 Co C23 C22 -118.7(3) C20 Co C23 C22 -80.3(2) C21 Co C23 C22 -37.1(2) C3 Co C23 C28 -29(2) C1 Co C23 C28 -20.5(5) C2 Co C23 C28 -50.0(5) C4 Co C23 C28 73.8(5) C24 Co C23 C28 119.1(5) C20 Co C23 C28 157.5(5) C22 Co C23 C28 -122.2(5) C21 Co C23 C28 -159.3(5) C22 C23 C24 C20 0.2(4) C28 C23 C24 C20 178.3(4) Co C23 C24 C20 -60.4(2) C22 C23 C24 C29 -176.8(4) C28 C23 C24 C29 1.3(6) Co C23 C24 C29 122.5(4) C22 C23 C24 Co 60.7(3) C28 C23 C24 Co -121.2(4) C21 C20 C24 C23 -1.1(4) C25 C20 C24 C23 -179.1(4) Co C20 C24 C23 60.0(3) C21 C20 C24 C29 176.0(4) C25 C20 C24 C29 -2.0(6) Co C20 C24 C29 -123.0(4) C21 C20 C24 Co -61.0(3) C25 C20 C24 Co 120.9(4) C3 Co C24 C23 175.5(2) C1 Co C24 C23 53.8(3) C2 Co C24 C23 54.7(10) C4 Co C24 C23 150.9(2) C20 Co C24 C23 -117.9(3) C22 Co C24 C23 -37.9(2) C21 Co C24 C23 -80.7(2) C3 Co C24 C20 -66.6(3) C1 Co C24 C20 171.7(2) C2 Co C24 C20 172.6(8) C4 Co C24 C20 -91.2(2) C23 Co C24 C20 117.9(3) C22 Co C24 C20 80.0(2) C21 Co C24 C20 37.2(2) C3 Co C24 C29 53.8(5) C1 Co C24 C29 -67.9(5) C2 Co C24 C29 -67.0(11) C4 Co C24 C29 29.2(4) C23 Co C24 C29 -121.7(5) C20 Co C24 C29 120.4(5) C22 Co C24 C29 -159.6(4) C21 Co C24 C29 157.6(4)