Crystallography Open Database

Information card for entry 7018906

Preview

Coordinates	7018906.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	bis((μ2-3,5-bis(trifluoromethyl)pyrazolato)-bis(η2-ethylene)-rhodium(i))
Formula	C18 H18 F12 N4 Rh2
Calculated formula	C18 H18 F12 N4 Rh2
SMILES	[Rh]123(n4[n]([Rh]56([n]7n1c(C(F)(F)F)cc7C(F)(F)F)([CH2]=[CH2]5)[CH2]=[CH2]6)c(cc4C(F)(F)F)C(F)(F)F)([CH2]=[CH2]2)[CH2]=[CH2]3
Title of publication	Rhodium pyrazolate complexes as potential CVD precursors.
Authors of publication	Rivers, Joseph H.; Depue Anderson, Lauren J.; Starr, Cotton M. N.; Jones, Richard A.
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2012
Journal volume	41
Journal issue	17
Pages of publication	5401 - 5408
a	9.3215 ± 0.0017 Å
b	19.009 ± 0.003 Å
c	13.182 ± 0.002 Å
α	90°
β	101.582 ± 0.005°
γ	90°
Cell volume	2288.2 ± 0.7 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0746
Residual factor for significantly intense reflections	0.0487
Weighted residual factors for significantly intense reflections	0.0915
Weighted residual factors for all reflections included in the refinement	0.1002
Goodness-of-fit parameter for all reflections included in the refinement	1.086
Diffraction radiation wavelength	0.71069 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179893 (current)	2016-03-25	cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/89.	7018906.cif
120112	2014-07-12	Adding DOIs to range 7 structures.	7018906.cif
55991	2012-05-08	cif/ Adding structures of 7018906, 7018907, 7018908, 7018909, 7018910 via cif-deposit CGI script.	7018906.cif