Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 4308375
Preview
| Coordinates | 4308375.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C46 H78 N S3 Si6 V |
|---|---|
| Calculated formula | C46 H78 N S3 Si6 V |
| SMILES | [V](Sc1c([Si](C)(C)C)cccc1[Si](C)(C)C)(Sc1c([Si](C)(C)C)cccc1[Si](C)(C)C)(Sc1c([Si](C)(C)C)cccc1[Si](C)(C)C)=NC12CC3CC(C1)CC(C2)C3 |
| Title of publication | Synthesis of a Vanadium(III) Tris(arylthiolato) Complex and Its Reactions with Azide and Azo Compounds: Formation of a Sulfenamide Complex via Cleavage of an Azo NN Bond |
| Authors of publication | Komuro, Takashi; Matsuo, Tsukasa; Kawaguchi, Hiroyuki; Tatsumi, Kazuyuki |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 2005 |
| Journal volume | 44 |
| Journal issue | 2 |
| Pages of publication | 175 - 177 |
| a | 12.295 ± 0.003 Å |
| b | 16.438 ± 0.004 Å |
| c | 27.386 ± 0.007 Å |
| α | 90° |
| β | 99.814 ± 0.003° |
| γ | 90° |
| Cell volume | 5454 ± 2 Å3 |
| Cell temperature | 173.1 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for significantly intense reflections | 0.055 |
| Weighted residual factors for all reflections included in the refinement | 0.154 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.001 |
| Diffraction radiation wavelength | 0.7107 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 210259 (current) | 2018-08-31 | cif/4/30/ Updating bibliography in entries 4300938-4300941, 4308373-4308376. Marking entries 4300938-4300941 as duplicates of entries 4308373-4308376. |
4308375.cif |
| 176467 | 2016-02-16 | cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4. |
4308375.cif |
| 120081 | 2014-07-12 | Adding DOIs to range 4/30 structures. | 4308375.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4308375.cif |
| 32063 | 2012-01-26 | cif/4 Correction of volume and publication year for files coming from a couple of issues of Inorg. Chem. The mistake was made when fetching bibliography for these entries and detected just now. I have checked that all other Inorg. Chem. files are correct. |
4308375.cif |
| 1526 | 2010-09-26 | cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming). |
4308375.cif |
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.