#------------------------------------------------------------------------------
#$Date: 2008-01-14 00:15:36 +0200 (Mon, 14 Jan 2008) $
#$Revision: 14 $
#$URL: file:///home/coder/svn-repositories/cod/cif/9/9001224.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_9001224
_chemical_name 'Geigerite'
loop_
_publ_author_name
'Graeser S'
'Schwander H'
'Bianchi R'
'Pilati T'
'Gramaccioli C M'
_journal_name_full "American Mineralogist"
_journal_volume 74
_journal_year 1989
_journal_page_first 676
_journal_page_last 684
_publ_section_title
;
 Geigerite, the Mn analogue of chudobaite: Its description and crystal structure
;
_chemical_formula_sum 'As4 Mn5 O26 H22'
_cell_length_a 7.944
_cell_length_b 10.691
_cell_length_c 6.770
_cell_angle_alpha 80.97
_cell_angle_beta 84.20
_cell_angle_gamma 81.85
_cell_volume 560.281
_symmetry_space_group_name_H-M 'P -1'
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_Uiso_or_equiv
As1   0.36967   0.36543   0.40344 ?
As2  -0.03902   0.33350  -0.07716 ?
Mn1   0.00000   0.00000   0.00000 ?
Mn2   0.08271   0.59557   0.59920 ?
Mn3   0.36170   0.43412  -0.10853 ?
O1   0.18600   0.30510   0.35710 ?
O2   0.50370   0.23720   0.48640 ?
O3   0.43830   0.44250   0.18210 ?
O4   0.31520   0.46180   0.57760 ?
O5  -0.11730   0.19690  -0.09000 ?
O6  -0.04800   0.42680  -0.30160 ?
O7   0.16770   0.31020  -0.01900 ?
O8  -0.15250   0.40940   0.10350 ?
O9   0.15790   0.78510   0.51520 ?
O10   0.53240   0.24780  -0.11980 ?
O11   0.08630   0.04360   0.27510 ?
O12   0.23210   0.06200  -0.16160 ?
O13   0.55420  -0.06470  -0.24280 ?
H1   0.17900   0.31000   0.21100   0.09000
H91   0.27000   0.77800   0.54300   0.07000
H92   0.12500   0.80500   0.37500   0.10000
H101   0.52700   0.22700  -0.23400   0.10000
H102   0.63600   0.23000  -0.11100   0.05000
H111   0.03200   0.07400   0.37100   0.05000
H112   0.18600   0.05600   0.27400   0.05000
H121   0.33300   0.03300  -0.19100   0.11000
H122   0.24100   0.13700  -0.14600   0.05000
H131   0.52800  -0.10400  -0.32000   0.07000
H132   0.55400  -0.13800  -0.12700   0.33000