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Information card for entry 7035574
Preview
| Coordinates | 7035574.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Chemical name | bis(μ~2~-Bromo)-bis(N,N'-bis(2,6-dimethylphenyl)pentane-2,4-diiminato-N,N')-diphenyl-di-rhodium(II) toluene solvate |
|---|---|
| Formula | C49 H62 Br2 N4 Rh2 |
| Calculated formula | C49 H62 Br2 N4 Rh2 |
| Title of publication | Rhodium(ii) dimers without metal-metal bonds. |
| Authors of publication | Zhu, Di; Sharma, Arzoo Z.; Wiebe, Christopher R.; Budzelaar, Peter H. M. |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2015 |
| Journal volume | 44 |
| Journal issue | 30 |
| Pages of publication | 13460 - 13463 |
| a | 18.862 ± 0.007 Å |
| b | 11.848 ± 0.005 Å |
| c | 14.22 ± 0.005 Å |
| α | 90° |
| β | 131.564 ± 0.013° |
| γ | 90° |
| Cell volume | 2377.7 ± 1.6 Å3 |
| Cell temperature | 293 ± 2 K |
| Ambient diffraction temperature | 293 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 12 |
| Hermann-Mauguin space group symbol | C 1 2/m 1 |
| Hall space group symbol | -C 2y |
| Residual factor for all reflections | 0.0358 |
| Residual factor for significantly intense reflections | 0.0347 |
| Weighted residual factors for significantly intense reflections | 0.1024 |
| Weighted residual factors for all reflections included in the refinement | 0.1042 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.05 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 176428 (current) | 2016-02-13 | Replaced deprecated COD CIF data names with their more modern alternatives. The _cod_cif_authors_sg_Hall and _cod_cif_authors_sg_H-M data items were renamed to _cod_original_sg_symbol_Hall and _cod_cif_authors_sg_H-M respectively. |
7035574.cif |
| 153148 | 2015-08-08 | cif/ Updating files of 7035573, 7035574 Original log message: Adding full bibliography for 7035573--7035574.cif. |
7035574.cif |
| 139712 | 2015-06-27 | cif/ Adding structures of 7035573, 7035574 via cif-deposit CGI script. |
7035574.cif |
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Users of the data should acknowledge the original authors of the
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