#------------------------------------------------------------------------------ #$Date: 2023-07-08 10:42:25 +0300 (Sat, 08 Jul 2023) $ #$Revision: 285095 $ #$URL: file:///home/coder/svn-repositories/cod/cif/9/01/34/9013435.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided the American Mineralogist Crystal Structure Database, # http://rruff.geo.arizona.edu/AMS/amcsd.php # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_9013435 loop_ _publ_author_name 'Bennett, J. M.' 'Smith, J. V.' _publ_section_title ; Positions of cations and molecules in zeolites with the faujasite-type framework III. Hydrated Ca-exchanged faujasite ; _journal_name_full 'Materials Research Bulletin' _journal_page_first 933 _journal_page_last 940 _journal_paper_doi 10.1016/0025-5408(68)90105-0 _journal_volume 3 _journal_year 1968 _chemical_compound_source 'Sasbach, Kaiserstuhl, Germany' _chemical_formula_sum 'Al1.782 Ca0.731 H6 O13.625 Si4.218' _chemical_name_mineral Faujasite-Ca _space_group_IT_number 227 _symmetry_space_group_name_Hall '-F 4vw 2vw 3' _symmetry_space_group_name_H-M 'F d -3 m :2' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_length_a 24.710 _cell_length_b 24.710 _cell_length_c 24.710 _cell_volume 15087.533 _database_code_amcsd 0014217 _exptl_crystal_density_diffrn 1.479 _cod_original_cell_volume 15087.531 _cod_original_sg_symbol_H-M 'F d -3 m' _cod_original_formula_sum '(Si4.218 Al1.782) O13.625 Ca.731 H6' _cod_database_code 9013435 loop_ _space_group_symop_operation_xyz x,y,z x,1/2+y,1/2+z 1/2+x,y,1/2+z 1/2+x,1/2+y,z 3/4+z,1/2-x,1/4+y 3/4+z,-x,3/4+y 1/4+z,1/2-x,3/4+y 1/4+z,-x,1/4+y 3/4-y,1/2+z,1/4-x 3/4-y,+z,3/4-x 1/4-y,1/2+z,3/4-x 1/4-y,+z,1/4-x 3/4+x,1/2-y,1/4+z 3/4+x,-y,3/4+z 1/4+x,1/2-y,3/4+z 1/4+x,-y,1/4+z 3/4-z,1/2+x,1/4-y 3/4-z,+x,3/4-y 1/4-z,1/2+x,3/4-y 1/4-z,+x,1/4-y 3/4+y,1/2-z,1/4+x 3/4+y,-z,3/4+x 1/4+y,1/2-z,3/4+x 1/4+y,-z,1/4+x 3/4-x,1/2+y,1/4-z 3/4-x,+y,3/4-z 1/4-x,1/2+y,3/4-z 1/4-x,+y,1/4-z 1/2+x,3/4-z,1/4-y 1/2+x,1/4-z,3/4-y +x,3/4-z,3/4-y +x,1/4-z,1/4-y 1/2-z,3/4+y,1/4+x 1/2-z,1/4+y,3/4+x -z,3/4+y,3/4+x -z,1/4+y,1/4+x 1/2+y,3/4-x,1/4-z 1/2+y,1/4-x,3/4-z +y,3/4-x,3/4-z +y,1/4-x,1/4-z 1/2-x,3/4+z,1/4+y 1/2-x,1/4+z,3/4+y -x,3/4+z,3/4+y -x,1/4+z,1/4+y 1/2+z,3/4-y,1/4-x 1/2+z,1/4-y,3/4-x +z,3/4-y,3/4-x +z,1/4-y,1/4-x 1/2-y,3/4+x,1/4+z 1/2-y,1/4+x,3/4+z -y,3/4+x,3/4+z -y,1/4+x,1/4+z x,1/2+z,1/2+y x,+z,+y 1/2+x,1/2+z,+y 1/2+x,+z,1/2+y -z,1/2-y,1/2-x -z,-y,-x 1/2-z,1/2-y,-x 1/2-z,-y,1/2-x y,1/2+x,1/2+z y,+x,+z 1/2+y,1/2+x,+z 1/2+y,+x,1/2+z -x,1/2-z,1/2-y -x,-z,-y 1/2-x,1/2-z,-y 1/2-x,-z,1/2-y z,1/2+y,1/2+x z,+y,+x 1/2+z,1/2+y,+x 1/2+z,+y,1/2+x -y,1/2-x,1/2-z -y,-x,-z 1/2-y,1/2-x,-z 1/2-y,-x,1/2-z 3/4+z,1/4+x,1/2-y 3/4+z,3/4+x,-y 1/4+z,1/4+x,-y 1/4+z,3/4+x,1/2-y 3/4-y,1/4-z,1/2+x 3/4-y,3/4-z,+x 1/4-y,1/4-z,+x 1/4-y,3/4-z,1/2+x 3/4+x,1/4+y,1/2-z 3/4+x,3/4+y,-z 1/4+x,1/4+y,-z 1/4+x,3/4+y,1/2-z 3/4-z,1/4-x,1/2+y 3/4-z,3/4-x,+y 1/4-z,1/4-x,+y 1/4-z,3/4-x,1/2+y 3/4+y,1/4+z,1/2-x 3/4+y,3/4+z,-x 1/4+y,1/4+z,-x 1/4+y,3/4+z,1/2-x 3/4-x,1/4-y,1/2+z 3/4-x,3/4-y,+z 1/4-x,1/4-y,+z 1/4-x,3/4-y,1/2+z -z,3/4+x,3/4+y -z,1/4+x,1/4+y 1/2-z,3/4+x,1/4+y 1/2-z,1/4+x,3/4+y y,3/4-z,3/4-x y,1/4-z,1/4-x 1/2+y,3/4-z,1/4-x 1/2+y,1/4-z,3/4-x -x,3/4+y,3/4+z -x,1/4+y,1/4+z 1/2-x,3/4+y,1/4+z 1/2-x,1/4+y,3/4+z z,3/4-x,3/4-y z,1/4-x,1/4-y 1/2+z,3/4-x,1/4-y 1/2+z,1/4-x,3/4-y -y,3/4+z,3/4+x -y,1/4+z,1/4+x 1/2-y,3/4+z,1/4+x 1/2-y,1/4+z,3/4+x x,3/4-y,3/4-z x,1/4-y,1/4-z 1/2+x,3/4-y,1/4-z 1/2+x,1/4-y,3/4-z 1/4-x,1/2+z,3/4-y 1/4-x,+z,1/4-y 3/4-x,1/2+z,1/4-y 3/4-x,+z,3/4-y 1/4+z,1/2-y,3/4+x 1/4+z,-y,1/4+x 3/4+z,1/2-y,1/4+x 3/4+z,-y,3/4+x 1/4-y,1/2+x,3/4-z 1/4-y,+x,1/4-z 3/4-y,1/2+x,1/4-z 3/4-y,+x,3/4-z 1/4+x,1/2-z,3/4+y 1/4+x,-z,1/4+y 3/4+x,1/2-z,1/4+y 3/4+x,-z,3/4+y 1/4-z,1/2+y,3/4-x 1/4-z,+y,1/4-x 3/4-z,1/2+y,1/4-x 3/4-z,+y,3/4-x 1/4+y,1/2-x,3/4+z 1/4+y,-x,1/4+z 3/4+y,1/2-x,1/4+z 3/4+y,-x,3/4+z 3/4-x,3/4-z,y 3/4-x,1/4-z,1/2+y 1/4-x,3/4-z,1/2+y 1/4-x,1/4-z,y 3/4+z,3/4+y,-x 3/4+z,1/4+y,1/2-x 1/4+z,3/4+y,1/2-x 1/4+z,1/4+y,-x 3/4-y,3/4-x,z 3/4-y,1/4-x,1/2+z 1/4-y,3/4-x,1/2+z 1/4-y,1/4-x,z 3/4+x,3/4+z,-y 3/4+x,1/4+z,1/2-y 1/4+x,3/4+z,1/2-y 1/4+x,1/4+z,-y 3/4-z,3/4-y,x 3/4-z,1/4-y,1/2+x 1/4-z,3/4-y,1/2+x 1/4-z,1/4-y,x 3/4+y,3/4+x,-z 3/4+y,1/4+x,1/2-z 1/4+y,3/4+x,1/2-z 1/4+y,1/4+x,-z -z,-x,-y -z,1/2-x,1/2-y 1/2-z,-x,1/2-y 1/2-z,1/2-x,-y y,z,x y,1/2+z,1/2+x 1/2+y,z,1/2+x 1/2+y,1/2+z,x -x,-y,-z -x,1/2-y,1/2-z 1/2-x,-y,1/2-z 1/2-x,1/2-y,-z z,x,y z,1/2+x,1/2+y 1/2+z,x,1/2+y 1/2+z,1/2+x,y -y,-z,-x -y,1/2-z,1/2-x 1/2-y,-z,1/2-x 1/2-y,1/2-z,-x loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv _atom_site_type_symbol _atom_site_attached_hydrogens SiT 0.96390 0.87450 0.05360 0.70300 0.01140 Si 0 AlT 0.96390 0.87450 0.05360 0.29700 0.01140 Al 0 O1 0.10570 0.89430 0.00000 1.00000 0.02913 O 0 O2 0.00270 0.00270 0.85730 1.00000 0.02280 O 0 O3 0.92370 0.92370 0.03250 1.00000 0.02533 O 0 O4 0.92840 0.92840 0.67750 1.00000 0.02406 O 0 O5 0.27380 0.27380 0.27380 0.73100 0.14438 O 0 Ca1 0.06920 0.06920 0.06920 0.30300 0.02913 Ca 0 Ca2 0.16660 0.16660 0.16660 0.35900 0.05953 Ca 0 Ca3 0.48360 0.48360 0.48360 0.06900 0.04306 Ca 0 Wat 0.44100 0.44100 0.57500 0.29800 0.08359 O 2 loop_ _cod_changelog_entry_id _cod_changelog_entry_author _cod_changelog_entry_date _cod_changelog_entry_text 1 ;cod-tools version 3.8.0 Id: cif_guess_AMCSD_atom_types 9581 2023-05-17 12:35:41Z saulius ; 2023-05-23T09:25:00+03:00 ;Derived atom types and hydrogen counts from atom names that follow the AMCSD naming convention (Wat == water, O-H == hydroxyl). ; loop_ _cod_related_entry_id _cod_related_entry_database _cod_related_entry_code 1 AMCSD 0014217 _cell_formula_units_Z 32