Crystallography Open Database

Information card for entry 7018909

Preview

Coordinates	7018909.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	bis((μ2-3,5-bis(trifluoromethyl)pyrazolato)-bis(trimethylphosphine)-rhodium(i))
Formula	C22 H38 F12 N4 P4 Rh2
Calculated formula	C22 H38 F12 N4 P4 Rh2
SMILES	[Rh]([P](C)(C)C)([P](C)(C)C)([n]1n([Rh]2([P](C)(C)C)[P](C)(C)C)c(C(F)(F)F)cc1C(F)(F)F)[n]1n2c(C(F)(F)F)cc1C(F)(F)F
Title of publication	Rhodium pyrazolate complexes as potential CVD precursors.
Authors of publication	Rivers, Joseph H.; Depue Anderson, Lauren J.; Starr, Cotton M. N.; Jones, Richard A.
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2012
Journal volume	41
Journal issue	17
Pages of publication	5401 - 5408
a	11.0386 ± 0.0003 Å
b	15.8199 ± 0.0004 Å
c	39.769 ± 0.0005 Å
α	90°
β	93.99 ± 0.02°
γ	90°
Cell volume	6928 ± 0.3 Å³
Cell temperature	123 ± 2 K
Ambient diffraction temperature	123 ± 2 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.1108
Residual factor for significantly intense reflections	0.0733
Weighted residual factors for significantly intense reflections	0.2079
Weighted residual factors for all reflections included in the refinement	0.2219
Goodness-of-fit parameter for all reflections included in the refinement	1.855
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179893 (current)	2016-03-25	cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/89.	7018909.cif
120112	2014-07-12	Adding DOIs to range 7 structures.	7018909.cif
55991	2012-05-08	cif/ Adding structures of 7018906, 7018907, 7018908, 7018909, 7018910 via cif-deposit CGI script.	7018909.cif