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Information card for entry 7250395
Preview
| Coordinates | 7250395.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C41 H34 Cl N2 Ni P |
|---|---|
| Calculated formula | C41 H34 Cl N2 Ni P |
| Title of publication | Chiral PCN pincer Ni(ii) complex-catalyzed asymmetric hydrophosphination of 2-alkenoylpyridines with diphenylphosphine |
| Authors of publication | Li, Jin-Ge; Qiu, Bing-Bo; Jiang, Hui; Song, Mao-Ping; Gong, Jun-Fang |
| Journal of publication | RSC Advances |
| Year of publication | 2025 |
| Journal volume | 15 |
| Journal issue | 20 |
| Pages of publication | 15904 - 15918 |
| a | 9.9018 ± 0.00014 Å |
| b | 16.9395 ± 0.0003 Å |
| c | 19.7237 ± 0.0003 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 3308.29 ± 0.09 Å3 |
| Cell temperature | 293 ± 2 K |
| Ambient diffraction temperature | 293 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 19 |
| Hermann-Mauguin space group symbol | P 21 21 21 |
| Hall space group symbol | P 2ac 2ab |
| Residual factor for all reflections | 0.0447 |
| Residual factor for significantly intense reflections | 0.0397 |
| Weighted residual factors for significantly intense reflections | 0.094 |
| Weighted residual factors for all reflections included in the refinement | 0.0976 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.046 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 1.54184 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 299687 (current) | 2025-05-15 | cif/ Adding structures of 7250395, 7250396, 7250397 via cif-deposit CGI script. |
7250395.cif |
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Users of the data should acknowledge the original authors of the
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