#------------------------------------------------------------------------------
#$Date: 2018-01-10 07:45:33 +0200 (Wed, 10 Jan 2018) $
#$Revision: 205019 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/99/7229935.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7229935
loop_
_publ_author_name
'Yang, Wei'
'Lu, Huanchang'
'Liao, Longyu'
'Fan, Guijuan'
'Ma, Qing'
'Huang, Jinglun'
_publ_section_title
;
 Synthesis, and single crystal structure of fully-substituted
 polynitrobenzene derivatives for high-energy materials
;
_journal_issue                   4
_journal_name_full               'RSC Advances'
_journal_page_first              2203
_journal_paper_doi               10.1039/C7RA13346D
_journal_volume                  8
_journal_year                    2018
_chemical_formula_sum            'C10 H8 N10 O4'
_chemical_formula_weight         332.26
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2017-05-25 deposited with the CCDC.
2018-01-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 106.328(15)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.941(3)
_cell_length_b                   7.445(3)
_cell_length_c                   20.759(7)
_cell_measurement_reflns_used    509
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      39.658
_cell_measurement_theta_min      4.747
_cell_volume                     1326.1(8)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0749
_diffrn_reflns_av_unetI/netI     0.0746
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            7331
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.499
_diffrn_reflns_theta_min         2.045
_exptl_absorpt_coefficient_mu    0.135
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6267
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.664
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             680
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.130
_exptl_crystal_size_min          0.070
_refine_diff_density_max         0.245
_refine_diff_density_min         -0.218
_refine_diff_density_rms         0.052
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.974
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     225
_refine_ls_number_reflns         2456
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.974
_refine_ls_R_factor_all          0.1012
_refine_ls_R_factor_gt           0.0522
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0574P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1137
_refine_ls_wR_factor_ref         0.1328
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1430
_reflns_number_total             2456
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7ra13346d2.cif
_cod_data_source_block           cd16469
_cod_database_code               7229935
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.977
_shelx_estimated_absorpt_t_max   0.991
_shelxl_version_number           2013-4
_shelx_res_file
; 
TITL cd16469    P21/c 
CELL  0.71073    8.9410    7.4450   20.7590    90.000   106.328    90.000 
ZERR  4           0.0030    0.0030    0.0070     0.000     0.015     0.000 
LATT 1 
SYMM             - X ,    0.50000 + Y ,    0.50000 - Z 
SFAC C  H  N  O 
UNIT 40 32 40 16 
OMIT  -3.00  51.00 
L.S. 10 
ACTA 
BOND $H 
FMAP 2 
PLAN 0 
CONF 
size 0.17 0.13 0.07 
wpdb -1 
mpla n8 n9 n10 c9 c10 
mpla n1 n2 n3 c7 c8 
mpla c1 > c6 
htab 
conf 
WGHT    0.057400 
FVAR       0.19113 
N1    3    0.639110    0.162502    0.133082    11.00000    0.03082    0.03583 = 
         0.02586   -0.00142    0.01170   -0.00673 
N2    3    0.539831    0.026583    0.137339    11.00000    0.05434    0.04466 = 
         0.03765   -0.00011    0.01891   -0.01764 
N3    3    0.633491    0.164014    0.237241    11.00000    0.05248    0.05698 = 
         0.02880   -0.00061    0.01706   -0.00289 
N4    3    0.403284    0.231984    0.020448    11.00000    0.02579    0.06651 = 
         0.03442    0.00494    0.00992   -0.00054 
N5    3    0.458648    0.358024   -0.100761    11.00000    0.03307    0.04722 = 
         0.02784    0.00245    0.00685    0.00762 
N6    3    0.774496    0.363114   -0.103202    11.00000    0.03629    0.09588 = 
         0.03383    0.01744    0.01569    0.00327 
AFIX  93 
H6A   2    0.869802    0.363180   -0.104484    11.00000   -1.20000 
H6B   2    0.701454    0.395970   -0.137852    11.00000   -1.20000 
AFIX   0 
N7    3    1.018048    0.239299    0.006568    11.00000    0.02551    0.05511 = 
         0.02885    0.00171    0.01005    0.00607 
N8    3    0.942194    0.167685    0.128089    11.00000    0.02584    0.04488 = 
         0.03069    0.00167    0.00547   -0.00004 
N9    3    1.047044    0.297311    0.157629    11.00000    0.03792    0.06288 = 
         0.03915   -0.00585   -0.00215   -0.00612 
N10   3    1.097329    0.034309    0.213329    11.00000    0.05559    0.08634 = 
         0.05282    0.01727   -0.00508    0.01208 
O1    4    0.324489    0.363254   -0.096616    11.00000    0.02725    0.10850 = 
         0.04744    0.01764    0.01089    0.01785 
O2    4    0.483568    0.399429   -0.153358    11.00000    0.04920    0.09517 = 
         0.03070    0.02069    0.01301    0.01615 
O3    4    1.060936    0.324817   -0.033751    11.00000    0.03938    0.09482 = 
         0.05806    0.01543    0.02239   -0.00013 
O4    4    1.102235    0.129624    0.044628    11.00000    0.03574    0.06924 = 
         0.06070    0.00695    0.01815    0.01001 
C1    1    0.671659    0.200452    0.071415    11.00000    0.03128    0.03046 = 
         0.02316   -0.00140    0.00954   -0.00297 
C2    1    0.546294    0.244551    0.014275    11.00000    0.02832    0.02771 = 
         0.02913   -0.00362    0.00980   -0.00150 
C3    1    0.583022    0.305064   -0.043998    11.00000    0.02916    0.03258 = 
         0.02531   -0.00110    0.00724    0.00155 
C4    1    0.740415    0.312719   -0.048200    11.00000    0.03331    0.03751 = 
         0.02777   -0.00298    0.01115   -0.00104 
C5    1    0.858294    0.257972    0.009585    11.00000    0.02525    0.03924 = 
         0.03205   -0.00129    0.01134   -0.00369 
C6    1    0.822133    0.206298    0.068425    11.00000    0.02648    0.03025 = 
         0.02755   -0.00259    0.00716    0.00197 
C7    1    0.692600    0.241748    0.193269    11.00000    0.03808    0.05026 = 
         0.02367   -0.00527    0.00795   -0.00601 
AFIX  43 
H7    2    0.761675    0.337982    0.202456    11.00000   -1.20000 
AFIX   0 
C8    1    0.541480    0.035070    0.200378    11.00000    0.05902    0.05684 = 
         0.03635    0.00386    0.02519   -0.01057 
AFIX  43 
H8    2    0.483086   -0.042629    0.218762    11.00000   -1.20000 
AFIX   0 
C9    1    0.975876    0.014769    0.161997    11.00000    0.04693    0.05035 = 
         0.05274    0.01472    0.00808    0.00615 
AFIX  43 
H9    2    0.920180   -0.091590    0.150557    11.00000   -1.20000 
AFIX   0 
C10   1    1.135128    0.207778    0.208216    11.00000    0.04741    0.08681 = 
         0.04634    0.00056   -0.00801   -0.00063 
AFIX  43 
H10   2    1.219520    0.260924    0.239099    11.00000   -1.20000 
AFIX   0 
H4B   2    0.331638    0.251932   -0.014874    11.00000    0.03188 
H4A   2    0.396479    0.175129    0.058422    11.00000    0.05254 
HKLF 4 1  1.0000  0.0000  0.0000  0.0000 -1.0000  0.0000 -1.0000  0.0000 -1.0000 
  
REM  cd16469    P21/c 
REM R1 =  0.0522 for    1430 Fo > 4sig(Fo)  and  0.1012 for all    2456 data 
REM    225 parameters refined using      0 restraints 
  
END 
  
WGHT      0.0554      0.0000 
  
REM Instructions for potential hydrogen bonds 
HTAB N6 O3 
EQIV $1 x, -y+1/2, z-1/2 
HTAB N6 N3_$1 
HTAB N6 O2 
EQIV $2 -x+2, y+1/2, -z+1/2 
HTAB C7 N10_$2 
EQIV $3 -x+1, y-1/2, -z+1/2 
HTAB C8 N3_$3 
HTAB N4 O1 
EQIV $4 x-1, y, z 
HTAB N4 O3_$4 
HTAB N4 N2 
  
REM Highest difference peak  0.245,  deepest hole -0.218,  1-sigma level  0.052 
Q1    1   0.6985  0.3230 -0.1520  11.00000  0.05    0.25 
Q2    1   0.9272  0.2445  0.0105  11.00000  0.05    0.24 
Q3    1   0.8513  0.1938  0.0332  11.00000  0.05    0.23 
Q4    1   0.2684  0.2528  0.0479  11.00000  0.05    0.20 
Q5    1   1.1550  0.2557  0.1569  11.00000  0.05    0.20 
Q6    1   0.2310  0.3134 -0.1585  11.00000  0.05    0.19 
Q7    1   0.7200  0.1024  0.2725  11.00000  0.05    0.19 
Q8    1   0.4147  0.5523 -0.1803  11.00000  0.05    0.18 
Q9    1   0.5778  0.2085 -0.0201  11.00000  0.05    0.18 
Q10   1   0.8116  0.3235 -0.0093  11.00000  0.05    0.18 
Q11   1   0.9151  0.4448  0.0210  11.00000  0.05    0.18 
Q12   1   0.7341  0.1269  0.0581  11.00000  0.05    0.17 
Q13   1   0.6528  0.2975 -0.0475  11.00000  0.05    0.17 
Q14   1   1.1598  0.2094  0.1096  11.00000  0.05    0.17 
Q15   1   0.3584  0.4649 -0.1423  11.00000  0.05    0.17 
Q16   1   0.7327  0.2624  0.0723  11.00000  0.05    0.16 
Q17   1   1.1256  0.0218  0.1137  11.00000  0.05    0.16 
Q18   1   0.8788  0.2085  0.0912  11.00000  0.05    0.16 
Q19   1   0.5526  0.3414 -0.0057  11.00000  0.05    0.16 
Q20   1   0.3633  0.2636 -0.0955  11.00000  0.05    0.16 
;
_shelx_res_checksum              95982
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
N1 N 0.6391(3) 0.1625(3) 0.13308(10) 0.0301(6) Uani 1 1 d . .
N2 N 0.5398(3) 0.0266(4) 0.13734(12) 0.0443(7) Uani 1 1 d . .
N3 N 0.6335(3) 0.1640(4) 0.23724(12) 0.0449(7) Uani 1 1 d . .
N4 N 0.4033(3) 0.2320(4) 0.02045(16) 0.0419(7) Uani 1 1 d . .
N5 N 0.4586(3) 0.3580(3) -0.10076(11) 0.0364(6) Uani 1 1 d . .
N6 N 0.7745(3) 0.3631(4) -0.10320(12) 0.0541(8) Uani 1 1 d . .
H6A H 0.8698 0.3632 -0.1045 0.065 Uiso 1 1 calc R U
H6B H 0.7015 0.3960 -0.1379 0.065 Uiso 1 1 calc R U
N7 N 1.0180(3) 0.2393(4) 0.00657(12) 0.0360(6) Uani 1 1 d . .
N8 N 0.9422(3) 0.1677(3) 0.12809(11) 0.0343(6) Uani 1 1 d . .
N9 N 1.0470(3) 0.2973(4) 0.15763(13) 0.0493(7) Uani 1 1 d . .
N10 N 1.0973(4) 0.0343(5) 0.21333(15) 0.0691(9) Uani 1 1 d . .
O1 O 0.3245(3) 0.3633(4) -0.09662(10) 0.0610(8) Uani 1 1 d . .
O2 O 0.4836(2) 0.3994(3) -0.15336(10) 0.0580(7) Uani 1 1 d . .
O3 O 1.0609(3) 0.3248(4) -0.03375(12) 0.0623(7) Uani 1 1 d . .
O4 O 1.1022(2) 0.1296(3) 0.04463(11) 0.0543(7) Uani 1 1 d . .
C1 C 0.6717(3) 0.2005(4) 0.07142(12) 0.0279(7) Uani 1 1 d . .
C2 C 0.5463(3) 0.2446(4) 0.01427(13) 0.0280(7) Uani 1 1 d . .
C3 C 0.5830(3) 0.3051(4) -0.04400(13) 0.0291(7) Uani 1 1 d . .
C4 C 0.7404(3) 0.3127(4) -0.04820(13) 0.0323(7) Uani 1 1 d . .
C5 C 0.8583(3) 0.2580(4) 0.00959(14) 0.0315(7) Uani 1 1 d . .
C6 C 0.8221(3) 0.2063(4) 0.06842(13) 0.0282(7) Uani 1 1 d . .
C7 C 0.6926(3) 0.2417(4) 0.19327(13) 0.0375(8) Uani 1 1 d . .
H7 H 0.7617 0.3380 0.2025 0.045 Uiso 1 1 calc R U
C8 C 0.5415(4) 0.0351(5) 0.20038(15) 0.0483(9) Uani 1 1 d . .
H8 H 0.4831 -0.0426 0.2188 0.058 Uiso 1 1 calc R U
C9 C 0.9759(4) 0.0148(5) 0.16200(16) 0.0512(9) Uani 1 1 d . .
H9 H 0.9202 -0.0916 0.1506 0.061 Uiso 1 1 calc R U
C10 C 1.1351(4) 0.2078(6) 0.20822(18) 0.0645(11) Uani 1 1 d . .
H10 H 1.2195 0.2609 0.2391 0.077 Uiso 1 1 calc R U
H4B H 0.332(4) 0.252(4) -0.0149(15) 0.032(9) Uiso 1 1 d . .
H4A H 0.396(4) 0.175(4) 0.0584(17) 0.053(10) Uiso 1 1 d . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
N1 0.0308(13) 0.0358(15) 0.0259(13) -0.0014(11) 0.0117(11) -0.0067(11)
N2 0.0543(17) 0.0447(17) 0.0376(15) -0.0001(13) 0.0189(13) -0.0176(14)
N3 0.0525(18) 0.0570(19) 0.0288(14) -0.0006(13) 0.0171(13) -0.0029(15)
N4 0.0258(16) 0.067(2) 0.0344(17) 0.0049(15) 0.0099(14) -0.0005(14)
N5 0.0331(16) 0.0472(17) 0.0278(14) 0.0024(12) 0.0069(12) 0.0076(12)
N6 0.0363(16) 0.096(2) 0.0338(15) 0.0174(15) 0.0157(12) 0.0033(16)
N7 0.0255(14) 0.0551(18) 0.0289(13) 0.0017(13) 0.0101(12) 0.0061(13)
N8 0.0258(14) 0.0449(17) 0.0307(13) 0.0017(12) 0.0055(11) 0.0000(12)
N9 0.0379(16) 0.063(2) 0.0392(15) -0.0058(15) -0.0022(13) -0.0061(14)
N10 0.056(2) 0.086(3) 0.0528(19) 0.0173(19) -0.0051(16) 0.0121(19)
O1 0.0272(13) 0.108(2) 0.0474(14) 0.0176(14) 0.0109(11) 0.0178(13)
O2 0.0492(15) 0.095(2) 0.0307(12) 0.0207(12) 0.0130(11) 0.0161(13)
O3 0.0394(14) 0.095(2) 0.0581(15) 0.0154(14) 0.0224(12) -0.0001(13)
O4 0.0357(14) 0.0692(17) 0.0607(15) 0.0070(13) 0.0181(12) 0.0100(12)
C1 0.0313(17) 0.0305(17) 0.0232(14) -0.0014(13) 0.0095(12) -0.0030(13)
C2 0.0283(17) 0.0277(17) 0.0291(15) -0.0036(13) 0.0098(13) -0.0015(13)
C3 0.0292(16) 0.0326(17) 0.0253(14) -0.0011(13) 0.0072(12) 0.0016(13)
C4 0.0333(17) 0.0375(18) 0.0278(15) -0.0030(14) 0.0111(13) -0.0010(14)
C5 0.0252(16) 0.0392(19) 0.0320(16) -0.0013(14) 0.0113(13) -0.0037(13)
C6 0.0265(16) 0.0302(17) 0.0275(15) -0.0026(13) 0.0072(13) 0.0020(12)
C7 0.0381(18) 0.050(2) 0.0237(15) -0.0053(14) 0.0080(14) -0.0060(15)
C8 0.059(2) 0.057(2) 0.0363(18) 0.0039(17) 0.0252(16) -0.0106(19)
C9 0.047(2) 0.050(2) 0.053(2) 0.0147(19) 0.0081(18) 0.0061(18)
C10 0.047(2) 0.087(3) 0.046(2) 0.001(2) -0.0080(18) -0.001(2)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C7 N1 N2 109.5(2)
C7 N1 C1 130.0(2)
N2 N1 C1 120.5(2)
C8 N2 N1 101.8(2)
C7 N3 C8 102.7(2)
C2 N4 H4B 115(2)
C2 N4 H4A 115(2)
H4B N4 H4A 128(3)
O2 N5 O1 119.0(2)
O2 N5 C3 121.0(2)
O1 N5 C3 120.0(2)
C4 N6 H6A 120.0
C4 N6 H6B 120.0
H6A N6 H6B 120.0
O3 N7 O4 122.8(3)
O3 N7 C5 119.4(3)
O4 N7 C5 117.7(3)
C9 N8 N9 110.1(2)
C9 N8 C6 129.7(3)
N9 N8 C6 120.2(2)
C10 N9 N8 100.6(3)
C9 N10 C10 102.3(3)
C6 C1 N1 120.2(2)
C6 C1 C2 120.7(2)
N1 C1 C2 119.0(2)
N4 C2 C3 124.7(3)
N4 C2 C1 117.3(3)
C3 C2 C1 118.0(2)
C2 C3 N5 118.6(2)
C2 C3 C4 122.2(2)
N5 C3 C4 119.2(2)
N6 C4 C5 121.2(3)
N6 C4 C3 122.3(3)
C5 C4 C3 116.5(2)
C6 C5 C4 121.2(2)
C6 C5 N7 118.8(2)
C4 C5 N7 119.8(2)
C1 C6 C5 121.3(2)
C1 C6 N8 117.8(2)
C5 C6 N8 120.8(2)
N3 C7 N1 110.3(3)
N3 C7 H7 124.9
N1 C7 H7 124.9
N2 C8 N3 115.8(3)
N2 C8 H8 122.1
N3 C8 H8 122.1
N10 C9 N8 110.6(3)
N10 C9 H9 124.7
N8 C9 H9 124.7
N9 C10 N10 116.4(3)
N9 C10 H10 121.8
N10 C10 H10 121.8
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
N1 C7 1.342(3)
N1 N2 1.365(3)
N1 C1 1.419(3)
N2 C8 1.306(4)
N3 C7 1.311(4)
N3 C8 1.353(4)
N4 C2 1.324(4)
N4 H4B 0.84(3)
N4 H4A 0.91(3)
N5 O2 1.214(3)
N5 O1 1.227(3)
N5 C3 1.430(3)
N6 C4 1.316(3)
N6 H6A 0.8600
N6 H6B 0.8600
N7 O3 1.197(3)
N7 O4 1.234(3)
N7 C5 1.454(4)
N8 C9 1.328(4)
N8 N9 1.365(3)
N8 C6 1.422(3)
N9 C10 1.305(4)
N10 C9 1.298(4)
N10 C10 1.347(5)
C1 C6 1.365(4)
C1 C2 1.423(4)
C2 C3 1.413(4)
C3 C4 1.435(4)
C4 C5 1.416(4)
C5 C6 1.402(4)
C7 H7 0.9300
C8 H8 0.9300
C9 H9 0.9300
C10 H10 0.9300
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C7 N1 N2 C8 0.0(3)
C1 N1 N2 C8 179.9(3)
C9 N8 N9 C10 -0.6(3)
C6 N8 N9 C10 -178.9(3)
C7 N1 C1 C6 53.7(4)
N2 N1 C1 C6 -126.1(3)
C7 N1 C1 C2 -121.9(3)
N2 N1 C1 C2 58.3(4)
C6 C1 C2 N4 178.5(3)
N1 C1 C2 N4 -5.9(4)
C6 C1 C2 C3 -3.9(4)
N1 C1 C2 C3 171.7(2)
N4 C2 C3 N5 0.4(4)
C1 C2 C3 N5 -177.1(3)
N4 C2 C3 C4 -178.8(3)
C1 C2 C3 C4 3.8(4)
O2 N5 C3 C2 -175.0(3)
O1 N5 C3 C2 5.4(4)
O2 N5 C3 C4 4.2(4)
O1 N5 C3 C4 -175.3(3)
C2 C3 C4 N6 177.6(3)
N5 C3 C4 N6 -1.6(4)
C2 C3 C4 C5 -0.6(4)
N5 C3 C4 C5 -179.8(3)
N6 C4 C5 C6 179.2(3)
C3 C4 C5 C6 -2.5(4)
N6 C4 C5 N7 -6.3(4)
C3 C4 C5 N7 172.0(3)
O3 N7 C5 C6 -159.7(3)
O4 N7 C5 C6 22.9(4)
O3 N7 C5 C4 25.7(4)
O4 N7 C5 C4 -151.7(3)
N1 C1 C6 C5 -174.7(2)
C2 C1 C6 C5 0.9(4)
N1 C1 C6 N8 2.0(4)
C2 C1 C6 N8 177.5(2)
C4 C5 C6 C1 2.5(4)
N7 C5 C6 C1 -172.1(3)
C4 C5 C6 N8 -174.1(3)
N7 C5 C6 N8 11.4(4)
C9 N8 C6 C1 66.7(4)
N9 N8 C6 C1 -115.5(3)
C9 N8 C6 C5 -116.7(4)
N9 N8 C6 C5 61.2(4)
C8 N3 C7 N1 -0.3(3)
N2 N1 C7 N3 0.2(3)
C1 N1 C7 N3 -179.6(3)
N1 N2 C8 N3 -0.2(4)
C7 N3 C8 N2 0.3(4)
C10 N10 C9 N8 -0.2(4)
N9 N8 C9 N10 0.5(4)
C6 N8 C9 N10 178.6(3)
N8 N9 C10 N10 0.5(4)
C9 N10 C10 N9 -0.2(5)