data_4116422 loop_ _publ_author_name 'Jean Michel Brunel' 'Olivier Legrand' 'S\'ebastien Reymond' 'G\'erard Buono' _publ_section_title ; First Iminodiazaphospholidines with a Stereogenic Phosphorus Center. Application to Asymmetric Copper-Catalyzed Cyclopropanation ; _journal_name_full 'Journal of the American Chemical Society' _journal_page_first 5807 _journal_page_last 5808 _journal_volume 121 _journal_year 1999 _cod_data_source_file ja984295g.hkl _cod_data_source_block test loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_meas _refln_F_squared_calc _refln_F_squared_sigma 1 0 3 6745.4 7249.5 477.3 1 1 2 656.2 636.1 33.2 1 1 4 768.2 652.6 36.5 1 1 6 323.5 396.1 17.9 2 -1 1 1067.2 2614.7 108.0 2 -1 3 1888.8 2015.6 67.7 2 -1 5 65.0 53.3 7.4 2 0 2 7438.6 7842.5 260.6 2 0 4 5021.2 4968.1 172.3 2 0 6 354.6 308.1 18.3 2 0 8 177.6 145.6 14.9 2 1 1 14421.0 46180.8 1686.4 2 1 3 4317.1 4109.1 158.4 2 1 5 2394.3 2436.6 152.8 2 1 7 718.8 583.5 117.0 2 2 0 218.6 870.4 34.1 2 2 2 2250.0 2364.3 66.3 2 2 4 60.0 59.5 3.7 3 -2 3 1852.6 1789.7 58.4 3 -2 5 6251.0 6220.5 243.7 3 -2 7 1542.3 1573.4 73.2 3 -1 0 4140.8 6831.1 342.5 3 -1 2 2344.7 2571.3 61.8 3 -1 4 3437.8 3247.4 139.0 3 -1 6 122.2 150.4 10.5 3 -1 8 35.1 22.9 9.9 3 0 1 3007.6 3360.4 86.6 3 0 3 15071.9 16304.0 513.4 3 0 5 4142.1 4028.3 170.9 3 1 2 4926.3 5006.3 149.3 3 1 4 12529.6 10764.4 650.4 3 1 6 1399.3 1268.9 69.7 3 1 8 867.2 811.5 43.5 3 2 1 4892.1 5650.8 140.2 3 2 3 3077.3 3260.2 95.5 3 2 5 1309.3 1231.4 44.0 3 2 7 277.6 268.3 13.2 3 3 0 115.8 111.9 6.6 3 3 2 5196.0 5795.6 154.8 3 3 4 47.9 35.0 5.8 3 3 6 734.7 721.2 30.2 4 -3 1 3168.4 3262.0 82.1 4 -3 3 163.3 158.4 7.6 4 -3 5 142.6 148.8 10.7 4 -3 7 340.9 350.0 14.3 4 -3 9 140.7 162.0 12.7 4 -2 0 20748.7 23159.3 995.5 4 -2 2 4979.4 5401.8 125.7 4 -2 4 5275.6 5041.1 161.9 4 -2 6 288.2 351.2 17.2 4 -2 8 684.7 755.8 36.0 4 -1 3 5493.9 5594.7 211.9 4 -1 5 948.3 877.3 29.4 4 -1 7 1238.0 1288.7 51.3 4 -1 9 174.1 197.9 19.8 4 0 0 414.9 436.3 21.1 4 0 2 2132.6 2260.8 58.0 4 0 4 100.7 101.6 8.2 4 0 6 282.7 269.3 13.7 4 1 1 2633.4 2487.5 75.8 4 1 3 912.2 977.3 29.4 4 1 5 2314.2 2241.4 107.2 4 1 7 236.1 173.2 21.2 4 2 0 17244.1 19448.2 808.5 4 2 2 2483.9 2752.4 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